CN106544852A - A kind of multi-functional weaving material of far-infrared magnet therapeutic and the medicated cushion being made from it - Google Patents
A kind of multi-functional weaving material of far-infrared magnet therapeutic and the medicated cushion being made from it Download PDFInfo
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- CN106544852A CN106544852A CN201610910319.7A CN201610910319A CN106544852A CN 106544852 A CN106544852 A CN 106544852A CN 201610910319 A CN201610910319 A CN 201610910319A CN 106544852 A CN106544852 A CN 106544852A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic System; Titanates; Zirconates; Stannates; Plumbates
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47C—CHAIRS; SOFAS; BEDS
- A47C27/00—Spring, stuffed or fluid mattresses or cushions specially adapted for chairs, beds or sofas
- A47C27/12—Spring, stuffed or fluid mattresses or cushions specially adapted for chairs, beds or sofas with fibrous inlays, e.g. made of wool, of cotton
- A47C27/122—Spring, stuffed or fluid mattresses or cushions specially adapted for chairs, beds or sofas with fibrous inlays, e.g. made of wool, of cotton with special fibres, such as acrylic thread, coconut, horsehair
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47C—CHAIRS; SOFAS; BEDS
- A47C31/00—Details or accessories for chairs, beds, or the like, not provided for in other groups of this subclass, e.g. upholstery fasteners, mattress protectors, stretching devices for mattress nets
- A47C31/004—Means for protecting against undesired influence, e.g. magnetic radiation or static electricity
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic System; Aluminates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
Abstract
The invention provides a kind of multi-functional weaving material of far-infrared magnet therapeutic and the medicated cushion being made from it.The textile material includes fabric body, and the fabric body includes precoat and lining layer, also including at least one far IR fibre layer and at least one spacer fabric layer being arranged between precoat and lining layer.By made by the textile material, medicated cushion can promote blood circulation of human body.
Description
Technical field
The present invention relates to textile material, more particularly to a kind of multi-functional weaving material of far-infrared magnet therapeutic and it is made from it
Medicated cushion.
Background technology
Far-infrared fabric is that addition can absorb different wave length in the fiber process of fabric or in last handling process
Far infrared, Far-infrared Absorption agent that in turn can be radiation infrared and a kind of obtained functional fibre fabric.Far infrared is fine
The far infrared radiation of dimension not only has heat insulation effect, and the far infrared of radiation also has functions that blood circulation promoting, is to have concurrently
Insulation, the new chemical fibre raw material of health care.In the mid-term of the eighties in last century, Japanese You Ni contract cards company and Toray rate
Far-infrared functional fiber is developed first, subsequently the Supreme Being people of Japan, Asahi Chemical Industry, Zhong Fangdeng companies have also begun to take autumn and winter
The developmental research of fabric fibre.The beginning of the nineties in last century, numerous domestic colleges and universities, R＆D institution and enterprise also actively expand this side
The research work in face, and it is proposed far IR fibre and its product.
Infrared ray is the electromagnetic wave that wave-length coverage is 0.78 μm -1000 μm, and its medium wavelength is 2.5 μm -1000 μm and is referred to as
Far infrared.The mechanism of Heated by Far-Infrared Radiation is Spectral matching.Radiation wavelength i.e. when radiation source and the absorption by radiant matter
When wavelength is consistent, this is just absorbed infrared energy by radiating object, so as to aggravate its, the motion of molecule, reach heating up
Heat effect.As human body is an organism, its have to far-infrared absorption rate, conductivity is high the characteristics of.When by certain
The material for kind being capable of efficient absorption human infrared radiation is made and takes material, the material molecule human body can be absorbed in resonance with
The energy of the outside release of infra-red radiation, moreover it is possible to absorb the wavelength required for human body discharged by the sun and human peripheral's environment and exist
4 μm -14 μm of infrared energy, while these energy give people body with human body heat release identical frequency feedback, so as to reach body
Sense temperature rise effect, and by the activity-stimulat human tissue cell of ICW, by precipitation in the cell decrepit and behind the times discarded
Material is excreted, and strengthens metabolism, improves blood of human body microcirculation and body fluid microcirculation, keeps the health of human body cell,
Microcirculation disturbance is eliminated, health care, auxiliary treatment, the purpose of rehabilitation disease is reached.
CN1982533A discloses a kind of far-infrared ceramic fabric, will be the far-infrared finishing working solution containing ceramics uniform
Spray on the fabric with the ramee of cotton or pure biological degumming as raw material, which adopts spray to roll plant equipment with bath raio as 1：7
Spraying, by preliminary drying dehydration, bakes setting process, obtains far-infrared ceramic ramie cotton fabric.
CN103774458A discloses a kind of with far infrared functional fibre fabric, the weight of each component in its fiber for adopting
Amount proportioning includes：Germanic tourmaline powder 1～5%, other fibers 35～55%, cotton fiber 40～65%.
CN 103122490A disclose a kind of Far-infrared self heating warming fabric, during fibre spinning, will be quantitative
Tourmaline, silver ion, iron powder are uniformly implanted into fibrous inside and are organically combined with fiber and be spun into fabric.The electricity
Gas stone, silver ion, iron powder are nano-scale particle, and mass ratio is：Tourmaline：Silver ion：Iron powder=3：2：1, by tourmaline, silver
Ion, iron powder add fabric simultaneously, then fiber is inherently provided with the function of radiation far infrared spontaneous heating antibacterial, then
This fabric is penetrated and can play in vivo thermal effect.
CN103317781A discloses a kind of far IR fibre fabric, and the fabric is made up of top layer, intermediate layer and bottom, its
It is characterised by：The top layer is antimicrobial fabric layer, and the intermediate layer is synthetic fiber fabric layer, and the bottom is far infrared
The fabric side bed of material, the antimicrobial fabric layer are formed by bamboo carbon fiber and polyster fibre blending, the synthetic fiber fabric layer
For in terylene, chinlon, spandex one or more, the far-infrared fabric precoat is by Sargassum carbon fiber, cotton fiber and Semen sojae atricolor egg
White fiber blending is formed.
CN1285428A discloses far infrered fiber cotton, and which with the far infrared chopped fiber that can send 5-25 μm of far infrared is
Raw material, with spun-bonded filament non-woven fabric as skeleton；Using dry-lay techniques, needle point method mechanical consolidation is made.
CN1312411A discloses a kind of far-infrared fabric and its manufacture method altogether, and described fabric has a tissue layer, knits
The layer of polyurethane of one layer of oxide containing potassium, calcium, zirconium, ferrum or manganese and Maifanitum, the system of far-infrared fabric are coated with nitride layer
The method of making be by Maifanitum, calcium oxide or potassium oxide or its combination, and the one kind in the oxide of zirconium, ferrum, manganese or its combination
Brush or silk-screen on fabric after being mixed in proportion with polyurethane slurry, cold curing, 80-100 DEG C of drying are formed.
CN1108316A discloses a kind of polyster fibre, and far-infrared radiation ceramic powders are uniform-distribution with fiber cross-sectional
Silicon dioxide (SiO2), zirconium dioxide (ZrO2) and iron sesquioxide (Fe2O3), far-infrared radiation ceramic powders content is fibre
The 1-10% of dimension total amount, the composition of the far-infrared radiation ceramic powders also have copper oxide (CuO).
CN101037327A discloses a kind of nano far-infrared composite material and its application, adds in zirconium system far-infrared material
Enter nano material TiO2Made by nano combined far-infrared material, and constitute after mixing with nano nickel, rare earth, volcanic mud a kind of new
Material, the material (50 DEG C) in room temperature, 8-25M normal direction emissivity are 0.92, are 0.93 in 14-25M, and all-wave length integration is sent out
It is 0.91 to penetrate rate, with respect to the strong peak of far infrared transmission between 7.8-12M, 4.8-5.8M, absorbs peak match with animal and plant cellss.
" exploitation of far infrared polypropylene fiber and fabric ", Li Heyu, petrochemical technology and application, the 1st phase of volume 18,2000,
22-23 page, the far infrared polypropylene fiber of some specifications is have studied, have detected the far infrared transmissivity of multiple fiber, analyze which
Insulation and promotion blood of human body circulating function.
However, in the above prior art, far infrared transmissivity is relatively low at low temperature for the far infrared additive for using, and
Effectively far infrared wavelength is narrower, it is impossible to enough meet for example harsh outdoor activity environment of applied environment of high request to medicated cushion far infrared
The requirement of performance.This area need it is a kind of being capable of far infrared transmissivity is higher at low temperature and effective far infrared wavelength is wider spinning
Knit material, and the medicated cushion for needing slow pressure property, resilience, heat insulating ability and static electricity resistance good.
The content of the invention
To overcome drawbacks described above present in prior art and deficiency, on the basis of the present inventor previously applies, pass through
Further investigation and many experiments, in addition, in the present invention, it is contemplated that medicated cushion to compressibility, slow pressure property, resilience, heat insulating ability and
The requirement of static electricity resistance etc., there is provided technical scheme below.
In one aspect of the invention, there is provided a kind of multi-functional weaving material of far-infrared magnet therapeutic, the textile material include
Fabric body, the fabric body precoat (1) and lining layer (4), it is characterised in that the textile material also includes being arranged on
At least one far IR fibre layer (2,3) and at least one spacer fabric layer between precoat (1) and lining layer (4) is (not
Illustrate).
The spacer fabric layer is preferably warp-knitted spacer fabric layer.
The spacer fabric layer is preferably provided at the position near lining layer.
The a diameter of 0.10-0.20mm of paraphysis between the spacer fabric layer, preferred 0.15mm, the thickness of spacer fabric layer is
5-10mm, preferred 8mm.
The space fabric heat transfer and moisture conductance can be respectively 50 × 10-3W·(m·K)-1To 120 × 10-3W·
(m·K)-1With 40-60W (mK)-1, preferably 75.88 × 10-3W·(m·K)-1With 45.85W (mK)-1。
Research finds, when a paraphysis diameter, spacer fabric layer thickness, space fabric heat transfer and moisture conductance are in above range
Or during above-mentioned value, be the space fabric performance for being best suitable for medicated cushion.When space fabric is pressurized, the energy of required consumption is less than
Non-woven batts, and due to the special construction of space fabric make its exist it is non-knit the buffer stage not having, space fabric it is initial
Modulus is also relatively small, and this shows more more particularly suitable than non-batts of knitting as cushion class product using space fabric, in addition antistatic
Performance and heat-insulating property are also optimal.Using equilibrium area is just reached during sponge in force value very little, and between secant moduluss are far smaller than
Every fabric, this shows the ability very little of the holding capacity of sponge products, is easily deformed when pressurized, delays the ability very little of pressure, between not having
Strong every the enabling capabilities of fabric, space fabric is more suitable as cushion class product than sponge.
Preferably, the fiber in the far IR fibre layer is carried out arranging with far infrared additive later.
Additionally or alternatively, the fiber in the far IR fibre layer is added in spinning process and has far infrared to add
Agent.
Fiber in the far IR fibre layer can be polypropylene fiber or polyster fibre.
For the present invention, the far infrared additive bag ZrO containing nanometer2Powder body.
Nanometer ZrO2Powder body is particularly preferably obtained nanometer ZrO by the following method2Powder body：Take ZrOCl8H2O
The aqueous solution that concentration is 0.9-1.0mol/L is configured to, it is 0.01mol/L to be subsequently adding dispersant and make its concentration, in the same of stirring
When reaction system is warming up to into 50-75 DEG C, add ammonia maintain pH value of reaction system be 6-l0 (preferably 9), obtain be hydrated ZrO2
Gel, precipitate is still aging, then precipitation is washed with distilled water, till without chloride ion, in cleaning process
In, appropriate ammonia is added with the pH value of maintenance system as 6-l0, after being finally dehydrated with absolute ethanol washing precipitation, do at 80 DEG C
It is dry, then 600 DEG C, 700 DEG C, 800 DEG C, 900 DEG C and 1000 DEG C are warming up to 10-15 DEG C/min programming rates, at a temperature of each
20-40min, preferred 30min are maintained, nano zirconium oxide powder is obtained.The mean diameter of the nano zirconium oxide powder is preferably
1-15nm, preferably 2-10nm, more preferably 3nm.The crystalline phase of the nano zirconium oxide powder can be, for example, monoclinic phase, Tetragonal
Or its mixture, preferred monoclinic phase.
In the coprecipitation method, zirconic pattern such as particle size has than larger shadow to its far infrared performance
Ring.Affect the factor of powder granule pattern a lot, the concentration of such as solution, temperature, pH value, settling velocity etc. are all given birth to zirconium oxide
Into size and stability have directly impact, still no clear and definite rule can be followed at present, be substantially and adjusted by experience
Section.Under the above-mentioned optimal conditions of the present invention, in reaction nucleation process, after dispersant enters solution, formed in system a lot
Diameter is about 0.5-1.5 μm of small solution pool, and after adding ammonia, ammonia can enter small solution pool by dispersant
In, therefore the growth of the generated precipitation that reacts in each solution pool is restricted, the particle of generation is very fine, when heavy
After starch grain is formed, dispersant adsorbs again on established granular precursor surface, forms one layer of molecular film and hinders between granule
Contact with each other the secondary agglomeration of generation, while preventing water and suction instep of other ions on colloid, occurs these micelle particles
The trend of agglomeration alkali significantly is weak, so as to maintain high nano zirconium oxide powder dispersibility and stability.
By above-mentioned analysis, dispersant is for can the size and ammonia of solution pool be efficiently entering solution pool
It is very crucial, and then influence whether nano zirconium oxide powder granular size, pattern, dispersibility and stability.For this purpose, special at one
In other preferred embodiment, the present invention selects lower formula (I) from thousands of dispersants through numerous studies and experiment
Shown dispersant：
Wherein R is methyl；Integers of the n for 1-3；X is 2-5, preferably 3；Y is 5-15, preferably 10；Z is 5-10, preferably 8；Z-
For SO3 -Or PO3 2-, M+For alkali metal cation or NH4 +。
Formula (I) compound for example can be purchased from Sigma companies with commercially available.
The dispersant is particularly suitable for the preparation of the nano zirconium oxide powder of polymolecularity and stability.Using the dispersion
During agent, a diameter of control of solution pool is particularly conducive to the entrance of ammonia in 0.90-0.95 μ ms, can control to obtain
Good nano zirconium oxide powder granule-morphology, makes obtained nano zirconium oxide powder particle size distribution highly uniform, while
Can stop that other impurity enter solution pool again.
In a further preferred embodiment, the dispersant used in the inventive method is the dispersion shown in lower formula (II)
Agent：
The dispersant is obtained by following steps：Take raw material 2,2- bis- (4- dodecyloxy phenyl)-propane 5.7g
(0.01mol) it is put in there-necked flask, is dissolved with chloroform (such as 30mL), then ice bath certain hour (such as 15min),
Dropwise it is slowly added to chlorosulfonic acid to be dissolved in the solution of chloroform (for example 1.3mL chlorosulfonic acids are dissolved in 10mL chloroforms), control reaction temperature
Spend for 20-40 DEG C, preferably 30 DEG C, stir 1-3h, preferred 2h, during the course of the reaction will be anti-with the NaOH aqueous solutions of 5.0 weight %
The HCl ingredient draws produced in answering, under room temperature, sulfonated products are neutralized with the triethanolamine ethanol solution of 30 weight %,
Liquid is filtered, and filtrate is spin-dried for Rotary Evaporators, obtains buff thick solid, then with activated carbon decolorizing, with petroleum ether-second
Acetoacetic ester mixed solution removes non polar impurities, then with anhydrous alcohol solution and rotates removing alcohol solvent, you can this point is obtained
Powder.
The use of the dispersant can make a diameter of control of solution pool in 0.90-0.92 μm of narrower scope, make to be obtained
Nano zirconium oxide powder particle size distribution it is highly uniform, in very good monodisperse status, under good stability and low temperature
Emissivity is high.
In a preferred embodiment, nanometer ZrO2Powder body is nanometer ZrO of oxidized stabillzed with yttrium2Powder body.
In a preferred embodiment, nanometer ZrO2Powder body is doped with other inorganic oxides.The inorganic oxygen
Compound can be, for example, SiO2、CaO、TiO2、Al2O3In one or more.The doping of the inorganic oxide by
ZrOCl·8H2Add the corresponding precursor salt of doping to carry out in the aqueous solution of O.For example, SiO2Precursor salt can be
Tetraethyl orthosilicate, TiO2Precursor salt can be butyl titanate, Al2O3Precursor salt can be boehmite or chlorination
Aluminum.
It is further preferred that obtained nanometer ZrO doped with other inorganic oxides2Powder body is consisted of：ZrO2
95.0w%, TiO21.5w%, SiO20.5w%, Al2O31.5w%, MgO 0.5w%, Y2O31.0w%.This nanometer of ZrO2
Powder granule has wider far infrared transmissivity, in the range of such as 8-20 μm has higher far infrared transmission ability.
In an especially preferred embodiment, textile material of the invention has two far IR fibre layers, i.e., and the
One far IR fibre layer (2) and the second far IR fibre layer (3), the close precoat (1) of the first far IR fibre layer (2), second
Far IR fibre layer (3) is near lining layer (4).
It is highly preferred that the far infrared additive used by the first far IR fibre layer (2) is fine with second far infrared
Far infrared additive used by dimension layer (3) is different.Far infrared additive for example used by the first far IR fibre layer (2) is composition
For ZrO295.0w%, TiO21.5w%, SiO20.5w%, Al2O31.5w%, MgO 0.5w%, Y2O31.0w%'s receives
Rice ZrO2Powder body, and the far infrared additive used by the second far IR fibre layer (3) is to consist of ZrO295.5w%, TiO2
1.0w%, SiO20.5w%, Al2O31.5w%, CaO 0.5w%, Y2O3Nanometer ZrO of 1.0w%2Powder body.Vice versa.
Additionally or alternatively, it is remote red used by one of the first far IR fibre layer (2) and the second far IR fibre layer (3)
External additive is preferably nanometer ZrO of the present invention2Powder body, and while the far infrared additive used by another is preferably stone
Black alkene.The unique structure of Graphene imparts the excellent electricity of Graphene, optics, mechanically and thermally learns performance.Graphite can be adopted
Alkene/resin solution is processed to fabric, to improve its heat transfer property, can such as increase substantially the heat conductivity of fabric.
The fibrous layer of Graphene process can effective launch wavelength 9-11 μm far infrared radiation, which is easy to by human body skin institute
Absorb, there is protrusion at warming aspect.And aforementioned use nanometer ZrO of the invention2Powder body is used as far infrared additive
Infrared fibre layer can launch wavelength be effectively 10-16 μm of far infrared radiation, and its frequency is consolidated with human body organo-functional group peptide chain
There is frequency of vibration consistent, therefore the resonance of human body cell can be caused and cause heating effect, promote blood of human body circulation.This
The far infrared transmission wavelength of two kinds of fibrous layers can realize effectively linking, and this particular combination can realize warming and health care simultaneously
Function.
It is further preferred that the fiber type of the first far IR fibre layer (2) and the second far IR fibre layer
(3) fiber type is different.First far IR fibre layer (2) can be polypropylene, and the second far IR fibre layer (3) can be terylene
Or nylon etc..
In fiber or fabric are processed, can be by far infrared additive and fiber base material by a certain percentage (such as 1:50) mix
Close uniform, far infrared synthetic fibers have been prepared Jing after melting, spinning.The fiber Jing weavings are obtained fabric.Or, with including
The suspension of far infrared additive is contaminated or dip-coating fabric.
In another aspect of this invention, there is provided a kind of to use medicated cushion made by above-mentioned textile material.Certainly, this area skill
Art personnel are it can be appreciated that the products such as glove, protector, sheet, pillowcase, vest, footwear, cap can be made by the fabric.
In the present invention, at least achieve one or more in following significant technique effect：(1) by nanometer
ZrO2In the preparation of powder body, specific selection or the dispersant for synthesizing, obtained nanometer ZrO have been used2Powder granule uniform particle sizes,
Stability is high, at low temperature with higher emissivity；(2) by the modifying inorganic oxide of adulterate particular types and ratio,
Nanometer ZrO2Far infrared transmission wave-length coverage substantially broaden, can be effectively realized in 8-20 μ ms far infrared send out
Penetrate；(3) by using two far IR fibre layers, using the different characteristics of two far IR fibre layers, realize specific of performance
With and it is complementary.
Description of the drawings
Accompanying drawing described herein is for helping to understand the present invention, to constitute the part of the application, but do not constitute it is right
The improper restriction of the present invention, in the accompanying drawings：
Fig. 1 is the cross section structure schematic diagram of the fabric for including two far IR fibre layers of the invention；
Wherein：1 is precoat；2 is the first far IR fibre layer, and 3 is the second far IR fibre layer, and 4 is lining layer.
Specific embodiment
With reference to following examples and comparative example, the present invention is described in further detail, but the embodiment party of the present invention
Formula not limited to this.
Embodiment 1
Far-infrared magnet therapeutic multifunctional textile cloth, the weaving cloth include fabric body, the fabric body precoat (1) and
Lining layer (4), and far IR fibre layer (2), and spacer fabric layer (not shown), spacer fabric layer is closest to lining layer (4)；
The far IR fibre layer is prepared with above-mentioned coprecipitation, and its preparation method includes：Take ZrOCl8H2O is configured to concentration
The aqueous solution of 0.9mol/L, is subsequently adding the dispersant of 0.01mol/L, and reaction system is warming up to 60 DEG C while stirring,
It is 9 to add ammonia to maintain pH value of reaction system, obtains being hydrated ZrO2Gel, precipitate is still aging, then with distilled water pair
Precipitation is washed, till without chloride ion.In cleaning process, appropriate ammonia is added with the pH value of maintenance system as 8.Most
Afterwards with absolute ethanol washing precipitation dehydration after, at 80 DEG C be dried, then with 10 DEG C/min programming rates be warming up to 600 DEG C, 700
DEG C, 800 DEG C, 900 DEG C and 1000 DEG C, 30min is maintained at a temperature of each, nano zirconium oxide powder is obtained.It is described nano oxidized
The mean diameter of zirconium powder body is 3nm, and the dispersant is compound above shown in formula (II).By the nano zirconium oxide powder
1 is pressed with polypropylene fiber base material:50 mix homogeneously, have prepared far infrared synthetic fibers Jing after melting, spinning.The fiber Jing spins
Knit prepared textile material.Between the spacer fabric layer, paraphysis diameter is preferably 0.15mm, and the thickness of spacer fabric layer is 8mm,
Heat transfer and moisture conductance can be respectively 75.88 × 10-3W·(m·K)-1With 45.85W (mK)-1。
Normal emittance detection is carried out according to far infrared textile material touchstone Fz/T 64010-2000.After testing,
The normal emittance of the textile material is 92%, and the standard than specifying is higher by 12%.
Embodiment 2
In this embodiment, increase by a second far IR fibre layer near lining on the basis of embodiment 1, remaining
It is identical with the textile material structure of embodiment 1.The far infrared additive of the second far IR fibre layer is Graphene, wherein adopting
Graphene/polyurethane solutions are processed to fabric.
Normal emittance detection is carried out according to far infrared textile material touchstone Fz/T 64010-2000.After testing,
The normal emittance of the textile material is 95%, and the standard than specifying is higher by 15%.
Comparative example 1
The textile material of the comparative example is differed only in nano zirconium oxide powder preparation with the textile material of embodiment 1
The conventional dispersant PEG for using.
Normal emittance detection is carried out according to far infrared textile material touchstone Fz/T 64010-2000.After testing,
The normal emittance of the textile material is 88%.
Clearly can be seen that using dispersant of the invention and using two by above-described embodiment and comparative example
The textile material of complementary far IR fibre layer, with significantly higher far infrared transmissivity, such that it is able to more effectively promote
Warming and health-care effect.
In addition, Jing tests, the medicated cushion by made by textile material of the invention is suitable as padding class material, is sponge
Optimal substitute products, can be good at solving those as a variety of causes wants sitting or lies, for example baby, both legs disabled patient,
Decubital ulcer and Other diseases that the crowds such as old man produce therefrom, the actual production to cushion class product have very high directive significance.
This written description discloses the present invention using example, including optimal mode, and also enables those skilled in the art
Manufacture and using the present invention.The present invention can patentable scope be defined by the claims, and this area skill can be included
Other examples that art personnel expect.If this other examples have the structural elements of literal language not different from claims
Element, or if this other examples include equivalent structure element of the literal language without substantial differences with claims,
Then this other examples are intended within the scope of claims.In the case where inconsistent degree is not resulted in, by reference to
To be incorporated herein in place of all references of reference herein.
Claims (10)
1. the multi-functional weaving material of a kind of far-infrared magnet therapeutic, the textile material include fabric body, the fabric body fabric
Layer (1) and lining layer (4), it is characterised in that the textile material also includes being arranged between precoat (1) and lining layer (4)
At least one far IR fibre layer (2,3) and at least one spacer fabric layer.
2. textile material according to claim 1, it is characterised in that the fiber far infrared in the far IR fibre layer
Additive carries out arranging later.
3. textile material according to claim 1, it is characterised in that the fiber in the far IR fibre layer is in spinning
Adding in journey has far infrared additive.
4. the textile material according to Claims 2 or 3, it is characterised in that the spacer fabric layer is warp-knitted spacer fabric
Layer.
5. the textile material according to any one of claim 2-4, it is characterised in that the far infrared additive bag is containing receiving
Rice ZrO2Powder body.
6. textile material according to claim 5, it is characterised in that nanometer ZrO2Powder body is oxidized stabillzed with yttrium
Nanometer ZrO2Powder body.
7. according to textile material in any one of the preceding claims wherein, it is characterised in that the textile material is remote with two
Infrared fibre layer, i.e. the first far IR fibre layer (2) and the second far IR fibre layer (3), the first far IR fibre layer (2) are close
Precoat (1), the second far IR fibre layer (3) is near lining layer (4).
8. textile material according to claim 7, it is characterised in that remote used by the first far IR fibre layer (2)
Infrared additive is different from the far infrared additive used by the second far IR fibre layer (3).
9. textile material according to claim 8, it is characterised in that the fiber-like of the first far IR fibre layer (2)
Type is different from the fiber type of the second far IR fibre layer (3).
10. using the medicated cushion according to made by textile material in any one of the preceding claims wherein.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610910319.7A CN106544852B (en) | 2016-10-19 | 2016-10-19 | A kind of cushion far-infrared magnet therapeutic multi-functional weaving material and be made from it |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610910319.7A CN106544852B (en) | 2016-10-19 | 2016-10-19 | A kind of cushion far-infrared magnet therapeutic multi-functional weaving material and be made from it |
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| Publication Number | Publication Date |
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| CN106544852A true CN106544852A (en) | 2017-03-29 |
| CN106544852B CN106544852B (en) | 2019-05-17 |
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| CN201610910319.7A Active CN106544852B (en) | 2016-10-19 | 2016-10-19 | A kind of cushion far-infrared magnet therapeutic multi-functional weaving material and be made from it |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108642887A (en) * | 2018-04-20 | 2018-10-12 | 宿迁南航新材料与装备制造研究院有限公司 | A kind of wearable health-care material |
| TWI702927B (en) * | 2019-06-20 | 2020-09-01 | 明達精密有限公司 | Anti-mattress and washable mattress |
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| CN201709408U (en) * | 2009-07-23 | 2011-01-19 | 中山市康益保健用品有限公司 | Novel far infrared fabric |
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Also Published As
| Publication number | Publication date |
|---|---|
| CN106544852B (en) | 2019-05-17 |
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