CN108716016A - A kind of surface treatment method of auto parts machinery - Google Patents

A kind of surface treatment method of auto parts machinery Download PDF

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Publication number
CN108716016A
CN108716016A CN201810624455.9A CN201810624455A CN108716016A CN 108716016 A CN108716016 A CN 108716016A CN 201810624455 A CN201810624455 A CN 201810624455A CN 108716016 A CN108716016 A CN 108716016A
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Prior art keywords
auto parts
parts machinery
surface treatment
parts
treatment method
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CN201810624455.9A
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CN108716016B (en
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毛泽楠
毛明光
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Ningbo Runnan Mechanical and Electrical Industry Co., Ltd.
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NINGBO MINGWANG AUTOMOBILE DECORATIONS CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • C25D11/12Anodising more than once, e.g. in different baths
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/026Anodisation with spark discharge
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • C25D11/06Anodisation of aluminium or alloys based thereon characterised by the electrolytes used
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • C25D11/06Anodisation of aluminium or alloys based thereon characterised by the electrolytes used
    • C25D11/08Anodisation of aluminium or alloys based thereon characterised by the electrolytes used containing inorganic acids
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • C25D11/16Pretreatment, e.g. desmutting
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • C25D11/18After-treatment, e.g. pore-sealing
    • C25D11/24Chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • C25D11/18After-treatment, e.g. pore-sealing
    • C25D11/24Chemical after-treatment
    • C25D11/246Chemical after-treatment for sealing layers

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Coating By Spraying Or Casting (AREA)

Abstract

The present patent application discloses a kind of auto parts machinery surface treatment method, it includes the following steps:1)Blasting treatment;2)Saponification;3)Differential arc oxidation processing;4)Anodic oxidation;5)Coloring;6)Sealing pores.The surface treatment method of the auto parts machinery of the present invention is easy to operation, through present invention process treated auto parts machinery case hardness, high, corrosion-resistant, resistance to oxidation, wear-resistant, resistance to resistance, good antirust property, resistance to temperature change are good, service life is long, can bring good economic benefit.

Description

A kind of surface treatment method of auto parts machinery
Technical field
The invention belongs to auto-parts production technical fields, are especially a kind of surface treatment method of auto parts machinery.
Background technology
Auto parts machinery is the part and accessory for constituting automobile, than matching if any engine fittings, braking system accessory, steering system Part, Running System accessory, electrical instrumentation system accessory, automobile lamp, automotive seat, vehicle body etc..It is largely metal in these accessories Plank, and sheet metal is in the prevalence of etching problem.Corrosion not only breaks up the appearance of automobile, also directly affects the use of automobile Service life, while the pollution of environment is brought, the generation of accident and the waste of material and the energy.For this purpose, the manufacture of auto parts machinery It all needs by Treatment of Metal Surface, the common surface treatment mode of automobile has:Electrochemical treatments(Plating and anodic oxidation);Application (Spraying, electrophoresis);Chemical treatment(Phosphatization, passivation, nigrescence);Heat treatment(Hot-dip, thermal spraying, hot stamping, thermo-chemical treatment Deng);Vacuum method(Evaporation plating, sputtering plating, ion plating etc.).Each processing method all cuts both ways, and when application should consider, Such as material cost, production process, process time, treatment effect, environmental pollution etc..After prior art handles auto parts machinery, There is crackle on surface, and coloring is not uneven lasting, corrosion resistant antiwear poor performance.The above problems need urgent solution.
Invention content
The technical problem to be solved by the invention is to provide a kind of surface treatment method of auto parts machinery, obtained vapour Vehicle accessory surface flawless, uniform coloring are lasting, wear-resistant corrosion-resistant.
Technical solution of the invention is as follows:A kind of surface treatment method of auto parts machinery, it includes the following steps:
1) blasting treatment:It uses compressed air for power, material spray is ejected into the surface of auto parts machinery, so that its surface is obtained certain Cleannes and different roughness;
2) saponification:The auto parts machinery of blasting treatment is put into aqueous soup solution, 25 ~ 35 DEG C of 2 ~ 4h of immersion form one layer of tristearin Sour iron thin film;
3) differential arc oxidation is handled:Auto parts machinery is put into electrolyte, is carried out with alternating current-direct current overlapping waveform constant-current mode micro- Arc oxidation processes form micro-arc oxidation films;The electrolyte is grouped as by the group of following weight ratio:Potassium hydroxide 1 ~ 3 Part, 2 ~ 4 parts of sodium metasilicate, 3 ~ 5 parts of tertiary sodium phosphate;
4) anodic oxidation:Aluminum alloy base material after processing is put into as anode in the sulfuric acid of 150 ~ 200g/L, and with stereotype As cathode, power on and carry out anodic oxidation under the conditions of -15 ~ 15 DEG C, in oxidation process control voltage from starting voltage by After gradually rising to final voltage, deenergization, oxidation terminates, and forms anode oxide film;
5) it colours:Auto parts machinery after anodic oxidation is put into 70 ~ 90 DEG C of coloring solution, is impregnated 15 ~ 20 minutes, washing, Form dyed layer;The coloring solution is grouped as by the group of following weight ratio:8 ~ 12 parts of potassium bichromate, sodium carbonate 10 ~ 30 parts, 1 ~ 2 part of red algae extract, 100 parts of water;
6) sealing pores:Workpiece after anodized is subjected to sealing pores in hole sealing agent, dries, that is, completes automobile The surface treatment of accessory;The hole sealing agent is grouped as by the group of following weight ratio:10 ~ 20 parts of nickel acetate, flyash 3 ~ 5 Part, 2 ~ 5 parts of Lauric Acid Imidazoline Ampholytic Surfactant, 1 ~ 3 part of glacial acetic acid, 100 parts of water.
Preferably, the step 1)In material spray be grouped as by the group of following weight ratio:6 ~ 10 parts of SEMEN AMOMI LONGILIGULA, copper 1 ~ 2 part of ore in sand form, 1 ~ 2 part of pearl powder, 0.2 ~ 0.4 part of quartz sand.
Preferably, a concentration of the 5 ~ 20% of the aqueous soup solution.
Preferably, the step 3)The voltage of middle application is 400 ~ 600V, and current density is 4.0 ~ 10A/dm2
Preferably, the step 3)With alternating current-direct current overlapping waveform constant-current mode for 40 ~ 60Hz.
Preferably, the step 4)In starting voltage be 10 ~ 15V, final voltage be 25 ~ 50V.
Preferably, the thickness of the oxidation film is 13 ~ 17 μm, and the thickness of the anode oxide film is 10 ~ 15 μm.
Beneficial effects of the present invention are as follows:1) pearl powder is added in material spray, pearl powder density is smaller, SEMEN AMOMI LONGILIGULA, copper mine The density of sand and quartz sand is larger so that surface becomes coarse, and pearl powder then reduces roughness in right amount, increases cleannes;Sandblasting Processing can arbitrarily select between different roughness, avoid caused by chemical agent cleaning that surface is excessively smooth is unfavorable for coating Bonding;
2) first differential arc oxidation is handled, then carries out anodized, is effectively reduced workpiece surface and is formed porous type Oxidation film, and reduce the possibility cracked on film in subsequent processing;
3) anodic oxidation is compared with conventional treatment process, and easy to operate, gained anode oxide film has both decoration function and hardness is high The characteristics of;
4) be added to red algae extract in coloring solution, can increase the coloring effect of potassium bichromate, improve uniform coloring and The durability of color, the oxidation film of protection formation early period, makes the carry out sealing pores that subsequently can more rapidly stablize,
5) it is added to flyash and Lauric Acid Imidazoline Ampholytic Surfactant in hole sealing agent, significantly increase permeability and glues Knot property so that hole sealing agent can be filled into the hole of slight curves, improve wear-resistant corrosion resistance;
6) surface treatment method of the auto parts machinery is easy to operation, through present invention process treated auto parts machinery case hardness High, corrosion-resistant, resistance to oxidation, wear-resistant, resistance to resistance, good antirust property, resistance to temperature change is good, and service life is long.
Specific implementation mode
The present invention is described in further details with specific embodiment below, but the present invention is not only limited to implement in detail below Example.
SEMEN AMOMI LONGILIGULA, copper ore, pearl powder, quartz sand, potassium hydroxide, sodium metasilicate, tertiary sodium phosphate, sulfuric acid, potassium bichromate, Sodium carbonate, red algae extract, nickel acetate, Lauric Acid Imidazoline Ampholytic Surfactant, glacial acetic acid, above-mentioned raw materials or reagent are logical Cross commercially available buying.Aqueous soup solution is mixed with water by commercially available soap and be can be obtained, and flyash is after collecting burning moxa stick Fine ash.
Embodiment provided below be not to limit the range that is covered of the present invention, described step nor with Sequence is executed to limit its.Those skilled in the art are the present invention in conjunction with existing common knowledge conspicuously improved, also fall Enter the present invention claims protection domain within.
Embodiment one
A kind of surface treatment method of auto parts machinery, includes the following steps:1) blasting treatment:Use compressed air for power, it will Material spray is ejected into the surface of auto parts machinery, its surface is made to obtain certain cleannes and different roughness;Material spray is by following heavy The group of amount number ratio is grouped as:6 parts of SEMEN AMOMI LONGILIGULA, 1 part of copper ore, 1 part of pearl powder, 0.2 part of quartz sand;
2) saponification:The auto parts machinery of blasting treatment is put into a concentration of 5% aqueous soup solution, 25 DEG C of immersion 4h form one layer Ferric stearate film;
3) differential arc oxidation is handled:Auto parts machinery is put into electrolyte, the voltage of 400V is applied, current density is 4.0 A/ dm2, differential arc oxidation processing is carried out with 40Hz alternating current-direct currents overlapping waveform constant-current mode, forms the differential arc oxidation that thickness is 13 μm Film;The electrolyte is grouped as by the group of following weight ratio:1 part of potassium hydroxide, 2 parts of sodium metasilicate, tertiary sodium phosphate 3 Part;
4) anodic oxidation:Aluminum alloy base material after processing is put into as anode in the sulfuric acid of 150 g/L, and using stereotype as Cathode powers on and carries out anodic oxidation under the conditions of -15 DEG C, in oxidation process control voltage from starting voltage 10V it is gradual on After rising to final voltage 25V, deenergization, oxidation terminates, and forms the anode oxide film that thickness is 10 μm;
5) it colours:Auto parts machinery after anodic oxidation is put into 70 DEG C of coloring solution, is impregnated 20 minutes, washing is formed Chromatograph;The coloring solution is grouped as by the group of following weight ratio:8 parts of potassium bichromate, 10 parts of sodium carbonate, red algae extraction 1 part of object, 100 parts of water;
6) sealing pores:Workpiece after anodized is subjected to sealing pores in hole sealing agent, dries, that is, completes vapour The surface treatment of vehicle accessory;The hole sealing agent is grouped as by the group of following weight ratio:10 parts of nickel acetate, 3 parts of flyash, 2 parts of Lauric Acid Imidazoline Ampholytic Surfactant, 13 parts of glacial acetic acid, 100 parts of water.
Embodiment two
A kind of surface treatment method of auto parts machinery, includes the following steps:1) blasting treatment:Use compressed air for power, it will Material spray is ejected into the surface of auto parts machinery, its surface is made to obtain certain cleannes and different roughness;Material spray is by following heavy The group of amount number ratio is grouped as:10 parts of SEMEN AMOMI LONGILIGULA, 2 parts of copper ore, 2 parts of pearl powder, 0.2 part of quartz sand;
2) saponification:The auto parts machinery of blasting treatment is put into a concentration of 20% aqueous soup solution, 35 DEG C of immersion 2h form one Layer ferric stearate film;
3) differential arc oxidation is handled:Auto parts machinery is put into electrolyte, the voltage of 600V, current density 4.010A/ are applied dm2, differential arc oxidation processing is carried out with 60Hz alternating current-direct currents overlapping waveform constant-current mode, forms the differential arc oxidation that thickness is 17 μm Film;The electrolyte is grouped as by the group of following weight ratio:3 parts of potassium hydroxide, 4 parts of sodium metasilicate, tertiary sodium phosphate 3 Part;
4) anodic oxidation:Aluminum alloy base material after processing is put into as anode in the sulfuric acid of 200g/L, and using stereotype as the moon Pole powers on and carries out anodic oxidation under the conditions of 15 DEG C, and voltage is controlled in oxidation process and is gradually risen up to from starting voltage 15V After final voltage 50V, deenergization, oxidation terminates, and forms the anode oxide film that thickness is 15 μm;
5) it colours:Auto parts machinery after anodic oxidation is put into 90 DEG C of coloring solution, is impregnated 15 minutes, washing is formed Chromatograph;The coloring solution is grouped as by the group of following weight ratio:12 parts of potassium bichromate, 30 parts of sodium carbonate, red algae carry Take 1 part of object, 100 parts of water;
6) sealing pores:Workpiece after anodized is subjected to sealing pores in hole sealing agent, dries, that is, completes automobile The surface treatment of accessory;The hole sealing agent is grouped as by the group of following weight ratio:20 parts of nickel acetate, flyash 5 part, month 5 parts of cinnamic acid imidazoline amophoteric surface active agent, 3 parts of glacial acetic acid, 100 parts of water.
Embodiment three
A kind of surface treatment method of auto parts machinery, includes the following steps:1) blasting treatment:Use compressed air for power, it will Material spray is ejected into the surface of auto parts machinery, its surface is made to obtain certain cleannes and different roughness;Material spray is by following heavy The group of amount number ratio is grouped as:8 parts of SEMEN AMOMI LONGILIGULA, 1 part of copper ore, 1 part of pearl powder, 0.3 part of quartz sand;
2) saponification:The auto parts machinery of blasting treatment is put into a concentration of 10% aqueous soup solution, 30 DEG C of immersion 3h form one Layer ferric stearate film;
3) differential arc oxidation is handled:Auto parts machinery is put into electrolyte, the voltage of 500V, current density 7A/dm are applied2, with 50Hz alternating current-direct currents are overlapped waveform constant-current mode and carry out differential arc oxidation processing, form the micro-arc oxidation films that thickness is 15 μm;Institute Electrolyte is stated to be grouped as by the group of following weight ratio:2 parts of potassium hydroxide, 3 parts of sodium metasilicate, 4 parts of tertiary sodium phosphate;
4) anodic oxidation:Aluminum alloy base material after processing is put into as anode in the sulfuric acid of 180g/L, and using stereotype as the moon Pole powers on and carries out anodic oxidation under the conditions of 20 DEG C, and voltage is controlled in oxidation process and is gradually risen up to from starting voltage 13V After final voltage 35V, deenergization, oxidation terminates, and forms the anode oxide film that thickness is 12 μm;
5) it colours:Auto parts machinery after anodic oxidation is put into 80 DEG C of coloring solution, is impregnated 18 minutes, washing is formed Chromatograph;The coloring solution is grouped as by the group of following weight ratio:10 parts of potassium bichromate, 20 parts of sodium carbonate, red algae carry Take 2 parts of object, 100 parts of water;
6) sealing pores:Workpiece after anodized is subjected to sealing pores in hole sealing agent, dries, that is, completes automobile The surface treatment of accessory;The hole sealing agent is grouped as by the group of following weight ratio:15 parts of nickel acetate, flyash 4 part, month 4 parts of cinnamic acid imidazoline amophoteric surface active agent, 2 parts of glacial acetic acid, 100 parts of water.
Product test
The auto parts machinery that surface treatment method through auto parts machinery of the present invention obtains, after tested, tensile strength are 7 ~ 15 GPa, bullet Property modulus be 130 ~ 150 GPa, friction coefficient be 0.2 ~ 0.4.
Comparative example 1:With present invention is distinguished in that being not added with pearl powder in material spray.Tensile strength is 7 ~ 15 GPa, Elasticity modulus is 110 ~ 130 GPa, and friction coefficient is 0.2 ~ 0.4.
Comparative example 2:With present invention is distinguished in that being not added with red algae extract in coloring solution.What is coloured is uniform Degree and persistence reduce.
Comparative example 3:With present invention is distinguished in that being not added with flyash and lauric acid imidazoline both sexes in hole sealing agent Surfactant.Tensile strength is 6 ~ 12GPa, and elasticity modulus is 120 ~ 140 GPa, and friction coefficient is 0.3 ~ 0.6, wear-resistant resistance to Corrosive nature reduces.
The above is only preferably feasible implementation example of the invention, cannot therefore be the interest field for limiting to the present invention, For those skilled in the art, other all made with technical scheme of the present invention and technical concept are various corresponding Change should all belong within the protection domain of the claims in the present invention.

Claims (7)

1. a kind of surface treatment method of auto parts machinery, which is characterized in that it includes the following steps:
1) blasting treatment:It uses compressed air for power, material spray is ejected into the surface of auto parts machinery, so that its surface is obtained certain Cleannes and different roughness;
2) saponification:The auto parts machinery of blasting treatment is put into aqueous soup solution, 25 ~ 35 DEG C of 2 ~ 4h of immersion form one layer of tristearin Sour iron thin film;
3) differential arc oxidation is handled:Auto parts machinery is put into electrolyte, is carried out with alternating current-direct current overlapping waveform constant-current mode micro- Arc oxidation processes form micro-arc oxidation films;The electrolyte is grouped as by the group of following weight ratio:Potassium hydroxide 1 ~ 3 Part, 2 ~ 4 parts of sodium metasilicate, 3 ~ 5 parts of tertiary sodium phosphate;
4) anodic oxidation:Aluminum alloy base material after processing is put into as anode in the sulfuric acid of 150 ~ 200g/L, and with stereotype As cathode, power on and carry out anodic oxidation under the conditions of -15 ~ 15 DEG C, in oxidation process control voltage from starting voltage by After gradually rising to final voltage, deenergization, oxidation terminates, and forms anode oxide film;
5) it colours:Auto parts machinery after anodic oxidation is put into 70 ~ 90 DEG C of coloring solution, is impregnated 15 ~ 20 minutes, washing, Form dyed layer;The coloring solution is grouped as by the group of following weight ratio:8 ~ 12 parts of potassium bichromate, sodium carbonate 10 ~ 30 parts, 1 ~ 2 part of red algae extract, 100 parts of water;
6)Sealing pores:Workpiece after anodized is subjected to sealing pores in hole sealing agent, dries, that is, completes automobile The surface treatment of accessory;The hole sealing agent is grouped as by the group of following weight ratio:10 ~ 20 parts of nickel acetate, flyash 3 ~ 5 Part, 2 ~ 5 parts of Lauric Acid Imidazoline Ampholytic Surfactant, 1 ~ 3 part of glacial acetic acid, 100 parts of water.
2. the surface treatment method of auto parts machinery according to claim 1, which is characterized in that the step 1)In material spray It is grouped as by the group of following weight ratio:6 ~ 10 parts of SEMEN AMOMI LONGILIGULA, 1 ~ 2 part of copper ore, 1 ~ 2 part of pearl powder, quartz sand 0.2 ~ 0.4 part.
3. the surface treatment method of auto parts machinery according to claim 1, which is characterized in that the aqueous soup solution it is dense Degree is 5 ~ 20%.
4. the surface treatment method of auto parts machinery according to claim 1, which is characterized in that the step 3)Middle application Voltage is 400 ~ 600V, and current density is 4.0 ~ 10A/dm2
5. the surface treatment method of auto parts machinery according to claim 1, which is characterized in that the step 3)With alternating current-direct current Overlapping waveform constant-current mode is 40 ~ 60Hz.
6. the surface treatment method of auto parts machinery according to claim 1, which is characterized in that the step 4)In starting Voltage is 10 ~ 15V, and final voltage is 25 ~ 50V.
7. the surface treatment method of auto parts machinery according to claim 1, which is characterized in that the thickness of the micro-arc oxidation films Degree is 13 ~ 17 μm, and the thickness of the anode oxide film is 10 ~ 15 μm.
CN201810624455.9A 2018-06-16 2018-06-16 A kind of surface treatment method of automobile parts Active CN108716016B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110983406A (en) * 2019-11-28 2020-04-10 太仓市珠港金属制品有限公司 Surface treatment process for corrosion-resistant and wear-resistant new energy trolley car support
CN112323054A (en) * 2020-11-04 2021-02-05 浙江伟星实业发展股份有限公司 Preparation method of metal aluminum tooth zipper with black coating
CN112342551A (en) * 2020-10-22 2021-02-09 仪征常众汽车部件有限公司 Surface strengthening treatment process for automobile parts

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005218192A (en) * 2004-01-28 2005-08-11 Nsk Ltd Ultrasonic motor
CN103643278A (en) * 2013-11-21 2014-03-19 桂林福冈新材料有限公司 Micro-arc oxidation method of car part aluminum material
CN104562145A (en) * 2014-12-23 2015-04-29 昆明理工大学 Method for preparing bioceramic membrane by composite oxidation
CN205603702U (en) * 2016-05-06 2016-09-28 西安靖安特环境科技有限公司 Titanium alloy anodic oxidation system

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005218192A (en) * 2004-01-28 2005-08-11 Nsk Ltd Ultrasonic motor
CN103643278A (en) * 2013-11-21 2014-03-19 桂林福冈新材料有限公司 Micro-arc oxidation method of car part aluminum material
CN104562145A (en) * 2014-12-23 2015-04-29 昆明理工大学 Method for preparing bioceramic membrane by composite oxidation
CN205603702U (en) * 2016-05-06 2016-09-28 西安靖安特环境科技有限公司 Titanium alloy anodic oxidation system

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110983406A (en) * 2019-11-28 2020-04-10 太仓市珠港金属制品有限公司 Surface treatment process for corrosion-resistant and wear-resistant new energy trolley car support
CN112342551A (en) * 2020-10-22 2021-02-09 仪征常众汽车部件有限公司 Surface strengthening treatment process for automobile parts
CN112323054A (en) * 2020-11-04 2021-02-05 浙江伟星实业发展股份有限公司 Preparation method of metal aluminum tooth zipper with black coating
CN112323054B (en) * 2020-11-04 2022-11-25 浙江伟星实业发展股份有限公司 Preparation method of metal aluminum tooth zipper with black coating

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