CN108609743A - A method of utilizing microbial degradation ammonia nitrogen - Google Patents
A method of utilizing microbial degradation ammonia nitrogen Download PDFInfo
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- CN108609743A CN108609743A CN201810497655.2A CN201810497655A CN108609743A CN 108609743 A CN108609743 A CN 108609743A CN 201810497655 A CN201810497655 A CN 201810497655A CN 108609743 A CN108609743 A CN 108609743A
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- brown sugar
- ammonia nitrogen
- garbage sludge
- microbial degradation
- bacterium
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/28—Anaerobic digestion processes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/06—Nutrients for stimulating the growth of microorganisms
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- Life Sciences & Earth Sciences (AREA)
- Microbiology (AREA)
- Biodiversity & Conservation Biology (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
Abstract
The present invention provides a kind of methods using microbial degradation ammonia nitrogen, the denitrification pond of the middle-end in sewage treatment project, and garbage sludge bacterium is added in buffer pool and carries out biochemical treatment；The additive amount of microorganism, garbage sludge bacterium is 10~20 grams/every cubic metre sewage；Brown sugar is added simultaneously, the additive amount of brown sugar is 46 kilograms of brown sugar/80 100 kilogram sewage；The feed postition of brown sugar is：It impregnates 0.5~12 hour, is then uniformly splashed in denitrification pond and buffer pool in water, activated sludge stirring fermentation 35 days is then added afterwards again.This launches suitable microorganism using the method for microbial degradation ammonia nitrogen in nitrification tank or denitrification pond, can promote the growth and breeding of microorganism, to play the effect of microorganism to greatest extent, can handle the nitrogenous effluent of high concentration, at low cost.
Description
Technical field
The present invention relates to technical field of sewage, and in particular, to a method of utilizing microbial degradation ammonia nitrogen.
Background technology
With the continuous development of society and people's living standards continue to improve, water environment is worsening, and the nitrogen in water contains
Amount, which is continuously increased, causes water quality severe exacerbation.The development of recent decades is so that rural area, the surface water in city, underground water all have three
The pollution of nitrogen (ammonia nitrogen, nitrate nitrogen and nitrite nitrogen).
Ammoniacal nitrogen is that nitrogen is primarily present form in aqueous environment.It is provided when ammonia-containing water is discharged into rivers and lakes, especially water
Source not in very sufficient river, fish pond when, receiving water body can be caused to lose oxygen, unwanted aquatic organism is grown, fish is caused to be poisoned.City
City's sanitary wastewater, the discharge water of various feed lots, septic tank lixivium, ammonia-nitrogen content is between 100~500mg/L.With
The hydrometallurgical development of non-ferrous metal, these factories often give off existing containing ammonia or ammonium waste water, ammonia-nitrogen content for high concentration
10g/L or more, some are even as high as 100g/L or so.2000 annual forest monitorings statistics indicate that, the Yellow River Ningxia enter a country section (centre halfback
Lower river bank) ammonia nitrogen concentration be no more than country《Environmental Quality Standard of Surface Water》(GZHG1-1999) requirement in providing, but reach
Control section (silver Gu highway bridge) and departure section (peaceful steel pontoon bridge) are exceeded serious, wherein silver Gu bridge highway bridge section exceeding standard rate
It is 66.7%, exceeded 2.16 times, peaceful steel pontoon bridge section exceeding standard rate is up to 100.0%, exceeded 3.20 times.Ammonia and nitrogen pollution becomes along Cheng Jiachong
Gesture is fairly obvious.In recent years, Yellow River control section (silver Gu highway bridge) ammonia and nitrogen pollution was in apparent ascendant trend year by year.Ammonia nitrogen
Having become influences the primary pollution of Yellow River.At present, Yellow River classification with V class or surpasses based on V class water quality.
Pollution of nitrate nitrogen most has become a global environmental problem in the past 40 years.Such as the U.S. states Texas
NO in the counties Runnels underground water3Content reaches 233mg/L；Britain was in NO in 19703-- N intervals are more than 113mg/L, and 1980 are about
For 90mg/L, 142mg/L is reached within 1987；BeiJing, China's nitrate in groundwater peak is 314mg/L, Shijiazhuang City underground water
Middle NO3Content is up to 20~40mg/L, peak 96mg/L.In addition there are Denmark, France, Canada, Germany, Holland, prints
The Drinking Water of the country such as degree, Egypt is also by different degrees of pollution.Some of Britain and the U.S. results of study are shown, are drunk
It is directly proportional to gastric cancer, the incidence of cancer of the esophagus and the death rate with the nitrate content of underground water.It is done in Linzhou City of Henan Province, Anyang County
Drinking water NO3Investigation of content, water sampling 43, NO in the underground water that resident drinks3Content substantially exceeds world health group
Knit drinking water quality standard 45mg/L (or the NO of (WHO) promulgation3In N be 10mg/L).Such as Anyang County one village is drunk
NO-3 contents are up to 94mg/L in underground water.
Though content of the nitrite in water body is high not as good as ammonia nitrogen and nitrate nitrogen, its harmfulness is not also small.Nitrous acid
Salt can form stable, carcinogenic and mutagenicity N-nitrosamine and nitroso under the effect of various organic compounds containing nitrogens
The various N- nitrosos compounds of group of amide.Nitrite ion can cause methemoglobinemia or baby after entering human body
Blue mass formed by blood stasis.Nitrite is the precursor for synthesizing strong carcinogen nitrosamine, and Japan, Britain, Chile, Colombia reported
Nitrite, nitrate and incidence gastric cancer rate have great correlation.Water Environment Nitrogen pollution is toxic to aquatic animals such as fish
Evil effect.The ammonia of low concentration can be interfered in water body transmits with the oxygen of the fish gill, can be to aquatic when its concentration reaches 0.5mg/L
Animal especially fish cause toxic action；Due to nitrification in water body, ammonia nitrogen will continue to be oxidized to nitrate nitrogen, and consume
The a large amount of dissolved oxygens of water body can make the aquatic animals death by suffocation such as fish when serious.Nitrogen is the indispensable nutrient of plant, but
If total N is excessive in water body, algal bloom, enrichment can be made, eutrophication occur, a large amount of dissolvings consumed in water
Oxygen makes water ecological setting deteriorate.
Everything shows that the polluted by nitrogen in water body is extremely serious, study polluted by nitrogen, and propose it is practicable improvement with
Modification measures, it has also become the task of top priority of scientific worker and government department.
The processing method of nitrogenous effluent has bioanalysis, Physical, chemical method, physical-chemical process etc. at this stage.It is most widely used
Be bioanalysis, bioanalysis is most widely used denitrogenation core technology, easy to operate because this method is at low cost, without secondary
Pollution.
By microbial degradation ammonia nitrogen, principle is：Biological denitrificaion is by nitration reaction under aerobic condition first by ammonia
Nitrogen oxidation is nitrate, then is removed nitrate reduction from water at gaseous nitrogen by the anti-nitration reaction under anoxia condition.It is raw
Object denitrogenation is completed by three ammonification, nitrification, denitrification steps.
Wherein, aminating reaction：Ammoniation refers to the process of converting organonitrogen compound to NH3-N, also referred to as mineralising
Effect.The bacterium for participating in ammoniation is known as amonifying bacteria.In nature, there are many their type, mainly have aerobic
Pseudomonas fluorescens and Bacterium prodigiosum, facultative proteus and anaerobism clostridium septicum etc..Under aerobic condition, there are mainly two types of
Degradation mode, first, the oxidative deamination under oxidase catalyzed, another is certain aerobic bacterias, can water under the catalytic action of hydrolase
Solve denitrification reaction.Under conditions of anaerobism or anoxic, anaerobe and amphimicrobe carry out organonitrogen compound
Restore deamination, hydrolytic deaminzation and the aminating reaction for being dehydrated three kinds of approach of deamination.
Nitration reaction is under the action of nitrobacteria, and ammoniacal nitrogen is further decomposed, aoxidized, with regard to this in two stages into
Row.First, under the action of nitrite bacteria, ammonia (NH4+) is made to be converted into cultured water, effect of the cultured water in Nitromonas
Under, it is further converted to nitrate nitrogen.Nitrosomas has nitrous acid zygosaccharomyces, nitrous acid Helicobacterium and nitrous acid Coccus.
Nitromonas has nitric acid Bacillus, nitric acid Coccus.
Anti-nitration reaction：Anti-nitration reaction refers to nitrate nitrogen and cultured water under the action of denitrifying bacterium, is reduced to
The process of gaseous nitrogen (N2).The bacterium for carrying out this kind of reaction mainly has Proteus, Micrococcus, pseudomonas, brood cell
The facultative bacterias such as Bacillus, alcaligenes, Flavobacterium, they are widespread in nature.
Traditional biological denitrificaion method research application time is long, technical maturity, but handles the nitrogenous effluent effect of high concentration
Unobvious, and it is of high cost.
Invention content
For overcome the deficiencies in the prior art, the present invention provides a kind of methods using microbial degradation ammonia nitrogen, in nitre
Change in pond or denitrification pond and launch suitable microorganism, the growth and breeding of microorganism can be promoted, to send out to greatest extent
The effect of microorganism is waved, the nitrogenous effluent of high concentration can be handled, it is at low cost.
Technical scheme is as follows：A method of using microbial degradation ammonia nitrogen, in sewage treatment project
The denitrification pond of middle-end, addition garbage sludge bacterium carries out biochemical treatment in buffer pool；The additive amount of microorganism, garbage sludge bacterium is
10~20 grams/every cubic metre sewage；Brown sugar is added simultaneously, the additive amount of brown sugar is 4-6 kilograms of brown sugar/80-100 kilograms of sewage；
The feed postition of brown sugar is：It impregnates 0.5~12 hour, is then uniformly splashed in denitrification pond and buffer pool, then again in water
Activated sludge stirring fermentation 3-5 days is added afterwards.
The garbage sludge bacterium bag includes Nitrosomas, Nitromonas and anti-digestion compound bacteria.
Preferably, the garbage sludge bacterium is recycled by reflux technique, and reuse, frequency of use is once a week；
Application method is that first drop garbage sludge bacterium is dissolved in a small amount of water, after be directly added into denitrification pond, in buffer pool.
The garbage sludge bacterium flows to the anoxic pond and aerobic tank of follow-up A/O techniques；And by the reflux pump of aerobic tank,
A viable bacteria reflux part after the aerobic breeding of garbage sludge bacterium is to the denitrification pond and the buffer pool, to economize on bacterium
Or the utilization rate of the garbage sludge bacterium is improved as far as possible.
Beneficial effects of the present invention are：Method of the present invention using microbial degradation ammonia nitrogen, in the denitrification
The garbage sludge bacterium is added in pond and the buffer pool, to digest the ammonia nitrogen in degradation sewage；Have by the anti-nitre
Change in pond and the buffer pool and brown sugar is added, to assist the garbage sludge bacterium growth and breeding.
Specific implementation mode
In order to make the goal of the invention of the present invention, technical solution and technique effect are more clearly understood, with reference to specific reality
Applying mode, the present invention is described further.It should be understood that specific embodiment described herein, be only used for explaining the present invention,
It is not intended to limit the present invention.
A kind of method using microbial degradation ammonia nitrogen of embodiment 1, the denitrification pond of the middle-end in sewage treatment project,
Garbage sludge bacterium is added in buffer pool carries out biochemical treatment；The additive amount of microorganism, garbage sludge bacterium is 10 grams/every cubic metre dirt
Water；Brown sugar is added simultaneously, the additive amount of brown sugar is 4 kilograms of brown sugar/80 kilogram sewage；The feed postition of brown sugar is：It soaks in water
Bubble 12 hours, then uniformly splashes in denitrification pond and buffer pool, and activated sludge stirring fermentation 3 days is then added afterwards again.
The garbage sludge bacterium bag includes Nitrosomas, Nitromonas and anti-digestion compound bacteria.
Preferably, the garbage sludge bacterium is recycled by reflux technique, and reuse, frequency of use is once a week；
Application method is that first drop garbage sludge bacterium is dissolved in a small amount of water, after be directly added into denitrification pond, in buffer pool.
The garbage sludge bacterium flows to the anoxic pond and aerobic tank of follow-up A/O techniques；And by the reflux pump of aerobic tank,
A viable bacteria reflux part after the aerobic breeding of garbage sludge bacterium is to the denitrification pond and the buffer pool, to economize on bacterium
Or the utilization rate of the garbage sludge bacterium is improved as far as possible.
A kind of method using microbial degradation ammonia nitrogen of embodiment 2, the denitrification pond of the middle-end in sewage treatment project,
Garbage sludge bacterium is added in buffer pool carries out biochemical treatment；The additive amount of microorganism, garbage sludge bacterium is 15 grams/every cubic metre dirt
Water；Brown sugar is added simultaneously, the additive amount of brown sugar is 6 kilograms of brown sugar/100 kilogram sewage；The feed postition of brown sugar is：It soaks in water
Bubble 5 hours, then uniformly splashes in denitrification pond and buffer pool, and activated sludge stirring fermentation 5 days is then added afterwards again.
The garbage sludge bacterium bag includes Nitrosomas, Nitromonas and anti-digestion compound bacteria.
Preferably, the garbage sludge bacterium is recycled by reflux technique, and reuse, frequency of use is once a week；
Application method is that first drop garbage sludge bacterium is dissolved in a small amount of water, after be directly added into denitrification pond, in buffer pool.
The garbage sludge bacterium flows to the anoxic pond and aerobic tank of follow-up A/O techniques；And by the reflux pump of aerobic tank,
A viable bacteria reflux part after the aerobic breeding of garbage sludge bacterium is to the denitrification pond and the buffer pool, to economize on bacterium
Or the utilization rate of the garbage sludge bacterium is improved as far as possible.
A kind of method using microbial degradation ammonia nitrogen of embodiment 3, the denitrification pond of the middle-end in sewage treatment project,
Garbage sludge bacterium is added in buffer pool carries out biochemical treatment；The additive amount of microorganism, garbage sludge bacterium is 20 grams/every cubic metre dirt
Water；Brown sugar is added simultaneously, the additive amount of brown sugar is 5 kilograms of brown sugar/90 kilogram sewage；The feed postition of brown sugar is：It soaks in water
Bubble 0.5 hour, then uniformly splashes in denitrification pond and buffer pool, and activated sludge stirring fermentation 4 days is then added afterwards again.
The garbage sludge bacterium bag includes Nitrosomas, Nitromonas and anti-digestion compound bacteria.
Preferably, the garbage sludge bacterium is recycled by reflux technique, and reuse, frequency of use is once a week；
Application method is that first drop garbage sludge bacterium is dissolved in a small amount of water, after be directly added into denitrification pond, in buffer pool.
The garbage sludge bacterium flows to the anoxic pond and aerobic tank of follow-up A/O techniques；And by the reflux pump of aerobic tank,
A viable bacteria reflux part after the aerobic breeding of garbage sludge bacterium is to the denitrification pond and the buffer pool, to economize on bacterium
Or the utilization rate of the garbage sludge bacterium is improved as far as possible.
The above content is a further detailed description of the present invention in conjunction with specific preferred embodiments, and it cannot be said that
The specific implementation of the present invention is confined to these explanations.For those of ordinary skill in the art to which the present invention belongs, exist
Under the premise of not departing from present inventive concept, architectural form cans be flexible and changeable, can be with derivative series product.It only makes several
Simple deduction or replace all shall be regarded as belonging to present invention scope of patent protection determined by the appended claims.
Claims (5)
1. a kind of method using microbial degradation ammonia nitrogen, which is characterized in that the denitrification of the middle-end in sewage treatment project
Pond, addition garbage sludge bacterium carries out biochemical treatment in buffer pool；Microorganism, the additive amount of garbage sludge bacterium is 10~20 grams/it is every
Cubic meter sewage；Brown sugar is added simultaneously, the additive amount of brown sugar is 4-6 kilograms of brown sugar/80-100 kilograms of sewage；The addition side of brown sugar
Formula is：It impregnates 0.5~12 hour, is then uniformly splashed in denitrification pond and buffer pool in water, it is dirty that activity is then added afterwards again
Mud stirring fermentation 3-5 days.
2. the method for utilizing microbial degradation ammonia nitrogen as described in claim 1, which is characterized in that the garbage sludge bacterium bag includes
Nitrosomas, Nitromonas and anti-digestion compound bacteria.
3. the method for utilizing microbial degradation ammonia nitrogen as described in claim 1, which is characterized in that the garbage sludge bacterium passes through
Reflux technique recycles, and reuses, and frequency of use is once a week.
4. the method for utilizing microbial degradation ammonia nitrogen as claimed in claim 3, which is characterized in that the garbage sludge bacterium makes
It is with method：The garbage sludge bacterium is first dissolved in a small amount of water, after be directly added into denitrification pond, in buffer pool.
5. the method for utilizing microbial degradation ammonia nitrogen as claimed in claim 3, which is characterized in that the garbage sludge bacterium flows to
The anoxic pond and aerobic tank of follow-up A/O techniques；And by the reflux pump of aerobic tank, after the aerobic breeding of garbage sludge bacterium
Viable bacteria reflux is a part of to the denitrification pond and the buffer pool.
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| CN201810497655.2A CN108609743A (en) | 2018-05-22 | 2018-05-22 | A method of utilizing microbial degradation ammonia nitrogen |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110591959A (en) * | 2019-09-28 | 2019-12-20 | 成都市锦鑫汇生物科技有限公司 | Proteus mirabilis preparation for treating domestic sludge and preparation method and application thereof |
| CN110591961A (en) * | 2019-09-28 | 2019-12-20 | 成都市锦鑫汇生物科技有限公司 | Composite biological agent for treating domestic sludge and preparation method and application thereof |
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| CN101259977A (en) * | 2007-12-28 | 2008-09-10 | 凌亮 | Method for removing total nitrogen by using microorganism |
| CN102465101A (en) * | 2010-11-04 | 2012-05-23 | 中国石油化工股份有限公司 | Denitrification bacterium preparation capable of utilizing nitrite to realize denitrification and use thereof |
| WO2012137220A2 (en) * | 2011-04-04 | 2012-10-11 | Indian Oil Corporation Ltd. | Bio-augmentation composition and use thereof for improving efficiency of effluent treatment in hydrocarbon processing plant |
| CN103508559A (en) * | 2013-09-29 | 2014-01-15 | 浦城正大生化有限公司 | Aerobic treatment method applied in antibiotic wastewater treatment |
| CN105906150A (en) * | 2016-06-06 | 2016-08-31 | 李丹丹 | Sewage treatment system and technology for river ways in city |
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2018
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101259977A (en) * | 2007-12-28 | 2008-09-10 | 凌亮 | Method for removing total nitrogen by using microorganism |
| CN102465101A (en) * | 2010-11-04 | 2012-05-23 | 中国石油化工股份有限公司 | Denitrification bacterium preparation capable of utilizing nitrite to realize denitrification and use thereof |
| WO2012137220A2 (en) * | 2011-04-04 | 2012-10-11 | Indian Oil Corporation Ltd. | Bio-augmentation composition and use thereof for improving efficiency of effluent treatment in hydrocarbon processing plant |
| CN103508559A (en) * | 2013-09-29 | 2014-01-15 | 浦城正大生化有限公司 | Aerobic treatment method applied in antibiotic wastewater treatment |
| CN105906150A (en) * | 2016-06-06 | 2016-08-31 | 李丹丹 | Sewage treatment system and technology for river ways in city |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110591959A (en) * | 2019-09-28 | 2019-12-20 | 成都市锦鑫汇生物科技有限公司 | Proteus mirabilis preparation for treating domestic sludge and preparation method and application thereof |
| CN110591961A (en) * | 2019-09-28 | 2019-12-20 | 成都市锦鑫汇生物科技有限公司 | Composite biological agent for treating domestic sludge and preparation method and application thereof |
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Application publication date: 20181002 |