CN108682717A - A kind of preparation method of diamond position sensitive detector - Google Patents

A kind of preparation method of diamond position sensitive detector Download PDF

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CN108682717A
CN108682717A CN201810582199.1A CN201810582199A CN108682717A CN 108682717 A CN108682717 A CN 108682717A CN 201810582199 A CN201810582199 A CN 201810582199A CN 108682717 A CN108682717 A CN 108682717A
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diamond
electrode
sensitive detector
position sensitive
preparation
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CN108682717B (en
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代兵
朱嘉琦
王伟华
刘康
韩杰才
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Harbin Institute of Technology
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Harbin Institute of Technology
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0224Electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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  • Condensed Matter Physics & Semiconductors (AREA)
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  • Microelectronics & Electronic Packaging (AREA)
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  • Crystals, And After-Treatments Of Crystals (AREA)
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Abstract

A kind of preparation method of diamond position sensitive detector, the invention belongs to detector field, the electrode that it will solve existing two-dimension position-sensitive detector acts on single, the big problem in gap between adjacent electrode.Preparation method:One, single-crystal CVD diamond is placed in processing in the nitration mixture bath of boiling, the diamond after being cleaned;Two, mask plate is fixed on to the surface of diamond, the back side of diamond is pasted on the glass sheet;Three, diamond is placed in vacuum magnetron sputtering coating film system, and using magnetron sputtering deposition gold electrode, four central angles of deposition growing are the gold electrode of 90 ° of sector structures;Four, mask plate is detached;Five, the diamond for being coated with gold electrode is fixed on pad, electrode is connect with conducting wire with strip electrode on pcb pads respectively.The present invention is prepared for a kind of novel diamond position sensitive detector, has many advantages, such as that electrode structure is simple, electrode area is big, inter-electrode gap is small and particle beams transmitance is high.

Description

A kind of preparation method of diamond position sensitive detector
Technical field
The invention belongs to detector fields, and in particular to a kind of preparation method of metal sites sensitive detector.
Background technology
Position sensitive detector refers to that a kind of data-signal of output is presented with particle beam (including light beam) application position Therefore the semiconductor devices of certain relationship, this kind of detector are normally used for the monitoring of synchrotron radiation X-ray beam, radioactivity harness prison The fields such as survey and charged particle beam monitoring.Currently, common plan-position sensitive detector is mostly former based on lateral photo effect Reason, lateral photo effect refer to being parallel to the one of knot when P-N junction or the one side of metal-semiconductor junction are by uneven irradiation There is the phenomenon that potential difference in face.This kind of detector has four side type structures, two surface structures, two-dimentional pillow-type structure or square knot more Structure etc..
Diamond becomes a kind of excellent semi-conducting material by properties such as its excellent electricity, light, heat, mechanics.But due to Diamond is difficult to carry out n-type doping, so current diamond position sensitive detector is mostly based under lateral photo effect What metal-diamond knot carried out.
Invention content
The invention solves the effect of the electrode of existing two-dimension position-sensitive detector is single, gap is big between adjacent electrode asks Topic, and a kind of preparation method of diamond position sensitive detector is provided.
The preparation method of diamond position sensitive detector of the present invention is realized according to the following steps:
One, by single-crystal CVD diamond be placed in boiling nitration mixture bath in handle 30~60min, then successively deionized water, It is cleaned by ultrasonic 5~30min respectively in absolute ethyl alcohol and acetone, the diamond after being cleaned;
Two, by tool, there are four the stainless steel mask plates that central angle is 90 ° of sector structures to fix diamond after cleaning Surface, four central angles are that 90 ° of sector structures form circle, and the back side of the diamond after cleaning is pasted on the glass sheet, is obtained Diamond with sheet glass;
Three, Au targets are installed to magnetic controlled sputtering target, the diamond with sheet glass that step 2 obtains is placed in vacuum On warm table in magnetron sputtering coating system, start vacuum system will be evacuated in vacuum warehouse so that vacuum degree be 1.0 × 10-4~8.0 × 10-4Pa, using magnetron sputtering method, under the protection of Ar atmosphere, control Ar throughputs are 10~30sccm, control Sputtering power processed is that 30~50W carries out deposition gold electrode, and deposition growing is the gold electrode of 90 ° of sector structures there are four central angle, Obtaining sputtering has the diamond of electrode;
Four, stainless steel mask plate is separated from the diamond that sputtering has electrode, obtains the Buddha's warrior attendant for being coated with gold electrode Stone;
Five, the diamond for being coated with gold electrode is fixed on pad, four gold electrodes use conducting wire and four on pad respectively A strip electrode connection, obtains the diamond position sensitive detector of the two-dimension plane structure with four electrodes.
The present invention is when light beam through electrode, since area difference of the light irradiation in two lateral electrodes causes at Different electrodes Carrier concentration is different, and then there are potential differences in metal-semiconductor junction.The present invention is prepared for a kind of novel diamond position spirit Quick detector has many advantages, such as that electrode structure is simple, particle beams transmitance is high.
Diamond position sensitive detector of the present invention includes mainly following advantageous effect:
1, it is 90 ° of sector structures, simple in structure, the electrode of diamond surface that the electrode of diamond surface, which is four central angles, Not only collect photo-generated carrier, moreover it is possible to form metal-semiconductor junction with diamond, and then form built in field, promote carrier Diffusion drift;
2, electrode area is big, covers diamond surface substantially, enhances collection efficiency of the electrode to carrier, and between electrode Gap is only 0~1mm, is such as used for White-beam Synchrotron Radiation light beam detection field, there is superior sensitivity and transmitance.
Description of the drawings
Fig. 1 is the structural schematic diagram of diamond position sensitive detector of the present invention;
Fig. 2 is diamond position sensitive detector current signal under forward and reverse bias in test process under different biass Difference and light-beam position graph of relation, wherein ■ represent IU=100v+IU=-100v, ● represent IU=80v+IU=-80v, ▲ represent IU=60v +IU=-60v, ▼ represents IU=40v+IU=-40v, ◆ represent IU=20v+IU=-20v
Specific implementation mode
Specific implementation mode one:The preparation method of present embodiment diamond position sensitive detector is real according to the following steps It applies:
One, by single-crystal CVD diamond be placed in boiling nitration mixture bath in handle 30~60min, then successively deionized water, It is cleaned by ultrasonic 5~30min respectively in absolute ethyl alcohol and acetone, the diamond after being cleaned;
Two, by tool, there are four the stainless steel mask plates that central angle is 90 ° of sector structures to fix diamond after cleaning Surface, four central angles are that 90 ° of sector structures form circle, and the back side of the diamond after cleaning is pasted on the glass sheet, is obtained Diamond with sheet glass;
Three, Au targets are installed to magnetic controlled sputtering target, the diamond with sheet glass that step 2 obtains is placed in vacuum On warm table in magnetron sputtering coating system, start vacuum system will be evacuated in vacuum warehouse so that vacuum degree be 1.0 × 10-4~8.0 × 10-4Pa, using magnetron sputtering method, under the protection of Ar atmosphere, control Ar throughputs are 10~30sccm, control Sputtering power processed is that 30~50W carries out deposition gold electrode, and deposition growing is the gold electrode of 90 ° of sector structures there are four central angle, Obtaining sputtering has the diamond of electrode;
Four, stainless steel mask plate is separated from the diamond that sputtering has electrode, obtains the Buddha's warrior attendant for being coated with gold electrode Stone;
Five, the diamond for being coated with gold electrode is fixed on pad, four gold electrodes use conducting wire and four on pad respectively A strip electrode connection, obtains the diamond position sensitive detector of the two-dimension plane structure with four electrodes.
Present embodiment is contacted by metal-diamond-metal, is prepared for a kind of position sensitive detector, i.e. output electricity Flowing signal, there are certain linear relationships with beam position.
Present embodiment metallographic is higher than diamond to the surface contact potential of probe, according to the pass of work function and contact potential System, the fermi level for being derived by gold are higher than diamond.When gold is with diamond contact, the electronic carrier in gold is to diamond Diffusion forms depletion layer in diamond side, and when gold is equal with the fermi level of diamond, the diffusion of electronics stops, body System reaches dynamic equilibrium.The fermi level of diamond gradually rises, and energy band bends in depletion layer area, and interface energy level is bright It is aobvious to be less than inside diamond, so forming potential barrier, that is, built in field.After applying illumination, light beam through electrode is generated in depletion layer Electron-hole pair, electronics carry direction of an electric field drift, and hole drifts about towards direction of an electric field, this results in barrier height to reduce, energy Band bending degree reduces, but in the electrode zone of no light, barrier height does not reduce.When a forward bias is applied, voltage Direction is consistent with built in field direction;When a reverse bias is applied, voltage direction it is opposite with built in field direction thus generate Photo-signal has differences in size.With the change of light position, current signal the change of divergence.Current signal difference with Linear relationship is presented in position.
Specific implementation mode two:The present embodiment is different from the first embodiment in that the single-crystal CVD described in step 1 The size of diamond is 3.0 × 3.0mm2, thickness 0.5mm.
Specific implementation mode three:The present embodiment is different from the first and the second embodiment in that the nitration mixture in step 1 is Volume ratio is 1:1:The perchloric acid and mass fraction that nitric acid that 1 mass fraction is 68%, mass fraction are 70% are 98% sulphur The mixed acid of acid.
Specific implementation mode four:In step 1 unlike one of present embodiment and specific implementation mode one to three with The power ultrasonic of 300~600W cleans 15~30min.
Specific implementation mode five:Start in step 3 unlike one of present embodiment and specific implementation mode one to four Vacuum system will be evacuated in vacuum warehouse so that vacuum degree is 4.5 × 10-4Pa。
Specific implementation mode six:Step 3 uses magnetic unlike one of present embodiment and specific implementation mode one to five Control sputtering method, under the protection of Ar gas atmosphere, control Ar throughputs be 20sccm, control sputtering power for 40W carry out deposition 1~ 2min。
Specific implementation mode seven:Gold electricity in step 3 unlike one of present embodiment and specific implementation mode one to six The thickness of pole is 20~50nm.
Specific implementation mode eight:It is adjacent in step 3 unlike one of present embodiment and specific implementation mode one to seven The spacing of gold electrode is 0~1mm.
Specific implementation mode nine:Step 5 unlike one of present embodiment and specific implementation mode one to eight will be coated with The diamond of gold electrode is fixed on elargol on pad.
Specific implementation mode ten:Unlike one of present embodiment and specific implementation mode one to nine described in step 5 Conducting wire be silver wire.
Embodiment:The preparation method of the present embodiment diamond position sensitive detector is implemented according to the following steps:
One, it is 3.0 × 3.0mm by size2, thickness be 0.5mm single-crystal CVD diamond be placed in boiling nitration mixture bath Interior processing 40min, is then cleaned by ultrasonic 22.5min, after obtaining cleaning respectively in deionized water, absolute ethyl alcohol and acetone successively Diamond, wherein mixed strong acids be by volume ratio be 1:1:1 nitric acid:Perchloric acid:Sulfuric acid mixes;
Two, by tool, there are four the stainless steel mask plates that central angle is 90 ° of sector structures to fix diamond after cleaning Surface, four central angles are that 90 ° of sector structures form circle, and the back side of the diamond after cleaning is pasted onto 2.0 × 6.0cm2's On sheet glass, the diamond with sheet glass is obtained;
Three, Au targets are installed to magnetic controlled sputtering target, the diamond with sheet glass that step 2 obtains is placed in vacuum On warm table in magnetron sputtering coating system, start vacuum system will be evacuated in vacuum warehouse so that vacuum degree be 4.5 × 10-4Pa, using magnetron sputtering method, under the protection of Ar atmosphere, control Ar throughputs are 20sccm, and control sputtering power is 40W Deposition gold electrode is carried out, there are four the gold electrode that thickness is that 25nm central angles are 90 ° of sector structures, adjacent gold electrodes for deposition growing Spacing be 0.5mm, obtaining sputtering has the diamond of electrode;
Four, stainless steel mask plate is separated from the diamond that sputtering has electrode, obtains the Buddha's warrior attendant for being coated with gold electrode Stone;
Five, it is 2 × 2cm the diamond for being coated with gold electrode to be fixed on size with elargol2Plastic land on, four Gold electrode is connect with conducting wire with four strip electrodes on pcb pads respectively, obtains the two-dimension plane structure with four electrodes Diamond position sensitive detector.
The diamond position sensitive detector that the present embodiment obtains is tested for the property, is original with the center of circle of gold electrode Point selects two electrodes of A and B in Fig. 1, is biased from -100V and changes to 100V, and it is respectively 20V to obtain bias size, Under the conditions of 40V, 60V, 80V, 100V, the laser of the model DH2000 produced using OCEAN OPTICS companies is as compound Light source irradiates gold electrode, spot diameter 1.96mm, changes light-beam position along X-direction, and test obtains forward bias and anti- To the photoelectric current that bias size is different location under U.If I+UFor the photoelectricity that forward bias size under certain position is polychromatic light under U Stream, if I-UIt is the photoelectric current under polychromatic light under U for reverse biased size under certain position, current difference is Δ I=I+U+I-U;Root According to photoelectricity flow data, the variation relation curve graph of Δ I and X position is made, as shown in Figure 2.As seen from the figure, in certain distance range (-1.0mm<x<In 1.0mm), linear relationship is presented with light-beam position in current signal difference, this shows that the detector has well Position sensitive detecting function.

Claims (10)

1. a kind of preparation method of diamond position sensitive detector, it is characterised in that this method is to follow these steps to realize:
One, single-crystal CVD diamond is placed in the nitration mixture bath of boiling and handles 30~60min, then successively in deionized water, anhydrous It is cleaned by ultrasonic 5~30min respectively in ethyl alcohol and acetone, the diamond after being cleaned;
Two, the surface of the diamond by tool there are four the stainless steel mask plate that central angle is 90 ° of sector structures fixation after cleaning, Four central angles are that 90 ° of sector structures form circle, and the back side of the diamond after cleaning is pasted on the glass sheet, obtain carrying glass The diamond of glass piece;
Three, Au targets are installed to magnetic controlled sputtering target, the diamond with sheet glass that step 2 obtains is placed in vacuum magnetic control On warm table in sputter coating system, starting vacuum system will be evacuated in vacuum warehouse so that vacuum degree is 1.0 × 10-4 ~8.0 × 10-4Pa, using magnetron sputtering method, under the protection of Ar atmosphere, control Ar throughputs are 10~30sccm, and control is splashed It is that 30~50W carries out deposition gold electrode to penetrate power, and deposition growing is obtained there are four the gold electrode that central angle is 90 ° of sector structures Sputtering has the diamond of electrode;
Four, stainless steel mask plate is separated from the diamond that sputtering has electrode, obtains the diamond for being coated with gold electrode;
Five, the diamond for being coated with gold electrode is fixed on pad, four gold electrodes use conducting wire and four items on pad respectively Shape electrode connects, and obtains the diamond position sensitive detector of the two-dimension plane structure with four electrodes.
2. a kind of preparation method of diamond position sensitive detector according to claim 1, it is characterised in that step 1 The size of the single-crystal CVD diamond is 3.0 × 3.0mm2, thickness 0.5mm.
3. a kind of preparation method of diamond position sensitive detector according to claim 1, it is characterised in that step 1 In nitration mixture be volume ratio be 1:1:The perchloric acid and quality point that nitric acid that 1 mass fraction is 68%, mass fraction are 70% Number is the mixed acid of 98% sulfuric acid.
4. a kind of preparation method of diamond position sensitive detector according to claim 1, it is characterised in that step 1 In 15~30min cleaned with the power ultrasonic of 300~600W.
5. a kind of preparation method of diamond position sensitive detector according to claim 1, it is characterised in that step 3 Middle startup vacuum system will be evacuated in vacuum warehouse, and it is 4.5 × 10 to make vacuum degree in vacuum warehouse-4Pa。
6. a kind of preparation method of diamond position sensitive detector according to claim 1, it is characterised in that step 3 Using magnetron sputtering method, under the protection of Ar atmosphere, control Ar throughputs are 20sccm, and control sputtering power is that 40W is sunk 1~2min of product.
7. a kind of preparation method of diamond position sensitive detector according to claim 1, it is characterised in that step 3 The thickness of middle gold electrode is 20~50nm.
8. a kind of preparation method of diamond position sensitive detector according to claim 1, it is characterised in that step 3 In adjacent gold electrode spacing be 0~1mm.
9. a kind of preparation method of diamond position sensitive detector according to claim 1, it is characterised in that step 5 The diamond for being coated with gold electrode is fixed on elargol on pad.
10. a kind of preparation method of diamond position sensitive detector according to claim 1, it is characterised in that step 5 Described in conducting wire be silver wire.
CN201810582199.1A 2018-06-07 2018-06-07 Method for preparing diamond position sensitive detector Active CN108682717B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109001791A (en) * 2018-06-07 2018-12-14 哈尔滨工业大学 The beam position localization method of diamond position sensitive detector
CN111334761A (en) * 2020-04-02 2020-06-26 湖州中芯半导体科技有限公司 Method for preparing CVD diamond wafer with surface covered with metal grid
CN113917518A (en) * 2021-09-18 2022-01-11 中国原子能科学研究院 Device for measuring spatial distribution of different radiation components of irradiation beam for boron neutron capture treatment

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Patent Citations (1)

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Publication number Priority date Publication date Assignee Title
CN105006521A (en) * 2015-05-29 2015-10-28 金康康 Ultraviolet photoelectric detector based on PFH/n-SiC organic-inorganic heterostructure

Non-Patent Citations (2)

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KEWIN DESJARDINS等: ""Ultra-thin optical grade scCVD diamond as X-ray beam position monitor"", 《JOURNAL OF SYNCHROTRON RADIATION》 *
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109001791A (en) * 2018-06-07 2018-12-14 哈尔滨工业大学 The beam position localization method of diamond position sensitive detector
CN111334761A (en) * 2020-04-02 2020-06-26 湖州中芯半导体科技有限公司 Method for preparing CVD diamond wafer with surface covered with metal grid
CN113917518A (en) * 2021-09-18 2022-01-11 中国原子能科学研究院 Device for measuring spatial distribution of different radiation components of irradiation beam for boron neutron capture treatment

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