CN108685268A - A kind of running Special shoe pad - Google Patents
A kind of running Special shoe pad Download PDFInfo
- Publication number
- CN108685268A CN108685268A CN201810484053.3A CN201810484053A CN108685268A CN 108685268 A CN108685268 A CN 108685268A CN 201810484053 A CN201810484053 A CN 201810484053A CN 108685268 A CN108685268 A CN 108685268A
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- Prior art keywords
- insole
- parts
- waist
- heel
- upside
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Classifications
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
- A43B17/003—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined characterised by the material
- A43B17/006—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined characterised by the material multilayered
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
- A43B17/02—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined wedge-like or resilient
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a kind of running Special shoe pads, including insole body, from the front end of insole body to rear end, include waist and insole heel in insole half sole, the insole pad heart, insole successively, 3~8 male-type horizontal stripes are arranged on the upside of insole half sole, the downside of the rear end of insole half sole is equipped with half sole beam;The upside that insole pads the heart is equipped with ovum type convex surface, and ovum type convex surface, which is equipped with, pads heart spiral grooves, and the downside that insole pads the heart is equipped with memory bubble silk floss;Waist both sides up tilt respectively in insole, are arranged with the convex grain of ovum type of 20~60 upper flats in insole on the upside of waist;Round convex surface is equipped on the upside of the middle part of insole heel, the outer of insole heel up tilts, and tilting height is identical as the tilting height of waist both sides in insole, and back heel shock-absorbing pad is equipped on the downside of the middle part of insole heel.Damping shield foot effect of the present invention is strong, can radiate in time, alleviate medicine, skid resistance is good, can prevent ankle injury, health care massage, durable.
Description
Technical field
The present invention relates to a kind of insole, more particularly to a kind of running Special shoe pad.
Background technology
Insole be apply very universal articles for daily use, by effect point, insole can be divided into health insoles, functional insole and often
Advise insole.The structure of traditional sock is that the sewing of multilayer cloth is suppressed into either multilayer leather, has centainly soft
Softness and shock absorbing effect substantially conform to the demand of usual stroll wear shoes.However, it is desirable to when road-work, traditional sock is then
It is not applicable, it has as a drawback that:One, damping, shield foot effect are poor, when movement, foot's half sole and followed by bottom impact force it is big,
Traditional sock is difficult to absorb the impact force for generating foot bones in walking, motion process, it is difficult to protect vola bone, ankle-joint
And knee joint;Secondly, skid resistance it is poor, be unfavorable for toe stretching, extension, grab ground;Thirdly, traditional sock poor air permeability, be easy to grow thin
Bacterium, fungi are also easy to produce the foot problems such as tinea pedis;Four, effect of the traditional sock without package foot, during strenuous exercise,
It cannot prevent the joint displacements in motion process;Five, traditional sock is without heat sinking function, and when long-time is run, foot needs
It timely radiates, traditional sock cannot meet such demand;Six, traditional sock do not have health care massage act on and it is not sufficiently strong
It is durable, short life;It does not use memory bubble silk floss in existing insole substantially seven, even if having individually using memory bubble silk floss, but does not have
It is used for promoting blood circulation using cape jasmine pollen etc., the functions such as resistance building.
Invention content
The technical problem to be solved by the present invention is in view of the above shortcomings of the prior art, provide a kind of damping shield foot effect
By force, it can radiate in time, alleviate medicine, skid resistance is good, can prevent ankle injury, health care massage, and durable running is special
Use insole.
In order to solve the above technical problems, the technical scheme is that:A kind of running Special shoe pad, including insole body,
From the front end of insole body to rear end, exist successively including waist in insole half sole, the insole pad heart, insole and insole heel, feature
In:3~8 male-type horizontal stripes are arranged on the upside of the insole half sole, the width of the male-type horizontal stripe is 3~15.5mm,
The downside of the rear end of the insole half sole is equipped with half sole beam;The upside of the insole pad heart is equipped with ovum type convex surface, and ovum type is convex
Face is equipped with pad heart spiral grooves, and the downside of the insole pad heart is continuous equipped with memory bubble, and continuous shape and ovum type convex surface are steeped in memory
Shape it is corresponding;The both sides of waist up tilt respectively in the insole, and are arranged with 20~60 tops in insole on the upside of waist
The smooth convex grain of ovum type in portion;Round convex surface is equipped on the upside of the middle part of the insole heel, the outer of the insole heel is past to be upwarped
It rises, tilting height is identical as the tilting height of waist both sides in insole, and back heel shock-absorbing is equipped on the downside of the middle part of the insole heel
Pad, the shape of back heel shock-absorbing pad are corresponding with the shape on round convex surface.
As being expanded on further for the present invention:
Preferably, it is arranged with 3~6 male-type horizontal stripes on the upside of the insole half sole, the width of the male-type horizontal stripe is 5~
10.5mm;The convex grain of ovum type of 30~50 upper flats is arranged in the insole on the upside of waist.
Preferably, the insole body from top to bottom successively include nanometer bamboo carbon fiber layer, the first PU polyurethane foams layer,
2nd PU polyurethane foams layer and plant fiber layer, the 2nd PU polyurethane foam layers include in insole heel and insole
The latter half of waist, plant fiber layer rest part in addition to waist in insole lacks, and the plant fiber layer is equipped with and passes through
30~70 air holes of wear shoes pad body;The thickness of the nanometer bamboo carbon fiber layer is 0.25~0.8mm, and the first PU is poly-
The thickness of urethane foam sponge layer is 4~7mm, and the thickness of the 2nd PU polyurethane foam layers is 4~7mm, the plant fiber layer
Thickness be 0.3~0.9mm.
Preferably, it is respectively equipped with preceding accommodating cavity, middle accommodating cavity on the downside of the first PU polyurethane foam layers, described second
The downside of PU polyurethane foam layers is equipped with rear accommodating cavity, before the half sole beam is set in accommodating cavity, the continuous edge of memory bubble
In in middle accommodating cavity, the back heel shock-absorbing pad is set in rear accommodating cavity.
Preferably, it is that polyetherurethane foam bubble is continuous that the memory bubble is continuous;The half sole beam and back heel shock-absorbing pad
Thickness be respectively 2.5~10.5mm, the continuous thickness of the memory bubble is 3~6mm.
Preferably, the memory bubble is continuous made of the following raw material reaction foaming:100 parts of polyether polyol, 4,4 '-two
5~15 parts of methylenebis phenyl isocyanate, 5~10 parts of poly-succinic ethylene glycol binaryglycol ester, 2,4- toluene di-isocyanate(TDI)s
15~20 parts, 10~15 parts of diphenylmethylene diisocyanate, 5~10 parts of diisononyl phthalate, hexamethylene 1,2-
8~15 parts of dioctyl phthalate dinonyl, 1~3 part of cape jasmine pollen, 2~3 parts of water, 0.5~1.5 part of silicone oil, 0.2~1 part of catalyst,
0.5~1 part of foaming agent, 2~5 parts of crosslinking agent, 2~5 parts of heat sink material;The hydroxyl value of the polyether polyol is 50~90
MgKOH/g, molecular weight are 8000~10000, and the silicone oil is BF-2370 and two kinds of mass ratioes of L-5309 are 2:1 mixture,
The catalyst be tetramethyl dipropylenetriamine with it is double(Dimethylamino-propyl)Isopropanolamine 1:1 mixture;The foaming agent
For normal heptane;Crosslinking agent be ethylenediamine, three kinds of triethylene glycol and dipropylene glycol mixture, the heat sink material be selected from aluminium oxide,
Zinc oxide or titanium oxide.
Preferably, the preparation method for remembering foam sponge layer is:By the polyether polyol of corresponding parts by weight, 4,4 '-diphenyl
Methane diisocyanate, poly-succinic ethylene glycol binaryglycol ester, 2,4- toluene di-isocyanate(TDI)s, two isocyanide of diphenylmethylene
Acid esters, diisononyl phthalate, hexamethylene 1,2- dioctyl phthalate dinonyl, cape jasmine pollen are added in mixer and stir
It is even, 35~38 degrees Celsius are heated to, other raw materials of corresponding number are added in mixer, high-speed stirred waits for temperature
It rises to 80 DEG C, stops stirring, 5 min of vacuumizing and defoaming is poured into after mold foam and cure, and 3~5h of curing, obtains at 110 DEG C
It is continuous to corresponding memory bubble.
Preferably, the nanometer bamboo carbon fiber layer is fine by bamboo charcoal fiber, nano silver fibre, monocrystalline sapphire whisker and viscose glue
Dimension composition;Contain 0.8-1% ceramic powders and coupling agent in viscose rayon, coupling agent is the 0.1-0.3% of ceramic powders weight;Pottery
Porcelain powder is made of the ingredient of following parts by weight:50-60 parts of zirconium dioxide, 35-40 parts of silica, manganese dioxide 5-15
Part;Coupling agent is 1,1- diperoxy tertiary butyls, 4- hydroxycyclohexans and tetraethoxysilane by weight 1:Made from 1.
Preferably, the preparation method of the viscose rayon is:
(1), zirconium dioxide, silica and manganese dioxide mixed, it is 1-2 μm of ceramics to be crushed to average grain diameter after sintering
Powder;
(2), coupling agent mixed with the ceramic powders, obtain modified ceramic powder;
(3), by the modified ceramic powder and viscose glue blending, squeeze out, slice, viscose glue slice be made;
(4), by the viscose glue be sliced heating melting, squeeze, spinneret molding, you can be made viscose rayon.
Preferably, the preparation method of the nanometer bamboo carbon fiber layer is:
(1), bamboo charcoal fiber, nano silver fibre, monocrystalline sapphire whisker and viscose rayon be uniformly mixed, dispersant, viscous is added
Knot agent, softening agent are stirred, and dry processing;
(2), step will be passed through(1)The fiber of processing is handled through rove, spun yarn, automatic winding, yarn steaming, high speed doubling, double twisting
To spun yarn;
(3), weaved using cassimere twill;
(4), to fabric carry out washing process, water temperature control at 35-38 DEG C, wash 5-8min;
(5), adjustment pH value to 5-7, be warming up to 80 DEG C, then impregnate 50 minutes, dry, cut obtained nanometer bamboo carbon fiber layer.
The beneficial effects of the invention are as follows:One, damping, shield foot, since the downside of insole half sole and insole heel is set respectively
There is beam, therefore, insole elasticity is good, and hardness is moderate, can effectively absorb in walking, motion process and be rushed to foot bones generation
Hit power, protection vola bone, ankle-joint and knee joint;Secondly, alleviate medicine, the present invention according to principle of human engineering,
Insole pads center portion position setting ovum type convex surface, is bonded arch portion, sole center of gravity is redistributed, full sole stress equalization is made, alleviate
It moves, walk, generated stress fatigue of standing, insole pad heart downside, which is equipped with, remembers bubble silk floss, and remembering bubble silk floss has outstanding note
Recall function, original form, and good permeability can be restored after deformation rapidly;Thirdly, stablize it is anti-skidding, it is low early and high after, it is outer thickness in it is thin,
Gravity leans forward so that toe has the activity space of bigger, and 3~8 male-type horizontal stripes are arranged on the upside of insole half sole, is conducive to foot
Toe stretches, with grabbing, and the convex grain of waist and pad heart spiral grooves design, significantly enhance frictional force, reduce motion process in insole
In rear cunning and sideslip, so that biped is more balanced, support body more balance;Four, prevent ankle injury, middle waist both sides thicken packet
It encloses, wraps up foot, the joint displacements in motion process can be prevented, prevent to turn up, sprain the ankle situation, effectively reduce podarthrum meaning
The risk of outer injury;Five, health care massage, insole pad center portion position are provided with the ovum type convex surface of spiral grooves, can massage arch of the foot
Acupuncture point effectively facilitates vola blood circulation, and the downside continuous cape jasmine pollen used of memory bubble, which has, to promote blood circulation, enhances resistance
The function of power;Heat sink material is added during six, memory bubble is continuous, insole body can be effectively and timely distributed and be produced during running
Raw heat, the tetramethyl dipropylenetriamine used in the continuous production process of memory bubble with it is double(Dimethylamino-propyl)Isopropanolamine is urged
Agent can promote surface cure for reactivity gel catalyst, have low sporadic so that memory bubble is continuous with more outstanding
Memory function;Seven, the special preparation method of nanometer bamboo carbon fiber layer makes insole that there is stronger self-cleaning function and deodorization to imitate
Fruit, and there is anti-inflammatory analgetic, relieve fatigue and prevent spur and other effects, the crosslinking agent used in manufacturing process makes insole
Ontology has the characteristics that intensity higher, durability are stronger and the service life is longer;Eight, bamboo charcoal fiber is to take moso bamboo for raw material,
Use pure oxygen high temperature and the calcining new process and new technology of nitrogen barrier delay so that the micropore that bamboo charcoal innately has more refines
With honeycomb, then again with honeycomb microporous structure trend polyester modification slice melt spinning and it is manufactured.It is this only
Special fibre structure design has the characteristics that moisture absorption breathes freely, is bacteriostasis antibiosis, cool in summer and warm in winter, environmentally protective.
Description of the drawings
Fig. 1 is the dispersed structure schematic diagram one of the present invention.
Fig. 2 is the dispersed structure schematic diagram two of the present invention.
In figure:1. insole half sole;2. insole pads the heart;3. waist in insole;4. insole heel;5. male-type horizontal stripe;6. half sole
Beam;7. ovum type convex surface;8. padding heart spiral grooves;9. memory bubble is continuous;10. the convex grain of ovum type;11. back heel shock-absorbing pad;12. nanometer
Bamboo;13. the first PU polyurethane foam layers;14. the 2nd PU polyurethane foam layers;15. plant fiber layer;16. ventilative
Hole.
Specific implementation mode
Xia Mianjiehefutuduibenfamingjiegouyuanlihegongzuoyuanlizuojinyibuxiangxishuoming.
As shown in Figure 1 and Figure 2, the present invention is a kind of running Special shoe pad, including insole body, from the front end of insole body
Include waist 3 and insole heel 4 in insole half sole 1, the insole pad heart 2, insole successively to rear end, it is characterised in that:Before the insole
The upside of the palm 1 is arranged with 3~8 male-type horizontal stripes 5, and the width of the male-type horizontal stripe 5 is 3~15.5mm, before the insole
The downside of the rear end of the palm 1 is equipped with half sole beam 6;The upside of the insole pad heart 2 is equipped with ovum type convex surface 7, is set on ovum type convex surface 7
There are pad heart spiral grooves 8, the downside of the insole pad heart 2 to be equipped with memory bubble silk floss 9, the shape of memory bubble silk floss 9 and ovum type convex surface 7
Shape is corresponding;The both sides of waist 3 up tilt respectively in the insole, and the upside of waist 3 is arranged with 20~60 tops in insole
The convex grain of the smooth ovum type in portion 10;Round convex surface is equipped on the upside of the middle part of the insole heel 4(It is not shown in figure), after the insole
Outer with 4 up tilts, and tilts height, the middle part of the insole heel 4 identical as the tilting height of 3 both sides of waist in insole
Downside is equipped with back heel shock-absorbing pad 11, and the shape of back heel shock-absorbing pad 11 is corresponding with the shape on round convex surface.
As shown in Figure 1 and Figure 2, the upside of the insole half sole 1 is arranged with 3~6 male-type horizontal stripes 5, and the male-type is horizontal
The width of item 5 is 5~10.5mm;The upside of waist 3 is arranged with the convex grain of ovum type 10 of 30~50 upper flats in the insole.
As shown in Figure 1 and Figure 2, the insole body includes nanometer bamboo carbon fiber layer 12, the first poly- ammonia of PU successively from top to bottom
Ester foam sponge layer 13, the 2nd PU polyurethane foams layer 14 and plant fiber layer 15, the 2nd PU polyurethane foams layer 14 include
The latter half of waist 3 in insole heel 4 and insole, the plant fiber layer 15 except the outer rest part of waist 3 missing in insole, and
The plant fiber layer 15 is equipped with 30~70 air holes 16 through insole body;The thickness of the nanometer bamboo carbon fiber layer 12
Degree is 0.25~0.8mm, and the thickness of the first PU polyurethane foams layer 13 is 4~7mm, the 2nd PU polyurethane foam layers
14 thickness is 4~7mm, and the thickness of the plant fiber layer 15 is 0.3~0.9mm.
As shown in Figure 1 and Figure 2, the downside of the first PU polyurethane foams layer 13 is respectively equipped with preceding accommodating cavity(Do not show in figure
Go out), middle accommodating cavity(It is not shown in figure), the downside of the 2nd PU polyurethane foams layer 14 is equipped with rear accommodating cavity(Do not show in figure
Go out), before the half sole beam 6 is set in accommodating cavity, the memory bubble silk floss 9 is set in middle accommodating cavity, the back heel shock-absorbing pad
11 are set in rear accommodating cavity.
As shown in Figure 1 and Figure 2, the memory bubble silk floss 9 is continuous for polyetherurethane foam bubble;The half sole beam 6 and after
Thickness with beam 11 is respectively 2.5~10.5mm, and the thickness of the memory bubble silk floss 9 is 3~6mm.
It is material prescription and process example below.
Embodiment 1
The memory bubble silk floss 9 is made of the following raw material reaction foaming:100 parts of polyether polyol, 4,4 '-diphenyl methanes two
5 parts of isocyanates, 5 parts of poly-succinic ethylene glycol binaryglycol ester, 2,4- 15 parts of toluene di-isocyanate(TDI)s, diphenylmethylene two
10 parts of isocyanates, 5 parts of diisononyl phthalate, hexamethylene 1,8 parts of 2- dioctyl phthalate dinonyl, 1 part of cape jasmine pollen, water
2 parts, 0.5 part of silicone oil, 0.2 part of catalyst, 0.5 part of foaming agent, 2 parts of crosslinking agent, 2 parts of heat sink material;The polyether polyol
Hydroxyl value is 50~90 mgKOH/g, and molecular weight is 8000~10000, and the silicone oil is two kinds of mass ratioes of BF-2370 and L-5309
It is 2:1 mixture, the catalyst be tetramethyl dipropylenetriamine with it is double(Dimethylamino-propyl)Isopropanolamine 1:1 mixing
Object;The foaming agent is normal heptane;Crosslinking agent is the mixture of ethylenediamine, three kinds of triethylene glycol and dipropylene glycol, the heat dissipation material
Material is selected from aluminium oxide, zinc oxide or titanium oxide.
Continuous 9 layers of preparation method is steeped in memory:By the polyether polyol of corresponding parts by weight, 4,4 '-diphenyl methanes two
Isocyanates, poly-succinic ethylene glycol binaryglycol ester, 2,4- toluene di-isocyanate(TDI)s, diphenylmethylene diisocyanate,
Diisononyl phthalate, hexamethylene 1,2- dioctyl phthalate dinonyl, cape jasmine pollen are added in mixer and stir evenly, heats
35~38 degrees Celsius are warming up to, other raw materials of corresponding number are added in mixer, high-speed stirred waits for that temperature rises to 80
DEG C, stop stirring, 5 min of vacuumizing and defoaming is poured into after mold foam and cure, 3~5h is cured at 110 DEG C, is obtained accordingly
Memory bubble silk floss 9.
The nanometer bamboo carbon fiber layer 12 is by bamboo charcoal fiber, nano silver fibre, monocrystalline sapphire whisker and viscose rayon group
At;Contain 0.8% ceramic powders and coupling agent in viscose rayon, coupling agent is the 0.1% of ceramic powders weight;Ceramic powders are by such as
The ingredient of lower parts by weight is made:50 parts of zirconium dioxide, 35 parts of silica, 5 parts of manganese dioxide;Coupling agent is bis- mistakes of 1,1-
Aoxidize tertiary butyl, 4- hydroxycyclohexans and tetraethoxysilane by weight 1:Made from 1.
The preparation method of the viscose rayon is:
(1), zirconium dioxide, silica and manganese dioxide mixed, it is 1-2 μm of ceramics to be crushed to average grain diameter after sintering
Powder;
(2), coupling agent mixed with the ceramic powders, obtain modified ceramic powder;
(3), by the modified ceramic powder and viscose glue blending, squeeze out, slice, viscose glue slice be made;
(4), by the viscose glue be sliced heating melting, squeeze, spinneret molding, you can be made viscose rayon.
The preparation method of the nanometer bamboo carbon fiber layer 12 is:
(1), bamboo charcoal fiber, nano silver fibre, monocrystalline sapphire whisker and viscose rayon be uniformly mixed, dispersant, viscous is added
Knot agent, softening agent are stirred, and dry processing;
(2), step will be passed through(1)The fiber of processing is handled through rove, spun yarn, automatic winding, yarn steaming, high speed doubling, double twisting
To spun yarn;
(3), weaved using cassimere twill;
(4), to fabric carry out washing process, water temperature control at 35-38 DEG C, wash 5-8min;
(5), adjustment pH value to 5-7, be warming up to 80 DEG C, then impregnate 50 minutes, dry, cut obtained nanometer bamboo carbon fiber layer
12。
Embodiment 2
The memory bubble silk floss 9 is made of the following raw material reaction foaming:100 parts of polyether polyol, 4,4 '-diphenyl methanes two
15 parts of isocyanates, 10 parts of poly-succinic ethylene glycol binaryglycol ester, 2,4- 20 parts of toluene di-isocyanate(TDI)s, diphenylmethylene
15 parts of diisocyanate, 10 parts of diisononyl phthalate, 15 parts of hexamethylene 1,2- dioctyl phthalate dinonyl, cape jasmine pollen 3
Part, 3 parts of water, 1.5 parts of silicone oil, 1 part of catalyst, 1 part of foaming agent, 5 parts of crosslinking agent, 5 parts of heat sink material;The polyether polyol
Hydroxyl value is 50~90 mgKOH/g, and molecular weight is 8000~10000, and the silicone oil is two kinds of mass ratioes of BF-2370 and L-5309
It is 2:1 mixture, the catalyst be tetramethyl dipropylenetriamine with it is double(Dimethylamino-propyl)Isopropanolamine 1:1 mixing
Object;The foaming agent is normal heptane;Crosslinking agent is the mixture of ethylenediamine, three kinds of triethylene glycol and dipropylene glycol, the heat dissipation material
Material is selected from aluminium oxide, zinc oxide or titanium oxide.
Continuous 9 layers of preparation method is steeped in memory:By the polyether polyol of corresponding parts by weight, 4,4 '-diphenyl methanes two
Isocyanates, poly-succinic ethylene glycol binaryglycol ester, 2,4- toluene di-isocyanate(TDI)s, diphenylmethylene diisocyanate,
Diisononyl phthalate, hexamethylene 1,2- dioctyl phthalate dinonyl, cape jasmine pollen are added in mixer and stir evenly, heats
35~38 degrees Celsius are warming up to, other raw materials of corresponding number are added in mixer, high-speed stirred waits for that temperature rises to 80
DEG C, stop stirring, 5 min of vacuumizing and defoaming is poured into after mold foam and cure, 3~5h is cured at 110 DEG C, is obtained accordingly
Memory bubble silk floss 9.
The nanometer bamboo carbon fiber layer 12 is by bamboo charcoal fiber, nano silver fibre, monocrystalline sapphire whisker and viscose rayon group
At;Contain 1% ceramic powders and coupling agent in viscose rayon, coupling agent is the 0.3% of ceramic powders weight;Ceramic powders are by as follows
The ingredient of parts by weight is made:60 parts of zirconium dioxide, 40 parts of silica, 15 parts of manganese dioxide;Coupling agent is 1,1- diperoxies
Change tertiary butyl, 4- hydroxycyclohexans and tetraethoxysilane by weight 1:Made from 1.
The preparation method of the viscose rayon is:
(1), zirconium dioxide, silica and manganese dioxide mixed, it is 1-2 μm of ceramics to be crushed to average grain diameter after sintering
Powder;
(2), coupling agent mixed with the ceramic powders, obtain modified ceramic powder;
(3), by the modified ceramic powder and viscose glue blending, squeeze out, slice, viscose glue slice be made;
(4), by the viscose glue be sliced heating melting, squeeze, spinneret molding, you can be made viscose rayon.
The preparation method of the nanometer bamboo carbon fiber layer 12 is:
(1), bamboo charcoal fiber, nano silver fibre, monocrystalline sapphire whisker and viscose rayon be uniformly mixed, dispersant, viscous is added
Knot agent, softening agent are stirred, and dry processing;
(2), step will be passed through(1)The fiber of processing is handled through rove, spun yarn, automatic winding, yarn steaming, high speed doubling, double twisting
To spun yarn;
(3), weaved using cassimere twill;
(4), to fabric carry out washing process, water temperature control at 35-38 DEG C, wash 5-8min;
(5), adjustment pH value to 5-7, be warming up to 80 DEG C, then impregnate 50 minutes, dry, cut obtained nanometer bamboo carbon fiber layer
12。
Embodiment 3
The memory bubble silk floss 9 is made of the following raw material reaction foaming:100 parts of polyether polyol, 4,4 '-diphenyl methanes two
12 parts of isocyanates, 8 parts of poly-succinic ethylene glycol binaryglycol ester, 2,4- 18 parts of toluene di-isocyanate(TDI)s, diphenylmethylene
13 parts of diisocyanate, 8 parts of diisononyl phthalate, 12 parts of hexamethylene 1,2- dioctyl phthalate dinonyl, cape jasmine pollen 2.5
Part, 2.5 parts of water, 1 part of silicone oil, 0.8 part of catalyst, 0.7 part of foaming agent, 3.5 parts of crosslinking agent, 4 parts of heat sink material;The polyethers is more
The hydroxyl value of first alcohol is 50~90 mgKOH/g, and molecular weight is 8000~10000, and the silicone oil is BF-2370 and two kinds of L-5309
Mass ratio is 2:1 mixture, the catalyst be tetramethyl dipropylenetriamine with it is double(Dimethylamino-propyl)Isopropanolamine 1:1
Mixture;The foaming agent is normal heptane;Crosslinking agent is the mixture of ethylenediamine, three kinds of triethylene glycol and dipropylene glycol, described
Heat sink material is selected from aluminium oxide, zinc oxide or titanium oxide.
Continuous 9 layers of preparation method is steeped in memory:By the polyether polyol of corresponding parts by weight, 4,4 '-diphenyl methanes two
Isocyanates, poly-succinic ethylene glycol binaryglycol ester, 2,4- toluene di-isocyanate(TDI)s, diphenylmethylene diisocyanate,
Diisononyl phthalate, hexamethylene 1,2- dioctyl phthalate dinonyl, cape jasmine pollen are added in mixer and stir evenly, heats
35~38 degrees Celsius are warming up to, other raw materials of corresponding number are added in mixer, high-speed stirred waits for that temperature rises to 80
DEG C, stop stirring, 5 min of vacuumizing and defoaming is poured into after mold foam and cure, 3~5h is cured at 110 DEG C, is obtained accordingly
Memory bubble silk floss 9.
The other structures component of insole is that current material is obtained by commonsense method.
Embodiment 4
The nanometer bamboo carbon fiber layer 12 is made of bamboo charcoal fiber, nano silver fibre, monocrystalline sapphire whisker and viscose rayon;It is viscous
Contain 0.9% ceramic powders and coupling agent in glue fiber, coupling agent is the 0.25% of ceramic powders weight;Ceramic powders by weighing as follows
The ingredient of amount number is made:58 parts of zirconium dioxide, 38 parts of silica, 12 parts of manganese dioxide;Coupling agent is 1,1- diperoxies
Tertiary butyl, 4- hydroxycyclohexans and tetraethoxysilane by weight 1:Made from 1.
The preparation method of the viscose rayon is:
(1), zirconium dioxide, silica and manganese dioxide mixed, it is 1-2 μm of ceramics to be crushed to average grain diameter after sintering
Powder;
(2), coupling agent mixed with the ceramic powders, obtain modified ceramic powder;
(3), by the modified ceramic powder and viscose glue blending, squeeze out, slice, viscose glue slice be made;
(4), by the viscose glue be sliced heating melting, squeeze, spinneret molding, you can be made viscose rayon.
The preparation method of the nanometer bamboo carbon fiber layer 12 is:
(1), bamboo charcoal fiber, nano silver fibre, monocrystalline sapphire whisker and viscose rayon be uniformly mixed, dispersant, viscous is added
Knot agent, softening agent are stirred, and dry processing;
(2), step will be passed through(1)The fiber of processing is handled through rove, spun yarn, automatic winding, yarn steaming, high speed doubling, double twisting
To spun yarn;
(3), weaved using cassimere twill;
(4), to fabric carry out washing process, water temperature control at 35-38 DEG C, wash 5-8min;
(5), adjustment pH value to 5-7, be warming up to 80 DEG C, then impregnate 50 minutes, dry, cut obtained nanometer bamboo carbon fiber layer
12。
The other structures component of insole is that current material is obtained by commonsense method.
The memory bubble of embodiment 5 is continuous same as Example 1, but uses common nanometer bamboo carbon fiber layer.
The memory bubble of embodiment 6 is continuous same as Example 2, but uses common nanometer bamboo carbon fiber layer.
The memory bubble of embodiment 7 is continuous same as Example 3, but uses common nanometer bamboo carbon fiber layer.
The nanometer bamboo carbon fiber layer of embodiment 8 is same as Example 1, but it is that conventional polyurethanes bubble is continuous that it is continuous, which to remember bubble,.
The nanometer bamboo carbon fiber layer of embodiment 9 is same as Example 4, but it is that conventional polyurethanes bubble is continuous that it is continuous, which to remember bubble,.
The memory of embodiment 10 is steeped tender nanometer bamboo carbon fiber layer and is made using common existing material and method.
By memory bubble made from above example 1-10, continuous, nanometer bamboo carbon fiber layer and other structures are assembled into insole,
It was found that the insole of embodiment 1-9 is strong compared to embodiment 10 its damping, shield foot, insole elasticity is good, and hardness is moderate, and it is tired to alleviate foot
Labor, good permeability is stablized anti-skidding more durable, and odor-resistant result is good, and with heat dissipation performance and promotes blood circulation and other effects;
Wherein, embodiment 3, embodiment 5, embodiment 6, embodiment 7 all have good heat dissipation performance and promote blood circulation, enhance and support
The function of drag, and the memory function for remembering foam is more outstanding, but its durable degree compares embodiment 4 with permeability
And embodiment 8-9 is slightly worse;Embodiment 4, embodiment 8, embodiment 9 have apparent bacteriostasis antibiosis, deodorization functions, and gas permeability is more
It is strong and more durable, but its heat dissipation performance and promote blood circulation and other effects slightly worse compared to embodiment 3, embodiment 5-7;
Embodiment 1 and embodiment 2 are placed 72 hours after wearing in 37 DEG C of incubators, 3 every square centimeter of detection bacterium content hereinafter, and
The testing result of embodiment 10 is every square centimeter at 20-30.
The above is only better embodiment of the present invention, and every technical solution according to the present invention is to above implementation
Any subtle modifications, equivalent variations and modifications, belong in the range of technical solution of the present invention made by mode.
Claims (10)
1. a kind of running Special shoe pad, including insole body, from the front end of insole body to rear end, include successively insole half sole,
Insole pads waist and insole heel in the heart, insole, it is characterised in that:3~8 male-type cross are arranged on the upside of the insole half sole
The width of item, the male-type horizontal stripe is 3~15.5mm, and the downside of the rear end of the insole half sole is equipped with half sole beam;Institute
The upside for stating the insole pad heart is equipped with ovum type convex surface, and ovum type convex surface is equipped with pad heart spiral grooves, is set on the downside of the insole pad heart
There is memory bubble continuous, the continuous shape of memory bubble is corresponding with the shape on ovum type convex surface;The both sides of waist are past respectively in the insole upwarps
It rises, and is arranged with the convex grain of ovum type of 20~60 upper flats in insole on the upside of waist;It is set on the upside of the middle part of the insole heel
There are round convex surface, the outer of the insole heel up to tilt, tilting height is identical as the tilting height of waist both sides in insole,
Back heel shock-absorbing pad is equipped on the downside of the middle part of the insole heel, the shape of back heel shock-absorbing pad is corresponding with the shape on round convex surface.
2. running Special shoe pad according to claim 1, it is characterised in that:It is arranged with 3~6 on the upside of the insole half sole
The width of male-type horizontal stripe, the male-type horizontal stripe is 5~10.5mm;30~50 are arranged in the insole on the upside of waist
The convex grain of ovum type of upper flat.
3. running Special shoe pad according to claim 1, it is characterised in that:The insole body includes successively from top to bottom
Nanometer bamboo carbon fiber layer, the first PU polyurethane foams layer, the 2nd PU polyurethane foams layer and plant fiber layer, the 2nd PU
Polyurethane foam layer includes the latter half of waist in insole heel and insole, the plant fiber layer in addition to waist in insole remaining
Excalation, and the plant fiber layer is equipped with 30~70 air holes through insole body;The nanometer bamboo carbon fiber
The thickness of layer is 0.25~0.8mm, and the thickness of the first PU polyurethane foam layers is 4~7mm, the 2nd PU polyurethane foams
The thickness of continuous layer is 4~7mm, and the thickness of the plant fiber layer is 0.3~0.9mm.
4. running Special shoe pad according to claim 3, it is characterised in that:The downside of the first PU polyurethane foam layers
It is respectively equipped with preceding accommodating cavity, middle accommodating cavity, the downside of the 2nd PU polyurethane foam layers is equipped with rear accommodating cavity, and the half sole subtracts
Before shake pad is set in accommodating cavity, the memory bubble silk floss is set in middle accommodating cavity, and the back heel shock-absorbing pad is set in rear accommodating cavity.
5. the running Special shoe pad according to any one of Claims 1 to 4, it is characterised in that:Silk floss is steeped in the memory
Polyetherurethane foam bubble is continuous;The thickness of the half sole beam and back heel shock-absorbing pad is respectively 2.5~10.5mm, the note
It is 3~6mm to recall the continuous thickness of bubble.
6. running Special shoe pad according to claim 1, it is characterised in that:Continuous reacted by the following raw material of memory bubble is sent out
It is brewed to:100 parts of polyether polyol, 4,4 ' -5~15 parts of methyl diphenylene diisocyanates, poly-succinic ethylene glycol diethyl
5~10 parts of diol ester, 2,4- 15~20 parts of toluene di-isocyanate(TDI)s, 10~15 parts of diphenylmethylene diisocyanate, adjacent benzene
5~10 parts of dioctyl phthalate dinonyl, hexamethylene 1,8~15 parts of 2- dioctyl phthalate dinonyl, 1~3 part of cape jasmine pollen, water 2~3
Part, 0.5~1.5 part of silicone oil, 0.2~1 part of catalyst, 0.5~1 part of foaming agent, 2~5 parts of crosslinking agent, 2~5 parts of heat sink material;
The hydroxyl value of the polyether polyol be 50~90 mgKOH/g, molecular weight be 8000~10000, the silicone oil be BF-2370 and
Two kinds of mass ratioes of L-5309 are 2:1 mixture, the catalyst be tetramethyl dipropylenetriamine with it is double(Dimethylamino-propyl)
Isopropanolamine 1:1 mixture;The foaming agent is normal heptane;Crosslinking agent is three kinds of ethylenediamine, triethylene glycol and dipropylene glycol
Mixture, the heat sink material are selected from aluminium oxide, zinc oxide or titanium oxide.
7. running Special shoe pad according to claim 6, it is characterised in that:Memory foam sponge layer preparation method be:By phase
The polyether polyol of parts by weight, 4,4 '-methyl diphenylene diisocyanates, poly-succinic ethylene glycol binaryglycol ester, 2 are answered,
4- toluene di-isocyanate(TDI)s, diphenylmethylene diisocyanate, diisononyl phthalate, hexamethylene 1,2- dioctyl phthalate two
Different nonyl ester, cape jasmine pollen are added in mixer and stir evenly, and 35~38 degrees Celsius are heated to, by other originals of corresponding number
Material is added in mixer, high-speed stirred, waits for that temperature rises to 80 DEG C, stops stirring, and 5 min of vacuumizing and defoaming pours into mold hair
After steeping and curing, 3~5h is cured at 110 DEG C, obtains remembering bubble silk floss accordingly.
8. running Special shoe pad according to claim 3, it is characterised in that:The nanometer bamboo carbon fiber layer is by bamboo charcoal fibre
Dimension, nano silver fibre, monocrystalline sapphire whisker and viscose rayon composition;Contain 0.8-1% ceramic powders and coupling in viscose rayon
Agent, coupling agent are the 0.1-0.3% of ceramic powders weight;Ceramic powders are made of the ingredient of following parts by weight:Zirconium dioxide
50-60 parts, 35-40 parts of silica, 5-15 parts of manganese dioxide;Coupling agent is 1,1- diperoxy tertiary butyls, 4- hydroxyl rings
Hexane and tetraethoxysilane by weight 1:Made from 1.
9. running Special shoe pad according to claim 8, it is characterised in that:The preparation method of the viscose rayon is:
(1), zirconium dioxide, silica and manganese dioxide mixed, it is 1-2 μm of ceramics to be crushed to average grain diameter after sintering
Powder;
(2), coupling agent mixed with the ceramic powders, obtain modified ceramic powder;
(3), by the modified ceramic powder and viscose glue blending, squeeze out, slice, viscose glue slice be made;
(4), by the viscose glue be sliced heating melting, squeeze, spinneret molding, you can be made viscose rayon.
10. running Special shoe pad according to claim 8, it is characterised in that:The preparation side of the nanometer bamboo carbon fiber layer
Method is:
(1), bamboo charcoal fiber, nano silver fibre, monocrystalline sapphire whisker and viscose rayon be uniformly mixed, dispersant, viscous is added
Knot agent, softening agent are stirred, and dry processing;
(2), step will be passed through(1)The fiber of processing is handled through rove, spun yarn, automatic winding, yarn steaming, high speed doubling, double twisting
To spun yarn;
(3), weaved using cassimere twill;
(4), to fabric carry out washing process, water temperature control at 35-38 DEG C, wash 5-8min;
(5), adjustment pH value to 5-7, be warming up to 80 DEG C, then impregnate 50 minutes, dry, cut obtained nanometer bamboo carbon fiber layer.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109463846A (en) * | 2018-10-31 | 2019-03-15 | 东莞东辉鞋材制品有限公司 | A kind of formula and preparation method of high rebound permeable shoe pads |
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Application publication date: 20181023 |