CN108743999A - A kind of solid shoes tablet and preparation method thereof with citris aromas - Google Patents
A kind of solid shoes tablet and preparation method thereof with citris aromas Download PDFInfo
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- CN108743999A CN108743999A CN201810563782.8A CN201810563782A CN108743999A CN 108743999 A CN108743999 A CN 108743999A CN 201810563782 A CN201810563782 A CN 201810563782A CN 108743999 A CN108743999 A CN 108743999A
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- 239000007787 solid Substances 0.000 title claims abstract description 74
- 238000002360 preparation method Methods 0.000 title claims abstract description 49
- 235000019568 aromas Nutrition 0.000 title abstract description 24
- 235000005979 Citrus limon Nutrition 0.000 claims abstract description 126
- 239000002994 raw material Substances 0.000 claims abstract description 99
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 62
- 239000000796 flavoring agent Substances 0.000 claims abstract description 51
- 235000019634 flavors Nutrition 0.000 claims abstract description 51
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 45
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical class [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims abstract description 29
- 238000000034 method Methods 0.000 claims abstract description 26
- 235000019359 magnesium stearate Nutrition 0.000 claims abstract description 15
- 229920002261 Corn starch Polymers 0.000 claims abstract description 14
- 239000008120 corn starch Substances 0.000 claims abstract description 14
- 229940099112 cornstarch Drugs 0.000 claims abstract description 14
- 229920000168 Microcrystalline cellulose Polymers 0.000 claims abstract description 13
- 235000019813 microcrystalline cellulose Nutrition 0.000 claims abstract description 13
- 244000131522 Citrus pyriformis Species 0.000 claims description 123
- 239000000203 mixture Substances 0.000 claims description 60
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 54
- 241000207199 Citrus Species 0.000 claims description 46
- 235000020971 citrus fruits Nutrition 0.000 claims description 46
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 28
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 claims description 26
- 239000000341 volatile oil Substances 0.000 claims description 25
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 24
- 150000001299 aldehydes Chemical class 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 14
- HZYHMHHBBBSGHB-ODYTWBPASA-N (2E,6Z)-nona-2,6-dienal Chemical compound CC\C=C/CC\C=C\C=O HZYHMHHBBBSGHB-ODYTWBPASA-N 0.000 claims description 13
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 claims description 13
- 240000000560 Citrus x paradisi Species 0.000 claims description 13
- WEEGYLXZBRQIMU-UHFFFAOYSA-N Eucalyptol Chemical compound C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 claims description 13
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 13
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 claims description 13
- RFFOTVCVTJUTAD-UHFFFAOYSA-N cineole Natural products C1CC2(C)CCC1(C(C)C)O2 RFFOTVCVTJUTAD-UHFFFAOYSA-N 0.000 claims description 13
- 229960005233 cineole Drugs 0.000 claims description 13
- 235000000484 citronellol Nutrition 0.000 claims description 13
- 239000012153 distilled water Substances 0.000 claims description 13
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims description 13
- -1 hexanal ethanol Chemical compound 0.000 claims description 13
- IPWBXORAIBJDDQ-UHFFFAOYSA-N methyl 2-hexyl-3-oxocyclopentane-1-carboxylate Chemical compound CCCCCCC1C(C(=O)OC)CCC1=O IPWBXORAIBJDDQ-UHFFFAOYSA-N 0.000 claims description 13
- KXFSUVJPEQYUGN-UHFFFAOYSA-N trimethyl(phenyl)silane Chemical compound C[Si](C)(C)C1=CC=CC=C1 KXFSUVJPEQYUGN-UHFFFAOYSA-N 0.000 claims description 13
- 244000089742 Citrus aurantifolia Species 0.000 claims description 12
- AWUQZYYGHWROOV-UHFFFAOYSA-N decanal ethanol Chemical compound CCO.CCCCCCCCCC=O AWUQZYYGHWROOV-UHFFFAOYSA-N 0.000 claims description 12
- 239000008108 microcrystalline cellulose Substances 0.000 claims description 12
- 229940016286 microcrystalline cellulose Drugs 0.000 claims description 12
- 239000000377 silicon dioxide Substances 0.000 claims description 9
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 7
- 239000011435 rock Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 238000005516 engineering process Methods 0.000 claims description 3
- 229910003978 SiClx Inorganic materials 0.000 claims description 2
- 238000004458 analytical method Methods 0.000 claims 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 1
- 240000008042 Zea mays Species 0.000 claims 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- 238000005352 clarification Methods 0.000 claims 1
- 235000005822 corn Nutrition 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 239000013049 sediment Substances 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- 239000010985 leather Substances 0.000 abstract description 27
- 239000003205 fragrance Substances 0.000 abstract description 26
- 230000002045 lasting effect Effects 0.000 abstract description 11
- 125000003118 aryl group Chemical group 0.000 abstract description 8
- 244000248349 Citrus limon Species 0.000 abstract 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 15
- 235000013339 cereals Nutrition 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 230000001953 sensory effect Effects 0.000 description 6
- 238000012512 characterization method Methods 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- JKGITWJSGDFJKO-UHFFFAOYSA-N ethoxy(trihydroxy)silane Chemical class CCO[Si](O)(O)O JKGITWJSGDFJKO-UHFFFAOYSA-N 0.000 description 5
- 230000035943 smell Effects 0.000 description 5
- 230000002459 sustained effect Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000000022 bacteriostatic agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 230000036651 mood Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/012—Deodorant compositions characterised by being in a special form, e.g. gels, emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/013—Deodorant compositions containing animal or plant extracts, or vegetable material
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/014—Deodorant compositions containing sorbent material, e.g. activated carbon
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/20—Method-related aspects
- A61L2209/21—Use of chemical compounds for treating air or the like
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/20—Method-related aspects
- A61L2209/22—Treatment by sorption, e.g. absorption, adsorption, chemisorption, scrubbing, wet cleaning
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Botany (AREA)
- Zoology (AREA)
- Dispersion Chemistry (AREA)
- Fats And Perfumes (AREA)
Abstract
The invention discloses a kind of lemon flavor solid shoes fragrant tablets and preparation method thereof.It prepares raw material and is calculated by mass percentage is made of 43%-50% microcrystalline celluloses, 25%-30% cornstarch, 6%-8% nano-silicon dioxide hollow spheres, 8%-10% essence and 2%-18% magnesium stearates.The present invention utilizes the characteristics of nano-silicon dioxide hollow sphere cavity volume and large specific surface area, lemon extract is largely adsorbed, solid aromatic tablet with citris aromas is prepared using pressed disc method, the lemon flavor solid shoes are positioned over leather shoes with inside with fragrant tablet, leather shoes bad smell, fragrance harmonizing nature can be effectively covered, lasting is up to as long as June.
Description
Technical field
The present invention relates to a kind of solid shoes fragrant tablet, more particularly to a kind of solid shoes tablets with citris aromas
And preparation method thereof, belong to chemical field.
Background technology
Currently, with the continuous development of science and technology and people's living standards continue to improve, consumer is to leather and fur products
Demand be not merely satisfied with the demands such as comfortable feel, beautiful style and higher quality.Leather and fur products itself has
There is particularity smell specific to fur, such as meals, stink, although in leather processing procedure, these bad smells obtain centainly
Improvement, but still cannot remove completely.At the same time, it inevitably needs in process using some chemical materials
Material, especially during leather shoes are manufactured, needs that various inorganic agents, additive and adhesive etc. is added, leather shoes is caused to produce
Product have penetrating odor after completing.Aromatic props such as Aroma fabric, fragrant pencil, fragrant wallpaper etc. are continuous in recent years
It emerges in large numbers, fragrant leather products also have become a kind of development trend of leather industry.
However, the flavoring mode used in leather shoes product field so far is generally by using fragrant insole, virtue
Fragrant paper for polishing leather shoes, the modes such as sole flavoring carry out flavoring to leather shoes, as Publication No. CN107761455A reports a kind of fragrance
The production method of shoes cleaning paper is squeezed after woolliness paper is fully soaked in chemical fragrance and is made；Publication No.
CN202552353U reports a kind of antibacterial fragrance drifting leather shoes, and the antibacterial fragrance drifting function of the leather shoes is by essence and rubber pange shoes
A kind of flavoring expanded material of prepared by material is compound is simultaneously fixed in shoes, while being added shoes sterilizing agent and being realized.But
Existing fragrance leather shoes product is all directly to carry out flavoring using essence, destroys essence active ingredient to a certain extent, also
It is short that there are fragrance remaining times, fragrance instability problem.
Invention content
It is all directly to be carried out using essence that an object of the present invention, which is to solve above-mentioned existing fragrant leather shoes product,
The technical problems such as flavoring destroys essence active ingredient to a certain extent, and it is short that there is also fragrance remaining times, and fragrance is unstable and carry
For a kind of fragrant tablet of the solid shoes with citris aromas, it is that use is received to be somebody's turn to do the solid shoes with citris aromas with fragrant tablet
Rice hollow silica ball adsorbs lemon extract, while nano-silicon dioxide hollow sphere has higher specific surface area can
Essence is largely adsorbed, essence stability is improved, avoids the loss of effective fragrance component in product preparation process, make production
As long as product fragrance remaining time is up to June, have many advantages, such as that lasting is lasting, fragrance is stable and preparation process is simple.
This fragrance tablet is used for the heel position of leather shoes, can cover the bad smell of leather shoes product, and it is pure and fresh certainly to assign its
Right citris aromas.
The second object of the present invention is to provide a kind of preparation of the fragrant tablet of above-mentioned solid shoes with citris aromas
Method, the preparation method carry out absorption for the fragrant tablet of solid shoes due to the use of nano-silicon dioxide hollow sphere to essence
It prepares,
Technical scheme of the present invention
A kind of fragrant tablet of lemon flavor solid shoes, is calculated by mass percentage, the raw material used in preparation process
Composition and content are as follows：
The average grain diameter of the nano-silicon dioxide hollow sphere is 200-500nm；
A kind of above-mentioned lemon flavor solid shoes preparation method of fragrant tablet, specifically comprises the following steps：
(1), the preparation of nano-silicon dioxide hollow sphere
1., nano-silicon dioxide hollow sphere prepare raw material used, in parts by weight, raw material composition and content are such as
Under：
2., nano-silicon dioxide hollow sphere preparation process is as follows：
Trimethyl phenyl silane and water are mixed, it is that 300r/min stirs 1h that rotating speed is controlled in 60 DEG C of water-baths, so
Ethyl orthosilicate and concentrated ammonia liquor are added afterwards, continues to control rotating speed under 60 DEG C of water bath conditions to be that 300r/min is stirred to react 3h, gained
Reaction solution controlled at 60-90 DEG C be dried to get to average grain diameter be 200-500nm nano silicon dioxide it is hollow
Ball；
(2), the preparation of citrus scented solution
1., citrus scented solution prepare raw material used, be calculated by mass percentage, raw material composition and content are as follows：
2., citrus scented solution preparation process is as follows：
The mass percent that raw material used is prepared by above-mentioned citrus scented solution calculates, successively by grapefruit essential oil, in vain
Lemon, lemon, the ethanol water that concentration of volume percent is 70%, which is added in separatory funnel, rocks mixing, then
Distilled water jog funnel is added, each raw material is made to be uniformly mixed, 24-48h layerings are stood under the conditions of 4-5 DEG C, it is clear obtained by lower layer
Clear solution is citrus scented solution；
(3), the preparation of lemon extract
1., lemon extract prepare raw material used, be calculated by mass percentage, raw material composition and content are as follows：
2., lemon extract preparation process is as follows：
The mass percent that raw material used is prepared by above-mentioned lemon extract calculates, the lemon of the 2. gained in step (2)
It is 1% that cucumber aldehyde ethanol solution, concentration of volume percent that concentration of volume percent is 1% are sequentially added in lemon aroma solution
The last of the ten Heavenly stems that hexanal ethanol solution that cis- 6- nonenyl aldehydes ethanol solution, concentration of volume percent are 1%, concentration of volume percent are 1%
Aldehyde ethanol solution, dihydrojasmonate, ethyl acetate, Cineole and citronellol are after mixing to get lemon extract；
(4), the preparation of the fragrant tablet of lemon flavor solid shoes
By lemon flavor solid shoes with fragrant tablet prepare it is raw materials used be calculated by mass percentage, first by crystallite fibre
Dimension, cornstarch, nano-silicon dioxide hollow sphere, lemon extract and magnesium stearate are sufficiently mixed uniformly, obtain mixture, then
The mixture of gained is added in the mould for tabletting press of a diameter of 12mm, with the pressure of 10-15kN it is tabletted to get to
The fragrant tablet of lemon flavor solid shoes.
A kind of fragrant tablet of above-mentioned solid shoes with citris aromas, is used for leather shoes heel, is processed in leather shoes making
It is positioned in the process inside leather shoes heel, i.e., between the air-permeable layer of heel position and heel groove, skin is neither influenced when wearing
While shoes comfort, and it can make fragrance component in the process of walking since pressing and rubbing action make fragrance component release
Come.
A kind of above-mentioned solid shoes with citris aromas fragrant tablet and preparation method thereof, is suitable for passing through nanometer two
Silica hollow ball loads the essence of other different aromas, to prepare the solid shoes fragrant slice with a variety of different aromas
Agent discharges a variety of fragrance.
The advantageous effects of the present invention
The fragrant tablet of a kind of solid shoes with citris aromas of the present invention, due to happy citris aromas feature
Lemon extract is and to be made into tablet using nano-silicon dioxide hollow sphere as load and be directly used in leather shoes heel, greatly
Ground simplifies perfuming process.
Further, the fragrant tablet of a kind of solid shoes with citris aromas of the invention, due to preparing lemon used
Essence has pure and fresh citris aromas, can set the mind at rest, pleasure mood, while also having certain bacteriostasis, contributes to
Inhibit bacteria breed in shoes, without additionally dosing shoes bacteriostatic agent.
Further, the fragrant tablet of a kind of solid shoes with citris aromas of the invention, prepares nano-silica used
There is SiClx hollow ball higher specific surface area can adsorb a large amount of essence, have good protection and slow releasing function to essence,
The persistence and stability for ensuring essence lasting are released as long as the fragrant time is June, to effectively cover leather shoes in process
The bad smell of middle generation.
Further, the preparation method of the fragrant tablet of a kind of solid shoes with citris aromas of the invention, due to the use of
Addition tablet ingredients processed, can directly prepare piece agent, will not be broken while nano-silicon dioxide hollow sphere adsorbs essence, and
It is positioned in leather shoes process between heel air-permeable layer and groove, reduces the loss of fragrance component, therefore with essence profit
With rate height, it is easy to the characteristics of release.
Specific implementation mode
The present invention is further illustrated below by specific embodiment, but is not intended to limit the present invention.
The specification of various raw materials used in various embodiments of the present invention and the information of manufacturer are except following special instructions
Outside, it is commercially available：
The tablet press machine of a diameter of 12mm used in various embodiments of the present invention, model TDP-1.5, the bright brightness machinery in Chengdu have
Limit company produces.
Embodiment 1
A kind of fragrant tablet of lemon flavor solid shoes, is calculated by mass percentage, the raw material used in preparation process
Composition and content are as follows：
The average grain diameter of the nano-silicon dioxide hollow sphere is 200-500nm.
Above-mentioned nano-silicon dioxide hollow sphere prepares raw material used, and in parts by weight, raw material forms and contains
Amount is as follows：
Above-mentioned nano-silicon dioxide hollow sphere preparation process is as follows：
0.6g trimethyl phenyl silane and 97.1g water are added in the single necked round bottom flask of 250ml and mixed, 60
Control rotating speed is that 300r/min stirs 1h in DEG C water-bath, and 1.8g ethyl orthosilicates and 0.5g concentrated ammonia liquors, 60 DEG C of water-baths are then added
Under the conditions of continue control rotating speed be 300r/min be stirred to react 3h, the reaction solution of gained is dried controlled at 60 DEG C, i.e.,
Obtain the nano-silicon dioxide hollow sphere that average grain diameter is 200-500nm；
The lemon extract prepares raw material used, is calculated by mass percentage, and composition and content are as follows：
Above-mentioned lemon extract is prepared by a method comprising the following steps：
Raw material used, which is prepared, by above-mentioned lemon extract sequentially adds concentration of volume percent in citrus scented solution
For 1% cucumber aldehyde ethanol solution, concentration of volume percent be 1% cis- 6- nonenyl aldehydes ethanol solution, concentration of volume percent
For 1% hexanal ethanol solution, concentration of volume percent be 1% capraldehyde ethanol solution, dihydrojasmonate, acetic acid second
Ester, Cineole and citronellol are after mixing to get lemon extract；
The above-mentioned raw material citrus scented solution prepared used in lemon extract prepares raw material used, by mass percentage
It calculates, composition and content are as follows：
Above-mentioned citrus scented solution is prepared by a method comprising the following steps：
Raw material used is prepared by above-mentioned citrus scented solution, successively by grapefruit essential oil, limette essential oil, lemon
The ethanol water for being 70% with concentration of volume percent, which is added in separatory funnel, rocks mixing, and the leakage of distilled water jog is then added
Bucket makes each raw material be uniformly mixed, stands under the conditions of 4-5 DEG C and be layered for 24 hours, the clear solution obtained by lower layer is that citrus scented is molten
Liquid.
A kind of above-mentioned lemon flavor solid shoes are prepared with the method for fragrant tablet as follows：
Fragrant tablet is used to prepare by lemon flavor solid shoes raw materials used, first by microcrystalline cellulose, cornstarch, nanometer two
Silica hollow ball, lemon extract and magnesium stearate are sufficiently mixed uniformly, obtain mixture, and then the mixture of gained is added
It is tabletted to get fragrant to lemon flavor solid shoes with the pressure of 10kN into the mould for tabletting press of a diameter of 12mm
Tablet.
Using sensory evaluation method (Xiao Z, Zhang Y, Zhu G, et al.Preparation and
sustained-releasing characterization of aromatic wallpaper[J].Progress in
Organic Coatings,2017,104:When 50-57.) to the lasting of the fragrant tablet of the lemon flavor solid shoes of above-mentioned gained
Between be measured, the results showed that prepared solid shoes with fragrant tablet fragrance remaining time up to May as long as, and with stable
Pure and fresh citris aromas.
Embodiment 2
A kind of fragrant tablet of lemon flavor solid shoes, is calculated by mass percentage, the raw material used in preparation process
Composition and content are as follows：
The average grain diameter of the nano-silicon dioxide hollow sphere is 200-500nm.
Above-mentioned nano-silicon dioxide hollow sphere prepares raw material used, and in parts by weight, raw material forms and contains
Amount is as follows：
Above-mentioned nano-silicon dioxide hollow sphere preparation process is as follows：
1.0g trimethyl phenyl silane and 95.8g water are added in the single necked round bottom flask of 250ml and mixed, 60
Control rotating speed is that 300r/min stirs 1h in DEG C water-bath, and 2.2g ethyl orthosilicates and 1.0g concentrated ammonia liquors, 60 DEG C of water-baths are then added
Under the conditions of continue control rotating speed be 300r/min be stirred to react 3h, the reaction solution of gained is dried controlled at 90 DEG C, i.e.,
Obtain the nano-silicon dioxide hollow sphere that average grain diameter is 200-500nm；
The lemon extract prepares raw material used, is calculated by mass percentage, and raw material composition and content are as follows：
Above-mentioned lemon extract is prepared by a method comprising the following steps：
Raw material used, which is prepared, by above-mentioned lemon extract sequentially adds concentration of volume percent in citrus scented solution
For 1% cucumber aldehyde ethanol solution, concentration of volume percent be 1% cis- 6- nonenyl aldehydes ethanol solution, concentration of volume percent
For 1% hexanal ethanol solution, concentration of volume percent be 1% capraldehyde ethanol solution, dihydrojasmonate, acetic acid second
Ester, Cineole and citronellol are after mixing to get lemon extract；
The above-mentioned raw material citrus scented solution prepared used in lemon extract prepares raw material used, by mass percentage
It calculates, composition and content are as follows：
Above-mentioned citrus scented solution is prepared by a method comprising the following steps：
Raw material used is prepared by above-mentioned citrus scented solution, successively by grapefruit essential oil, limette essential oil, lemon
The ethanol water for being 70% with concentration of volume percent, which is added in separatory funnel, rocks mixing, and the leakage of distilled water jog is then added
Bucket makes each raw material be uniformly mixed, and 48h layerings is stood under the conditions of 4-5 DEG C, the clear solution obtained by lower layer is that citrus scented is molten
Liquid.
A kind of above-mentioned lemon flavor solid shoes are prepared with the method for fragrant tablet as follows：
Fragrant tablet is used to prepare by lemon flavor solid shoes raw materials used, first by microcrystalline cellulose, cornstarch, nanometer two
Silica hollow ball, lemon extract and magnesium stearate are sufficiently mixed uniformly, obtain mixture, and then the mixture of gained is added
It is tabletted to get fragrant to lemon flavor solid shoes with the pressure of 15kN into the mould for tabletting press of a diameter of 12mm
Tablet.
Using sensory evaluation method (Xiao Z, Zhang Y, Zhu G, et al.Preparation and
sustained-releasing characterization of aromatic wallpaper[J].Progress in
Organic Coatings,2017,104:When 50-57.) to the lasting of the fragrant tablet of the lemon flavor solid shoes of above-mentioned gained
Between be measured, the results showed that prepared solid shoes with fragrant tablet fragrance remaining time up to July as long as, and with stable
Pure and fresh citris aromas.
Embodiment 3
A kind of fragrant tablet of lemon flavor solid shoes, is calculated by mass percentage, the raw material used in preparation process
Composition and content are as follows：
The average grain diameter for the nano-silicon dioxide hollow sphere method as follows of 200-500nm prepares and
At：
The raw material used in nano-silicon dioxide hollow sphere is prepared, in parts by weight, raw material composition and content are as follows：
Preparation process is as follows：
0.7g trimethyl phenyl silane and 96.7g water are added in the single necked round bottom flask of 250ml and mixed, 60
Control rotating speed is that 300r/min stirs 1h in DEG C water-bath, and 2.0g ethyl orthosilicates and 0.6g concentrated ammonia liquors, 60 DEG C of water-baths are then added
Under the conditions of continue control rotating speed be 300r/min be stirred to react 3h, the reaction solution of gained is dried controlled at 70 DEG C, i.e.,
Obtain the nano-silicon dioxide hollow sphere that average grain diameter is 200-500nm；
The lemon extract, is calculated by mass percentage, and raw material composition and content are as follows：
Above-mentioned lemon extract is prepared by a method comprising the following steps：
Raw material used, which is prepared, by above-mentioned lemon extract sequentially adds concentration of volume percent in citrus scented solution
For 1% cucumber aldehyde ethanol solution, concentration of volume percent be 1% cis- 6- nonenyl aldehydes ethanol solution, concentration of volume percent
For 1% hexanal ethanol solution, concentration of volume percent be 1% capraldehyde ethanol solution, dihydrojasmonate, acetic acid second
Ester, Cineole and citronellol are after mixing to get lemon extract；
The above-mentioned raw material citrus scented solution prepared used in lemon extract prepares raw material used, by mass percentage
It calculates, composition and content are as follows：
Above-mentioned citrus scented solution is prepared by a method comprising the following steps：
Raw material used is prepared by above-mentioned citrus scented solution, successively by grapefruit essential oil, limette essential oil, lemon
The ethanol water for being 70% with concentration of volume percent, which is added in separatory funnel, rocks mixing, and the leakage of distilled water jog is then added
Bucket makes each raw material be uniformly mixed, and 36h layerings is stood under the conditions of 4-5 DEG C, the clear solution obtained by lower layer is that citrus scented is molten
Liquid.
A kind of above-mentioned lemon flavor solid shoes preparation method of fragrant tablet, is as follows：
Fragrant tablet is used to prepare by lemon flavor solid shoes raw materials used, first by microcrystalline cellulose, cornstarch, nanometer two
Silica hollow ball, lemon extract and magnesium stearate are sufficiently mixed uniformly, obtain mixture, and then the mixture of gained is added
It is tabletted to get fragrant to lemon flavor solid shoes with the pressure of 12kN into the mould for tabletting press of a diameter of 12mm
Tablet.
Using sensory evaluation method (Xiao Z, Zhang Y, Zhu G, et al.Preparation and
sustained-releasing characterization of aromatic wallpaper[J].Progress in
Organic Coatings,2017,104:When 50-57.) to the lasting of the fragrant tablet of the lemon flavor solid shoes of above-mentioned gained
Between be measured, the results showed that prepared solid shoes with fragrant tablet fragrance remaining time up to June as long as, and with stable
Pure and fresh citris aromas.
Embodiment 4
A kind of fragrant tablet of lemon flavor solid shoes, is calculated by mass percentage, the raw material used in preparation process
Composition and content are as follows：
The average grain diameter for the nano-silicon dioxide hollow sphere method as follows of 200-500nm prepares and
At：
The raw material used in nano-silicon dioxide hollow sphere is prepared, in parts by weight, raw material composition and content are as follows：
Preparation process is as follows：
0.8g trimethyl phenyl silane and 96.4g water are added in the single necked round bottom flask of 250ml and mixed, 60
Control rotating speed is that 300r/min stirs 1h in DEG C water-bath, and 2.0g ethyl orthosilicates and 0.8g concentrated ammonia liquors, 60 DEG C of water-baths are then added
Under the conditions of continue control rotating speed be 300r/min be stirred to react 3h, the reaction solution of gained is dried controlled at 80 DEG C, i.e.,
Obtain the nano-silicon dioxide hollow sphere that average grain diameter is 200-500nm；
The lemon extract, is calculated by mass percentage, and raw material composition and content are as follows：
Above-mentioned lemon extract is prepared by a method comprising the following steps：
Raw material used, which is prepared, by above-mentioned lemon extract sequentially adds concentration of volume percent in citrus scented solution
For 1% cucumber aldehyde ethanol solution, concentration of volume percent be 1% cis- 6- nonenyl aldehydes ethanol solution, concentration of volume percent
For 1% hexanal ethanol solution, concentration of volume percent be 1% capraldehyde ethanol solution, dihydrojasmonate, acetic acid second
Ester, Cineole and citronellol are after mixing to get lemon extract；
The above-mentioned raw material citrus scented solution prepared used in lemon extract prepares raw material used, by mass percentage
It calculates, composition and content are as follows：
Above-mentioned citrus scented solution is prepared by a method comprising the following steps：
Raw material used is prepared by above-mentioned citrus scented solution, successively by grapefruit essential oil, limette essential oil, lemon
The ethanol water for being 70% with concentration of volume percent, which is added in separatory funnel, rocks mixing, and the leakage of distilled water jog is then added
Bucket makes each raw material be uniformly mixed, and 32h layerings is stood under the conditions of 4-5 DEG C, the clear solution obtained by lower layer is that citrus scented is molten
Liquid.
A kind of above-mentioned lemon flavor solid shoes preparation method of fragrant tablet, is as follows：
Fragrant tablet is used to prepare by lemon flavor solid shoes raw materials used, first by microcrystalline cellulose, cornstarch, nanometer two
Silica hollow ball, lemon extract and magnesium stearate are sufficiently mixed uniformly, obtain mixture, and then the mixture of gained is added
It is tabletted to get fragrant to lemon flavor solid shoes with the pressure of 13kN into the mould for tabletting press of a diameter of 12mm
Tablet.
Using sensory evaluation method (Xiao Z, Zhang Y, Zhu G, et al.Preparation and
sustained-releasing characterization of aromatic wallpaper[J].Progress in
Organic Coatings,2017,104:When 50-57.) to the lasting of the fragrant tablet of the lemon flavor solid shoes of above-mentioned gained
Between be measured, the results showed that prepared solid shoes with fragrant tablet fragrance remaining time up to June as long as, and with stable
Pure and fresh citris aromas.
Embodiment 5
A kind of fragrant tablet of lemon flavor solid shoes, is calculated by mass percentage, the raw material used in preparation process
Composition and content are as follows：
The average grain diameter for the nano-silicon dioxide hollow sphere method as follows of 200-500nm prepares and
At：
The raw material used in nano-silicon dioxide hollow sphere is prepared, in parts by weight, raw material composition and content are as follows：
Preparation process is as follows：
0.8g trimethyl phenyl silane and 96.2g water are added in the single necked round bottom flask of 250ml and mixed, 60
Control rotating speed is that 300r/min stirs 1h in DEG C water-bath, and 2.1g ethyl orthosilicates and 0.9g concentrated ammonia liquors, 60 DEG C of water-baths are then added
Under the conditions of continue control rotating speed be 300r/min be stirred to react 3h, the reaction solution of gained is dried controlled at 75 DEG C, i.e.,
Obtain the nano-silicon dioxide hollow sphere that average grain diameter is 200-500nm；
The lemon extract, is calculated by mass percentage, and raw material composition and content are as follows：
Above-mentioned lemon extract is prepared by a method comprising the following steps：
Raw material used, which is prepared, by above-mentioned lemon extract sequentially adds concentration of volume percent in citrus scented solution
For 1% cucumber aldehyde ethanol solution, concentration of volume percent be 1% cis- 6- nonenyl aldehydes ethanol solution, concentration of volume percent
For 1% hexanal ethanol solution, concentration of volume percent be 1% capraldehyde ethanol solution, dihydrojasmonate, acetic acid second
Ester, Cineole and citronellol are after mixing to get lemon extract；
The above-mentioned raw material citrus scented solution prepared used in lemon extract prepares raw material used, by mass percentage
It calculates, composition and content are as follows：
Above-mentioned citrus scented solution is prepared by a method comprising the following steps：
Raw material used is prepared by above-mentioned citrus scented solution, successively by grapefruit essential oil, limette essential oil, lemon
The ethanol water for being 70% with concentration of volume percent, which is added in separatory funnel, rocks mixing, and the leakage of distilled water jog is then added
Bucket makes each raw material be uniformly mixed, and 42h layerings is stood under the conditions of 4-5 DEG C, the clear solution obtained by lower layer is that citrus scented is molten
Liquid.
A kind of above-mentioned lemon flavor solid shoes preparation method of fragrant tablet, is as follows：
Fragrant tablet is used to prepare by lemon flavor solid shoes raw materials used, first by microcrystalline cellulose, cornstarch, nanometer two
Silica hollow ball, lemon extract and magnesium stearate are sufficiently mixed uniformly, obtain mixture, and then the mixture of gained is added
It is tabletted to get fragrant to lemon flavor solid shoes with the pressure of 10kN into the mould for tabletting press of a diameter of 12mm
Tablet.
Using sensory evaluation method (Xiao Z, Zhang Y, Zhu G, et al.Preparation and
sustained-releasing characterization of aromatic wallpaper[J].Progress in
Organic Coatings,2017,104:When 50-57.) to the lasting of the fragrant tablet of the lemon flavor solid shoes of above-mentioned gained
Between be measured, the results showed that prepared solid shoes with fragrant tablet fragrance remaining time up to June as long as, and with stable
Pure and fresh citris aromas.
In conclusion a kind of fragrant tablet of lemon flavor solid shoes of the present invention, is used for the heel position of leather shoes, can cover
The bad smell of lid leather shoes product assigns leather shoes fresh and clean citris aromas, and further, a kind of lemon flavor of the invention is solid
The fragrant tablet of body shoes, largely inhales lemon extract due to the use of the higher nano-silicon dioxide hollow sphere of specific surface area
It is attached, lemon extract utilization rate and stability can be effectively improved, the loss of effective fragrance component in product preparation process is avoided.Through
Sensory evaluation measures the shoes solid aromatic tablet fragrance remaining time up to or so June, has that lasting is lasting, fragrance is stable and prepares
The advantages that simple for process.
Above said content is only the basic explanation under present inventive concept, and is appointed made by technical solution according to the present invention
What equivalent transformation, is within the scope of protection of the invention.
Claims (10)
1. a kind of fragrant tablet of lemon flavor solid shoes, it is characterised in that the lemon flavor solid shoes are pressed with fragrant tablet
Mass percent calculates, and the composition and content of the raw material used in preparation process are as follows：
Microcrystalline cellulose 43%-50%
Cornstarch 25%-30%
Nano-silicon dioxide hollow sphere 6%-8%
Lemon extract 8%-10%
Magnesium stearate 2%-18%；
The average grain diameter of the nano-silicon dioxide hollow sphere is 200-500nm；
The lemon extract, is calculated by mass percentage, and prepares raw material composition used and content is as follows：
Citrus scented solution 78.82%-81.08%
The cucumber aldehyde ethanol solution 2.59%-3.05% that concentration of volume percent is 1%
The cis- 6- nonenyl aldehydes ethanol solution 1.62%-1.75% that concentration of volume percent is 1%
The hexanal ethanol solution 1.57%-2.05% that concentration of volume percent is 1%
The capraldehyde ethanol solution 4.45%-5.44% that concentration of volume percent is 1%
Dihydrojasmonate 6.95%-7.03%
Ethyl acetate 0.60%-0.66%
Cineole 0.11%-0.14%
Citronellol 1.03%-1.06%；
Above-mentioned lemon extract preparation process is as follows：
The mass percent that raw material used is prepared by above-mentioned lemon extract calculates, and volume is sequentially added in citrus scented solution
Cis- 6- nonenyl aldehydes ethanol solution that cucumber aldehyde ethanol solution that percent concentration is 1%, concentration of volume percent are 1%, volume hundred
Capraldehyde ethanol solution that hexanal ethanol solution that point specific concentration is 1%, concentration of volume percent are 1%, dihydrojasmonate,
Ethyl acetate, Cineole and citronellol are after mixing to get lemon extract；
Above-mentioned citrus scented solution used prepares raw material used, is calculated by mass percentage, and raw material composition and content are such as
Under：
Grapefruit essential oil 4.87%-5.15%
Limette essential oil 6.50%-7.35%
Lemon 4.87%-5.32%
The ethanol water 62.79%-67.20% that concentration of volume percent is 70%
Distilled water 16.56%-19.39%；
Above-mentioned citrus scented solution preparation process is as follows：
The mass percent that raw material used is prepared by above-mentioned citrus scented solution calculates, successively by grapefruit essential oil, limette
Essential oil, lemon, the ethanol water that concentration of volume percent is 70%, which is added in separatory funnel, rocks mixing, is then added
Distilled water jog funnel makes each raw material be uniformly mixed, and 24-48h layerings are stood under the conditions of 4-5 DEG C, and the clarification obtained by lower layer is molten
Liquid is citrus scented solution.
2. a kind of fragrant tablet of lemon flavor solid shoes as described in claim 1, it is characterised in that the nano-silica
SiClx hollow ball prepares raw material used, and in parts by weight, raw material composition and content are as follows：
0.6-1.0 parts of trimethyl phenyl silane
95.8-97.1 parts of water
1.8-2.2 parts of ethyl orthosilicate
0.5-1.0 parts of concentrated ammonia liquor
Nano-silicon dioxide hollow sphere preparation process is as follows：
Trimethyl phenyl silane and water are mixed, it is that 300r/min stirs 1h that rotating speed is controlled in 60 DEG C of water-baths, is then added
Enter ethyl orthosilicate and concentrated ammonia liquor, continue to control rotating speed under 60 DEG C of water bath conditions to be that 300r/min is stirred to react 3h, gained it is anti-
Liquid is answered to be dried to get the nano-silicon dioxide hollow sphere to average grain diameter for 200-500nm controlled at 60-90 DEG C.
3. a kind of fragrant tablet of lemon flavor solid shoes as claimed in claim 2, it is characterised in that the lemon flavor
Solid shoes are calculated by mass percentage with fragrant tablet, and the composition and content of the raw material used in preparation process are as follows：
Microcrystalline cellulose 43%
Cornstarch 25%
Nano-silicon dioxide hollow sphere 6%
Lemon extract 8%
Magnesium stearate 18%；
The nano-silicon dioxide hollow sphere prepares raw material used, and in parts by weight, raw material composition and content are as follows：
0.6 part of trimethyl phenyl silane
97.1 parts of water
1.8 parts of ethyl orthosilicate
0.5 part of concentrated ammonia liquor
It prepares raw material used to the lemon extract, is calculated by mass percentage, and composition and content are as follows：
Citrus scented solution 81.08%
The cucumber aldehyde ethanol solution 2.59% that concentration of volume percent is 1%
The cis- 6- nonenyl aldehydes ethanol solution 1.62% that concentration of volume percent is 1%
The hexanal ethanol solution 1.57% that concentration of volume percent is 1%
The capraldehyde ethanol solution 4.45% that concentration of volume percent is 1%
Dihydrojasmonate 6.95%
Ethyl acetate 0.60%
Cineole 0.11%
Citronellol 1.03%；
Above-mentioned citrus scented solution used prepares raw material used, is calculated by mass percentage, and composition and content are as follows：
Grapefruit essential oil 4.87%
Limette essential oil 6.50%
Lemon 4.87%
The ethanol water 67.20% that concentration of volume percent is 70%
Distilled water 16.56%.
4. a kind of fragrant tablet of lemon flavor solid shoes as claimed in claim 2, it is characterised in that the lemon flavor
Solid shoes are calculated by mass percentage with fragrant tablet, and the composition and content of the raw material used in preparation process are as follows：
Microcrystalline cellulose 50%
Cornstarch 30%
Nano-silicon dioxide hollow sphere 8%
Lemon extract 10%
Magnesium stearate 2%；
The nano-silicon dioxide hollow sphere prepares raw material used, and in parts by weight, raw material composition and content are as follows：
1.0 parts of trimethyl phenyl silane
95.8 parts of water
2.2 parts of ethyl orthosilicate
1.0 parts of concentrated ammonia liquor
It prepares raw material used to the lemon extract, is calculated by mass percentage, and composition and content are as follows：
Citrus scented solution 78.82%
The cucumber aldehyde ethanol solution 3.05% that concentration of volume percent is 1%
The cis- 6- nonenyl aldehydes ethanol solution 1.75% that concentration of volume percent is 1%
The hexanal ethanol solution 2.05% that concentration of volume percent is 1%
The capraldehyde ethanol solution 5.44% that concentration of volume percent is 1%
Dihydrojasmonate 7.03%
Ethyl acetate 0.66%
Cineole 0.14%
Citronellol 1.06%；
Above-mentioned citrus scented solution used prepares raw material used, is calculated by mass percentage, and composition and content are as follows：
Grapefruit essential oil 5.15%
Limette essential oil 7.35%
Lemon 5.32%
The ethanol water 62.79% that concentration of volume percent is 70%
Distilled water 19.39%.
5. a kind of fragrant tablet of lemon flavor solid shoes as claimed in claim 2, it is characterised in that the lemon flavor
Solid shoes are calculated by mass percentage with fragrant tablet, and the composition and content of the raw material used in preparation process are as follows：
Microcrystalline cellulose 45%
Cornstarch 27%
Nano-silicon dioxide hollow sphere 7%
Lemon extract 9%
Magnesium stearate 12%；
The nano-silicon dioxide hollow sphere prepares raw material used, and in parts by weight, raw material composition and content are as follows：
0.7 part of trimethyl phenyl silane
96.78 parts of water
2.0 parts of ethyl orthosilicate
0.6 part of concentrated ammonia liquor
It prepares raw material used to the lemon extract, is calculated by mass percentage, and composition and content are as follows：
Citrus scented solution 80.36%
The cucumber aldehyde ethanol solution 2.66% that concentration of volume percent is 1%
The cis- 6- nonenyl aldehydes ethanol solution 1.77% that concentration of volume percent is 1%
The hexanal ethanol solution 1.85% that concentration of volume percent is 1%
The capraldehyde ethanol solution 4.62% that concentration of volume percent is 1%
Dihydrojasmonate 696%
Ethyl acetate 0.64%
Cineole 0.11%
Citronellol 1.03%；
Above-mentioned citrus scented solution used prepares raw material used, is calculated by mass percentage, and composition and content are as follows：
Grapefruit essential oil 4.965%
Limette essential oil 6.53%
Lemon 5.03%
The ethanol water 64.09% that concentration of volume percent is 70%
Distilled water 19.39%.
6. a kind of fragrant tablet of lemon flavor solid shoes as claimed in claim 2, it is characterised in that the lemon flavor
Solid shoes are calculated by mass percentage with fragrant tablet, and the composition and content of the raw material used in preparation process are as follows：
Microcrystalline cellulose 49%
Cornstarch 26%
Nano-silicon dioxide hollow sphere 7%
Lemon extract 10%
Magnesium stearate 8%；
The nano-silicon dioxide hollow sphere prepares raw material used, and in parts by weight, raw material composition and content are as follows：
0.8 part of trimethyl phenyl silane
96.4 parts of water
2.0 parts of ethyl orthosilicate
0.8 part of concentrated ammonia liquor
It prepares raw material used to the lemon extract, is calculated by mass percentage, and composition and content are as follows：
Citrus scented solution 80.87%
The cucumber aldehyde ethanol solution 2.65% that concentration of volume percent is 1%
The cis- 6- nonenyl aldehydes ethanol solution 1.63% that concentration of volume percent is 1%
The hexanal ethanol solution 1.61% that concentration of volume percent is 1%
The capraldehyde ethanol solution 4.45% that concentration of volume percent is 1%
Dihydrojasmonate 6.99%
Ethyl acetate 0.63%
Cineole 0.11%
Citronellol 1.06%；
Above-mentioned citrus scented solution used prepares raw material used, is calculated by mass percentage, and composition and content are as follows：
Grapefruit essential oil 5.02%
Limette essential oil 7.00%
Lemon 5.01%
The ethanol water 63.67% that concentration of volume percent is 70%
Distilled water 19.30%.
7. a kind of fragrant tablet of lemon flavor solid shoes as claimed in claim 2, it is characterised in that the lemon flavor
Solid shoes are calculated by mass percentage with fragrant tablet, and the composition and content of the raw material used in preparation process are as follows：
Microcrystalline cellulose 47%
Cornstarch 28%
Nano-silicon dioxide hollow sphere 7%
Lemon extract 9%
Magnesium stearate 9%；
The nano-silicon dioxide hollow sphere prepares raw material used, and in parts by weight, raw material composition and content are as follows：
0.8 part of trimethyl phenyl silane
96.2 parts of water
2.1 parts of ethyl orthosilicate
0.9 part of concentrated ammonia liquor
It prepares raw material used to the lemon extract, is calculated by mass percentage, and composition and content are as follows：
Citrus scented solution 80.70%
The cucumber aldehyde ethanol solution 2.74% that concentration of volume percent is 1%
The cis- 6- nonenyl aldehydes ethanol solution 1.69% that concentration of volume percent is 1%
The hexanal ethanol solution 1.60% that concentration of volume percent is 1%
The capraldehyde ethanol solution 4.49% that concentration of volume percent is 1%
Dihydrojasmonate 6.96%
Ethyl acetate 0.64%
Cineole 0.13%
Citronellol 1.05%；
Above-mentioned citrus scented solution used prepares raw material used, is calculated by mass percentage, and composition and content are as follows：
Grapefruit essential oil 4.95%
Limette essential oil 7.30%
Lemon 4.88%
The ethanol water 64.35% that concentration of volume percent is 70%
Distilled water 18.52%.
8. the fragrant tablet of lemon flavor solid shoes as described in claim 1-7 any claims, it is characterised in that described
Microcrystalline cellulose, analysis it is pure, Sinopharm Chemical Reagent Co., Ltd. production；
The cornstarch, SILVER REAGENT, the production of Shanghai Jing Chun biochemical technologies limited liability company；
The magnesium stearate, analysis is pure, Sinopharm Chemical Reagent Co., Ltd.'s production.
9. the preparation method of the fragrant tablet of lemon flavor solid shoes as described in claim 1-7 any claims, special
Sign is that steps are as follows：
By lemon odor type solid shoes with fragrant tablet prepare it is raw materials used be calculated by mass percentage, crystallite, corn are formed sediment first
Powder, nano-silicon dioxide hollow sphere, lemon extract and magnesium stearate are sufficiently mixed uniformly, obtain mixture, then by gained
Mixture, which is added in mould for tabletting press, is made tablet to get to the fragrant tablet of lemon flavor solid shoes.
10. the lemon flavor solid shoes preparation method of fragrant tablet as described in claim 1-7 any claims, is
The a diameter of 12mm of the mould for tabletting press, control pressure is 10-15kN in tabletted process.
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