CN108690627A - A kind of soil conditioner manufactured with gutter oil and preparation method and purposes - Google Patents
A kind of soil conditioner manufactured with gutter oil and preparation method and purposes Download PDFInfo
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- CN108690627A CN108690627A CN201810466341.6A CN201810466341A CN108690627A CN 108690627 A CN108690627 A CN 108690627A CN 201810466341 A CN201810466341 A CN 201810466341A CN 108690627 A CN108690627 A CN 108690627A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/08—Reclamation of contaminated soil chemically
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2101/00—Agricultural use
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Soil Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Abstract
The invention discloses a kind of soil conditioner manufactured with gutter oil and preparation methods and purposes.Soil conditioner includes the raw material of following parts by weight:20-32 parts of gutter oil, 25-40 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 15-20 parts of arachidonic acid, 6-11 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid, 6-10 parts of polymeric aluminium ferrum silicate, 5-15 parts of Herba Dendrobii extract.The soil conditioner of the present invention manufactured with gutter oil is by gutter oil, sodium sulfate of polyethenoxy ether of fatty alcohol, arachidonic acid, 1-hydroxy ethylidene-1,1-diphosphonic acid, polymeric aluminium ferrum silicate and Herba Dendrobii extract is compound is prepared, have the effect of it is water-saving, increase production, increase income and improve crop quality, with preferable economic value, it is worthy to be popularized.
Description
Technical field
The present invention relates to a kind of soil conditioner, specifically a kind of soil conditioner manufactured with gutter oil and preparation method
And purposes.
Background technology
Gutter oil is actually a concept referred to, is common name of the people for all kinds of poor oils in life.Trench
Oil can be divided into following a few classes:First, the gutter oil of narrow sense, i.e., by sewer greasy floating material or by hotel, restaurant it is surplus
Meal, leftovers (common name swill) pass through the oil simply processed, extracted;Second is that pork inferior, haslet, pigskin processing and refinement
The oil of output afterwards;Third, the oily access times for fried food are again repeated more than after prescribed requirement and use or add thereto
Add the oil reused after some fresh oils.Waste oil is that quality is very poor, extremely unhygienic, and peroxide value, acid value, moisture severely exceed
Unedible oil.It contains toxin, and water nutrition can be caused by flowing to rivers, once it is edible, then it can destroy white blood cell and digestion
Mucous membrane causes to poison by food or even carcinogenic.The fried Cargo Oil of one of " crossing rape oil " is repeatedly used for a long at high operating temperatures, with
Oxygen contact in air, occurs the complex reactions such as hydrolysis, oxidation, polymerization, oily viscosity is caused to increase, color and luster is deepened, peroxide value
It increases, and generates the substance of the irritant smell such as some volatile matters and aldehyde, ketone, lactone, these substances have carcinogenesis.But
The main component of gutter oil is that aliphatic acid, palmitic acid, stearic acid, swill etc. belong to organic matter, and organic matter in the soil may be used
As the nutriment of microorganism, be conducive to abundant edaphon.The main path of gutter oil recycling has at present, warp
Paint is produced after crossing purification processes, washs the aliphatic acid of industry, production biodiesel etc. after esterification reaction of organic acid, but due to
The reason of gutter oil source, approach, every batch of quality difference is too big, causes to recycle difficulty, cost is higher.
Long-term chemical fertilizer uses so that soil organic matter content is insufficient, and microorganism living environment is destroyed, soil fertilizer
Power declines, hardened serious, while crops quality declines.Therefore, it is necessary to a kind of new technology by gutter oil for improving soil
Environment.
Invention content
The purpose of the present invention is to provide a kind of soil conditioner manufactured with gutter oil and preparation methods and purposes, with solution
Certainly the problems mentioned above in the background art.
To achieve the above object, the present invention provides the following technical solutions:
A kind of soil conditioner manufactured with gutter oil, includes the raw material of following parts by weight:20-32 parts of gutter oil, fat
25-40 parts of fat alcohol polyethenoxy ether sodium sulfate, 15-20 parts of arachidonic acid, 6-11 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid, polymer aluminium silicate
6-10 parts of iron, 5-15 parts of Herba Dendrobii extract.
As a further solution of the present invention:Include the raw material of following parts by weight:24 parts of gutter oil, fatty alcohol polyoxy second
35 parts of alkene ether sodium sulfate, 18 parts of arachidonic acid, 10 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid, 8 parts of polymeric aluminium ferrum silicate, Herba Dendrobii extract 11
Part.
A kind of preparation method of the soil conditioner manufactured with gutter oil, includes the following steps:
(1) preparation of Herba Dendrobii extract:The stem of noble dendrobium is taken, dices, be homogenized, 0.4mol/L, pH that 2-4 times of stem of noble dendrobium weight is added are
The phosphate buffer of 6.0-7.0 impregnates, and is placed at -5 DEG C after refrigerating 5-8 hours, refrigerated centrifuge, upper layer is that stem of noble dendrobium albumen is thick
Extract;The ethanol solution that the mass fraction of its 1/3-1 times of volume is 65% is slowly added into gained stem of noble dendrobium protein crude extract, so
The calcium hydroxide solution that mass fraction is 1% is used to adjust pH to 7.5 afterwards, after being stood overnight in ice bath, refrigerated centrifuge, it is heavy to collect
It forms sediment, is freeze-dried up to stem of noble dendrobium protein freeze-dried powder;The distilled water that 3-5 times of weight is added into gained stem of noble dendrobium protein freeze-dried powder is dilute
It releases, then with the vinegar acid for adjusting pH of 1mol/L to 5;Into acquired solution by enzyme bottom than 1:Acid protease is added in (15-20),
It is digested 0.5-2 hours at 52 DEG C, enzyme deactivation is cooled to room temperature;The enzyme bottom is than for acid protease and stem of noble dendrobium protein freeze-dried powder
Mass ratio;With 0.1mol/L acetic acid regulating step (4) acquired solution pH to 3, by enzyme bottom than 1:Stomach cardia is added in (100-200)
Enzyme digests 0.5-2 hours at 35 DEG C, and enzyme deactivation is cooled to room temperature, and 5 DEG C, 5000 revs/min centrifuge 15 minutes, collect supernatant
Liquid, it is dry to get;
(2) gutter oil and arachidonic acid are mixed, is stirred 4-7min at 135-158 DEG C, obtains mixture A;
(3) sodium sulfate of polyethenoxy ether of fatty alcohol and 1-hydroxy ethylidene-1,1-diphosphonic acid are mixed, 1-3 times of quality of mixture is added
Water is placed at 100-125 DEG C and is stirred 10-20min, obtains mixture B;
(4) polymeric aluminium ferrum silicate is mixed with Herba Dendrobii extract, after mixing, is placed at 130-150 DEG C and bakes 10-
20min obtains mixture C;
(5) mixture A is mixed with mixture B, is placed at 135-140 DEG C and is stirred to react 1-3h;
(6) mixture C is mixed with upper step gains, be placed at 80-95 DEG C be stirred 10-20min to get.
As a further solution of the present invention:The preparation of step (1) Herba Dendrobii extract:The stem of noble dendrobium is taken, dices, be homogenized, is added
0.4mol/L, pH that 3 times of stem of noble dendrobium weight be 6.5 phosphate buffer impregnate, be placed at -5 DEG C after refrigerating 7 hours, freeze from
The heart, upper layer are stem of noble dendrobium protein crude extract;The mass fraction of its 1/2 times of volume is slowly added into gained stem of noble dendrobium protein crude extract
For 65% ethanol solution, then uses the calcium hydroxide solution that mass fraction is 1% to adjust pH to 7.5, stood overnight in ice bath
Afterwards, refrigerated centrifuge collects precipitation, is freeze-dried up to stem of noble dendrobium protein freeze-dried powder;4 times are added into gained stem of noble dendrobium protein freeze-dried powder
The distilled water of weight dilutes, then with the vinegar acid for adjusting pH of 1mol/L to 5;Into acquired solution by enzyme bottom than 1:18 are added acidity
Protease digests 1 hour at 52 DEG C, and enzyme deactivation is cooled to room temperature;The enzyme bottom ratio is that acid protease is lyophilized with stem of noble dendrobium albumen
The mass ratio of powder;With 0.1mol/L acetic acid regulating step (4) acquired solution pH to 3, by enzyme bottom than 1:120 are added pepsin,
It being digested 1 hour at 35 DEG C, enzyme deactivation is cooled to room temperature, and 5 DEG C, 5000 revs/min centrifuge 15 minutes, collect supernatant, dry,
To obtain the final product.
As a further solution of the present invention:Step (2) mixes gutter oil and arachidonic acid, is stirred at 145 DEG C
5min is mixed, mixture A is obtained.
As a further solution of the present invention:Step (3) is by two phosphorus of sodium sulfate of polyethenoxy ether of fatty alcohol and hydroxy ethylidene
Acid mixing, is added the water of 2 times of quality of mixture, is placed at 118 DEG C and is stirred 16min, obtain mixture B.
As a further solution of the present invention:Step (4) mixes polymeric aluminium ferrum silicate with Herba Dendrobii extract, is uniformly mixed
Afterwards, it is placed at 140 DEG C and bakes 15min, obtain mixture C.
As a further solution of the present invention:Step (5) mixes mixture A with mixture B, is placed at 138 DEG C and stirs
React 2h.
As a further solution of the present invention:Step (6) mixes mixture C with upper step gains, is placed at 88 DEG C and stirs
Mix mixing 17min to get.
A kind of application of the soil conditioner manufactured with gutter oil in soil remediation technology field.
Compared with prior art, the beneficial effects of the invention are as follows:
The soil conditioner of the present invention manufactured with gutter oil passes through gutter oil, sodium sulfate of polyethenoxy ether of fatty alcohol, flower
Raw tetraenoic acid, 1-hydroxy ethylidene-1,1-diphosphonic acid, polymeric aluminium ferrum silicate and Herba Dendrobii extract is compound is prepared, have water-saving, volume increase, increase
The effect of crop quality is received and improved, there is preferable economic value, be worthy to be popularized.
Specific implementation mode
The technical solution of this patent is described in more detail With reference to embodiment.
Embodiment 1
A kind of soil conditioner manufactured with gutter oil, includes the raw material of following parts by weight:20 parts of gutter oil, fatty alcohol
25 parts of polyethenoxy ether sodium sulfate, 15 parts of arachidonic acid, 6 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid, 6 parts of polymeric aluminium ferrum silicate, the stem of noble dendrobium carry
Take 5 parts of object.
A kind of preparation method of the soil conditioner manufactured with gutter oil, includes the following steps:(1) system of Herba Dendrobii extract
It is standby:The stem of noble dendrobium is taken, dices, be homogenized, the phosphate buffer that 0.4mol/L, pH that 2 times of stem of noble dendrobium weight is added are 6.0 impregnates, be placed in-
After being refrigerated 5 hours at 5 DEG C, refrigerated centrifuge, upper layer is stem of noble dendrobium protein crude extract;Slowly add into gained stem of noble dendrobium protein crude extract
Enter the ethanol solution that the mass fraction of its 1/3 times of volume is 65%, the calcium hydroxide solution that mass fraction is 1% is then used to adjust
PH to 7.5, after standing overnight in ice bath, refrigerated centrifuge collects precipitation, is freeze-dried up to stem of noble dendrobium protein freeze-dried powder;To gained
The distilled water dilution of 3 times of weight is added in stem of noble dendrobium protein freeze-dried powder, then with the vinegar acid for adjusting pH of 1mol/L to 5;It is molten to gained
By enzyme bottom than 1 in liquid:15 are added acid protease, are digested 0.5 hour at 52 DEG C, enzyme deactivation is cooled to room temperature;The enzyme bottom ratio
For the mass ratio of acid protease and stem of noble dendrobium protein freeze-dried powder;With 0.1mol/L acetic acid regulating step (4) acquired solution pH to 3,
By enzyme bottom than 1:100 are added pepsin, are digested 0.5 hour at 35 DEG C, enzyme deactivation is cooled to room temperature, 5 DEG C, 5000 revs/min
Centrifugation 15 minutes, collects supernatant, it is dry to get;(2) gutter oil and arachidonic acid are mixed, is stirred at 135 DEG C
4min obtains mixture A;(3) sodium sulfate of polyethenoxy ether of fatty alcohol and 1-hydroxy ethylidene-1,1-diphosphonic acid are mixed, 1 times of mixture is added
The water of quality is placed at 100 DEG C and is stirred 10min, obtains mixture B;(4) polymeric aluminium ferrum silicate and Herba Dendrobii extract are mixed
It closes, after mixing, is placed at 130 DEG C and bakes 10min, obtain mixture C;(5) mixture A is mixed with mixture B, is placed in
It is stirred to react 1h at 135 DEG C;(6) mixture C is mixed with upper step gains, be placed at 80 DEG C be stirred 10min to get.
Embodiment 2
A kind of soil conditioner manufactured with gutter oil, includes the raw material of following parts by weight:32 parts of gutter oil, fatty alcohol
40 parts of polyethenoxy ether sodium sulfate, 20 parts of arachidonic acid, 11 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid, 10 parts of polymeric aluminium ferrum silicate, the stem of noble dendrobium
15 parts of extract.
A kind of preparation method of the soil conditioner manufactured with gutter oil, includes the following steps:(1) system of Herba Dendrobii extract
It is standby:The stem of noble dendrobium is taken, dices, be homogenized, the phosphate buffer that 0.4mol/L, pH that 4 times of stem of noble dendrobium weight is added are 7.0 impregnates, be placed in-
After being refrigerated 8 hours at 5 DEG C, refrigerated centrifuge, upper layer is stem of noble dendrobium protein crude extract;Slowly add into gained stem of noble dendrobium protein crude extract
Enter the ethanol solution that the mass fraction of its 1 times of volume is 65%, the calcium hydroxide solution that mass fraction is 1% is then used to adjust pH
To 7.5, after being stood overnight in ice bath, refrigerated centrifuge collects precipitation, is freeze-dried up to stem of noble dendrobium protein freeze-dried powder;To gained stone
The distilled water dilution of 5 times of weight is added in dry measure used in former times protein freeze-dried powder, then with the vinegar acid for adjusting pH of 1mol/L to 5;To acquired solution
In by enzyme bottom than 1:20 are added acid protease, are digested 2 hours at 52 DEG C, enzyme deactivation is cooled to room temperature;The enzyme bottom ratio is acid
The mass ratio of property protease and stem of noble dendrobium protein freeze-dried powder;With 0.1mol/L acetic acid regulating step (4) acquired solution pH to 3, by enzyme
Bottom is than 1:200 are added pepsin, are digested 2 hours at 35 DEG C, and enzyme deactivation is cooled to room temperature, 5 DEG C, 5000 revs/min of centrifugations 15
Minute, collect supernatant, it is dry to get;(2) gutter oil and arachidonic acid are mixed, 7min are stirred at 158 DEG C,
Obtain mixture A;(3) sodium sulfate of polyethenoxy ether of fatty alcohol and 1-hydroxy ethylidene-1,1-diphosphonic acid are mixed, 3 times of quality of mixture is added
Water is placed at 125 DEG C and is stirred 20min, obtains mixture B;(4) polymeric aluminium ferrum silicate is mixed with Herba Dendrobii extract, is mixed
After uniformly, it is placed at 150 DEG C and bakes 20min, obtain mixture C;(5) mixture A is mixed with mixture B, is placed at 140 DEG C and stirs
Mix reaction 3h;(6) mixture C is mixed with upper step gains, be placed at 95 DEG C be stirred 20min to get.
Embodiment 3
A kind of soil conditioner manufactured with gutter oil, includes the raw material of following parts by weight:24 parts of gutter oil, fatty alcohol
35 parts of polyethenoxy ether sodium sulfate, 18 parts of arachidonic acid, 10 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid, 8 parts of polymeric aluminium ferrum silicate, the stem of noble dendrobium carry
Take 11 parts of object.
A kind of preparation method of the soil conditioner manufactured with gutter oil, includes the following steps:(1) system of Herba Dendrobii extract
It is standby:The stem of noble dendrobium is taken, dices, be homogenized, the phosphate buffer that 0.4mol/L, pH that 3 times of stem of noble dendrobium weight is added are 6.5 impregnates, be placed in-
After being refrigerated 7 hours at 5 DEG C, refrigerated centrifuge, upper layer is stem of noble dendrobium protein crude extract;Slowly add into gained stem of noble dendrobium protein crude extract
Enter the ethanol solution that the mass fraction of its 1/2 times of volume is 65%, the calcium hydroxide solution that mass fraction is 1% is then used to adjust
PH to 7.5, after standing overnight in ice bath, refrigerated centrifuge collects precipitation, is freeze-dried up to stem of noble dendrobium protein freeze-dried powder;To gained
The distilled water dilution of 4 times of weight is added in stem of noble dendrobium protein freeze-dried powder, then with the vinegar acid for adjusting pH of 1mol/L to 5;It is molten to gained
By enzyme bottom than 1 in liquid:18 are added acid protease, are digested 1 hour at 52 DEG C, enzyme deactivation is cooled to room temperature;The enzyme bottom ratio is
The mass ratio of acid protease and stem of noble dendrobium protein freeze-dried powder;With 0.1mol/L acetic acid regulating step (4) acquired solution pH to 3, press
Enzyme bottom is than 1:120 are added pepsin, are digested 1 hour at 35 DEG C, and enzyme deactivation is cooled to room temperature, 5 DEG C, 5000 revs/min of centrifugations
15 minutes, collect supernatant, it is dry to get.(2) gutter oil and arachidonic acid are mixed, is stirred at 145 DEG C
5min obtains mixture A.(3) sodium sulfate of polyethenoxy ether of fatty alcohol and 1-hydroxy ethylidene-1,1-diphosphonic acid are mixed, 2 times of mixture is added
The water of quality is placed at 118 DEG C and is stirred 16min, obtains mixture B.(4) polymeric aluminium ferrum silicate and Herba Dendrobii extract are mixed
It closes, after mixing, is placed at 140 DEG C and bakes 15min, obtain mixture C.(5) mixture A is mixed with mixture B, is placed in
It is stirred to react 2h at 138 DEG C.(6) mixture C is mixed with upper step gains, be placed at 88 DEG C be stirred 17min to get.
Comparative example 1
In addition to without sodium sulfate of polyethenoxy ether of fatty alcohol, other preparation methods are same as Example 3.
Comparative example 2
In addition to without arachidonic acid, other preparation methods are same as Example 3.
Comparative example 3
In addition to without sodium sulfate of polyethenoxy ether of fatty alcohol and arachidonic acid, other preparation methods are same as Example 3.
Experimental example
One, it is used to plant on sandy soil using 1-3 of the embodiment of the present invention and comparative example the 1-3 soil conditioner prepared
Soybean makees base fertilizer application, amount of application 35kg/hm2, 1 is the results are shown in Table after.
Table 1
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Water-saving (%) | 25.8 | 28.4 | 30.6 | 15.5 | 16.2 | 10.1 |
| Increase production (%) | 39.2 | 41.5 | 45.8 | 30.1 | 28.7 | 22.6 |
| It increases income (%) | 36.5 | 34.7 | 41.2 | 24.1 | 25.7 | 20.2 |
Two, processing method:Embodiment 1-3 and comparative example the 1-3 soil conditioner prepared are applied in experimental plot respectively, applied
Dosage is 28kg/hm2.It is experimental subjects that each processing group, which selects the identical tobacco seedling of 3 mu of growing ways,;Experimental field is Guangdong ox
Liver soil field.Control treatment is set simultaneously, control treatment does not add soil conditioner.Various soil conditioners are measured to tobacco growing
It influences, is harvested after tobacco maturation, measure each group tobacco per mu yield and average yield per mu value, and produce obtained flue-cured tobacco and ask cigarette
The leaf expert that smokes panel test smokes panel test, and measures the quality for the flue-cured tobacco that every group obtains, the results are shown in Table 2.
Table 2
| Project | Kg/ mus of yield of flue-cured tobacco | Better-than-average cigarette ratio % | Score of smokeing panel test (total score 100) |
| Embodiment 1 | 152.6 | 98.25 | 88 |
| Embodiment 2 | 155.8 | 96.98 | 90 |
| Embodiment 3 | 161.7 | 99.13 | 93 |
| Comparative example 1 | 141.3 | 92.41 | 85 |
| Comparative example 2 | 138.2 | 90.36 | 82 |
| Comparative example 3 | 133.8 | 90.25 | 80 |
| Control group | 128.7 | 89.14 | 79 |
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party
Formula, one skilled in the relevant art within the scope of knowledge, can also be under the premise of not departing from this patent objective
It makes a variety of changes.
Claims (10)
1. a kind of soil conditioner manufactured with gutter oil, which is characterized in that include the raw material of following parts by weight:Gutter oil
20-32 parts, 25-40 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 15-20 parts of arachidonic acid, 6-11 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid,
6-10 parts of polymeric aluminium ferrum silicate, 5-15 parts of Herba Dendrobii extract.
2. the soil conditioner according to claim 1 manufactured with gutter oil, which is characterized in that including following parts by weight
Raw material:24 parts of gutter oil, 35 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 18 parts of arachidonic acid, 1-hydroxy ethylidene-1,1-diphosphonic acid 10
Part, 8 parts of polymeric aluminium ferrum silicate, 11 parts of Herba Dendrobii extract.
3. a kind of preparation method of soil conditioner manufactured with gutter oil as described in claim 1-2 is any, feature exist
In including the following steps:
(1) preparation of Herba Dendrobii extract:The stem of noble dendrobium is taken, dices, be homogenized, 0.4mol/L, pH 6.0- of 2-4 times of stem of noble dendrobium weight is added
7.0 phosphate buffer impregnates, and is placed at -5 DEG C after refrigerating 5-8 hours, refrigerated centrifuge, upper layer is that stem of noble dendrobium albumen slightly carries
Liquid;The ethanol solution that the mass fraction of its 1/3-1 times of volume is 65% is slowly added into gained stem of noble dendrobium protein crude extract, then
The calcium hydroxide solution for being 1% with mass fraction adjusts pH to 7.5, and after being stood overnight in ice bath, refrigerated centrifuge collects precipitation,
It is freeze-dried up to stem of noble dendrobium protein freeze-dried powder;The distilled water dilution of 3-5 times of weight is added into gained stem of noble dendrobium protein freeze-dried powder, so
Afterwards with the vinegar acid for adjusting pH of 1mol/L to 5;Into acquired solution by enzyme bottom than 1:Acid protease is added in (15-20), at 52 DEG C
Lower enzymolysis 0.5-2 hours, enzyme deactivation is cooled to room temperature;The enzyme bottom is than the quality for acid protease and stem of noble dendrobium protein freeze-dried powder
Than;With 0.1mol/L acetic acid regulating step (4) acquired solution pH to 3, by enzyme bottom than 1:Pepsin is added in (100-200),
It is digested 0.5-2 hours at 35 DEG C, enzyme deactivation is cooled to room temperature, and 5 DEG C, 5000 revs/min centrifuge 15 minutes, collect supernatant, do
It is dry to get;
(2) gutter oil and arachidonic acid are mixed, is stirred 4-7min at 135-158 DEG C, obtains mixture A;
(3) sodium sulfate of polyethenoxy ether of fatty alcohol and 1-hydroxy ethylidene-1,1-diphosphonic acid are mixed, the water of 1-3 times of quality of mixture are added,
It is placed at 100-125 DEG C and is stirred 10-20min, obtain mixture B;
(4) polymeric aluminium ferrum silicate is mixed with Herba Dendrobii extract, after mixing, is placed at 130-150 DEG C and bakes 10-20min,
Obtain mixture C;
(5) mixture A is mixed with mixture B, is placed at 135-140 DEG C and is stirred to react 1-3h;
(6) mixture C is mixed with upper step gains, be placed at 80-95 DEG C be stirred 10-20min to get.
4. the preparation method of the soil conditioner manufactured as claimed in claim 3 with gutter oil, which is characterized in that step (1)
The preparation of Herba Dendrobii extract:The stem of noble dendrobium is taken, dices, be homogenized, the phosphate that 0.4mol/L, pH that 3 times of stem of noble dendrobium weight is added are 6.5 is slow
Fliud flushing is impregnated, and is placed at -5 DEG C after refrigerating 7 hours, refrigerated centrifuge, upper layer is stem of noble dendrobium protein crude extract;To gained stem of noble dendrobium albumen
The ethanol solution that the mass fraction of its 1/2 times of volume is 65% is slowly added in crude extract, it is 1% hydrogen then to use mass fraction
Calcium oxide solution adjusts pH to 7.5, and after being stood overnight in ice bath, refrigerated centrifuge collects precipitation, is freeze-dried up to stem of noble dendrobium albumen
Freeze-dried powder;The distilled water dilution of 4 times of weight is added into gained stem of noble dendrobium protein freeze-dried powder, then uses the vinegar acid for adjusting pH of 1mol/L
To 5;Into acquired solution by enzyme bottom than 1:18 are added acid protease, are digested 1 hour at 52 DEG C, enzyme deactivation is cooled to room temperature;
The enzyme bottom is than the mass ratio for acid protease and stem of noble dendrobium protein freeze-dried powder;Obtained by 0.1mol/L acetic acid regulating step (4)
PH value of solution is to 3, by enzyme bottom than 1:120 are added pepsin, are digested 1 hour at 35 DEG C, and enzyme deactivation is cooled to room temperature, 5 DEG C,
5000 revs/min centrifuge 15 minutes, collect supernatant, it is dry to get.
5. the preparation method of the soil conditioner manufactured as claimed in claim 3 with gutter oil, which is characterized in that step (2)
Gutter oil and arachidonic acid are mixed, 5min is stirred at 145 DEG C, obtains mixture A.
6. the preparation method of the soil conditioner manufactured as claimed in claim 3 with gutter oil, which is characterized in that step (3)
Sodium sulfate of polyethenoxy ether of fatty alcohol and 1-hydroxy ethylidene-1,1-diphosphonic acid are mixed, the water of 2 times of quality of mixture is added, is placed in 118 DEG C
Under be stirred 16min, obtain mixture B.
7. the preparation method of the soil conditioner manufactured as claimed in claim 3 with gutter oil, which is characterized in that step (4)
Polymeric aluminium ferrum silicate is mixed with Herba Dendrobii extract, after mixing, is placed at 140 DEG C and bakes 15min, obtain mixture C.
8. the preparation method of the soil conditioner manufactured as claimed in claim 3 with gutter oil, which is characterized in that step (5)
Mixture A is mixed with mixture B, is placed at 138 DEG C and is stirred to react 2h.
9. the preparation method of the soil conditioner manufactured as claimed in claim 3 with gutter oil, which is characterized in that step (6)
Mixture C is mixed with upper step gains, be placed at 88 DEG C be stirred 17min to get.
10. a kind of soil conditioner manufactured with gutter oil as described in claim 1-2 is any is in soil remediation technology field
In application.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114989833A (en) * | 2022-06-30 | 2022-09-02 | 润涵(山东)生态科技有限公司 | Ecological environment-friendly functional sand fixing agent and sand fixing method |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101962555A (en) * | 2009-07-23 | 2011-02-02 | 中国科学院兰州化学物理研究所 | Multi-functional salinization soil improved material |
| CN102533274A (en) * | 2011-01-04 | 2012-07-04 | 河南农业大学 | Soil conditioning agent helpful for farming |
| CN103086800A (en) * | 2013-02-05 | 2013-05-08 | 中国水稻研究所 | Fertilizer for controlling cadmium accumulation of crops, and its preparation method |
| CN104818311A (en) * | 2015-05-13 | 2015-08-05 | 武昌理工学院 | Preparation method and application of onion active polypeptide extract |
| CN105018103A (en) * | 2015-06-26 | 2015-11-04 | 北京华夏先河新材料有限公司 | Soil solidifying agent, and preparation method and use method thereof |
| CN105949080A (en) * | 2016-05-09 | 2016-09-21 | 深圳市大物科技有限责任公司 | Method for preparation of heavy metal chelating agent from gutter oil or animal and vegetable oil |
| CN107311816A (en) * | 2017-07-31 | 2017-11-03 | 钟春明 | It is acidified soil soil conditioner |
-
2018
- 2018-05-16 CN CN201810466341.6A patent/CN108690627A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101962555A (en) * | 2009-07-23 | 2011-02-02 | 中国科学院兰州化学物理研究所 | Multi-functional salinization soil improved material |
| CN102533274A (en) * | 2011-01-04 | 2012-07-04 | 河南农业大学 | Soil conditioning agent helpful for farming |
| CN103086800A (en) * | 2013-02-05 | 2013-05-08 | 中国水稻研究所 | Fertilizer for controlling cadmium accumulation of crops, and its preparation method |
| CN104818311A (en) * | 2015-05-13 | 2015-08-05 | 武昌理工学院 | Preparation method and application of onion active polypeptide extract |
| CN105018103A (en) * | 2015-06-26 | 2015-11-04 | 北京华夏先河新材料有限公司 | Soil solidifying agent, and preparation method and use method thereof |
| CN105949080A (en) * | 2016-05-09 | 2016-09-21 | 深圳市大物科技有限责任公司 | Method for preparation of heavy metal chelating agent from gutter oil or animal and vegetable oil |
| CN107311816A (en) * | 2017-07-31 | 2017-11-03 | 钟春明 | It is acidified soil soil conditioner |
Non-Patent Citations (2)
| Title |
|---|
| 朱洪法: "《生活化学品与健康》", 30 April 2013, 金盾出版社 * |
| 王才良: "《中国化工产品分析方法手册 有机分册》", 31 March 1993, 农业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114989833A (en) * | 2022-06-30 | 2022-09-02 | 润涵(山东)生态科技有限公司 | Ecological environment-friendly functional sand fixing agent and sand fixing method |
| CN114989833B (en) * | 2022-06-30 | 2024-03-22 | 润涵(山东)生态科技有限公司 | Ecological environment-friendly functional sand-fixing agent and sand-fixing method |
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