CN104824890A - Gluing multi-layer flocking type high-elastic antibiosis warm-retention sheet-shaped material and preparation method thereof - Google Patents
Gluing multi-layer flocking type high-elastic antibiosis warm-retention sheet-shaped material and preparation method thereof Download PDFInfo
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- CN104824890A CN104824890A CN201510251562.8A CN201510251562A CN104824890A CN 104824890 A CN104824890 A CN 104824890A CN 201510251562 A CN201510251562 A CN 201510251562A CN 104824890 A CN104824890 A CN 104824890A
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Abstract
The invention relates to a gluing multi-layer flocking type high-elastic antibiosis warm-retention sheet-shaped material and a preparation method thereof and belongs to the technical field of textiles. An antibacterial agent is sprayed inside an upper layer fiber web, an upper-middle layer fiber web, a middle-lower layer fiber web, a lower layer fiber web of the high-elastic antibiosis warm-retention sheet-shaped material, upper fluff are clamped between the upper layer fiber web and the upper-middle layer fiber web in an up-right shape, lower fluff are clamped between the middle-lower layer fiber web and the lower layer fiber web, and the upper-middle layer fiber web and the middle-lower layer fiber web are fixedly combined together. The preparation method includes the steps of 1, preparing fiber web, 2, spraying the antibacterial agent, 3, drying, 4, gluing, 5, electrostatic flocking, 6, drying, 7, sucking fluff, 8, fixedly combining films on the fiber webs, 9, compounding the fiber webs, 10, drying, and 11, winding. Compared with the prior art, the prepared warm-retention sheet-shaped material has the advantages that the antibacterial function is achieved, the elasticity is good, and the warm retention performance is good.
Description
Technical field
The present invention relates to the high-elastic antibacterial thermal insulating flaky material of a kind of gluing Multi-layer flocking formula and manufacture method thereof, belong to field of textiles.
Background technology
In life in the past, the tradition that people's use is prepared using cotton, fiber crops, silk, hair and common terylene, polyamide fibre, acrylic fibers and staple fibre etc. is heat insulating material formed as heat insulating material formed, during these are heat insulating material formed, silk and wool warmth retention property are better, but the easy breed bacteria of fiber, not resistance toly to damage by worms, and silk is expensive, wool fiber has peculiar smell, forming degree poor, and the cashmere price after multiple working procedure processing is more expensive, and the scope of application is limited to for many years.Along with living standard and scientific and technical development, people start will heat insulating material formed with regard to development of new, occur that by terylene, polypropylene fibre and acrylic fibers be main chemical fibre insulation flocculus, as the far infrared such as gum sprayed cotton, acupuncture cotton, space wadding, hot melting wool, melt-blown far infrared cotton, ultra-fine hot melting wool, down-like cotton.The principal mode of heat trnasfer has heat transfer, heat radiation and thermal convection current three kinds of modes.Material characteristics and internal structure determine the speed of its heat conduction velocity under normal circumstances, material internal structure and outer shape determine the quality of its heat radiation and antiradiation performance, its ability keeping still air and stop air flowing of material shape and structures shape.Traditional heat insulating material formedly to carry out between increased fiber still air layer to improve thermal property mainly through increasing thickness and density.The thickness of usual material is larger, density is less, the warmth retention property of material is larger, if but the density of material is too small, when causing air wherein to produce convection current, heat-insulating property declines on the contrary, for clothes with for heat insulating material formed, thickness is crossed conference and is caused the volume ratio of clothes more too fat to move, is not easy to motion and lacks aesthetic feeling again.Therefore, the exploitation of novel heat-preserving material becomes the main flow of heat insulating material formed research with research.The novel heat-preserving material developed in recent years also has far-infrared warm material, sunlight heat accumulation thermal material, medium phase-changing and temperature-regulating material etc., this kind ofly heat insulating material formedly not only follow traditional heat-insulation warm keeping principle, and can by some other form, such as absorb external heat, store and produce fuel factor to human body transmission, or solar energy, electric energy and chemical energy etc. are changed into heat energy to reach the object of heat-insulation warm keeping.In order to the insulation flocculus that processability is more excellent, static flocking technology is also incorporated into the preparation of insulation flocculus.Utilize static flocking technology to combine with traditional insulation flocculus manufacture method to prepare Novel heat-preservation flocculus and have bibliographical information.As Chinese invention patent application publication No. CN102493128A, denomination of invention is a kind of manufacture method of melt blowing warm retention wadding, this application case discloses a kind of manufacture method of melt blowing warm retention wadding, heat-accumulation temperature-adjustment short fiber is implanted in the middle of melt-blowing nonwoven by electrostatic field, obtained melt blowing warm retention wadding.This method utilizes static flocking technology, short fiber is implanted to non-woven webs inside, little to the performance impact such as elasticity and bulkiness of insulation flocculus.In daily life, bacterium is ubiquitous, and too much bacterium can cause the problem of the aspect such as skin disease, respiratory infectious disease, and the invasion and attack of common textile to bacterium do not have too many protective action.In present insulation flocculus product, high resiliency, bulkiness, warmth retention property and the insulation flocculus with anti-microbial property compares shortage can be realized, therefore, prepare a kind of high-elastic antibacterial thermal insulating flocculus and there is realistic meaning.
Summary of the invention
The object of the present invention is to provide that a kind of warmth retention property is good, the antibacterial thermal insulating flaky material of good springiness and manufacture method thereof.
To achieve these goals, technical scheme of the present invention is: the high-elastic antibacterial thermal insulating flaky material of a kind of gluing Multi-layer flocking formula, it is characterized in that: upper strata fibre web, fibre web at the middle and upper levels, middle lower floor fibre web, the inside of lower floor's fibre web is sprayed with antiseptic, upper strata fibre web and at the middle and upper levels fibre web surface are in opposite directions coated with respectively and are covered with binder film, in upper binder film, upper fine hair is clipped in upper strata fibre web and at the middle and upper levels between fibre web, the two ends of upper fine hair are inserted in binder film respectively, in among upper binder film, be cemented in the surface of upper strata fibre web and the surface of fibre web at the middle and upper levels, lower binder film during middle lower floor fibre web and lower floor's fibre web surface in opposite directions apply respectively, lower binder film, lower fine hair is clipped between middle lower floor fibre web and lower floor's fibre web, lower binder film during the two ends of lower fine hair are inserted in respectively, among lower binder film, be cemented in the surface of middle lower floor fibre web and lower floor's fibre web, fibre web and middle lower floor fibre web are consolidated by one deck hot melt film at the middle and upper levels.
Described upper strata fibre web, at the middle and upper levels fibre web, middle lower floor fibre web, lower floor's fibre web are the fibre web of short-fibred mechanical carding or air lay.
Described antiseptic is good anti-bacterial effect, laundry-resistant antiseptic.
Described upper binder film, in upper binder film, in the adhesive selected of lower binder film, lower binder film be that adhesion strength is high, water-fastness, the adhesive of aging-resisting type.
Described upper binder film, in upper binder film, in lower binder film, lower binder film shape be bar shaped or grid shape, size is identical.
Described upper fine hair, the material of lower fine hair are polyester fiber or Fypro.
A manufacture method for the high-elastic antibacterial thermal insulating flaky material of above-mentioned gluing Multi-layer flocking formula, is characterized in that: the method comprises the steps:
(1) fibre web preparation: prepare upper strata fibre web, at the middle and upper levels fibre web, middle lower floor fibre web, lower floor's fibre web respectively;
(2) antiseptic is sprayed: spray to upper strata fibre web, at the middle and upper levels fibre web, middle lower floor fibre web, lower floor's fibre web the antiseptic prepared under a certain pressure respectively;
(3) drying: respectively to being sprayed with upper strata fibre web, the at the middle and upper levels fibre web of antiseptic, middle lower floor fibre web, lower floor's fibre web carry out drying;
(4) gluing: be coated with in the one side of upper strata fibre web, at the middle and upper levels fibre web, middle lower floor fibre web, lower floor's fibre web be respectively covered with binder film, on binder film, in lower binder film, lower binder film;
(5) electrostatic spinning: be coated with on the surface of adhesive at fibre web and middle lower floor fibre web at the middle and upper levels and carry out electrostatic spinning, is implanted in the surface of fibre web, middle lower floor fibre web at the middle and upper levels respectively by upper fine hair, lower fine hair;
(6) drying: drying is carried out to the fibre web at the middle and upper levels and middle lower floor fibre web that complete electrostatic spinning;
(7) suede is inhaled: the fibre web at the middle and upper levels crossed by drying and middle lower floor fibre web carry out the process of suction suede;
(8) fibre web overlay film consolidation: do not have the one side of flocking to be superimposed with each other the fibre web at the middle and upper levels after the process of suction suede and middle lower floor fibre web, and therebetween one deck hot melt film, through Overheating Treatment will fibre web and middle lower floor fibre web be consolidated at the middle and upper levels;
(9) fibre web compound: one side upper strata fibre web being had upper binder film, is compounded on the flocked surface of fibre web at the middle and upper levels, lower floor's fibre web is had the one side of lower binder film, is compounded on the flocked surface of middle lower floor fibre web;
(10) drying: after fibre web compound, carries out drying;
(11) reel: after drying, winding, the obtained high-elastic antibacterial thermal insulating flaky material of gluing Multi-layer flocking formula.
Owing to adopting above technical scheme, the high-elastic antibacterial thermal insulating flaky material of gluing Multi-layer flocking formula of the present invention, has following characteristics:
One, the present invention utilizes static flocking technology to implant fine hair short fiber between multilayer fibre web, still air region is formed between fibre web, not only warming effect can be improved, and compared with prior art, the space of fibre web inside is large, under the condition of same thickness, the use amount of fibrous material can be reduced, reduce production cost.
Two, the present invention selects the antiseptic of good anti-bacterial effect, sprays into fibre web with the form of spraying, and can realize the antibacterial requirement of warming flaky material, also ensure the gas permeability of material, warmth retention property simultaneously, and to human body and environmental nonpollution.
Three, because the bonded oxidant layer in two ends of fine hair is cemented on two-layer fibre web, fine hair is shorter, and when villus length direction is stressed, bending resistance is strong, and recovery is good, the good springiness of the warming flaky material of manufacture.
Four, the hot melt film that the present invention selects is the hot melt net of Reticular breathable structure, while can meeting the bonding compound between two layer web, ensures the gas permeability of flaky material.
Five, the adhesive that the present invention selects is adhesive that is water-fastness, aging-resisting type, the requirement of clothes can be met, take bar shaped or grid shape glue spreading method, realizing the high resiliency of warming flaky material, while improving warmth retention property, can ensure the gas permeability of flaky material, be the ideal material of alternative eider down, as filler, garment industry can be widely used in.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention.
Fig. 2 be according to embodiment of the present invention at the middle and upper levels fibre web carry out the structural representation after the flocking of bar shaped gluing.
Fig. 3 be according to embodiment of the present invention at the middle and upper levels fibre web carry out the structural representation after the flocking of grid shape gluing.
Detailed description of the invention
Below in conjunction with the drawings and specific embodiments, the present invention is described in further detail.
See Fig. 1-Fig. 3.
The high-elastic antibacterial thermal insulating flaky material of gluing Multi-layer flocking formula, comprise upper strata fibre web 1, upper binder film 2, in upper binder film 4
,, fibre web 2, hot melt film 6, middle lower floor fibre web 2 at the middle and upper levels
,, in lower binder film 5, lower binder film 5
,, lower floor's fibre web 1
,, upper fine hair 3, lower fine hair 3
,, antiseptic 7,7
,, 8,8
,.Upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor fibre web 2
,, lower floor's fibre web 1
,for the fibre web of short-fibred mechanical carding or air lay.The antiseptic 7 of the chitosan-containing of upper strata fibre web 1 internal spray good anti-bacterial effect, the at the middle and upper levels antiseptic 7 of the chitosan-containing of fibre web 2 internal spray good anti-bacterial effect
,, middle lower floor fibre web 2
,the antiseptic 8 of the chitosan-containing of internal spray good anti-bacterial effect
,, lower floor's fibre web 1
,the antiseptic 8 of the chitosan-containing of internal spray good anti-bacterial effect, shitosan can affect bacterial activity, obtains good antibacterial effect, and shitosan has good wash durability.Upper strata fibre web 1 and fibre web 2 surface in opposite directions be at the middle and upper levels coated with respectively be covered with binder film 4, in upper binder film 4
,, upper fine hair 3 is clipped in upper strata fibre web 1 and at the middle and upper levels between fibre web 2, the two ends of upper fine hair 3 be inserted in respectively binder film 4, in upper binder film 4
,among, be cemented in the surface of upper strata fibre web 1 and the surface of fibre web 2 at the middle and upper levels, middle lower floor fibre web 2
,with lower floor fibre web 1
,lower binder film 5, lower binder film 5 during surface in opposite directions applies respectively
,, lower fine hair 3
,be clipped in middle lower floor fibre web 2
,with lower floor fibre web 1
,between, lower fine hair 3
,two ends be inserted in respectively in lower binder film 5, lower binder film 5
,among, be cemented in middle lower floor fibre web 2
,with lower floor fibre web 1
,surface, fibre web 2 and middle lower floor fibre web 2 at the middle and upper levels
,be consolidated by one deck hot melt film 6.Upper binder film 4, in upper binder film 4
,size identical, shape is bar shaped or lattice shape, and the position being coated in the surface of upper strata fibre web 1 and the surface of fibre web 2 is at the middle and upper levels corresponding, lower binder film 5, lower binder film 5
,size identical, shape is bar shaped or lattice shape, is coated in middle lower floor fibre web 2
,surface and lower floor's fibre web 1
,the position on surface corresponding, be conducive to fine hair 3 and lower fine hair 3
,become vertical, improve the elasticity of warming flaky material.In order to improve the performances such as the resistance to water of warming flaky material, upper binder film 4, in upper binder film 4
,, in lower binder film 5, lower binder film 5
,the adhesive selected is that adhesion strength is high, water-fastness, the adhesive of aging-resisting type.Upper fine hair 3 and lower fine hair 3
,material be polyester fiber or Fypro.
The manufacture method of the high-elastic antibacterial thermal insulating flaky material of gluing Multi-layer flocking formula, the method comprises the steps:
(1) fibre web preparation: prepare upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor fibre web 2 respectively
,, lower floor's fibre web 1
,;
(2) spray antiseptic: evenly spray to upper strata fibre web 1 antiseptic 7 prepared under a certain pressure respectively, evenly spray to fibre web 2 at the middle and upper levels the antiseptic 7 prepared
,, to middle lower floor fibre web 2
,the antiseptic 8 that even sprinkling prepares
,, lower floor's fibre web 1
,the antiseptic 8 that even sprinkling prepares, makes antiseptic 7,7
,, 8
,, 8 can be evenly distributed in upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor fibre web 2 as far as possible
,, lower floor's fibre web 1
,inside, obtain good anti-microbial property after being convenient to drying;
(3) drying: respectively to being sprayed with antiseptic 7,7
,, 8
,, the upper strata fibre web 1 of 8, at the middle and upper levels fibre web 2, middle lower floor fibre web 2
,, lower floor's fibre web 1
,carry out drying;
(4) gluing: respectively at upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor fibre web 2
,, lower floor's fibre web 1
,one side on application of adhesive, upper binder film 4, in upper binder film 4
,, in lower binder film 5, lower binder film 5
,, upper binder film 4 with in upper binder film 4
,shape and the identical bar shaped of size or lattice shape, be coated in upper strata fibre web 1 corresponding with the position on the surface of fibre web 2 at the middle and upper levels, be convenient to when electrostatic spinning, upper fine hair 3 one-tenth vertical, in lower binder film 5, lower binder film 5
,shape and the identical bar shaped of size or lattice shape, be coated in middle lower floor fibre web 2
,, lower floor's fibre web 1
,the position on surface be correspondingly convenient to when electrostatic spinning, lower fine hair 3
,become vertical;
(5) electrostatic spinning: at fibre web 2 and middle lower floor fibre web 2 at the middle and upper levels
,electrostatic spinning is carried out, respectively by upper fine hair 3, lower fine hair 3 in the surface being coated with adhesive
,be implanted in fibre web 2, middle lower floor fibre web 2 at the middle and upper levels
,surface be in plumbness;
(6) drying: to the fibre web at the middle and upper levels 2 and the middle lower floor fibre web 2 that complete electrostatic spinning
,carry out drying, in upper binder film 4
,with in the moisture of lower binder film 5 evaporate, upper fine hair 3 and lower fine hair 3
,be cemented in fibre web 2 and middle lower floor fibre web 2 at the middle and upper levels
,surface;
(7) suede is inhaled: fibre web at the middle and upper levels 2 and the middle lower floor fibre web 2 crossed by drying
,carry out the process of suction suede, fibre web 2 and middle lower floor fibre web 2 at the middle and upper levels will be scattered in
,there is no the position of application of adhesive on the surface and not by the upper fine hair 3 of adhesive secure bond and lower fine hair 3
,sop up, make fibre web 2 and middle lower floor fibre web 2 at the middle and upper levels
,surface clean clean and tidy;
(8) fibre web overlay film consolidation: by fibre web at the middle and upper levels 2 and the middle lower floor fibre web 2 inhaled after suede process
,the one side of flocking is not had to be superimposed with each other, and therebetween one deck hot melt film 6, incite somebody to action fibre web 2 and middle lower floor fibre web 2 at the middle and upper levels through Overheating Treatment
,be consolidated;
(9) fibre web compound: under electrostatic field, has the one side of upper binder film 4 by upper strata fibre web 1, be compounded on the flocked surface of fibre web 2 at the middle and upper levels, by lower floor's fibre web 1
,there is lower binder film 5
,one side, be compounded in middle lower floor fibre web 2
,flocked surface on, upper fine hair 3 and lower fine hair 3
,be in the erectility stretched;
(10) drying: after fibre web compound, carries out drying;
(11) reel: after drying, winding, the obtained high-elastic antibacterial thermal insulating flaky material of gluing Multi-layer flocking formula.
embodiment 1
Bar shaped gluing flocking formula machinery becomes net height bullet antibacterial thermal insulating flaky material and preparation method thereof:
See Fig. 1, Fig. 2, the high-elastic antibacterial thermal insulating flaky material of gluing Multi-layer flocking formula, comprise upper strata fibre web 1, upper binder film 4, in upper binder film 4 ', at the middle and upper levels fibre web 2, hot melt film 6, middle lower floor fibre web 2 ', in lower binder film 5, lower binder film 5 ', lower floor's fibre web 1 ', upper fine hair 3, lower fine hair 3 ', antiseptic 7,7
,, 8,8
,.Upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor fibre web 2 ', lower floor's fibre web 1 ' for fineness be 3D, length is the hollow polyester fibre of the three-dimensional crimp of 51mm and fineness is 3D, length is 51mm, fusing point is the low-melting fiber of 110 DEG C, shredding mixing is carried out, through the fibre web that short-fibred mechanical combing prepares according to weight ratio 80%:20%.The antiseptic 7 of the chitosan-containing of upper strata fibre web 1 internal spray good anti-bacterial effect, the at the middle and upper levels antiseptic 7 of the chitosan-containing of fibre web 2 internal spray good anti-bacterial effect
,, middle lower floor fibre web 2
,the antiseptic 8 of the chitosan-containing of internal spray good anti-bacterial effect
,, lower floor's fibre web 1
,the antiseptic 8 of the chitosan-containing of internal spray good anti-bacterial effect, upper strata fibre web 1 and at the middle and upper levels fibre web 2 surface are in opposite directions coated with respectively and are covered with binder film 4, in upper binder film 4 ', upper fine hair 3 is clipped in upper strata fibre web 1 and at the middle and upper levels between fibre web 2, the two ends of upper fine hair 3 are inserted in binder film 4 respectively, in among upper binder film 4 ', be cemented in the surface of upper strata fibre web 1 and the surface of fibre web 2 at the middle and upper levels, lower binder film 5 during middle lower floor fibre web 2 ' and lower floor's fibre web 1 ' surface in opposite directions apply respectively, lower binder film 5 ', lower fine hair 3 ' is clipped between middle lower floor fibre web 2 ' and lower floor's fibre web 1 ', lower binder film 5 during the two ends of lower fine hair 3 ' are inserted in into respectively, among lower binder film 5 ', be cemented in the surface of middle lower floor fibre web 2 ' and lower floor's fibre web 1 ', fine hair selects fineness to be 5D, length is the polyester staple fiber of 1.5mm.Fibre web 2 and middle lower floor fibre web 2 ' are consolidated by the EVA hot-melt adhesive nethike embrane that one deck melting temperature is 110 DEG C at the middle and upper levels, upper binder film 4, in upper binder film 4 ' size identical, shape is bar shaped, the position being coated in the surface of upper strata fibre web 1 and the surface of fibre web 2 is at the middle and upper levels corresponding, in lower binder film 5, lower binder film 5 ' size identical, shape is bar shaped, and the position being coated in the surface of middle lower floor fibre web 2 ' and the surface of lower floor's fibre web 1 ' is corresponding.The adhesive that adhesive is selected is high, water-fastness, the ageing-resistant polyacrylate static flocking adhesive of adhesion strength.
The manufacture method of the high-elastic antibacterial thermal insulating flaky material of gluing Multi-layer flocking formula, the method comprises the steps:
(1) fibre web preparation: adopt mechanical carding method into the net, prepares upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor fibre web 2 ', lower floor's fibre web 1 ' respectively;
(2) antiseptic is sprayed: obtained upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor fibre web 2 ', lower floor's fibre web 1 ' feed flusher, antiseptic 7 are evenly sprayed onto upper strata fibre web 1, antiseptic 7
,evenly be sprayed onto fibre web 2 at the middle and upper levels, antiseptic 8
,evenly be sprayed onto middle lower floor fibre web 2 ', it is inner that antiseptic 8 is evenly sprayed onto lower floor's fibre web 1 ';
(3) drying: respectively to being sprayed with antiseptic 7,7
,, 8
,, the upper strata fibre web 1 of 8, at the middle and upper levels fibre web 2, middle lower floor fibre web 2 ', lower floor's fibre web 1 ' carry out drying, drying mode is hot blast drying, and temperature is 160 DEG C, and criteria thus the drying time is 3min;
(4) gluing: respectively at upper strata fibre web 1, fibre web 2 at the middle and upper levels, middle lower floor fibre web 2 ', application of adhesive in the one side of lower floor's fibre web 1 ', formation width is 1cm, thickness is 0.5mm, spacing distance is the upper binder film 4 of the strip along fabric width directional spreding of 1cm, in upper binder film 4 ', in lower binder film 5, lower binder film 5 ', upper binder film 4 with in the shape of upper binder film 4 ' and size identical, be coated in upper strata fibre web 1 corresponding with the position on the surface of fibre web 2 at the middle and upper levels, in lower binder film 5, shape and the size of lower binder film 5 ' are identical, be coated in middle lower floor fibre web 2 ', the position on the surface of lower floor's fibre web 1 ' is corresponding,
(5) electrostatic spinning: be coated with on the surface of adhesive at fibre web 2 and middle lower floor fibre web 2 ' at the middle and upper levels and carry out electrostatic spinning, use rated voltage is 50kV, output current is 5mA, the high voltage electric field of high voltage electric field anode-cathode distance 12cm, respectively upper fine hair 3, lower fine hair 3 ' are implanted in the surface of fibre web 2, middle lower floor fibre web 2 ' at the middle and upper levels, and make the surface of fine hair 3 and fibre web 2 at the middle and upper levels and lower fine hair 3 ' be in plumbness with the surface of middle lower floor fibre web 2 ';
(6) drying: drying is carried out to the fibre web at the middle and upper levels 2 and middle lower floor fibre web 2 ' that complete electrostatic spinning, drying mode is hot blast drying, temperature is 160 DEG C, criteria thus the drying time is 3min, during drying makes upper binder film 4 ' with in the moisture of lower binder film 5 evaporate, one end of upper fine hair 3 and lower fine hair 3 ' is cemented in the surface of fibre web 2, middle lower floor fibre web 2 ' at the middle and upper levels respectively;
(7) suede is inhaled: the fibre web at the middle and upper levels 2 crossed by drying and middle lower floor fibre web 2 ' carry out the process of suction suede, do not have the upper fine hair 3 on the position of application of adhesive, lower fine hair 3 ' on the surface and are not sopped up by the upper fine hair 3 of adhesive secure bond, lower fine hair 3 ' respectively by being scattered in fibre web 2 and middle lower floor fibre web 2 ' at the middle and upper levels;
(8) fibre web overlay film consolidation: do not have the one side of flocking to be superimposed with each other with middle lower floor fibre web 2 ' fibre web at the middle and upper levels 2 after inhaling suede process, and therebetween one deck hot melt film 6, to fibre web 2 and middle lower floor fibre web 2 ' be consolidated at the middle and upper levels through Overheating Treatment, hot pressing temperature is 160 DEG C, pressure size is 2.5bar, and hot pressing time is 10min;
(9) fibre web compound: be 50kV in rated voltage, output current is 5mA, under the high voltage electric field effect of high voltage electric field anode-cathode distance 12cm, upper strata fibre web 1 there is the one side of adhesive, be compounded on the flocked surface of fibre web 2 at the middle and upper levels, lower floor's fibre web 1 ' there is is the one side of adhesive, be compounded on the flocked surface of middle lower floor fibre web 2 '; Upper fine hair 3 and lower fine hair 3 ' are vertical with the surface of upper strata fibre web 1, lower floor's fibre web 1 ' respectively;
(10) drying: after fibre web compound, carry out drying, drying mode is hot blast drying, temperature is 160 DEG C, criteria thus the drying time is 3min, drying makes the moisture of binder film 4, lower binder film 5 ' evaporate, and one end of upper fine hair 3 is cemented in the surface of upper strata fibre web 1, and one end of lower fine hair 3 ' is cemented in the surface of lower floor's fibre web 1 ';
(11) reel: after drying, winding, the obtained high-elastic antibacterial thermal insulating flaky material of gluing Multi-layer flocking formula.
embodiment 2
Grid shape gluing flocking formula machinery becomes net height bullet antibacterial thermal insulating flaky material and preparation method thereof:
See Fig. 1, Fig. 3, the high-elastic antibacterial thermal insulating flaky material of gluing Multi-layer flocking formula, comprise upper strata fibre web 1, upper binder film 4, in upper binder film 4 ', at the middle and upper levels fibre web 2, hot melt film 6, middle lower floor fibre web 2 ', in lower binder film 5, lower binder film 5 ', lower floor's fibre web 1 ', upper fine hair 3, lower fine hair 3 ', antiseptic 7,7
,, 8,8
,.Upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor fibre web 2 ', lower floor's fibre web 1 ' are for being 3D for fineness, length is the hollow polyester fibre of the three-dimensional crimp of 51mm and fineness is 3D, length is 51mm, fusing point is the low-melting fiber of 110 DEG C, shredding mixing is carried out, through the fibre web that short-fibred mechanical combing prepares according to weight ratio 80%:20%.The antiseptic 7 of the chitosan-containing of upper strata fibre web 1 internal spray good anti-bacterial effect, the at the middle and upper levels antiseptic 7 of the chitosan-containing of fibre web 2 internal spray good anti-bacterial effect
,, middle lower floor fibre web 2
,the antiseptic 8 of the chitosan-containing of internal spray good anti-bacterial effect
,, lower floor's fibre web 1
,the antiseptic 8 of the chitosan-containing of internal spray good anti-bacterial effect, upper strata fibre web 1 and at the middle and upper levels fibre web 2 surface are in opposite directions coated with respectively and are covered with binder film 4, in upper binder film 4 ', upper fine hair 3 is clipped in upper strata fibre web 1 and at the middle and upper levels between fibre web 2, the two ends of upper fine hair 3 are inserted in binder film 4 respectively, in among upper binder film 4 ', be cemented in the surface of upper strata fibre web 1 and the surface of fibre web 2 at the middle and upper levels, lower binder film 5 during middle lower floor fibre web 2 ' and lower floor's fibre web 1 ' surface in opposite directions apply respectively, lower binder film 5 ', lower fine hair 3 ' is clipped between middle lower floor fibre web 2 ' and lower floor's fibre web 1 ', lower binder film 5 during the two ends of lower fine hair 3 ' are inserted in into respectively, among lower binder film 5 ', be cemented in the surface of middle lower floor fibre web 2 ' and lower floor's fibre web 1 ', fine hair selects fineness to be 5D, length is the polyamide short fibre of 1.5mm.Fibre web 2 and middle lower floor fibre web 2 ' are consolidated by the EVA hot-melt adhesive nethike embrane that one deck melting temperature is 110 DEG C at the middle and upper levels, upper binder film 4, in upper binder film 4 ' size identical, shape is grid shape, the position being coated in the surface of upper strata fibre web 1 and the surface of fibre web 2 is at the middle and upper levels corresponding, in lower binder film 5, lower binder film 5 ' size identical, shape is grid shape, and the position being coated in the surface of middle lower floor fibre web 2 ' and the surface of lower floor's fibre web 1 ' is corresponding.The adhesive that adhesive is selected is high, water-fastness, the ageing-resistant polyacrylate static flocking adhesive of adhesion strength.
The manufacture method of the high-elastic antibacterial thermal insulating flaky material of gluing Multi-layer flocking formula, the method comprises the steps:
(1) fibre web preparation: adopt mechanical carding method into the net, prepares upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor fibre web 2 ', lower floor's fibre web 1 ' respectively;
(2) antiseptic is sprayed: obtained upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor fibre web 2 ', lower floor's fibre web 1 ' feed flusher, antiseptic 7 are evenly sprayed onto upper strata fibre web 1, antiseptic 7
,evenly be sprayed onto fibre web 2 at the middle and upper levels, antiseptic 8
,evenly be sprayed onto middle lower floor fibre web 2 ', it is inner that antiseptic 8 is evenly sprayed onto lower floor's fibre web 1 ';
(3) drying: respectively to being sprayed with antiseptic 7,7
,, 8
,, the upper strata fibre web 1 of 8, at the middle and upper levels fibre web 2, middle lower floor fibre web 2 ', lower floor's fibre web 1 ' carry out drying, drying mode is hot blast drying, and temperature is 160 DEG C, and criteria thus the drying time is 3min;
(4) gluing: respectively at upper strata fibre web 1, fibre web 2 at the middle and upper levels, middle lower floor fibre web 2 ', application of adhesive in the one side of lower floor's fibre web 1 ', being formed along fabric width direction width is 1cm, spacing distance is 1cm, be 1cm along width length direction width, spacing distance is 1cm, thickness is the upper binder film 4 of the grid shape of 0.5mm, in upper binder film 4 ', in lower binder film 5, lower binder film 5 ', upper binder film 4 with in the shape of upper binder film 4 ' and size identical, be coated in upper strata fibre web 1 corresponding with the position on the surface of fibre web 2 at the middle and upper levels, in lower binder film 5, shape and the size of lower binder film 5 ' are identical, be coated in middle lower floor fibre web 2 ', the position on the surface of lower floor's fibre web 1 ' is corresponding,
(5) electrostatic spinning: be coated with on the surface of adhesive at fibre web 2 and middle lower floor fibre web 2 ' at the middle and upper levels and carry out electrostatic spinning, use rated voltage is 50kV, output current is 5mA, the high voltage electric field of high voltage electric field anode-cathode distance 12cm, respectively upper fine hair 3, lower fine hair 3 ' are implanted in the surface of fibre web 2, middle lower floor fibre web 2 ' at the middle and upper levels, and make the surface of fine hair 3 and fibre web 2 at the middle and upper levels and lower fine hair 3 ' be in plumbness with the surface of middle lower floor fibre web 2 ';
(6) drying: drying is carried out to the fibre web at the middle and upper levels 2 and middle lower floor fibre web 2 ' that complete electrostatic spinning, drying mode is hot blast drying, temperature is 160 DEG C, criteria thus the drying time is 3min, during drying makes upper binder film 4 ' with in the moisture of lower binder film 5 evaporate, one end of upper fine hair 3 and lower fine hair 3 ' is cemented in the surface of fibre web 2, middle lower floor fibre web 2 ' at the middle and upper levels respectively;
(7) suede is inhaled: the fibre web at the middle and upper levels 2 crossed by drying and middle lower floor fibre web 2 ' carry out the process of suction suede, there is no the upper fine hair 3 on the position of application of adhesive, lower fine hair 3 ' on the surface by being scattered in fibre web 2 and middle lower floor fibre web 2 ' at the middle and upper levels and not sopped up by the upper fine hair 3 of adhesive secure bond, lower fine hair 3 ' respectively, make the surface clean of fibre web 2 and middle lower floor fibre web 2 ' at the middle and upper levels clean and tidy, the fine hair after flocking is neat;
(8) fibre web overlay film consolidation: do not have the one side of flocking to be superimposed with each other with middle lower floor fibre web 2 ' fibre web at the middle and upper levels 2 after inhaling suede process, and therebetween one deck hot melt film 6, to fibre web 2 and middle lower floor fibre web 2 ' be consolidated at the middle and upper levels through Overheating Treatment, hot pressing temperature is 160 DEG C, pressure size is 2.5bar, and hot pressing time is 10min;
(9) fibre web compound: be 50kV in rated voltage, output current is 5mA, under the high voltage electric field effect of high voltage electric field anode-cathode distance 12cm, upper strata fibre web 1 there is the one side of adhesive, be compounded on the flocked surface of fibre web 2 at the middle and upper levels, lower floor's fibre web 1 ' there is is the one side of adhesive, be compounded on the flocked surface of middle lower floor fibre web 2 '; Upper fine hair 3 and lower fine hair 3 ' are vertical with the surface of upper strata fibre web 1, lower floor's fibre web 1 ' respectively;
(10) drying: after fibre web compound, carry out drying, drying mode is hot blast drying, temperature is 160 DEG C, criteria thus the drying time is 3min, drying makes the moisture of binder film 4, lower binder film 5 ' evaporate, and one end of upper fine hair 3 is cemented in the surface of upper strata fibre web 1, and one end of lower fine hair 3 ' is cemented in the surface of lower floor's fibre web 1 ';
(11) reel: after drying, winding, the obtained high-elastic antibacterial thermal insulating flaky material of gluing Multi-layer flocking formula.
embodiment 3
High-elastic antibacterial thermal insulating flaky material of bar shaped gluing flocking formula air lay and preparation method thereof:
See Fig. 1, Fig. 2, the high-elastic antibacterial thermal insulating flaky material of gluing Multi-layer flocking formula, comprise upper strata fibre web 1, upper binder film 4, in upper binder film 4 ', at the middle and upper levels fibre web 2, hot melt film 6, middle lower floor fibre web 2 ', in lower binder film 5, lower binder film 5 ', lower floor's fibre web 1 ', upper fine hair 3, lower fine hair 3 ', antiseptic 7,7
,, 8,8
,.Upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor fibre web 2 ', lower floor's fibre web 1 ' for fineness be 3D, length is the hollow polyester fibre of the three-dimensional crimp of 51mm and fineness is 3D, length is 51mm, fusing point is the low-melting fiber of 110 DEG C, shredding mixing is carried out, through the fibre web that short-fiber airlaid prepares according to weight ratio 80%:20%.The antiseptic 7 of the chitosan-containing of upper strata fibre web 1 internal spray good anti-bacterial effect, the at the middle and upper levels antiseptic 7 of the chitosan-containing of fibre web 2 internal spray good anti-bacterial effect
,, middle lower floor fibre web 2
,the antiseptic 8 of the chitosan-containing of internal spray good anti-bacterial effect
,, lower floor's fibre web 1
,the antiseptic 8 of the chitosan-containing of internal spray good anti-bacterial effect, upper strata fibre web 1 and at the middle and upper levels fibre web 2 surface are in opposite directions coated with respectively and are covered with binder film 4, in upper binder film 4 ', upper fine hair 3 is clipped in upper strata fibre web 1 and at the middle and upper levels between fibre web 2, the two ends of upper fine hair 3 are inserted in binder film 4 respectively, in among upper binder film 4 ', be cemented in the surface of upper strata fibre web 1 and the surface of fibre web 2 at the middle and upper levels, lower binder film 5 during middle lower floor fibre web 2 ' and lower floor's fibre web 1 ' surface in opposite directions apply respectively, lower binder film 5 ', lower fine hair 3 ' is clipped between middle lower floor fibre web 2 ' and lower floor's fibre web 1 ', lower binder film 5 during the two ends of lower fine hair 3 ' are inserted in into respectively, among lower binder film 5 ', be cemented in the surface of middle lower floor fibre web 2 ' and lower floor's fibre web 1 ', fine hair selects fineness to be 5D, length is the polyester staple fiber of 1.5mm.Fibre web 2 and middle lower floor fibre web 2 ' are consolidated by the EVA hot-melt adhesive nethike embrane that one deck melting temperature is 110 DEG C at the middle and upper levels, upper binder film 4, in upper binder film 4 ' size identical, shape is bar shaped, the position being coated in the surface of upper strata fibre web 1 and the surface of fibre web 2 is at the middle and upper levels corresponding, in lower binder film 5, lower binder film 5 ' size identical, shape is bar shaped, and the position being coated in the surface of middle lower floor fibre web 2 ' and the surface of lower floor's fibre web 1 ' is corresponding.The adhesive that adhesive is selected is high, water-fastness, the ageing-resistant polyacrylate static flocking adhesive of adhesion strength.
The manufacture method of the high-elastic antibacterial thermal insulating flaky material of gluing Multi-layer flocking formula, the method comprises the steps:
(1) fibre web preparation: the method adopting air lay, prepares upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor fibre web 2 ', lower floor's fibre web 1 ' respectively;
(2) antiseptic is sprayed: obtained upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor fibre web 2 ', lower floor's fibre web 1 ' feed flusher, antiseptic 7 are evenly sprayed onto upper strata fibre web 1, antiseptic 7
,evenly be sprayed onto fibre web 2 at the middle and upper levels, antiseptic 8
,evenly be sprayed onto middle lower floor fibre web 2 ', it is inner that antiseptic 8 is evenly sprayed onto lower floor's fibre web 1 ';
(3) drying: respectively to being sprayed with antiseptic 7,7
,, 8
,, the upper strata fibre web 1 of 8, at the middle and upper levels fibre web 2, middle lower floor fibre web 2 ', lower floor's fibre web 1 ' carry out drying, drying mode is hot blast drying, and temperature is 160 DEG C, and criteria thus the drying time is 3min;
(4) gluing: respectively at upper strata fibre web 1, fibre web 2 at the middle and upper levels, middle lower floor fibre web 2 ', application of adhesive in the one side of lower floor's fibre web 1 ', formation width is 1cm, thickness is 0.5mm, spacing distance is the upper binder film 4 of the strip along fabric width directional spreding of 1cm, in upper binder film 4 ', in lower binder film 5, lower binder film 5 ', upper binder film 4 with in the shape of upper binder film 4 ' and size identical, be coated in upper strata fibre web 1 corresponding with the position on the surface of fibre web 2 at the middle and upper levels, in lower binder film 5, shape and the size of lower binder film 5 ' are identical, be coated in middle lower floor fibre web 2 ', the position on the surface of lower floor's fibre web 1 ' is corresponding,
(5) electrostatic spinning: be coated with on the surface of adhesive at fibre web 2 and middle lower floor fibre web 2 ' at the middle and upper levels and carry out electrostatic spinning, use rated voltage is 50kV, output current is 5mA, the high voltage electric field of high voltage electric field anode-cathode distance 12cm, respectively upper fine hair 3, lower fine hair 3 ' are implanted in the surface of fibre web 2, middle lower floor fibre web 2 ' at the middle and upper levels, and make the surface of fine hair 3 and fibre web 2 at the middle and upper levels and lower fine hair 3 ' be in plumbness with the surface of middle lower floor fibre web 2 ';
(6) drying: drying is carried out to the fibre web at the middle and upper levels 2 and middle lower floor fibre web 2 ' that complete electrostatic spinning, drying mode is hot blast drying, temperature is 160 DEG C, criteria thus the drying time is 3min, during drying makes upper binder film 4 ' with in the moisture of lower binder film 5 evaporate, one end of upper fine hair 3 and lower fine hair 3 ' is cemented in the surface of fibre web 2, middle lower floor fibre web 2 ' at the middle and upper levels respectively;
(7) suede is inhaled: the fibre web at the middle and upper levels 2 crossed by drying and middle lower floor fibre web 2 ' carry out the process of suction suede, do not have the upper fine hair 3 on the position of application of adhesive, lower fine hair 3 ' on the surface and are not sopped up by the upper fine hair 3 of adhesive secure bond, lower fine hair 3 ' respectively by being scattered in fibre web 2 and middle lower floor fibre web 2 ' at the middle and upper levels;
(8) fibre web overlay film consolidation: do not have the one side of flocking to be superimposed with each other with middle lower floor fibre web 2 ' fibre web at the middle and upper levels 2 after inhaling suede process, and therebetween one deck hot melt film 6, to fibre web 2 and middle lower floor fibre web 2 ' be consolidated at the middle and upper levels through Overheating Treatment, hot pressing temperature is 160 DEG C, pressure size is 2.5bar, and hot pressing time is 10min;
(9) fibre web compound: be 50kV in rated voltage, output current is 5mA, under the high voltage electric field effect of high voltage electric field anode-cathode distance 12cm, upper strata fibre web 1 there is the one side of adhesive, be compounded on the flocked surface of fibre web 2 at the middle and upper levels, lower floor's fibre web 1 ' there is is the one side of adhesive, be compounded on the flocked surface of middle lower floor fibre web 2 '; Upper fine hair 3 and lower fine hair 3 ' are vertical with the surface of upper strata fibre web 1, lower floor's fibre web 1 ' respectively;
(10) drying: after fibre web compound, carry out drying, drying mode is hot blast drying, temperature is 160 DEG C, criteria thus the drying time is 3min, drying makes the moisture of binder film 4, lower binder film 5 ' evaporate, and one end of upper fine hair 3 is cemented in the surface of upper strata fibre web 1, and one end of lower fine hair 3 ' is cemented in the surface of lower floor's fibre web 1 ';
(11) reel: after drying, winding, the obtained high-elastic antibacterial thermal insulating flaky material of gluing Multi-layer flocking formula.
Claims (7)
1. the high-elastic antibacterial thermal insulating flaky material of gluing Multi-layer flocking formula, it is characterized in that: upper strata fibre web (1) inside is sprayed with antiseptic (7), fibre web (2) inside is sprayed with antiseptic (7 at the middle and upper levels
,), middle lower floor fibre web (2
,) inside is sprayed with antiseptic (8
,), lower floor's fibre web (1
,) inside be sprayed with antiseptic (8), upper strata fibre web (1) and fibre web (2) surface in opposite directions be at the middle and upper levels coated with respectively be covered with binder film (4), in upper binder film (4
,), upper fine hair (3) is clipped in upper strata fibre web (1) and at the middle and upper levels between fibre web (2), the two ends of upper fine hair (3) be inserted in respectively binder film (4), in upper binder film (4
,) among, be cemented in the surface of upper strata fibre web (1) and the surface of fibre web (2) at the middle and upper levels, middle lower floor fibre web (2
,) and lower floor's fibre web (1
,) surface in opposite directions lower binder film (5), lower binder film (5 in applying respectively
,), lower fine hair (3
,) be clipped in middle lower floor fibre web (2
,) and lower floor's fibre web (1
,) between, lower fine hair (3
,) two ends be inserted in respectively in lower binder film (5), lower binder film (5
,) among, be cemented in middle lower floor fibre web (2
,) and lower floor's fibre web (1
,) surface, fibre web (2) and middle lower floor fibre web (2 at the middle and upper levels
,) be consolidated by one deck hot melt film (6).
2. the high-elastic antibacterial thermal insulating flaky material of a kind of gluing Multi-layer flocking formula as claimed in claim 1, is characterized in that: described upper strata fibre web (1), at the middle and upper levels fibre web (2), middle lower floor fibre web (2
,), lower floor's fibre web (1
,) be the fibre web of short-fibred mechanical carding or air lay.
3. the high-elastic antibacterial thermal insulating flaky material of a kind of gluing Multi-layer flocking formula as claimed in claim 1, is characterized in that: described antiseptic (7) (7
,) (8) (8
,) be good anti-bacterial effect, laundry-resistant antiseptic.
4. the high-elastic antibacterial thermal insulating flaky material of a kind of gluing Multi-layer flocking formula as claimed in claim 1, is characterized in that: described upper binder film (4), in upper binder film (4
,), in lower binder film (5), lower binder film (5
,) adhesive selected is that adhesion strength is high, water-fastness, the adhesive of aging-resisting type.
5. the high-elastic antibacterial thermal insulating flaky material of a kind of gluing Multi-layer flocking formula as claimed in claim 1, is characterized in that: described upper binder film (4), in upper binder film (4
,), in lower binder film (5), lower binder film (5
,) shape be bar shaped or grid shape, size is identical.
6. the high-elastic antibacterial thermal insulating flaky material of a kind of gluing Multi-layer flocking formula as claimed in claim 1, is characterized in that: described upper fine hair (3), lower fine hair (3
,) material be polyester fiber or Fypro.
7. the manufacture method of the high-elastic antibacterial thermal insulating flaky material of a kind of gluing Multi-layer flocking formula according to any one of claim 1-6, is characterized in that: the method comprises the steps:
(1) fibre web preparation: prepare upper strata fibre web (1), at the middle and upper levels fibre web (2), middle lower floor fibre web (2 respectively
,), lower floor's fibre web (1
,);
(2) spray antiseptic: spray antiseptic (7) to upper strata fibre web (1) under a certain pressure, fibre web (2) sprays antiseptic (7 at the middle and upper levels
,), middle lower floor fibre web (2
,) spray antiseptic (8
,), lower floor's fibre web (1
,) spray antiseptic (8);
(3) drying: respectively to the upper strata fibre web (1) being sprayed with antiseptic (7), be sprayed with antiseptic (7
,) fibre web (2) at the middle and upper levels, be sprayed with antiseptic (8
,) middle lower floor fibre web (2
,), be sprayed with antiseptic (8) lower floor fibre web (1
,) carry out drying;
(4) gluing: respectively at upper strata fibre web (1), at the middle and upper levels fibre web (2), middle lower floor fibre web (2
,), lower floor's fibre web (1
,) one side on painting be covered with binder film (4), in upper binder film (4
,), in lower binder film (5), lower binder film (5
,);
(5) electrostatic spinning: at fibre web (2) and middle lower floor fibre web (2 at the middle and upper levels
,) be coated with adhesive surface on carry out electrostatic spinning, respectively by upper fine hair (3), lower fine hair (3
,) be implanted in fibre web (2), middle lower floor fibre web (2 at the middle and upper levels
,) surface;
(6) drying: to the fibre web at the middle and upper levels (2) and the middle lower floor fibre web (2 that complete electrostatic spinning
,) carry out drying;
(7) suede is inhaled: the fibre web at the middle and upper levels (2) crossed by drying and middle lower floor fibre web (2
,) carry out the process of suction suede;
(8) fibre web overlay film consolidation: by fibre web at the middle and upper levels (2) and the middle lower floor fibre web (2 inhaled after suede process
,) do not have the one side of flocking to be superimposed with each other, and therebetween one deck hot melt film (6), incite somebody to action fibre web (2) and middle lower floor fibre web (2 at the middle and upper levels through Overheating Treatment
,) be consolidated;
(9) fibre web compound: one side upper strata fibre web (1) being had upper binder film (4), is compounded on the flocked surface of fibre web (2) at the middle and upper levels, by lower floor's fibre web (1
,) there is lower binder film (5
,) one side, be compounded in middle lower floor fibre web (2
,) flocked surface on;
(10) drying: after fibre web compound, carries out drying;
(11) reel: after drying, winding, the obtained high-elastic antibacterial thermal insulating flaky material of gluing Multi-layer flocking formula.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108851296A (en) * | 2018-08-27 | 2018-11-23 | 江苏阳光股份有限公司 | A kind of production technology and shirt of shirt adhesive lining |
CN112971229A (en) * | 2021-02-06 | 2021-06-18 | 本宅久(杭州)服饰有限公司 | Antibacterial and antiallergic knitted sweater |
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CN201480065U (en) * | 2009-08-06 | 2010-05-26 | 桐乡市蒙成纺织有限公司 | Plush flocking fabric |
CN204071466U (en) * | 2014-08-29 | 2015-01-07 | 上海胤添电子商务有限公司 | A kind of compound warm blankets |
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2015
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CN2381484Y (en) * | 1999-05-26 | 2000-06-07 | 陈学清 | Thermal insulating composite flannelette |
CN2439447Y (en) * | 2000-07-21 | 2001-07-18 | 上海菲常保暖制品开发应用有限公司 | Bacteriostasis, high strength of extension and super warm keeping composite material |
GB2369294A (en) * | 2000-11-24 | 2002-05-29 | Milliken & Co | A carpet tile |
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CN108851296A (en) * | 2018-08-27 | 2018-11-23 | 江苏阳光股份有限公司 | A kind of production technology and shirt of shirt adhesive lining |
CN112971229A (en) * | 2021-02-06 | 2021-06-18 | 本宅久(杭州)服饰有限公司 | Antibacterial and antiallergic knitted sweater |
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