CN108640717A - Nixing pottery inlays the manufacture craft of silverware ware - Google Patents

Nixing pottery inlays the manufacture craft of silverware ware Download PDF

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Publication number
CN108640717A
CN108640717A CN201810525279.3A CN201810525279A CN108640717A CN 108640717 A CN108640717 A CN 108640717A CN 201810525279 A CN201810525279 A CN 201810525279A CN 108640717 A CN108640717 A CN 108640717A
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CN
China
Prior art keywords
nixing pottery
silver powder
cooling
manufacture craft
fired
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810525279.3A
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Chinese (zh)
Inventor
钟恒成
李秀明
王宁
闭宗庭
陶艳华
罗志胜
吴尚玉
陈玉星
刘展鹏
刘鹏飞
何艳梅
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Qinzhou University
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Qinzhou University
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Publication date
Application filed by Qinzhou University filed Critical Qinzhou University
Priority to CN201810525279.3A priority Critical patent/CN108640717A/en
Publication of CN108640717A publication Critical patent/CN108640717A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • C04B41/90Coating or impregnation for obtaining at least two superposed coatings having different compositions at least one coating being a metal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/001Applying decorations on shaped articles, e.g. by painting
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Powder Metallurgy (AREA)

Abstract

The present invention provides the manufacture crafts that Nixing pottery inlays silverware ware, include the following steps:1) Nixing pottery billet surface is carved out into pattern, then dried;2) last layer silver powder is uniformly spread in the pattern area of dry base substrate, 1~2h is fired at 900~950 DEG C, it is cooling;3) one layer of Nixing pottery blank is uniformly smeared on silver powder, and 1~3h is fired at 980~1000 DEG C, it is cooling;4) fill up pattern area with silver powder, fire 6~8h at 1150~1200 DEG C, it is cooling to get.The wellability of Nixing pottery and metallic silver can be greatly improved in the present invention, and good connecting effect is not easily to fall off.

Description

Nixing pottery inlays the manufacture craft of silverware ware
Technical field
The present invention relates to the manufacture crafts of Nixing pottery, and in particular to Nixing pottery inlays the manufacture craft of silverware ware.
Background technology
The technique of Nixing pottery includes mainly following steps:1) blank is prepared:Blank, which is selected, crosses admiring for Qiezhou urban district The soil of Jiang Yidong, being commonly called as eastern mud, (for mild-clay, color is yellow-white, contains micro quartz sand, in the production technology of Nixing pottery In serve adjustment plasticity with associativity), and by the emperor himself to the west of river region soil, be commonly called as western mud (containing a small amount of K2O、NaO、 CaO、MgO、Fe203、TiO2、MnO2, it is a kind of higher purple mudstone of iron-holder, color is aubergine, and superficial layer has a small amount of irony Dip dyeing is hard paste, and plasticity and associativity are poor), the weight percent by eastern mud 40~60%, western mud 40~60% is mixed It closes, blank is made in the series of process such as ground, dehydration;The moisture content of blank is 20~25%;2) blank forming:Using plastic The green body of various types is made in blank by method or slip casting method;3) green body is modified:Green body is modified to reach design requirement;4) it does It is dry:Green body is dried using aeration drying, green body moisture is made to exclude;5) drawing engraving:It picture and is carried out in green body writing of submitting a written statement to a higher authority Engraving;6):Body drying;7) green body is fired:Dry green body loading of kiln to be fired, firing temperature is controlled at 1100~1200 DEG C, Firing time is 10h, kiln discharge after cooling;8) polishing grinding:By green body polishing polish to get.Silver is inlayed on Nixing pottery green body, Since silver is poor with the wellability of Nixing pottery, extremely it is easy to fall off.
Invention content
Technical problem to be solved by the invention is to provide the manufacture craft that Nixing pottery inlays silverware ware, which can greatly carry The wellability of high Nixing pottery and silver powder, good connecting effect are not easily to fall off.
In order to solve the above technical problems, the technical solution adopted by the present invention is the manufacture craft of Nixing pottery edge silverware ware, packet Include following steps:
1) Nixing pottery billet surface is carved out into pattern, then dried;
2) last layer silver powder is uniformly spread in the pattern area of dry base substrate, 1~2h is fired at 900~950 DEG C, it is cooling;
3) one layer of Nixing pottery blank is uniformly smeared on silver powder, and 1~3h is fired at 980~1000 DEG C, it is cooling;
4) fill up pattern area with silver powder, fire 6~8h at 1150~1200 DEG C, it is cooling to get.
In step 2), silver-colored melting temperature is 960 DEG C, melting temperature of the control firing temperature less than silver, it is ensured that few The silver powder of amount will not form liquid phase, avoid silver powder diffusional resistance too small, lead to metal grain fast growth, it is ensured that silver powder crystal grain Tinyization, and Nixing pottery green body is combined closely.The thickness of silver powder is 0.1~0.15mm.
In step 3), firing temperature is 980~1000 DEG C, is higher than the melting temperature of silver powder, but less than the burning of Nixing pottery At temperature, the Al in Nixing pottery blank2O3、Fe2O3The spontaneous solid solution for being diffused into silver powder phase and carrying out certain depth with silver powder, simultaneously Al2O3、Fe2O3It reacts with Ag and generates AgO and combined with silver powder surface, to realize the tight of Nixing pottery and silver powder two-phase interface Close combination.The moisture content of Nixing pottery blank is 20~25%.The thickness of Nixing pottery blank is 0.1~0.15mm.
In step 4), since Nixing pottery green body outer layer has been sequentially filled silver powder layer, Nixing pottery blank material layer and silver powder layer, occupy Silver powder particles growth can be limited in sintering procedure in intermediate Nixing pottery blank material layer so that silver powder crystal grain is tiny, more easily Indenting shape is formed with Nixing pottery layer, to improve the bond strength of silver powder and Nixing pottery.
In step 4), the flyash of its weight 0.1~0.5% is mixed in silver powder.The addition of flyash is in cooled and solidified In the process, silver powder crystal grain refinement, dendritic growth can be made to get muddled, preferably form dog with flyash and Nixing pottery The staggered solid solution of tooth increases the bond strength of silver powder and Nixing pottery.The addition of flyash can also alleviate silver powder and be expanded with Nixing pottery The difference of coefficient prevents falling off for silverware.
Compared with prior art, the wellability of Nixing pottery and metallic silver can be greatly improved in the present invention, and good connecting effect is not easy It falls off.
Specific implementation mode
The essentiality content further illustrated the present invention below with embodiment, but the present invention is not limited with this.
Embodiment 1
1) 100 Nixing pottery green bodies are taken, its surface engraving is gone out into identical patterns, is then dried;
2) silver powder that a layer thickness is 0.1mm is uniformly sprinkled in the pattern area of dry base substrate, 1h is fired at 900 DEG C, it is cold But;
3) the Nixing pottery blank that a layer thickness is 0.1mm is uniformly smeared on silver powder, and 1h is fired at 980 DEG C, it is cooling;Mud The moisture content of emerging greenwave material is 20%;
4) fill up pattern area with silver powder, fire 6h at 1150 DEG C, it is cooling to get.
Through statistics, fall off 5, intact 95.
Embodiment 2
1) the Nixing pottery green body for taking 100 shape sizes same as Example 1 goes out its surface engraving and 1 phase of embodiment Same pattern, is then dried;
2) silver powder that a layer thickness is 0.15mm is uniformly sprinkled in the pattern area of dry base substrate, 2h is fired at 950 DEG C, it is cold But;
3) the Nixing pottery blank that a layer thickness is 0.15mm is uniformly smeared on silver powder, and 3h is fired at 1000 DEG C, it is cooling; The moisture content of Nixing pottery blank is 25%;
4) flyash of its weight 0.5% is mixed in silver powder, mixing fills up pattern area, 8h is fired at 1200 DEG C, cold But to get.
Through statistics, fall off 1, intact 99.
Embodiment 3
1) the Nixing pottery green body for taking 100 shape sizes same as Example 1 goes out its surface engraving and 1 phase of embodiment Same pattern, is then dried;
2) silver powder that a layer thickness is 0.1mm is uniformly sprinkled in the pattern area of dry base substrate, 1.5h is fired at 920 DEG C, It is cooling;
3) the Nixing pottery blank that a layer thickness is 0.1mm is uniformly smeared on silver powder, and 2h is fired at 990 DEG C, it is cooling;Mud The moisture content of emerging greenwave material is 24%;
4) flyash of its weight 0.1% is mixed in silver powder, mixing fills up pattern area, 7h is fired at 1180 DEG C, cold But to get.
Through statistics, fall off 1, intact 99.
Embodiment 4
1) the Nixing pottery green body for taking 100 shape sizes same as Example 1 goes out its surface engraving and 1 phase of embodiment Same pattern, is then dried;
2) silver powder that a layer thickness is 0.1mm is uniformly sprinkled in the pattern area of dry base substrate, 1h is fired at 950 DEG C, it is cold But;
3) the Nixing pottery blank that a layer thickness is 0.15mm is uniformly smeared on silver powder, and 3h is fired at 980 DEG C, it is cooling; The moisture content of Nixing pottery blank is 20%;
4) flyash of its weight 0.5% is mixed in silver powder, mixing fills up pattern area, 8h is fired at 1150 DEG C, cold But to get.
Through statistics, fall off 0, intact 100.

Claims (5)

1. Nixing pottery inlays the manufacture craft of silverware ware, it is characterised in that:Include the following steps:
1) Nixing pottery billet surface is carved out into pattern, then dried;
2) last layer silver powder is uniformly spread in the pattern area of dry base substrate, 1~2h is fired at 900~950 DEG C, it is cooling;
3) one layer of Nixing pottery blank is uniformly smeared on silver powder, and 1~3h is fired at 980~1000 DEG C, it is cooling;
4) fill up pattern area with silver powder, fire 6~8h at 1150~1200 DEG C, it is cooling to get.
2. the manufacture craft of Nixing pottery edge silverware ware according to claim 1, it is characterised in that:In step 3), Nixing pottery The moisture content of blank is 20~25%.
3. the manufacture craft of Nixing pottery edge silverware ware according to claim 1, it is characterised in that:In step 2), silver powder Thickness is 0.1~0.15mm.
4. the manufacture craft of Nixing pottery edge silverware ware according to claim 1, it is characterised in that:In step 3), Nixing pottery The thickness of blank is 0.1~0.15mm.
5. the manufacture craft of Nixing pottery edge silverware ware according to claim 1, it is characterised in that:In step 4), in silver powder The middle flyash for mixing its weight 0.1~0.5%.
CN201810525279.3A 2018-05-28 2018-05-28 Nixing pottery inlays the manufacture craft of silverware ware Pending CN108640717A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810525279.3A CN108640717A (en) 2018-05-28 2018-05-28 Nixing pottery inlays the manufacture craft of silverware ware

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Application Number Priority Date Filing Date Title
CN201810525279.3A CN108640717A (en) 2018-05-28 2018-05-28 Nixing pottery inlays the manufacture craft of silverware ware

Publications (1)

Publication Number Publication Date
CN108640717A true CN108640717A (en) 2018-10-12

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001309808A (en) * 2000-04-28 2001-11-06 Aida Kagaku Kogyo Kk Decorating method of silver sintered body
CN1338392A (en) * 2000-08-16 2002-03-06 薛发伟 Simple method for wrapping pottery artwork with copper layer
CN1429714A (en) * 2001-12-30 2003-07-16 毛志毅 Metal pattern decorative ceramic product and its mannfacturing method
CN104446592A (en) * 2014-12-04 2015-03-25 河北工业大学 Large-area connection method of ceramic and ceramic or ceramic and metal
CN106431353A (en) * 2016-09-23 2017-02-22 钦州学院 Process for decorating nixing pottery with metal

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001309808A (en) * 2000-04-28 2001-11-06 Aida Kagaku Kogyo Kk Decorating method of silver sintered body
CN1338392A (en) * 2000-08-16 2002-03-06 薛发伟 Simple method for wrapping pottery artwork with copper layer
CN1429714A (en) * 2001-12-30 2003-07-16 毛志毅 Metal pattern decorative ceramic product and its mannfacturing method
CN104446592A (en) * 2014-12-04 2015-03-25 河北工业大学 Large-area connection method of ceramic and ceramic or ceramic and metal
CN106431353A (en) * 2016-09-23 2017-02-22 钦州学院 Process for decorating nixing pottery with metal

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
肖杰等: "陶瓷与金属的连接方法", 《硅酸盐通报》 *

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Application publication date: 20181012