CN108634480A - A kind of snowfield sport shoe-pad - Google Patents
A kind of snowfield sport shoe-pad Download PDFInfo
- Publication number
- CN108634480A CN108634480A CN201810384393.9A CN201810384393A CN108634480A CN 108634480 A CN108634480 A CN 108634480A CN 201810384393 A CN201810384393 A CN 201810384393A CN 108634480 A CN108634480 A CN 108634480A
- Authority
- CN
- China
- Prior art keywords
- parts
- insole
- layer
- continuous
- pad
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000001102 lavandula vera Substances 0.000 claims description 8
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Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
- A43B17/003—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined characterised by the material
- A43B17/006—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined characterised by the material multilayered
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
- A43B17/02—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined wedge-like or resilient
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
- A43B17/08—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined ventilated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
- C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0023—Use of organic additives containing oxygen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0028—Use of organic additives containing nitrogen
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
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- D—TEXTILES; PAPER
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- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
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- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
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Abstract
The invention discloses a kind of snowfield sport shoe-pads, including insole body, insole body includes breathable heat insulating layer successively from top to bottom, polyurethane foam layer, heating layer and plant fiber layer, from the front end of insole body to rear end, the downside of plant fiber layer is equipped with the first accommodating cavity successively, second accommodating cavity and third accommodating cavity, it is continuous that memory bubble is accordingly inlaid in the accommodating cavity respectively, the convex grain of more upper flats is arranged on the upside of insole half sole, insole pad in the heart the convex surfaces side Luan Xing and followed by middle part on the upside of round convex surface on be equipped with a plurality of spiral grooves, the convex grain of more upper flats is arranged in insole on the side of waist corresponded on the inside of human foot.Insole damping of the present invention, shield foot effect are strong, and insole good permeability is avoided that bacterial fungus is grown, and foot can be made be bonded with insole firm, difficult to slide, carry heating function and ensure that foot heat is supplied, this external enwergy significantly promotes blood circulation, with health care massage effect.
Description
Technical field
The present invention relates to a kind of insole, more particularly to a kind of snowfield sport shoe-pad.
Background technology
In order to experience the natural snow brought in the ice and snow world interest, have a taste of Ice ＆ Snow Culture landscape heartily, more and more people's ginsengs
In being moved to snowfield.Other entertaining movement meetings etc. no matter are run, jump or carried out in snowfield, and people avenge in experience
When ground moves the joy brought, snowfield movement is because the factor of environment also has great requirement to the dress of players, in order to more
The good protection foot of oneself, to foot it is warming be it is essential, in addition snowfield, which moves, must also pay special attention to anti-skidding, therefore market
On have the insoles of a variety of suitable varying environments.
Insole be apply very universal articles for daily use, by effect point, insole can be divided into health insoles, functional insole and often
Advise insole.The structure of traditional sock is that the sewing of multilayer cloth is suppressed into either multilayer leather, has centainly soft
Softness and shock absorbing effect substantially conform to general wear shoes demand.But emergency stop, zig zag, the urgency in snowfield movement add
During speed etc., traditional sock is then not suitable for, and is had as a drawback that：One, traditional sock damping, shield foot act on poor, snowfield
When movement, foot's half sole and followed by bottom impact force it is big, traditional sock be difficult to absorb in walking, motion process to foot bones produce
Raw impact force, it is difficult to protect vola bone, ankle-joint and knee joint；Secondly, snowfield movement likely results in because of motion intense
Foot is perspired, if sweat is discharged can lead to the ice-cold danger for having frostbite of foot not in time after perspiration, and traditional sock cannot allow
The air in vola circulates with external, increasingly moister in shoes after long-time use, increasingly heavier, and bacterium, fungi grow, damage
The sole of sporter；Thirdly, traditional sock upper side it is relatively flat, unobstructed at left and right sides of insole, rapid traverse or when slowing down, foot exists
It is easily ejected to the left and right sides of shoes in shoes, be easy to cause vola bone, ankle-joint and kneed injury；Four, conventional footwear
Pad is acted on without health care massage, can not be alleviated medicine, be caused sports fatigue, is eventually led to people and is unwilling to participate in snowfield fortune
It is dynamic；Five, traditional insole is without heating function, to winter, in equal public transport or on foot when can all feel that foot is cold, if wanted
It is that skiing or outdoor sports will obviously be more serious, traditional sock does not have the works such as improvement blood microcirculation, anti-inflammatory, analgesia
With, cannot give sporter's foot strip come it is warm.
Invention content
The technical problem to be solved by the present invention is in view of the above shortcomings of the prior art, provide a kind of snowfield sport shoe-pad,
The insole damping protects foot effect by force, and insole good permeability is avoided that bacterial fungus is grown, and foot can be made to be bonded with insole and consolidated, no
Easily sliding carries heating function and ensures that the supply of foot heat, this external enwergy significantly promote blood circulation, there is health care massage to make
With.
In order to solve the above technical problems, the technical scheme is that：A kind of snowfield sport shoe-pad, including insole body,
The insole body includes breathable heat insulating layer, polyurethane foam layer, heating layer and plant fiber layer, feature successively from top to bottom
It is：From the front end of insole body to rear end, the downside of the plant fiber layer is equipped with the first accommodating cavity, the second accommodating cavity successively
And third accommodating cavity, the first memory bubble is inlaid in first accommodating cavity, the second accommodating cavity and third accommodating cavity respectively
Continuous, the second memory bubble silk floss and third memory bubble are continuous, and it is 2.5~10.5mm that continuous thickness is steeped in first memory, described
The continuous thickness of second memory bubble distinguishes 3.5~12.0mm, and the continuous thickness of the third memory bubble is 2.5~9.5mm.
It is expanded on further as to the present invention：
Preferably, include insole half sole, the insole pad heart successively, in insole after waist and insole from the front end of insole body to rear end
With being arranged with the convex grain of 70~130 upper flats on the upside of the insole half sole, the downside of the insole half sole is equipped with first
Memory bubble is continuous；The upside of the insole pad heart is equipped with ovum type convex surface, and ovum type convex surface is equipped with 10~30 pad heart spiral grooves, institute
The downside for stating the insole pad heart is equipped with the second memory bubble silk floss, and the continuous shape of the second memory bubble is corresponding with the shape on ovum type convex surface；Institute
State the convex grain for being arranged with 30~50 upper flats in insole on the side of waist corresponded on the inside of human foot；After the insole
With middle part on the upside of be equipped with round convex surface, the round convex surface be equipped with 5~10 followed by spiral grooves, the insole heel
Third memory bubble silk floss is equipped on the downside of middle part, the continuous shape of third memory bubble is corresponding with the shape on round convex surface.
Preferably, the convex grain of 80~110 upper flats is arranged on the upside of the insole half sole, the insole pad is in the heart
The side convex surfaces Luan Xing are equipped with 13~22 pad heart spiral grooves, and waist corresponds on the side on the inside of human foot in the insole
It is arranged with the convex grain of 35~45 upper flats；Round convex surface on the upside of the insole followed by middle part is equipped with 6~9 followed by spiral shell
Revolve groove, it is described pad heart spiral grooves and followed by spiral grooves a diameter of 0.3~0.6mm.
Preferably, the thickness of the breathable heat insulating layer is 0.5~0.9 mm, the thickness of the polyurethane foam layer is 3~
6mm, the fever layer thickness are 3.0~5.5mm, and the thickness of the plant fiber layer is 2.0~5.0mm.
Preferably, the thickness of the breathable heat insulating layer is 0.55~0.80 mm, and the thickness of the polyurethane foam layer is
3.6~5.2mm, the fever layer thickness are 4.0~5.0mm, and the thickness of the plant fiber layer is 2.50~4.52mm.
Preferably, the breathable heat insulating layer is made of the raw material of following each component, -12 parts of nylon 8,6-9 parts of acrylic fibers, spandex
9-15 parts, 5-7 parts of polypropylene fibre, 6-13 parts of acrylic fibers, 9-15 parts of polyvinyl, 5-7 parts of polyvinyl alcohol, 8-12 parts of isocyanates is described ventilative
Heat preservation layer is the modified fibre layer made from the above raw material.
Preferably, the polyurethane foam layer includes pure layer of polyurethane and the flexible polyurethane alveolar layer containing medicinal powder, described
Flexible polyurethane alveolar layer is polyurethane foam material, and medicinal powder is Radix Angelicae Sinensis medicinal powder and Radix Notoginseng powder, the weight ratio of Radix Angelicae Sinensis medicinal powder and Radix Notoginseng powder
It is 0.6:1；
The flexible polyurethane alveolar layer is made of the following raw material reaction foaming：100 parts of polyether polyol, isophorone diisocyanate
10~15 parts of ester, 2~3 parts of water, 0.5~3 part of silicone oil, 0.9~3 part of dichloromethane, 0.2~1 part of catalyst, foaming agent 0.5~1
Part, 0.5~1 part of crosslinking agent；
The preparation method of the flexible polyurethane alveolar layer is：By the polyether polyol and isophorone diisocyanate of corresponding parts by weight
Ester is added in mixer and stirs evenly, and is heated to 35~38 degrees Celsius, other raw materials of corresponding number are added to mixing
In device, high-speed stirred is poured into after 6~8 seconds after mold foams and cure, and corresponding flexible polyurethane alveolar layer is obtained；The polyethers is more
The hydroxyl value of first alcohol is 50~85mgKOH/g, and molecular weight is 8000~10000, and the silicone oil is two germplasm of BF-2370 and B-4900
Amount is than being 2-5：1 mixture；The catalyst is N, N- dimethylaminoethyl-N- methyl amino ethanols and acetylacetone,2,4-pentanedione zirconium matter
Amount is than being 0.5-1：1 mixture；The foaming agent is normal octane；Crosslinking agent is three kinds of ethylenediamine, triethylene glycol and dipropylene glycol
Mixture.
Preferably, the heating layer is carbon fiber heating layer, and the carbon fiber heating layer is the inorganic height that carbon amounts is higher than 95%
Performance fibers.
Preferably, the preparation method of the plant fiber layer is：
（1）Prepare zein fiber yarn；
（2）Lavender micro-capsule is prepared with complex coacervation；
（3）Make Lavender sustained release-soybean fiber；
（4）Woven fabric：
Using step（1）Zein fiber yarn obtained makees warp, step（3）Lavender sustained release-soybean protein obtained
Fiber makees weft, and fabric is formed using conventional woven fabric method woven fabric；（4）Surface applies warming dose, and plant fiber layer is made；
Described warming dose composed of the following components：108 parts of waterglass, 30 parts of ethylene glycol monomethyl ether acetate, 36 parts of prodan,
42 parts of barium sulfate, 18 parts of formaldehyde, 48 parts of flake asbestos, 20 parts of ammonium polyphosphate, 15 parts of triethylenediamine；Warming dose of the preparation method
For：By 108 parts of waterglass, 30 parts of ethylene glycol monomethyl ether acetate, 36 parts of prodan, 42 parts of barium sulfate, 18 parts of formaldehyde, asbestos
It in 15 parts of 48 parts of powder, 20 parts of ammonium polyphosphate, triethylenediamine addition reaction kettles, stirs evenly, is made warming dose.
Preferably, the first memory bubble is continuous, the second memory bubble is continuous and continuous reacted by the following raw material of third memory bubble is sent out
It is brewed to：100 parts of polyether polyol, 5~15 parts of diethanol amine, 1-3 parts of triethylenediamine, double-（Dimethyl aminoethyl）Ether
0.1-0.2 parts, 2~4 parts of water, 0.5~3 part of silicone oil, 0.2~1 part of dibutyl tin laurate, 0.5~1 part of foaming agent, catalyst
0.3~3 part；
The first memory bubble is continuous, the second memory steeps the continuous preparation method of continuous and third memory bubble and is：By corresponding parts by weight
Polyether polyol, diethanol amine, triethylenediamine, double-（Dimethyl aminoethyl）Ether, water, silicone oil, dibutyl tin laurate,
Foaming agent, catalyst are added in mixer and stir evenly, and 45-50 degrees Celsius are heated to, by other raw materials of corresponding number
It is added in mixer, high-speed stirred is poured into after 6~8 seconds after mold foams and cure, and obtains remembering foam sponge layer accordingly；Institute
State polyether polyol hydroxyl value be 53.5~58.5mgKOH/g, molecular weight be 8000~10000, the silicone oil be BF-2370 and
Two kinds of mass ratioes of B-4900 are 3：1 mixture；The catalyst is N, N- dimethylaminoethyl-N- methyl amino ethanols and second
Acyl acetone zirconium mass ratio is 0.5：1 mixture；The foaming agent is normal heptane.
The beneficial effects of the invention are as follows：One, damping, shield foot, since the downside of insole half sole and insole heel is set respectively
There is memory bubble continuous, memory bubble is continuous to have outstanding memory function, can restore original form, and good permeability after deformation rapidly,
Therefore, insole elasticity is good, and hardness is moderate, can effectively absorb and be rushed to foot bones generation in snowfield movement walking, motion process
Hit power, protection vola bone, ankle-joint and knee joint；Secondly, alleviate medicine, the present invention according to principle of human engineering,
Insole pads center portion position setting ovum type convex surface, is bonded arch portion, sole center of gravity is redistributed, full sole stress equalization is made, alleviate
Movement, walking, generated stress fatigue of standing；Thirdly, stablize it is anti-skidding, it is low early and high after, it is outer thickness in it is thin, gravity leans forward so that
Toe has the activity space of bigger, conducive to toe stretching, extension, grabs ground, convex grain and spiral grooves design, significantly enhances frictional force, subtract
Rear cunning and the sideslip in snowfield motion process are lacked, biped are made more to balance, support body more balances；Four, health care massage, insole
Pad center portion position is provided with the ovum type convex surface of spiral grooves, can massage arch of the foot acupuncture point, polyurethane foam layer includes pure layer of polyurethane
And the flexible polyurethane alveolar layer containing medicinal powder, flexible polyurethane alveolar layer are polyurethane foam material, medicinal powder is Radix Angelicae Sinensis medicinal powder and Radix Notoginseng
Powder can effectively facilitate vola blood circulation, reduce the fatigue in snowfield motion process；Five, insole carries heating function, fever
Layer is carbon fiber heating layer, and lost, the ventilative guarantor of insole body top layer of foot heat in snowfield motion process can be replenished in time
The special cooked mode of warm layer so that insole appearance is light refreshing clean, has measured gas permeability and drapability；It is soft texture, light
Thin transparent, the smooth high resilience of feel, it is very strong to be through comfort on foot, good physical performance, and fibre strength is high, wear-resisting, prolonged
Endurable, chemical property is good, alkaline-resisting, chemical-resistant resistance, and anti-insect, antifungi further ensures its thermal property and gas permeability
Energy.
Description of the drawings
Fig. 1 is one of the dispersed structure schematic diagram of the present invention.
Fig. 2 is the two of the dispersed structure schematic diagram of the present invention.
In figure：100. insole body；1. breathable heat insulating layer；2. polyurethane foam layer；3. heating layer；4. plant fiber layer；
5. the first accommodating cavity；6. the second accommodating cavity；7. third accommodating cavity；8. the first memory bubble is continuous；9. the second memory bubble is continuous；10. third
Memory bubble is continuous；11. insole half sole；12. insole pads the heart；13. waist in insole；14. insole heel；15. convex grain；16. ovum type convex surface；
17. padding heart spiral grooves；18. round convex surface；19. followed by spiral grooves.
Specific implementation mode
Xia Mianjiehefutuduibenfamingjiegouyuanlihegongzuoyuanlizuojinyibuxiangxishuoming.
As shown in Figure 1, the present invention is a kind of snowfield sport shoe-pad, including insole body 100, the insole body 100 from
Include successively breathable heat insulating layer 1, polyurethane foam layer 2, heating layer 3 and plant fiber layer 4 under, from insole body 100
The downside of front end to rear end, the plant fiber layer 4 is equipped with the first accommodating cavity 5, the second accommodating cavity 6 and third accommodating cavity successively
7, the first memory bubble silk floss 8, second is inlaid in first accommodating cavity 5, the second accommodating cavity 6 and third accommodating cavity 7 respectively and is remembered
Recall bubble silk floss 9 and third memory bubble silk floss 10, the thickness of the first memory bubble silk floss 8 is 2.5~10.5mm, second note
The thickness for recalling bubble silk floss 9 distinguishes 3.5~12.0mm, and the thickness of the third memory bubble silk floss 10 is 2.5~9.5mm.
Include insole half sole 11, the insole pad heart 12, shoes successively as shown in Figure 1, from the front end of insole body 100 to rear end
Waist 13 and insole heel 14 in pad, the upside of the insole half sole 11 is arranged with the convex grain 15 of 70~130 upper flats, described
The downside of insole half sole 11 is equipped with the first memory bubble silk floss 8；The upside of the insole pad heart 12 is equipped with ovum type convex surface 16, ovum type convex surface
16 are equipped with 10~30 pad heart spiral grooves 17, and the downside of the insole pad heart 12 is equipped with the second memory bubble silk floss 9, the second memory
The shape of bubble silk floss 9 is corresponding with the shape on ovum type convex surface 16；The side of waist 13 corresponded on the inside of human foot in the insole
On be arranged with the convex grains 15 of 30~50 upper flats；Round convex surface 18 is equipped on the upside of the middle part of the insole heel 14, it is described
Round convex surface 18 is equipped with 5~10 followed by spiral grooves 19, and third memory bubble is equipped on the downside of the middle part of the insole heel 14
The shape of silk floss 10, third memory bubble silk floss 10 is corresponding with the shape on round convex surface 18.
As shown in Figure 1, the upside of the insole half sole 11 is arranged with the convex grain 15 of 80~110 upper flats, the shoes
The pad pad heart 12 upside ovum type convex surface 16 is equipped with 13~22 pad heart spiral grooves 17, and waist 13 corresponds to human body in the insole
The convex grain 15 of 35~45 upper flats is arranged on side on the inside of sole；It is round convex on the upside of 14 middle part of the insole heel
Face 18 is equipped with 6~9 followed by spiral grooves 19, the pad heart spiral grooves 17 and followed by spiral grooves 19 a diameter of 0.3
~0.6mm.
As shown in Figure 1, the thickness of the breathable heat insulating layer 1 is 0.5~0.9 mm, the thickness of the polyurethane foam layer 2
For 3~6mm, 3 thickness of the heating layer is 3.0~5.5mm, and the thickness of the plant fiber layer 4 is 2.0~5.0mm.
As shown in Figure 1, the thickness of the breathable heat insulating layer 1 is 0.55~0.80 mm, the thickness of the polyurethane foam layer 2
Degree is 3.6~5.2mm, and 3 thickness of the heating layer is 4.0~5.0mm, the thickness of the plant fiber layer 4 is 2.50~
4.52mm。
Embodiment 1
The breathable heat insulating layer is made of the raw material of following each component, 10 parts of nylon, 8 parts of acrylic fibers, 11 parts of spandex, 6 parts of polypropylene fibre, nitrile
7 parts of synthetic fibre, 12 parts of polyvinyl, 5 parts of polyvinyl alcohol, 9 parts of isocyanates, the breathable heat insulating layer are modified fine made from the above raw material
Tie up layer.
The polyurethane foam layer includes pure layer of polyurethane and the flexible polyurethane alveolar layer containing medicinal powder, the flexible polyurethane
Alveolar layer is polyurethane foam material, and medicinal powder is Radix Angelicae Sinensis medicinal powder and Radix Notoginseng powder, and the weight ratio of Radix Angelicae Sinensis medicinal powder and Radix Notoginseng powder is 0.6:1；
The flexible polyurethane alveolar layer is made of the following raw material reaction foaming：100 parts of polyether polyol, isophorone diisocyanate
13 parts of ester, 2.5 parts of water, 2.5 parts of silicone oil, 1.2 parts of dichloromethane .9 parts of catalyst, 0.7 part of foaming agent, 0.75 part of crosslinking agent；
The preparation method of the flexible polyurethane alveolar layer is：By the polyether polyol and isophorone diisocyanate of corresponding parts by weight
Ester is added in mixer and stirs evenly, and is heated to 35~38 degrees Celsius, other raw materials of corresponding number are added to mixing
In device, high-speed stirred is poured into after 6~8 seconds after mold foams and cure, and corresponding flexible polyurethane alveolar layer is obtained；The polyethers is more
The hydroxyl value of first alcohol is 75mgKOH/g, and molecular weight 8800, the silicone oil is BF-2370 and two kinds of mass ratioes of B-4900 are 3：1
Mixture；The catalyst is N, and N- dimethylaminoethyl-N- methyl amino ethanols and acetylacetone,2,4-pentanedione zirconium mass ratio are 0.9：1
Mixture；The foaming agent is normal octane；Crosslinking agent is three kinds of ethylenediamine, triethylene glycol and dipropylene glycol mixtures.
The heating layer is carbon fiber heating layer, and the carbon fiber heating layer is that inorganic high-performance of the carbon amounts higher than 95% is fine
Dimension.
The preparation method of the plant fiber layer is：
（1）Prepare zein fiber yarn；
（2）Lavender micro-capsule is prepared with complex coacervation；
（3）Make Lavender sustained release-soybean fiber；
（4）Woven fabric：
Using step（1）Zein fiber yarn obtained makees warp, step（3）Lavender sustained release-soybean protein obtained
Fiber makees weft, and fabric is formed using conventional woven fabric method woven fabric；（4）Surface applies warming dose, and plant fiber layer 4 is made.
Described warming dose composed of the following components：108 parts of waterglass, 30 parts of ethylene glycol monomethyl ether acetate, prodan
36 parts, 42 parts of barium sulfate, 18 parts of formaldehyde, 48 parts of flake asbestos, 20 parts of ammonium polyphosphate, 15 parts of triethylenediamine；Warming dose of the system
Preparation Method is：By 108 parts of waterglass, 30 parts of ethylene glycol monomethyl ether acetate, 36 parts of prodan, 42 parts of barium sulfate, formaldehyde 18
It in 15 parts of part, 48 parts of flake asbestos, 20 parts of ammonium polyphosphate, triethylenediamine addition reaction kettles, stirs evenly, is made warming dose.
The first memory bubble is continuous, the second memory bubble is continuous and third memory bubble is continuous is made of the following raw material reaction foaming
's：100 parts of polyether polyol, 9 parts of diethanol amine, 2.2 parts of triethylenediamine, double-（Dimethyl aminoethyl）0.13 part of ether, water 3
Part, 2.8 parts of silicone oil, 0.95 part of dibutyl tin laurate, 0.65 part of foaming agent, 2.25 parts of catalyst；
The first memory bubble is continuous, the second memory steeps the continuous preparation method of continuous and third memory bubble and is：By corresponding parts by weight
Polyether polyol, diethanol amine, triethylenediamine, double-（Dimethyl aminoethyl）Ether, water, silicone oil, dibutyl tin laurate,
Foaming agent, catalyst are added in mixer and stir evenly, and 45-50 degrees Celsius are heated to, by other raw materials of corresponding number
It is added in mixer, high-speed stirred is poured into after 6~8 seconds after mold foams and cure, and obtains remembering foam sponge layer accordingly；Institute
The hydroxyl value for stating polyether polyol is 57mgKOH/g, and molecular weight 9000, the silicone oil is two kinds of quality of BF-2370 and B-4900
Than being 3：1 mixture；The catalyst is N, N- dimethylaminoethyl-N- methyl amino ethanols and acetylacetone,2,4-pentanedione zirconium mass ratio
It is 0.5：1 mixture；The foaming agent is normal heptane.
Embodiment 2
The breathable heat insulating layer is made of the raw material of following each component, 12 parts of nylon, 8 parts of acrylic fibers, 12 parts of spandex, 5 parts of polypropylene fibre, nitrile
13 parts of synthetic fibre, 12 parts of polyvinyl, 6 parts of polyvinyl alcohol, 11 parts of isocyanates, the breathable heat insulating layer are modified made from the above raw material
Fibrous layer.
The polyurethane foam layer includes pure layer of polyurethane and the flexible polyurethane alveolar layer containing medicinal powder, the flexible polyurethane
Alveolar layer is polyurethane foam material, and medicinal powder is Radix Angelicae Sinensis medicinal powder and Radix Notoginseng powder, and the weight ratio of Radix Angelicae Sinensis medicinal powder and Radix Notoginseng powder is 0.6:1；
The flexible polyurethane alveolar layer is made of the following raw material reaction foaming：100 parts of polyether polyol, isophorone diisocyanate
13 parts of ester, 3 parts of water, 3 parts of silicone oil, 3 parts of dichloromethane, 1 part of catalyst, 0.8 part of foaming agent, 0.6 part of crosslinking agent；
The preparation method of the flexible polyurethane alveolar layer is：By the polyether polyol and isophorone diisocyanate of corresponding parts by weight
Ester is added in mixer and stirs evenly, and is heated to 35~38 degrees Celsius, other raw materials of corresponding number are added to mixing
In device, high-speed stirred is poured into after 6~8 seconds after mold foams and cure, and corresponding flexible polyurethane alveolar layer is obtained；The polyethers is more
The hydroxyl value of first alcohol is 82mgKOH/g, and molecular weight 9000, the silicone oil is BF-2370 and two kinds of mass ratioes of B-4900 are 4：1
Mixture；The catalyst is N, and N- dimethylaminoethyl-N- methyl amino ethanols and acetylacetone,2,4-pentanedione zirconium mass ratio are 0.7：1
Mixture；The foaming agent is normal octane；Crosslinking agent is three kinds of ethylenediamine, triethylene glycol and dipropylene glycol mixtures.
The other structures component of insole is that current material is obtained by commonsense method.
Embodiment 3
Polyurethane foam layer, heating layer, plant fiber layer and the first memory bubble are continuous, the second memory bubble is continuous, third memory bubble is continuous
Such as embodiment 1, the breathable heat insulating layer and other structure members of insole are that current material is obtained by commonsense method.
Embodiment 4
The polyurethane foam layer and other structure members of insole are that current material is obtained by commonsense method, other and embodiment 1
It is identical.
Embodiment 5
Breathable heat insulating layer, polyurethane foam layer, heating layer are same as Example 1, the plant fiber layer of insole, the first memory bubble
The other structures component such as continuous, the second memory bubble silk floss and third memory bubble silk floss is that current material is obtained by commonsense method.
Embodiment 6
The heating layer is carbon fiber heating layer, and the carbon fiber heating layer is the inorganic high-performance fiber that carbon amounts is higher than 95%.
The preparation method of the plant fiber layer is：
（1）Prepare zein fiber yarn；
（2）Lavender micro-capsule is prepared with complex coacervation；
（3）Make Lavender sustained release-soybean fiber；
（4）Woven fabric：
Using step（1）Zein fiber yarn obtained makees warp, step（3）Lavender sustained release-soybean protein obtained
Fiber makees weft, and fabric is formed using conventional woven fabric method woven fabric；（4）Surface applies warming dose, and plant fiber layer 4 is made；
Described warming dose composed of the following components：108 parts of waterglass, 30 parts of ethylene glycol monomethyl ether acetate, 36 parts of prodan,
42 parts of barium sulfate, 18 parts of formaldehyde, 48 parts of flake asbestos, 20 parts of ammonium polyphosphate, 15 parts of triethylenediamine；Warming dose of the preparation method
For：By 108 parts of waterglass, 30 parts of ethylene glycol monomethyl ether acetate, 36 parts of prodan, 42 parts of barium sulfate, 18 parts of formaldehyde, asbestos
It in 15 parts of 48 parts of powder, 20 parts of ammonium polyphosphate, triethylenediamine addition reaction kettles, stirs evenly, is made warming dose.
The first memory bubble is continuous, the second memory bubble is continuous and third memory bubble is continuous is made of the following raw material reaction foaming
's：100 parts of polyether polyol, 5 parts of diethanol amine, triethylenediamine part, double-（Dimethyl aminoethyl）0.11 part of ether, 2 parts of water,
0.5 part of silicone oil, 0.2 part of dibutyl tin laurate, 0.5 part of foaming agent, 0.3 part of catalyst；
The first memory bubble is continuous, the second memory steeps the continuous preparation method of continuous and third memory bubble and is：By corresponding parts by weight
Polyether polyol, diethanol amine, triethylenediamine, double-（Dimethyl aminoethyl）Ether, water, silicone oil, dibutyl tin laurate,
Foaming agent, catalyst are added in mixer and stir evenly, and are heated to 48 degrees Celsius, and other raw materials of corresponding number are added
Into mixer, high-speed stirred is poured into after 6~8 seconds after mold foams and cure, and obtains remembering foam sponge layer accordingly；It is described poly-
The hydroxyl value of ethoxylated polyhydric alcohol is 54.5mgKOH/g, and molecular weight 8000, the silicone oil is two kinds of mass ratioes of BF-2370 and B-4900
It is 3：1 mixture；The catalyst is N, and N- dimethylaminoethyl-N- methyl amino ethanols and acetylacetone,2,4-pentanedione zirconium mass ratio are
0.5：1 mixture；The foaming agent is normal heptane.
The other structures components such as the breathable heat insulating layer of embodiment 6, polyurethane foam layer are that current material passes through commonsense method
It obtains.
All it is that current material is carried out by the insole that commonsense method obtains by the embodiment 1-6 insoles prepared and all components
Comparison finds no matter excellent from wearing comfort and the more common insole of warming, ventilative, elastic property etc. embodiment 1-6 is,
The especially insole of embodiment 1, warmth retention property is best, heating property is best and gas permeability and comfort highest.
The heating property of embodiment 2 embodiment 1 that compares with elastic property is slightly worse, 3 heat insulation effect of embodiment and gas permeability
The embodiment that can compare 1 is slightly worse, and for embodiment 4 without the effect significantly to promote blood circulation, comfort is slightly worse compared with embodiment 1, real
The embodiment 1 that compares in terms of applying 5 wearing comfort of example, wearability and elastic property is slightly worse, 6 gas permeability of embodiment and warming effect
Fruit and antifatigue etc. the embodiment 1 that compares are slightly worse.
The above is only better embodiment of the present invention, and every technical solution according to the present invention is to above implementation
Any subtle modifications, equivalent variations and modifications, belong in the range of technical solution of the present invention made by mode.
Claims (10)
1. a kind of snowfield sport shoe-pad, including insole body, the insole body includes from top to bottom breathable heat insulating layer successively, gathers
Urethane foam sponge layer, heating layer and plant fiber layer, it is characterised in that：From the front end of insole body to rear end, the plant fiber
The downside of layer is equipped with the first accommodating cavity, the second accommodating cavity and third accommodating cavity, first accommodating cavity, the second accommodating cavity successively
And it is inlaid with that the first memory bubble is continuous, the second memory bubble is continuous and third memory bubble is continuous in third accommodating cavity respectively, it is described
The continuous thickness of first memory bubble is 2.5~10.5mm, and the continuous thickness of the second memory bubble distinguishes 3.5~12.0mm, described the
The continuous thickness of three memory bubbles is 2.5~9.5mm.
2. snowfield sport shoe-pad according to claim 1, it is characterised in that：From the front end of insole body to rear end, successively
Including waist and insole heel in insole half sole, the insole pad heart, insole, 70~130 tops are arranged on the upside of the insole half sole
The downside of the smooth convex grain in portion, the insole half sole is equipped with the first memory bubble silk floss；It is convex that the upside of the insole pad heart is equipped with ovum type
Face, ovum type convex surface are equipped with 10~30 pad heart spiral grooves, and the downside of the insole pad heart is continuous equipped with the second memory bubble, and second
The continuous shape of memory bubble is corresponding with the shape on ovum type convex surface；Waist corresponds on the side on the inside of human foot in the insole
It is arranged with the convex grain of 30~50 upper flats；Round convex surface, the round convex surface are equipped on the upside of the middle part of the insole heel
Equipped with 5~10 followed by spiral grooves, third memory bubble silk floss is equipped on the downside of the middle part of the insole heel, third memory bubble is continuous
Shape it is corresponding with the shape on round convex surface.
3. snowfield sport shoe-pad according to claim 2, it is characterised in that：It is arranged with 80 on the upside of the insole half sole~
The convex grain of 110 upper flats, the convex surfaces side Luan Xing are equipped with 13~22 pad heart spiral grooves, the shoes to the insole pad in the heart
The convex grain of 35~45 upper flats is arranged in pad on the side of waist corresponded on the inside of human foot；In the insole heel
Round convex surface on the upside of portion is equipped with 6~9 followed by spiral grooves, the pad heart spiral grooves and followed by spiral grooves diameter
For 0.3~0.6mm.
4. snowfield sport shoe-pad according to claim 1, it is characterised in that：The thickness of the breathable heat insulating layer be 0.5~
The thickness of 0.9 mm, the polyurethane foam layer are 3~6mm, and the fever layer thickness is 3.0~5.5mm, the plant fiber
The thickness of layer is 2.0~5.0mm.
5. snowfield sport shoe-pad according to claim 4, it is characterised in that：The thickness of the breathable heat insulating layer be 0.55~
The thickness of 0.80 mm, the polyurethane foam layer are 3.6~5.2mm, and the fever layer thickness is 4.0~5.0mm, the plant
The thickness of fibres layer is 2.50~4.52mm.
6. the snowfield sport shoe-pad according to any one of Claims 1 to 5, it is characterised in that：The breathable heat insulating layer
It is made of the raw material of following each component, -12 parts of nylon 8,6-9 parts of acrylic fibers, 9-15 parts of spandex, 5-7 parts of polypropylene fibre, 6-13 parts of acrylic fibers,
9-15 parts of polyvinyl, 5-7 parts of polyvinyl alcohol, 8-12 parts of isocyanates, the breathable heat insulating layer are modified made from the above raw material
Fibrous layer.
7. the snowfield sport shoe-pad according to any one of Claims 1 to 5, it is characterised in that：The polyurethane foam
Layer includes pure layer of polyurethane and the flexible polyurethane alveolar layer containing medicinal powder, and the flexible polyurethane alveolar layer is polyurethane foam material,
Medicinal powder is Radix Angelicae Sinensis medicinal powder and Radix Notoginseng powder, and the weight ratio of Radix Angelicae Sinensis medicinal powder and Radix Notoginseng powder is 0.6:1；
The flexible polyurethane alveolar layer is made of the following raw material reaction foaming：100 parts of polyether polyol, isophorone diisocyanate
10~15 parts of ester, 2~3 parts of water, 0.5~3 part of silicone oil, 0.9~3 part of dichloromethane, 0.2~1 part of catalyst, foaming agent 0.5~1
Part, 0.5~1 part of crosslinking agent；
The preparation method of the flexible polyurethane alveolar layer is：By the polyether polyol and isophorone diisocyanate of corresponding parts by weight
Ester is added in mixer and stirs evenly, and is heated to 35~38 degrees Celsius, other raw materials of corresponding number are added to mixing
In device, high-speed stirred is poured into after 6~8 seconds after mold foams and cure, and corresponding flexible polyurethane alveolar layer is obtained；The polyethers is more
The hydroxyl value of first alcohol is 50~85mgKOH/g, and molecular weight is 8000~10000, and the silicone oil is two germplasm of BF-2370 and B-4900
Amount is than being 2-5：1 mixture；The catalyst is N, N- dimethylaminoethyl-N- methyl amino ethanols and acetylacetone,2,4-pentanedione zirconium matter
Amount is than being 0.5-1：1 mixture；The foaming agent is normal octane；Crosslinking agent is three kinds of ethylenediamine, triethylene glycol and dipropylene glycol
Mixture.
8. the snowfield sport shoe-pad according to any one of Claims 1 to 5, it is characterised in that：The heating layer is carbon
Fiber heating layer, the carbon fiber heating layer are the inorganic high-performance fiber that carbon amounts is higher than 95%.
9. the snowfield sport shoe-pad according to any one of Claims 1 to 5, it is characterised in that：The plant fiber layer
Preparation method be：
（1）Prepare zein fiber yarn；
（2）Lavender micro-capsule is prepared with complex coacervation；
（3）Make Lavender sustained release-soybean fiber；
（4）Woven fabric：
Using step（1）Zein fiber yarn obtained makees warp, step（3）Lavender sustained release-soybean protein obtained
Fiber makees weft, and fabric is formed using conventional woven fabric method woven fabric；（4）Surface applies warming dose, and plant fiber layer is made；
Described warming dose composed of the following components：108 parts of waterglass, 30 parts of ethylene glycol monomethyl ether acetate, 36 parts of prodan,
42 parts of barium sulfate, 18 parts of formaldehyde, 48 parts of flake asbestos, 20 parts of ammonium polyphosphate, 15 parts of triethylenediamine；Warming dose of the preparation method
For：By 108 parts of waterglass, 30 parts of ethylene glycol monomethyl ether acetate, 36 parts of prodan, 42 parts of barium sulfate, 18 parts of formaldehyde, asbestos
It in 15 parts of 48 parts of powder, 20 parts of ammonium polyphosphate, triethylenediamine addition reaction kettles, stirs evenly, is made warming dose.
10. the snowfield sport shoe-pad according to any one of Claims 1 to 5, it is characterised in that：The first memory bubble
It is continuous, the second memory bubble is continuous and third memory bubble is continuous made of the following raw material reaction foaming：100 parts of polyether polyol, diethyl
5~15 parts of hydramine, 1-3 parts of triethylenediamine, double-（Dimethyl aminoethyl）0.1-0.2 parts of ether, 2~4 parts of water, silicone oil 0.5~3
Part, 0.2~1 part of dibutyl tin laurate, 0.5~1 part of foaming agent, 0.3~3 part of catalyst；
The first memory bubble is continuous, the second memory steeps the continuous preparation method of continuous and third memory bubble and is：By corresponding parts by weight
Polyether polyol, diethanol amine, triethylenediamine, double-（Dimethyl aminoethyl）Ether, water, silicone oil, dibutyl tin laurate,
Foaming agent, catalyst are added in mixer and stir evenly, and 45-50 degrees Celsius are heated to, by other raw materials of corresponding number
It is added in mixer, high-speed stirred is poured into after 6~8 seconds after mold foams and cure, and obtains remembering foam sponge layer accordingly；Institute
State polyether polyol hydroxyl value be 53.5~58.5mgKOH/g, molecular weight be 8000~10000, the silicone oil be BF-2370 and
Two kinds of mass ratioes of B-4900 are 3：1 mixture；The catalyst is N, N- dimethylaminoethyl-N- methyl amino ethanols and second
Acyl acetone zirconium mass ratio is 0.5：1 mixture；The foaming agent is normal heptane.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810384393.9A CN108634480B (en) | 2018-04-26 | 2018-04-26 | Sports shoe-pad for snowfield |
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|---|---|---|---|
| CN201810384393.9A CN108634480B (en) | 2018-04-26 | 2018-04-26 | Sports shoe-pad for snowfield |
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| CN107440231A (en) * | 2017-07-04 | 2017-12-08 | 东莞市顺风运动器材有限公司 | A kind of strenuous exercise protects shoe-pad |
| US20180000196A1 (en) * | 2016-06-30 | 2018-01-04 | Boot Royalty Company, L.P. | Comfort system for boots |
| US20180084865A1 (en) * | 2016-09-28 | 2018-03-29 | Te-Wei TANG | Insole |
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| CN105780250A (en) * | 2014-12-13 | 2016-07-20 | 南通建伟色织服装有限公司 | Warm-keeping fabric |
| CN205409920U (en) * | 2016-03-23 | 2016-08-03 | 四川东瑞仁兴环保科技有限公司 | Health preserving shoe -pad generates heat |
| US20180000196A1 (en) * | 2016-06-30 | 2018-01-04 | Boot Royalty Company, L.P. | Comfort system for boots |
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