CN108640620B - Ceramic tile glue and preparation method thereof - Google Patents
Ceramic tile glue and preparation method thereof Download PDFInfo
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- CN108640620B CN108640620B CN201810875851.9A CN201810875851A CN108640620B CN 108640620 B CN108640620 B CN 108640620B CN 201810875851 A CN201810875851 A CN 201810875851A CN 108640620 B CN108640620 B CN 108640620B
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- 239000000919 ceramic Substances 0.000 title claims abstract description 90
- 239000003292 glue Substances 0.000 title claims abstract description 75
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 62
- 239000000853 adhesive Substances 0.000 claims abstract description 50
- 230000001070 adhesive effect Effects 0.000 claims abstract description 50
- 239000004568 cement Substances 0.000 claims abstract description 41
- 239000011148 porous material Substances 0.000 claims abstract description 34
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims description 36
- 239000002699 waste material Substances 0.000 claims description 29
- 239000011398 Portland cement Substances 0.000 claims description 19
- 229920000642 polymer Polymers 0.000 claims description 19
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 17
- 238000009413 insulation Methods 0.000 claims description 17
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 17
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 15
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 15
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 15
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 15
- 239000004816 latex Substances 0.000 claims description 15
- 229920000126 latex Polymers 0.000 claims description 15
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 14
- 239000002562 thickening agent Substances 0.000 claims description 13
- 229920002554 vinyl polymer Polymers 0.000 claims description 12
- 239000011230 binding agent Substances 0.000 claims description 11
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 11
- 238000005192 partition Methods 0.000 claims description 10
- 239000002174 Styrene-butadiene Substances 0.000 claims description 7
- 150000004645 aluminates Chemical class 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 239000011115 styrene butadiene Substances 0.000 claims description 7
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 claims description 5
- 229920003086 cellulose ether Polymers 0.000 claims description 5
- 229920001353 Dextrin Polymers 0.000 claims description 4
- 239000004375 Dextrin Substances 0.000 claims description 4
- 229920002472 Starch Polymers 0.000 claims description 4
- 235000019425 dextrin Nutrition 0.000 claims description 4
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical group C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 claims description 4
- 229920000609 methyl cellulose Polymers 0.000 claims description 4
- 239000001923 methylcellulose Substances 0.000 claims description 4
- 235000010981 methylcellulose Nutrition 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- HXHCOXPZCUFAJI-UHFFFAOYSA-N prop-2-enoic acid;styrene Chemical compound OC(=O)C=C.C=CC1=CC=CC=C1 HXHCOXPZCUFAJI-UHFFFAOYSA-N 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 3
- 239000004576 sand Substances 0.000 abstract description 14
- 239000002245 particle Substances 0.000 abstract description 11
- 239000011159 matrix material Substances 0.000 abstract description 4
- 239000004566 building material Substances 0.000 abstract description 2
- 238000007873 sieving Methods 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 26
- 239000011435 rock Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000010276 construction Methods 0.000 description 4
- 239000004570 mortar (masonry) Substances 0.000 description 4
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000011083 cement mortar Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000006101 laboratory sample Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000005335 volcanic glass Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/06—Aluminous cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00637—Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Finishing Walls (AREA)
Abstract
The invention relates to the technical field of building materials, and particularly provides a tile glue and a preparation method thereof. The invention provides a ceramic tile adhesive, which comprises 30-40 parts of cement, 55-65 parts of inorganic porous material powder sieved by a-30-mesh sieve and 0.05-4 parts of optional auxiliary agent. The inorganic porous material powder is used for replacing the traditional sand, so that the using amount of the sand is reduced, and meanwhile, the porous structure has a larger specific surface area, so that the density of the tile glue is reduced, and the bearing capacity of a matrix is further reduced. The particle size of the inorganic porous material powder is limited to be less than 500 mu m (sieving by a minus 30-mesh sieve), so that the uniformity of the components of the ceramic tile glue can be ensured, and the advantages of the inorganic porous material powder are not lost.
Description
Technical Field
The invention relates to the technical field of building materials, in particular to a tile glue and a preparation method thereof.
Background
With the progress of society, related industries of ceramic tiles are rapidly developed, and the types and application scenes of the ceramic tiles are more and more. On one hand, cement mortar is mostly adopted in the traditional tile pasting method, namely, the sand and the cement are mixed on site to prepare simple cement mortar. The mortar is applied to the back of the pre-impregnated or pre-wetted tile, the mortar-coated tile is pressed onto the pre-wetted surface, and the tile is tapped to ensure that the tile has a consistent flatness. The mortar has the disadvantages of easy saltpetering, thick coating, weak binding power, poor durability, easy stripping and large using amount of construction materials. On the other hand, tiles with low water absorption and larger sizes become the mainstream choice for building construction, and cement paste cannot permeate into the back of the tiles due to the compact and smooth back of the tiles, so that the problem of falling off is easy to occur, and the tiles need to be mechanically fixed or reinforced. The existing ceramic tile glue can meet the quality requirement only by continuous improvement. The current ceramic tile has large mortar consumption, large consumption during construction and high density, and leads to the problems of overlarge bearing of a wall body, easy falling off and the like. Therefore, the development of the tile adhesive with low density, strong bonding capability and low construction consumption has important significance.
In view of the above, the present invention is particularly proposed.
Disclosure of Invention
The invention aims to provide a tile glue and a preparation method thereof, which are used for relieving the technical problems of overlarge usage amount, overlarge density and large construction usage amount of sand in the tile glue in the prior art.
In order to achieve the above purpose of the present invention, the following technical solutions are adopted:
the invention provides a ceramic tile adhesive which comprises the following raw materials in parts by weight: 30-40 parts of cement, 55-65 parts of inorganic porous material powder which is sieved by a minus 30-mesh sieve and 0.05-4 parts of optional auxiliary agent.
Further, the feed comprises the following raw materials in parts by weight: 31-38 parts of cement, 56-63 parts of inorganic porous material powder and 0.5-3.5 parts of optional auxiliary agent.
Further, the feed comprises the following raw materials in parts by weight: 33-37 parts of cement, 58-62 parts of inorganic porous material powder and 1-3 parts of optional auxiliary agent.
Further, the raw materials of the inorganic porous material powder comprise one or more of volcanic rock, light partition board waste residues or foamed ceramic insulation board waste residues.
Further, the cement comprises one or more of portland cement, aluminate cement and sulphoaluminate cement.
Further, the auxiliary agents comprise a water-retaining thickener, a binder and redispersible latex powder;
preferably, the water-retaining thickener is 0.1-0.3 part, preferably 0.12-0.28 part, and further preferably 0.15-0.25 part;
preferably, the binder is 0.05 to 0.25 part, preferably 0.07 to 0.23 part, and more preferably 0.1 to 0.2 part;
preferably, the redispersible latex powder is 0.5 to 3.5 parts, preferably 1 to 3 parts, and more preferably 1.5 to 2.5 parts.
The water-retaining thickener is cellulose ether, preferably one or more of methylcellulose, hydroxyethyl cellulose, hydroxyethyl methylcellulose or hydroxypropyl methylcellulose, and more preferably hydroxypropyl methylcellulose.
Further, the binder comprises one or more of polyvinyl alcohol, starch or dextrin, preferably polyvinyl alcohol.
Further, the redispersible latex powder comprises a vinyl acetate-ethylene polymer, an ethylene-vinyl chloride-vinyl laurate polymer, a vinyl acetate-ethylene-vinyl versatate polymer, an acrylate-styrene polymer or a styrene-butadiene polymer, preferably a styrene-butadiene polymer, and more preferably styrene-butadiene rubber powder.
The invention provides a preparation method of the ceramic tile glue, which is characterized in that cement, inorganic porous material powder and optional auxiliary agents are uniformly mixed to obtain the ceramic tile glue.
Compared with the prior art, the invention has the beneficial effects that:
the invention provides a ceramic tile adhesive, which comprises 30-40 parts of cement, 55-65 parts of inorganic porous material powder sieved by a-30-mesh sieve and optional auxiliary agents. The cement is the most important inorganic cementing material in the tile glue and is the important basis of various mechanical properties of the tile glue, and the mixing amount of the cement directly influences the water-resistant adhesive strength and freeze-thaw resistant adhesive strength of the tile glue. The inorganic porous material powder is used for replacing the traditional sand, so that the using amount of the sand is reduced, and meanwhile, the porous structure has a larger specific surface area, so that the density of the tile glue is reduced, and the bearing capacity of a matrix is further reduced. The particle size of the inorganic porous material powder is limited to be less than 500 mu m (sieving by a minus 30-mesh sieve), so that the uniformity of the components of the ceramic tile glue can be ensured, and the advantages of the inorganic porous material powder are not lost. The ceramic tile glue prepared from the cement and the inorganic porous material powder which is sieved by a minus 30-mesh sieve in a reasonable proportion has good mechanical property and low density, and meanwhile, compared with the ceramic tile glue with sand, the ceramic tile glue also reduces the production cost, and can be widely applied to various ceramic tile sticking places.
The invention provides a preparation method of the ceramic tile adhesive, which can be used for directly and uniformly mixing all the raw materials without additional operation and has low cost.
Detailed Description
Embodiments of the present invention will be described in detail below with reference to examples, but it will be understood by those skilled in the art that the following examples are only illustrative of the present invention and should not be construed as limiting the scope of the present invention. The examples, in which specific conditions are not specified, were conducted under conventional conditions or conditions recommended by the manufacturer.
The invention provides a ceramic tile adhesive which comprises the following raw materials in parts by weight: 30-40 parts of cement, 55-65 parts of inorganic porous material powder which is sieved by a minus 30-mesh sieve and 0.05-4 parts of optional auxiliary agent.
The cement is the most important inorganic cementing material in the tile glue and is the important basis of various mechanical properties of the tile glue, and the mixing amount of the cement directly influences the water-resistant adhesive strength and freeze-thaw resistant adhesive strength of the tile glue. The inorganic porous material powder is used for replacing the traditional sand, so that the using amount of the sand is reduced, and meanwhile, the porous structure has a larger specific surface area, so that the density of the tile glue is reduced, and the bearing capacity of a matrix is further reduced. The particle size of the inorganic porous material powder is limited to be less than 500 mu m (passing through a minus 30-mesh sieve), so that the uniformity of the components of the tile adhesive can be ensured, and meanwhile, in order to not lose the advantages of the inorganic porous material powder, the particle size of the inorganic porous material powder is preferably more than 250 mu m (passing through a plus 60-mesh sieve), namely the particle size of the inorganic porous material powder is 250-500 mu m (passing through a minus 30-plus 60-mesh sieve). The ceramic tile glue prepared from the cement and the inorganic porous material powder which is sieved by a minus 30-mesh sieve in a reasonable proportion has good mechanical property and low density, and meanwhile, compared with the ceramic tile glue with sand, the ceramic tile glue also reduces the production cost, and can be widely applied to various ceramic tile sticking places.
It should be noted that the mesh is often used as a unit of material particle size or mesh size. The larger the mesh number, the finer the particles, a quantifier commonly used in laboratory samples to break down particle size. Generally, mesh size (microns) is 15000. For those skilled in the art, a "- (negative sign)" is often added before the arabic numeral of the mesh number to indicate that the granule passes through the selected sieve, and a "+ (positive sign)" indicates that the granule fails to pass through the selected sieve. For example: "-80 mesh" means particles that pass through an 80 mesh screen; "+ 120 mesh" indicates particles that do not pass through a 120 mesh screen.
Typical but not limiting cements are 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts, or 40 parts; the inorganic porous material powder sieved by a minus 30-mesh sieve is typically, but not limited to, 55 parts, 56 parts, 57 parts, 58 parts, 59 parts, 60 parts, 61 parts, 62 parts, 63 parts, 64 parts or 65 parts.
In a preferred embodiment of the invention, the composition comprises the following raw materials in parts by weight: 31-38 parts of cement, 56-63 parts of inorganic porous material powder sieved by a minus 30-mesh sieve and 0.5-3.5 parts of optional auxiliary agent.
In a preferred embodiment of the invention, the composition comprises the following raw materials in parts by weight: 33-37 parts of cement, 58-62 parts of inorganic porous material powder which is sieved by a minus 30-mesh sieve and 1-3 parts of optional auxiliary agent.
The proportion of cement in the ceramic tile glue and inorganic porous material powder which is sieved by a minus 30-mesh sieve is further optimized, so that the performance of the ceramic tile glue can be further improved.
In a preferred embodiment of the invention, the raw material of the inorganic porous material powder which is sieved by a-30-mesh sieve comprises one or more of volcanic rock, light partition board waste residue or foamed ceramic insulation board waste residue.
Volcanic rock is a functional environment-friendly material, is a very precious porous stone material formed by volcanic glass, minerals and air bubbles after volcanic eruption, and can be applied to ceramic tile glue to increase the mechanical property of the ceramic tile glue and reduce the density of the ceramic tile glue.
Light partition wall board waste residue and foamed ceramic heated board waste residue belong to the industrial waste material of environmental protection, and in the production process of light partition wall board and foamed ceramic heated board, cut edge can produce a large amount of waste materials, is applied to the production that the ceramic tile was glued with it, has played waste utilization's effect, has reduced the manufacturing cost of enterprise. The light partition wall board waste residue and the foamed ceramic insulation board waste residue are used for preparing the ceramic tile glue, so that the density of the ceramic tile glue can be greatly reduced, the production cost of the ceramic tile glue is reduced, and the mechanical property of the ceramic tile glue is enhanced.
In a preferred embodiment of the invention, the cement comprises one or more of portland cement, aluminate cement, sulphoaluminate cement. Preferably ordinary portland cement.
In a preferred embodiment of the invention, the auxiliaries comprise a water-retaining thickener, a binder and a redispersible latex powder.
In a preferred embodiment of the present invention, the water-retaining thickener is 0.1 to 0.3 parts, preferably 0.12 to 0.28 parts, and more preferably 0.15 to 0.25 parts.
The water-retaining thickener can improve the scraping performance, the wet-sticking performance, the opening time and the anti-slip performance of the tile adhesive, and simultaneously ensures that the tile adhesive can be fully hydrated when being mixed with water. The water-retaining thickener is typically, but not limited to, 0.1 part, 0.12 part, 0.14 part, 0.05 part, 0.17 part, 0.19 part, 0.2 part, 0.22 part, 0.24 part, 0.25 part, 0.26 part, 0.28 part, or 0.3 part by weight part.
In a preferred embodiment of the invention, the binder is present in an amount of 0.05 to 0.25 parts, preferably 0.07 to 0.23 parts, and more preferably 0.1 to 0.2 parts.
The adhesive can improve the binding power and the anti-sliding performance of the tile adhesive, reduce the construction amount of the tile adhesive and enable the tile adhesive to have more application scenes. The binder is typically, but not limited to, 0.05 parts, 0.07 parts, 0.09 parts, 0.1 parts, 0.12 parts, 0.14 parts, 0.15 parts, 0.17 parts, 0.19 parts, 0.2 parts, 0.23 parts, or 0.25 parts by weight.
In a preferred embodiment of the invention, the redispersible latex powder is 0.5 to 3.5 parts, preferably 1 to 3 parts, and more preferably 1.5 to 2.5 parts.
The redispersible latex powder can form tiny emulsion particles after the ceramic tile adhesive is added with water and stirred, and inside the ceramic tile adhesive, the ceramic tile adhesive and a matrix, and a film is formed between the ceramic tile adhesive and a ceramic tile, so that the bonding force of the ceramic tile adhesive is improved, and the flexibility and the bonding performance of the ceramic tile adhesive are improved. Redispersible latex powders are typically, but not limited to, 0.5 parts, 0.7 parts, 0.9 parts, 1 part, 1.2 parts, 1.4 parts, 1.5 parts, 1.7 parts, 1.9 parts, 2 parts, 2.2 parts, 2.4 parts, 2.5 parts, 2.7 parts, 2.9 parts, 3 parts, 3.2 parts, 3.4 parts, or 3.5 parts by weight.
In a preferred embodiment of the present invention, the water retention thickener is a cellulose ether, preferably one or more of methylcellulose, hydroxyethylcellulose, hydroxyethylmethylcellulose or hydroxypropylmethylcellulose, and further preferably hydroxypropylmethylcellulose.
In a preferred embodiment of the invention, the binder comprises one or more of polyvinyl alcohol, starch or dextrin, preferably polyvinyl alcohol.
In a preferred embodiment of the present invention, the redispersible latex powder comprises a vinyl acetate-ethylene polymer, an ethylene-vinyl chloride-vinyl laurate polymer, a vinyl acetate-ethylene-vinyl versatate polymer, an acrylate-styrene polymer or a styrene-butadiene polymer, preferably a styrene-butadiene polymer, and more preferably a styrene-butadiene rubber powder.
The invention provides a preparation method of the ceramic tile glue, which is characterized in that cement, inorganic porous material powder which is sieved by a minus 30-mesh sieve and optional auxiliary agents are uniformly mixed to obtain the ceramic tile glue. The method can directly and uniformly mix all the raw materials, does not need additional operation and has low cost.
In order to facilitate a further understanding of the present invention, the technical solutions of the present invention will now be described in detail with reference to the preferred embodiments.
Example 1
The embodiment provides a ceramic tile adhesive, which comprises the following raw materials in parts by weight: 30 parts of aluminate cement and 65 parts of volcanic rock powder sieved by a minus 30-mesh sieve.
Example 2
The embodiment provides a ceramic tile adhesive, which comprises the following raw materials in parts by weight: 40 parts of aluminate cement and 55 parts of volcanic rock powder sieved by a minus 30-mesh sieve.
Example 3
The embodiment provides a ceramic tile adhesive, which comprises the following raw materials in parts by weight: 31 parts of sulphoaluminate cement and 63 parts of light partition wall board waste residue sieved by a minus 30-mesh sieve.
Example 4
The embodiment provides a ceramic tile adhesive, which comprises the following raw materials in parts by weight: 38 portions of sulphoaluminate cement and 56 portions of light partition board waste residue which is sieved by a minus 30 mesh sieve.
Example 5
The embodiment provides a ceramic tile adhesive, which comprises the following raw materials in parts by weight: 33 parts of Portland cement and 62 parts of foamed ceramic insulation board waste residues which are sieved by a minus 30-mesh sieve.
Example 6
The embodiment provides a ceramic tile adhesive, which comprises the following raw materials in parts by weight: 37 parts of Portland cement and 58 parts of foamed ceramic insulation board waste residues which are sieved by a minus 30-mesh sieve.
Example 7
The embodiment provides a ceramic tile adhesive, which comprises the following raw materials in parts by weight: 35 parts of Portland cement and 60 parts of foamed ceramic insulation board waste residues sieved by a minus 30-mesh sieve.
Comparative example 1
The comparative example provides a ceramic tile adhesive which comprises the following raw materials in parts by weight: 25 parts of Portland cement and 70 parts of foamed ceramic insulation board waste residues sieved by a minus 30-mesh sieve.
Comparative example 2
The comparative example provides a ceramic tile adhesive which comprises the following raw materials in parts by weight: 50 parts of Portland cement and 40 parts of foamed ceramic insulation board waste residues which are sieved by a minus 30-mesh sieve.
Comparative example 3
The comparative example provides a ceramic tile adhesive which comprises the following raw materials in parts by weight: 35 parts of Portland cement and 60 parts of sand.
Test example 1
The tile adhesives of examples 1-7 and comparative examples 1-3 were tested for their performance according to the relevant specifications in JC/T547-:
as can be seen from the data in the table above, the performances of the examples 1 to 7 are improved compared with those of the comparative examples 1 to 3, which shows that the ceramic tile glue provided by the invention is reasonable in proportion, and the inorganic porous material powder which is sieved by a minus 30-mesh sieve is used for replacing sand, so that the performance of the ceramic tile glue is not influenced and is also beneficial to the improvement of the performance of the ceramic tile glue. Meanwhile, under the same test conditions, the thickness of the tile glue in example 7 is reduced by about one fourth compared with that of the tile glue in comparative example 3, and the density of the tile glue in example 7 is much lower than that of the tile glue in comparative example 3.
Example 8
The embodiment provides a ceramic tile adhesive, which comprises the following raw materials in parts by weight: 30 parts of aluminate cement, 65 parts of volcanic rock sieved by a minus 30-mesh sieve, 0.1 part of methyl cellulose, 0.25 part of starch and 0.5 part of vinyl acetate-ethylene polymer.
Example 9
The embodiment provides a ceramic tile adhesive, which comprises the following raw materials in parts by weight: 40 parts of aluminate cement, 55 parts of volcanic rock sieved by a minus 30-mesh sieve, 0.3 part of hydroxyethyl cellulose, 0.05 part of dextrin and 3.5 parts of ethylene-vinyl chloride-vinyl laurate polymer.
Example 10
The embodiment provides a ceramic tile adhesive, which comprises the following raw materials in parts by weight: 31 parts of sulphoaluminate cement, 63 parts of light partition board waste residue sieved by a minus 30-mesh sieve, 0.12 part of hydroxyethyl methyl cellulose, 0.23 part of polyvinyl alcohol and 1 part of vinyl acetate-ethylene-vinyl versatate polymer.
Example 11
The embodiment provides a ceramic tile adhesive, which comprises the following raw materials in parts by weight: 38 parts of sulphoaluminate cement, 56 parts of light partition board waste residues sieved by a minus 30-mesh sieve, 0.28 part of hydroxypropyl methyl cellulose, 0.07 part of polyvinyl alcohol and 3 parts of acrylate-styrene polymer.
Example 12
The embodiment provides a ceramic tile adhesive, which comprises the following raw materials in parts by weight: 33 parts of Portland cement, 62 parts of foamed ceramic insulation board waste residues sieved by a minus 30-mesh sieve, 0.15 part of hydroxyethyl methyl cellulose, 0.2 part of polyvinyl alcohol and 1.5 parts of styrene-butadiene polymer.
Example 13
The embodiment provides a ceramic tile adhesive, which comprises the following raw materials in parts by weight: 37 parts of Portland cement, 58 parts of foamed ceramic insulation board waste residues sieved by a minus 30-mesh sieve, 0.25 part of hydroxypropyl methyl cellulose, 0.1 part of polyvinyl alcohol and 2.5 parts of butadiene styrene rubber powder.
Example 14
The embodiment provides a ceramic tile adhesive, which comprises the following raw materials in parts by weight: 35 parts of Portland cement, 60 parts of foamed ceramic insulation board waste residues sieved by a minus 30-mesh sieve, 0.2 part of hydroxypropyl methyl cellulose, 0.15 part of polyvinyl alcohol and 2 parts of butadiene styrene rubber powder.
Comparative example 4
The comparative example provides a ceramic tile adhesive which comprises the following raw materials in parts by weight: 25 parts of Portland cement, 70 parts of foamed ceramic insulation board waste residues sieved by a minus 30-mesh sieve, 0.05 part of hydroxypropyl methyl cellulose, 0.5 part of polyvinyl alcohol and 0.1 part of butadiene styrene rubber powder.
The formulation was different from that of example 14.
Comparative example 5
The comparative example provides a ceramic tile adhesive which comprises the following raw materials in parts by weight: 50 parts of Portland cement, 40 parts of foamed ceramic insulation board waste residues sieved by a minus 30-mesh sieve, 0.5 part of hydroxypropyl methyl cellulose, 0.01 part of polyvinyl alcohol and 4 parts of butadiene styrene rubber powder.
The formulation was different from that of example 14.
Comparative example 6
The comparative example provides a ceramic tile adhesive which comprises the following raw materials in parts by weight: 35 parts of Portland cement, 60 parts of foamed ceramic insulation board waste residues sieved by a minus 30-mesh sieve, 0.15 part of polyvinyl alcohol and 2 parts of butadiene styrene rubber powder.
In contrast to example 14, hydroxypropyl methylcellulose was absent.
Comparative example 7
The comparative example provides a ceramic tile adhesive which comprises the following raw materials in parts by weight: 35 parts of Portland cement, 60 parts of foamed ceramic insulation board waste residues sieved by a minus 30-mesh sieve, 0.2 part of hydroxypropyl methyl cellulose and 2 parts of butadiene styrene rubber powder.
In contrast to example 14, polyvinyl alcohol is absent.
Comparative example 8
The comparative example provides a ceramic tile adhesive which comprises the following raw materials in parts by weight: 35 parts of Portland cement, 60 parts of foamed ceramic insulation board waste residues sieved by a minus 30-mesh sieve, 0.2 part of hydroxypropyl methyl cellulose and 0.15 part of polyvinyl alcohol.
Compared with example 14, the styrene-butadiene rubber powder is lacked.
Comparative example 9
The comparative example provides a ceramic tile adhesive which comprises the following raw materials in parts by weight: 35 parts of Portland cement, 60 parts of sand, 0.2 part of hydroxypropyl methyl cellulose, 0.15 part of polyvinyl alcohol and 2 parts of butadiene styrene rubber powder.
Test example 2
The tile adhesives of examples 8-14 and comparative examples 4-9 were tested for performance according to the relevant specifications in JC/T547-:
as can be seen from the data in the table above, the performances of examples 8 to 14 are improved compared with those of comparative examples 4 to 9, which shows that the ceramic tile glue provided by the invention is reasonable in proportion, and the inorganic porous material powder which is sieved by a minus 30-mesh sieve is used for replacing sand, so that the performance of the ceramic tile glue is not influenced, and the improvement of the performance of the ceramic tile glue is facilitated. Meanwhile, under the same test conditions, the thickness of the tile glue in example 14 is reduced by about one fourth compared with that of the tile glue in comparative example 9, and the density of the tile glue in example 14 is much lower than that of the tile glue in comparative example 9.
While particular embodiments of the present invention have been illustrated and described, it would be obvious that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.
Claims (23)
1. The tile glue is characterized by comprising the following raw materials in parts by weight: 30-40 parts of cement, 55-65 parts of inorganic porous material powder which is sieved by a minus 30 to +60 mesh sieve and 0.05-4 parts of optional auxiliary agent;
the inorganic porous material powder is light partition wall board waste residue or foamed ceramic insulation board waste residue.
2. The tile glue according to claim 1, characterized by comprising the following raw materials in parts by weight: 31-38 parts of cement, 56-63 parts of inorganic porous material powder and 0.5-3.5 parts of optional auxiliary agent.
3. The tile glue according to claim 2, characterized by comprising the following raw materials in parts by weight: 33-37 parts of cement, 58-62 parts of inorganic porous material powder and 1-3 parts of optional auxiliary agent.
4. The tile glue of claim 1, wherein the cement comprises one or more of portland cement, aluminate cement, and sulphoaluminate cement.
5. The tile glue of any one of claims 1 to 4, wherein the auxiliaries include water-retaining thickeners, binders and redispersible latex powders.
6. The tile glue of claim 5, wherein the water retention thickener is 0.1-0.3 parts.
7. The tile glue of claim 6, wherein the water retention thickener is 0.12-0.28 parts.
8. The tile glue of claim 7, wherein the water retention thickener is 0.15-0.25 parts.
9. The tile glue of claim 5, wherein the adhesive is 0.05-0.25 parts.
10. The tile glue of claim 9, wherein the binder is 0.07-0.23 parts.
11. The tile glue of claim 10, wherein the adhesive is 0.1-0.2 parts.
12. The tile glue of claim 5, wherein the redispersible latex powder is 0.5-3.5 parts.
13. The tile glue of claim 12, wherein the redispersible latex powder is 1-3 parts.
14. The tile glue of claim 13, wherein the redispersible latex powder is 1.5-2.5 parts.
15. The tile glue of claim 5, wherein the water retention thickener is a cellulose ether.
16. The tile glue of claim 15, wherein the cellulose ether is one or more of methyl cellulose, hydroxyethyl methyl cellulose, or hydroxypropyl methyl cellulose.
17. The tile glue of claim 16, wherein the cellulose ether is hydroxypropyl methylcellulose.
18. The tile glue of claim 5, wherein the binder comprises one or more of polyvinyl alcohol, starch, or dextrin.
19. The tile glue of claim 18, wherein said binder is polyvinyl alcohol.
20. The tile glue of claim 5, wherein the redispersible latex powder comprises a vinyl acetate-ethylene polymer, an ethylene-vinyl chloride-vinyl laurate polymer, a vinyl acetate-ethylene-vinyl versatate polymer, an acrylate-styrene polymer, or a styrene-butadiene polymer.
21. The tile glue of claim 20, wherein the re-dispersible latex powder is a styrene-butadiene polymer.
22. The tile glue of claim 21, wherein the re-dispersible latex powder is styrene-butadiene rubber powder.
23. A process for preparing a tile glue according to any one of claims 1 to 22, wherein the tile glue is obtained by uniformly mixing cement, inorganic porous material powder and optionally an auxiliary agent.
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CN113896485B (en) * | 2021-11-26 | 2023-02-28 | 佛山市卓仕高新型材料有限公司 | High-strength tile glue and preparation method thereof |
CN115477508A (en) * | 2022-09-15 | 2022-12-16 | 江门市俞嘉科技有限公司 | Preparation process for producing ceramic tile glue by utilizing foamed ceramic tailings |
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