CN108751937A - Thin crystallite sheen brick - Google Patents
Thin crystallite sheen brick Download PDFInfo
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- CN108751937A CN108751937A CN201810713086.0A CN201810713086A CN108751937A CN 108751937 A CN108751937 A CN 108751937A CN 201810713086 A CN201810713086 A CN 201810713086A CN 108751937 A CN108751937 A CN 108751937A
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- additive
- frit
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- ground
- coat enamel
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/444—Halide containing anions, e.g. bromide, iodate, chlorite
Abstract
The application provides a kind of thin crystallite sheen brick, including the green body, ground-coat enamel, protection glaze, clear frit, transparent thin frit and protection glue of stratiform setting successively；Green body includes green body additive sodium chloride；Ground-coat enamel includes ground-coat enamel additive, and ground-coat enamel additive is C5 resin solutions, and C5 resin solutions are that solute is C5 resins, the solution that solvent is hexamethylene, mass concentration is 5-8%；It includes protection glaze additive yttrium oxide to protect glaze；Clear frit includes clear frit additive, and clear frit additive is the mixture of tungsten oxide, molybdenum oxide and nickel oxide；Transparent thin frit includes transparent thin frit additive, and transparent thin frit additive is the mixture of SnO2, Pr6O11, La2O3, Ce2O3 and TeO2；Protection glue is methacrylic acid adhesive.Thin crystallite sheen brick provided by the present application, can obtain light effect it is soft, with natural jade decorative effect similar in thin crystallite sheen brick.
Description
Technical field
The present invention relates to chemical fields for this, in particular to a kind of thin crystallite sheen brick.
Background technology
Why natural material is liked by people, and advantage essentially consists in it and used as ornament materials, especially indoor
When decoration, light is more naturally soft, will not be gloomy but will not be especially glittering dazzling.
Thin crystallite brick body in ceramic brick body is a kind of a kind of product being frequently used to as natural material substitute.It is existing
Some crystallite brick body microcrystalline coating thickness is big, reflective serious, directly affects the decorative effect and practicability of brick body, it is difficult to realize
The sparkling and crystal-clear penetrating decorative effect with nature jade of color and luster.
In view of this, special propose the present invention.
Invention content
The first object of the present invention is to provide a kind of thin crystallite sheen brick, and the thin crystallite sheen brick has structural strength
Well, the advantages that light effect is soft.
In order to realize that the above-mentioned purpose of the present invention, spy use following technical scheme：
A kind of thin crystallite sheen brick, which is characterized in that green body, ground-coat enamel, protection glaze, transparent including the setting of stratiform successively
Glaze, transparent thin frit and protection glue；
The green body includes green body additive, and the green body additive is sodium chloride；
The ground-coat enamel includes ground-coat enamel additive, and the ground-coat enamel additive is C5 resin solutions, and the C5 resin solutions are molten
Matter is C5 resins, the solution that solvent is hexamethylene, mass concentration is 5-8%；
The protection glaze includes protection glaze additive, and the protection glaze additive is yttrium oxide；
The clear frit includes clear frit additive, and the clear frit additive is tungsten oxide, molybdenum oxide and nickel oxide
Mixture；
The transparent thin frit includes transparent thin frit additive, the transparent thin frit additive be SnO2, Pr6O11,
The mixture of La2O3, Ce2O3 and TeO2；
The protection glue is methacrylic acid adhesive.
The addition of green body additive sodium chloride is conducive to optimize the structure of green body, improves structural strength, changes green body and fire
The glossiness of green part afterwards；The use of ground-coat enamel additive can improve mobility when its firing, reinforce green body and protection glaze
Between conjugation, improve structural stability；It is to reinforce protecting effect to protect the use of glaze additive；Clear frit additive
Use, be to weaken the light transmission refractive power effect of transparent glaze layer, preferably obtain soft light reflection；Transparent thin frit additive
Use, on the one hand can ensure the mobility of transparent thin frit, make its fire when be more evenly distributed, what can be done is thinner,
On the other hand also change microstructure so that surface layer reflecting effect reduces so that light is softer；Protection glue wet concentration selects methyl-prop
Olefin(e) acid adhesive, it is at low cost, effect is good, a large amount of carbon distributions are not will produce in sintering procedure, while transparent thin frit can be sticked to
Together, it is not easy to loosen or blow away in kiln firing.
Preferably, the green body includes by percentage to the quality：The green body additive 1-3%, feldspar 25-30%, leaf
Cured stone 18-20%, kaolin 15-25%, white clay 10-12%, black mud 7-9%, gold sand stone 10-12%, ooze 1-3% and magnesia
Mud 1-3%.
The selection of the ingredient of green body is to enhance its intensity on the basis of ensureing the decorative effect of product, gold sand stone is added
It is to ensure its overall effect.
Preferably, the ground-coat enamel includes by percentage to the quality：The ground-coat enamel additive 1-3%, SiO240-55%,
Al2O310-15%, CaO8-10%, MgO5-8%, ZnO10-15%, K2O4-6%, Na2O1-3%, ZrO21-3%,
Sb2O31-3%, Ga2O30.1-0.3%.
It is further preferred that the flow velocity of the ground-coat enamel is 4.5-5.0g/s, proportion 1.4-1.6g/ml, applied amount is
730-750g/m2, fineness are that siccative weight percent is 0.4%-0.6% after 325 mesh sieve.
The addition of ZrO2, Sb2O3, Ga2O3 interact between can improving each component in ground-coat enamel, reduce splitting for ground glaze layer
The optimization of line and bubble, parameter can ensure that the glossiness of ground-coat enamel is in suitable range simultaneously.
Preferably, the protection glaze includes marzacotto, print cream and the protection glaze additive, mass ratio 2-4:1：
0.1；The marzacotto includes transparent powdered frit 60-65%, sodium carboxymethylcellulose 0.2-0.5%, three by mass percentage
Polyphosphate sodium 0.2-0.4%, aluminium chloride 1-2%, aluminum sulfate 1-2%, 12 hydrazine aluminum sulfate potassium 1-2% and water 30-36%.
It is further preferred that the protection glaze proportion 1.5-2.0g/ml, flow velocity 4.5-5.0g/s, fineness is through 325 mesh
Siccative weight percent is 0.3-0.5% after sieve.
It is to protect ink-jet printed pattern not by next work using the purpose protected glaze and optimized to its parameter
The influence of sequence.
Preferably, the clear frit based on mass fraction, including the 0.3% clear frit additive and 99.7% institute
Marzacotto is stated, the mass ratio of the tungsten oxide, the molybdenum oxide and the nickel oxide is 1:1:1.
It is further preferred that the clear frit proportion is 1.2-1.5g/ml, applied amount 310-320g/m2.
Purpose using clear frit is in sintering process, and the gas in green body is when clear frit melts not yet, green body
Middle major part gas can be discharged, and the small gas on green body can be prevented to be discharged when clear frit melts, to make firing go out
The surface of semi-finished come does not have small pore.The optimization of parameter is to perform to most preferably the effect.
Preferably, the transparent thin frit includes by mass percentage：The transparent thin frit additive 0.5%,
Al2O35-15%, SiO240-55%, CaO10-18%, K2O5-10%, MgO5-12%, BaO4-10%, ZnO 2-5%,
Lu2O30.1-0.5%；Each component dosage is equal in the transparent thin frit additive.
The selection of transparent thin frit ingredient, the especially addition of Lu2O3 are to obtain better crystallite on brick body surface
Glassy layer ensures the decorative effect on its surface layer.
It is further preferred that the applied amount of the transparent thin frit is 23-28g/m2, application thickness is 0.8-1.2mm.
The optimization of parameter is to obtain preferably decoration performance.
Compared with prior art, beneficial effects of the present invention are：
(1) additive is added by each layer to thin crystallite sheen brick, it is ensured that the best decorative effect of product；
(2) to the selection of the basic ingredient of each layer, good structural strength, decorative effect and natural jade height phase can be obtained
Close product.
Specific implementation mode
Embodiment of the present invention is described in detail below in conjunction with embodiment, but those skilled in the art will
Understand, the following example is merely to illustrate the present invention, and is not construed as limiting the scope of the invention.It is not specified in embodiment specific
Condition person carries out according to conventional conditions or manufacturer's recommended conditions.Reagents or instruments used without specified manufacturer is
The conventional products that can be obtained by commercially available purchase.
First, the preparation method of thin crystallite sheen brick is illustrated.Specifically include following steps：A. blank forming；?
Dry base substrate is obtained after body drying；Dry base substrate is ground into the particle of 200-250 mesh, molding is then added water, in 150-
Dry 60min, obtains molding blank under the conditions of 200 DEG C；B. apply ground-coat enamel, the then ink-jet on ground-coat enamel to the surface of molding blank
Stamp under conditions of 150 DEG C after dry 1-2min, then in the abortive haul of 140 mesh of ink-jet printed one side prints one layer and protects glaze；?
The surface of glaze is protected to spray layer of transparent glaze, then the surface of the clear frit thin frit of waterfall type distributing mode cloth layer of transparent, obtains
To the first base brick；The one side spray protection glue of transparent thin frit is provided with to the first base brick, then in 150-250 DEG C of drying
1min obtains the second base brick；C. the second base brick is obtained semi-finished product through 1170-1240 DEG C of high-temperature firing 70-75mim；D. half at
Product use the polish line that is made of successively elastic module, dumb light abrading block, abrasive brush and fiber brush, beat super clean bright obtaining Bao Wei
Brilliant sheen brick.
Embodiment 1
A kind of thin crystallite sheen brick, including from the bottom to top successively stratiform setting green body, ground-coat enamel, protection glaze, clear frit, thoroughly
Detailed frit and protection glue；
Green body includes by percentage to the quality：Sodium chloride 1%, feldspar 25%, pyrophillite 18%, kaolin 25%, white clay
12%, black mud 7%, gold sand stone 10%, ooze 1% and magnesia mud 1%；
Ground-coat enamel includes by percentage to the quality：Ground-coat enamel additive 1%, SiO249%, Al2O315%, CaO8%,
MgO5%, ZnO10%, K2O4%, Na2O3%, ZrO21.7%, Sb2O33%, Ga2O30.3%；Ground-coat enamel additive is solute
For the C5 resin solutions that C5 resins, solvent are hexamethylene, mass concentration is 5%；The flow velocity of ground-coat enamel is 4.5g/s, and proportion is
1.6g/ml, applied amount 730g/m2, fineness are that siccative weight percent is 0.4%% after 325 mesh sieve；
Protection glaze includes marzacotto, print cream and yttrium oxide, mass ratio 2:1：0.1；Marzacotto presses quality percentage
Than meter include transparent powdered frit 65%, sodium carboxymethylcellulose 0.2%, sodium tripolyphosphate 0.2%, aluminium chloride 1%, aluminum sulfate 2%,
12 hydrazine aluminum sulfate potassium 1% and water 30.6%；The protection glaze proportion 1.5g/ml, flow velocity 5.0g/s, fineness are warp
Siccative weight percent is 0.3% after 325 mesh sieve；
Clear frit based on mass fraction, including tungsten oxide 0.1%, molybdenum oxide 0.1%, nickel oxide 0.1% and 99.7%
Aforementioned transparent glaze, clear frit proportion are 1.5g/ml, applied amount 310g/m2；
Transparent thin frit includes by mass percentage：SnO20.1%, Pr6O110.1%, La2O30.1%,
Ce2O30.1%, TeO20.1%, Al2O315%, SiO255%, CaO10%, K2O5%, MgO5%, BaO4%, ZnO5%,
Lu2O30.5%；The applied amount of transparent thin frit is 23g/m2, and application thickness is 0.8mm.
Embodiment 2
A kind of thin crystallite sheen brick, including from the bottom to top successively stratiform setting green body, ground-coat enamel, protection glaze, clear frit, thoroughly
Detailed frit and protection glue；
Green body includes by percentage to the quality：Sodium chloride 3%, feldspar 30%, pyrophillite 20%, kaolin 15%, white clay
10%, black mud 7%, gold sand stone 12%, ooze 3% and magnesia mud 3%；
Ground-coat enamel includes by percentage to the quality：Ground-coat enamel additive 1.1%, SiO255%, Al2O310%, CaO10%,
MgO5.3%, ZnO11%, K2O4.5%, Na2O1%, ZrO21%, Sb2O31%, Ga2O30.1%；Ground-coat enamel additive is molten
The C5 resin solutions that matter is C5 resins, solvent is hexamethylene, mass concentration is 8%；The flow velocity of ground-coat enamel is 5.0g/s, and proportion is
1.4g/ml, applied amount 750g/m2, fineness are that siccative weight percent is 0.6% after 325 mesh sieve；
Protection glaze includes marzacotto, print cream and yttrium oxide, mass ratio 4:1：0.1；Marzacotto presses quality percentage
Include transparent powdered frit 60%, sodium carboxymethylcellulose 0.5%, sodium tripolyphosphate 0.4%, aluminium chloride 1.05%, aluminum sulfate than meter
1%, 12 hydrazine aluminum sulfate potassium 1.05% and water 36%；Glaze proportion 2.0g/ml is protected, flow velocity 4.5g/s, fineness is warp
Siccative weight percent is 0.5% after 325 mesh sieve；
Clear frit based on mass fraction, including tungsten oxide 0.1%, molybdenum oxide 0.1%, nickel oxide 0.1% and 99.7%
Aforementioned transparent glaze；Clear frit proportion is 1.2g/ml, applied amount 320g/m2；
Transparent thin frit includes by mass percentage：SnO20.1%, Pr6O110.1%, La2O30.1%,
Ce2O30.1%, TeO20.1%, Al2O3 5%, SiO240%, CaO18%, K2O10%, MgO12%, BaO10%, ZnO
4.4%, Lu2O30.1%；The applied amount of transparent thin frit is 28g/m2, and application thickness is 1.2mm.
Embodiment 3
A kind of thin crystallite sheen brick, including from the bottom to top successively stratiform setting green body, ground-coat enamel, protection glaze, clear frit, thoroughly
Detailed frit and protection glue；
Green body includes by percentage to the quality：Sodium chloride 1.5%, feldspar 30%, pyrophillite 18.5%, kaolin 16%,
White clay 11%, black mud 8%, gold sand stone 11%, ooze 2% and magnesia mud 2%；
Ground-coat enamel includes by percentage to the quality：Ground-coat enamel additive 3%, SiO240%, Al2O310.8%, CaO9.5%,
MgO8%, ZnO15%, K2O6%, Na2O2%, ZrO23%, Sb2O32.5%, Ga2O30.2%；Ground-coat enamel additive is solute
For the C5 resin solutions that C5 resins, solvent are hexamethylene, mass concentration is 6%；The flow velocity of ground-coat enamel is 4.8g/s, and proportion is
1.5g/ml, applied amount 740g/m2, fineness are that siccative weight percent is 0.5%% after 325 mesh sieve；
Protection glaze includes marzacotto, print cream and yttrium oxide, mass ratio 3:1：0.1；Marzacotto presses quality percentage
Than meter include transparent powdered frit 65%, sodium carboxymethylcellulose 0.2%, sodium tripolyphosphate 0.2%, aluminium chloride 1%, aluminum sulfate 2%,
12 hydrazine aluminum sulfate potassium 1% and water 30.6%；Glaze proportion 1.8g/ml is protected, flow velocity 4.8g/s, fineness is through 325 mesh
Siccative weight percent is 0.4% after sieve；
Clear frit based on mass fraction, tungsten oxide 0.1%, molybdenum oxide 0.1%, nickel oxide 0.1% and 99.7% it is aforementioned
Marzacotto；Clear frit proportion is 1.4g/ml, applied amount 315g/m2；
Transparent thin frit includes by mass percentage：SnO20.1%, Pr6O110.1%, La2O30.1%,
Ce2O30.1%, TeO20.1%, Al2O310%, SiO250%, CaO15%, K2O8.1%, MgO8%, BaO6%, ZnO
2%, Lu2O30.4%；Each component dosage is equal in transparent thin frit additive；The applied amount of the transparent thin frit is 25g/
M2, application thickness are 1mm.
Comparative example 1
Compared with Example 1, the difference is that, green body does not include green body additive；
Comparative example 2
Compared with Example 1, the difference is that, ground-coat enamel does not include ground-coat enamel additive；
Comparative example 3
Compared with Example 2, the difference is that, it includes protection glaze additive to protect glaze not；
Comparative example 4
Compared with Example 2, the difference is that, clear frit does not include clear frit additive；
Comparative example 5
Compared with Example 3, the difference is that, transparent thin frit does not include transparent thin frit additive；
Comparative example 6
Compared with Example 3, the difference is that, do not include ZrO21-3%, Sb2O31-3%, Ga2O3 in ground-coat enamel.
Comparative example 7
Compared with Example 1, the difference is that, the application thickness of transparent thin frit is 2mm.
Comparative example 8
Compared with Example 2, the difference is that, Lu2O3 is free of in transparent thin frit.
The parameter of testing example 1-3 and comparative example 1-8 resulting products, as a result as shown in table 1 below：
1 test result of table
| Detection project | Glossiness | Flexural strength MPa | Water absorption rate % |
| Technical indicator | Nothing | ≥35 | ≤0.5 |
| Embodiment 1 | 29 | 45 | 0.02 |
| Embodiment 2 | 30 | 44 | 0.02 |
| Embodiment 3 | 28 | 44 | 0.02 |
| Comparative example 1 | 40 | 39 | 0.03 |
| Comparative example 2 | 63 | 43 | 0.04 |
| Comparative example 3 | 38 | 37 | 0.03 |
| Comparative example 4 | 89 | 40 | 0.03 |
| Comparative example 5 | 93 | 36 | 0.03 |
| Comparative example 6 | 73 | 40 | 0.03 |
| Comparative example 7 | 95 | 43 | 0.02 |
By upper table 1 it is found that the use of each layer of additive all has a certain impact (gloss to structural strength and glossiness
Angle value is higher, illustrates that its reflective degree is higher, mildness is poorer, and decorative effect is bad, and light effect is poor).The application for
The use of additive, the selection of ingredient optimize the Integral decoration effect of product.
The product light effect of thin crystallite sheen brick provided by the present application, acquisition is weak, will not be brought to user strong
Light stimulates, and decorative effect is similar to the height of natural jade.
For those skilled in the art, the application can have various modifications and variations.It is all in spirit herein
Within principle, any modification, equivalent replacement, improvement and so on should be included within the protection domain of the application.Although
The present invention is illustrate and described with specific embodiment, however will be appreciated that without departing substantially from the spirit and scope of the present invention
In the case of can make many other change and modification.It is, therefore, intended that including belonging to this hair in the following claims
All such changes and modifications in bright range.
Claims (10)
1. a kind of thin crystallite sheen brick, which is characterized in that including stratiform successively setting green body, ground-coat enamel, protection glaze, clear frit,
Transparent thin frit and protection glue；
The green body includes green body additive, and the green body additive is sodium chloride；
The ground-coat enamel includes ground-coat enamel additive, and the ground-coat enamel additive is C5 resin solutions, and the C5 resin solutions are that solute is
The solution that C5 resins, solvent are hexamethylene, mass concentration is 5-8%；
The protection glaze includes protection glaze additive, and the protection glaze additive is yttrium oxide；
The clear frit includes clear frit additive, and the clear frit additive is the mixing of tungsten oxide, molybdenum oxide and nickel oxide
Object；
The transparent thin frit includes transparent thin frit additive, the transparent thin frit additive be SnO2, Pr6O11,
The mixture of La2O3, Ce2O3 and TeO2；
The protection glue is methacrylic acid adhesive.
2. thin crystallite sheen brick according to claim 1, which is characterized in that the green body includes by percentage to the quality：
The green body additive 1-3%, feldspar 25-30%, pyrophillite 18-20%, kaolin 15-25%, white clay 10-12%, black mud
7-9%, gold sand stone 10-12%, ooze 1-3% and magnesia mud 1-3%.
3. thin crystallite sheen brick according to claim 1, which is characterized in that the ground-coat enamel includes by percentage to the quality：
The ground-coat enamel additive 1-3%, SiO240-55%, Al2O310-15%, CaO8-10%, MgO5-8%, ZnO10-15%,
K2O4-6%, Na2O1-3%, ZrO21-3%, Sb2O31-3%, Ga2O30.1-0.3%.
4. thin crystallite sheen brick according to claim 3, which is characterized in that the flow velocity of the ground-coat enamel is 4.5-5.0g/s,
Proportion is 1.4-1.6g/ml, and applied amount 730-750g/m2, fineness is that siccative weight percent is 0.4%- after 325 mesh sieve
0.6%.
5. thin crystallite sheen brick according to claim 1, which is characterized in that the protection glaze includes marzacotto, print cream
With the protection glaze additive, mass ratio 2-4:1：0.1；The marzacotto includes transparent powdered frit by mass percentage
60-65%, sodium carboxymethylcellulose 0.2-0.5%, sodium tripolyphosphate 0.2-0.4%, aluminium chloride 1-2%, aluminum sulfate 1-2%,
12 hydrazine aluminum sulfate potassium 1-2% and water 30-36%.
6. thin crystallite sheen brick according to claim 5, which is characterized in that the protection glaze proportion 1.5-2.0g/ml, stream
Speed is 4.5-5.0g/s, and fineness is that siccative weight percent is 0.3-0.5% after 325 mesh sieve.
7. thin crystallite sheen brick according to claim 5, which is characterized in that the clear frit based on mass fraction, including
The 0.3% clear frit additive and 99.7% marzacotto, the tungsten oxide, the molybdenum oxide and the oxidation
The mass ratio of nickel is 1:1:1.
8. thin crystallite sheen brick according to claim 7, which is characterized in that the clear frit proportion is 1.2-1.5g/ml,
Applied amount is 310-320g/m2.
9. thin crystallite sheen brick according to claim 1, which is characterized in that the transparent thin frit is by mass percentage
Including：The transparent thin frit additive 0.5%, Al2O35-15%, SiO240-55%, CaO10-18%, K2O5-10%,
MgO5-12%, BaO4-10%, ZnO 2-5%, Lu2O30.1-0.5%；Each component dosage in the transparent thin frit additive
It is equal.
10. thin crystallite sheen brick according to claim 9, which is characterized in that the applied amount of the transparent thin frit is 23-
28g/m2, application thickness are 0.8-1.2mm.
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|---|---|---|---|---|
| JPH11130511A (en) * | 1997-10-23 | 1999-05-18 | Moriaki Oogushi | Pottery with attached heat resistant fiber |
| CN102503575A (en) * | 2011-11-02 | 2012-06-20 | 广东博德精工建材有限公司 | Method for producing transparent clinker capable of being compounded with colored glaze ceramic blank |
| CN103833423A (en) * | 2014-01-14 | 2014-06-04 | 佛山市东鹏陶瓷有限公司 | Ceramic tile preparation method and product thereof |
| CN104478491A (en) * | 2014-12-30 | 2015-04-01 | 佛山市三水新明珠建陶工业有限公司 | Enameled tile with protection enamel layer and manufacturing method thereof |
-
2018
- 2018-06-29 CN CN201810713086.0A patent/CN108751937B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11130511A (en) * | 1997-10-23 | 1999-05-18 | Moriaki Oogushi | Pottery with attached heat resistant fiber |
| CN102503575A (en) * | 2011-11-02 | 2012-06-20 | 广东博德精工建材有限公司 | Method for producing transparent clinker capable of being compounded with colored glaze ceramic blank |
| CN103833423A (en) * | 2014-01-14 | 2014-06-04 | 佛山市东鹏陶瓷有限公司 | Ceramic tile preparation method and product thereof |
| CN104478491A (en) * | 2014-12-30 | 2015-04-01 | 佛山市三水新明珠建陶工业有限公司 | Enameled tile with protection enamel layer and manufacturing method thereof |
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