CN106398376A - Printing ink cleaning fluid and preparation method thereof - Google Patents
Printing ink cleaning fluid and preparation method thereof Download PDFInfo
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- CN106398376A CN106398376A CN201610854990.4A CN201610854990A CN106398376A CN 106398376 A CN106398376 A CN 106398376A CN 201610854990 A CN201610854990 A CN 201610854990A CN 106398376 A CN106398376 A CN 106398376A
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- printing ink
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/04—Chemical paint or ink removers with surface-active agents
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention provides a printing ink cleaning fluid. The printing ink cleaning fluid comprises, by weight, 10-15 parts of dibutyl phosphite, 4-8 parts of sodium oleate, 4-8 parts of polyolefin acid, 6-20 parts of water-soluble nonionic surfactants, 2-6 parts of anionic surfactants, 2-6 parts of adjuvants and 90-110 parts of water. A preparation method includes the steps of 1) adding the dibutyl phosphite, the sodium oleate, the polyolefin acid, the water-soluble nonionic surfactants and parts of the water into a mixing kettle, heating to 60-70 DEG C and stirring till full dissolution; 2) adding the anionic surfactants, the adjuvants and the left water into the mixing kettle, stirring uniformly and cooling to the room temperature. The printing ink cleaning fluid is high in cleaning efficiency, safety, non-toxic, non-volatile and non-corrosive.
Description
Technical field
The invention belongs to detergent for ink technical field is and in particular to a kind of printing ink cleanout fluid and its preparation side
Method.
Background technology
China's printing industry development is swift and violent, defines product in developed regions such as Pearl River Delta, the Yangtze River Delta, Bohai Economic Rim
Industry band, and just in accelerated development, just receive much concern because the regional economy that China's press has increases bright spot.And in printing
While producing high speed development, the demand as requisite auxiliary material detergent for ink in printing also will increasingly
Greatly.Printing enterprise of China there are about 170,000 at present, and every printing equipment of Mei Jia enterprise monthly at least consumes 100 liters of abluents,
From this, the whole nation demand at least 6.12 hundred million liters of printing ink washing agent every year, and the Yangtze River Delta, Pearl River Delta area are then
Occupy about 70% ratio, therefore, printing ink washing agent has huge market capacity.
Currently used abluent is mainly the pure solvent solvent such as gasoline, kerosene, clear with pure solvent such as gasoline, kerosene
Lotion is to clean ink roller, blanket has a lot of drawbacks：First, gasoline, kerosene contain volatile material, flash-point low it is easy to
There is the perils such as fire, consumption is big, high cost, environmental pollution is serious, and the healthy injury to worker is larger；The
Two, a large amount of aromatic compounds containing in gasoline, kerosene, easily make the swell rubber of ink roller, affect printing quality, to being attached to
The cleaning performance of the water-soluble stains such as the paper hair on ink roller, paper powder, Radix Acaciae senegalis is not good, easily makes various impurity heap from level to level
Amass on ink roller surface, make ink roller ink transfer hydraulic performance decline, affect printing effect；3rd, gasoline, kerosene consumes substantial amounts of oil, right
Environmental resource causes certain burden.With the attention to environmental protection for the whole world, printing industry is also green in promotion low-carbon environment-friendly
Color prints, and a lot of clients require that all correlation printing materials will meet environmental requirement.
Content of the invention
The present invention proposes a kind of printing ink cleanout fluid, the clean dirt efficiency high of this abluent, safety non-toxic, no waves
Send out, there are no corrosivity.
The technical scheme is that and be achieved in that：
A kind of printing ink cleanout fluid, is prepared by the raw materials in：
10～15 parts of di-n-butyl phosphite, 4～8 parts of enuatrol, 4～8 parts of polyolefin acid, water-soluble nonionic surface activity
6～20 parts of agent, 2～6 parts of anion surfactant, 2～6 parts of auxiliary agent and 90～110 parts of water；Described auxiliary agent is by following weight portion
Raw material make：Carboxymethyl cellulose 4～6,4～8 parts of organic silicon surfactant Silwet408, N- palmitamide glycine betaine 2
～4 parts, 2～4 parts of silane coupler KH-580 and 10～15 parts of ethanol.
Further, the preparation method of auxiliary agent is：By carboxymethyl cellulose, N- palmitamide glycine betaine, silane coupler KH-
580 are mixed with ethanol, are heated to 50～60 DEG C, after stirring 20～30 minutes, add other residual componentss, are warming up to 65～75
DEG C, stir 30～40 minutes, obtain final product.
Further, water soluble nonionic surfactant is polyoxyethylene sorbitan fatty acid ester, fatty alcohol polyoxy
The mixture that vinyl Ether is formed with inositol six di-n-butyl phosphite, mass ratio is 2～5:3～6:1.
Further, anion surfactant is fatty acid monoalkyl sulfonate or alkylsulfonate.
It is a further object to provide a kind of printing ink cleans liquid and preparation method thereof, comprise the following steps：
1) by di-n-butyl phosphite, enuatrol, polyolefin acid, water soluble nonionic surfactant and part under room temperature
Water adds in mixing kettle, after being heated to 60～70 DEG C, stirs to being completely dissolved；
2) will be stirred uniformly in anion surfactant, auxiliary agent and excess water heating and mixing still, with 3000～
6000 revs/min of speed stirs 3～4 minutes, is subsequently cooled to room temperature.
Further, the preparation method of auxiliary agent is：By carboxymethyl cellulose, N- palmitamide glycine betaine, silane coupler KH-
580 are mixed with ethanol, are heated to 50～60 DEG C, after stirring 20～30 minutes, add other residual componentss, are warming up to 65～75
DEG C, stir 30～40 minutes, obtain final product.
Beneficial effects of the present invention：
1st, the present invention adds auxiliary agent, improves the processing performance of abluent, reduces its toxic and side effects and the pollution to environment；
Cleansing power of the present invention is strong, clean dirt efficiency high, safety non-toxic, non-volatile, does not have corrosivity, properties of product are stable, system
Make low cost.
2nd, the printing ink cleanout fluid flash-point of the present invention is high, up to 95～100 DEG C, performance test results such as table 1 below：
The performance test results of the printing ink cleanout fluid of table 1 present invention
| Detection project | Technical specification | Testing result |
| Washing power | 90% | 98 |
| Foaming properties | (5min height)≤20 | 4 |
| Stability | Uniformly, not stratified | Conformance with standard specifies |
| No. 45 steel corrosions | 0 grade ,≤2mg | 0 grade, 0.04mg |
| LY12 duralumin corrosivity | 0 grade ,≤2mg | 0 grade, 0.01mg |
Specific embodiment
Embodiment 1
Auxiliary agent is prepared by the raw materials in：Carboxymethyl cellulose 4,4 parts of organic silicon surfactants
2 parts of Silwet408, N- palmitamide glycine betaine, 2 parts of silane coupler KH-580 and 10 parts of ethanol.
The preparation method of auxiliary agent is：By carboxymethyl cellulose, N- palmitamide glycine betaine, silane coupler KH-580 and second
Alcohol mixes, and is heated to 50 DEG C, after stirring 30 minutes, adds other residual componentss, is warming up to 65 DEG C, stirs 40 minutes, obtains final product
The formula of printing ink cleanout fluid is：
10 parts of di-n-butyl phosphite, 4 parts of enuatrol, 4 parts of polyolefin acid, 6～20 parts of water soluble nonionic surfactant,
3 parts of fatty acid monoalkyl sodium sulfonate, 2 parts of auxiliary agent and 90 parts of water；Water soluble nonionic surfactant is polyoxyethylene sorbitan mountain
The mixture of pears alcohol fatty acid ester, fatty alcohol-polyoxyethylene ether and inositol six di-n-butyl phosphite composition, mass ratio is 2:3:
1.
Printing ink cleans liquid and preparation method thereof, comprises the following steps：
1) by di-n-butyl phosphite, enuatrol, polyolefin acid, water soluble nonionic surfactant and part under room temperature
Water adds in mixing kettle, after being heated to 60 DEG C, stirs to being completely dissolved；
2) will be stirred uniformly in fatty acid monoalkyl sodium sulfonate, auxiliary agent and excess water heating and mixing still, with 3000
Rev/min speed stir 3 minutes, be subsequently cooled to room temperature.
Embodiment 2
Auxiliary agent is prepared by the raw materials in：Carboxymethyl cellulose 5,5 parts of organic silicon surfactants
3 parts of Silwet408, N- palmitamide glycine betaine, 3 parts of silane coupler KH-580 and 12 parts of ethanol.
The preparation method of auxiliary agent is：By carboxymethyl cellulose, N- palmitamide glycine betaine, silane coupler KH-580 and second
Alcohol mixes, and is heated to 55 DEG C, after stirring 24 minutes, adds other residual componentss, is warming up to 70 DEG C, stirs 35 minutes, obtains final product.
The formula of printing ink cleanout fluid is：
12 parts of di-n-butyl phosphite, 6 parts of enuatrol, 5 parts of polyolefin acid, 10 parts of water soluble nonionic surfactant, alkane
4 parts of base sodium sulfonate, 3 parts of auxiliary agent and 100 parts of water；Water soluble nonionic surfactant is polyoxyethylene sorbitan fatty acid
The mixture of ester, fatty alcohol-polyoxyethylene ether and inositol six di-n-butyl phosphite composition, mass ratio is 3:4:1.
Printing ink cleans liquid and preparation method thereof, comprises the following steps：
1) by di-n-butyl phosphite, enuatrol, polyolefin acid, water soluble nonionic surfactant and part under room temperature
Water adds in mixing kettle, after being heated to 65 DEG C, stirs to being completely dissolved；
2) will be stirred uniformly in sodium alkyl sulfonate, auxiliary agent and excess water heating and mixing still, with 4000 revs/min of speed
Degree stirring 4 minutes, is subsequently cooled to room temperature.
Embodiment 3
Auxiliary agent is prepared by the raw materials in：Carboxymethyl cellulose 6,8 parts of organic silicon surfactants
4 parts of Silwet408, N- palmitamide glycine betaine, 4 parts of silane coupler KH-580 and 15 parts of ethanol.
The preparation method of auxiliary agent is：By carboxymethyl cellulose, N- palmitamide glycine betaine, silane coupler KH-580 and second
Alcohol mixes, and is heated to 60 DEG C, after stirring 20 minutes, adds other residual componentss, is warming up to 75 DEG C, stirs 30 minutes, obtains final product.
The formula of printing ink cleanout fluid is：
15 parts of di-n-butyl phosphite, 8 parts of enuatrol, 8 parts of polyolefin acid, 20 parts of water soluble nonionic surfactant, alkane
6 parts of base potassium sulfonate, 6 parts of auxiliary agent and 110 parts of water
A kind of printing ink cleans liquid and preparation method thereof, comprises the following steps：
1) by di-n-butyl phosphite, enuatrol, polyolefin acid, water soluble nonionic surfactant and part under room temperature
Water adds in mixing kettle, after being heated to 70 DEG C, stirs to being completely dissolved；
2) will be stirred uniformly in alkyl sulfonic acid potassium, auxiliary agent and excess water heating and mixing still, with 6000 revs/min of speed
Degree stirring 4 minutes, is subsequently cooled to room temperature.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention
Within god and principle, any modification, equivalent substitution and improvement made etc., should be included within the scope of the present invention.
Claims (6)
1. a kind of printing ink cleanout fluid is it is characterised in that be prepared by the raw materials in：
10～15 parts of di-n-butyl phosphite, 4～8 parts of enuatrol, 4～8 parts of polyolefin acid, water soluble nonionic surfactant 6
～20 parts, 2～6 parts of anion surfactant, 2～6 parts of auxiliary agent and 90～110 parts of water；Described auxiliary agent is by following weight portion
Raw material is made：Carboxymethyl cellulose 4～6,4～8 parts of organic silicon surfactant Silwet408, N- palmitamide glycine betaine 2～
4 parts, 2～4 parts of silane coupler KH-580 and 10～15 parts of ethanol.
2. printing ink cleanout fluid according to claim 1 is it is characterised in that the preparation method of auxiliary agent is：By carboxylic first
Base cellulose, N- palmitamide glycine betaine, silane coupler KH-580 are mixed with ethanol, are heated to 50～60 DEG C, stirring 20～
After 30 minutes, add other residual componentss, be warming up to 65～75 DEG C, stir 30～40 minutes, obtain final product.
3. printing ink cleanout fluid according to claim 1 and 2 is it is characterised in that water-soluble nonionic surface activity
Agent is polyoxyethylene sorbitan fatty acid ester, fatty alcohol-polyoxyethylene ether and inositol six di-n-butyl phosphite composition mixed
Compound, mass ratio is 2～5:3～6:1.
4. printing ink cleanout fluid according to claim 1 and 2 is it is characterised in that anion surfactant is fat
Fat acid monoalkyl sulfonate or alkylsulfonate.
5. a kind of printing ink cleaning liquid and preparation method thereof as claimed in claim 1 is it is characterised in that comprise the following steps：
1) under room temperature, di-n-butyl phosphite, enuatrol, polyolefin acid, water soluble nonionic surfactant and part water are added
Enter in mixing kettle, after being heated to 60～70 DEG C, stir to being completely dissolved；
2) will be stirred uniformly in anion surfactant, auxiliary agent and excess water heating and mixing still, with 3000～6000
Rev/min speed stir 3～4 minutes, be subsequently cooled to room temperature.
6. printing ink according to claim 5 cleaning liquid and preparation method thereof is it is characterised in that the preparation method of auxiliary agent
For：Carboxymethyl cellulose, N- palmitamide glycine betaine, silane coupler KH-580 are mixed with ethanol, are heated to 50～60 DEG C,
After stirring 20～30 minutes, add other residual componentss, be warming up to 65～75 DEG C, stir 30～40 minutes, obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610854990.4A CN106398376A (en) | 2016-09-27 | 2016-09-27 | Printing ink cleaning fluid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610854990.4A CN106398376A (en) | 2016-09-27 | 2016-09-27 | Printing ink cleaning fluid and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106398376A true CN106398376A (en) | 2017-02-15 |
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ID=57997571
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610854990.4A Pending CN106398376A (en) | 2016-09-27 | 2016-09-27 | Printing ink cleaning fluid and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116333426A (en) * | 2022-12-22 | 2023-06-27 | 广州敬信高聚物科技有限公司 | Waterproof low-dielectric thermoplastic elastomer insulating material for charging pile cable and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101434764A (en) * | 2007-11-15 | 2009-05-20 | 中国石油化工股份有限公司 | Printing ink cleaning agent |
| CN101824243A (en) * | 2010-04-19 | 2010-09-08 | 江苏海迅实业集团股份有限公司 | Micro-emulsion ink cleaning agent and preparation method thereof |
| CN102120901A (en) * | 2010-12-15 | 2011-07-13 | 浙江传化华洋化工有限公司 | Paper-making environmentally-friendly mineral deinking agent |
| CN103214898A (en) * | 2013-04-26 | 2013-07-24 | 南京信息工程大学 | Water-based printing ink cleaning agent and preparation method thereof |
-
2016
- 2016-09-27 CN CN201610854990.4A patent/CN106398376A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101434764A (en) * | 2007-11-15 | 2009-05-20 | 中国石油化工股份有限公司 | Printing ink cleaning agent |
| CN101824243A (en) * | 2010-04-19 | 2010-09-08 | 江苏海迅实业集团股份有限公司 | Micro-emulsion ink cleaning agent and preparation method thereof |
| CN102120901A (en) * | 2010-12-15 | 2011-07-13 | 浙江传化华洋化工有限公司 | Paper-making environmentally-friendly mineral deinking agent |
| CN103214898A (en) * | 2013-04-26 | 2013-07-24 | 南京信息工程大学 | Water-based printing ink cleaning agent and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116333426A (en) * | 2022-12-22 | 2023-06-27 | 广州敬信高聚物科技有限公司 | Waterproof low-dielectric thermoplastic elastomer insulating material for charging pile cable and preparation method thereof |
| CN116333426B (en) * | 2022-12-22 | 2024-01-09 | 广州敬信高聚物科技有限公司 | Waterproof low-dielectric thermoplastic elastomer insulating material for charging pile cable and preparation method thereof |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20170215 |