CN108720170A - A kind of cool insole - Google Patents
A kind of cool insole Download PDFInfo
- Publication number
- CN108720170A CN108720170A CN201810401282.4A CN201810401282A CN108720170A CN 108720170 A CN108720170 A CN 108720170A CN 201810401282 A CN201810401282 A CN 201810401282A CN 108720170 A CN108720170 A CN 108720170A
- Authority
- CN
- China
- Prior art keywords
- layer
- polyurethane
- insole
- parts
- foot
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
- A43B17/003—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined characterised by the material
- A43B17/006—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined characterised by the material multilayered
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
- A43B17/02—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined wedge-like or resilient
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
- A43B17/10—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined specially adapted for sweaty feet; waterproof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3206—Polyhydroxy compounds aliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3228—Polyamines acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
- C08G18/6685—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3225 or polyamines of C08G18/38
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/302—Conductive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/56—Damping, energy absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2437/00—Clothing
- B32B2437/02—Gloves, shoes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2410/00—Soles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/08—Polyurethanes from polyethers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a kind of cool insoles, are related to insole technical field.The present invention includes insole body, the insole body includes nanometer bamboo carbon fiber layer and the first layer of polyurethane, memory foam sponge layer, the second layer of polyurethane successively from top to bottom, position on the downside of the front end of second layer of polyurethane corresponding to vola before human body is provided with the first cushioning piece, the position for corresponding to human body heel portion on the downside of the rear end of second layer of polyurethane is provided with the second cushioning piece, and the downside of second layer of polyurethane corresponds to the flexible shield foot of position setting of human body arch portion.The present invention can allow wearer's dress comfortable, can cater to foot protruding parts and be deformed, can be restored automatically after deformation, and damping, shield foot effect are strong, carry the cool function of foot, good permeability.
Description
Technical field
The present invention relates to a kind of insole, more particularly to a kind of cool insole.
Background technology
Foot is the second heart of human body, as the improvement of people's living standards, more and more people pay attention to the shield of foot
Reason, the nursing of foot can have the benefit of body：Improve sleep；Face-beautifying health-care supports brain and protects brain；It promotes blood circulation；Promote
Human metabolism.
Foot in addition to need to pay attention to it is warming other than, it is also necessary to timely cool down to it, keep foot cool, foot temperature mistake
Height, double-legged blood vessel are easy overdistension, and blood more flows to lower limb in human body, easily cause the important device such as the heart, brain, kidney
Official's blood supply insufficiency is tantamount to make the matter worse especially for the friend with cardiovascular and cerebrovascular disease；On the other hand, foot temperature
It is excessively high, it is easily destroyed the sebum film on pedal skin surface, cuticula drying is made even to chap.
Insole be apply very universal articles for daily use, by effect point, insole can be divided into health insoles, functional insole and often
Advise insole.It easily perspires crowd for foot, the health care of foot needs to realize by insole, and the structure of traditional sock is laminates
Material sewing is suppressed into either multilayer leather, with certain pliability and shock absorbing effect, is substantially conformed to general
Logical people takes a walk, moves the demands of wear shoes usually, but for foot easily perspiration crowd, then has as a drawback that：One, biography
The upper layer of system insole and the nonhomogeneous hardness of vola skin are larger, and foot easily perspiration crowd can be enabled to feel that foot is uncomfortable；Secondly, pass
The material of main part of system insole is not easy to deform, or is also difficult to restore after deformation, easily aggravates the foot of foot easily perspiration crowd
The problems such as numbness, pain, thrombosis, blue, oedema of blacking；Thirdly, traditional sock damping, shield foot effect it is poor, foot is easy
Foot's half sole of perspiration crowd and followed by bottom be easier to be impacted, easily aggravate vola bone, ankle-joint and kneed disease
Sick problem；Five, traditional sock poor air permeability is easy to grow bacterium, fungi, easily aggravates pedal edema, and interdigit is rotten to the corn to ask
Topic；Six, traditional sock causes the foot of foot easily perspiration crowd that cannot timely carry out cooling and causes not without cooling function
It is suitable.
Invention content
The technical problem to be solved by the present invention is in view of the above shortcomings of the prior art, provide a kind of cool insole,
The insole can allow wearer's dress comfortable, can cater to foot protruding parts and be deformed, can be restored automatically after deformation, damping,
Shield foot effect is strong, carries the cool function of foot, good permeability.
In order to solve the above technical problems, the technical scheme is that：A kind of cool insole, including insole body,
It is characterized in that：The insole body includes that nanometer bamboo carbon fiber layer and the first layer of polyurethane, memory bubble are continuous successively from top to bottom
The front end downside of layer, the second layer of polyurethane, second layer of polyurethane is provided with first corresponding to the position of vola before human body
The rear end downside of cushioning piece, second layer of polyurethane is provided with the second beam corresponding to the position of human body heel portion
The downside of piece, second layer of polyurethane corresponds to the flexible shield foot of position setting of human body arch portion；The first poly- ammonia
The front end of corresponding insole body is equipped with two S type grooves for exhaust on the upside of ester layer, and one end of the S types groove extends to shoes
The left end of pad body, the other ends of the S type grooves extend to the right end of insole body, and the memory foam sponge layer corresponds to the up and down
The position of two S type grooves of one layer of polyurethane also is provided with two S type grooves；It is arranged with 120 on the upside of second layer of polyurethane
The convex grain of~160 upper flats.
It is expanded on further as to the present invention：
Preferably, the shape of first cushioning piece is in tongue type, and the shape of second cushioning piece is rounded, the elasticity
The shape for protecting foot is in half-moon-shaped, and the elasticity shield foot wraps up entire human body arch portion, is arranged on the upside of second layer of polyurethane
Show the convex grain of 130~150 upper flats.
Preferably, the thickness of the nanometer bamboo carbon fiber layer is 0.4~1.2 mm, and the thickness of first layer of polyurethane is
3.0~8.0mm, the thickness of the memory foam sponge layer are 2.95~8.55mm, the thickness of second layer of polyurethane is 3.5~
The thickness of 9.5mm, first cushioning piece are 3.8~6.0mm, and the thickness of second cushioning piece is 3.5~6.0mm,
The thickness of the elasticity shield foot is 3.5~6.5mm.
Preferably, include waist and insole heel in insole half sole, insole successively from the front end of insole body to rear end,
In, waist and insole heel are both provided with the outer rim up tilted in the insole, and the tilting height of the insole heel is less than shoes
The tilting height of waist both sides in pad.
Preferably, first layer of polyurethane is cooling layer of polyurethane, made of the following raw material reaction foaming：Polyethers is more
100 parts of first alcohol, 5~15 parts of methyl diphenylene diisocyanate, 5-10 parts of isophorone diisocyanate, 12~13 parts of water, silicon
0.5~3 part of oil, 0.2~1 part of catalyst, 0.5~1 part of foaming agent, 2~5 parts of crosslinking agent, 3~5 parts of freshener, stabilizer 0.2
~1.3 parts；
The preparation method of first layer of polyurethane is：By the polyether polyol of corresponding parts by weight, two isocyanide of diphenyl methane
Acid esters, isophorone diisocyanate are added in mixer and stir evenly, and 35~38 degrees Celsius are heated to, by corresponding number
Other raw materials be added in mixer, high-speed stirred is poured into after 6~8 seconds after mold foams and cure, and obtains corresponding
One layer of polyurethane.
Preferably, the hydroxyl value of the polyether polyol is 50~90 mgKOH/g, and molecular weight is 8000~10000, described
Silicone oil is BF-2370 and two kinds of mass ratioes of B-4900 are 3：1 mixture；The catalyst is N, N- dimethylaminoethyls-N-
Methyl amino ethanol and acetylacetone,2,4-pentanedione zirconium mass ratio are 0.5：1 mixture；The foaming agent is normal heptane；Crosslinking agent is second two
Amine, triethylene glycol and dipropyl（Support）Three kinds of mixtures of glycol；The freshener is that menthol, 3- hydroxybutyric acids menthyl ester, lactic acid are thin
Lotus ester, glutaric acid menthyl ester, 3-L- menthoxypropane -1,2- glycol, menthyl acetate, isopulegol, peppermint oxygroup -2-
Methyl-1,2- propylene glycol, menthol diglycol carbonate ester admixture carry out powdered with low-temperature airflow contact under spray pattern and
At；The stabilizer is cyclodextrin, methylcellulose, pectin, gelatin hydrolysied matter, carrageenan, gellan gum, furcellaran, sea
Mixture made of the components such as alginic acid, enzymolysis lecithin, casein, xanthans.
Preferably, the memory foam sponge layer is made of the following raw material reaction foaming：100 parts of polyether polyol, six methylenes
5~10 parts of group diisocyanate, 5~15 parts of methyl diphenylene diisocyanate, 5-10 parts of isophorone diisocyanate, water 12
~13 parts, 0.5~3 part of silicone oil, 0.2~1 part of stannous octoate, 0.5~1 part of foaming agent, 2~5 parts of crosslinking agent；
It is described memory foam sponge layer preparation method be：By the polyether polyol of corresponding parts by weight, diphenylmethane diisocyanate
Ester, isophorone diisocyanate are added in mixer and stir evenly, and 35~38 degrees Celsius are heated to, by corresponding number
Other raw materials are added in mixer, and high-speed stirred is poured into after 6~8 seconds after mold foams and cure, and is remembered accordingly
Foam sponge layer；
The hydroxyl value of the polyether polyol is 55~85 mgKOH/g, and molecular weight is 8000~9000, and the silicone oil is BF-2370
It is 1.5 with two kinds of mass ratioes of B-4900：1 mixture；The catalyst is stannous octoate；The foaming agent is trichlorine fluorine first
Alkane；Crosslinking agent is ethylenediamine, triethylene glycol and dipropyl（Support）Three kinds of mixtures of glycol.
Preferably, second layer of polyurethane is made of the following raw material reaction foaming：100 parts of polyether polyol, folium artemisiae argyi
5~8 parts of 7~13 parts of fiber powder, 2~3.5 parts of silane coupling agent and isophorone diisocyanate, 12~13 parts of water, silicone oil 0.5
~3 parts, 0.2~1 part of catalyst, 0.5~1 part of foaming agent, 2~5 parts of crosslinking agent；
The preparation method of second layer of polyurethane is：The polyether polyol of corresponding parts by weight, folium artemisiae argyi fiber powder, silane is even
Connection agent and isophorone diisocyanate, which are added in mixer, to stir evenly, and 35~38 degrees Celsius is heated to, by corresponding part
Several other raw materials are added in mixer, and high-speed stirred is poured into after 6~8 seconds after mold foams and cure, and is obtained corresponding
Second layer of polyurethane；
The hydroxyl value of the polyether polyol is 50~90 mgKOH/g, and molecular weight is 8000~10000, and the silicone oil is BF-
2370 and B-4900, two kinds of mass ratioes are 6：1 mixture；The catalyst is N, N- dimethylaminoethyl-N- methylamino second
Alcohol and acetylacetone,2,4-pentanedione zirconium mass ratio are 0.1-1：1 mixture；The foaming agent is sodium sulfate of polyethenoxy ether of fatty alcohol.
Preferably, the preparation method of the elasticity shield foot is：
（1）Prepare zein fiber yarn；
（2）Peppermint grass essential oil micro-capsule is prepared with complex coacervation；
（3）Make peppermint grass essential oil sustained release-soybean fiber；
（4）Woven fabric：
Using step（1）Zein fiber yarn obtained makees warp, step（3）Peppermint grass essential oil sustained release-soybean protein obtained
Fiber makees weft, and fabric is formed using conventional woven fabric method woven fabric；（4）Surface applies warming dose, and elasticity shield foot is made.
The beneficial effects of the invention are as follows：One, due to insole body upper layer be nanometer bamboo carbon fiber layer and vola skin
Nonhomogeneous hardness it is smaller, foot easily perspiration crowd can be enabled to feel that foot is very comfortable；Secondly, dividing into due to nanometer bamboo carbon fiber layer
Memory foam sponge layer is set, foot protruding parts can be catered to and deformed, can be restored automatically after deformation, realizes and easily perspires people to foot
The foot health-care of group；Thirdly, elasticity shield foot is equipped with due to the medial end portions of the second layer of polyurethane, can arch upward in the middle part of insole body,
It is bonded the arch portion of wearer, plays the role of pressing arch of foot acupuncture point, promotes blood circulation；Four, due to the second polyurethane
Position on the downside of the front end of layer corresponding to vola before human body is provided with the first cushioning piece, and human body foot is corresponded on the downside of rear end
The position of heel is provided with the second cushioning piece, and flexible shield foot is arranged in the position that downside corresponds on the inside of human body arch portion,
Therefore, insole elasticity is good, can effectively absorb the foot bones impact force of foot easily perspiration crowd, protection vola bone, ankle-joint
And knee joint, there is outstanding damping shield foot effect；Five, nanometer bamboo carbon fiber layer has that moisture absorption is ventilative, bacteriostasis antibiosis, green
The feature of environmental protection, also, the first cushioning piece, the second cushioning piece and elasticity shield foot are respectively provided with outstanding air permeability effect；
Six, elasticity shield foot manufacturing process in be added with folium artemisiae argyi fiber, while effective massaging feet, be avoided that grow bacterium,
Fungi etc.；Seventh, the first layer of polyurethane is cooling layer, the addition of freshener can make insole itself carry cooling function, prevent
The foot of foot easily perspiration crowd cannot timely carry out cooling and cause discomfort, improve the comfort of insole.
Description of the drawings
Fig. 1 is one of the dispersed structure schematic diagram of the present invention.
Fig. 2 is the two of the dispersed structure schematic diagram of the present invention.
In figure：1. nanometer bamboo carbon fiber layer；2. the first layer of polyurethane；3. remembering foam sponge layer；4. the second layer of polyurethane；5. the
One cushioning piece；6. the second cushioning piece；7. elasticity shield foot；8.S type grooves；9. convex grain.
Specific implementation mode
Xia Mianjiehefutuduibenfamingjiegouyuanlihegongzuoyuanlizuojinyibuxiangxishuoming.
As shown in Fig. 1~Fig. 2, the present invention is a kind of cool insole, including insole body, it is characterised in that：It is described
Insole body includes nanometer bamboo carbon fiber layer 1 and the first layer of polyurethane 2, memory foam sponge layer 3, the second polyurethane successively from top to bottom
The front end downside of layer 4, second layer of polyurethane 4 is provided with the first cushioning piece 5, institute corresponding to the position of vola before human body
It states and corresponds to the position of human body heel portion on the downside of the rear end of the second layer of polyurethane 4 and be provided with the second cushioning piece 6, described second
Flexible shield foot 7 is arranged in the position that the downside of layer of polyurethane 4 corresponds to human body arch portion；First layer of polyurethane, 2 upside
The front end of corresponding insole body is equipped with two S types grooves 8 for exhaust, and one end of the S types groove 8 extends to insole body
Left end, the other end of the S types groove 8 extends to the right end of insole body, and it is poly- that about the 3 memory foam sponge layer corresponds to first
The position of two S types grooves 8 of urethane layer 2 also is provided with two S types grooves 8；Second layer of polyurethane, 4 upside is arranged with 120
The convex grain 9 of~160 upper flats.Nanometer bamboo carbon fiber layer has moisture absorption ventilative, bacteriostasis antibiosis, cool in summer and warm in winter, environmentally protective
The characteristics of；Memory foam sponge layer can cater to foot protruding parts and be deformed, and can restore automatically after deformation, realize to wearer's
Foot health-care, the memory foam sponge layer is preferably polyetherurethane foam foam sponge layer.S types groove 8 designs, and can enhance this shoes
The exhaust of pad, heat sinking function.
As shown in Fig. 1~Fig. 2, the shape of first cushioning piece 5 is in tongue type, the shape of second cushioning piece 6
Rounded, for the shape of the elasticity shield foot 7 in half-moon-shaped, the elasticity shield foot 7 wraps up entire human body arch portion, and described the
Two layer of polyurethane, 4 upside is arranged with the convex grain 9 of 130~150 upper flats.The elasticity shield design of foot 7 further enhances shoes
The elasticity of pad and protection to wearer's arch portion.
As shown in Fig. 1~Fig. 2, the thickness of the nanometer bamboo carbon fiber layer 1 is 0.4~1.2 mm, first polyurethane
The thickness of layer 2 is 3.0~8.0mm, and the thickness of the memory foam sponge layer 3 is 2.95~8.55mm, second layer of polyurethane 4
Thickness is 3.5~9.5mm, and the thickness of first cushioning piece 5 is 3.8~6.0mm, the thickness of second cushioning piece 6
Thickness for 3.5~6.0mm, the elasticity shield foot 7 is 3.5~6.5mm.Preferably, the thickness of the nanometer bamboo carbon fiber layer 1
Degree is 0.45~1.1 mm, and the thickness of first layer of polyurethane 2 is 3.5~7.0mm, and the thickness of the memory foam sponge layer 3 is
The thickness of 3.05~8.05mm, second layer of polyurethane 4 are 3.8~9.0mm, and the thickness of first cushioning piece 5 is 3.8
The thickness of~5.5mm, second cushioning piece 6 are 4.0~5.5mm, and the thickness of the elasticity shield foot 7 is 3.8~6.3mm
Include successively insole half sole, in insole after waist and insole from the front end of insole body to rear end as shown in Fig. 1~Fig. 2
With, wherein waist and insole heel are both provided with the outer rim up tilted in the insole, and the tilting height of the insole heel is low
The tilting height of waist both sides in insole.
Embodiment 1：
First layer of polyurethane 2 prepares raw material and weighs：Polyether polyol 100kg, methyl diphenylene diisocyanate 5~
15kg, isophorone diisocyanate 5-10kg, 12~13kg of water, 0.5~3kg of silicone oil, 0.2~1kg of catalyst, foaming agent
0.5~1kg, 2~5kg of crosslinking agent, 3~5kg of freshener, 0.2~1.3kg of stabilizer；
The preparation method of first layer of polyurethane 2 is：By the polyether polyol of corresponding weight kg numbers, two isocyanide of diphenyl methane
Acid esters, isophorone diisocyanate are added in mixer and stir evenly, and 35~38 degrees Celsius are heated to, by corresponding kg numbers
Other raw materials be added in mixer, high-speed stirred is poured into after 6~8 seconds after mold foams and cure, and corresponding reality is obtained
Apply the first layer of polyurethane 2 of example 1.So that insole carries cool function, satisfaction easily goes out for the addition of freshener and stabilizer
The demand that sweat crowd cools down automatically to foot.
The hydroxyl value of the polyether polyol is 50~90 mgKOH/g, and molecular weight is 8000~10000, and the silicone oil is
Two kinds of mass ratioes of BF-2370 and B-4900 are 3：1 mixture；The catalyst is N, N- dimethylaminoethyl-N- methyl ammonia
Base ethyl alcohol and acetylacetone,2,4-pentanedione zirconium mass ratio are 0.5：1 mixture；The foaming agent is normal heptane；Crosslinking agent is ethylenediamine, three
Glycol and dipropyl（Support）Three kinds of mixtures of glycol；The freshener be menthol, 3- hydroxybutyric acids menthyl ester, menthyl lactate,
Glutaric acid menthyl ester, 3-L- menthoxypropane -1,2- glycol, menthyl acetate, isopulegol, peppermint oxygroup -2- methyl -
1,2-PD, menthol diglycol carbonate ester admixture carry out powdered with low-temperature airflow contact under spray pattern and form；Institute
State stabilizer be cyclodextrin, methylcellulose, pectin, gelatin hydrolysied matter, carrageenan, gellan gum, furcellaran, alginic acid,
Digest mixture made of the components such as lecithin, casein, xanthans.
3 raw material of memory foam sponge layer weighs as follows：Polyether polyol 100kg, hexamethylene diisocyanate 5~
10kg, 5~15kg of methyl diphenylene diisocyanate, isophorone diisocyanate 5-10kg, 12~13kg of water, silicone oil 0.5
~3kg, 0.2~1kg of stannous octoate, 0.5~1kg of foaming agent, 2~5kg of crosslinking agent；
It is described memory foam sponge layer 3 preparation method be：By the polyether polyol of corresponding parts by weight, diphenylmethane diisocyanate
Ester, isophorone diisocyanate are added in mixer and stir evenly, and 35~38 degrees Celsius are heated to, by corresponding number
Other raw materials are added in mixer, and high-speed stirred is poured into after 6~8 seconds after mold foams and cure, and is implemented accordingly
The memory foam sponge layer 3 of example 1；
The hydroxyl value of the polyether polyol is 55~85 mgKOH/g, and molecular weight is 8000~9000, and the silicone oil is BF-2370
It is 1.5 with two kinds of mass ratioes of B-4900：1 mixture；The catalyst is stannous octoate；The foaming agent is trichlorine fluorine first
Alkane；Crosslinking agent is ethylenediamine, triethylene glycol and dipropyl（Support）Three kinds of mixtures of glycol.
The raw material of second layer of polyurethane 4 is as follows：Polyether polyol 100kg, 7~13kg of folium artemisiae argyi fiber powder, silane are even
Connection 2~3.5kg of agent and 5~8kg of isophorone diisocyanate, 12~13kg of water, 0.5~3kg of silicone oil, catalyst 0.2~
1kg, 0.5~1kg of foaming agent, 2~5kg of crosslinking agent；
The preparation method of second layer of polyurethane 4 is：Polyether polyol 100kg, 7~13kg of folium artemisiae argyi fiber powder, silane is even
Connection 2~3.5kg of agent and 5~8kg of isophorone diisocyanate, which is added in mixer, to stir evenly, and is heated to 35~38 and takes the photograph
Other raw materials of corresponding number are added in mixer by family name's degree, and high-speed stirred pours into mold and foams and cure after 6~8 seconds
Afterwards, the second layer of polyurethane 4 of corresponding embodiment 1 is obtained；The addition of folium artemisiae argyi fiber powder can be obviously promoted foot bottom blood circulation,
Play the role of giving foot massage health care, deodorizing sterilizing effect more preferable.
The hydroxyl value of the polyether polyol is 50~90 mgKOH/g, and molecular weight is 8000~10000, and the silicone oil is
Two kinds of mass ratioes of BF-2370 and B-4900 are 6：1 mixture；The catalyst is N, N- dimethylaminoethyl-N- methyl ammonia
Base ethyl alcohol and acetylacetone,2,4-pentanedione zirconium mass ratio are 0.1-1：1 mixture；The foaming agent is sodium sulfate of polyethenoxy ether of fatty alcohol.
It is described elasticity shield foot 7 preparation method be：
（1）Prepare zein fiber yarn；
（2）Peppermint grass essential oil micro-capsule is prepared with complex coacervation；
（3）Make peppermint grass essential oil sustained release-soybean fiber；
（4）Woven fabric：
Using step（1）Zein fiber yarn obtained makees warp, step（3）Peppermint grass essential oil sustained release-soybean protein obtained
Fiber makees weft, and fabric is formed using conventional woven fabric method woven fabric；（4）Surface applies warming dose, and the elasticity of embodiment 1 is made
Protect foot 7.
The other structures component of insole is that current material is obtained by commonsense method.
Embodiment 2：
3 raw material of memory foam sponge layer weighs as follows：Polyether polyol 100kg, hexamethylene diisocyanate 5~10kg, two
5~15kg of methylenebis phenyl isocyanate, isophorone diisocyanate 5-10kg, 12~13kg of water, silicone oil 0.5~3kg are pungent
Sour 0.2~1kg of stannous, 0.5~1kg of foaming agent, 2~5kg of crosslinking agent；
It is described memory foam sponge layer 3 preparation method be：By the polyether polyol of corresponding parts by weight, diphenylmethane diisocyanate
Ester, isophorone diisocyanate are added in mixer and stir evenly, and 35~38 degrees Celsius are heated to, by corresponding number
Other raw materials are added in mixer, and high-speed stirred is poured into after 6~8 seconds after mold foams and cure, and is implemented accordingly
The memory foam sponge layer 3 of example 2；
The hydroxyl value of the polyether polyol is 55~85 mgKOH/g, and molecular weight is 8000~9000, and the silicone oil is BF-2370
It is 1.5 with two kinds of mass ratioes of B-4900：1 mixture；The catalyst is stannous octoate；The foaming agent is trichlorine fluorine first
Alkane；Crosslinking agent is ethylenediamine, triethylene glycol and dipropyl（Support）Three kinds of mixtures of glycol.
The raw material of second layer of polyurethane 4 is as follows：Polyether polyol 100kg, 7~13kg of folium artemisiae argyi fiber powder, silane are even
Connection 2~3.5kg of agent and 5~8kg of isophorone diisocyanate, 12~13kg of water, 0.5~3kg of silicone oil, catalyst 0.2~
1kg, 0.5~1kg of foaming agent, 2~5kg of crosslinking agent；
The preparation method of second layer of polyurethane 4 is：Polyether polyol 100kg, 7~13kg of folium artemisiae argyi fiber powder, silane is even
Connection 2~3.5kg of agent and 5~8kg of isophorone diisocyanate, which is added in mixer, to stir evenly, and is heated to 35~38 and takes the photograph
Other raw materials of corresponding number are added in mixer by family name's degree, and high-speed stirred pours into mold and foams and cure after 6~8 seconds
Afterwards, the second layer of polyurethane 4 of corresponding embodiment 2 is obtained；
The hydroxyl value of the polyether polyol is 50~90 mgKOH/g, and molecular weight is 8000~10000, and the silicone oil is BF-
2370 and B-4900, two kinds of mass ratioes are 6：1 mixture；The catalyst is N, N- dimethylaminoethyl-N- methylamino second
Alcohol and acetylacetone,2,4-pentanedione zirconium mass ratio are 0.1-1：1 mixture；The foaming agent is sodium sulfate of polyethenoxy ether of fatty alcohol.
It is described elasticity shield foot 7 preparation method be：
（1）Prepare zein fiber yarn；
（2）Peppermint grass essential oil micro-capsule is prepared with complex coacervation；
（3）Make peppermint grass essential oil sustained release-soybean fiber；
（4）Woven fabric：
Using step（1）Zein fiber yarn obtained makees warp, step（3）Peppermint grass essential oil sustained release-soybean protein obtained
Fiber makees weft, and fabric is formed using conventional woven fabric method woven fabric；（4）Surface applies warming dose, and the elasticity of embodiment 2 is made
Protect foot 7.
The other structures component of insole is that current material is obtained by commonsense method.
Embodiment 3：
First layer of polyurethane 2 prepares raw material and weighs：Polyether polyol 100kg, methyl diphenylene diisocyanate 5~
15kg, isophorone diisocyanate 5-10kg, 12~13kg of water, 0.5~3kg of silicone oil, 0.2~1kg of catalyst, foaming agent
0.5~1kg, 2~5kg of crosslinking agent, 3~5kg of freshener, 0.2~1.3kg of stabilizer；
The preparation method of first layer of polyurethane 2 is：By the polyether polyol of corresponding weight kg numbers, two isocyanide of diphenyl methane
Acid esters, isophorone diisocyanate are added in mixer and stir evenly, and 35~38 degrees Celsius are heated to, by corresponding kg numbers
Other raw materials be added in mixer, high-speed stirred is poured into after 6~8 seconds after mold foams and cure, and corresponding reality is obtained
Apply the first layer of polyurethane 2 of example 3.
The hydroxyl value of the polyether polyol is 50~90 mgKOH/g, and molecular weight is 8000~10000, and the silicone oil is
Two kinds of mass ratioes of BF-2370 and B-4900 are 3：1 mixture；The catalyst is N, N- dimethylaminoethyl-N- methyl ammonia
Base ethyl alcohol and acetylacetone,2,4-pentanedione zirconium mass ratio are 0.5：1 mixture；The foaming agent is normal heptane；Crosslinking agent is ethylenediamine, three
Glycol and dipropyl（Support）Three kinds of mixtures of glycol；The freshener be menthol, 3- hydroxybutyric acids menthyl ester, menthyl lactate,
Glutaric acid menthyl ester, 3-L- menthoxypropane -1,2- glycol, menthyl acetate, isopulegol, peppermint oxygroup -2- methyl -
1,2-PD, menthol diglycol carbonate ester admixture carry out powdered with low-temperature airflow contact under spray pattern and form；Institute
State stabilizer be cyclodextrin, methylcellulose, pectin, gelatin hydrolysied matter, carrageenan, gellan gum, furcellaran, alginic acid,
Digest mixture made of the components such as lecithin, casein, xanthans.
The raw material of second layer of polyurethane 4 is as follows：Polyether polyol 100kg, 7~13kg of folium artemisiae argyi fiber powder, silane are even
Connection 2~3.5kg of agent and 5~8kg of isophorone diisocyanate, 12~13kg of water, 0.5~3kg of silicone oil, catalyst 0.2~
1kg, 0.5~1kg of foaming agent, 2~5kg of crosslinking agent；
The preparation method of second layer of polyurethane 4 is：Polyether polyol 100kg, 7~13kg of folium artemisiae argyi fiber powder, silane is even
Connection 2~3.5kg of agent and 5~8kg of isophorone diisocyanate, which is added in mixer, to stir evenly, and is heated to 35~38 and takes the photograph
Other raw materials of corresponding number are added in mixer by family name's degree, and high-speed stirred pours into mold and foams and cure after 6~8 seconds
Afterwards, the second layer of polyurethane 4 of corresponding embodiment 3 is obtained；
The hydroxyl value of the polyether polyol is 50~90 mgKOH/g, and molecular weight is 8000~10000, and the silicone oil is BF-
2370 and B-4900, two kinds of mass ratioes are 6：1 mixture；The catalyst is N, N- dimethylaminoethyl-N- methylamino second
Alcohol and acetylacetone,2,4-pentanedione zirconium mass ratio are 0.1-1：1 mixture；The foaming agent is sodium sulfate of polyethenoxy ether of fatty alcohol.
It is described elasticity shield foot 7 preparation method be：
（1）Prepare zein fiber yarn；
（2）Peppermint grass essential oil micro-capsule is prepared with complex coacervation；
（3）Make peppermint grass essential oil sustained release-soybean fiber；
（4）Woven fabric：
Using step（1）Zein fiber yarn obtained makees warp, step（3）Peppermint grass essential oil sustained release-soybean protein obtained
Fiber makees weft, and fabric is formed using conventional woven fabric method woven fabric；（4）Surface applies warming dose, and the elasticity of embodiment 3 is made
Protect foot 7.
The other structures component of insole is that current material is obtained by commonsense method.
Embodiment 4
First layer of polyurethane 2 prepares raw material and weighs：Polyether polyol 100kg, methyl diphenylene diisocyanate 5~
15kg, isophorone diisocyanate 5-10kg, 12~13kg of water, 0.5~3kg of silicone oil, 0.2~1kg of catalyst, foaming agent
0.5~1kg, 2~5kg of crosslinking agent, 3~5kg of freshener, 0.2~1.3kg of stabilizer；
The preparation method of first layer of polyurethane 2 is：By the polyether polyol of corresponding weight kg numbers, two isocyanide of diphenyl methane
Acid esters, isophorone diisocyanate are added in mixer and stir evenly, and 35~38 degrees Celsius are heated to, by corresponding kg numbers
Other raw materials be added in mixer, high-speed stirred is poured into after 6~8 seconds after mold foams and cure, and corresponding reality is obtained
Apply the first layer of polyurethane 2 of example 4.
The hydroxyl value of the polyether polyol is 50~90 mgKOH/g, and molecular weight is 8000~10000, and the silicone oil is
Two kinds of mass ratioes of BF-2370 and B-4900 are 3：1 mixture；The catalyst is N, N- dimethylaminoethyl-N- methyl ammonia
Base ethyl alcohol and acetylacetone,2,4-pentanedione zirconium mass ratio are 0.5：1 mixture；The foaming agent is normal heptane；Crosslinking agent is ethylenediamine, three
Glycol and dipropyl（Support）Three kinds of mixtures of glycol；The freshener be menthol, 3- hydroxybutyric acids menthyl ester, menthyl lactate,
Glutaric acid menthyl ester, 3-L- menthoxypropane -1,2- glycol, menthyl acetate, isopulegol, peppermint oxygroup -2- methyl -
1,2-PD, menthol diglycol carbonate ester admixture carry out powdered with low-temperature airflow contact under spray pattern and form；Institute
State stabilizer be cyclodextrin, methylcellulose, pectin, gelatin hydrolysied matter, carrageenan, gellan gum, furcellaran, alginic acid,
Digest mixture made of the components such as lecithin, casein, xanthans.
3 raw material of memory foam sponge layer weighs as follows：Polyether polyol 100kg, hexamethylene diisocyanate 5~
10kg, 5~15kg of methyl diphenylene diisocyanate, isophorone diisocyanate 5-10kg, 12~13kg of water, silicone oil 0.5
~3kg, 0.2~1kg of stannous octoate, 0.5~1kg of foaming agent, 2~5kg of crosslinking agent；
It is described memory foam sponge layer 3 preparation method be：By the polyether polyol of corresponding parts by weight, diphenylmethane diisocyanate
Ester, isophorone diisocyanate are added in mixer and stir evenly, and 35~38 degrees Celsius are heated to, by corresponding number
Other raw materials are added in mixer, and high-speed stirred is poured into after 6~8 seconds after mold foams and cure, and is implemented accordingly
The memory foam sponge layer 3 of example 4；
The hydroxyl value of the polyether polyol is 55~85 mgKOH/g, and molecular weight is 8000~9000, and the silicone oil is BF-2370
It is 1.5 with two kinds of mass ratioes of B-4900：1 mixture；The catalyst is stannous octoate；The foaming agent is trichlorine fluorine first
Alkane；Crosslinking agent is ethylenediamine, triethylene glycol and dipropyl（Support）Three kinds of mixtures of glycol.
It is described elasticity shield foot 7 preparation method be：
（1）Prepare zein fiber yarn；
（2）Peppermint grass essential oil micro-capsule is prepared with complex coacervation；
（3）Make peppermint grass essential oil sustained release-soybean fiber；
（4）Woven fabric：
Using step（1）Zein fiber yarn obtained makees warp, step（3）Peppermint grass essential oil sustained release-soybean protein obtained
Fiber makees weft, and fabric is formed using conventional woven fabric method woven fabric；（4）Surface applies warming dose, and the elasticity of embodiment 4 is made
Protect foot 7.
The other structures component of insole is that current material is obtained by commonsense method.
All it is that current material is carried out by the insole that commonsense method obtains by the embodiment 1-4 insoles prepared and all components
Comparison finds that the comfort of embodiment 1,2,3,4 and physical therapy performance are substantially better than the shoes that current material is obtained by commonsense method
Pad, the especially insole of embodiment 1, comfort highest, and temperature reduction performance, massage property and elasticity are best；Embodiment 2 is without apparent
Cool function；Memory bubble continuous production method of the embodiment 3 because not using embodiment 1, elasticity and comfort level aspect are compared
Embodiment 1 is slightly worse；Embodiment 4, foot massages promote blood circulation function compared to embodiment 1 it is slightly worse.
The above is only better embodiment of the present invention, and every technical solution according to the present invention is to above implementation
Any subtle modifications, equivalent variations and modifications, belong in the range of technical solution of the present invention made by mode.
Claims (9)
1. a kind of cool insole, including insole body, it is characterised in that：The insole body includes receiving successively from top to bottom
Rice bamboo and the first layer of polyurethane, memory foam sponge layer, the second layer of polyurethane, under the front end of second layer of polyurethane
Side is provided with the first cushioning piece corresponding to the position of vola before human body, corresponds on the downside of the rear end of second layer of polyurethane
The position of human body heel portion is provided with the second cushioning piece, and the downside of second layer of polyurethane corresponds to the position of human body arch portion
It installs and is equipped with elasticity shield foot；The front end of corresponding insole body is equipped with two S for exhaust on the upside of first layer of polyurethane
One end of type groove, the S types groove extends to the left end of insole body, and the other end of the S type grooves extends to insole body
Right end, the position of two S type grooves that the memory foam sponge layer corresponds to the first layer of polyurethane up and down also is provided with two S type ditches
Slot；The convex grain of 120~160 upper flats is arranged on the upside of second layer of polyurethane.
2. cool insole according to claim 1, it is characterised in that：The shape of first cushioning piece is in tongue
The shape of type, second cushioning piece is rounded, and the shape of the elasticity shield foot is in half-moon-shaped, the elasticity shield foot packet
Entire human body arch portion is wrapped up in, the convex grain of 130~150 upper flats is arranged on the upside of second layer of polyurethane.
3. cool insole according to claim 1, it is characterised in that：The thickness of the nanometer bamboo carbon fiber layer is
0.4~1.2 mm, the thickness of first layer of polyurethane are 3.0~8.0mm, the thickness of the memory foam sponge layer is 2.95~
The thickness of 8.55mm, second layer of polyurethane are 3.5~9.5mm, and the thickness of first cushioning piece is 3.8~6.0mm,
The thickness of second cushioning piece is 3.5~6.0mm, and the thickness of the elasticity shield foot is 3.5~6.5mm.
4. cool insole according to any one of claims 1 to 3, it is characterised in that：Before insole body
End includes waist and insole heel in insole half sole, insole successively, wherein waist and insole heel are all provided in the insole to rear end
It is equipped with the outer rim up tilted, the tilting height of the insole heel is less than the tilting height of waist both sides in insole.
5. cool insole according to claim 1, it is characterised in that：First layer of polyurethane is cooling polyurethane
Layer, made of the following raw material reaction foaming：100 parts of polyether polyol, 5~15 parts of methyl diphenylene diisocyanate, different Buddhist
5-10 parts of ketone diisocyanate of that, 12~13 parts of water, 0.5~3 part of silicone oil, 0.2~1 part of catalyst, 0.5~1 part of foaming agent are handed over
Join 2~5 parts of agent, 3~5 parts of freshener, 0.2~1.3 part of stabilizer；
The preparation method of first layer of polyurethane is：By the polyether polyol of corresponding parts by weight, two isocyanide of diphenyl methane
Acid esters, isophorone diisocyanate are added in mixer and stir evenly, and 35~38 degrees Celsius are heated to, by corresponding number
Other raw materials be added in mixer, high-speed stirred is poured into after 6~8 seconds after mold foams and cure, and obtains corresponding
One layer of polyurethane.
6. cool insole according to claim 5, it is characterised in that：The hydroxyl value of the polyether polyol is 50~90
MgKOH/g, molecular weight are 8000~10000, and the silicone oil is BF-2370 and two kinds of mass ratioes of B-4900 are 3：1 mixture；
The catalyst is N, and N- dimethylaminoethyl-N- methyl amino ethanols and acetylacetone,2,4-pentanedione zirconium mass ratio are 0.5：1 mixture；
The foaming agent is normal heptane；Crosslinking agent is ethylenediamine, triethylene glycol and dipropyl（Support）Three kinds of mixtures of glycol；The freshener is
Menthol, 3- hydroxybutyric acids menthyl ester, menthyl lactate, glutaric acid menthyl ester, 3-L- menthoxypropane -1,2- glycol,
Menthyl acetate, isopulegol, peppermint oxygroup -2- methyl-1s, 2- propylene glycol, menthol diglycol carbonate ester admixture are being atomized
Carry out powdered with low-temperature airflow contact under state to form；The stabilizer is cyclodextrin, methylcellulose, pectin, gelatin hydrolysis
Mixing made of the components such as object, carrageenan, gellan gum, furcellaran, alginic acid, enzymolysis lecithin, casein, xanthans
Object.
7. cool insole according to claim 1, it is characterised in that：The memory foam sponge layer is reacted by the following raw material
Made of foaming：100 parts of polyether polyol, 5~10 parts of hexamethylene diisocyanate, methyl diphenylene diisocyanate 5~
15 parts, 5-10 parts of isophorone diisocyanate, 12~13 parts of water, 0.5~3 part of silicone oil, 0.2~1 part of stannous octoate, foaming agent
0.5~1 part, 2~5 parts of crosslinking agent；
It is described memory foam sponge layer preparation method be：By the polyether polyol of corresponding parts by weight, diphenylmethane diisocyanate
Ester, isophorone diisocyanate are added in mixer and stir evenly, and 35~38 degrees Celsius are heated to, by corresponding number
Other raw materials are added in mixer, and high-speed stirred is poured into after 6~8 seconds after mold foams and cure, and is remembered accordingly
Foam sponge layer；
The hydroxyl value of the polyether polyol is 55~85 mgKOH/g, and molecular weight is 8000~9000, and the silicone oil is BF-2370
It is 1.5 with two kinds of mass ratioes of B-4900：1 mixture；The catalyst is stannous octoate；The foaming agent is trichlorine fluorine first
Alkane；Crosslinking agent is ethylenediamine, triethylene glycol and dipropyl（Support）Three kinds of mixtures of glycol.
8. cool insole according to claim 1, it is characterised in that：Second layer of polyurethane 4 is by the following raw material
Made of reaction foaming：100 parts of polyether polyol, 7~13 parts of folium artemisiae argyi fiber powder, 2~3.5 parts of silane coupling agent and isophorone
5~8 parts of diisocyanate, 12~13 parts of water, 0.5~3 part of silicone oil, 0.2~1 part of catalyst, 0.5~1 part of foaming agent, crosslinking agent
2~5 parts；
The preparation method of second layer of polyurethane is：The polyether polyol of corresponding parts by weight, folium artemisiae argyi fiber powder, silane is even
Connection agent and isophorone diisocyanate, which are added in mixer, to stir evenly, and 35~38 degrees Celsius is heated to, by corresponding part
Several other raw materials are added in mixer, and high-speed stirred is poured into after 6~8 seconds after mold foams and cure, and is obtained corresponding
Second layer of polyurethane；
The hydroxyl value of the polyether polyol is 50~90 mgKOH/g, and molecular weight is 8000~10000, and the silicone oil is BF-
2370 and B-4900, two kinds of mass ratioes are 6：1 mixture；The catalyst is N, N- dimethylaminoethyl-N- methylamino second
Alcohol and acetylacetone,2,4-pentanedione zirconium mass ratio are 0.1-1：1 mixture；The foaming agent is sodium sulfate of polyethenoxy ether of fatty alcohol.
9. cool insole according to claim 1, it is characterised in that：It is described elasticity shield foot preparation method be：
（1）Prepare zein fiber yarn；
（2）Peppermint grass essential oil micro-capsule is prepared with complex coacervation；
（3）Make peppermint grass essential oil sustained release-soybean fiber；
（4）Woven fabric：
Using step（1）Zein fiber yarn obtained makees warp, step（3）Peppermint grass essential oil sustained release-soybean protein obtained
Fiber makees weft, and fabric is formed using conventional woven fabric method woven fabric；（4）Surface applies warming dose, and elasticity shield foot is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810401282.4A CN108720170A (en) | 2018-04-28 | 2018-04-28 | A kind of cool insole |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810401282.4A CN108720170A (en) | 2018-04-28 | 2018-04-28 | A kind of cool insole |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108720170A true CN108720170A (en) | 2018-11-02 |
Family
ID=63940027
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810401282.4A Pending CN108720170A (en) | 2018-04-28 | 2018-04-28 | A kind of cool insole |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108720170A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109796579A (en) * | 2019-03-05 | 2019-05-24 | 浙江德清昂沃泡沫塑料有限公司 | A kind of polyurethane sponge |
| CN109880059A (en) * | 2019-03-05 | 2019-06-14 | 浙江德清昂沃泡沫塑料有限公司 | A kind of preparation method of polyurethane sponge |
| USD903268S1 (en) | 2019-02-06 | 2020-12-01 | S. C. Johnson & Son, Inc. | Insole |
| USD906658S1 (en) | 2019-02-19 | 2021-01-05 | S. C. Johnson & Son, Inc. | Insole |
| CN112761004A (en) * | 2021-01-20 | 2021-05-07 | 广州溢成印花有限公司 | Ice feeling printing paste, printed clothes and manufacturing process thereof |
| WO2023044944A1 (en) * | 2021-09-27 | 2023-03-30 | 福建鸿星尔克体育用品有限公司 | High-resilience ultra-light insole and preparation method therefor |
Citations (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101165094A (en) * | 2007-09-29 | 2008-04-23 | 山东东大一诺威聚氨酯有限公司 | Urethane micro-pore elastomer composite material adapated for insole and preparation method thereof |
| CN101781454A (en) * | 2009-12-25 | 2010-07-21 | 山东东大一诺威聚氨酯有限公司 | Low hardness polyurethane elastic body composite |
| WO2010111623A1 (en) * | 2009-03-26 | 2010-09-30 | Stratten Performance Group, Llc | Weighted shoe insole and method for making the same |
| CN102120877A (en) * | 2011-01-17 | 2011-07-13 | 中国皮革和制鞋工业研究院 | Ultralow-hardness polyurethane elastomer and preparation method thereof |
| CN103571364A (en) * | 2013-10-08 | 2014-02-12 | 东莞市雄林新材料科技有限公司 | Hot-melt-adhesive laminated TPU (thermoplastic polyurethane) foamed film |
| CN103755912A (en) * | 2014-01-15 | 2014-04-30 | 上海后先聚氨酯有限公司 | Preparation method of modified polyurethane material |
| CN104387544A (en) * | 2014-09-26 | 2015-03-04 | 黄朝扬 | Production formula and process of multifunctional insoles |
| CN104414017A (en) * | 2013-08-28 | 2015-03-18 | 青岛医防消毒专业技术中心 | Moxa leaf healthcare insole |
| CN104684412A (en) * | 2012-10-05 | 2015-06-03 | 小川香料株式会社 | Powdery refreshing composition |
| CN104761803A (en) * | 2015-03-19 | 2015-07-08 | 苏州市景荣科技有限公司 | Antiskid EVA sole material and preparation method thereof |
| CN104761746A (en) * | 2015-03-19 | 2015-07-08 | 苏州市景荣科技有限公司 | PVC material compound foaming agent |
| CN105711091A (en) * | 2016-02-03 | 2016-06-29 | 华南理工大学 | Individualized 3D printed insole and making method thereof |
| US20170129205A1 (en) * | 2015-11-10 | 2017-05-11 | Heedae Park | Footwear insole and manufacturing method thereof |
| CN206238572U (en) * | 2016-11-29 | 2017-06-13 | 际华三五一五皮革皮鞋有限公司 | One kind buffering, anti-pin shoe-pad of rivering bend |
| CN107095392A (en) * | 2017-07-04 | 2017-08-29 | 东莞市顺风运动器材有限公司 | A kind of the elderly's Special shoe pad |
| CN107129601A (en) * | 2017-06-09 | 2017-09-05 | 深圳领护运动防护科技有限公司 | A kind of athletic protective vibration-absorptive material and preparation method thereof |
| CN107125841A (en) * | 2017-07-04 | 2017-09-05 | 东莞市顺风运动器材有限公司 | A kind of deambulation shoe-pad of walking with vigorous strides |
| CN107136643A (en) * | 2017-07-12 | 2017-09-08 | 东莞市顺风运动器材有限公司 | A kind of diabetic's health insoles |
| CN107136641A (en) * | 2017-07-12 | 2017-09-08 | 东莞市顺风运动器材有限公司 | A kind of fire-fighting operational training shoe-pad |
| CN107467785A (en) * | 2017-09-22 | 2017-12-15 | 成都卡美多鞋业投资有限公司 | Novel shoe pad with ventilative deodorizing effect |
| CN107594761A (en) * | 2017-09-06 | 2018-01-19 | 成都卡美奇鞋业有限公司 | A kind of high-heeled shoes based on footwear of Chinese medicine shoe-pad |
-
2018
- 2018-04-28 CN CN201810401282.4A patent/CN108720170A/en active Pending
Patent Citations (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101165094A (en) * | 2007-09-29 | 2008-04-23 | 山东东大一诺威聚氨酯有限公司 | Urethane micro-pore elastomer composite material adapated for insole and preparation method thereof |
| WO2010111623A1 (en) * | 2009-03-26 | 2010-09-30 | Stratten Performance Group, Llc | Weighted shoe insole and method for making the same |
| CN101781454A (en) * | 2009-12-25 | 2010-07-21 | 山东东大一诺威聚氨酯有限公司 | Low hardness polyurethane elastic body composite |
| CN102120877A (en) * | 2011-01-17 | 2011-07-13 | 中国皮革和制鞋工业研究院 | Ultralow-hardness polyurethane elastomer and preparation method thereof |
| CN104684412A (en) * | 2012-10-05 | 2015-06-03 | 小川香料株式会社 | Powdery refreshing composition |
| CN104414017A (en) * | 2013-08-28 | 2015-03-18 | 青岛医防消毒专业技术中心 | Moxa leaf healthcare insole |
| CN103571364A (en) * | 2013-10-08 | 2014-02-12 | 东莞市雄林新材料科技有限公司 | Hot-melt-adhesive laminated TPU (thermoplastic polyurethane) foamed film |
| CN103755912A (en) * | 2014-01-15 | 2014-04-30 | 上海后先聚氨酯有限公司 | Preparation method of modified polyurethane material |
| CN104387544A (en) * | 2014-09-26 | 2015-03-04 | 黄朝扬 | Production formula and process of multifunctional insoles |
| CN104761746A (en) * | 2015-03-19 | 2015-07-08 | 苏州市景荣科技有限公司 | PVC material compound foaming agent |
| CN104761803A (en) * | 2015-03-19 | 2015-07-08 | 苏州市景荣科技有限公司 | Antiskid EVA sole material and preparation method thereof |
| US20170129205A1 (en) * | 2015-11-10 | 2017-05-11 | Heedae Park | Footwear insole and manufacturing method thereof |
| CN105711091A (en) * | 2016-02-03 | 2016-06-29 | 华南理工大学 | Individualized 3D printed insole and making method thereof |
| CN206238572U (en) * | 2016-11-29 | 2017-06-13 | 际华三五一五皮革皮鞋有限公司 | One kind buffering, anti-pin shoe-pad of rivering bend |
| CN107129601A (en) * | 2017-06-09 | 2017-09-05 | 深圳领护运动防护科技有限公司 | A kind of athletic protective vibration-absorptive material and preparation method thereof |
| CN107095392A (en) * | 2017-07-04 | 2017-08-29 | 东莞市顺风运动器材有限公司 | A kind of the elderly's Special shoe pad |
| CN107125841A (en) * | 2017-07-04 | 2017-09-05 | 东莞市顺风运动器材有限公司 | A kind of deambulation shoe-pad of walking with vigorous strides |
| CN107136643A (en) * | 2017-07-12 | 2017-09-08 | 东莞市顺风运动器材有限公司 | A kind of diabetic's health insoles |
| CN107136641A (en) * | 2017-07-12 | 2017-09-08 | 东莞市顺风运动器材有限公司 | A kind of fire-fighting operational training shoe-pad |
| CN107594761A (en) * | 2017-09-06 | 2018-01-19 | 成都卡美奇鞋业有限公司 | A kind of high-heeled shoes based on footwear of Chinese medicine shoe-pad |
| CN107467785A (en) * | 2017-09-22 | 2017-12-15 | 成都卡美多鞋业投资有限公司 | Novel shoe pad with ventilative deodorizing effect |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USD903268S1 (en) | 2019-02-06 | 2020-12-01 | S. C. Johnson & Son, Inc. | Insole |
| USD906658S1 (en) | 2019-02-19 | 2021-01-05 | S. C. Johnson & Son, Inc. | Insole |
| USD935758S1 (en) | 2019-02-19 | 2021-11-16 | S. C. Johnson & Son, Inc. | Insole |
| CN109796579A (en) * | 2019-03-05 | 2019-05-24 | 浙江德清昂沃泡沫塑料有限公司 | A kind of polyurethane sponge |
| CN109880059A (en) * | 2019-03-05 | 2019-06-14 | 浙江德清昂沃泡沫塑料有限公司 | A kind of preparation method of polyurethane sponge |
| CN112761004A (en) * | 2021-01-20 | 2021-05-07 | 广州溢成印花有限公司 | Ice feeling printing paste, printed clothes and manufacturing process thereof |
| WO2023044944A1 (en) * | 2021-09-27 | 2023-03-30 | 福建鸿星尔克体育用品有限公司 | High-resilience ultra-light insole and preparation method therefor |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108720170A (en) | A kind of cool insole | |
| US4510699A (en) | Insole | |
| CN107136643A (en) | A kind of diabetic's health insoles | |
| KR100825493B1 (en) | Lightweight Silicon Implant and the Method of Producing This | |
| CN107125841B (en) | Light sports shoe-pad is walked with vigorous strides | |
| CN107095392A (en) | A kind of the elderly's Special shoe pad | |
| CN107157014A (en) | A kind of foot physical therapy insole | |
| CN105885124A (en) | Latex pillow containing aloe and preparation method thereof | |
| CN108634482A (en) | A kind of football insole | |
| CN108685266A (en) | A kind of racing car Special shoe pad | |
| CN108741412B (en) | Decompression antifatigue shoe-pad of taking a step | |
| CN108685269A (en) | A kind of professional insole of cycling | |
| CN108741411A (en) | A kind of golf Special shoe pad | |
| CN206964140U (en) | A kind of moulding body therapeutic massage sport shoe-pad | |
| CN107772650A (en) | A kind of anion shoe-pad and preparation method thereof | |
| CN113710120A (en) | Shoe comprising an insole for adhering pebbles and an outsole for foot correction | |
| CN108741409A (en) | A kind of health monitoring insole | |
| CN102318927A (en) | Sole or insole with healthcare function and manufacturing method thereof | |
| KR101807844B1 (en) | Shoes improving ventilation and method for manufacturing thereof | |
| CN206964137U (en) | A kind of diabetic's health insoles | |
| CN112205714A (en) | Multifunctional acupoint physiotherapy insole and preparation method thereof | |
| CN108741410A (en) | A kind of two-in-one insole of socks insole | |
| CN108634480A (en) | A kind of snowfield sport shoe-pad | |
| CN108685268A (en) | A kind of running Special shoe pad | |
| CN205568035U (en) | Arch of foot pillow shoe -pad |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181102 |
|
| RJ01 | Rejection of invention patent application after publication |