CN108642887A - A kind of wearable health-care material - Google Patents

A kind of wearable health-care material Download PDF

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Publication number
CN108642887A
CN108642887A CN201810396566.9A CN201810396566A CN108642887A CN 108642887 A CN108642887 A CN 108642887A CN 201810396566 A CN201810396566 A CN 201810396566A CN 108642887 A CN108642887 A CN 108642887A
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CN
China
Prior art keywords
transition metal
metal oxide
cotton
ceramic powder
oxide ceramic
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Pending
Application number
CN201810396566.9A
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Chinese (zh)
Inventor
王恩慧
其他发明人请求不公开姓名
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Suqian Southern Airlines New Materials And Equipment Manufacturing Research Institute Co Ltd
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Suqian Southern Airlines New Materials And Equipment Manufacturing Research Institute Co Ltd
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Publication date
Application filed by Suqian Southern Airlines New Materials And Equipment Manufacturing Research Institute Co Ltd filed Critical Suqian Southern Airlines New Materials And Equipment Manufacturing Research Institute Co Ltd
Priority to CN201810396566.9A priority Critical patent/CN108642887A/en
Publication of CN108642887A publication Critical patent/CN108642887A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic System
    • D06M11/42Oxides or hydroxides of copper, silver or gold
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/48Oxides or hydroxides of chromium, molybdenum or tungsten; Chromates; Dichromates; Molybdates; Tungstates
    • D06M11/485Oxides or hydroxides of manganese; Manganates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/49Oxides or hydroxides of elements of Groups 8, 9, 10 or 18 of the Periodic System; Ferrates; Cobaltates; Nickelates; Ruthenates; Osmates; Rhodates; Iridates; Palladates; Platinates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/74Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them

Abstract

The present invention provides a kind of wearable health-care materials, are made of laminated fiberglass cotton and cotton surface transition metal oxide ceramic material coating, and the laminated fiberglass cotton is impregnated through graphene/polyurethane compositional liquor to be made;Transition metal oxide ceramic powder coating is with transition metal oxide Fe2O3、MnO2、Co2O3, CuO be primary raw material, apply to form uniform coating on glass fibre cotton surface layer using polyacrylate as adhesive.Transition metal oxide ceramic powder coating good film-forming property in the present invention, with washability and folding line recovery capability, with high far infrared transmissivity, it can improve body surface microcirculation using infra-red radiation under room temperature or body temperature and improve shell temperature, immune function is improved, health-care effect is reached.

Description

A kind of wearable health-care material
Technical field
The present invention relates to a kind of health-care material more particularly to a kind of wearable health-care materials.
Background technology
With the development of society, the raising of living standards of the people, ordinary consumer is increasingly heavier when choosing various products Depending on the safety and health of product.People have higher requirement to dress materials, in the warmth retention property for ensureing general dress materials On the basis of it is also desirable that there is more additional functions.Such as people to the favor of far infrared health care material subsist benefit improve, people The reasons why far-infrared fabric is favored:It traces it to its cause, in that it has health properties.Far infrared radioactivity substance is deposited In the hygiogenesis for constituting fabric.When people wear and use this fabric, the far infrared of sunlight etc. can be absorbed simultaneously It is converted into thermal energy, the heat of human body can also be reflected and obtain warming effect, this far infrared radioactivity substance is in body Under the action of temperature, can expeditiously radiate the far infrared that wavelength is 8~14 μm also has in addition to it can be used as thermal insulation material Antibacterial, deodorization, the functions such as promote blood circulation, and is ideal warm body-building textile.Far infrared is humans and animals existence life Long necessary nutrition, the far infrared of this wave band is easily absorbed by human body, after absorption of human body, not only produces the surface layer of skin Heat effect, but also resonant interaction is generated by molecule, to make the deep tissue of skin cause the effect of self-heating, this The generation of kind of effect can cell stimulating activity, promote the metabolism of human body, and then improve the microcirculation of blood, improve machine The immunocompetence of body plays a series of medical health effect.With the development of science and technology meeting the health-care material of people's needs It emerges one after another, but most of health-care material functionality is also relatively simple currently on the market, complicated, wearing of going out is inconvenient, Therefore antibacterial and with far-infrared health care function clothing is increasingly becoming the direction of people's demand and selection.Current domestic and international antibacterial Polyester fiber is mainly that anti-bacterial fibre is made with polyester blend melt spinning in metal ion type antiseptic.With metal ion antibacterial Agent compares, and the antibiotic property of graphene oxide is stronger, and harmless, therefore its application is widely paid close attention to.
Chinese Patent Application No. 2009200613325 is related to novel far infrared fabric, including at least two layers, including extremely A few far IR fibre shell fabric internal layer and an at least near-infrared fiber shell fabric outer layer;New far infrared face as described above Material, the wherein healthcare face fabric are two layers;Wherein the far IR fibre shell fabric is the polyacrylonitrile by incorporation ceramic powders With fabric made of cotton blend;Wherein the near-infrared fiber shell fabric is the polyacrylonitrile and cotton blend by incorporation zirconium carbide Made of fabric;Providing for the utility model is simple in structure, the good Novel health fabric of heat insulation effect, but it presses down in antibacterial Deficient function in terms of bacterium.
Chinese Patent Application No. 2013106529103 its be related to it is a kind of suitable for winter dress Far-infrared shell fabric of bluish dogbane Insulation garment, including garment body, garment body are provided with solar panel behind, and solar panel and setting are in clothes The accumulator of body interior connects, and is provided with multiple infrared heat-transfer devices in the interlayer of garment body, infrared heat-transfer device with Accumulator be connected, the garment body is made of fabric, the fabric from the inside to the outside successively by far infrared layer, bluish dogbane layer and it is pure Cotton fabric layer is total to three-decker closely compound composition, and far infrared coating is foam coating, may be implemented to reduce winter to clothes The quantity of dress, and have the function of infrared health, but its equipment is complicated, cleaning wearing is inconvenient.
In conclusion there has been no meet to have far infrared health care performance, antibacterial bacteriostatic performance, warming heat insulating ability simultaneously at present Can, dress convenient, the wearable health-care material of resistance to cleaning performance.
Invention content
The present invention is directed to overcome the deficiencies of the prior art and provide a kind of wearable health-care material.
To realize the present invention purpose the technical solution adopted is that:Provide a kind of wearable health-care material, it is characterised in that It is made of laminated fiberglass cotton and cotton surface transition metal oxide ceramic material coating, the laminated fiberglass cotton By glass fibre and hydroxyl silicon oil modified acrylic resin adhesive according to mass ratio (2~5): 1 forms, and through nano oxidized Graphene/polyurethane compositional liquor, which impregnates, to be made, and layered glass fibre cotton thickness is 0.6~2cm;The oxo transition metal Compound ceramic powder coating is with transition metal oxide Fe2O3、MnO2、Co2O3, CuO be primary raw material, be viscous with polyacrylate Mixture applies to form the uniform coating that thickness is 150~250 μm on laminated fiberglass cotton surface layer.
Further, in the nano graphene oxide/polyurethane compositional liquor nano graphene oxide mass fraction It is 0.9%~2%.
Further, the transition metal oxide ceramic powder coating by transition metal oxide ceramic powder and gathers The slurry that acrylic ester adhesive is formed is made, and the mass fraction of the slurry is 20%~40%, room temperature far infrared radiation rate It is 0.86~0.93.
Further, the transition metal oxide ceramic powder is at being grouped as and mass ratio is:Fe2O3(16%~ 25%), MnO2(53%~64%), Co2O3(10%~11%), CuO (10%~11%).
The present invention is by above technical scheme, generated advantageous effect:(1) glass fibre cotton of the present invention is fine It is ultra-fine to tie up diameter, and fiber surface is uniformly wrapped in by acrylic acid, fiber is not easy brittle failure, and heat-preservation cotton thermal coefficient is low, heat insulating ability It can be excellent.(2) transition metal oxide ceramic powder coating good film-forming property has washability and folding line recovery capability.(3) coating With high far infrared transmissivity, the heat sources such as electricity, gas, oil are not depended on, it can using infra-red radiation under room temperature or body temperature To improve body surface microcirculation and improve shell temperature, immune function is improved, health-care effect is reached.(4) through through nano oxidized The glass fibre cotton that graphene/polyurethane compositional liquor impregnates has good antibiotic property, biocidal property.

Claims (4)

1. a kind of wearable health-care material, it is characterised in that made pottery by laminated fiberglass cotton and cotton surface transition metal oxide Ceramic powder coating forms, and the laminated fiberglass cotton is pressed by glass fibre and hydroxyl silicon oil modified acrylic resin adhesive According to mass ratio (2~5): 1 composition, and impregnate and be made through nano graphene oxide/polyurethane compositional liquor, layered glass fibers Vinylon and cotton blend thickness is 0.6~2cm;The transition metal oxide ceramic powder coating is with transition metal oxide Fe2O3、MnO2、 Co2O3, CuO be primary raw material, apply on laminated fiberglass cotton surface layer that form thickness be 150 by adhesive of polyacrylate ~250 μm of uniform coating.
2. a kind of wearable health-care material according to claim 1, it is characterised in that the nano graphene oxide/poly- The mass fraction of nano graphene oxide is 0.9%~2% in urethane compositional liquor.
3. a kind of wearable health-care material according to claim 1, it is characterised in that the transition metal oxide pottery The slurry that ceramic powder coating is formed by transition metal oxide ceramic powder and palyacrylate binder is made, the slurry Mass fraction is 20%~40%, and room temperature far infrared radiation rate is 0.86~0.93.
4. a kind of wearable health-care material according to claim 1 and 3, it is characterised in that the transition metal oxide Ceramic powder is at being grouped as and mass ratio is:Fe2O3(16%~25%), MnO2(53%~64%), Co2O3(10%~ 11%), CuO (10%~11%).
CN201810396566.9A 2018-04-20 2018-04-20 A kind of wearable health-care material Pending CN108642887A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111411533A (en) * 2020-04-17 2020-07-14 成都新柯力化工科技有限公司 Method for preparing graphene heating non-woven fabric through roll-to-roll printing

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CN104118174A (en) * 2014-08-08 2014-10-29 太仓派欧技术咨询服务有限公司 Glass fiber blanket with high heat conductivity
CN204919184U (en) * 2015-03-10 2015-12-30 李强 Flexible wire, conductive fabric , fabric generates heat
CN106544853A (en) * 2016-10-19 2017-03-29 珠海富琳科技发展有限公司 A kind of far-infrared magnet therapeutic multifunctional textile product and the clothing being made from it
CN106544852A (en) * 2016-10-19 2017-03-29 珠海富琳科技发展有限公司 A kind of multi-functional weaving material of far-infrared magnet therapeutic and the medicated cushion being made from it
CN106988115A (en) * 2017-03-06 2017-07-28 常熟市东宇绝缘复合材料有限公司 High-performance alkali-resistant glass fibre felt
CN107460633A (en) * 2017-08-19 2017-12-12 宿迁南航新材料与装备制造研究院有限公司 A kind of field exploration clothes novel heat preserving cotton

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120251796A1 (en) * 2011-03-30 2012-10-04 Owens Corning Intellectual Capital, Llc High thermal resistivity insulation material with opacifier uniformly distributed thoughout
CN104118174A (en) * 2014-08-08 2014-10-29 太仓派欧技术咨询服务有限公司 Glass fiber blanket with high heat conductivity
CN204919184U (en) * 2015-03-10 2015-12-30 李强 Flexible wire, conductive fabric , fabric generates heat
CN106544853A (en) * 2016-10-19 2017-03-29 珠海富琳科技发展有限公司 A kind of far-infrared magnet therapeutic multifunctional textile product and the clothing being made from it
CN106544852A (en) * 2016-10-19 2017-03-29 珠海富琳科技发展有限公司 A kind of multi-functional weaving material of far-infrared magnet therapeutic and the medicated cushion being made from it
CN106988115A (en) * 2017-03-06 2017-07-28 常熟市东宇绝缘复合材料有限公司 High-performance alkali-resistant glass fibre felt
CN107460633A (en) * 2017-08-19 2017-12-12 宿迁南航新材料与装备制造研究院有限公司 A kind of field exploration clothes novel heat preserving cotton

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111411533A (en) * 2020-04-17 2020-07-14 成都新柯力化工科技有限公司 Method for preparing graphene heating non-woven fabric through roll-to-roll printing

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Application publication date: 20181012