CN107936806A - A kind of Environment-friendlywater-base water-base rust inhibitor - Google Patents
A kind of Environment-friendlywater-base water-base rust inhibitor Download PDFInfo
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/685—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen
- C08G63/6854—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen derived from polycarboxylic acids and polyhydroxy compounds
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- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
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- C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
- C09D171/02—Polyalkylene oxides
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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Abstract
The invention discloses the component composition of a kind of Environment-friendlywater-base water-base rust inhibitor, including following weight percents：Nonionic surfactant 1% 2%, water-soluble organic alcohol amine 10% 25%, polybasic carboxylic acid 5% 15%, corrosion inhibiter 1% 10%, film forming agent 1% 5%, defoamer 0.1% 0.5%, solubilizer 1% 5%, remaining is deionized water, and the sum of above-mentioned each component dosage is 100%；It is a kind of Environment-friendlywater-base water-base rust inhibitor compared with prior art, the present invention not containing the harmful substances such as nitrite, phosphorus and boron in this product；By water-soluble organic alcohol amine and the polycarboxylic acid crosslinked main body for forming this Environment-friendlywater-base water-base rust inhibitor, coordinate the use of film forming agent so as to obtain good rustless property；By being used cooperatively for solubilizer and nonionic surfactant, so as to enhance the stability of this Environment-friendlywater-base water-base rust inhibitor, the yellow transparent liquid that a kind of stability is strong and is evenly distributed is obtained.
Description
Technical field
The present invention relates to antirust reagent field, and in particular to a kind of Environment-friendlywater-base water-base rust inhibitor.
Background technology
Corrosion is the rotten of destruction or its performance of the metal caused by the reaction with surrounding medium.In process of production
Contacted with organic media, acid-alkali medium, all inevitably will corrode metal, cause the hidden danger of quality of product.
Metal processing piece is also easy to get rusty during production and processing and transport, and the solution of these hidden danger is required for using antirust
Product, i.e., form thin film in metal surface, prevents the chemicals of corrosion of metal.
So-called rust is due to the mixture that oxygen and water act on metal surface generation oxide and hydroxide, and iron rust is red
Color, patina is green, and the rust of aluminum and zinc claims white rust.Machinery be difficult in operation and storage not with the oxygen in air, wet
Gas or the contact of other Korrosionsmediums, these materials will occur electrochemical corrosion in metal surface and get rusty, and prevent corrosion just
Above material must be prevented to be contacted with metal.
Antirust process is generally divided into rust prevention during manufacture and product seals antirust up for safekeeping.Rust prevention during manufacture will make part adding in postorder
There is no corrosion during work, and surface rust-preventing film is easy to clean, may be selected to use water-based antirust or antirust oil.Aqueous rustproof
Agent is nontoxic or toxicity very little, smaller without smell or smell, will not burn, using such product metal works enter it is next
Without cleaning or only needing simply to clean before procedure, treatment process is enormously simplify, improves efficiency, is substituted plus with water
Organic solvent, environmental protection, fire prevention, operating personnel are endangered it is small, but for antirust oil, antirust cycle of water-based antirust
Shorter (usually within one month), therefore can not meet inter process standing time longer part.The antirust cycle of antirust oil
Normally about 1 year, it is ensured that the longer part not corrosion of inter process standing time, but antirust oil use cost is high, under part enters
Need to clean up Rust Preventing Oil Film before one process, take time and effort, and flash-point is low, it is inflammable, it is harmful containing aromatic hydrocarbon, lead etc.
Carcinogen, have escaping gas generation in use, pollute environment, homininoxious health.
Comprehensive each side considers that water-based antirust is commercially more more favourable than antirust oil, but is gathered around currently on the market
There is long-acting water-based antirust agent most of all containing harmful substances such as nitrite, phosphorus, boron, the harm after use to human body is compared
Greatly, it is easy to cause human body and suffers from a variety of diseases.
The content of the invention
For the deficiency in the presence of the prior art, it is an object of the invention to provide a kind of Environment-friendlywater-base water-base rust inhibitor,
With solution in the prior art, the problem of water-based antirust is not environmentally and antirust time is short.
To achieve the above object, present invention employs following technical solution：A kind of Environment-friendlywater-base water-base rust inhibitor, including under
The component composition of row percentage by weight：
The sum of above-mentioned each component dosage is 100%.
Optimization, the water solubility organic alcohol amine is at least one of monoethanolamine, triethanolamine, isopropanolamine or more
Kind.
Optimization, the water solubility organic alcohol amine is monoethanolamine and the mixture of triethanolamine.
Optimization, the polybasic carboxylic acid is 11 carbon monoacid, eleven carbon diacids, dodecanedicarboxylic acid, decanedioic acid, new
At least one of capric acid, isononanoic acid, isomer fatty acids, two glyceric acid of polyoxyethylene are a variety of.
Optimization, the polybasic carboxylic acid is the mixture of dodecanedicarboxylic acid, decanedioic acid and isomer fatty acids.
Optimization, the nonionic surfactant for nonylphenol polyoxyethylene ether, octyl phenol polyoxyethylene ether, C12~
C18 fatty alcohol polyoxyethylene ether, fatty acid methyl ester ethoxylate, ethylene oxide adduct, sorbitan fatty acid ester gather
At least one of ethylene oxide ether, alkylolamides derivative are a variety of.
Optimization, the film forming agent is at least one of aqueous polyurethane, polycarboxylic acid, fatty acid amide or a variety of.
Optimization, the corrosion inhibiter is silicate, dimethylsilane, molybdate, at least one of benzotriazole or
It is a variety of.
Optimization, the defoamer is silicone emulsion, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene season penta
Four alcohol ethers, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether, polyoxyethylene polyoxypropylene glycerin ether, poly dimethyl silicon
At least one of oxygen alkane is a variety of；
Optimization, the solubilizer is alkenyl succinic anhydride, organic long-chain carboxylic acid, in dodecyl benzene sulfonate at least
It is one or more.
Compared with the prior art, the present invention has the advantages that：
1st, the harmful substances such as nitrite, phosphorus and boron are not contained in this product, are a kind of Environment-friendlywater-base water-base rust inhibitors；
2nd, by water-soluble organic alcohol amine and the polycarboxylic acid crosslinked main body for forming this Environment-friendlywater-base water-base rust inhibitor, with synthesis
The use of film is so as to obtain good rustless property；
3rd, being used cooperatively by solubilizer and nonionic surfactant, so as to enhance this Environment-friendlywater-base water-base rust inhibitor
Stability, obtain the yellow transparent liquid that a kind of stability is strong and is evenly distributed.
Embodiment
Below by embodiment to Environment-friendlywater-base water-base rust inhibitor of the present invention in the laboratory of Company in Chongqing into
It is prepared by row：
Embodiment 1
Step 1：2kg fatty acid methyl ester ethoxylates, 8kg triethanolamines, 15kg monoethanolamines, 8kg ten are weighed successively
Two carbon dicarboxylic acids, 4kg decanedioic acid, 3kg isomer fatty acids, 5kg aqueous polyurethanes, 2kg silicates, 1kg benzotriazole,
0.2kg dimethyl silicone polymers, 1kg alkenyl succinic anhydrides and 50.8kg deionized waters；
Step 2：Load weighted triethanolamine, monoethanolamine, dodecanedicarboxylic acid, decanedioic acid and isomer fatty acids are added
Enter in dissolving tank, the 10kg deionized waters being then added thereto into dissolving tank, 80 DEG C -90 is heated to by the temperature in dissolving tank
DEG C, it is stirred using the mixing speed of 60-80r/min, is completely dissolved each component；
Step 3：Then remaining deionized water is added in dissolving tank, then by load weighted fatty acid methyl ester ethoxy
Glycolylate, aqueous polyurethane, silicate, benzotriazole, dimethyl silicone polymer and alkenyl succinic anhydride are added to dissolving tank
In, constantly stirring is completely dissolved each component.
Embodiment 2
Step 1：0.5kg nonylphenol polyoxyethylene ether, 0.5kg octyl phenol polyoxyethylene ether, 10kg isopropanols are weighed successively
Amine, two glyceric acid of 5kg polyoxyethylene, 0.5kg polycarboxylic acids, 0.5kg fatty acid amides, 1kg molybdates, 0.05kg high-carbon alcohol esters
Fat acid esters compound, 0.05kg polyoxyethylene polyoxypropylene pentaerythrites ether, 0.5kg organic long-chains carboxylic acid, 0.5kg dodecyls
Benzene sulfonate and 80.9kg deionized waters；
Step 2：Load weighted isopropanolamine and two glyceric acid of polyoxyethylene are added in dissolving tank, then to dissolving tank
In the 10kg deionized waters that are added thereto, the temperature in dissolving tank is heated to 80 DEG C -90 DEG C, using the stirring of 60-80r/min
Speed is stirred, and is completely dissolved each component；
Step 3：Then remaining deionized water is added in dissolving tank, then by load weighted Nonyl pheno
Ether, octyl phenol polyoxyethylene ether, polycarboxylic acid, fatty acid amide, molybdate, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene
Polyoxypropylene pentaerythrite ether, organic long-chain carboxylic acid and dodecyl benzene sulfonate are added in dissolving tank, and constantly stirring makes
Each component is completely dissolved.
Embodiment 3
Step 1：Weigh successively 0.5kg ethylene oxide adducts, 0.5kg sorbitan fatty acid esters polyoxyethylene ether,
0.5kg alkylolamideses derivative, 5kg monoethanolamines, 5kg triethanolamines, 7kg isopropanolamines, 5kg neodecanoic acids, the different nonyls of 5kg
Acid, 2kg silicates, 3kg dimethylsilanes, 3kg polycarboxylic acids, 0.3kg polyoxyethylene polyoxypropylenes glycerin ether, 2kg have captain
Chain carboxylic acid, 1kg dodecyl benzene sulfonates and 60.2kg deionized waters；
Step 2：Load weighted monoethanolamine, triethanolamine, isopropanolamine, neodecanoic acid and isononanoic acid are added into dissolving tank
In, the 10kg deionized waters that are then added thereto into dissolving tank, are heated to 80 DEG C -90 DEG C by the temperature in dissolving tank, use
The mixing speed of 60-80r/min is stirred, and is completely dissolved each component；
Embodiment 4
Step 1：Weigh successively 1kgC12~C18 fatty alcohol polyoxyethylene ether, 1kg fatty acid methyl ester ethoxylates,
12kg triethanolamines, 13kg isopropanolamines, 11 carbon monoacid of 7kg, two glyceric acid of 8kg polyoxyethylene, 3kg dimethylsilanes,
3kg molybdates, 4kg benzotriazole, 5kg fatty acid amides, 0.2kg silicone emulsions, 0.3kg higher alcohols are fatty acid ester compounded
Thing, 5kg organic long-chains carboxylic acid and 37.5kg deionized waters；
Step 2：Load weighted triethanolamine, isopropanolamine, 11 carbon monoacid and two glyceric acid of polyoxyethylene are added
In dissolving tank, the temperature in dissolving tank is heated to 80 DEG C -90 by the 10kg deionized waters that are then added thereto into dissolving tank
DEG C, it is stirred using the mixing speed of 60-80r/min, is completely dissolved each component；
Step 3：Then remaining deionized water is added in dissolving tank, then by load weighted C12~C18 fatty alcohols
Polyoxyethylene ether, fatty acid methyl ester ethoxylate, dimethylsilane, molybdate, benzotriazole, fatty acid amide, emulsification
The fatty acid ester compounded thing of silicone oil, higher alcohols and organic long-chain carboxylic acid are added in dissolving tank, and constantly stirring makes each component complete
Fully dissolved.
Embodiment 5
Step 1：2kg fatty acid methyl ester ethoxylates, 8kg triethanolamines, 15kg isopropanolamines, 8kg ten are weighed successively
Two carbon dicarboxylic acids, two glyceric acid of 4kg polyoxyethylene, 3kg isomer fatty acids, 5kg aqueous polyurethanes, 2kg silicates, 1kg benzos
Triazole, 0.2kg dimethyl silicone polymers, 1kg alkenyl succinic anhydrides and 50.8kg deionized waters；
Step 2：By load weighted triethanolamine, isopropanolamine, dodecanedicarboxylic acid, two glyceric acid of polyoxyethylene and different
Structure aliphatic acid is added in dissolving tank, and the 10kg deionized waters being then added thereto into dissolving tank, the temperature in dissolving tank is added
Heat is stirred using the mixing speed of 60-80r/min to 80 DEG C -90 DEG C, is completely dissolved each component；
Step 3：Then remaining deionized water is added in dissolving tank, then by load weighted fatty acid methyl ester ethoxy
Glycolylate, aqueous polyurethane, silicate, benzotriazole, dimethyl silicone polymer and alkenyl succinic anhydride are added to dissolving tank
In, constantly stirring is completely dissolved each component.
Embodiment 6
Step 1：2kg fatty acid methyl ester ethoxylates, 8kg monoethanolamines, 15kg isopropanolamines, the 8kg last of the ten Heavenly stems are weighed successively
Diacid, 4kg neodecanoic acids, 3kg isononanoic acids, 5kg aqueous polyurethanes, 2kg silicates, 1kg benzotriazole, 0.2kg poly dimethyls
Siloxanes, 1kg alkenyl succinic anhydrides and 50.8kg deionized waters；
Step 2：Load weighted monoethanolamine, isopropanolamine, decanedioic acid, neodecanoic acid and isononanoic acid are added in dissolving tank,
Then the 10kg deionized waters being added thereto into dissolving tank, are heated to 80 DEG C -90 DEG C, using 60- by the temperature in dissolving tank
The mixing speed of 80r/min is stirred, and is completely dissolved each component；
Step 3：Then remaining deionized water is added in dissolving tank, then by load weighted fatty acid methyl ester ethoxy
Glycolylate, aqueous polyurethane, silicate, benzotriazole, dimethyl silicone polymer and alkenyl succinic anhydride are added to dissolving tank
In, constantly stirring is completely dissolved each component.
Embodiment 7
Step 1：Weigh successively 1kg fatty acid methyl ester ethoxylates, 1kg ethylene oxide adducts, 8kg monoethanolamines,
15kg isopropanolamines, 8kg dodecanedicarboxylic acid, 4kg decanedioic acid, 3kg neodecanoic acids, 5kg aqueous polyurethanes, 1kg benzotriazole,
0.2kg dimethyl silicone polymers, 1kg alkenyl succinic anhydrides and 52.8kg deionized waters；
Step 2：Load weighted monoethanolamine, isopropanolamine, dodecanedicarboxylic acid, decanedioic acid and neodecanoic acid are added molten
Solving in groove, the 10kg deionized waters being then added thereto into dissolving tank, 80 DEG C -90 DEG C are heated to by the temperature in dissolving tank,
It is stirred using the mixing speed of 60-80r/min, is completely dissolved each component；
Step 3：Then remaining deionized water is added in dissolving tank, then by load weighted fatty acid methyl ester ethoxy
Glycolylate, ethylene oxide adduct, aqueous polyurethane, benzotriazole, dimethyl silicone polymer and alkenyl succinic anhydride add
Into dissolving tank, constantly stirring is completely dissolved each component.
It will be detected by Environment-friendlywater-base water-base rust inhibitor made from embodiment 1- embodiments 7 by following experimental method
Obtain the data in table 1：
1 multigroup embodiment of table detects data
Data in table 1 can analyze：It is made that a kind of stability is strong, is in by the formula of embodiment 1- embodiments 7
The yellow transparent liquid of alkalescence, is mainly reached by the cooperation of solubilizer and nonionic surfactant and improves its appearance and steady
Qualitative energy；Its rustless property is detected by QB/T 2117-199 experimental methods, has exceeded professional standard, is had preferable anti-
Rust performance；Its corrosive nature is detected by JB/T 4323.2-1999 experimental methods, detection base is used as by brass and LY12 aluminium
Plate, show that the corrosive nature grade of Environment-friendlywater-base water-base rust inhibitor more than 1 grade, has good Corrosion Protection；Comparative example
Detection data in 1- embodiments 7 can be seen that by Environment-friendlywater-base water-base rust inhibitor effect made from the formula of embodiment 1 more
It is excellent, contrasted by embodiment 1, embodiment 5 and embodiment 6, analyze the effect of embodiment 1 more preferably the reason is that passing through three second
The water-soluble organic alcohol amines of hydramine, two kinds of monoethanolamine and dodecanedicarboxylic acid, decanedioic acid, isomer fatty acids these three polybasic carboxylic acids
Compounding forms and obtains a kind of more efficient Environment-friendlywater-base water-base rust inhibitor.
By Environment-friendlywater-base water-base rust inhibitor made from the formula of embodiment 1 with existing water-based antirust product respectively according to following
Experimental method carry out 20 groups of contrast experiments, each performance detection data is averaged, draws the experiment number in table 2
According to：
The detection data of table 2 and existing water-based antirust product
It can be seen that by detecting data in table 2：By Environment-friendlywater-base water-base rust inhibitor made from the formula of embodiment 1 and now
There is water-based antirust product to compare, there is more preferable rustless property and Corrosion Protection, mainly pass through water-soluble organic alcohol amine
With the main body of polycarboxylic acid crosslinked this Environment-friendlywater-base water-base rust inhibitor of formation, coordinate the use of film forming agent so as to obtain good antirust
Performance, and with the addition of the harmful substances such as a certain amount of nitrite, phosphorus and boron in existing water-based antirust, is using it
During easily human body is damaged, belong to environmentally friendly machine compared to by water-based antirust made from this formula, meet city
The demand of field.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to compared with
The present invention is described in detail in good embodiment, it will be understood by those of ordinary skill in the art that, can be to the skill of the present invention
Art scheme technical scheme is modified or replaced equivalently, without departing from the objective and scope of technical solution of the present invention, it should all cover at this
Among the right of invention.
Claims (10)
- A kind of 1. Environment-friendlywater-base water-base rust inhibitor, it is characterised in that the component composition including following weight percents：The sum of above-mentioned each component dosage is 100%.
- A kind of 2. Environment-friendlywater-base water-base rust inhibitor according to claim 1, it is characterised in that：It is described water solubility organic alcohol amine be At least one of monoethanolamine, triethanolamine, isopropanolamine are a variety of.
- A kind of 3. Environment-friendlywater-base water-base rust inhibitor according to claim 2, it is characterised in that：It is described water solubility organic alcohol amine be The mixture of monoethanolamine and triethanolamine.
- A kind of 4. Environment-friendlywater-base water-base rust inhibitor according to claim 1, it is characterised in that：The polybasic carboxylic acid is 11 carbon Monoacid, eleven carbon diacids, dodecanedicarboxylic acid, decanedioic acid, neodecanoic acid, isononanoic acid, isomer fatty acids, polyoxyethylene two are sweet At least one of oleic acid is a variety of.
- A kind of 5. Environment-friendlywater-base water-base rust inhibitor according to claim 4, it is characterised in that：The polybasic carboxylic acid is 12 carbon The mixture of binary acid, decanedioic acid and isomer fatty acids.
- A kind of 6. Environment-friendlywater-base water-base rust inhibitor according to claim 1, it is characterised in that：The nonionic surfactant For nonylphenol polyoxyethylene ether, octyl phenol polyoxyethylene ether, C12~C18 fatty alcohol polyoxyethylene ether, fatty acid methyl ester ethyoxyl At least one of compound, ethylene oxide adduct, sorbitan fatty acid ester polyoxyethylene ether, alkylolamides derivative It is or a variety of.
- A kind of 7. Environment-friendlywater-base water-base rust inhibitor according to claim 1, it is characterised in that：The film forming agent is water-based poly- ammonia At least one of ester, polycarboxylic acid, fatty acid amide are a variety of.
- A kind of 8. Environment-friendlywater-base water-base rust inhibitor according to claim 1, it is characterised in that：The corrosion inhibiter for silicate, At least one of dimethylsilane, molybdate, benzotriazole are a variety of.
- A kind of 9. Environment-friendlywater-base water-base rust inhibitor according to claim 1, it is characterised in that：The defoamer is emulsification silicon Oil, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polyoxy At least one of propylene glycerin ether, polyoxyethylene polyoxypropylene glycerin ether, dimethyl silicone polymer are a variety of.
- A kind of 10. Environment-friendlywater-base water-base rust inhibitor according to claim 1, it is characterised in that：The solubilizer is alkenyl amber At least one of amber acid anhydrides, organic long-chain carboxylic acid, dodecyl benzene sulfonate are a variety of.
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| CN108707905A (en) * | 2018-06-04 | 2018-10-26 | 合肥汇之新机械科技有限公司 | A kind of novel antirust agent and preparation method thereof |
| CN109129758A (en) * | 2018-07-25 | 2019-01-04 | 佛山市华格化工有限公司 | The clean method and detergent of edge sealing of furniture plate |
| CN109763120A (en) * | 2018-12-19 | 2019-05-17 | 长沙艾森设备维护技术有限公司 | The more water-base metal antirusting agents of environment-friendly type and preparation method |
| CN109913626A (en) * | 2019-04-29 | 2019-06-21 | 南京正明观新材料有限公司 | A kind of hardening media and preparation method thereof |
| CN110042397A (en) * | 2019-05-24 | 2019-07-23 | 南京工业大学 | A kind of water-based antirust agent and preparation method thereof |
| CN111253815A (en) * | 2020-02-17 | 2020-06-09 | 丫肯(上海)新材料科技有限公司 | Antirust agent and preparation method thereof |
| CN111808457A (en) * | 2020-05-29 | 2020-10-23 | 烟台康恩环保科技有限公司 | Film forming agent and preparation method and application thereof |
| CN112877126A (en) * | 2021-01-12 | 2021-06-01 | 吉林省海孚生物科技有限公司 | Environment-friendly water-based antirust agent |
| CN114456871A (en) * | 2022-01-12 | 2022-05-10 | 浙江机电职业技术学院 | Water-soluble metal surface antirust agent and use method thereof |
| CN116043229A (en) * | 2022-12-30 | 2023-05-02 | 富兰克润滑科技（太仓）有限公司 | Environment-friendly tubing liquid friendly to galvanized layer and preparation method thereof |
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| CN109129758A (en) * | 2018-07-25 | 2019-01-04 | 佛山市华格化工有限公司 | The clean method and detergent of edge sealing of furniture plate |
| CN109763120A (en) * | 2018-12-19 | 2019-05-17 | 长沙艾森设备维护技术有限公司 | The more water-base metal antirusting agents of environment-friendly type and preparation method |
| CN109913626A (en) * | 2019-04-29 | 2019-06-21 | 南京正明观新材料有限公司 | A kind of hardening media and preparation method thereof |
| CN110042397A (en) * | 2019-05-24 | 2019-07-23 | 南京工业大学 | A kind of water-based antirust agent and preparation method thereof |
| CN111253815A (en) * | 2020-02-17 | 2020-06-09 | 丫肯(上海)新材料科技有限公司 | Antirust agent and preparation method thereof |
| CN111808457A (en) * | 2020-05-29 | 2020-10-23 | 烟台康恩环保科技有限公司 | Film forming agent and preparation method and application thereof |
| CN112877126A (en) * | 2021-01-12 | 2021-06-01 | 吉林省海孚生物科技有限公司 | Environment-friendly water-based antirust agent |
| CN114456871A (en) * | 2022-01-12 | 2022-05-10 | 浙江机电职业技术学院 | Water-soluble metal surface antirust agent and use method thereof |
| CN114456871B (en) * | 2022-01-12 | 2022-12-13 | 浙江机电职业技术学院 | Water-soluble metal surface antirust agent and use method thereof |
| CN116043229A (en) * | 2022-12-30 | 2023-05-02 | 富兰克润滑科技（太仓）有限公司 | Environment-friendly tubing liquid friendly to galvanized layer and preparation method thereof |
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