CN106978075A - White wood wax oil of a kind of environment-friendly spray coating type and its preparation method and application - Google Patents
White wood wax oil of a kind of environment-friendly spray coating type and its preparation method and application Download PDFInfo
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- CN106978075A CN106978075A CN201710330594.6A CN201710330594A CN106978075A CN 106978075 A CN106978075 A CN 106978075A CN 201710330594 A CN201710330594 A CN 201710330594A CN 106978075 A CN106978075 A CN 106978075A
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- wood wax
- wax oil
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- 238000005507 spraying Methods 0.000 title claims abstract description 49
- 235000009414 Elaeocarpus kirtonii Nutrition 0.000 title claims abstract description 35
- 235000013584 Tabebuia pallida Nutrition 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 241000377588 Atalaya hemiglauca Species 0.000 title 1
- 239000003921 oil Substances 0.000 claims abstract description 98
- 235000019198 oils Nutrition 0.000 claims abstract description 98
- 239000002023 wood Substances 0.000 claims abstract description 61
- -1 Polytetrafluoroethylene Polymers 0.000 claims abstract description 34
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000002904 solvent Substances 0.000 claims abstract description 31
- 239000013530 defoamer Substances 0.000 claims abstract description 21
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 20
- 239000008158 vegetable oil Substances 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 17
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 17
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 17
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims abstract description 17
- 239000000839 emulsion Substances 0.000 claims abstract description 16
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 16
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 16
- 244000236151 Tabebuia pallida Species 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 12
- 239000003760 tallow Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 8
- 238000010790 dilution Methods 0.000 claims description 7
- 239000012895 dilution Substances 0.000 claims description 7
- 239000007921 spray Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 4
- 125000004494 ethyl ester group Chemical group 0.000 claims description 3
- 239000011268 mixed slurry Substances 0.000 claims description 3
- 239000011435 rock Substances 0.000 claims description 3
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000007664 blowing Methods 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 239000011572 manganese Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 150000007524 organic acids Chemical group 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 239000000344 soap Substances 0.000 claims description 2
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 239000008159 sesame oil Substances 0.000 claims 1
- 235000011803 sesame oil Nutrition 0.000 claims 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract description 18
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract description 15
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract description 12
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract description 8
- 229910052804 chromium Inorganic materials 0.000 abstract description 8
- 239000011651 chromium Substances 0.000 abstract description 8
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 6
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052753 mercury Inorganic materials 0.000 abstract description 5
- 229960004279 formaldehyde Drugs 0.000 abstract description 4
- 235000019256 formaldehyde Nutrition 0.000 abstract description 4
- 241000199223 Elaeocarpus kirtonii Species 0.000 abstract 1
- 239000001993 wax Substances 0.000 description 76
- 230000000052 comparative effect Effects 0.000 description 13
- 238000000576 coating method Methods 0.000 description 10
- 239000003973 paint Substances 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 6
- 239000004203 carnauba wax Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000001514 detection method Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000021388 linseed oil Nutrition 0.000 description 2
- 239000000944 linseed oil Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000012178 vegetable wax Substances 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention relates to white wood wax oil of a kind of environment-friendly spray coating type and its preparation method and application, the wood wax oil is made up of by mass fraction the following raw material：40~60 parts of vegetable oil, 3~8 parts of Polytetrafluoroethylene emulsion, 20~40 parts of titanium dioxide, 5~10 parts of aldehyde ketone resin, 0.2~0.6 part of ultra-violet absorber, 0.1~0.3 part of defoamer, 0.2~0.5 part of drier, 10~25 parts of environmentally friendly solvent.Compared with traditional wood wax oil, the wood wax oil that the present invention is provided has preferable gloss, wearability, hardness, film forming and stability；The wood wax oil that the present invention is provided can be truly realized no benzene, toluene and Form aldehyde release, while heavy metal free lead, chromium, mercury, chromium are detected, it is preferable for product glossiness and feel after woodwork.In addition, the wood wax oil that the present invention is provided is realized is used for woodwork by wood wax oil in the way of spraying film forming, with larger application value.
Description
Technical field
The present invention relates to technical field of coatings, and in particular to white wood wax oil of a kind of environment-friendly spray coating type and preparation method thereof and
Using.
Background technology
With the raising of economic life water product, the health problem of people's growing interest living environment, and it is sought for green
Colour circle protects raw material for the natural paint of main component to replace traditional coating.Natural paint is due to its totally nontoxic, harmless, health
Natural characteristic start to be welcome by a part, and start to be increasingly used on the fields such as indoor external decoration, finishing.1991
Year, natural paint starts to occur in the Japanese market.Start within 1998, natural class coating is approved by the most of Europe common people.
2000, each government bodies of developed country advised that the common people use natural paint on the finishing, anticorrosive coating of public sphere.2001
Year, " ENAV is organized in Europe（Natural paint TIA）" set up, signed various agreements and joint development material and
Formulate professional standard.Since then, the environmental-friendly natural coating by representative of wood wax oil enters fast-developing passage and the market share
Expand year by year, be a kind of very promising new coating.
Wood wax oil, which is that vegetable oil Wax coatings are domestic, to be commonly called as, and is a kind of similar natural woodenware for painting and being different from paint
Coating.It and that is entirely different based on the paint that petrochemical industry class synthetic resin is produced at present, raw material mainly with refine linseed oil,
The crude vegetals such as palm wax and vegetable wax simultaneously coordinate some other natural component to merge to form.Because oil can be penetrated into timber
Portion, carries out deep layer to timber and moistens maintenance；Wax can combine closely with lumber fibre, enhancing case hardness, water proof anti-soil, therefore,
Wood wax oil can provide most outstanding beautification and protective effect.
Remain able to detect in part haze tallow oil product on the market at present the Elements in Organic Solvents such as toluene, dimethylbenzene with
And heavy metal, or added with chemical naval stores, it is not truly realized materials safety, environmental protection；And also there is product gloss
Difference, low hardness, wearability and film forming are poor, between each composition the problems such as incompatible caused product stability difference.And it is existing
Haze tallow oil component in technology is relatively simple, can only be constructed mostly by way of brushing, it is impossible on wooden articles surface
Film forming, and wood wax oil can not substitute seal coat and the fiber pore of wood internal is filled.Therefore, still need to research and develop a kind of ring
Guarantor, glossiness height, hardness, wearability, good film-forming property, are easy to the wood wax oil of construction.
The content of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of white wood wax oil of environment-friendly spray coating type, this hair
The wood wax oil of bright offer has preferable glossiness, wearability, hardness, film forming and stability, and no benzene, toluene and formaldehyde are released
Put, while heavy metal free lead, chromium, mercury, chromium are detected；Woodwork can be used for by way of spraying film forming.
Another object of the present invention is to provide the preparation method of the white wood wax oil of above-mentioned environment-friendly spray coating type.
Another object of the present invention is to provide the application method of the white wood wax oil of above-mentioned environment-friendly spray coating type.
To achieve the above object, the present invention is adopted the following technical scheme that：
A kind of white wood wax oil of environment-friendly spray coating type, the wood wax oil is made up of by mass fraction the following raw material：
40~60 parts of vegetable oil, 3~8 parts of Polytetrafluoroethylene emulsion, 20~40 parts of titanium dioxide, 5~10 parts of aldehyde ketone resin, ultra-violet absorber
0.2~0.6 part, 0.1~0.3 part of defoamer, 0.2~0.5 part of drier, 10~25 parts of environmentally friendly solvent.
Preferably, the vegetable oil is the one or more in castor oil, linseed oil or blowing oil.
Preferably, the environmentally friendly solvent is D30 solvent naphthas and/or D40 solvent naphthas.
Preferably, the drier is organic acid metal soaps and/or manganese iso-octoate drier.
Preferably, the defoamer is without benzene class polyethers organic silicon defoamer.
As a kind of preferably technical scheme, the wood wax oil is made up of by mass fraction the following raw material：
45~55 parts of vegetable oil, 3~6 parts of Polytetrafluoroethylene emulsion, 25~35 parts of titanium dioxide, 6~8 parts of aldehyde ketone resin, ultra-violet absorber
0.3~0.5 part, 0.15~0.25 part of defoamer, 0.2~0.4 part of drier, 12~22 parts of environmentally friendly solvent.
The preparation method of the white wood wax oil of above-mentioned environment-friendly spray coating type, methods described comprises the following steps：
S1：Aldehyde ketone resin is melted, and is well mixed with vegetable oil and environmentally friendly solvent, titanium dioxide is then added, to be not less than
1200r/min 20~30min of rotating speed high-speed stirred makes the particle diameter of mixed slurry be not higher than 50 μm；
S2：Perfluor wax is added in being mixed obtained by S1, in 15~20min of stirring under 1000~1200r/min speed；
S3：Ultra-violet absorber, drier and defoamer are added into mixture obtained by S2, and in 400~800 r/min speed
Degree 5~10min of lower stirring,；Produce the environment-friendly spray coating type wood wax oil.
The application method of the white wood wax oil of above-mentioned environment-friendly spray coating type, the application method is：By the wood wax oil and haze tallow
Water is according to 1：0.8~1.2 mass ratio is diluted, and is well mixed and is used strainer filtering；Then the wood wax oil after dilution is fallen
Enter in spray gun and wooden articles to be sprayed using two-layer cross spraying process；Wherein, the haze tallow water by butyl ester, ethyl ester and
Environmentally friendly solvent is with 50~80：30~40：5~10 mass ratio composition.
Above-mentioned environmentally friendly solvent can select D30 solvent naphthas and/or D40 solvent naphthas.
Measure 50ml it is above-mentioned through dilution mix after wood wax oil and pour into rock field cup in, in 25 DEG C, 50~75%RH conditions
Lower its viscosity of test, with manual time-keeping, is defined so that wood wax oil stream is complete.The viscosity of wood wax oil is 12~15 seconds after test dilution, warp
Experimental verification, when the viscosity of wood wax oil is 12~15 seconds, its spraying effect is optimal.
Preferably, the mesh number of the filter screen is 80~100 mesh, and the bore of the spray gun is 1.5~2.0mm.
Compared with prior art, the beneficial effect of technical solution of the present invention is：
Compared with traditional wood wax oil, the wood wax oil that the present invention is provided has preferable glossiness, wearability, hardness, film forming
And stability.And the wood wax oil that the present invention is provided can be truly realized no benzene, toluene and Form aldehyde release, while heavy metal free
Lead, chromium, mercury, chromium detection, it is preferable for product feel after woodwork.It is real that the wood wax oil that the present invention is provided can also substitute seal coat
Now lumber fibre pipe and pore are closed, it is to avoid wooden articles water suction deformation etc..
The wood wax oil that the present invention is provided is environment-protecting and non-poisonous with material, and preparation technology and usability methods are simple, will to operator's specialty
Ask not high, the wood wax oil can either be constructed by way of brushing erasing, wooden articles can also be carried out by spray gun
Spraying, and can assign wooden articles good gloss, and improve the resistance to of wooden articles in wooden articles surface filming
Mill property and hardness etc., with larger application value.
Embodiment
The present invention is further explained with reference to specific embodiment, but specific embodiment is not to the present invention
It is limited in any way.Unless stated otherwise, in the embodiment that all present invention are provided there is provided raw material can from market buying obtain
.
Embodiment 1
A kind of white wood wax oil of environment-friendly spray coating type, the wood wax oil is made up of by mass fraction the following raw material：
Vegetable oil 40g, Polytetrafluoroethylene emulsion 3g, titanium dioxide 20g, the g of aldehyde ketone resin 5, ultra-violet absorber 0.2g, defoamer 0.1g, urge
Dry agent 0.2g, environmentally friendly solvent 10g.
The preparation method for the white wood wax oil of environment-friendly spray coating type that the present embodiment is provided is as follows：
S1：Aldehyde ketone resin is melted, and is well mixed with vegetable oil and environmentally friendly solvent, titanium dioxide is then added, to be not less than
1200r/min 20~30min of rotating speed high-speed stirred makes the particle diameter of mixed slurry be not higher than 50 μm；
S2：Perfluor wax is added in being mixed obtained by S1, in 15~20min of stirring under 1000~1200r/min speed；
S3：Ultra-violet absorber, drier and defoamer are added into mixture obtained by S2, and in 400~800 r/min speed
Degree 5~10min of lower stirring,；Produce the environment-friendly spray coating type wood wax oil.
Embodiment 2
A kind of white wood wax oil of environment-friendly spray coating type, the wood wax oil is made up of by mass fraction the following raw material：
Vegetable oil 60g, the g of Polytetrafluoroethylene emulsion 8, the g of titanium dioxide 40, the g of aldehyde ketone resin 10, the g of ultra-violet absorber 0.6, defoamer 0.3
G, the g of drier 0.5, the g of environmentally friendly solvent 25.
The preparation method be the same as Example 1 for the white wood wax oil of environment-friendly spray coating type that the present embodiment is provided.
Embodiment 3
A kind of white wood wax oil of environment-friendly spray coating type, the wood wax oil is made up of by mass fraction the following raw material：
Vegetable oil 50g, Polytetrafluoroethylene emulsion 6g, the g of titanium dioxide 30, aldehyde ketone resin 8g, the g of ultra-violet absorber 0.4, defoamer 0.2g,
The g of drier 0.4, environmentally friendly solvent 20g.
The preparation method be the same as Example 1 for the white wood wax oil of environment-friendly spray coating type that the present embodiment is provided.
Embodiment 4
A kind of white wood wax oil of environment-friendly spray coating type, the wood wax oil is made up of by mass fraction the following raw material：
Vegetable oil 40g, the g of Polytetrafluoroethylene emulsion 8, the g of titanium dioxide 30, the g of aldehyde ketone resin 8, ultra-violet absorber 0.5g, defoamer 0.2g,
The g of drier 0.4, environmentally friendly solvent 22g.
The preparation method be the same as Example 1 for the white wood wax oil of environment-friendly spray coating type that the present embodiment is provided.
Embodiment 5
A kind of white wood wax oil of environment-friendly spray coating type, the wood wax oil is made up of by mass fraction the following raw material：
Vegetable oil 45g, Polytetrafluoroethylene emulsion 6g, titanium dioxide 25g, aldehyde ketone resin 8g, the g of ultra-violet absorber 0.5, defoamer 0.2g, urge
Dry agent 0.3g, environmentally friendly solvent 15g.
The preparation method be the same as Example 1 for the white wood wax oil of environment-friendly spray coating type that the present embodiment is provided.
Embodiment 6
A kind of white wood wax oil of environment-friendly spray coating type, the wood wax oil is made up of by mass fraction the following raw material：
Vegetable oil 55g, Polytetrafluoroethylene emulsion 6g, titanium dioxide 35g, aldehyde ketone resin 8g, ultra-violet absorber 0.5g, defoamer 0.18g, urge
Dry agent 0.4g, environmentally friendly solvent 18g.
The preparation method be the same as Example 1 for the white wood wax oil of environment-friendly spray coating type that the present embodiment is provided.
Comparative example 1
This comparative example provide wood wax oil select palm wax alternate embodiment 1 in Polytetrafluoroethylene emulsion, other components and content with
Embodiment 1 is identical.Specifically, the wood wax oil is made up of by mass fraction the following raw material：
Vegetable oil 40g, palm wax 3g, titanium dioxide 20g, the g of aldehyde ketone resin 5, ultra-violet absorber 0.2g, defoamer 0.1g, urge dry
Agent 0.2g, environmentally friendly solvent 10g.
The preparation method be the same as Example 1 for the white wood wax oil of environment-friendly spray coating type that the present embodiment is provided.
Comparative example 2
The consumption of Polytetrafluoroethylene emulsion in the wood wax oil that this comparative example is provided is less, and other components and content are same as Example 1.
Specifically, the wood wax oil is made up of by mass fraction the following raw material：
Vegetable oil 40g, Polytetrafluoroethylene emulsion 2.5g, titanium dioxide 20g, the g of aldehyde ketone resin 5, ultra-violet absorber 0.2g, defoamer 0.1g,
Drier 0.2g, environmentally friendly solvent 10g.
The preparation method be the same as Example 1 for the white wood wax oil of environment-friendly spray coating type that the present embodiment is provided.
Comparative example 3
The consumption of Polytetrafluoroethylene emulsion in the wood wax oil that this comparative example is provided is more, and other components and content are same as Example 1.
Specifically, the wood wax oil is made up of by mass fraction the following raw material：
Vegetable oil 40g, Polytetrafluoroethylene emulsion 8.5g, titanium dioxide 20g, the g of aldehyde ketone resin 5, ultra-violet absorber 0.2g, defoamer 0.1g,
Drier 0.2g, environmentally friendly solvent 10g.
The preparation method be the same as Example 1 for the white wood wax oil of environment-friendly spray coating type that the present embodiment is provided.
The environment-friendly spray coating type wood wax oil that embodiment 1~6 and comparative example 1~3 are provided is used to spray wooden articles, the haze tallow
The application method of oil is as follows：
By the wood wax oil and haze tallow water according to 1：1 mass ratio is diluted, and is well mixed and is crossed 80~100 mesh filter screens；So
The wood wax oil after dilution is poured into spray gun afterwards wooden articles sprayed using two-layer cross spraying process；Wherein, it is described
Haze tallow water is by butyl ester, ethyl ester and environmentally friendly solvent with 50~80：30~40：5~10 mass ratio composition.Woodenware system after spraying
The surface drying time of product is 15~20 minutes, does solid work the time for 6~12 hours.
Performance test is carried out to the wooden articles after the completion of spraying, method of testing is as follows, and test result see the table below 1.
（1）Wearability：Wooden articles after spraying are wiped with rag, the wear-resisting of wood wax oil is determined according to resistance to wiping number of times
Property；
（2）Hardness：Use trolley type measuring pencil durometer；
（3）Viscosity
By the wood wax oil and haze tallow water according to 1：0.8~1.2 mass ratio is diluted, and measures 50ml above-mentioned through dilution mixing
Wood wax oil after good is simultaneously poured into the cup of rock field, its viscosity is tested under the conditions of 25 DEG C, 50~75%RH, with manual time-keeping, with haze tallow
Oil, which has flowed, to be defined.
（4）Gloss：Measurement of luster is carried out by BC-D512 glossometers；
（5）Benzene, toluene level detection
With reference to the requirement of limits of harmful substances in GB 18581-2009 indoor hardware fitting solvent wood coatings, sample is detected
The content of middle benzene, toluene.
（6）Lead, cadmium, chromium, mercury, the heavy metal analysis of formaldehyde
With reference to the requirement of limits of harmful substances in GB 18581-2009 indoor hardware fitting solvent wood coatings, sample is detected
Middle dissoluble lead, chromium, the content of cadmium and mercury.
The physical and chemical performance for the white wood wax oil of environment-friendly spray coating type that embodiment 1~6 and comparative example 1~3 are provided
。
The organic matter for the white wood wax oil of environment-friendly spray coating type that embodiment 1~6 and comparative example 1~3 are provided and heavy metal detection
。
From upper Tables 1 and 2, the wood wax oil that various embodiments of the present invention are prepared has preferable glossiness, according to
Manufacturer requires that all light can be accomplished（More than 100 °）Also it can accomplish complete mute（0 °~10 °）, disclosure satisfy that wanting for different manufacturers
Ask；And the wood wax oil that the present invention is provided is in terms of film forming, hardness, scratch resistance and feel than the performance of commercially available wood wax oil
It is better.Compared with each comparative example, the consumption for the perfluor wax that comparative example 1 is selected in palm wax, comparative example 2 and 3 is excessive or very few, system
The glossiness of standby obtained wood wax oil is poor, it is impossible to accomplish all light.In addition, compared with each comparative example, various embodiments of the present invention
In wood wax oil particle diameter it is thinner, construction effect is preferable；And each reference examples are also better than in terms of wearability, hardness.This hair
The wood wax oil that bright each embodiment is provided also has preferable stability, and long-term storage is not stratified at room temperature, uses it for woodenware system
Adhesive force preferably, is not fallen off after product.
Claims (10)
1. the white wood wax oil of a kind of environment-friendly spray coating type, it is characterised in that the wood wax oil is made up of by mass fraction the following raw material：
40~60 parts of vegetable oil, 3~8 parts of Polytetrafluoroethylene emulsion, 20~40 parts of titanium dioxide, 5~10 parts of aldehyde ketone resin, ultra-violet absorber
0.2~0.6 part, 0.1~0.3 part of defoamer, 0.2~0.5 part of drier, 10~25 parts of environmentally friendly solvent.
2. the white wood wax oil of environment-friendly spray coating type according to claim 1, it is characterised in that the vegetable oil is castor oil, Asia
One or more in sesame oil or blowing oil.
3. the white wood wax oil of environment-friendly spray coating type according to claim 1, it is characterised in that the environmentally friendly solvent is D30 solvents
Oil and/or D40 solvent naphthas.
4. the white wood wax oil of environment-friendly spray coating type according to claim 1, it is characterised in that the drier is organic acid metal
Soaps and/or manganese iso-octoate drier.
5. the white wood wax oil of environment-friendly spray coating type according to claim 1, it is characterised in that the defoamer is without benzene class polyethers
Organic silicon defoamer.
6. the white wood wax oil of environment-friendly spray coating type according to claim 1, it is characterised in that the wood wax oil by mass fraction by
The following raw material is constituted：
45~55 parts of vegetable oil, 3~6 parts of Polytetrafluoroethylene emulsion, 25~35 parts of titanium dioxide, 6~8 parts of aldehyde ketone resin, ultra-violet absorber
0.3~0.5 part, 0.15~0.25 part of defoamer, 0.2~0.4 part of drier, 12~22 parts of environmentally friendly solvent.
7. the preparation method of the white wood wax oil of any environment-friendly spray coating type of claim 1~6, it is characterised in that methods described
Comprise the following steps：
S1：Aldehyde ketone resin is melted, and is well mixed with vegetable oil and environmentally friendly solvent, titanium dioxide is then added, to be not less than
1200r/min 20~30min of rotating speed high-speed stirred makes the particle diameter of mixed slurry be not higher than 50 μm；
S2：Perfluor wax is added in being mixed obtained by S1, in 15~20min of stirring under 1000~1200r/min speed；
S3：Ultra-violet absorber, drier and defoamer are added into mixture obtained by S2, and in 400~800 r/min speed
Degree 5~10min of lower stirring,；Produce the environment-friendly spray coating type wood wax oil.
8. the application method of the white wood wax oil of any environment-friendly spray coating type of claim 1~6, it is characterised in that described to use
Method is：By the wood wax oil and haze tallow water according to 1：0.8~1.2 mass ratio is diluted, and is well mixed and is used filter screen mistake
Filter；Then the wood wax oil after dilution is poured into spray gun and wooden articles sprayed using two-layer cross spraying process；Wherein,
The haze tallow water is by butyl ester, ethyl ester and environmentally friendly solvent with 50~80：30~40：5~10 mass ratio composition.
9. preparation method according to claim 8, it is characterised in that the mesh number of the filter screen is 80~100 mesh.
10. preparation method according to claim 8, it is characterised in that the haze tallow after measuring that 50ml is above-mentioned and being mixed through dilution
Oil is simultaneously poured into the cup of rock field, and its viscosity is tested under the conditions of 25 DEG C, 50~75%RH；The viscosity of the wood wax oil is 12~15 seconds.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108753170A (en) * | 2018-07-03 | 2018-11-06 | 邱平亮 | A kind of environmental protection electrostatic spary coating type wood wax oil and its preparation method and application |
| CN109054638A (en) * | 2018-07-12 | 2018-12-21 | 东莞公民实业有限公司 | environment-friendly wood wax oil and preparation method thereof |
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| CN101698779A (en) * | 2009-10-29 | 2010-04-28 | 姜桥 | Wood wax lacquer and preparation process thereof |
| CN102284990A (en) * | 2011-06-22 | 2011-12-21 | 嘉宝莉化工集团股份有限公司 | White wood wax oil for woodware and preparation method thereof |
| CN105505165A (en) * | 2015-12-25 | 2016-04-20 | 澳达树熊涂料(惠州)有限公司 | Scratch-resistant double-component waterborne glossy varnish and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101519568A (en) * | 2009-03-27 | 2009-09-02 | 长春帝博科技有限公司 | Natural oil for wood products |
| CN101550316A (en) * | 2009-05-19 | 2009-10-07 | 天津市现代人再就业服务有限公司 | Environment protecting wood wax oil |
| CN101698779A (en) * | 2009-10-29 | 2010-04-28 | 姜桥 | Wood wax lacquer and preparation process thereof |
| CN102284990A (en) * | 2011-06-22 | 2011-12-21 | 嘉宝莉化工集团股份有限公司 | White wood wax oil for woodware and preparation method thereof |
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| CN108753170A (en) * | 2018-07-03 | 2018-11-06 | 邱平亮 | A kind of environmental protection electrostatic spary coating type wood wax oil and its preparation method and application |
| CN109054638A (en) * | 2018-07-12 | 2018-12-21 | 东莞公民实业有限公司 | environment-friendly wood wax oil and preparation method thereof |
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| CN106978075B (en) | 2018-04-20 |
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