CN108707243A - 一种新型高分子塑胶 - Google Patents

一种新型高分子塑胶 Download PDF

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CN108707243A
CN108707243A CN201810636534.1A CN201810636534A CN108707243A CN 108707243 A CN108707243 A CN 108707243A CN 201810636534 A CN201810636534 A CN 201810636534A CN 108707243 A CN108707243 A CN 108707243A
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潘杰
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Anhui Shenke Plastic Industry Co Ltd
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Abstract

一种新型高分子塑胶，包括耐高温基层、耐磨抗菌层；其中所述耐高温基层设于所述耐磨抗菌层的底部；所述耐高温基层由耐高温材料制成，所述耐磨抗菌层由耐磨抗菌材料均匀涂覆于所述耐高温基层上自然风干而成。本发明的有益效果为：(1)该高分子塑胶具有较强的抗摔性、耐高温性、耐磨性及抗菌性；(2)由于壳聚糖具有良好的抗菌特性，本发明使用范围广，不仅使用于包装行业，同样可以适用于医学行业；(3)该高分子塑胶制备方法简单，环保性强，化学性能稳定。

Description

一种新型高分子塑胶
技术领域
本发明属于新材料领域，具体涉及一种新型高分子塑胶。
背景技术
新材料是指新近发展的或正在研发的、性能超群的一些材料，具有比传统材料更为优异的性能。近年来，新材料越来越受重视，国家也重视新材料产业发展。
新材料技术则是按照人的意志，通过物理研究、材料设计、材料加工、试验评价等一系列研究过程，创造出能满足各种需要的新型材料的技术。
先进高分子材料。制定发布丁基橡胶等特种橡胶及专用助剂、聚酰胺等工程塑料及制品、电池隔膜、光学功能薄膜、特种分离膜及组件、环境友好型涂料以及功能性化学品等一批重点产品标准，完成测定方法、通用技术条件、应用规范等配套标准制修订。完成功能薄膜、特种橡胶等领域65项重点新材料标准制修订工作，提出110项重点标准研制计划。
高分子材料：macromolecular material，以高分子化合物为基础的材料。高分子材料是由相对分子质量较高的化合物构成的材料，包括橡胶、塑料、纤维、涂料、胶粘剂和高分子基复合材料，高分子是生命存在的形式。所有的生命体都可以看作是高分子的集合。高分子材料按来源分为天然高分子材料和合成高分子材料。
天然高分子是存在于动物、植物及生物体内的高分子物质，可分为天然纤维、天然树脂、天然橡胶、动物胶等。合成高分子材料主要是指塑料、合成橡胶和合成纤维三大合成材料，此外还包括胶黏剂、涂料以及各种功能性高分子材料。合成高分子材料具有天然高分子材料所没有的或较为优越的性能--较小的密度、较高的力学、耐磨性、耐腐蚀性、电绝缘性等。
现有的塑胶在抗摔性、耐热性、耐磨性及抗菌性方面都不是很良好。
发明内容
本发明的目的是为了克服现有技术中的不足，提供一种新型高分子塑胶。
为解决上述技术问题，本发明的技术方案为：
一种新型高分子塑胶，包括耐高温基层、耐磨抗菌层；其中所述耐高温基层设于所述耐磨抗菌层的底部；所述耐高温基层由耐高温材料制成，所述耐磨抗菌层由耐磨抗菌材料均匀涂覆于所述所述耐高温基层上自然风干而成；
所述耐高温材料由如下重量份数原料组成：聚乙烯50-70份、聚芳碱1-4份、增塑剂2-6 份、对苯二甲酸丙二醇酯-戊酸丁二醇7-9份、聚壬二酐2-4份、聚2,6-二甲基苯醚5-7份、交联淀粉3-5份、炭黑2-4份；
所述耐磨抗菌材料由如下重量份数原料组成：环氧树脂60-80份、玻璃纤维7-11份、纯度为92％以上的石墨烯粉2-6份、邻苯二甲酸二异壬酯11-12份、磷酸二氢锌1-3份、磷酸二氢锌磺酸钠2-4份、纳米填料9-11份、壳聚糖4-6份、交联剂1-2份。
优选地，所述耐高温材料由如下重量份数原料组成：聚乙烯50份、聚芳碱1份、增塑剂 2份、对苯二甲酸丙二醇酯-戊酸丁二醇7份、聚壬二酐2份、聚2,6-二甲基苯醚5份、交联淀粉3份、炭黑2份；
所述耐磨抗菌材料由如下重量份数原料组成：环氧树脂60份、玻璃纤维7份、纯度为 92％以上的石墨烯粉2份、邻苯二甲酸二异壬酯11份、磷酸二氢锌1份、磷酸二氢锌磺酸钠 2份、纳米填料9份、壳聚糖4份、交联剂1份。
优选地，所述耐高温材料由如下重量份数原料组成：聚乙烯70份、聚芳碱4份、增塑剂 6份、对苯二甲酸丙二醇酯-戊酸丁二醇9份、聚壬二酐4份、聚2,6-二甲基苯醚7份、交联淀粉5份、炭黑4份；
所述耐磨抗菌材料由如下重量份数原料组成：环氧树脂80份、玻璃纤维11份、纯度为 92％以上的石墨烯粉6份、邻苯二甲酸二异壬酯12份、磷酸二氢锌3份、磷酸二氢锌磺酸钠 4份、纳米填料11份、壳聚糖6份、交联剂2份。
优选地，所述耐高温材料由如下重量份数原料组成：聚乙烯60份、聚芳碱2份、增塑剂 4份、对苯二甲酸丙二醇酯-戊酸丁二醇8份、聚壬二酐3份、聚2,6-二甲基苯醚6份、交联淀粉4份、炭黑3份；
所述耐磨抗菌材料由如下重量份数原料组成：环氧树脂70份、玻璃纤维9份、纯度为92％以上的石墨烯粉4份、邻苯二甲酸二异壬酯11.5份、磷酸二氢锌2份、磷酸二氢锌磺酸钠3 份、纳米填料10份、壳聚糖5份、交联剂1.5份。
优选地，所述耐磨抗菌材料均匀涂覆于所述所述耐高温基层上的次数为2-3次。
优选地，所述耐磨抗菌层厚度为20-30μm。
本发明的有益效果为：(1)该高分子塑胶具有较强的抗摔性、耐高温性、耐磨性及抗菌性；(2)由于壳聚糖具有良好的抗菌特性，本发明使用范围广，不仅使用于包装行业，同样可以适用于医学行业；(3)该高分子塑胶制备方法简单，环保性强，化学性能稳定。
附图说明
图1是本发明的结构示意图。
具体实施方式
为使对本发明的结构特征及所达成的功效有更进一步的了解与认识，用以较佳的实施例配合详细的说明，说明如下：
为了更加清楚的解释本发明的结构关系，如附图1所示，一种新型高分子塑胶，包括耐高温基层100、耐磨抗菌层200；其中所述耐高温基层100设于所述耐磨抗菌层200的底部；所述耐高温基层100由耐高温材料制成，所述耐磨抗菌层200由耐磨抗菌材料均匀涂覆于所述所述耐高温基层100上自然风干而成。且所述耐磨抗菌材料均匀涂覆于所述所述耐高温基层100上的次数为2-3次，所述耐磨抗菌层厚度为20-30μm。
实施例1
所述耐高温材料由如下重量份数原料组成：聚乙烯50份、聚芳碱1份、增塑剂2份、对苯二甲酸丙二醇酯-戊酸丁二醇7份、聚壬二酐2份、聚2,6-二甲基苯醚5份、交联淀粉3份、炭黑2份；
所述耐磨抗菌材料由如下重量份数原料组成：环氧树脂60份、玻璃纤维7份、纯度为 92％以上的石墨烯粉2份、邻苯二甲酸二异壬酯11份、磷酸二氢锌1份、磷酸二氢锌磺酸钠 2份、纳米填料9份、壳聚糖4份、交联剂1份。
实施例2
所述耐高温材料由如下重量份数原料组成：聚乙烯70份、聚芳碱4份、增塑剂6份、对苯二甲酸丙二醇酯-戊酸丁二醇9份、聚壬二酐4份、聚2,6-二甲基苯醚7份、交联淀粉5份、炭黑4份；
所述耐磨抗菌材料由如下重量份数原料组成：环氧树脂80份、玻璃纤维11份、纯度为 92％以上的石墨烯粉6份、邻苯二甲酸二异壬酯12份、磷酸二氢锌3份、磷酸二氢锌磺酸钠 4份、纳米填料11份、壳聚糖6份、交联剂2份。
实施例3
所述耐高温材料由如下重量份数原料组成：聚乙烯60份、聚芳碱2份、增塑剂4份、对苯二甲酸丙二醇酯-戊酸丁二醇8份、聚壬二酐3份、聚2,6-二甲基苯醚6份、交联淀粉4份、炭黑3份；
所述耐磨抗菌材料由如下重量份数原料组成：环氧树脂70份、玻璃纤维9份、纯度为92％以上的石墨烯粉4份、邻苯二甲酸二异壬酯11.5份、磷酸二氢锌2份、磷酸二氢锌磺酸钠3 份、纳米填料10份、壳聚糖5份、交联剂1.5份。
本发明的有益效果为：(1)该高分子塑胶具有较强的抗摔性、耐高温性、耐磨性及抗菌性；(2)由于壳聚糖具有良好的抗菌特性，本发明使用范围广，不仅使用于包装行业，同样可以适用于医学行业；(3)该高分子塑胶制备方法简单，环保性强，化学性能稳定。
以上显示和描述了本发明的基本原理、主要特征和本发明的优点。本行业的技术人员应该了解，本发明不受上述实施例的限制，上述实施例和说明书中描述的只是本发明的原理，在不脱离本发明精神和范围的前提下本发明还会有各种变化和改进，这些变化和改进都落入要求保护的本发明的范围内。本发明要求的保护范围由所附的权利要求书及其等同物界定。

Claims (6)

1.一种新型高分子塑胶，其特征在于：包括耐高温基层、耐磨抗菌层；其中所述耐高温基层设于所述耐磨抗菌层的底部；所述耐高温基层由耐高温材料制成，所述耐磨抗菌层由耐磨抗菌材料均匀涂覆于所述所述耐高温基层上自然风干而成；
所述耐高温材料由如下重量份数原料组成：聚乙烯50-70份、聚芳碱1-4份、增塑剂2-6份、对苯二甲酸丙二醇酯-戊酸丁二醇7-9份、聚壬二酐2-4份、聚2,6-二甲基苯醚5-7份、交联淀粉3-5份、炭黑2-4份；
所述耐磨抗菌材料由如下重量份数原料组成：环氧树脂60-80份、玻璃纤维7-11份、纯度为92％以上的石墨烯粉2-6份、邻苯二甲酸二异壬酯11-12份、磷酸二氢锌1-3份、磷酸二氢锌磺酸钠2-4份、纳米填料9-11份、壳聚糖4-6份、交联剂1-2份。
2.根据权利要求1所述的一种新型高分子塑胶，其特征在于：所述耐高温材料由如下重量份数原料组成：聚乙烯50份、聚芳碱1份、增塑剂2份、对苯二甲酸丙二醇酯-戊酸丁二醇7份、聚壬二酐2份、聚2,6-二甲基苯醚5份、交联淀粉3份、炭黑2份；
所述耐磨抗菌材料由如下重量份数原料组成：环氧树脂60份、玻璃纤维7份、纯度为92％以上的石墨烯粉2份、邻苯二甲酸二异壬酯11份、磷酸二氢锌1份、磷酸二氢锌磺酸钠2份、纳米填料9份、壳聚糖4份、交联剂1份。
3.根据权利要求1所述的一种新型高分子塑胶，其特征在于：所述耐高温材料由如下重量份数原料组成：聚乙烯70份、聚芳碱4份、增塑剂6份、对苯二甲酸丙二醇酯-戊酸丁二醇9份、聚壬二酐4份、聚2,6-二甲基苯醚7份、交联淀粉5份、炭黑4份；
所述耐磨抗菌材料由如下重量份数原料组成：环氧树脂80份、玻璃纤维11份、纯度为92％以上的石墨烯粉6份、邻苯二甲酸二异壬酯12份、磷酸二氢锌3份、磷酸二氢锌磺酸钠4份、纳米填料11份、壳聚糖6份、交联剂2份。
4.根据权利要求1所述的一种新型高分子塑胶，其特征在于：所述耐高温材料由如下重量份数原料组成：聚乙烯60份、聚芳碱2份、增塑剂4份、对苯二甲酸丙二醇酯-戊酸丁二醇8份、聚壬二酐3份、聚2,6-二甲基苯醚6份、交联淀粉4份、炭黑3份；
所述耐磨抗菌材料由如下重量份数原料组成：环氧树脂70份、玻璃纤维9份、纯度为92％以上的石墨烯粉4份、邻苯二甲酸二异壬酯11.5份、磷酸二氢锌2份、磷酸二氢锌磺酸钠3份、纳米填料10份、壳聚糖5份、交联剂1.5份。
5.根据权利要求1所述的一种新型高分子塑胶，其特征在于：所述耐磨抗菌材料均匀涂覆于所述所述耐高温基层上的次数为2-3次。
6.根据权利要求1所述的一种新型高分子塑胶，其特征在于：所述耐磨抗菌层厚度为20-30μm。
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105061793A (zh) * 2015-08-13 2015-11-18 宁波申山新材料科技有限公司 一种护肤汽车贴膜及其制备方法
CN106750785A (zh) * 2016-12-13 2017-05-31 无锡市四方达高分子材料有限公司 高分子材料
CN107216607A (zh) * 2017-05-27 2017-09-29 南通成山高分子材料有限公司 一种耐磨高分子材料
CN107522929A (zh) * 2017-08-26 2017-12-29 南通成山高分子材料有限公司 一种抗静电的高分子材料
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CN105061793A (zh) * 2015-08-13 2015-11-18 宁波申山新材料科技有限公司 一种护肤汽车贴膜及其制备方法
CN106750785A (zh) * 2016-12-13 2017-05-31 无锡市四方达高分子材料有限公司 高分子材料
CN107216607A (zh) * 2017-05-27 2017-09-29 南通成山高分子材料有限公司 一种耐磨高分子材料
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Application publication date: 20181026