CN109663436A - The system and method for bioprocessing industry exhaust gas, dust - Google Patents

The system and method for bioprocessing industry exhaust gas, dust Download PDF

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CN109663436A
CN109663436A CN201811506646.1A CN201811506646A CN109663436A CN 109663436 A CN109663436 A CN 109663436A CN 201811506646 A CN201811506646 A CN 201811506646A CN 109663436 A CN109663436 A CN 109663436A
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exhaust gas
dust
microorganism
layer
solution
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CN109663436B (en
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侯受树
侯瑞威
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Guangdong South Environmental Biological Treatment Engineering Co Ltd
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Guangdong South Environmental Biological Treatment Engineering Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/84Biological processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D49/00Separating dispersed particles from gases, air or vapours by other methods
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/56Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/62Carbon oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/68Halogens or halogen compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
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  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses a kind of bioprocessing industry exhaust gas, the system and method for dust, and the system comprises the microorganism cultivation pond being sequentially communicated through draft bend, biological solution processing spray column and deep solid biologic treatment and purification towers;Using biological treatment, physics, the technique that chemistry combines, the polluter that can be effectively removed according to different exhaust gas in exhaust gas, exhaust gas, polluter in dust is converted under the action of microorganism, degradation, it absorbs, removal, it realizes to the efficient of exhaust gas, completely innoxious deep purifying processing, purified exhaust gas is non-toxic and tasteless, realize qualified discharge, no waste water and the discharge of various impurity dangerous waste substances, do not generate secondary pollution, safe and reliable and this process operation is at low cost, without often more conversion materials, annual maintenance only adds some microbial nutrient solutions, it is kept an eye on without special messenger, it can run steadily in the long term.

Description

The system and method for bioprocessing industry exhaust gas, dust
Technical field:
The present invention relates to exhaust gas, dust processing technology field, and in particular to a kind of bioprocessing industry exhaust gas, dust are System and method.
Background technique:
Atmosphere pollution at present has had reached quite serious stage, and industry is an important sources of atmosphere pollution.Industry The pollutant kind being discharged into atmosphere is various, have flue dust, sulfur oxide, nitrogen oxide, organic compound, halide, Carbon compound etc..Wherein have plenty of flue dust, has plenty of gas.It is analyzed from form, industrial waste gas can be divided into graininess exhaust gas Gentle state property exhaust gas.The active carbon adsorption of principle of industrial waste gas processing, Production by Catalytic Combustion Process, plasma-catalysis oxidation A variety of principles such as method, condensing recovery, absorption.Active carbon adsorption belongs to physical transfer, utilizes the porosity of active carbon, will Pollutant is transferred to another by the organic pollutant adsorption storage in exhaust gas between the hole of active carbon from an object It is transferred to another place in a object or by pollutant from a place, is substantially that there is no right for pollutant transfer The processing of exhaust gas progress essence.And the active carbon after being saturated belongs to dangerous solid waste, replacement frequency is high, consumption pole Greatly, such method is gradually eliminated by environmental protection industry (epi).Production by Catalytic Combustion Process refers to organic exhaust gas in the catalytic action of catalyst Under, 300~400 DEG C at a temperature of burn.The method mostly uses platinum of with higher heat-resisting and antitoxin performance etc. expensive The catalyst of metal, it is at high cost to guarantee the activity of catalyst;Two-stage treatment process is had to pass through when burning processing, it must also be right Organic exhaust gas carries out pre-add heat treatment to maintain catalysis ignition temperature, and energy consumption is high, operating cost is high;It simultaneously must strict control combustion Temperature is burnt to generate other harmful substances when preventing and burning, this not only proposes more requirements to the technology of incinerator itself, And it is difficult to absolute guarantee's substance without secondary pollution and generates;Benzene-like compounds and oxidation category, stench class compound are urged when burning Changing burning has great hidden danger to safety in production, and there is also the potential dangers of explosion, especially effumability fuel gas particle Property exhaust gas.Plasma-catalytic oxidation is the strong oxidation using ozone, by the organic exhaust gas object oxidation point in exhaust gas The chemical substance and inorganic matter of Xie Weixin.Using ozone strong oxidation when, excessive ozone must be passed through, and excessive smelly Oxygen can generate biggish harm to human health with exhaust emissions into air;And ozone generator is needed in forceful electric power Ozone is generated under the action of pressure, under the action of strong voltage, ozone generating apparatus is also easy to produce electric spark, and it is hidden that there are security against fires Suffer from;And during Strong oxdiative, the product of oxidation reaction has uncertainty, easily generate it is new, more intractable two Secondary pollutant.Processing method relatively above, biologic treating technique have its unique advantage, it is to utilize microorganism by Industry Waste Gas is converted into harmless or available substance.However, being directed to the biologic treating technique of exhaust gas not on the market at present Obtain satisfactory effect, it is difficult to realize efficient, the completely innoxious processing to exhaust gas;And irrational mix So that equipment volume is huge, strength disposal is small, and being applied in production not only will increase production cost and can also cause to production efficiency It influences.
Summary of the invention:
The object of the present invention is to provide the system and method for a kind of bioprocessing industry exhaust gas, dust, using biological treatment Method, physics, the technique that combines of chemistry can be effectively removed exhaust gas, the pollutant in dust according to different exhaust gas, dust Matter realizes that efficient, the completely innoxious deep purifying to exhaust gas, dust is handled, and purified exhaust gas is non-toxic and tasteless, and realization reaches Mark discharge, no waste water and the discharge of various impurity dangerous waste substances, do not generate secondary pollution, safe and reliable and this process operation cost Low, without often more conversion materials, annual maintenance only adds some microbial nutrient solutions, keeps an eye on, can be transported steadily in the long term without special messenger Row.
The present invention is achieved by the following technical programs:
The system of a kind of bioprocessing industry exhaust gas, dust, the system comprises the micro- lifes being sequentially communicated through draft bend Object aquaculture pond, biological solution processing spray column and deep solid biologic treatment and purification tower;Wherein middle upper end in microorganism cultivation pond Equipped with two layers or more of sieve, the material for being suitble to various microbial reproduction growths is laid on sieve, comprising: wild sludge 45- 50wt%, crock 3-5wt%, waste wood slag chaff (i.e. Shen wood wool) 5-15wt%, broken potsherd 3-5wt%, sheep dung 5- It is 8wt%, solid carbon dioxide taro skin 5-8wt%, charcoal 5-8wt%, waste bamboo 5-8wt%, dry and soft bark 5-8wt%, pineapple peel 3-5%, rotten Grape-fruit 1-3% is microbial reproduction grown layer, different microorganisms is inoculated with according to pollutant different in exhaust gas, dust Strain, microorganism cultivation pond top are mounted with warm and humid regulation and control system, photosynthesizer, and that places on control sieve is suitable The material humidity of various microbial reproduction growths is closed 43% -55%, promotes microorganism mass propagation, efficient growth;Micro- life Object aquaculture pond top is equipped with feed opening, air outlet, and the air outlet handles spray column bottom through draft bend connection biological solution End;Microorganism cultivation pond lower end is the solution layer equipped with water, and the warm and humid regulation and control system in microorganism cultivation pond top is by atomization System spray water assigns to microbial reproduction grown layer, extra water and microorganism and is stored in solution layer, solution layer from sieve discharge As microbial activities layer and for water layer, it more than solution layer side liquid level is equipped with exhaust gas entrance, pressurization wind is equipped with before exhaust gas entrance Machine, the solution layer bottom of pond other side are communicated with water tank, and the water tank in water circulating pump connection biological solution processing spray column through spraying The circulating water pipe of leaching system;Biological solution handles the carbon steel net that spray column is equipped with two layers or more, places wild mixing in carbon steel net Charcoal, activated carbon fibre, every layer of carbon steel are just mounted with spray system on the net, and the spray system is through circulating pump with microorganism cultivation The water tank of bottom of pond portion is connected to, and the liquid pools that biological solution processing spray column spray system sprays are then return to microorganism Bottom of pond portion is cultivated, a circulation loop is formed;Biological solution handles spray column top and is equipped with air outlet, be equipped at air outlet every The network of rivers, air outlet are connected to through bend pipe with the bottom of deep solid biologic treatment and purification tower;Deep solid biologic treatment and purification tower by First layer carbon steel net, the second carbon steel net, third layer carbon steel net are successively arranged on down, first layer carbon steel net is equipped with biochemistry Solution spraying system, different biochemistry solution formulas is selected according to different exhaust gas, dust pollution source, and biochemistry is molten Water tank convergence of the liquid that liquid spray system sprays through deep solid biologic treatment and purification tower side is then through in water tank Water circulating pump returns to biochemistry solution spraying system, forms a circulation loop;Contain micro- life in the biochemistry solution Object bacterium, sodium carbonate, magnesium carbonate, dirty stem water etc., such as: for non-methane total hydrocarbons and lacquer spraying waste gas, the biochemistry solution can Leaching 24 hours is mixed with pork tripe dried fruit with dirty stem water, then is configured with wild sludge through Soaking treatment, paraxylene has very well Degradation, removal effect;The dirt stem water is to incinerate to be filtered with the alkalinity that mountain spring water is obtained by filtration again after plant dirt stem tree is dried Liquid, pork tripe fruit are a kind of plant fruits of similar haw berry, belong to acid, have a sterilizing effect, and pork tripe dried fruit, which refers to, to be collected Then pork tripe fruit using washing is then 80-90wt% is crushed air-drying to pork tripe fruit mass content after air-drying, can degrade two Sulfur oxide, dimethylbenzene promote microorganism growth;Be placed in the second layer carbon steel net cocoanut shell, peanut shell, bark, wild charcoal, Activated carbon fibre, zeolite, pork tripe dried fruit, urea and plant hay, surface spraying have different biochemical materials such as ferment The aqueous solution of female bacterium and yeast powder, baking powder, humidity carry out the fermentation purification of solid biologic filler 48% or so;Particularly: It is handled when laying aqueous solution after sodium carbonate, sodium sulfite and plant epipremnum aureum hydrolyze thermalization for lacquer spraying waste gas in wild charcoal After be placed in this layer, its aqueous solution sprays in filler material, and wherein the humidity of filler material promotes filler 48% or so The purification purpose of removing Degradation and Transformation is reacted and reached in thermalization process;The plant hay is according to the different selections of exhaust gas Different plants, such as: in exhaust gas containing heavy metal processing just with caraway, celery leaf extract after processing mixed preparing and At progress heavy metal exhaust gas waste water absorption absorbs;Be placed in third layer carbon steel net amount of activated Carbon fibe, active carbon it is a small amount of, Cocoanut shell, lemon dry, pork tripe dried fruit, plant plait, peanut shell, walnut shell etc., spray has the chemical materials such as diethylenetriamine;It is deep Portion's solid biologic treatment and purification top of tower is equipped with air outlet.
The material for being suitble to various microbial reproduction growths is laid on sieve, comprising: wild sludge 45-50wt%, broken watt Piece 3-5wt%, waste wood slag chaff (i.e. Shen wood wool) 5-15wt%, broken potsherd 3-5wt%, sheep dung 5-8wt%, solid carbon dioxide taro skin 5-8wt%, charcoal 5-8wt%, waste bamboo 5-8wt%, dry and soft bark 5-8wt%, pineapple peel 3-5%, rotten grape-fruit 1-3%, Described in wild sludge refer in mountain that wild mud natural air drying in one week activates in the gully of pollution-free mistake, it is relatively wet Degree has a variety of biotic populations containing a large amount of minerals and plant elements in 46% -60%wt or so.Crock, waste wood Slag chaff, broken potsherd etc. can also improve porosity while improving the impact strength of filler, and pineapple peel, rotten grape-fruit are used to Increasing sugar, said components act synergistically to be formed with porosity height, large specific surface area, various microbial reproductions is suitble to grow, Impact-resistant stable biological bed, can run, exhaust treatment efficiency is steady in a long-term steadily in the long term.
Particularly, microbial reproduction grown layer is additionally provided with observation panel.
Uniform intervals distance is 0.6- in two layers of sieve vertical direction of microbial reproduction grown layer in microorganism cultivation pond 0.8cm。
A kind of method of bioprocessing industry exhaust gas, dust, which is characterized in that using above-mentioned bioprocessing industry exhaust gas, The system of dust comprising the steps of:
1) exhaust gas, the dust collected enter microorganism cultivation pond progress original place through exhaust gas entrance after pressurizeing by blower and stablize Microbiological treatment, for the nature and characteristic of polluter different in exhaust gas, dust, the cultivation of microbial reproduction grown layer has not Same microorganism fungus kind carries out the preliminary harmless treatments such as biological oxidation, conversion, degradation, absorption to harmful substance, is had Exhaust gas after the evil effective bioconversion of substance;
2) exhaust gas that step 1) obtains enters biological solution processing spray column bottom end, and organic exhaust gas constantly rises, with spray System spray or be attached to wild mixing charcoal in carbon steel net, activated carbon fibre microorganism contact-impact during, give up Harmful gaseous substances in gas enter in biomembrane by complete absorption, conversion, degradation, absorb and obtain harmful gaseous substances and had The gas for imitating control sprays the liquid to get off and returns to microorganism cultivation through the water tank convergence of biological solution processing spray column side The water tank of bottom of pond portion provides nutrient for the quick flourish of microorganism;
3) gas that step 2) obtains is after the processing of deep solid biologic treatment and purification tower, the nocuousness that is free in gas Substance thoroughly purifies completely.
Exhaust gas, dust microbiological treatment principle are transferred to gaseous pollutant in the liquid film of liquid phase or the surface of solids, so Organic matters various in exhaust gas, dust and odorant are degraded or are converted into harmless or low using the metabolic process of microorganism afterwards Evil substance.Pollutant in exhaust gas, dust is contacted and is dissolved with Biological water solution, i.e., diffuses into biological liquid film by air film In pollutant biomembrane is diffused into due to concentration difference, then by microorganism-capturing therein and absorb.Microbe It carries out oxygenolysis and assimilation, pollutant is decomposed as the energy and nutriment, be eventually converted into harmless chemical combination Object.The gaseous products of biochemical reaction are detached from biomembrane, reverse to spread.
Pollutant in exhaust gas includes Atmospheric particulates, sulfur-containing compound, nitrogen oxides, oxycarbide, hydrocarbon With halide etc..Atmospheric particulates include various solids, liquid and aerosol again.
The exhaust gas includes aluminium industry, chemical industry, printing industry, ceramic kiln, the organic exhaust gas of waste incineration, spray Paint exhaust gas, boiler waste gas, pickling exhaust gas.
Harmful gaseous substances in exhaust gas include VOCs, dust, oxysulfide, nitrogen oxides etc..Particularly, VOCs includes The benzene series organic exhaust gas such as benzene,toluene,xylene.
Acid gas-containing (HCI, fluoride, oxysulfide, nitrogen oxides), CO, hydrogen, vapor, acid in pickling exhaust gas Mist and tobacco.
For the nature and characteristic of polluter different in exhaust gas, dust, the cultivation of microbial reproduction grown layer has different Microorganism fungus kind, including autotrophic bacterium and heterotroph, mainly using inorganic carbon as carbon source, heterotroph is mainly made with organic matter autotrophic bacterium For carbon source and the energy.
Particularly, microorganism fungus kind is selected from the raw green bacterium of mud, saccharomycete, thermus aquaticus, Thiobacillus, sulfate reducing bacteria, Denitrifying bacterium etc..
The above various bacterium are that specific aim training is grown, for example, ceramic exhaust gas cool down first after drop to the temperature that biological bacteria is born, it is micro- The raw green bacterium of mud, the dry bacterium of sulphur, reducing bacteria are laid in biological culture pond, it is main to select in filler containing acid, basic active filler.
Such as utilize microorganism flue gas desulfurization: using autotrophic microbe, being acted on by the indirect oxidation of sulphur removal microorganism, it will SO in flue gas2It is oxidized to sulfuric acid, microbial bacteria therefrom obtains energy and nutrient.
The microorganisms such as sulfate reducing bacteria are using organic matter as electron donor, using sulphite and sulfate as final electronics Receptor is simultaneously reduced to sulfide.It is alienation sulfate reduction, the H of generation by the above biochemical reaction process2S etc. Sulfide can be used as the electron donor of Thiobacillus and photosynthetic bacteria.
It denitrogenates: being acted on using the anaerobic respiration of denitrifying bacterium, nitrogen oxide NOx passes through denitrification in denitrification process Bacterium is converted into N through catabolism2, adsorbed by anabolism by denitrifying bacterium and solid phase carrier, then in denitrifying bacterium In, N is reduced to by the effect of nitric-oxide reductase2
Mass transport process and biochemical reaction process: nitrogen oxide NOx is transferred in liquid phase or solid phase surface liquid film simultaneously by gas phase And it is removed and purifies by microorganism in liquid phase or solid phase surface.
Beneficial effects of the present invention are as follows:
1) technique that the present invention is combined using biological treatment, physics, chemistry, can effectively go according to different exhaust gas Polluter in removing exhaust gas, the polluter in exhaust gas, dust converted under the action of microorganism, degraded, absorbed, Removal realizes and handles efficient, the completely innoxious deep purifying of exhaust gas that purified exhaust gas is non-toxic and tasteless, realizes up to standard Discharge, no waste water and the discharge of various impurity dangerous waste substances, do not generate secondary pollution, and safe and reliable and this process operation is at low cost, Without often more conversion materials, annual maintenance only adds some microbial nutrient solutions, keeps an eye on, can be run steadily in the long term without special messenger.
2) present invention cultivates microorganism using the supply source original place of industrial waste gas, dust, i.e. industrial waste gas, dust serves as micro- The fuel (carbon source, the energy) of biology, and utilize the effect of microorganism carries out oxygenolysis and same to exhaust gas, dust pollution object Change effect, is eventually converted into harmless compound, reaches bioprocessing industry exhaust gas, dust optimum efficiency.
Detailed description of the invention:
Fig. 1 is the structural schematic diagram of the system of bioprocessing industry exhaust gas of the present invention, dust;
Wherein, 1, microorganism cultivation pond, 2, biological solution processing spray column, 3, deep solid biologic treatment and purification tower, 4, Sieve, 5, exhaust gas entrance, 6,13, water circulating pump, 7,10, water tank, 8, draft bend, 9, spray system, 11, water proof net, 12, Biochemistry solution spraying system.
Specific embodiment:
It is to further explanation of the invention, rather than limiting the invention below.
The system of a kind of bioprocessing industry exhaust gas, dust as shown in Figure 1, the system comprises through draft bend 8 according to Microorganism cultivation pond 1, biological solution processing spray column 2 and the deep solid biologic treatment and purification tower 3 of secondary connection;Wherein micro- life Middle upper end is equipped with three-layer screen 4 in object aquaculture pond 1, and uniform intervals distance is 0.7cm, bottom in two layers of sieve vertical direction Sieve lay 30-35 centimetres high on microorganism cultivation pond bottom of pond 1m, sieve 4 and be suitble to the various microbial reproductions raw Long material, comprising: wild sludge 45wt%, crock 5wt%, waste wood slag chaff 12wt%, broken potsherd 5wt%, sheep dung 5wt%, solid carbon dioxide taro skin 5wt%, charcoal 5wt%, waste bamboo 5wt%, dry and soft bark 5wt%, pineapple peel 5%, rotten grape-fruit 3%, For microbial reproduction grown layer, different microorganism fungus kinds, microorganism are inoculated with according to pollutant different in exhaust gas, dust Aquaculture pond top is mounted with warm and humid regulation and control system, photosynthesizer, and that places on control sieve is suitble to various microorganisms The material humidity of flourish promotes microorganism mass propagation, efficient growth 43% -55%;Microorganism cultivation pond top Equipped with feed opening, air outlet, the air outlet is connected to biological solution through draft bend 15 and handles 2 bottom end of spray column, and microorganism is numerous Reproductive growth layer is additionally provided with observation panel;1 lower end of microorganism cultivation pond is the solution layer equipped with water, top temperature in microorganism cultivation pond 1 Wet regulation and control system assigns to microbial reproduction grown layer, extra water and microorganism from sieve by atomization system spray water Discharge is stored in solution layer, and solution layer is as microbial activities layer and for water layer, and more than solution layer side liquid level 10 centimeters are set There is exhaust gas entrance 5, is equipped with booster fan before exhaust gas entrance 5, the solution layer bottom of pond other side is communicated with height 1.3m -1.6m, width Degree 0.6m -0.8m, width are with the water tank 7 being of uniform thickness, and the water tank 7 is through being connected to biological solution processing spray through water circulating pump 6 Drench the circulating water pipe of spray system 9 in tower 2;Biological solution handles spray column 2 and is equipped with three layers of carbon steel net, places in carbon steel net wild Raw mixing charcoal, activated carbon fibre, every layer of carbon steel are just mounted with spray system 9 on the net, and the spray system 9 is through circulating pump 6 with micro- The water tank 7 of 1 bottom of biological culture pond is connected to, and the liquid pools that biological solution processing 2 spray system 9 of spray column sprays are right After return to microorganism cultivation bottom of pond portion water tank 7, form a circulation loop;Biological solution handles 2 top of spray column and is equipped with outlet air Mouthful, water proof net 11 is equipped at air outlet, air outlet is connected to through bend pipe with the bottom of deep solid biologic treatment and purification tower 3;Deep Solid biologic treatment and purification tower 3 is sequentially provided with first layer carbon steel net, the second carbon steel net, third layer carbon steel net, and first Layer carbon steel net is equipped with biochemistry solution spraying system 12, selects different bioids according to different exhaust gas, dust pollution source Solution formula is learned, microbial bacteria, sodium carbonate, magnesium carbonate, dirty stem water etc. are contained in the biochemistry solution, biochemistry is molten Water tank 10 convergence of the liquid that liquid spray system 12 sprays through 3 side of deep solid biologic treatment and purification tower is then through following Ring water pump 13 returns to biochemistry solution spraying system 12, forms a circulation loop;Coconut is placed in second layer carbon steel net The high 30- of the compositions such as shell, peanut shell, bark, wild charcoal, activated carbon fibre, zeolite, pork tripe dried fruit, urea and plant hay 40 centimetres of filler, surface are mounted with the water of different biochemical materials such as saccharomycete and yeast powder, baking powder through spraying Solution, humidity carry out the fermentation purification of solid biologic filler 48% or so;Particularly, when laying carbonic acid for lacquer spraying waste gas Aqueous solution after sodium, sodium sulfite and the hydrolysis thermalization of plant epipremnum aureum is placed in this layer after the processing of wild charcoal, it water-soluble Liquid sprays in filler material, and wherein the humidity of filler material promotes filler to react in thermalization process and reach removing 48% or so The purification purpose of Degradation and Transformation;The biochemical material is different according to the difference of pollutant in exhaust gas, and humidity is maintained at 48% or so;It is placed with that amount of activated Carbon fibe, active carbon a small amount of, cocoanut shell, lemon be dry, pork tripe fruit in third layer carbon steel net Dry, plant plait, peanut shell, walnut shell etc., spray have the chemical materials such as diethylenetriamine;Deep solid biologic treatment and purification tower Top is equipped with air outlet.
Embodiment 1: the method for lacquer spraying waste gas pollutant biological treatment
Harmful gaseous substances in lacquer spraying waste gas include VOCs 400mg/m3, wherein benzene 15mg/m3, toluene and dimethylbenzene 60mg/m3, dust 120mg/m3
The cultivation of the microbial reproduction grown layer of microorganism cultivation pond shown in Fig. 1 has the microorganism fungus kinds such as the raw green bacterium of mud, saccharomycete, Solid biologic treatment and purification tower 3 first layer carbon steel net in deep is equipped with the biochemistry that biochemistry solution spraying system 12 is selected Solution formula, containing microbial bacteria, sodium carbonate, magnesium carbonate, dirty stem water etc. in the biochemistry solution, the preparation method is as follows: It is dirty stem water with the alkaline filtrate that mountain spring water is obtained by filtration that plant dirt stem tree incinerates again after drying;The pork tripe fruit wind being collected Pork tripe dried fruit is obtained for 85wt% using washing and then air-drying to pork tripe fruit content after dry, is then crushed, then with dirty stem water It is soaked 24 hours with mixing, then configured with wild sludge through Soaking treatment, has to sulfur dioxide, dimethylbenzene and degrade, go very well Except effect, promote microorganism growth.Cocoanut shell, peanut shell, bark, wild charcoal, active carbon fibre are placed in second layer carbon steel net Dimension, zeolite, pork tripe dried fruit, urea and plant hay, surface spraying have saccharomycete, sodium carbonate, sodium sulfite and plant green Aqueous solution after trailing plants hydrolysis thermalization is placed in this layer after the processing of wild charcoal, and humidity promotes filler in thermalization 48% or so Process reaction and reach removing Degradation and Transformation purification purpose.
Lacquer spraying waste gas is steady from exhaust gas entrance 5 shown in FIG. 1 into the progress original place of microorganism cultivation pond 1 after being pressurizeed by blower Determine microbiological treatment, the cultivation of microbial reproduction grown layer has the microorganism fungus kinds such as the raw green bacterium of mud, saccharomycete, to harmful substance into The preliminary harmless treatment such as row biological oxidation, conversion, degradation, absorption, the exhaust gas after obtaining the effective bioconversion of harmful substance;
2) exhaust gas that step 1) obtains enters biological solution processing spray column bottom end, and organic exhaust gas constantly rises, with spray System spray or be attached to wild mixing charcoal in carbon steel net, activated carbon fibre microorganism contact-impact during, give up Harmful gaseous substances in gas enter in biomembrane by complete absorption, conversion, degradation, absorb and obtain harmful gaseous substances and had The gas for imitating control sprays the liquid to get off and returns to microorganism cultivation through the water tank convergence of biological solution processing spray column side The water tank of bottom of pond portion provides nutrient for the quick flourish of microorganism;
3) gas that step 2) obtains is after the processing of deep solid biologic treatment and purification tower, the nocuousness that is free in gas Substance thoroughly purifies completely.Harmful gaseous substances content is respectively VOCs 30mg/m after purification3, wherein benzene 1mg/m3, toluene with Dimethylbenzene 5mg/m3, dust 20mg/m3
Embodiment 2: the method for South Sea Aluminum exhaust emission biological treatment
Harmful gaseous substances in exhaust gas include VOCs 400mg/m3, sulfur dioxide 920mg/m3, nitrogen oxides 640mg/ m3, dust 450mg/m3
Exhaust gas enters microorganism cultivation pond 1 from the exhaust gas entrance 5 of device shown in FIG. 1 after pressurizeing by blower and carries out original place Stabilised microorganism processing, the cultivation of microbial reproduction grown layer have the raw green bacterium of mud, saccharomycete, Thiobacillus, sulfate reducing bacteria, anti- The microorganism fungus kinds such as nitrifier, harmful gaseous substances content is respectively VOCs 30mg/m after purification3, sulfur dioxide 50mg/m3、 Nitrogen oxides 30mg/m3, dust 10mg/m3

Claims (10)

1. the system of a kind of bioprocessing industry exhaust gas, dust, which is characterized in that the system comprises successively connect through draft bend Logical microorganism cultivation pond, biological solution processing spray column and deep solid biologic treatment and purification tower;Wherein microorganism cultivation pond Interior middle upper end is equipped with two layers or more of sieve, the material for being suitble to various microbial reproduction growths is laid on sieve, comprising: wild Sludge 45-50wt%, crock 3-5wt%, waste wood slag chaff 5-15wt%, broken potsherd 3-5wt%, sheep dung 5-8wt%, solid carbon dioxide Taro skin 5-8wt%, charcoal 5-8wt%, waste bamboo 5-8wt%, dry and soft bark 5-8wt%, pineapple peel 3-5%, rotten grape-fruit 1- 3%, it is microbial reproduction grown layer, different microorganism fungus kinds, micro- life is inoculated with according to pollutant different in exhaust gas, dust Object aquaculture pond top is mounted with warm and humid regulation and control system, photosynthesizer, and that places on control sieve is suitble to various micro- lifes The material humidity of object flourish is 43% -55%;Microorganism cultivation pond top is equipped with feed opening, air outlet, the air outlet Spray column bottom end is handled through draft bend connection biological solution;Microorganism cultivation pond lower end is the solution layer equipped with water, solution layer It more than side liquid level is equipped with exhaust gas entrance, is equipped with booster fan before exhaust gas entrance, the solution layer bottom of pond other side is communicated with water tank, institute State circulating water pipe of the water tank through the spray system in water circulating pump connection biological solution processing spray column;The biological solution processing Spray column is equipped with two layers or more of carbon steel net, places wild mixing charcoal, activated carbon fibre, the online Fang An of every layer of carbon steel in carbon steel net It is equipped with spray system, the spray system is connected to through circulating pump with the water tank of microorganism cultivation bottom of pond portion, biological solution processing spray The liquid pools that leaching tower spray system sprays are then return to microorganism cultivation bottom of pond portion, form a circulation loop;Biology Solution handles spray column top and is equipped with air outlet, is equipped with water proof net at air outlet, air outlet through bend pipe and deep solid biologic at Manage the bottom connection of purifying column;Deep solid biologic treatment and purification tower is sequentially provided with first layer carbon steel net, the second carbon Steel mesh, third layer carbon steel net, first layer carbon steel net are equipped with biochemistry solution spraying system, dirty according to different exhaust gas, dust Different biochemistry solution formulas is selected in dye source, and the liquid that biochemistry solution spraying system sprays is raw through deep solid Then the water tank convergence of object treatment and purification tower side returns to biochemistry solution spraying system through the water circulating pump in water tank, formed One circulation loop;Containing microbial bacteria, sodium carbonate, magnesium carbonate, dirty stem water in the biochemistry solution, the dirt stem water is Plant dirt stem tree incinerates the alkaline filtrate being obtained by filtration again with mountain spring water after drying, and is placed with coconut in second layer carbon steel net Shell, peanut shell, bark, wild charcoal, activated carbon fibre, zeolite, pork tripe dried fruit, urea and plant hay, surface spraying have not Same biochemical material, humidity carry out the fermentation purification of solid biologic filler 48% or so;It is placed in third layer carbon steel net Activated carbon fibre, active carbon, cocoanut shell, lemon be dry, pork tripe dried fruit, plant plait, peanut shell, walnut shell, and spray has divinyl three Amine;Deep solid biologic treatment and purification top of tower is equipped with air outlet.
2. the system of bioprocessing industry exhaust gas, dust according to claim 1, which is characterized in that microbial reproduction growth Layer is additionally provided with observation panel.
3. the system of bioprocessing industry exhaust gas according to claim 1 or claim 2, dust, which is characterized in that microorganism cultivation pond Uniform intervals distance is 0.6-0.8cm in two layers of sieve vertical direction of interior microbial reproduction grown layer.
4. the system of bioprocessing industry exhaust gas according to claim 1 or claim 2, dust, which is characterized in that exhaust gas is non-methane When total hydrocarbon or lacquer spraying waste gas, biochemistry solution spraying system that deep solid biologic treatment and purification tower first layer carbon steel net is equipped with Described in biochemistry solution can be mixed and soak 24 hours with pork tripe dried fruit with dirty stem water, then configured with wild sludge through Soaking treatment It forms;Cocoanut shell, peanut shell, bark, wild charcoal, activity are placed in the solid biologic treatment and purification tower second layer carbon steel net of deep Carbon fibe, zeolite, pork tripe dried fruit, urea and plant hay, surface spraying have biochemical material, the biochemical material It hydrolyzes after the aqueous solution after thermalization is handled with wild charcoal and is sprayed in filler material for sodium carbonate, sodium sulfite and plant epipremnum aureum, The humidity of filler material is 48% or so;The plant hay plant different according to the different selections of exhaust gas;The dirt stem water It is the alkaline filtrate being obtained by filtration again with mountain spring water that incinerates after plant dirt stem tree is dried, pork tripe dried fruit refers to the pork tripe fruit being collected It is then crushed using washing and then air-drying to pork tripe fruit content for 80-90wt% after air-drying.
5. a kind of method of bioprocessing industry exhaust gas, dust, which is characterized in that utilize Arbitrary Term right in claim 1-4 It is required that the system of the bioprocessing industry exhaust gas, dust comprising the steps of:
1) exhaust gas, the dust collected enter microorganism cultivation pond progress original place through exhaust gas entrance after pressurizeing by blower and stablize micro- life Object processing, for the nature and characteristic of polluter different in exhaust gas, dust, the cultivation of microbial reproduction grown layer has different micro- Biological inoculum carries out the preliminary harmless treatments such as biological oxidation, conversion, degradation, absorption to harmful substance, and obtaining harmful substance has Exhaust gas after imitating bioconversion;
2) exhaust gas that step 1) obtains enters biological solution processing spray column bottom end, and organic exhaust gas constantly rises, with spray system Spray or be attached to wild mixing charcoal in carbon steel net, activated carbon fibre microorganism contact-impact during, in exhaust gas Harmful gaseous substances enter in biomembrane by complete absorption, conversion, degradation, absorb and obtain harmful gaseous substances and be effectively controlled Gas, spray the liquid that gets off through the water tank convergence of biological solution processing spray column side and return to microorganism cultivation bottom of pond portion Water tank provides nutrient for the quick flourish of microorganism;
3) gas that step 2) obtains is after the processing of deep solid biologic treatment and purification tower, the harmful substance that is free in gas Thoroughly purification is clean.
6. the method for bioprocessing industry exhaust gas according to claim 5, dust, which is characterized in that the pollution in exhaust gas Object includes Atmospheric particulates, sulfur-containing compound, nitrogen oxides, oxycarbide, hydrocarbon and halide.
7. the method for bioprocessing industry exhaust gas according to claim 5, dust, which is characterized in that the nocuousness in exhaust gas Gaseous material includes VOCs, dust, oxysulfide, nitrogen oxides.
8. the method for bioprocessing industry exhaust gas according to claim 7, dust, which is characterized in that VOCs includes benzene, first Benzene, dimethylbenzene.
9. the method for bioprocessing industry exhaust gas according to claim 5, dust, which is characterized in that be directed to exhaust gas, dust The nature and characteristic of middle different polluter, the cultivation of microbial reproduction grown layer have different microorganism fungus kinds, including autotrophic bacterium And heterotroph, autotrophic bacterium is mainly using inorganic carbon as carbon source, and heterotroph is mainly using organic matter as carbon source and the energy.
10. the method for bioprocessing industry exhaust gas according to claim 9, dust, which is characterized in that microorganism fungus kind choosing From the raw green bacterium of mud, saccharomycete, thermus aquaticus, Thiobacillus, sulfate reducing bacteria, denitrifying bacterium.
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