CN108751795A - A kind of permeable granitic production technology of artificial ecological - Google Patents

A kind of permeable granitic production technology of artificial ecological Download PDF

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Publication number
CN108751795A
CN108751795A CN201810921884.2A CN201810921884A CN108751795A CN 108751795 A CN108751795 A CN 108751795A CN 201810921884 A CN201810921884 A CN 201810921884A CN 108751795 A CN108751795 A CN 108751795A
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CN
China
Prior art keywords
parts
permeable
artificial ecological
granitic
stone
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Pending
Application number
CN201810921884.2A
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Chinese (zh)
Inventor
孙法虎
孙启祥
马驰
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Zaozhuang Snksan Intelligent Machinery Co Ltd
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Zaozhuang Snksan Intelligent Machinery Co Ltd
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Priority to CN201810921884.2A priority Critical patent/CN108751795A/en
Publication of CN108751795A publication Critical patent/CN108751795A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/18Polyesters; Polycarbonates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00284Materials permeable to liquids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/54Substitutes for natural stone, artistic materials or the like
    • C04B2111/542Artificial natural stone

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a kind of permeable granites of artificial ecological, including below according to the raw material of parts by weight:100-120 parts of stone, 6-9 parts of glass waste, 100-120 parts of unsaturated polyester resin, 10-15 parts of ashes bits, 9-14 parts of shraff, 5-9 parts of drier, poly- light ball 1-5 parts, the invention also discloses the permeable granitic production technologies of the artificial ecological.Unsaturated polyester resin, drier are added in product of the present invention, it is at low cost, it greatly improves the structure wear-resisting property of product, compressive property and anti-tears strength character open, water permeability is good, recharge of groundwater, recharging groundwater, not only the generation of urban flooding had been reduced, but also has kept valuable freshwater resources here, has significantly improved ecology and the life in city.

Description

A kind of permeable granitic production technology of artificial ecological
Technical field
The present invention relates to decorative building material technical field, specifically a kind of permeable granitic production technology of artificial ecological.
Background technology
Granite is that a kind of lava by volcano eruption swells under the molten condition by comparable pressure to earth's crust table Layer, magma do not spray ground, and the tectonite formed behind underground slowly cooled and solidified, are a kind of plutonic acidic igneous rocks, Belong to magmatic rock (igneous rock).Granite is using quartz, feldspar and mica as main component.Wherein feldspar content is 40%-60%, stone English content is 20%-40%, and color is decided by the type and quantity of ingredient.Granite is the rock of holocrystalline structure, excellent Matter granite crystal grain is thin and uniform, construction is close, quartz content is more, feldspar gloss is bright.Granitic dioxide-containing silica compared with Height belongs to acid rock.Certain granites contain trace-level activity element, and this kind of granite should be avoided for interior.Granite Compact structure, quality be hard, acid and alkali-resistance, against weather are good, can be in outdoor long-time service.
But existing granite water permeability is poor, and natural stone resource is limited, Costco Wholesale is high, as society is sent out Exhibition, country proposes to greatly develop conservation culture and sponge urban construction, therefore proposes a kind of permeable granitic life of artificial ecological Production. art.
Invention content
The purpose of the present invention is to provide a kind of permeable granitic production technologies of artificial ecological, to solve above-mentioned background skill The problem of being proposed in art.
To achieve the above object, the present invention provides the following technical solutions:A kind of permeable granite of artificial ecological, including it is following According to the raw material of parts by weight:100-120 parts of stone, 6-9 parts of glass waste, 100-120 parts of unsaturated polyester resin, ashes bits 10-15 parts, 9-14 parts of shraff, 5-9 parts of drier, poly- light ball 1-5 parts;
The waste residue refers to not generating the industrial residue of physical and chemical changes, such as after steel plant, smeltery are by refinement Waste residue.
The shraff, glass waste refer to the substandard product of ceramics and glass, such as damaged ceramics, glass and useless pottery Porcelain and cullet.
The unsaturated polyester resin is O-phthalic acid type, M-phthalic acid type, bisphenol A-type and vinyl ester type, halogen For in unsaturated polyester resin one kind or mixed in equal amounts forms two-by-two.
As a further solution of the present invention:The permeable granitic production technology of artificial ecological, specific steps are such as Under:
S1 is crushed, and stone, glass waste, shraff, ashes bits are clayed into power shape using crusher, the crusher Model PE-250 × 400, discharging-material size 20-60mm, motor power (output) 15KW;
Stone after being crushed in S1, glass waste, ashes bits are mixed, and drier, poly- light ball are added, are added by S2, mixing The water of 500g, is uniformly mixed, and mixing while is heated, and heating condition is:10 DEG C of rate per minute rises to 50- It 60 DEG C, during which uninterruptedly stirs, heating time 30-40min;Obtain mixture;
S3, matrix cast, mixture is cast in the fine sand layer in mold, smooth through pushing, under vibration or reduced pressure Deposition is filled in degasification, waits for matrix gel, hardening, then demould;
S4, solidification, 5-8 hours are kept the temperature under the conditions of 60-65 DEG C, eliminate the internal stress generated when solidification, trimmed to obtain finished product.
Compared with prior art, the beneficial effects of the invention are as follows:
1, the artificial granitic raw material of ecological permeable of the present invention is extremely important to industry pollution treatment and environmental protection, is conducive to green warp Ji development;The utilization of the industrial residues such as waste ceramic, cullet reduces pollution of the industrial residue to environment, the recyclable cycle of product It recycles, greatlys save mineral resources;Product can be recycled repeatedly, be conducive to the development of circular economy;
2, unsaturated polyester resin, drier are added in product, it is at low cost, greatly improve product structure wear-resisting property, Compressive property and anti-tear strength character open;
3, water permeability is good, recharge of groundwater, recharging groundwater, has not only reduced the generation of urban flooding, but also keeps valuable fresh water here Resource significantly improves ecology and the life in city.
Specific implementation mode
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common The every other embodiment that technical staff is obtained without making creative work belongs to the model that the present invention protects It encloses.
Embodiment 1
A kind of permeable granite of artificial ecological, including below according to the raw material of parts by weight:100 parts of stone, 6 parts of glass waste, no It is saturated 100 parts of alkyd resin, 10 parts of ashes bits, 9 parts of shraff, 5 parts of drier, 1 part of poly- light ball;
The waste residue refers to not generating the industrial residue of physical and chemical changes, such as after steel plant, smeltery are by refinement Waste residue.
The shraff, glass waste refer to the substandard product of ceramics and glass, such as damaged ceramics, glass.
The unsaturated polyester resin is O-phthalic acid type.
In the present embodiment, the permeable granitic production technology of artificial ecological is as follows:
S1 is crushed, and stone, glass waste, shraff, ashes bits are clayed into power shape using crusher, the crusher Model PE-250 × 400, discharging-material size 20mm, motor power (output) 15KW;
Stone after being crushed in S1, glass waste, ashes bits are mixed, and drier, poly- light ball are added, are added by S2, mixing The water of 500g, is uniformly mixed, and mixing while is heated, and heating condition is:10 DEG C of rate per minute rises to 50 DEG C, it during which uninterruptedly stirs, heating time 30min;Obtain mixture;
S3, matrix cast, mixture is cast in the fine sand layer in mold, smooth through pushing, under vibration or reduced pressure Deposition is filled in degasification, waits for matrix gel, hardening, then demould;
S4, solidification, 5 hours are kept the temperature under the conditions of 60 DEG C, eliminate the internal stress generated when solidification, trimmed to obtain finished product.
Embodiment 2
A kind of permeable granite of artificial ecological, including below according to the raw material of parts by weight:108 parts of stone, 7 parts of glass waste, no It is saturated 110 parts of alkyd resin, 11 parts of ashes bits, 10 parts of shraff, 6 parts of drier, 2 parts of poly- light ball;
The waste residue refers to the industrial residue for not generating physical and chemical changes, as smeltery passes through the waste residue after refinement.
The shraff, glass waste refer to the substandard product of ceramics and glass, such as waste ceramic and cullet.
The unsaturated polyester resin is M-phthalic acid type.
In the present embodiment, the permeable granitic production technology of artificial ecological is as follows:
S1 is crushed, and stone, glass waste, shraff, ashes bits are clayed into power shape using crusher, the crusher Model PE-250 × 400, discharging-material size 30mm, motor power (output) 15KW;
Stone after being crushed in S1, glass waste, ashes bits are mixed, and drier, poly- light ball are added, are added by S2, mixing The water of 500g, is uniformly mixed, and mixing while is heated, and heating condition is:10 DEG C of rate per minute rises to 54 DEG C, it during which uninterruptedly stirs, heating time 33min;Obtain mixture;
S3, matrix cast, mixture is cast in the fine sand layer in mold, smooth through pushing, under vibration or reduced pressure Deposition is filled in degasification, waits for matrix gel, hardening, then demould;
S4, solidification, 6 hours are kept the temperature under the conditions of 62 DEG C, eliminate the internal stress generated when solidification, trimmed to obtain finished product.
Embodiment 3
A kind of permeable granite of artificial ecological, including below according to the raw material of parts by weight:115 parts of stone, 7 parts of glass waste, no It is saturated 113 parts of alkyd resin, 13 parts of ashes bits, 12 parts of shraff, 8 parts of drier, 3.5 parts of poly- light ball;
The waste residue refers to the industrial residue for not generating physical and chemical changes, as steel plant pass through the waste residue after refinement.
The shraff, glass waste refer to the substandard product of ceramics and glass, such as damaged ceramics, glass.
The unsaturated polyester resin is bisphenol A-type and vinyl ester type.
In the present embodiment, the permeable granitic production technology of artificial ecological is as follows:
S1 is crushed, and stone, glass waste, shraff, ashes bits are clayed into power shape using crusher, the crusher Model PE-250 × 400, discharging-material size 50mm, motor power (output) 15KW;
Stone after being crushed in S1, glass waste, ashes bits are mixed, and drier, poly- light ball are added, are added by S2, mixing The water of 500g, is uniformly mixed, and mixing while is heated, and heating condition is:10 DEG C of rate per minute rises to 57 DEG C, it during which uninterruptedly stirs, heating time 38min;Obtain mixture;
S3, matrix cast, mixture is cast in the fine sand layer in mold, smooth through pushing, under vibration or reduced pressure Deposition is filled in degasification, waits for matrix gel, hardening, then demould;
S4, solidification, 7 hours are kept the temperature under the conditions of 63 DEG C, eliminate the internal stress generated when solidification, trimmed to obtain finished product.
Embodiment 4
A kind of permeable granite of artificial ecological, including below according to the raw material of parts by weight:120 parts of stone, 9 parts of glass waste, no It is saturated 120 parts of alkyd resin, 15 parts of ashes bits, 14 parts of shraff, 9 parts of drier, 5 parts of poly- light ball;
The waste residue refers to the industrial residue for not generating physical and chemical changes, as smeltery passes through the waste residue after refinement.
The shraff, glass waste refer to the substandard product of ceramics and glass, such as damaged ceramics, glass.
The unsaturated polyester resin is halogenated unsaturated polyester resin.
In the present embodiment, the permeable granitic production technology of artificial ecological is as follows:
S1 is crushed, and stone, glass waste, shraff, ashes bits are clayed into power shape using crusher, the crusher Model PE-250 × 400, discharging-material size 60mm, motor power (output) 15KW;
Stone after being crushed in S1, glass waste, ashes bits are mixed, and drier, poly- light ball are added, are added by S2, mixing The water of 500g, is uniformly mixed, and mixing while is heated, and heating condition is:10 DEG C of rate per minute rises to 60 DEG C, it during which uninterruptedly stirs, heating time 40min;Obtain mixture;
S3, matrix cast, mixture is cast in the fine sand layer in mold, smooth through pushing, under vibration or reduced pressure Deposition is filled in degasification, waits for matrix gel, hardening, then demould;
S4, solidification, 8 hours are kept the temperature under the conditions of 65 DEG C, eliminate the internal stress generated when solidification, trimmed to obtain finished product.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Profit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiment being appreciated that.

Claims (8)

1. a kind of permeable granite of artificial ecological, which is characterized in that including below according to the raw material of parts by weight:Stone 100-120 Part, 6-9 parts of glass waste, 100-120 parts of unsaturated polyester resin, 10-15 parts of ashes bits, 9-14 parts of shraff, drying 5-9 parts of agent, poly- light ball 1-5 parts.
2. the permeable granite of artificial ecological according to claim 1, which is characterized in that the waste residue refers to not generation The industrial residue of reason and chemical change.
3. the permeable granite of artificial ecological according to claim 2, which is characterized in that the shraff, glass waste It refer to the substandard product of ceramics and glass.
4. the permeable granite of artificial ecological according to claim 3, which is characterized in that the unsaturated polyester resin is neighbour One kind in terephthalate-type, M-phthalic acid type, bisphenol A-type and vinyl ester type, halogenated unsaturated polyester resin.
5. a kind of permeable granitic production technology of artificial ecological as described in claim 1-4 is any, which is characterized in that step It is as follows:
S1 is crushed, and stone, glass waste, shraff, ashes bits are clayed into power shape using crusher;
Stone after being crushed in S1, glass waste, ashes bits are mixed, and drier, poly- light ball are added, are added by S2, mixing The water of 500g, is uniformly mixed, and mixing while is heated, and mixture is obtained;
S3, matrix cast, mixture is cast in the fine sand layer in mold, smooth through pushing, under vibration or reduced pressure Deposition is filled in degasification, waits for matrix gel, hardening, then demould;
S4, solidification, 5-8 hours are kept the temperature under the conditions of 60-65 DEG C, eliminate the internal stress generated when solidification, trimmed to obtain finished product.
6. the permeable granitic production technology of artificial ecological according to claim 5, which is characterized in that in step S1, institute State crusher model PE-250 × 400, discharging-material size 20-60mm, motor power (output) 15KW.
7. the permeable granitic production technology of artificial ecological according to claim 6, which is characterized in that in step S2, add Heat condition is:10 DEG C of rate per minute rises to 50-60 DEG C, during which uninterruptedly stirs, heating time 30-40min.
8. purposes of the granite in producing stonite's product as described in claim 1-4 is any.
CN201810921884.2A 2018-08-14 2018-08-14 A kind of permeable granitic production technology of artificial ecological Pending CN108751795A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020238716A1 (en) * 2019-05-24 2020-12-03 南京林业大学 Method for preparing garden rockery or terrain by using solid waste of buildings regenerated from demolition sites

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1076158A (en) * 1992-03-09 1993-09-15 孔凯旋 Man-made composite slabstone
CN1188748A (en) * 1997-01-21 1998-07-29 王纯玉 Granolith and its manufacturing method
CN105271945A (en) * 2015-09-29 2016-01-27 广西钟山县中源石业有限公司 Artificial granite and making method thereof
CN107446507A (en) * 2017-09-11 2017-12-08 济南大学 A kind of preparation method of granite polishing powder
CN107445643A (en) * 2016-06-01 2017-12-08 上海铭成永美环保科技有限公司 A kind of permeable granite of artificial ecological
CN107445650A (en) * 2016-06-01 2017-12-08 上海铭成永美环保科技有限公司 A kind of permeable granite of artificial ecological

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1076158A (en) * 1992-03-09 1993-09-15 孔凯旋 Man-made composite slabstone
CN1188748A (en) * 1997-01-21 1998-07-29 王纯玉 Granolith and its manufacturing method
CN105271945A (en) * 2015-09-29 2016-01-27 广西钟山县中源石业有限公司 Artificial granite and making method thereof
CN107445643A (en) * 2016-06-01 2017-12-08 上海铭成永美环保科技有限公司 A kind of permeable granite of artificial ecological
CN107445650A (en) * 2016-06-01 2017-12-08 上海铭成永美环保科技有限公司 A kind of permeable granite of artificial ecological
CN107446507A (en) * 2017-09-11 2017-12-08 济南大学 A kind of preparation method of granite polishing powder

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020238716A1 (en) * 2019-05-24 2020-12-03 南京林业大学 Method for preparing garden rockery or terrain by using solid waste of buildings regenerated from demolition sites
AU2020260393B2 (en) * 2019-05-24 2022-04-07 Nanjing Forestry University Method for preparing garden rockery or terrain by recycling building solid waste on demolished site

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Application publication date: 20181106