CN108676402A - A kind of environmentally-frieantirust antirust agent - Google Patents
A kind of environmentally-frieantirust antirust agent Download PDFInfo
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- CN108676402A CN108676402A CN201810669983.6A CN201810669983A CN108676402A CN 108676402 A CN108676402 A CN 108676402A CN 201810669983 A CN201810669983 A CN 201810669983A CN 108676402 A CN108676402 A CN 108676402A
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- ether
- antirust agent
- environmentally
- polyoxyethylene ether
- alkyl
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
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Abstract
The present invention relates to a kind of environmentally-frieantirust antirust agent, its raw material includes following components by weight percentage：Petroleum sodium sulfonate 3 ~ 5%；Dodecenylsuccinic acid sodium 5 ~ 10%；N, N diethyl ethylene diamine 6 ~ 10%；Benzene triazole 0.1 ~ 0.5%；Isomery fatty alcohol polyoxyethylene ether 5 ~ 10%；Alkylol monoalky lether 2 ~ 5%；Sorbitol monooleate 2 ~ 5%；1 alkyl, 3 methylimidazole haloid 3 ~ 8%；Surplus is cycloalkanes base oil.It can avoid using water in this way, in this way under low temperature, high temperature or super-humid conditions（Especially 10 DEG C hereinafter, 60 DEG C or more）Can overcome because water be demulsified and cause to emulsify unstable defect, be conducive to improve antirust agent stability and also rust-proof effect more preferably.
Description
Technical field
Industrial cleaning agent field of the present invention, is related to a kind of antirust agent, and in particular to a kind of environmentally-frieantirust antirust agent.
Background technology
Metal processing piece is during production and processing and transport, it is easy to get rusty, this is just needed using antirust oil in gold
Metal surface forms thin film, prevents the chemicals of corrosion of metal.So-called rust is since oxygen and water act on metal surface and generates
The mixture of oxide and hydroxide, iron rust are red, and patina is green, and the rust of aluminum and zinc claims white rust.Metal adds
Workpiece is difficult not contacted with oxygen, moisture or the other Korrosionsmediums in air in operation and storage, these substances are in metal
Surface will occur electrochemical corrosion and get rusty, and prevent corrosion from the above substance must be prevented to be contacted with metal.Antirust agent belongs to anti-
One kind of rust product.
Application No. is 201510418583.4 Chinese invention patents to be related to a kind of anti-rust emulsion oil and preparation method thereof, it
It is made of by weight percentage following components：Petroleum sodium sulfonate 5~10%；Barium mahogany sulfonate 5~10%；Dodecenylsuccinic acid
Sodium 3~6%；Polymaleic anhydride 1~3%；Triethanolamine 3~5%；Benzene triazole 0.1~1%；Fatty alcohol polyoxyethylene ether carboxylic
Acid 2~5%；Isomery fatty alcohol polyoxyethylene ether 5~10%；Diethylene glycol monobutyl ether 1~5%；Sorbitol monooleate 2~
5%；Water 2~5%；Surplus is cycloalkanes base oil；The anti-rust emulsion oil that compounding obtains in this way has more preferably antirust and emulsibility,
But its cold resistance, moisture-proof thermal energy are insufficient, and layering failure is easy under low temperature, super-humid conditions.
Invention content
A kind of environmentally-frieantirust antirust agent is provided the invention aims to overcome the deficiencies in the prior art.
In order to achieve the above objectives, the technical solution adopted by the present invention is：A kind of environmentally-frieantirust antirust agent, its raw material by weight hundred
It includes following components to divide ratio：
Petroleum sodium sulfonate 3~5%；
Dodecenylsuccinic acid sodium 5~10%；
N, N- diethyl ethylene diamine 6~10%；
Benzene triazole 0.1~0.5%；
Isomery fatty alcohol polyoxyethylene ether 5~10%；
Alkylol monoalky lether 2~5%；
Sorbitol monooleate 2~5%；
1- alkyl -3- methylimidazoles haloid 3~8%；
Surplus is cycloalkanes base oil.
Optimally, the alkylol monoalky lether is selected from glycol monoethyl ether, propylene glycol monomethyl ether, dipropylene glycol list first
Ether, poly glycol monomethyl ether, five glycol monomethyl ethers, tetraethylene glycol list nonyl ethers, diethylene glycol monoethyl ether, polypropylene glycol monobutyl base
The mixture of one or more compositions in ether, triethylene glycol monobutyl ether and tetraethylene glycol lauryl ether.
Optimally, the carbon atom number of alkyl is 10~18 in the 1- alkyl -3- methylimidazole haloids.
Further, the carbon atom number of the alkyl is 10~12, and halogen is chlorine element.
Optimally, the isomery fatty alcohol polyoxyethylene ether is poly- selected from heterogeneous ten alcohol polyoxyethylene ether, isomery undecyl alcohol
The mixture of one or more compositions in ethylene oxide ether and isomerous tridecanol polyoxyethylene ether.
Optimally, its raw material includes following components by weight percentage：
Petroleum sodium sulfonate 4%；
Dodecenylsuccinic acid sodium 8%；
N, N- diethyl ethylene diamine 8%；
Benzene triazole 0.1%；
Heterogeneous ten alcohol polyoxyethylene ether 8%；
Triethylene glycol monobutyl ether 1.5%；
Poly glycol monomethyl ether 1.5%；
Sorbitol monooleate 3%；
1- decyl -3- methylimidazole villaumites 5%；
Surplus is cycloalkanes base oil.
Since above-mentioned technical proposal is used, the present invention has following advantages compared with prior art：Environment-friendly antirust of the present invention
Agent, by using N, N- diethyl ethylene diamines, isomery fatty alcohol polyoxyethylene ether, alkylol monoalky lether etc. and 1- alkyl -3-
Methylimidazole haloid is coordinated, and can avoid using water in this way, in this way under low temperature, high temperature or super-humid conditions (especially-
10 DEG C hereinafter, 60 DEG C or more) it can overcome and cause to emulsify unstable defect because water is demulsified, be conducive to improve antirust agent
Stability and rust-proof effect is more preferably.
Specific implementation mode
Environmentally-frieantirust antirust agent of the present invention, its raw material include following components by weight percentage：Petroleum sodium sulfonate 3~5%；Ten
Dialkylene sodium succinate 5~10%；N, N- diethyl ethylene diamine 6~10%；Benzene triazole 0.1~0.5%；Isomery poly alkyl alcohol
Ethylene oxide ether 5~10%；Alkylol monoalky lether 2~5%；Sorbitol monooleate 2~5%；1- alkyl -3- methylimidazoles
Haloid 3~8%；Surplus is cycloalkanes base oil.By using N, N- diethyl ethylene diamines, isomery fatty alcohol polyoxyethylene ether,
Alkylol monoalky lether etc. is coordinated with 1- alkyl -3- methylimidazole haloids, can avoid using water in this way, in this way low
(especially -10 DEG C hereinafter, 60 DEG C or more) can overcome under temperature, high temperature or super-humid conditions causes emulsification unstable because water is demulsified
Fixed defect, be conducive to improve antirust agent stability and also rust-proof effect more preferably.
The alkylol monoalky lether is selected from glycol monoethyl ether, propylene glycol monomethyl ether, dipropylene glycol monomethyl ether, poly- second
It is glycol monomethyl ether, five glycol monomethyl ethers, tetraethylene glycol list nonyl ethers, diethylene glycol monoethyl ether, polypropylene glycol monobutyl base ether, three sweet
The mixture of one or more compositions in alcohol monobutyl ether and tetraethylene glycol lauryl ether, optimal is triethylene glycol monobutyl ether and poly- second
Glycol monomethyl ether in mass ratio 1:The mixture of 1 composition.The carbon atom number of alkyl in the 1- alkyl -3- methylimidazole haloids
Be 10~18, at this time usually have good emulsifying effectiveness, but carbon atom number be cannot it is excessive otherwise its be difficult to other components
It is compatible.The carbon atom number of alkyl is 10~12, and halogen is chlorine element.Isomery fatty alcohol polyoxyethylene ether is poly- selected from ten alcohol of isomery
The mixing of one or more compositions in ethylene oxide ether, isomery undecyl alcohol polyoxyethylene ether and isomerous tridecanol polyoxyethylene ether
Object, isomerous tridecanol polyoxyethylene ether are most common.Environmentally-frieantirust antirust agent is optimal to be：Its raw material include by weight percentage with
Lower component：Petroleum sodium sulfonate 4%；Dodecenylsuccinic acid sodium 8%；N, N- diethyl ethylene diamine 8%；Benzene triazole 0.1%；It is different
Ten alcohol polyoxyethylene ether 8% of structure；Triethylene glycol monobutyl ether 1.5%；Poly glycol monomethyl ether 1.5%；Sorbitol monooleate
3%；1- decyl -3- methylimidazole villaumites 5%；Surplus is cycloalkanes base oil.
The preferred embodiment of the invention will be described in detail below：
Embodiment 1
The present embodiment provides a kind of environmentally-frieantirust antirust agent, its raw material is：Petroleum sodium sulfonate 3kg, dodecenylsuccinic acid sodium
5kg, N, N- diethyl ethylene diamines 6kg, benzene triazole 0.1kg, isomerous tridecanol polyoxyethylene ether 5kg, glycol monoethyl ether
2kg, sorbitol monooleate 2kg, 1- decyl -3- methylimidazole villaumites 8kg, surplus are that (total amount is cycloalkanes base oil
100kg, similarly hereinafter)；
Its preparation method is included the following steps using routine：(a) the cycloalkanes base oil of formula ratio is added to reaction kettle
In, start blender；(b) petroleum sodium sulfonate, the N of formula ratio, N- diethyl ethylene diamines, ethylene glycol are sequentially added into reaction kettle
Monomethyl ether, isomerous tridecanol polyoxyethylene ether, sorbitol monooleate, 1- decyl -3- methylimidazole villaumites, laurylene base fourth
Diacid sodium and benzene triazole；A kind of lower raw material is added after the raw material stirring and dissolving of addition, after whole raw materials are added again
Continue stirring 2 hours；(c) blowing is packed after sampling analysis qualification.
Embodiment 2
The present embodiment provides a kind of environmentally-frieantirust antirust agent, it with it is almost the same in embodiment 1, unlike composition of raw materials
For：Petroleum sodium sulfonate 5kg, dodecenylsuccinic acid sodium 10kg, N, N- diethyl ethylene diamines 10kg, benzene triazole 0.5kg, isomery
Tridecanol polyoxyethylene ether 10kg, glycol monoethyl ether 5kg, sorbitol monooleate 5kg, 1- decyl -3- methylimidazole chlorine
Salt 3kg, surplus are cycloalkanes base oil.
Embodiment 3
The present embodiment provides a kind of environmentally-frieantirust antirust agent, it with it is almost the same in embodiment 1, unlike composition of raw materials
For：Petroleum sodium sulfonate 4kg, dodecenylsuccinic acid sodium 6kg, N, N- diethyl ethylene diamines 7kg, benzene triazole 0.2kg, isomery ten
Triol polyoxyethylene ether 8kg, glycol monoethyl ether 3kg, sorbitol monooleate 3kg, 1- decyl -3- methylimidazole villaumites
5kg, surplus are cycloalkanes base oil.
Embodiment 4
The present embodiment provides a kind of environmentally-frieantirust antirust agent, it with it is almost the same in embodiment 1, unlike composition of raw materials
For：Petroleum sodium sulfonate 4kg, dodecenylsuccinic acid sodium 8kg, N, N- diethyl ethylene diamines 8kg, benzene triazole 0.1kg, isomery ten
Triol polyoxyethylene ether 8kg, triethylene glycol monobutyl ether 1.5kg, poly glycol monomethyl ether 1.5kg, sorbitol monooleate 3kg,
1- decyl -3- methylimidazole villaumites 5kg, surplus are cycloalkanes base oil.
Embodiment 5
The present embodiment provides a kind of environmentally-frieantirust antirust agent, it with it is almost the same in embodiment 3, unlike：It uses
5kg1- dodecyl -3- methylimidazole bromides.
Embodiment 6
The present embodiment provides a kind of environmentally-frieantirust antirust agent, it with it is almost the same in embodiment 3, unlike：It uses
5kg1- octadecyl -3- methylimidazole salt compounded of iodine.
Comparative example 1
This example provides a kind of antirust agent, it with it is almost the same in embodiment 3, the difference is that：It is not added with 1- decyl -3- first
Base imidazoles villaumite 5kg.
Comparative example 2
This example provides a kind of antirust agent, it with it is almost the same in embodiment 3, the difference is that：It is not added with 1- decyl -3- first
Base imidazoles villaumite 5kg, but used the water of 5kg.
By the antirust agent of embodiment 1-6, comparative example 1-2 be respectively placed under super-humid conditions (relative humidity 80%), -10 DEG C
Stability test, salt fog cabinet, antirust ability test are carried out with 60 DEG C, the results are shown in Table 1.
The performance test table of antirust agent in 1 embodiment 1-6 of table, comparative example 1-2
The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow person skilled in the art
Scholar cans understand the content of the present invention and implement it accordingly, and it is not intended to limit the scope of the present invention, all according to the present invention
Equivalent change or modification made by Spirit Essence, should be covered by the protection scope of the present invention.
Claims (6)
1. a kind of environmentally-frieantirust antirust agent, which is characterized in that its raw material includes following components by weight percentage：
Petroleum sodium sulfonate 3 ~ 5%；
Dodecenylsuccinic acid sodium 5 ~ 10%；
N, N- diethyl ethylene diamine 6 ~ 10%；
Benzene triazole 0.1 ~ 0.5%；
Isomery fatty alcohol polyoxyethylene ether 5 ~ 10%；
Alkylol monoalky lether 2 ~ 5%；
Sorbitol monooleate 2 ~ 5%；
1- alkyl -3- methylimidazoles haloid 3 ~ 8%；
Surplus is cycloalkanes base oil.
2. environmentally-frieantirust antirust agent according to claim 1, it is characterised in that：The alkylol monoalky lether is selected from ethylene glycol
Monomethyl ether, propylene glycol monomethyl ether, dipropylene glycol monomethyl ether, poly glycol monomethyl ether, five glycol monomethyl ethers, tetraethylene glycol list nonyl
Ether, diethylene glycol monoethyl ether, polypropylene glycol monobutyl base ether, triethylene glycol monobutyl ether and one kind in tetraethylene glycol lauryl ether or
The mixture of a variety of compositions.
3. environmentally-frieantirust antirust agent according to claim 1, it is characterised in that：In the 1- alkyl -3- methylimidazole haloids
The carbon atom number of alkyl is 10 ~ 18.
4. environmentally-frieantirust antirust agent according to claim 3, it is characterised in that：The carbon atom number of the alkyl is 10 ~ 12, halogen
For chlorine element.
5. environmentally-frieantirust antirust agent according to claim 1, it is characterised in that：The isomery fatty alcohol polyoxyethylene ether be selected from
One or more groups in heterogeneous ten alcohol polyoxyethylene ether, isomery undecyl alcohol polyoxyethylene ether and isomerous tridecanol polyoxyethylene ether
At mixture.
6. environmentally-frieantirust antirust agent according to claim 1, which is characterized in that its raw material includes with the following group by weight percentage
Point：
Petroleum sodium sulfonate 4%；
Dodecenylsuccinic acid sodium 8%；
N, N- diethyl ethylene diamine 8%；
Benzene triazole 0.1%；
Heterogeneous ten alcohol polyoxyethylene ether 8%；
Triethylene glycol monobutyl ether 1.5%；
Poly glycol monomethyl ether 1.5%；
Sorbitol monooleate 3%；
1- decyl -3- methylimidazole villaumites 5%；
Surplus is cycloalkanes base oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810669983.6A CN108676402A (en) | 2018-06-26 | 2018-06-26 | A kind of environmentally-frieantirust antirust agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810669983.6A CN108676402A (en) | 2018-06-26 | 2018-06-26 | A kind of environmentally-frieantirust antirust agent |
Publications (1)
| Publication Number | Publication Date |
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| CN108676402A true CN108676402A (en) | 2018-10-19 |
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| CN201810669983.6A Pending CN108676402A (en) | 2018-06-26 | 2018-06-26 | A kind of environmentally-frieantirust antirust agent |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101503644A (en) * | 2008-12-15 | 2009-08-12 | 中国石油化工股份有限公司 | Method for producing anticorrosive oil composition |
| CN101724499A (en) * | 2009-10-23 | 2010-06-09 | 启东市合成化工厂有限公司 | Environment-friendly thixotropic antirust oil and manufacturing method thereof |
| CN102504918A (en) * | 2011-11-29 | 2012-06-20 | 上海博造实业有限公司 | Environmentally-friendly water-borne antirusting agent and preparation method thereof |
| CN105112132A (en) * | 2015-07-16 | 2015-12-02 | 路伯润滑油（苏州）有限公司 | Emulsified rust prevention oil and preparation method thereof |
| CN106929866A (en) * | 2017-04-20 | 2017-07-07 | 合肥华清金属表面处理有限责任公司 | A kind of Phosphateless environmentally friendly rust-removing and-preventing agent |
| CN107155367A (en) * | 2014-06-30 | 2017-09-12 | 恩特格里斯公司 | Aqueous and half aqueous cleaning agent of post-etch residues is removed using tungsten and cobalt compatibility |
-
2018
- 2018-06-26 CN CN201810669983.6A patent/CN108676402A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101503644A (en) * | 2008-12-15 | 2009-08-12 | 中国石油化工股份有限公司 | Method for producing anticorrosive oil composition |
| CN101724499A (en) * | 2009-10-23 | 2010-06-09 | 启东市合成化工厂有限公司 | Environment-friendly thixotropic antirust oil and manufacturing method thereof |
| CN102504918A (en) * | 2011-11-29 | 2012-06-20 | 上海博造实业有限公司 | Environmentally-friendly water-borne antirusting agent and preparation method thereof |
| CN107155367A (en) * | 2014-06-30 | 2017-09-12 | 恩特格里斯公司 | Aqueous and half aqueous cleaning agent of post-etch residues is removed using tungsten and cobalt compatibility |
| CN105112132A (en) * | 2015-07-16 | 2015-12-02 | 路伯润滑油（苏州）有限公司 | Emulsified rust prevention oil and preparation method thereof |
| CN106929866A (en) * | 2017-04-20 | 2017-07-07 | 合肥华清金属表面处理有限责任公司 | A kind of Phosphateless environmentally friendly rust-removing and-preventing agent |
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Application publication date: 20181019 |