CN108753083A - A kind of wicker plaiting article stain resistant imitation stone lacquer - Google Patents
A kind of wicker plaiting article stain resistant imitation stone lacquer Download PDFInfo
- Publication number
- CN108753083A CN108753083A CN201810666789.2A CN201810666789A CN108753083A CN 108753083 A CN108753083 A CN 108753083A CN 201810666789 A CN201810666789 A CN 201810666789A CN 108753083 A CN108753083 A CN 108753083A
- Authority
- CN
- China
- Prior art keywords
- imitation stone
- stain resistant
- plaiting article
- wicker plaiting
- stone lacquer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C08K2003/168—Zinc halides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of wicker plaiting article stain resistant imitation stone lacquers, are made of following component：Silicone acrylic emulsion, acidification sericite in powder, nano-calcium carbonate, glycerine, mill base, zinc chloride, secondary alkyl potassium sulfonate, coalescents, water；Wicker plaiting article prepared by the present invention, by the synergistic effect between each component, has stronger water-whitening resistance energy, reaches 1-2 grades with stain resistant imitation stone lacquer；The acidification sericite in powder acts synergistically with nano-calcium carbonate, can improve imitation stone lacquer and the adhesion of base material, can effectively improve resistance to performance of going mouldy, while can enhance resistance to the going mouldy property of rattan plaited material, while also having preferable water resistance, improves the workability of imitation stone lacquer；Secondary alkyl potassium sulfonate can improve the resistance to soiling and weatherability of film, extend its scope of application.
Description
Technical field
The invention belongs to technical field of biological environmental protection, and in particular to a kind of wicker plaiting article stain resistant imitation stone lacquer.
Background technology
Funan County is under the jurisdiction of Anhui Province's Fuyang City, belongs to inland exploitation area earlier, on the Anhui Province northwestward, Huaihe River
Middle reaches engaging portion north bank.Funan County be known as " famous-brand and high-quality specialty county ", " Natural resources reservoir " title, be national grain-production great Xian, in
The unique agricultural in township, the whole nation of state's wicker plaiting article（Forestry）Circular economy demonstration pilot project county, Funan are the township of national wicker plaiting article, wicker products
It is sold abroad.
Wicker products in process of production more improve its appearance condition and aesthetic feeling, imitation stone lacquer due to texture is strong,
It is easy for construction, service life is long, cheap, gradually using on the surface of your rattan plaited material, but will appear paint film after construction
Whiten, yellowing resistance is deteriorated, and resistance to rainprint phenomenon is serious.
Invention content
The present invention is achieved by the following technical solutions：A kind of wicker plaiting article stain resistant imitation stone lacquer, by weight by with
Lower ingredient is made：Silicone acrylic emulsion 90-92, acidification sericite in powder 8-12, nano-calcium carbonate 5.8, glycerine 3.5, mill base 3, zinc chloride
6.3, secondary alkyl potassium sulfonate 1.3, coalescents 1-2, water 70-75.
Further, the acidification sericite in powder preparation method is：
Prepare the organic acid soln that mass fraction is 5.5%, organic acid soln be heated to 88 DEG C, keeps the temperature 12min, then again to
After stirring evenly, sericite in powder is added into organic acid soln for the cerium chloride that its quality 0.012% is added in organic acid soln, is surpassed
Then sonicated 15min is stirred 2 hours, then cooled to room temperature with 1200r/min rotating speeds, filtering, drying to get.
Further, the organic acid soln is maleic acid solution.
Further, the ultrasonic power is 1200W, frequency 55kHz.
Further, solid content is 42.5% in the silicone acrylic emulsion.
Further, the coalescents are butyl glycol ether.
Further, the nano-calcium carbonate dynamics is 100nm.
The present invention has the following advantages compared with prior art：Wicker plaiting article stain resistant imitation stone lacquer prepared by the present invention passes through each group
/ synergistic effect, have stronger water-whitening resistance energy, reach 1-2 grades；The acidification sericite in powder and nano-calcium carbonate
Synergistic effect, can improve imitation stone lacquer and the adhesion of base material, can effectively improve resistance to performance of going mouldy, while can enhance rattan plaited material
Resistance to going mouldy property, while also there is preferable water resistance, improve the workability of imitation stone lacquer；Secondary alkyl potassium sulfonate can improve film
Resistance to soiling and weatherability, extend its scope of application.
Specific implementation mode
Embodiment 1
A kind of wicker plaiting article stain resistant imitation stone lacquer, is made of following component by weight：Silicone acrylic emulsion 90, acidification sericite in powder 8,
Nano-calcium carbonate 5.8, glycerine 3.5, mill base 3, zinc chloride 6.3, secondary alkyl potassium sulfonate 1.3, coalescents 1-2, water 70.
Further, the acidification sericite in powder preparation method is：
Prepare the organic acid soln that mass fraction is 5.5%, organic acid soln be heated to 88 DEG C, keeps the temperature 12min, then again to
After stirring evenly, sericite in powder is added into organic acid soln for the cerium chloride that its quality 0.012% is added in organic acid soln, is surpassed
Then sonicated 15min is stirred 2 hours, then cooled to room temperature with 1200r/min rotating speeds, filtering, drying to get.
Further, the organic acid soln is maleic acid solution.
Further, the ultrasonic power is 1200W, frequency 55kHz.
Further, solid content is 42.5% in the silicone acrylic emulsion.
Further, the coalescents are butyl glycol ether.
Further, the nano-calcium carbonate dynamics is 100nm.
Embodiment 2
A kind of wicker plaiting article stain resistant imitation stone lacquer, is made of following component by weight：Silicone acrylic emulsion 92, acidification sericite in powder
12, nano-calcium carbonate 5.8, glycerine 3.5, mill base 3, zinc chloride 6.3, secondary alkyl potassium sulfonate 1.3, coalescents 1-2, water 75.
Further, the acidification sericite in powder preparation method is：
Prepare the organic acid soln that mass fraction is 5.5%, organic acid soln be heated to 88 DEG C, keeps the temperature 12min, then again to
After stirring evenly, sericite in powder is added into organic acid soln for the cerium chloride that its quality 0.012% is added in organic acid soln, is surpassed
Then sonicated 15min is stirred 2 hours, then cooled to room temperature with 1200r/min rotating speeds, filtering, drying to get.
Further, the organic acid soln is maleic acid solution.
Further, the ultrasonic power is 1200W, frequency 55kHz.
Further, solid content is 42.5% in the silicone acrylic emulsion.
Further, the coalescents are butyl glycol ether.
Further, the nano-calcium carbonate dynamics is 100nm.
Embodiment 3
A kind of wicker plaiting article stain resistant imitation stone lacquer, is made of following component by weight：Silicone acrylic emulsion 91, acidification sericite in powder
10, nano-calcium carbonate 5.8, glycerine 3.5, mill base 3, zinc chloride 6.3, secondary alkyl potassium sulfonate 1.3, coalescents 1.2, water 72.
Further, the acidification sericite in powder preparation method is：
Prepare the organic acid soln that mass fraction is 5.5%, organic acid soln be heated to 88 DEG C, keeps the temperature 12min, then again to
After stirring evenly, sericite in powder is added into organic acid soln for the cerium chloride that its quality 0.012% is added in organic acid soln, is surpassed
Then sonicated 15min is stirred 2 hours, then cooled to room temperature with 1200r/min rotating speeds, filtering, drying to get.
Further, the organic acid soln is maleic acid solution.
Further, the ultrasonic power is 1200W, frequency 55kHz.
Further, solid content is 42.5% in the silicone acrylic emulsion.
Further, the coalescents are butyl glycol ether.
Further, the nano-calcium carbonate dynamics is 100nm.
Claims (7)
1. a kind of wicker plaiting article stain resistant imitation stone lacquer, which is characterized in that be made by weight of following component：Silicone acrylic emulsion 90-
92, acidification sericite in powder 8-12, nano-calcium carbonate 5.8, glycerine 3.5, mill base 3, zinc chloride 6.3, secondary alkyl potassium sulfonate 1.3, at
Film auxiliary agent 1-2, water 70-75.
2. a kind of wicker plaiting article stain resistant imitation stone lacquer as described in claim 1, which is characterized in that the acidification sericite in powder preparation side
Method is：
Prepare the organic acid soln that mass fraction is 5.5%, organic acid soln be heated to 88 DEG C, keeps the temperature 12min, then again to
After stirring evenly, sericite in powder is added into organic acid soln for the cerium chloride that its quality 0.012% is added in organic acid soln, is surpassed
Then sonicated 15min is stirred 2 hours, then cooled to room temperature with 1200r/min rotating speeds, filtering, drying to get.
3. a kind of wicker plaiting article stain resistant imitation stone lacquer as claimed in claim 2, which is characterized in that the organic acid soln is maleic acid
Solution.
4. a kind of wicker plaiting article stain resistant imitation stone lacquer as claimed in claim 2, which is characterized in that the ultrasonic power is 1200W,
Frequency is 55kHz.
5. a kind of wicker plaiting article stain resistant imitation stone lacquer as described in claim 1, which is characterized in that solid content in the silicone acrylic emulsion
It is 42.5%.
6. a kind of wicker plaiting article stain resistant imitation stone lacquer as described in claim 1, which is characterized in that the coalescents are ethylene glycol fourth
Ether.
7. a kind of wicker plaiting article stain resistant imitation stone lacquer as described in claim 1, which is characterized in that the nano-calcium carbonate dynamics is
100nm。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810666789.2A CN108753083A (en) | 2018-06-26 | 2018-06-26 | A kind of wicker plaiting article stain resistant imitation stone lacquer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810666789.2A CN108753083A (en) | 2018-06-26 | 2018-06-26 | A kind of wicker plaiting article stain resistant imitation stone lacquer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108753083A true CN108753083A (en) | 2018-11-06 |
Family
ID=63977722
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810666789.2A Pending CN108753083A (en) | 2018-06-26 | 2018-06-26 | A kind of wicker plaiting article stain resistant imitation stone lacquer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108753083A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110256926A (en) * | 2019-07-04 | 2019-09-20 | 济宁学院 | A kind of Nano self-cleaning formula lacquer and application method |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101891958A (en) * | 2010-08-12 | 2010-11-24 | 哈尔滨工业大学 | Method for improving heat resistance of organic silicon resin |
| CN102153903A (en) * | 2011-01-18 | 2011-08-17 | 广西民族大学 | Rust resisting pigment filler of dickite and preparation method thereof |
| CN105623314A (en) * | 2016-02-02 | 2016-06-01 | 安徽恒昊科技有限公司 | Method for preparing loose sericite powder |
| CN105802415A (en) * | 2016-04-20 | 2016-07-27 | 安徽巨力新型环保材料有限公司 | Reflective heat-insulating coating |
| CN107603399A (en) * | 2017-09-20 | 2018-01-19 | 阜南县中泰工艺品有限公司 | A kind of high attachment coating in rattan wicker plaiting article surface |
| CN107629611A (en) * | 2017-09-26 | 2018-01-26 | 阜南县腾祥工艺品有限公司 | A kind of preparation method of rattan plaited stain resistant stone similar paint |
-
2018
- 2018-06-26 CN CN201810666789.2A patent/CN108753083A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101891958A (en) * | 2010-08-12 | 2010-11-24 | 哈尔滨工业大学 | Method for improving heat resistance of organic silicon resin |
| CN102153903A (en) * | 2011-01-18 | 2011-08-17 | 广西民族大学 | Rust resisting pigment filler of dickite and preparation method thereof |
| CN105623314A (en) * | 2016-02-02 | 2016-06-01 | 安徽恒昊科技有限公司 | Method for preparing loose sericite powder |
| CN105802415A (en) * | 2016-04-20 | 2016-07-27 | 安徽巨力新型环保材料有限公司 | Reflective heat-insulating coating |
| CN107603399A (en) * | 2017-09-20 | 2018-01-19 | 阜南县中泰工艺品有限公司 | A kind of high attachment coating in rattan wicker plaiting article surface |
| CN107629611A (en) * | 2017-09-26 | 2018-01-26 | 阜南县腾祥工艺品有限公司 | A kind of preparation method of rattan plaited stain resistant stone similar paint |
Non-Patent Citations (2)
| Title |
|---|
| 汪多仁等: "《绿色纳米化学品》", 31 July 2007, 北京：科学技术文献出版社 * |
| 舒万艮等: "《有色金属精细化工产品生产与应用》", 31 December 1995, 中南工业大学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110256926A (en) * | 2019-07-04 | 2019-09-20 | 济宁学院 | A kind of Nano self-cleaning formula lacquer and application method |
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Application publication date: 20181106 |