CN108611003A - A kind of stretch-proof double-sided self-adhesive polymer modified bituminous polyester fiber waterproof sheet material - Google Patents

A kind of stretch-proof double-sided self-adhesive polymer modified bituminous polyester fiber waterproof sheet material Download PDF

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Publication number
CN108611003A
CN108611003A CN201810479868.2A CN201810479868A CN108611003A CN 108611003 A CN108611003 A CN 108611003A CN 201810479868 A CN201810479868 A CN 201810479868A CN 108611003 A CN108611003 A CN 108611003A
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adhesive
polymer modified
polyester fiber
self
rubber
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乔启信
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ANHUI LANGKAIQI BUILDING MATERIALS Co Ltd
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ANHUI LANGKAIQI BUILDING MATERIALS Co Ltd
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Publication of CN108611003A publication Critical patent/CN108611003A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/21Paper; Textile fabrics
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J195/00Adhesives based on bituminous materials, e.g. asphalt, tar, pitch
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0862Nickel
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/124Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00Presence of inorganic and organic materials
    • C09J2400/20Presence of organic materials
    • C09J2400/26Presence of textile or fabric
    • C09J2400/263Presence of textile or fabric in the substrate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2495/00Presence of bitume

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The present invention discloses a kind of stretch-proof double-sided self-adhesive polymer modified bituminous polyester fiber waterproof sheet material, and the waterproof roll is using polyester fiber non-woven fabric as tire base, both sides coated polymeric modified pitch self-adhesive;The polymer modified asphalt self-adhesive is kneaded by pitch, butadiene-styrene rubber, polyisoprene rubber, SIS rubber, polyvinyl acetic acid fat, naphthenic oil, turpentine oil, 3 thiocyanatopropyltriethoxysilanes, reinforcing agent;Wherein, reinforcing agent is with chromium carbide, the sintered product of ramet, tungsten carbide, silicon nitride, silica, nickel.The present invention strengthens coiled material skeleton structure using butadiene-styrene rubber, polyisoprene rubber, SIS rubber, polyvinyl acetic acid fat modified synergic pitch, synthesis advantage by reinforcing agent, and waterproof roll flexibility, wearability, the adhesiveness produced are excellent.

Description

A kind of stretch-proof double-sided self-adhesive polymer modified bituminous polyester fiber waterproof sheet material
Technical field
The present invention relates to modified asphalt waterproof coiled material fields, and in particular to a kind of stretch-proof double-sided self-adhesive polymer modification drip Green polyester tyre water-proof coiled material.
Background technology
Double-sided self-adhesive polymer modified bituminous polyester fiber waterproof sheet material is using polyester fiber non-woven fabric as tire base, with elastomer Modified pitch do impregnate, coating material, coated made of self-adhesive rubber asphalt and attached strippable isolated material on upper and lower surface A kind of double-sided self-adhesive waterproof coiled materials have good extending performance, and adhesive property is strong, the advantages such as wet construction.Currently, mostly with list One polymer is modified pitch, and waterproof roll obtained is protruded in one-sided performance, but in comprehensive performance not It is enough excellent, for example the asphalt water-proof coiled material that single butadiene-styrene rubber is modified has excellent abrasion resistance, heat resistance and ageing-resistant performance, But its tensile strength, adhesiveness, hot tear crack performance are poor, are easy contraction distortion.
Application No. is the patents of CN201410036546.2, disclose a kind of self-adhesive polymer modified bituminous polyester fiber waterproof volume Material and preparation method thereof is kneaded the waterproof using raw materials such as pitch, naphthenic oil, modifying agent, tackifier, talcum powder, butadiene-styrene rubber Coiled material, the upper and lower surface of gained coiled material respectively reach 5.5N/mm, 6.2N/mm with cutting aluminum plate intensity, but only with single butylbenzene rubber Glue is modified, and the tensile strength of gained waterproof roll is relatively low, and space structure is not sufficiently stable, in addition, the talcum powder in coiled material is hard Minimum inorganic mineral is spent, using it as filler material, the hardness and compression strength of waterproof roll are relatively low, in long-term high-pressure situations Under, the case where easily causing web break, and talcum powder is not chemically crosslinked with remaining Organic Ingredients is only simple object Easily there is the problem of pitch coating material sedimentation layering in reason addition.
Invention content
In view of the deficiencies of the prior art, the purpose of the present invention is to provide a kind of stretch-proof double-sided self-adhesive polymer to change Property pitch polyester tyre water-proof coiled material.
Technical scheme of the present invention is summarized as follows:
A kind of stretch-proof double-sided self-adhesive polymer modified bituminous polyester fiber waterproof sheet material, the waterproof roll is with polyester fiber Non-woven fabrics is tire base, both sides coated polymeric modified pitch self-adhesive;The polymer modified asphalt self-adhesive is by pitch, butylbenzene Rubber, polyisoprene rubber, SIS rubber, polyvinyl acetic acid fat, naphthenic oil, turpentine oil, 3- thiocyanogen propyl triethoxies Silane, reinforcing agent are kneaded;Wherein, reinforcing agent is with the sintering of chromium carbide, ramet, tungsten carbide, silicon nitride, silica, nickel Product.
Preferably, the polymer modified asphalt self-adhesive includes following parts by weight of component:
Preferably, the reinforcing agent includes following raw material:
Preferably, the average carbon atom number of the naphthenic oil is 9-15.
A kind of above-mentioned stretch-proof double-sided self-adhesive polymer modified bituminous polyester fiber waterproof sheet material preparation method, including following step Suddenly:
S1:Chromium carbide, ramet, tungsten carbide, silicon nitride, silica, nickel are ground to 100 mesh, mixing compacting is warming up to 1450-1650 DEG C, under 1.5-3.3MPa nitrogen protections, it is sintered 2h, obtains reinforcing agent;
S2:Pitch, turpentine oil are heated to 200 DEG C, butadiene-styrene rubber is added, polyisoprene rubber, SIS rubber, gathers Vinylacetic acid fat, stirring melt 2h, are cooled to 150-160 DEG C, be added naphthenic oil, 3- thiocyanatopropyltriethoxysilanes and Gained reinforcing agent is stirred to react 2-4h to get polymer modified asphalt self-adhesive;
S3:The polymer modified asphalt self-adhesive of 0.4-1.2mm thickness is respectively coated in polyester fiber non-woven fabric both sides, through pressure To get the waterproof roll after system, overlay film, cooling, curling, packaging.
Beneficial effects of the present invention:
(1) present invention is compounded multigroup using butadiene-styrene rubber, polyisoprene rubber, SIS rubber, polyvinyl acetic acid fat Divide thermoplastic elastomer modified pitch, concentrated the advantage of four kinds of components, is formed and had complementary advantages, improve the synthesis of waterproof roll Performance has the characteristics that stretch-proof, anti-crack, viscosity is high, elasticity is high, wherein polyisoprene rubber and polyvinyl acetic acid Tensile strength is more than 30MPa, and elasticity up to 80%, elongation is up to 1000%, and collaboration improves the coefficient of elasticity of coiled material And tensile strength, compensate for the defect of the synthetic rubber such as butadiene-styrene rubber and SIS rubber.
(2) present invention improves the structural strength of waterproof roll by reinforcing agent, makes it have higher toughness and wearability, Deformation retract is prevented, using chromium carbide, tungsten carbide, silicon nitride and silica as hard phase, improves hardness and the resistance to compression of waterproof roll Coefficient prevents hard phase from being sintered grain growth using ramet as hard phase inhibitor, and reinforcing agent is made to be uniformly dispersed in pitch breast In liquid, nickel has good ductility, improves the toughness of coiled material.
(3) interface between modified pitch and reinforcing agent is reduced in the present invention using 3- thiocyanatopropyltriethoxysilanes Power makes the two have good compatibility, improves the spatial stability of waterproof roll.
Specific implementation mode
With reference to embodiment, the present invention is described in further detail, to enable those skilled in the art with reference to specification Word can be implemented according to this.
Embodiment 1
A kind of stretch-proof double-sided self-adhesive polymer modified bituminous polyester fiber waterproof sheet material, the waterproof roll is with polyester fiber Non-woven fabrics is tire base, both sides coated polymeric modified pitch self-adhesive;The polymer modified asphalt self-adhesive is by pitch, butylbenzene Rubber, polyisoprene rubber, SIS rubber, polyvinyl acetic acid fat, naphthenic oil, turpentine oil, 3- thiocyanogen propyl triethoxies Silane, reinforcing agent are kneaded;Wherein, reinforcing agent is with the sintering of chromium carbide, ramet, tungsten carbide, silicon nitride, silica, nickel Product.
Above-mentioned polymer modified asphalt self-adhesive, including following parts by weight of component:
Wherein, reinforcing agent includes following raw material:
A kind of above-mentioned stretch-proof double-sided self-adhesive polymer modified bituminous polyester fiber waterproof sheet material preparation method, including following step Suddenly:
S1:Chromium carbide, ramet, tungsten carbide, silicon nitride, silica, nickel are ground to 100 mesh, mixing compacting is warming up to 1450 DEG C, under 1.5MPa nitrogen protections, it is sintered 2h, obtains reinforcing agent;
S2:Pitch, turpentine oil are heated to 200 DEG C, butadiene-styrene rubber is added, polyisoprene rubber, SIS rubber, gathers 2h is melted in vinylacetic acid fat, stirring, is cooled to 150 DEG C, and C9 naphthenic oils, 3- thiocyanatopropyltriethoxysilanes and institute is added Reinforcing agent is obtained, the average carbon atom number of the C9 naphthenic oils is 9, is stirred to react 2h to get polymer modified asphalt self-adhesive;
S3:It is respectively coated the polymer modified asphalt self-adhesive of 0.4mm thickness in polyester fiber non-woven fabric both sides, repressed, To get the waterproof roll after overlay film, cooling, curling, packaging.
Embodiment 2
Polymer modified asphalt self-adhesive, including following parts by weight of component:
Wherein, reinforcing agent includes following raw material:
The preparation method is the same as that of Example 1 for above-mentioned waterproof roll, difference lies in:
S1:Sintering condition is 1550 DEG C, 2.4MPa nitrogen;S2:It is respectively 155 DEG C, 3h to be stirred to react temperature and time; S3:Rubberization thickness is 0.8mm.
Embodiment 3
Polymer modified asphalt self-adhesive, including following parts by weight of component:
Wherein, reinforcing agent includes following raw material:
The preparation method is the same as that of Example 1 for above-mentioned waterproof roll, difference lies in:
S1:Sintering condition is 1650 DEG C, 3.3MPa nitrogen;S2:It is respectively 160 DEG C, 4h to be stirred to react temperature and time; S3:Rubberization thickness is 1.2mm.
As a comparison case with common self-adhesive polymer modified bituminous polyester fiber waterproof sheet material, respectively testing example 1-3 and The mechanical property and stability of comparative example, the results are shown in table below:
As seen from the above table, the present invention significantly improves waterproof roll tensile resistance and high temperature strength, and with excellent Flexibility, wearability, adhesiveness.
Although the embodiments of the present invention have been disclosed as above, but its is not only in the description and the implementation listed With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily Realize other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, the present invention is simultaneously unlimited In specific details.

Claims (5)

1. a kind of stretch-proof double-sided self-adhesive polymer modified bituminous polyester fiber waterproof sheet material, which is characterized in that the waterproof roll Using polyester fiber non-woven fabric as tire base, both sides coated polymeric modified pitch self-adhesive;The polymer modified asphalt self-adhesive By pitch, butadiene-styrene rubber, polyisoprene rubber, SIS rubber, polyvinyl acetic acid fat, naphthenic oil, turpentine oil, 3- thiocyanogens Propyl-triethoxysilicane, reinforcing agent are kneaded;Wherein, reinforcing agent is with chromium carbide, ramet, tungsten carbide, silicon nitride, oxidation The sintered product of silicon, nickel.
2. a kind of stretch-proof double-sided self-adhesive polymer modified bituminous polyester fiber waterproof sheet material according to claim 1, feature It is, the polymer modified asphalt self-adhesive includes following parts by weight of component:
3. according to a kind of arbitrary stretch-proof double-sided self-adhesive polymer modified bituminous polyester fiber waterproof sheet material of claims 1 or 2, It is characterized in that, the reinforcing agent includes following raw material:
4. according to a kind of arbitrary stretch-proof double-sided self-adhesive polymer modified bituminous polyester fiber waterproof sheet material of claims 1 or 2, It is characterized in that, the average carbon atom number of the naphthenic oil is 9-15.
5. a kind of stretch-proof double-sided self-adhesive polymer modified bituminous polyester fiber waterproof sheet material as described in claim any one of 1-4, It is characterized in that, the preparation method of the waterproof roll includes the following steps:
S1:Chromium carbide, ramet, tungsten carbide, silicon nitride, silica, nickel are ground to 100 mesh, mixing compacting is warming up to 1450-1650 DEG C, under 1.5-3.3MPa nitrogen protections, it is sintered 2h, obtains reinforcing agent;
S2:Pitch, turpentine oil are heated to 200 DEG C, add butadiene-styrene rubber, polyisoprene rubber, SIS rubber, polyethylene 2h is melted in base amyl acetate, stirring, is cooled to 150 DEG C, and C9 naphthenic oils, 3- thiocyanatopropyltriethoxysilanes and gained is added and increases Strong agent, the C9 naphthenic oils are stirred to react 2-4h to get polymer modified asphalt self-adhesive;
S3:It is respectively coated the polymer modified asphalt self-adhesive of 0.4-1.2mm thickness in polyester fiber non-woven fabric both sides, repressed, To get the waterproof roll after overlay film, cooling, curling, packaging.
CN201810479868.2A 2018-05-18 2018-05-18 A kind of stretch-proof double-sided self-adhesive polymer modified bituminous polyester fiber waterproof sheet material Pending CN108611003A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113478925A (en) * 2021-05-26 2021-10-08 郑永胜 High-resistance asphalt coiled material applied to regions with large temperature difference
CN114479687A (en) * 2022-02-25 2022-05-13 湖北华宇防水材料科技股份有限公司 Preparation process of double-sided self-adhesive non-asphalt-based waterproof roll
CN115305051A (en) * 2021-05-08 2022-11-08 韩爽 Novel chemical material with high melting point and corrosion resistance

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115305051A (en) * 2021-05-08 2022-11-08 韩爽 Novel chemical material with high melting point and corrosion resistance
CN113478925A (en) * 2021-05-26 2021-10-08 郑永胜 High-resistance asphalt coiled material applied to regions with large temperature difference
CN114479687A (en) * 2022-02-25 2022-05-13 湖北华宇防水材料科技股份有限公司 Preparation process of double-sided self-adhesive non-asphalt-based waterproof roll

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Application publication date: 20181002