CN108654357A - A kind of biological treatment device for the three wastes that burn and artificial microecosystem - Google Patents
A kind of biological treatment device for the three wastes that burn and artificial microecosystem Download PDFInfo
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- CN108654357A CN108654357A CN201810717232.7A CN201810717232A CN108654357A CN 108654357 A CN108654357 A CN 108654357A CN 201810717232 A CN201810717232 A CN 201810717232A CN 108654357 A CN108654357 A CN 108654357A
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- wastes
- pseudomonas
- biological treatment
- treatment device
- heat
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- 239000002699 waste material Substances 0.000 title claims abstract description 75
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 65
- 239000007788 liquid Substances 0.000 claims abstract description 47
- 239000007921 spray Substances 0.000 claims abstract description 30
- 238000006243 chemical reaction Methods 0.000 claims abstract description 28
- 239000007789 gas Substances 0.000 claims description 49
- 238000006477 desulfuration reaction Methods 0.000 claims description 27
- 230000023556 desulfurization Effects 0.000 claims description 27
- 230000029553 photosynthesis Effects 0.000 claims description 23
- 238000010672 photosynthesis Methods 0.000 claims description 23
- 238000012545 processing Methods 0.000 claims description 15
- 241000589516 Pseudomonas Species 0.000 claims description 13
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 12
- 239000000523 sample Substances 0.000 claims description 12
- 241000894006 Bacteria Species 0.000 claims description 11
- 241001453380 Burkholderia Species 0.000 claims description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 11
- 239000005864 Sulphur Substances 0.000 claims description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 11
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- 239000002028 Biomass Substances 0.000 claims description 5
- 239000003153 chemical reaction reagent Substances 0.000 claims description 5
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- 238000010564 aerobic fermentation Methods 0.000 claims description 4
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- 241000206602 Eukaryota Species 0.000 claims description 3
- 241000605716 Desulfovibrio Species 0.000 claims description 2
- 238000009434 installation Methods 0.000 claims 1
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- 238000000034 method Methods 0.000 abstract description 16
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- 239000002893 slag Substances 0.000 abstract description 4
- 238000012851 eutrophication Methods 0.000 abstract description 2
- 238000000746 purification Methods 0.000 description 23
- 239000003546 flue gas Substances 0.000 description 14
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 13
- 239000000126 substance Substances 0.000 description 10
- 239000002956 ash Substances 0.000 description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 239000003463 adsorbent Substances 0.000 description 8
- 239000001963 growth medium Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
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- 238000002485 combustion reaction Methods 0.000 description 6
- 239000002351 wastewater Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000002054 inoculum Substances 0.000 description 5
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- 239000000920 calcium hydroxide Substances 0.000 description 3
- 229940041514 candida albicans extract Drugs 0.000 description 3
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- 239000003245 coal Substances 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 229910000396 dipotassium phosphate Inorganic materials 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 238000002386 leaching Methods 0.000 description 3
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000012138 yeast extract Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 241000195493 Cryptophyta Species 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- 235000011116 calcium hydroxide Nutrition 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000010531 catalytic reduction reaction Methods 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000002803 fossil fuel Substances 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 230000010354 integration Effects 0.000 description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 239000013618 particulate matter Substances 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000012137 tryptone Substances 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- 241001495402 Nitrococcus Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 241001148470 aerobic bacillus Species 0.000 description 1
- FRHBOQMZUOWXQL-UHFFFAOYSA-L ammonium ferric citrate Chemical compound [NH4+].[Fe+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FRHBOQMZUOWXQL-UHFFFAOYSA-L 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052564 epsomite Inorganic materials 0.000 description 1
- 229960004642 ferric ammonium citrate Drugs 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000004313 iron ammonium citrate Substances 0.000 description 1
- 235000000011 iron ammonium citrate Nutrition 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000006166 lysate Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 230000037323 metabolic rate Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical group 0.000 description 1
- 230000007269 microbial metabolism Effects 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 230000009935 nitrosation Effects 0.000 description 1
- 238000007034 nitrosation reaction Methods 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000003716 rejuvenation Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 210000001533 respiratory mucosa Anatomy 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000009919 sequestration Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Inorganic materials [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000031068 symbiosis, encompassing mutualism through parasitism Effects 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/18—Absorbing units; Liquid distributors therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/84—Biological processes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
- F28D21/0001—Recuperative heat exchangers
- F28D21/0003—Recuperative heat exchangers the heat being recuperated from exhaust gases
- F28D21/001—Recuperative heat exchangers the heat being recuperated from exhaust gases for thermal power plants or industrial processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/102—Nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/302—Sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Biodiversity & Conservation Biology (AREA)
- Microbiology (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Treating Waste Gases (AREA)
- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
Abstract
The present invention provides a kind of biological treatment devices for the three wastes that burn, the device is made up of bio-reaction system, liquid and waste slag produced pretreatment system, heat-exchange system, spray gas-liquid exchange system placed in series, and synchronization process of the microorganism to the three wastes that burn is realized by water cycle, element circular and energy circulation.The present invention also provides a kind of Tiny ecosystem systems for handling the artificial component of the burning three wastes.Pass through the present apparatus, it can efficiently remove and purify the pollutant in the burning three wastes, avoid the secondary pollution of water quality, effectively realize the efficient utilization of nutrient, the eutrophication mode of production is greatly promoted the output efficiency of biological product, and economic benefit is huge, and operation cost is cheap, environment and industrial contradiction are coordinated, there is good social benefit.
Description
Technical field
The present invention relates to biological cleaning field, the biological treatment device of specially a kind of burning three wastes and artificial microecosystem
System.
Background technology
The burning of the fossil fuels such as coal, oil and natural gas will produce CO2、SO2、NOx, particulate matter and ash grade, largely
Discharge is concentrated to will result in serious environment and ecological problem in the combustion product short time.Wherein CO2Gas have heat absorption and every
The function of heat, formed in air after covering make solar radiation to tellurian heat can not outer layers space divergence, formed warm
Room effect, causes global warming.SO2Gas can be done directly on respiratory mucosa, cause disease, a large amount of SO2, it is granular material discharged
Sulfuric acid type smog can be formed.NOxGas includes NO, NO2、N2O5Deng being toxic gas, work as NOxContent accumulates to a certain dense
Degree, can form the photochemical fog of toxicity and harmfulness bigger.Particulate matter and ash content, which are discharged into air, can cause PM2.5 and PM10 dirty
Dye.
In the prior art, common sulfur method has：Limestone-gypsum method, indirect limestone-gypsum method, lemon absorb
Method etc., method of denitration has：（1）Selective non-catalytic reduction denitration（SNCR）;（2）It is selective-catalytic-reduction denitrified（SCR）.More than
Traditional desulphurization and denitration, discharge-reducing method investment are big, and energy consumption is high, need to consume the moneys such as a large amount of CaCO3, NH3, urea, lye catalyst
The product in source, generation cannot efficiently use, abandon transportation energy consumption cost, stack occupy a large amount of soils, some it is water-soluble in
Substance can cause secondary pollution again.In these three wastes, other than harmful substance, still there is the nutrition such as a large amount of N, P, K, Mg member
Element directly abandons undoubtedly a kind of huge waste.In patent CN105483013A, discloses a kind of synchronized using microalgae and produce
Oil, carbon sequestration, desulfurization, the method and apparatus except nitre, this application are handled exhaust gas using microalgae, compensate for biography to a certain extent
The deficiency for chemical method of uniting, but still there is following defect：1. the device is only handled exhaust gas, to waste water, waste residue it is net
Change processing without reference to；2 devices need additional addition culture medium that can realize the culture to microalgae and the processing to exhaust gas, at
This height, and the essential element in the three wastes is not efficiently used；3. the device utilizes specific single purebred algae
Using lacking the support of other biological in corresponding ecosystem, metabolic process is easy to be obstructed, and can not utilize certain members
Element, the even toxicity of some elements can poison algae, be extremely limited to eutrophic absorbability；4. the device is to open
Device, it is possible to generating secondary pollution after water body discharge that treated, and it is high to consume energy；5. the end product of the device is only oil
Fat is small using space.
Invention content
The purpose of the present invention one is to provide one kind and overcomes the shortage of prior art, at a kind of biology for the three wastes that burn of proposition
Manage device.
Biological treatment device provided by the invention includes such as lower part：Bio-reaction system, liquid and waste slag produced pretreatment system,
Heat-exchange system, spray gas-liquid exchange system, by placed in series between each system.
The specific design scheme of each system is as follows：
Bio-reaction system includes aerobic tank, photosynthesis physiological target and clarifying basin, and three parts are sequentially connected by pipeline.Its
In, be prokaryotes system in aerobic tank, including Burkholderia category, Nitrosomonas, Desulfovibrio, desulfurization Pseudomonas,
Desulfococcus, desulfurization line Pseudomonas and sulphur removal monospore Pseudomonas；It is eucaryote system, including chlorella in photosynthesis physiological target
Belong to and hydrogen bites born of the same parents Pseudomonas；The water pipe for being provided with water pump outside clarifying basin and being connected at the top of spray column, by purified water pump to spray
It drenches in tower and recycles, water pump is powered using external circuits.
Waste residue and liquid pretreatment system is a dissolving tank with deslagging device, and dissolving tank is interior using water as solvent, crosses and filters out
Solution after slag is entered by pipeline in photosynthesis physiological target, and burning waste liquid is by waste liquid entrance together with the waste liquid after slagging-off
Into photosynthesis physiological target.
Heat-exchange system is a heat exchanger, and heat is completed in the heat absorbing sheet air inlet pipe connection of stack gases inlet tube and heat exchanger
The stack gases of exchange are discharged from the outlet of heat absorbing sheet, and the heat absorbing sheet of heat exchanger absorbs heat from stack gases, passes through Jie
Matter cycle transfers heat to cooling fin, and cooling fin is installed on bioreactor bottom and surrounding, has connection external in heat exchanger
The circulating pump of circuit.
Spraying gas-liquid exchange system top has water inlet, and the side wall close to bottom has air inlet, by water from spray column
Top is eluted with the stack gases that fog-like liquid enters air inlet, and the soluble substance in flue gas is soluble in water, spray
Leaching carries bottom, and there is water outlet, water outlet to be connected to bio-reaction system with tube shaped.Spray system is designed using recirculated water,
The clarifying basin of water inlet and bio-reaction system connects, and is extracted by water pump and enters spray by the purified water of bio-reaction system
Tower.Spray column top sidewall has gas outlet, and the flue gas of preliminary purification is discharged into the light of bio-reaction system by pipeline
It closes in bioreactor.
Preferably, there is equipment for separating liquid from solid in light and reaction tank in bio-reaction system of the present invention, it is described
Equipment for separating liquid from solid is mechanical solid-liquid separator, such as belt grid.
Preferably, biological treatment device of the present invention further includes heavy metal adsorption tower, the heavy metal adsorption tower in
Between heat-exchange system outlet and the pipeline of spray column air inlet, filling carbon-based adsorbent, flying dust, mineral substance are inhaled in adsorption tower
Attached dose, metal class adsorbent, metal compound species adsorbent and complexing adsorbent.
Preferably, with by the automatic of PLC or SCM system integrated control in heat-exchange system of the present invention
Temperature control system, temperature are set as between 28-39 DEG C, if temperature is less than setting value, control system opens heat-exchange system
Circulating pump makes the hot water in heating tube flow, if temperature of reactor is higher than set temperature, stops circulating pump.
Preferably, being provided in bio-reaction system of the present invention by PLC or SCM system integrated control
PH automatic regulating systems include mainly that pH pops one's head in, power cycle unit and reagent adding device.PH value be set in 6.6 ~ 8.5 it
Between, if being less than setting value, there is control system control reagent addition pump operation, add milk of lime（Ca(OH)2）If be higher than
Setting value then organic acids such as adding citric acid or acetic acid.
Preferably, being provided with by PLC or microcontroller in light and reaction tank in bio-reaction system of the present invention
The illumination system of system integration control, includes mainly illumination probe and data processing unit and artificial light source, in continuous 72h, from
In the case of the intensity of illumination of right light is less than 60,000 lx, then control system opens artificial light source, to maintain the high reaction of biosystem to live
Property.
The illumination system, auto temperature controlled system and pH automatic regulating systems are powered by external circuitry.
Preferably, in biological treatment device of the present invention between heat-exchange system gas outlet and heavy metal adsorption tower
Flue on equipped with air blower, air valve and gas flow meter.
Another object of the present invention is to provide a kind of artificial constructed microecosystem for handling the burning three wastes.It should
Microecosystem specifically includes following bacterial strain：Burkholderia categoryBurkholderia, NitrosomonasNitrosomonas,
DesulfovibrioDesulfovibrio, desulfurization PseudomonasDesulfobacter, DesulfococcusDesulfococcus, desulfurization line
PseudomonasDesulfonema, sulphur removal monospore PseudomonasDesulfuromonas,ChlorellaChlorella, hydrogen bites born of the same parents PseudomonasHydrogenophaga。Wherein Burkholderia categoryBurkholderia 2.7x104 CFU/L, NitrosomonasNitrosomonas 8.6x104CFU/L, DesulfovibrioDesulfovibrio, desulfurization PseudomonasDesulfobacter, desulfurization
CoccusDesulfococcus, desulfurization line PseudomonasDesulfonema, sulphur removal monospore PseudomonasDesulfuromonasIt is
5.9x103 CFU/L, above-mentioned Mixed Microbes constitute aerobic fermentation system；ChlorellaChlorella 9.9x105CFU/L, hydrogen are bitten
Born of the same parents PseudomonasHydrogenophaga 6.4x104CFU/L, the mixing of above two bacterium constitute photosynthetic response system.Two system connection
With a kind of artificial constructed microecosystem for handling fossil energy and the biomass combustion three wastes of composition.
Biological treatment device of the present invention for handle the three wastes that burn is in a manner of recirculated water, by water from spray column
Top elutes flue gas with fog-like liquid, and flue gas obtains preliminary purification by the leaching of interior recirculated water, purification
Gas afterwards is discharged by the gas outlet of spray column in photosynthesis physiological target.Recirculated water can will be readily soluble in the oxidation of water
State metal（CaO、TiO2、MgO、K2O、Na2O etc.）, oxidation state it is nonmetallic（P2O5、SO3Deng）And part soluble gas（SO2、
NO2Deng）, the relatively low gas of partial solubility（CO2, NO etc.）It is dissolved into water body, water body forms eutrophic water body, and eutrophic water body is first
Aerobic tank is flowed into, part aerobic bacteria and chemoheterotrophy microorganism, such as nitrococcus are made, some harmful components in water body are carried out
Aerobic conversion makes compound valence state close to highest oxidation valence state, reduces toxicity as possible.The part for being dissolvable in water water in waste residue is logical
It crosses waste residue and liquid pretreatment system and enters photosynthesis physiological target, the nutrient in the lysate and waste liquid of waste residue（Predominantly：
MgO、K2O、Na2O、SO3、P2O5）It is added in photosynthesis physiological target, the flue gas of the preliminary purification of spray column discharge, mainly
Ingredient is undissolved CO2And N2, the space above photosynthesis physiological target water body is full of in the form of high concentrations of gas, with highly concentrated
The CO of degree2Promote the photosynthetic carbon fixation efficiency of aquatic objects system.All pollutions that burning generates are enriched in photosynthesis physiological target,
Including exhaust gas, lime-ash, waste liquid, the eutrophy cultivating system of high concentration is formed.Due in exhaust gas be mainly nonmetal oxide and
With acidity, main water dissolution ingredient is metal oxide in lime-ash, has alkalinity, both substances right in the bioreactor
PH value adjustment effect makes pH value close to neutrality, can directly carry out bioconversion.At this time photosynthesis physiological target using it is photosynthetic from
Health object it is quick to nutrient（N, P, K etc.）Assimilation be absorbed into vivo, form a large amount of biomass, while making dirt
Dye water body is purified becomes oligotrophic water body again, and the water body after photosynthesis physiological target is completed to be separated by solid-liquid separation enters clarification
Pond reenters spray column, aerobic tank, photosynthesis physiological target by water pump in clarifying basin and constantly recycles.It is detached in clarifying basin
Obtained biomass can enter biological feedstuff, bioenergy, bio-feritlizer etc. and be used as product output.In stack gases
The bio-reaction system that heat supplies energy to require temperature by heat-exchange system adjusts temperature by auto temperature controlled system
Degree ensures the growth conditions of microorganism in bio-reaction system.The setting of heavy metal adsorption tower can be by the huge sum of money in flue gas
Belong to substance to be pre-processed, to reduce the toxicity of stack gases, ensures the activity of microorganism in the present apparatus, improve the net of the present apparatus
Change efficiency.It is water-soluble to the three wastes that the pH automatic regulating systems and illumination system added in the present apparatus can improve microorganism in the present apparatus
The metabolic rate of nutriment in liquid improves purification efficiency, promotes the stability of microecosystem in the present apparatus, to further drop
Low cost.
Biological treatment device provided by the present invention for the processing burning three wastes is at the synchronization to waste water,waste gas and industrial residue
It manages, mutually auxiliary phase for the stability of microecosystem of the nutrient contained in three kinds of wastes for maintaining artificial component
At indispensable.
There are three cycle specificities for biological treatment device tool of the present invention for handling the burning three wastes：1. recirculated water is special
Sign.Life is derived from water, and recirculated water of the invention is both used as solvent, the nutriment in the exhaust gas, lime-ash, waste water of burning generation
Dissolving enters in water.It can be used as bio-culture solution again, suitable living environment is created for living matter.2. element circular is special
Sign.The present invention original nature, inherently move in the plant and equipment of the confined space by existing element circular, makes biological cleaning
Process, bioenergy process with thermal power plant burning production capacity process be combined, using Tiny ecosystem reconstruction the Nature itself
Purification function and ecological circulation.3. flue residue heat utilizes.The present invention is the waste heat of burning and exhausting and the temperature requirements of biological culture
Combine, forms low energy consumption, energy circulation production system.
Artificial microecosystem of the present invention for handling the burning three wastes is to combine to repair by Natural Selection to give birth to
The principles such as state, microbiology are added to a series of some engineering bacterias with specific function that can accelerate to decompose, purify
Strain, is considered by degradation capability and symbiosis, one efficient degradation of component, and the artificial Tiny ecosystem of each bacterial strain Co Existence
System, to ensure that a kind of Effec-tive Function for handling the biological treatment device of the burning three wastes of the present invention.
A kind of biological treatment device for handling the burning three wastes of the present invention is from element circular, first in fact
The removal and purification for having showed pollutant, it is huge to reduce carbon emission ecological benefits, after the present apparatus is to stack gas cleaning, discharge it is net
Change SO in gas2Removal efficiency reach 77.1%, NOx（With NO2Meter）Removal efficiency reach 78%, SO2With NOx indexs through the present invention
Treated that gas can reach for described device《Fossil-fuel power plant atmospheric pollutant emission standard GB13223-2011》Emission request；Cigarette
Road gas dissolves in the CO in water2Removal rate reaches 93% or so, to the SO being dissolved into water2Removal rate reaches 94% or so, avoids water
The secondary pollution of matter effectively realizes the efficient utilization of nutrient；By dissolving and biological treatment, the nutrient in waste residue
Also great utilization has been obtained, the dissolving utilization rate of N is 74.6%, P 69.6%, K 95.1%；The present apparatus is utilized largely
C, the biological elements such as N, S, P, K and some trace elements, handle the three wastes, i.e. flue gas, waste water and waste residue, to molten using the present apparatus
The utilization rate of nutrient in water is higher, and the utilization rate that the utilization rate that the utilization rate of Fe is 99.9%, Mg is 99.7%, K is
The utilization rate that the utilization rate of 99%, Ca are 95.5%, P is 96.7%, S 84.1%, and the eutrophication mode of production is greatly promoted
The output efficiency of biological product, can be with productions such as broad incorporation planting industry, feed, chemical fertilizer, cultivation, health products, biological industry, agriculturals
Industry, economic benefit are huge；The autotrophy or rain for realizing biology are supported, and entire industrial chain does not need the purchase of material, operating cost
It is cheap；The invention belongs to biological industrys, itself is pollution-free, belongs to no pollution industry；Secondary dirt is not generated to the processing of pollutant
Dye；The design of UTILIZATION OF VESIDUAL HEAT IN enhances biological productivity but also the utilization ratio of the energy increases；Environment and industry are coordinated
The contradiction of production；An emerging bioconversion industry is created, employment is increased, there is good social benefit.
Description of the drawings
Fig. 1 is the structural schematic diagram of embodiment 1.
In figure, 1 is aerobic tank, and 2 be photosynthesis physiological target, and 3 be clarifying basin, and 4 be pipeline, and 5 be equipment for separating liquid from solid, 6
It is dissolving tank for spray column, 7,8 be heat exchanger, and 9 be smoke inlet pipe, and 10 be outlet, and 11 be cooling fin, and 12 be air blower,
13 be air valve, and 14 be gas flowmeter, and 15 be water inlet, and 16 be air inlet, and 17 be water outlet, and 18 be gas outlet, and 19 be a huge sum of money
Belong to adsorption tower, 20 be waste liquid entrance, and 21 be water pump, and 22 be fluid flowmeter.
Specific implementation mode
With reference to specific implementation example, the present invention is described in detail.Following embodiment contributes to the skill in this field
Art personnel further understand the present invention, but the invention is not limited in any way.
Bacterial strain selected by following embodiment is Burkholderia categoryBurkholderia, NitrosomonasNitrosomonas, DesulfovibrioDesulfovibrio, desulfurization PseudomonasDesulfobacter, DesulfococcusDesulfococcus, desulfurization line PseudomonasDesulfonema, sulphur removal monospore PseudomonasDesulfuromonas,ChlorellaChlorella, hydrogen bites born of the same parents PseudomonasHydrogenophaga,Above-mentioned bacterial strains are preserved by this laboratory.
The culture medium prescription used in following embodiment is as follows：
LB culture mediums：Tryptone (Tryptone) 10g/L, yeast extract (Yeast extract) 5g/L, sodium chloride
(NaCl) 10g/L
Nitromonas bacteria culture media：(NH4)2SO42g/L, NaCl 0.3g/L, FeSO47H2O 0.03g/L,
K2HPO41g/L, MgSO47H2O 0.03g/L, NaHCO3 1.6g/L。
S metabolizing bacteria culture mediums：NaCl 2g/L, NH4Cl 1g/L, K2HPO40.5g/L, Na2PO40.5g/L, MgSO4
7H2O 2g/L, CaCl20.1g/L, FeSO4 (NH4)( SO4)26H2O 0.5g/L, 70% lactic acid 5mL/L, yeast extract 1g/L.
Green alga culture medium: NaNO315.0 g/L, K2HPO4 4g/L dH2O, MgSO4·7H2O 7.53.75 g/L,
CaCl2·2H2O 3.6 g/L, Citric acid 0.6 g/L, Ferric ammonium citrate 0.6g/l, EDTANa2
0.1g/L, Na2CO3 2.0g/L。
Each element and method for measuring components are as follows in liquid in following embodiment：
Each method for measuring components is as follows in gas in following embodiment：
Embodiment one builds biological treatment device
As shown in Figure 1, a kind of biological treatment device for the three wastes that burn of structure.This biological treatment device includes such as lower part：
Bio-reaction system, liquid and waste slag produced pretreatment system, heat-exchange system, spray gas-liquid exchange system, by pipeline string between each system
Connection.
In Fig. 1, bio-reaction system includes aerobic tank 1, photosynthesis physiological target 2 and clarifying basin 3, and three parts pass through pipe
Road 4 is sequentially connected.Wherein, it is prokaryotes system, including Burkholderia category, Nitrosomonas, desulfurization arc in aerobic tank 1
Pseudomonas, desulfurization Pseudomonas, Desulfococcus, desulfurization line Pseudomonas and sulphur removal monospore Pseudomonas；It is eucaryote in photosynthesis physiological target 2
System, including Chlorella and hydrogen bite born of the same parents Pseudomonas；The equipment for separating liquid from solid 5 of band-like grid is installed in photosynthesis physiological target 2；
It is provided with water pump 21 outside clarifying basin 3 and fluid flowmeter 22 is connected to the pipeline 4 at 6 top of spray column, extremely by purified water pump
It is recycled in spray column 6, water pump 21 is powered using external circuits.It is provided in aerobic tank 1 and is integrated by PLC or SCM system
The pH automatic regulating systems of control include mainly that pH pops one's head in, and power cycle unit and reagent adding device are constituted.PH value is set in
Between 6.6 ~ 8.5, if being less than setting value, there is control system control reagent addition pump operation, add milk of lime（Ca
(OH)2）, if higher than the organic acids such as adding citric acid or acetic acid if setting value.It is provided with by PLC or monolithic in light and reaction tank 2
The illumination system of machine system integration control, includes mainly illumination probe and data processing unit and artificial light source, in continuous 72h,
In the case of the intensity of illumination of natural light is less than 60,000 lx, then control system opens artificial light source, to maintain the high of biosystem to react
Activity.Illumination system, auto temperature controlled system and pH automatic regulating systems are powered by external circuitry.
Waste residue and liquid pretreatment system is a dissolving tank 7 with deslagging device, and dissolving tank 7 is interior using water as solvent, filtering
Solution after slagging-off is entered by pipeline 4 in photosynthesis physiological target 2, and burning waste liquid is directly entered pipeline by waste liquid entrance 20
4, photosynthesis physiological target 2 is entered together with the waste liquid after slagging-off.
Heat-exchange system is a heat exchanger 8, and smoke inlet pipe 9 is connect with the heat absorbing sheet air inlet pipe of heat exchanger 8, completes heat and hands over
The stack gases changed are discharged from the outlet 10 of heat absorbing sheet, are again introduced into this biological treatment device.The heat absorbing sheet of heat exchanger 8 is from cigarette
Heat is absorbed in road exhaust gas, cooling fin 11 is transferred heat to by medium circulation, it is each that cooling fin 11 is installed on bioreactor
Section bottom and surrounding have the circulating pump of connection external circuits in heat exchanger.With by PLC or microcontroller system in heat-exchange system
The auto temperature controlled system of system integrated control, temperature are set as between 28-39 DEG C, if temperature is less than setting value, control system
The circulating pump for opening heat-exchange system, makes the hot water in heating tube flow, if temperature of reactor is higher than set temperature,
Stop circulating pump.Air blower 13,13 and gas flow meter 14 of air valve are provided on outlet pipe, for controlling entire biological treatment
The air inflow of device, to ensure high-efficient purification.
Spraying gas-liquid exchange system top has water inlet 15, and the side wall close to bottom has air inlet 16, by water from spray
The stack gases that 6 top of leaching tower enters air inlet 16 with fog-like liquid elute, and the soluble substance in flue gas is dissolved in
In water, spray carries bottom, and there is water outlet 15, water outlet 17 to be connected to bio-reaction system with pipeline.Spray system is using cycle
Water designs, and water inlet 15 is connect with the clarifying basin 3 of bio-reaction system, is extracted by water pump purified by bio-reaction system
Water enters spray column 6.6 top sidewall of spray column has gas outlet 18, and the flue gas of preliminary purification is discharged into life by pipeline 4
In the photosynthesis physiological target 2 of object reaction system.
In Fig. 1, heavy metal suction is provided between the pipeline of 6 air inlet 16 of heat-exchange system outlet 10 and spray column
Attached tower 19, the interior filling carbon-based adsorbent of adsorption tower 19, flying dust, mineral substance adsorbent, metal class adsorbent, metal compound species are inhaled
Attached dose and complexing adsorbent.
2 artificial Tiny ecosystem system construction of embodiment
Prepare liquid seed liquor.The following bacterial strain that this laboratory is preserved：Burkholderia categoryBurkholderia, nitrosation monospore
PseudomonasNitrosomonas, DesulfovibrioDesulfovibrio, desulfurization PseudomonasDesulfobacter, DesulfococcusDesulfococcus, desulfurization line PseudomonasDesulfonema, sulphur removal monospore PseudomonasDesulfuromonas,ChlorellaChlorella, hydrogen bites born of the same parents PseudomonasHydrogenophagaUsing fluid nutrient medium rejuvenation, shaken cultivation, condition of culture pH 6 ~ 8,
25 ± 5 DEG C of cultivation temperature cultivates to the zymotic fluid of exponential phase and becomes seed liquor.
Wherein, Burkholderia categoryBurkholderiaUsing LB culture mediums, NitrosomonasNitrosomonasIt adopts
With Nitrosomonas bacteria culture media, DesulfovibrioDesulfovibrio, desulfurization PseudomonasDesulfobacter, desulfurization
CoccusDesulfococcus, desulfurization line PseudomonasDesulfonema, sulphur removal monospore PseudomonasDesulfuromonasIt is metabolized using S
Bacteria culture media,ChlorellaChlorella, hydrogen bites born of the same parents PseudomonasHydrogenophagaUsing green alga culture medium.
The bacterium solution of exponential phase is mixed for seed liquor, each strain viable count is as follows after mixing：Burkholderia categoryBurkholderiaInoculum concentration 2.7x104 CFU/L, NitrosomonasNitrosomonasInoculum concentration 8.6x104CFU/L,
DesulfovibrioDesulfovibrio, desulfurization PseudomonasDesulfobacter, DesulfococcusDesulfococcus, desulfurization line
PseudomonasDesulfonema, sulphur removal monospore PseudomonasDesulfuromonasInoculum concentration is 5.9x103 CFU/L, above-mentioned Mixed Microbes structure
At aerobic fermentation system；ChlorellaChlorellaInoculum concentration 9.9x105CFU/L, hydrogen bite born of the same parents PseudomonasHydrogenophaga
Inoculum concentration 6.4x104CFU/L, the mixing of above two bacterium constitute photosynthetic response system.Two system combinations are constituted a kind of artificial
The microecosystem for handling the burning three wastes of structure.
The purified treatment of 3 biomass energy of the embodiment burning three wastes
Using the artificial Tiny ecosystem system of 2 component of embodiment as core, i.e., aerobic fermentation system is put into the aerobic tank sterilized in advance,
Photosynthetic response system puts into the photosynthetic organism reaction tank that sterilizes in advance, by coal combustion exhaust from biological treatment device described in embodiment 1
Flue gas admission line be passed through from waste gas inlet access equipment, waste residue ash content described in embodiment 1 is added in coal-fired waste residue
Dissolving tank opens biological treatment device circuit, after the completion of processing, the waste residue in acquisition purified gas, liquid and dissolving tank
Composition measurement is carried out, particular content is as follows：
1. gas componant detects after purification
It is the preceding sample of purification with the flue gas in air inlet pipe, is purification from the overfall of photosynthetic reactor acquisition purified gas
Sample afterwards measures the preceding content with each ingredient in the gas sample of gas outlet of purification, and the results are shown in table below：
Experimental result shows that biological treatment device provided by the invention can relatively efficiently remove the CO in flue gas2、
SO2, NOx, to flue gas carry out desulphurization denitration.Wherein SO2Through this patent method, treated that gas can reach with NOx indexs《Fire
Power plant atmosphere pollutants emission standards GB13223-2011》Emission request.
2. each component content detection in water body after purification
It is the preceding sample of processing with the liquid in waste liquid suction line, samples, obtain purified from clarifying basin after the completion of purification
Liquid is sample after processing, measures the preceding content with each ingredient in liquid sample after processing of purification, the results are shown in table below：
Experimental result is shown, after carrying out purified treatment to coal-fired waste liquid using biological treatment device described in embodiment 1, in waste liquid
Nutrient by the microbial metabolism sorption enhanced in photosynthetic reaction system, utilization rate is higher, and waste liquid can obtain efficiently
Purification.
3. each component content detection in waste residue after purification
It is the preceding solid sample of purification to put into the waste residue before waste residue ash content dissolving tank, after the completion of purification, by waste residue ash content dissolving tank
In remaining waste residue pull out, and the solid of drying and processing is solid sample after purification, each in the front and back solid sample of detection purification
Component content, the results are shown in table below：
Experimental result shows, biological treatment device provided by the invention can preferably dissolve the battalion generated after coal combustion in ashes
Element is supported, wherein：74.6% can be reached to the dissolving utilization rate of N, 69.6% can be reached to P, 95.1% can be reached to K.
Microecosystem stability test after 4 purified treatment of embodiment
With in aerobic tank after purified treatment exhaust gas, waste water, waste residue in dilution-plate method measurement embodiment 3 and in photosynthetic response system
The number of viable of each bacterial strain, and be compared with the number of viable of the artificial constructed Tiny ecosystem system before processing, as a result see below
Table.
From the above results, it can be seen that artificial constructed Tiny ecosystem system can normally be given birth in processing unit described in embodiment 1
Long breeding, each strain can reach higher increment, this shows that the nutrient in the burning three wastes disclosure satisfy that Tiny ecosystem body
It is the demand of growth, the stability of artificial constructed system is high, disclosure satisfy that biological treatment device provided by the invention to burning three
Useless purification requirement, and duration is good, effectively reduces the operating cost of the device.
Embodiment 5 purifies combustion product gases experiment
It is similar to 3 experiment content of embodiment, the difference is that being only passed through flue gas into processing unit and being added without waste residue, make reality
It applies device described in example 3 and only purifies combustion product gases, detect the stability of purified water quality and the Tiny ecosystem system of artificial component.
Experimental result shows that exhaust gas cannot be handled by spraying obtained aqueous solution by the microecosystem of artificial component,
And the microorganism in microecosystem hardly survives, and a large amount of N element is contained in solution（261.5 mg/L）, containing very high
COD (2611 mg/L).
The embodiment proves that burning three wastes biological treatment device provided by the present invention must handle exhaust gas, waste water simultaneously
And waste residue, the element set in the three wastes could meet the stability and high efficiency of artificial component microorganism system.
Claims (9)
1. a kind of biological treatment device for the three wastes that burn, it is characterised in that described device includes bio-reaction system, waste liquid
Waste residue pretreatment system, heat-exchange system, spray gas-liquid exchange system, by placed in series between each system, wherein：
A. the bio-reaction system includes aerobic tank (1), photosynthesis physiological target (2) and clarifying basin (3), and three parts pass through
Pipeline (4) is sequentially connected, wherein be prokaryotes system in aerobic tank (1), including Burkholderia category, Nitrosomonas,
Desulfovibrio, desulfurization Pseudomonas, Desulfococcus, desulfurization line Pseudomonas and sulphur removal monospore Pseudomonas；It is in photosynthesis physiological target (2)
Eucaryote system, including Chlorella and hydrogen bite born of the same parents Pseudomonas；It is provided with water pump (21) outside clarifying basin (3) and is connected to spray column
(6) pipeline (4) at the top of；
B. the waste residue and liquid pretreatment system is a dissolving tank (7), has equipment for separating liquid from solid (5) in dissolving tank (7), leads to
Piping (4) is connect with photosynthesis physiological target (2), and a tool mouth branch pipe is arranged on pipeline (4), which is waste liquid entrance
(20)；
C. the heat-exchange system is a heat exchanger (8), the heat absorbing sheet air inlet pipe of stack gases inlet tube (9) and heat exchanger (8)
Road connects, and the stack gases for completing heat exchange are discharged from the outlet (10) of heat absorbing sheet, cooling fin (11) installation of heat exchanger (8)
In the circulating pump for having connection external circuits in the bottom of bio-reaction system and surrounding, heat exchanger (11)；
D. the spray gas-liquid exchange system is a spray column (6), and top has water inlet (15), and the side wall close to bottom has
There are air inlet (16), bottom that there is water outlet (17), water outlet (17) to be connected to aerobic tank (1), spray column by pipeline (4)
(6) top sidewall has gas outlet (18), is connected in photosynthesis physiological target (2) by pipeline 4.
2. according to claim 1 a kind of for the biological treatment device of the three wastes of burning, it is characterised in that the light and anti-
There is equipment for separating liquid from solid (5) in Ying Chi (2).
The three wastes biological treatment device 3. a kind of fossil according to claim 1 and biomass energy are burnt, it is characterised in that
It is provided with heavy metal adsorption tower (19) between the heat-exchange system outlet (10) and the pipeline of spray column air inlet (16).
4. a kind of biological treatment device for the three wastes that burn according to claim 1, it is characterised in that the heat exchange
Further include with the auto temperature controlled system by PLC or SCM system integrated control in system.
5. a kind of biological treatment device for the three wastes that burn according to claim 1, it is characterised in that the biology is anti-
The pH automatic regulating systems being provided in system by PLC or SCM system integrated control are answered, include mainly that pH pops one's head in, power follows
Ring element and reagent adding device.
6. according to claim 1 a kind of for the biological treatment device of the three wastes of burning, it is characterised in that the light and anti-
It is provided with the illumination system by PLC or SCM system integrated control in Ying Chi (2), includes mainly illumination probe and data processing
Unit and artificial light source.
7. a kind of biological treatment device for the three wastes that burn according to claim 2, it is characterised in that the solid-liquid
Separator (5) is band-like grid.
8. a kind of artificial constructed microecosystem for handle the three wastes that burn, it is characterised in that this is micro- for the microecosystem
The ecosystem includes following bacterial strain：Burkholderia categoryBurkholderia, NitrosomonasNitrosomonas, desulfurization arc
PseudomonasDesulfovibrio, desulfurization PseudomonasDesulfobacter, DesulfococcusDesulfococcus, desulfurization line PseudomonasDesulfonema, sulphur removal monospore PseudomonasDesulfuromonas,ChlorellaChlorella, hydrogen bites born of the same parents PseudomonasHydrogenophaga。
9. a kind of artificial constructed microecosystem for handling the burning three wastes according to claim 8, feature exist
It is as follows in the number of viable and building mode of each strain：Burkholderia categoryBurkholderia 2.7x104 CFU/L, it is sub-
Nitrify monospore PseudomonasNitrosomonas 8.6x104CFU/L, DesulfovibrioDesulfovibrio, desulfurization PseudomonasDesulfobacter, DesulfococcusDesulfococcus, desulfurization line PseudomonasDesulfonema, sulphur removal monospore PseudomonasDesulfuromonasIt is 5.9x103 CFU/L, above-mentioned Mixed Microbes constitute aerobic fermentation system；ChlorellaChlorella
9.9x105CFU/L, hydrogen bite born of the same parents PseudomonasHydrogenophaga 6.4x104CFU/L, the mixing of above two bacterium constitute photosynthetic anti-
System, two system combinations is answered to constitute the microecosystem.
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