CN108652014A - A kind of production method of caseinic acid calcium - Google Patents
A kind of production method of caseinic acid calcium Download PDFInfo
- Publication number
- CN108652014A CN108652014A CN201810437214.3A CN201810437214A CN108652014A CN 108652014 A CN108652014 A CN 108652014A CN 201810437214 A CN201810437214 A CN 201810437214A CN 108652014 A CN108652014 A CN 108652014A
- Authority
- CN
- China
- Prior art keywords
- calcium
- acid calcium
- production method
- casein
- caseinic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011575 calcium Substances 0.000 title claims abstract description 35
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 229910052791 calcium Inorganic materials 0.000 title claims abstract description 29
- 239000002253 acid Substances 0.000 title claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000005018 casein Substances 0.000 claims abstract description 22
- 235000021240 caseins Nutrition 0.000 claims abstract description 21
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 12
- 230000001954 sterilising effect Effects 0.000 claims abstract description 8
- 241000283690 Bos taurus Species 0.000 claims abstract description 5
- 238000001694 spray drying Methods 0.000 claims abstract description 5
- 230000036760 body temperature Effects 0.000 claims description 5
- 238000000034 method Methods 0.000 abstract description 5
- 108010076119 Caseins Proteins 0.000 description 16
- 108010033929 calcium caseinate Proteins 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000001506 calcium phosphate Substances 0.000 description 3
- 229910000389 calcium phosphate Inorganic materials 0.000 description 3
- 235000020247 cow milk Nutrition 0.000 description 3
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 2
- 239000002956 ash Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 108010082495 Dietary Plant Proteins Proteins 0.000 description 1
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 description 1
- 229930003316 Vitamin D Natural products 0.000 description 1
- QYSXJUFSXHHAJI-XFEUOLMDSA-N Vitamin D3 Natural products C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C/C=C1\C[C@@H](O)CCC1=C QYSXJUFSXHHAJI-XFEUOLMDSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 235000013351 cheese Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 235000019166 vitamin D Nutrition 0.000 description 1
- 239000011710 vitamin D Substances 0.000 description 1
- 150000003710 vitamin D derivatives Chemical class 0.000 description 1
- 229940046008 vitamin d Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
- A23L33/16—Inorganic salts, minerals or trace elements
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
- A23L33/17—Amino acids, peptides or proteins
- A23L33/19—Dairy proteins
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Abstract
The present invention relates to a kind of production method of caseinic acid calcium, this method refers to enriching Ca (OH) in bovine casein2Solution, it is agitated uniformly after, obtain casein solution；In the casein solution plus hydrochloric acid tune pH value is to after 6.5 ~ 7.5, successively through instantaneous sterilizing, spray drying to get product caseinic acid calcium.The method of the present invention is simple and practicable, products obtained therefrom albumen and calcium content integrally improve.
Description
Technical field
The present invention relates to casein production technical field more particularly to a kind of production methods of caseinic acid calcium.
Background technology
Calcium caseinate is ionized calcium, and the phosphate moiety stable bond of itself and the serine in casein, thus is one
The ideal substance of replenishing the calcium of kind, is easily absorbed by the human body utilization, and without coordinating vitamin D, abundant bad ammonia is contained compared with vegetable protein
Acid；Separately due to the specific functional characteristic such as thickening property, tackifying, emulsibility, foaming characteristic etc. that calcium caseinate itself has, make
It can be added in food well.
Casein in cow's milk exists with casein micelles state, and casein is combined with calcium generates calcium caseinate, then with
The calcium phosphate of colloidal combines and forms calcium caseinate-calcium phosphate complex (calcium casemate-calcium
Phosphate complex), it is present in cow's milk in the form of protomere.Calcium caseinate forms a kind of gel of white
Dispersion, rather than a kind of solution.
Although early in the fifties, foreign countries have begun to the research to calcium caseinate, the research work of preparation of industrialization
Just really start until in recent years, and China is less in terms of the research of calcium caseinate.Traditional calcium caseinate production technology is adopted
With Qula, pass through the dissolving of sodium hydroxide early period, and the fat in product is removed by butterfly seperator, then pass through food grade
NH3·H2O（Ammonia water）The point acid for carrying out product, by press filtration and baking step, obtains cheese after the completion of putting sour step
Element carries out following process after obtaining primary product, finally obtains caseinic acid calcium.As long as this method consuming time reaches 6h, at
This input is more.
Invention content
Technical problem to be solved by the invention is to provide a kind of simple and practicable and products obtained therefrom albumen and calcium content are high
The production method of caseinic acid calcium.
To solve the above problems, a kind of production method of caseinic acid calcium of the present invention, it is characterised in that：In cow's milk junket
The Ca (OH) of a concentration of 1mol/L is added in albumen2Solution, it is agitated uniformly after, obtain mass concentration be 13 ~ 15% casein
Solution；In the casein solution plus the hydrochloric acid tune pH value of a concentration of 0.1mol/L is to after 6.5 ~ 7.5, successively through instantaneous sterilizing,
Spray drying is to get product caseinic acid calcium.
The temperature of the instantaneous sterilizing is 55 ~ 65 DEG C.
The condition of the spray drying refers to steam pressure >=0.75MPa, 150 DEG C ~ 170 DEG C of tower body inlet air temperature, in tower
Temperature be 65 ~ 75 DEG C, 60 DEG C ~ 70 DEG C of tower body temperature of outgoing air, in tower negative pressure be -20 ~ -100Pa, high pressure pump pressure be 10 ~
25MPa。
Compared with the prior art, the present invention has the following advantages：
1, the production time of the invention totally expends time about 4h, more time saving compared with traditional handicraft takes 6h.
2, using traditional handicraft resulting product content of ashes >=3.0%, protein content（Butt）>=90%, fat content
≤ 2%, calcium content（Butt）>=0.4%, moisture≤8%；And it is whole using the product albumen of the invention obtained and calcium content
It improves, wherein content of ashes≤2.0%, protein content（Butt）>=95%, fat content≤1.5%, calcium content（Butt）≥
2%, moisture≤6%.
3, the method for the present invention is simple and practicable, economic and excellent.
Specific implementation mode
A kind of production method of 1 caseinic acid calcium of embodiment, is added the Ca of a concentration of 1mol/L in bovine casein
(OH)2Solution, it is agitated uniformly after, obtain mass concentration be 13% casein solution；It is in casein solution plus a concentration of
The hydrochloric acid tune pH value of 0.1mol/L is to after 6.5, prior to 55 DEG C instantaneous sterilizings, then in steam pressure >=0.75MPa, tower body air inlet
150 DEG C of temperature, temperature is 65 DEG C in tower, 60 DEG C of tower body temperature of outgoing air, and negative pressure is -20Pa in tower, and high pressure pump pressure is 10MPa's
Under the conditions of it is spray-dried to get product caseinic acid calcium.
A kind of production method of 2 caseinic acid calcium of embodiment, is added the Ca of a concentration of 1mol/L in bovine casein
(OH)2Solution, it is agitated uniformly after, obtain mass concentration be 15% casein solution；It is in casein solution plus a concentration of
The hydrochloric acid tune pH value of 0.1mol/L is to after 7.5, prior to 65 DEG C instantaneous sterilizings, then by centrifugal spray device tower in steam pressure
>=0.75MPa, 170 DEG C of tower body inlet air temperature, temperature is 75 DEG C in tower, 70 DEG C of tower body temperature of outgoing air, and negative pressure is -100Pa in tower,
High pressure pump pressure is spray-dried to get product caseinic acid calcium under conditions of being 25MPa.
A kind of production method of 3 caseinic acid calcium of embodiment, is added the Ca of a concentration of 1mol/L in bovine casein
(OH)2Solution, it is agitated uniformly after, obtain mass concentration be 14% casein solution；It is in casein solution plus a concentration of
The hydrochloric acid tune pH value of 0.1mol/L is to after 7.0, prior to 60 DEG C instantaneous sterilizings, then by centrifugal spray device tower in steam pressure
>=0.75MPa, 160 DEG C of tower body inlet air temperature, temperature is 70 DEG C in tower, 65 DEG C of tower body temperature of outgoing air, and negative pressure is -60Pa in tower,
High pressure pump pressure is spray-dried to get product caseinic acid calcium under conditions of being 15MPa.
Claims (3)
1. a kind of production method of caseinic acid calcium, it is characterised in that：The Ca of a concentration of 1mol/L is added in bovine casein
(OH)2Solution, it is agitated uniformly after, obtain mass concentration be 13 ~ 15% casein solution；Enriching in the casein solution
The hydrochloric acid tune pH value that degree is 0.1mol/L is to after 6.5 ~ 7.5, successively through instantaneous sterilizing, spray drying to get product caseinic acid calcium.
2. a kind of production method of caseinic acid calcium as claimed in claim, it is characterised in that：The temperature of the instantaneous sterilizing is
55~65℃。
3. a kind of production method of caseinic acid calcium as claimed in claim, it is characterised in that：The condition of the spray drying is
Refer to steam pressure >=0.75MPa, 150 DEG C ~ 170 DEG C of tower body inlet air temperature, temperature is 65 ~ 75 DEG C in tower, tower body temperature of outgoing air 60
DEG C ~ 70 DEG C, negative pressure is -20 ~ -100Pa in tower, and high pressure pump pressure is 10 ~ 25MPa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810437214.3A CN108652014A (en) | 2018-05-09 | 2018-05-09 | A kind of production method of caseinic acid calcium |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810437214.3A CN108652014A (en) | 2018-05-09 | 2018-05-09 | A kind of production method of caseinic acid calcium |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108652014A true CN108652014A (en) | 2018-10-16 |
Family
ID=63778792
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810437214.3A Pending CN108652014A (en) | 2018-05-09 | 2018-05-09 | A kind of production method of caseinic acid calcium |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108652014A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02157300A (en) * | 1988-12-08 | 1990-06-18 | Tosoh Corp | Production of solubilized calcium caseinate |
| CN1383746A (en) * | 2001-04-30 | 2002-12-11 | 陆晓民 | Application of calcium caseinate in food |
| CN1384117A (en) * | 2001-04-30 | 2002-12-11 | 陆晓民 | Production process of calcium caseinate |
| CN102293315A (en) * | 2010-06-26 | 2011-12-28 | 临夏州华夏乳品有限责任公司 | Method for producing calcium caseinate from milk |
| CN102763762A (en) * | 2012-07-31 | 2012-11-07 | 甘肃华羚生物技术研究中心 | Method for producing instant calcium caseinate from food-grade casein |
-
2018
- 2018-05-09 CN CN201810437214.3A patent/CN108652014A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02157300A (en) * | 1988-12-08 | 1990-06-18 | Tosoh Corp | Production of solubilized calcium caseinate |
| CN1383746A (en) * | 2001-04-30 | 2002-12-11 | 陆晓民 | Application of calcium caseinate in food |
| CN1384117A (en) * | 2001-04-30 | 2002-12-11 | 陆晓民 | Production process of calcium caseinate |
| CN102293315A (en) * | 2010-06-26 | 2011-12-28 | 临夏州华夏乳品有限责任公司 | Method for producing calcium caseinate from milk |
| CN102763762A (en) * | 2012-07-31 | 2012-11-07 | 甘肃华羚生物技术研究中心 | Method for producing instant calcium caseinate from food-grade casein |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181016 |
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| RJ01 | Rejection of invention patent application after publication |