CN108601837A - Extended release type perfume composition - Google Patents

Abstract

It provides and is extending in the period composition that fragrance is provided.These compositions include aromatic and one or more other compositions.

Description

Extended release type perfume composition

Technical field

Present invention relates in general to the dulcet hidroschesis combinations comprising one or more aromatic oil being dispersed in oil phase Object, it is characterised in that the fragrance characters of reduction over time and loss of strength.

Background technology

Antiperspirant composition is usually applied to skin, such as oxter, to prevent or reduce body perspiration and/or stink.Such group It closes object and uses a variety of physical forms, including stick, soft solid, gel, emulsifiable paste, roller coating liquid or pump type or aerosol-type spray. Antiperspirant composition is typically also containing aromatic to enhance smell, cover or the elimination body odor of personal care product or provide it His function benefit such as drives away insect.

However, the passage rapid deterioration or bad of the fragrance characters and intensity of many antiperspirant compositions in storage at any time Change.It has attempted to by the way that various stabilizers are introduced into antiperspirant composition come spice-aromatic loss when slowing down storage.(referring to, For example, EP 0274267) other methods for fighting fragrance loss be related to mixing antioxidant, improve aromatic it is horizontal, with And commercially available aromatic oil is prepared again.

This field still needs the composition comprising antiperspirant, has the fragrance characters of reduction over time and strong Degree loss, preferably on condition that not necessarily increasing aromatic load or needing special aromatic or stabilizer.

Therefore, the purpose of the present invention is to provide：Composition, these compositions are in antiperspirant composition, in feature and intensity Two aspects are each provided with the fragrant level loss reduced when storage；With the packaging personal care product containing such composition.

Introduce the property discussed above for being used for the purpose of more fully understanding this field problem encountered, and not Ying Yiren Where formula is construed to admission of prior art, should not also be considered as any bibliography cited herein and recognize such reference Document constitutes " prior art " of the application.

Invention content

According to foregoing purpose and other purposes, antiperspirant composition is provided, these antiperspirant compositions are in extended Storage period It is interior that stable fragrance characters and intensity are provided.It has surprisingly been found that with less saturated fatty acid content at it He compares the identical preparation of aspect, including one or more be dispersed in (has in total comprising one or more triglyceride oils At least 75% saturated fatty acid content) oil phase in the antiperspirant composition of aromatic oil the virtue of reduction over time is provided Fragrant feature and loss of strength.These antiperspirant compositions are desirable to provide other one or more desired benefits, such as when applied It shows the soft feeling to skin, moisturizing skin, the whitening effect for mitigating inorganic hidroschesis active matter confrontation skin, reduce skin thorn Sharp and/or darkening and the balanced colour of skin.

These compositions are typically in the shape of water or lotion (for example, oil-in-water or Water-In-Oil) or dispersion in alcohol Formula such as roller coating antiperspirant, but can also use the form of such as emulsifiable paste, gel, soft solid, stick or spray.The present invention's On one side, these compositions can include one or more aromatic oil, and amount individually or is total up to composition by weight Meter is from about 0.1% to about 3% (for example, about 0.5%, 1%, 1.5%, 2%, or about 2.5%).Aromatic oil can be for main The oil of aesthetic benefits (such as fragrance), functional benefits (for example, pest repellant such as citronella oil) or both.These compositions can be with Including oil phase.The oil phase in the composition existing amount typically by weight from about 0.1% to about 20%, be more typically By weight from about 1% to about 10%, or from about 2% to about 8%.The oil phase is typically by one or more triglyceride oil structures Have by weight at least 75% or more in total at, one or more triglyceride oils (for example, at least 80%, 85%, 90%, 95% etc.) saturated fatty acid content, such as coconut oil or palm-kernel oil.Typically, the content of fatty acid of the oil phase includes At least 75% aliphatic acid with C16 or less chain lengths.In some embodiments, the oil phase of these compositions includes and presses Weight meter is less than 5%, 4%, 3% or 2% or substantially free of (being less than 1% by weight) or without with relatively high The oil of unsaturated fatty acid content (being more than 25%), such as sunflower oil, rapeseed oil, corn oil, cottonseed oil, linseed oil, olive Olive oil, safflower oil, soybean oil, canola oil, peanut oil, sesame oil, apricot kernel oil, castor oil, and combinations thereof.These compositions can be with One or more antiperspirant actives substances that can reduce or eliminate body perspiration are further included, based on anhydrous solid, Amount is composition by weight from about 1% to about 25% (for example, about 5%-15%).Preferably, such antiperspirant actives substance It is based on aluminium or based on aluminium/zirconium.For example, one or more antiperspirant actives substances can be aluminium salt or aluminium/zirconates, aluminium glycol Complex compound or two alcohol complex of aluminium/zirconium, and/or a combination thereof.These compositions can further include polyalcohol, preferably glycerine, For example, by weight about 0.1% to about 25% in an amount of from composition, it is more typically by weight about from about 1% to about 10%.These compositions are typically aqueous, but they can be substantially anhydrous or anhydrous.Aquo-composition can be with Containing at least 1% water, but typically by comprising in an amount of from composition by weight from about 20%-95% or from about 50%- The water of 90% (for example, about 60%, 70%, 80% etc.).

The present invention composition can optionally include supplementary element, such as it is following in it is one or more：Emollient, moistening Agent, preservative, chelating agent, antioxidant, solvent, rheology modifier, pH adjusting agent, skin conditioning agent, emulsifier, stabilizer, Film forming agent, sun-screening agent, colorant (for example, pigment, color lake, dyestuff etc.), plant extracts can make composition have skin The other compositions (for example, antibacterial agent, antifungal agent etc.) of function or benefit.

In another aspect of the present invention, a kind of personal care product of packaging is provided comprising：Container, wherein cloth It is equipped with liquid composition according to the present invention；It is applied with the rollon for a certain amount of the composition to be delivered to user's body quilt Dauber.In other embodiments, the personal care product of packaging is provided comprising：Container, wherein accommodating according to the present invention Composition, the composition is in the form of solid or gel；With for the composition to be pushed away from the opening aperture of the container Into device.

To those skilled in the art, by reading following detailed description of the invention (including the attached claims Book), these and other aspects will become obvious.

Specific implementation mode

Unless otherwise stated, all amounts provided with weight percent are both with respect to entire composition.It should be appreciated that The summation of all wt percentage in given combination object will be no more than 100%.Unless otherwise defined, the present composition Any component can be with composition by weight from the amount of about 0.0001% to about 25%, including by weight from about 0.001%-20% or by weight 0.01%-10% or by weight from 0.05%-5% or by weight from 0.1%- 1% amount by comprising.All the components are preferably " physiologically acceptable ", it means that it is used it is horizontal under be safety And it is nonirritant.

The antiperspirant composition of the present invention typically comprises aromatic oil and oil phase.The aromatic oil is usually dissolved or dispersed in the oil Xiang Zhong.The oil phase has the unsaturated fatty acid of low content, and typically will include one or more vegetable triglycerides oil, It is in total with 75% or more the aliphatic acid being made of saturated fatty acid.

Aromatic

The composition of the present invention includes one or more aromatic oil.These aromatic oil typically account for composition by weight From about 0.1% to about 3% (for example, by weight about 0.5%, 1%, 1.5%, 2%, 2.5%).In one embodiment, should One or more aromatic oil individually or in total account for the by weight about 1%-2% or about 1.5% of composition.

Any aromatic oil may be used in the composition of the present invention, such as U.S. Patent Application Publication No. 2013/0280409 Those of described in, which is integrally joined to this by quoting with it.For example, aromatic oil may include any type or A variety of natural material extracts, such as essential oil, concentrate (concrete), absolute oil, resin, balm, face cream, tincture are such as imperial Saliva aromatin tincture, fat wingceltis oil, angelica seed oil, Angelica root oil, oil of badian, valerian oil, basil, tree moss absolute (wood moss Absolute), oreodaphene, wormwood oil, benzoin resin, bergamot oil, Absolute Oil of Beeswax, birch tar oil, almond oil, savoury Oil, cheek oil (bucco-leaf oil), Brazilian sandalwood oil (cabreuva oil), cade oil, calmus oil, camphorated oil, cus-cus Careless oil, cardamom oil, card multitude's oil, cinnamon oil, Chinese cassia tree absolute oil, castoreum absolute oil, cedar leaves oil, cedar wood oil, labdanum oil, lemongrass Oil, lemon oil, copaiba balsam, copaiba fatty oil, coriander oil, costus root oil, ziran oil, Cypress ethereal oil, davana oil, dill oil, Dill seed oil, cloth neglect former smart absolute oil (eau de brouts absolute), Oak Tree tundra essence, elemi oil, estragon oil, lemon Eucalyptus oil, eucalyptus oil, fennel oil, abies oil, galbanum oil, the fluffy resin of lattice, pelargonium oil, oil of grapefruit, guaiac wood oil, gurjun Fat, gurjun balsam oil, strawflower absolute oil, strawflower oil, ginger oil, iris root absolute oil, iris root oil, Jasmine are net Oil, calmus oil, blue Chamomile oil, flores anthemidis oil, carrot seed oil, cascarrilla oil, pinke needle oil, oleum menthae viridis, caraway oil, rock rose Common vetch oil (labdanum oil), labdanum absolute, ladanum resin, lavandin absolute, lavandin oil, lavender absolute, Lavender oil, lemongrass oil, lovage oil (lovage oil), distillation lime oil (distilled lime oil), pressurization Lime oil, linaloe oil, litsea citrate oil, laurel, mace oil, marjoram oil, mandarin oil, massoia bark oil (massoi Bark oil), sensitive plant absolute oil, ambutte-seed oil, Moschus tincture, sage clary oil, mace oil, myrrh absolute oil, myrrh oil, hill gooseberry Oil, clove leaf oil, cloves caul-fat, neroli oil, mastix absolute, frankincense oil, bisabol myrrh oil, the former essence of flores aurantii, orange oil, origanum oil, rose Rare hay-scented oil, patchouli oil, perilla oil, perubalsam oil, parsley leaves oil, parsley seed oil, petit grain oil, mentha piperita oil, recklessly Green pepper oil, allspice oil, pine-tree oil, penner oil, rose absolute, rosewood oil, attar of rose, rosemary oil, Dalmatia mouse Tail grass is oily (Dalmatian sage oil), Oil of Spanish sage, sandalwood oil, celery seed oil, oil of spike, and Japan is octagonal Fennel oil, levant storax oil, tagetes oil, abies oil, tea oil, turpentine oil, thyme essential oil, tolu balsam, tonka-bean absolute oil, evening Fragrant jade absolute oil, vanillon, violet leaf absolute oil, verbena oil, vetiver oil, juniper berry oil, vinasse oil, absinthium, wintergreen, according to Blue oil, root of bidentate achyranthes oil, Moschus oil, cinnamon leaves oil, cassia oil, and its fraction or ingredient from its separation；And combinations thereof.

In addition suitable aromatic, as listed in european patent number EP 2106704B1, including, such as it is following in appoint What is one or more：Hydrocarbon, as 3- carenes, australene, nopinene, α-terpinenes, γ-terpinenes, p-cymene, bisabolene, Amphene, carypohyllene, cedrene, farnesene, limonene, longifolene, laurene, ocimenum, all human relations tangerine alkene (valencene), (E, Z) -1,3,5- hendecane triolefins；

Fatty alcohol, such as hexanol, octanol, 3- octanols, 2,6- dimethyl enanthol, 2- isoocanols, 2- methyl-octanols, (E) -3- Hexanol, (E) and (Z) -3- hexanols, 1- octyl- 3- alcohol, 3,4,5,6,6- pentamethyl -3/4- hept- 2- alcohol and 3,5,6,6- tetramethyls - Mixture, (E, Z) -2,6- nonadienols, 3,7- dimethyl -7- methoxyl group octyl- 2- alcohol, the 9- decene of 4- methylene hept- 2- alcohol Alcohol, 10- undecylenic alcohols, 4- methyl -3- decene -5- alcohol；

Aliphatic aldehyde and its acetal, such as hexanal, enanthaldehyde, octanal, aldehyde C-9, capraldehyde, the hendecanal, lauric aldehyde, tridecylic aldehyde, 2- first Base octanal, 2- methyl aldehyde C-9, (E) -2- hexenoic aldehydes, (Z) -4- heptenals, 2,6- dimethyl -5- enanthaldehyde, the 10- hendecanals, (E) - 4- decenals, 2- laurylenes aldehyde, 11 carbon diene of 2,6,10- trimethyls -5,9-, enanthal diethyl acetal, dimethoxy -2 1,1-, 2,5- trimethyl -4- hexenes, lemongrass ethylhexanal base ether；

Aliphatic ketone and its oxime, such as 2-HEPTANONE, methyln-hexyl ketone, 3- octanones, methyl n-heptyl ketone, 5- methyl -3- heptanone, 5- methyl -3- Heptanone oxime, 2,4,4,7- tetramethyl -6- octyl- 3- ketone；

Aliphatic sulfur-containing compound, such as 3- methyl thios hexanols, the own ester of 3- trimethyl thioacetic acids, 3- sulfydryls hexanols, 3- Sulfydryl hexylacetic acids ester, 3- sulfydryl hexyls butyrates, 3- acyl thiocarbamates hexylacetic acids ester, 1- menthene -8- mercaptan；

Aliphatic nitrile, such as 2- nonenyl nitriles, 2- tridecylenes nitrile, 2,12- tridecylenes nitriles, 3,7- dimethyl -2,6- octadienes Nitrile, 3,7- dimethyl -6- octenes nitriles；

Aliphatic carboxylic acid and its ester, such as formic acid (E)-and (Z) -3- hexene esters, ethyl acetoacetate, isoamyl acetate, second The own ester of acid, the own ester of acetic acid 3,5,5- trimethyls, acetic acid 3- methyl-2-butenes ester, acetic acid (E) -2- hexene esters, acetic acid (E)-and (Z) -3- hexene esters, octyl acetate, acetic acid 3- monooctyl esters, 1-OCOL acetic acid esters (1-octen-3-yl acetate), butyric acid Ethyl ester, butyl butyrate, isoamyl butyrate, n-hexyl butyrate, isobutyric acid (E)-and (Z) -3- hexene esters, the own ester of crotonic acid, isovaleric acid Ethyl ester, 2 methyl valeric acid ethyl ester, ethyl hexylate, allyl hexanoate, cognac oil, allyl heptanoate, ethyl caprilate, (E, Z) -2, 4- decatrienoic acids ethyl ester, methyl 2-octynoate, methyl 2-octynoate, 2- allyl isoamyloxyacetates, methyl -3,7- diformazans Base -2,6- octadienoic acid ethyl esters；

Without cyclic terpene alcohol, such as citronellol, geraniol, nerol, linalool, lavandulol, nerolidol, farnesol, tetrahydrochysene Linalool, tetrahydrogeraniol, 2,6- dimethyl -7- octen-2-ols, 2,6- dimethyl-octa -2- alcohol, 2- methyl -6- methylene -7- Octen-2-ol, 2,6- dimethyl -5,7- octadiene -2- alcohol, 2,6- dimethyl -3,5- octadiene -2- alcohol, dimethyl -4 3,7-, 6- octadiene -3- alcohol, 3,7- dimethyl -1,5,7- sarohornene -3- alcohol, 2,6- dimethyl -2,5,7- sarohornene -1- alcohol；And its Formic acid esters, acetic acid esters, propionic ester, isobutyric acid fat, butyrite, isovalerate, valerate, capronate, crotonic acid, tiglic acid enester (tiglinate), 3- methyl -2- butyrites；

Acyclic terpene aldehyde and ketone, such as geranial, neral, citronellal, 7- hydroxyls -3,7- dimethyl octanal, 7- methoxyl groups - 3,7- dimethyl octanals, 2,6,10- trimethyl -9- undecylene aldehydes, geranyl acetone and geranial, neral, hydroxyl -3 7-, The dimethyl and diethyl acetal of 7- dimethyl octanals；

Cyclic terpene alcohol, such as menthol, isopulegol, alpha-terpineol, terpinol -4, peppermint -8- alcohol, peppermint -1- alcohol, peppermint - 7- alcohol, borneol, different borneol, linalool oxide, nopol, cedrol, imperial saliva alcohol, vetiverol, guaiol and its formic acid esters, second Acid esters, propionic ester, isobutyric acid fat, butyrite, isovalerate, valerate, capronate, crotonates, tiglic acid enester, 3- first Base -2- butyrates；

Cyclic terpene aldehyde and ketone, such as menthones, isomenthone, 8- sulfydryl peppermint -3- ketone, carvol, camphanone, fenchone, α-purple sieve Blue ketone, alpha, beta-lonone, α-n- methylionones, β-n- methylionones, α-daphnone, the different crystal violets of β- Rowland ketone, α-irone, α-damascenone, dorinone, dorinone, δ-damascenone, γ-damascenone, 1- (2,4,4- front threes Base -2- cyclohexene -1- bases) -2- butene-1s -one, 1,3,4,6,7,8a- hexahydro -1,1,5,5- tetramethyl -2H-2,4a- methanol Naphthalene -8 (5H) -one, Nootkatone, dihydronootkatone, α-sinensal, β-sinensal, acetylation parasol pine are oily (vertofix coeur)；

Cyclic alcohol, such as 4- tert. butyl cyclohexanols, 3,3,5- cyclonols, 3- Santalex, 2,6,9- trimethyls- Z2, Z5, E9- cyclodoecatriene -1- alcohol, Florol；

Cycloaliphatic alcohol, such as α -3,3- trimethylcyclohexyls methanol, 2- methyl -4- (2,2, the 3- amyl- 1- yls of trimethyl -3- rings) Butanol, 2- methyl -4- (the amyl- 1- yls of 2,2,3- trimethyl -3- rings) -2- butene-1-ols, 2- ethyls -4- (2,2,3- trimethyls - The amyl- 1- yls of 3- rings) -2- butene-1-ols, 3- methyl -5- (the amyl- 1- yls of 2,2,3- trimethyl -3- rings)-pentane -2- alcohol, 3- first Base -5- (the amyl- 1- yls of 2,2,3- trimethyl -3- rings) -4- amylene -2- alcohol, 3,3- dimethyl -5- (2,2,3- trimethyl -3- rings Amyl- 1- yls) -4- amylene -2- alcohol, 1- (2,2,6- trimethylcyclohexyls) pentane -3- alcohol, 1- (2,2,6- trimethylcyclohexyls) oneself Alkane -3- alcohol；

Cyclic ethers and ring grease ether, such as cineol, cedrol methyl ether, cyclo-dodecyl methyl ether, (ethoxymethyl) epoxide) ring ten Dioxane, α-epoxycedrane, 3a,-ten dihydronaphthalene of 6,6,9a- tetramethyls [2,1-b] furans, 3a- ethyl -6,6,9a- trimethyls Ten dihydros-naphthalene [2,1-b] furans, 1,5,9- trimethyl-13- oxabicyclos [10.1.0] 13-4,8- diene, rose oxide, 2- (2,4- dimethyl -3- cyclohexene -1- bases) -5- methyl -5- (1- methyl-propyls) -1,3- dioxanes；

Cyclic ketones, such as 4- tert-butyls cyclohexanone, 2,2,5- trimethyl -5- amyl cyclopentanones, alismone, 2- amyls Cyclopentanone, the amyl- 1- ketone of 2- hydroxy-3-methyl -2- rings, 3- methyl-cis- 2- amylene -1- base -2- cyclopentene-1-ones, 3- methyl - 2- amyl -2- cyclopentene-1-ones, 3- methyl -4- cyclopentadecylenes ketone, 3- methyl -5- cyclopentadecylenes ketone, 3- methyl cyclopentadecylenes Ketone, 4- (1- ethoxy ethylenes base) -3,3,5,5- tetramethyl-rings hexanone, 4- tert-s anyl cyclohexanone, 5- ring hexadecene -1- ketone, 6, - 4 (5H)-indone of penta methyl of 7- dihydros -1,1,2,3,3-, 17 alkene -1- ketone of 9- rings, cyclopentadecanone, Cyclohexadecanone；

Alicyclic ring aldehyde, such as 2,4- dimethyl -3- cyclohexene formaldehydes (cyclohexenecarbaldehyde), 2- methyl -4- (2,2,6- trimethyl cyclohex alkene -1- bases) -2- crotonaldehydes, 4- (4- hydroxy-4-methyls amyl) -3- cyclohexene formaldehydes, 4- (4- Methyl -3- amylene -1- bases) -3- cyclohexene formaldehydes；

Ring grease ketone, such as 1- (3,3- Dimethylcyclohexyl) -4- amylene -1- ketone, 1- (5,5- dimethyl -1- cyclohexene -1- Base) -4- amylene -1- ketone, 2,3,8,8- tetramethyl -1,2,3,4,5,6,7,8- octahydro -2- naphthyl methyl ketones, methyl -2,6,10- Trimethyl -2,5,9- cyclodoecatriene ketones, tert-butyl (2,4- dimethyl -3- cyclohexene -1- bases) ketone；

Cyclic alcohol ester, such as 2- tert-butyl cyclohexyl-acetic acids ester, 4- butylcyclohexyl yl acetates, 2- tert- pentylcyclohexyl second Acid esters, 4- tert- pentylcyclohexyls acetic acid esters, decahydro -2- naphthyl acetates, 3- amyl tetrahydrochysene -2H- pyrans -4- yl acetates, ten Hydrogen -2,5,5,8a- tetramethyl -2- naphthyl acetates, 4,7- endo-methylene groups -3a, 4,5,6,7,7a- hexahydro -5 or 6- indeneacetic acids Ester, 4,7- endo-methylene groups -3a, 4,5,6,7,7a- hexahydro -5 or 6- indenyls propionic ester, 4,7- endo-methylene groups -3a, 4,5,6,7, 7a- hexahydros -5 or 6- indenyls isobutyrate, 4,7- endo-methylene groups octahydro -5 or 6- indeneacetic acid esters；

Cycloaliphatic carboxylic acid's ester, as 3- allyl cyclohexyl propionates, galbanum oxyacetate, dihydrojasmonate, Methyl jasmonate, 2- hexyl -3- oxo cyclopentanecarboxylic acids methyl esters, 2- ethyl -6,6- dimethyl -2- cyclohexene carboxylates ethyl ester, 2, 3,6,6- tetramethyl -2- cyclohexene carboxylates ethyl ester, 2- methyl-1,3-dioxy heterocyclic pentane -2- ethyl acetate；

Aromatic hydrocarbon, such as styrene and diphenyl methane；

Aromatic grease group alcohol, such as benzylalcohol, 1- benzyl carbinols, 2 phenylethyl alcohol, 3- phenylpropanols, 2- phenylpropanols, 2- Phenoxyethanols, 2,2- bis- Methyl -3- phenylpropanols, 2,2- dimethyl -3- (3- aminomethyl phenyls) propyl alcohol, 1,1- dimethyl -2 phenylethyl alcohol, 1,1- dimethyl -3- Phenylpropanol, 1- ethyl -1- methyl -3- phenylpropanols, 2- methyl -5- phenylpropanols, 3- methyl -5- phenylpropanols, 3- phenyl -2- propyl-s 1- Alcohol, 4- methoxyl groups benzylalcohol, 1- (4- isopropyl phenyls) ethyl alcohol；

The ester of aromatic aliphatic alcohol and aliphatic carboxylic acid, such as benzyl acetate, benzyl propionate, benzyl isobutyrate, benzyl isovalerate, second Sour 2- phenethyl esters, propionic acid 2- phenethyl esters, isobutyric acid 2- phenethyl esters, isovaleric acid 2- phenethyl esters, acetic acid 1- phenethyl esters, acetic acid α-trichlorine Methyl benzyl ester, acetic acid alpha, alpha-dimethyl phenethyl ester, butyric acid alpha, alpha-dimethyl phenethyl ester, cinnamyl acetate, isobutyric acid 2- phenoxy groups Ethyl ester, acetic acid 4- methoxy benzyl esters；Aryl aliphatic ethers, such as 2- phenethyls methyl ether, 2- phenethyls isoamyl ether, 2- phenethyls 1- ethoxyethyl groups ether, phenylacetaldehyde dimethyl acetal, phenylacetaldehyde diethyl acetal, hydratropaldehyde dimethylacetal, phenylacetaldehyde glycerol acetonide Aldehyde, 2,4,6- trimethyl -4- phenyl -1,3- dioxanes, 4,4a, 5,9b- tetrahydroindenes [1,2-d]-m- bioxin, 4,4a, 5,9b- Tetrahydrochysene -2,4- dimethyl indenes [1,2-d]-m- bioxin；

Aromatics and aromatic aliphatic aldehyde, such as benzaldehyde, phenylacetaldehyde, 3-phenylpropion aldehyde, hydratropaldehyde, 4- tolyl aldehydes, 4- Methyl phenylacetaldehyde, 3- (4- ethylphenyls) -2,2- dimethyl propionic aldehyde, 2- methyl -3- (4- isopropyl phenyls) propionic aldehyde, 2- methyl - 3- (4- tert-butyls phenyl) propionic aldehyde, 3- (4- tert-butyls phenyl) propionic aldehyde, cinnamic acid, α-butylcinnamaldehyde, jasminal, Jasmonal H, 3- methyl -5- phenyl valeral, 4-methoxybenzaldehyde, 3-methoxy-4-hydroxybenzaldehyde, 4- hydroxyls -3- 3,4- methylenedioxybenzaldehydes, 3,4- Dimethoxy-benzaldehydes, 2- methyl -3- (4- methoxyphenyls) propionic aldehyde, 2- first Base -3- (4- methylenedioxyphenyls base) propionic aldehyde；

Aromatics and aromatic aliphatic ketone, such as acetophenone, 4- methyl acetophenones, 4- methoxyacetophenones, 4- tert-butyls -2,6- Dimethyl acetophenone, 4- Phenyl 2 butanones, 4- (4- hydroxyphenyls) -2- butanone, 1- (2- naphthalenes) ethyl ketone, Benzophenone, 1,1,2,3, 3,6- hexamethyl -5- indanes methyl ketone, 6- tert-butyl -1,1- dimethyl -4- indanes methyl ketone, 1- [dihydro -1,1,2 2,3-, 6- tetramethyls -3- (1- Methylethyls) -1H-5- indenyls] ethyl ketone, 5', 6', 7', 8'- tetrahydrochysenes -3', 5', 5', 6', 8', 8'- six Methyl -2- acetonaphthones；

Aromatics and aromatic aliphatic carboxylic acid and its ester, such as acid, phenylacetic acid, methyl benzoate, ethyl benzoate, hexyloxy benzoic acid Ester, Ergol, methyl phenylacetate, ethyl phenylacetate, geranyl phenyl acetate, phenylethyl phenylacetate, methyl cinnamate, Chinese cassia tree Acetoacetic ester, benzyl cinnamate, phenylethyl cinnamate, cinnamyl cinnamate, allyl phenoxyacetate, gaultherolin, salicylic acid Cis- -3- the hexene esters of isopentyl ester, 1-Hexyl salicylate, salicylate cyclohexyl ester, salicylic acid, benzyl salicylate, phenylethyl salicylate, 2, 4- dihydroxy -3,6- dimethylbenzoate methyl esters, 3- ethyl phenylglycidates, 3- methyl -3- ethyl phenylglycidates；

Nitrogenous aromatic compounds, such as 2,4,6- trinitro- -1,3- dimethyl -5- tert-butyls benzene, 3,5- dinitros -2,6- Dimethyl -4- tert-butyls acetophenone, cinnamonitrile, 5- phenyl -3- methyl -2- allyl acetonitriles, 5- phenyl -3- methyl valeronitrile, adjacent amino The seat of methyl benzoate, N- methyl anthranilic acids methyl esters, methyl anthranilate and 7- hydroxyl -3,7- dimethyl octanals Husband's alkali, 2- methyl -3- (4- tert-butyls phenyl) propionic aldehyde or 2,4- dimethyl -3- cyclohexene formaldehydes, 6- isopropyl quinolines, 6- are different Butyl quinoline, 6- sec-butyls quinoline, indoles, methyl indol, 2 methoxy 3 isopropyl pyrazine, 2- isobutyl group -3- methoxyl groups Pyrazine；

Phenol, phenyl ether and phenylester, as chavicol methyl ether, anethole, eugenol, eugenol methyl ether, isoeugenol, isobutyl are fragrant Phenol methyl ether, Thymol, carvacrol, diphenyl ether, β-naphthol methyl ether, bromelia, β-naphthalene isobutyl ether, 1,4- dimethoxy benzenes, Acetyl eugenol, 2- methoxyl group -4- cresols, 2- ethyoxyls -5- (1- acrylic) phenol, p-cresyl phenylacetate；

Heterocyclic compound, such as 2,5- dimethyl -4- hydroxyl -2H- furans -3- ketone, 2- ethyl -4- hydroxy-5-methyl bases -2H- Furans -3- ketone, 3- hydroxy-2-methyl -4H- pyrans -4- ketone, 2- ethyl -3- hydroxyl -4H- pyrans -4- ketone；And

Lactone, such as Isosorbide-5-Nitrae-caprylolactone, 3- methyl-1s, 4- caprylolactones, Isosorbide-5-Nitrae-nonalactone, Isosorbide-5-Nitrae-decalactone, 8- decylene-1s, 4- Lactone, 1,4- hendecoic acids lactone, 1,4- lauric acids lactone, 1,5- decalactones, 1,5- dodecalactones, 1,15- omega-pentadecanolides, 15 carbene -1,15- lactones of cis and trans -11-, 15 carbene -1,15- lactones of cis and trans -12-, in 1,16- 16 Ester, 9- hexadecene -1,16- lactones, 10- oxa- -1,16- hexadecanolides, 11- oxa- -1,16- hexadecanolides, 12- oxa-s - 1,16- hexadecanolides, 1,12 dodecanedioic acid vinyl acetate (ethylene1,12-dodecanedioate), 1,13- tridecanes Two vinyl acetates, cumarin, 2,3- dihydrocoumarin, octahydrocoumarin.

Other suitable aromatic oil are U.S. Patent Application Publication No.s 2012/0107529 and 2013/0202788, Yi Jimei Those of listed in state's patent No. 7,294,612, these patents are integrally joined to this by quoting with it.

The composition of the present invention can also be configured to provide the anthelmintic composition of extended release expelling parasite oil.These compositions Can include any one or more expelling parasite oil, including, such as lemongrass, the essential oil of Catnip and lavender, chinaberry seeds oil and big Soya-bean oil.Other suitable expelling parasite oil are PCT Application Publication WO/2003013243, U.S. Patent number 8,501,205 and the U.S. Those of listed in published application number 2013/0084347, these patents are integrally joined to this by quoting with it.These Including but not limited to：Lemongrass oil, French geranium oil, eucalyptus citriodora oil and litsea citrate oil, camphorated oil, mineral oil and geranium oil.Such as Used herein, term " aromatic oil " is intended to include expelling parasite oil.

Oil phase

Antiperspirant composition also include oil phase, amount typically by weight from about 0.1% to about 20%, more typically from About 1% to about 10%, or from about 2% to about 8%.The oil phase has the unsaturated hydrocarbons of low content.The oil phase typically comprises one Kind or various plants triglyceride oil, in total have 75% or more, 80% or more, 85% or more, 90% or more, Or 95% or more be saturated fatty acid aliphatic acid.In one embodiment, which includes by weight from about 2%- Such one or more vegetable triglycerides with higher unsaturated fatty acid content of 6% (for example, by weight about 4%) Oil.In one embodiment, which includes coconut oil and/or palm-kernel oil, rather than conventional sunflower oil.Implement at one In example, at least 50%, at least 60%, at least 70%, at least 80%, at least 90%, at least 95% or at least 98% oil phase It is made of coconut oil and/or palm-kernel oil.

Surprisingly it has been found that with the vegetable glycerides three in total with the saturated fatty acid less than 75% are included The composition of ester oil (for example, sunflower oil) is compared, including in total with 75% or more saturated fatty acid and with low water The oil phase of flat unsaturated fatty acid or one or more vegetable triglycerides oil without unsaturated fatty acid is in storage Significantly more longlasting fragrance is provided.While not wishing to bound by theory, it is believed that with the oil phase ratio containing a large amount unsaturated fatty acid, Double key number is less in HI SA highly saturated oil (such as coconut oil) keeps free radical smaller to the sensibility of autoxidation.For antiperspirant In conventional oil, sunflower oil, by about 25% monounsaturated fatty acids chain and about 60% polyunsaturated fatty acid chain (i.e. 85% unsaturated fatty acid content) is constituted.It is believed that such triglyceride oil is subjected to thermocatalytic autoxidation.Think automatic Oxidation process carried out by free radical chain mechanism and generate propagate the process be more than oxide (hyper-peroxide) and its His free radical.More than peroxide breaks down and aldehyde and ketone are formed, the fragrance intensity for changing fragrance characters, blockading perception, and in base Stink is generated in matter.It is believed that heavy metal and other ultimate constituents accelerate this process.On the other hand, coconut oil has the saturated fat of a large amount Fat acid (i.e. 75% or more saturated fatty acid).It is believed that such oily autoxidation to free radical with less double bond is less It is sensitive.

Typically, the content of fatty acid of oil phase includes at least 75% (or at least 80%, 85%, 90%, 95% or 98%) The aliphatic acid with C16 or less chain lengths.Substantially, with the aliphatic acid with the chain length for being longer than C16 with high-content Those of compare, many naturally occurring triglycerides of the C16 or less aliphatic acid with high-content are with relatively low Degree of unsaturation.In some embodiments, the oil phase of these compositions include less than 5%, 4%, 3%, 2%, substantially free of (i.e. Be less than by weight 1%) or without the oil with quite high unsaturated fatty acid content (be more than 25%), as sunflower oil, Sunflower oil, rapeseed oil, corn oil, cottonseed oil, linseed oil, olive oil, safflower oil, soybean oil, canola oil, peanut oil, sesame Sesame oil, apricot kernel oil, castor oil, and combinations thereof.

Be present in the present composition this it is one or more have higher unsaturated fatty acid content (i.e. 75% or more) Vegetable triglyceride oil can advantageously provide such as skin moisture-keeping, mitigate antiperspirant composition residual antiperspirant actives substance leave Whitening effect, reduce skin irritatin and/or darkening, and the benefit of the balanced colour of skin.

In some embodiments, the aliphatic acid in addition to those of discovery aliphatic acid in vegetable oil can also be added to In composition.The example of such other aliphatic acid includes but not limited to stearic acid, octanoic acid, lauric acid, myristic acid, palm Acid, arachidic acid, mountain Yu acid, lignoceric acid or cerinic acid.However, comprising such other aliphatic acid, amount will be group That closes object is less than 6%, 5%, 4%, 3%, 2% or 1% by weight.In some embodiments, composition substantially free of (that is,<1%) or without such other aliphatic acid.

Antiperspirant actives substance

The composition can also include one or more antiperspirant actives substances.Preferably, one or more antiperspirant actives Substance is based on aluminium salt or based on aluminium/zirconates.The example of suitable antiperspirant reagent includes aluminium chloride, aluminum sulfate, hydration chlorine Change aluminium, trichloride hydrate aluminium zirconium (aluminum zirconium trichlorohydrate), hydrated aluminum tetrachloride zirconium, hydration Phosphoric aluminium zirconium, and eight aluminium chloride zirconium alkali formula aluminium bromides of hydration, zirconyl chloride；Zirconyl hydroxide；Aluminium hydroxide, zirconyl chloride and Chloride hydrate oxygen zirconium (zirconyl chlorohydrate) complex compound of aluminium chlorohydrate；Aluminium hydroxide, chloride hydrate oxygen zirconium, With the complex compound of aluminium chlorohydrate；The complexing of basic aluminium glycinate, zirconyl chloride and/or chloride hydrate oxygen zirconium and aluminium chlorohydrate Object；The complex compound of zirconyl chloride and/or chloride hydrate oxygen zirconium (zirconyl clhorohydrate) and aluminium chlorohydrate；Chlorination The complex compound of oxygen zirconium and/or chloride hydrate oxygen zirconium and aluminium chlorohydrate and amino acid such as glycine；Or combinations thereof.In the present invention Antiperspirant actives substance can also include the aluminum chloride complex with urea.In addition, one or more antiperspirant actives substances can wrap It includes calcium chloride and/or other metal halide salts of body perspiration can be reduced.Preferably, antiperspirant actives substance is chloride hydrate Aluminium zirconium complex is such as hydrated tetrachloro aluminium zirconium and hydration pentachloro- aluminium zirconium.It is highly preferred that such complex compound and glycine combination (for example, It is hydrated trichlorine aluminium zirconium-glycine, hydration tetrachloro aluminium zirconium-glycine, hydration pentachloro- aluminium zirconium-glycine, hydration eight chlorine aluminium zirconiums-sweet ammonia Acid).

Typically, the amount of antiperspirant actives substance be from about 1% to about 25%, from about 5% to 25%, from about 5% to 15%, or from about 10% to 25%, which measures as anhydrous solid.When composition includes aluminium When antiperspirant actives substance, amount is preferably from 5% to 25%.When composition includes aluminium zirconium antiperspirant actives substance, deposit In amount preferably from about 5% to 20%.In one embodiment, the weight based on anhydrous aluminium zirconium, at least one aluminium zirconium hidroschesis are lived Property substance amount be 5%-15% by weight.

Emulsifier

The present invention can further include one or more suitable emulsifiers.Typically, the one or more emulsifying agents Amount separately or cooperatively be based on composition weight by weight from about 0.1% to 10% (for example, about 0.5%, 1%, 2%, 3%, 4%, 5%, 6% or 7%).The one or more emulsifying agents can be ionic, amphoteric ion or nonionic 's.Suitable emulsifier includes those of polyethoxylated type (such as polyethenoxy ether class or esters), polydiorganosiloxanepolyamide Alkane-polyoxyalkylene block copolymer (such as dimethicone copolyols), stereth (Steareth) -20, stearyl alcohol are poly- Ether -21, aliphatic alcohols (such as cetostearyl alcohol), polyoxyethylene sorbitan fatty acid ester class (i.e. polysorbate esters) and Rilanit special names just a few.Other emulsifier is provided in INCI Ingredient Dictionary and Handbook In 11th Edition 2006 [INCI Ingredient Dictionaries and handbook, the 11st edition 2006], the disclosure of which is hereby incorporated by reference This.Emulsifier can have high or low HLB.In a preferred embodiment, the composition includes between respectively having 3-17 The combination of the nonionic emulsifier (it is in such ratio, that is, so that final HLB is between 6-12) of HLB.At one In embodiment, the amount of the one or more emulsifying agents is 1%-5% by weight.In another embodiment, composition Including in an amount of from the low HLB emulsifier (i.e. HLB value is 1-6) of 0.1%-5% by weight, and in an amount of from 0.1%- by weight 5% high HLB emulsifier.

Polyalcohol

The composition of the present invention typically comprises polyalcohol, such as in an amount of from composition by weight from about 1% to about 20%, or from about 2% to about 15%, more typically in an amount of from composition by weight from about 2% to about 5%.In a reality It applies in example, polyalcohol (such as glycerine) will account for the by weight about 3%-5% of composition.To contain being suitble in the composition Polyalcohol includes but not limited to C_2-6Polyalcohol, as ethylene glycol, propylene glycol, butanediol, hexylene glycol, D-sorbite, diethylene glycol, And glycerine.In one embodiment, polyalcohol includes glycerine.Composition can also include wetting agent (in addition to polyalcohol), such as Polyalcohols (such as glycol), including but not limited to glycerine, propylene glycol, ethoxydiglycol, butanediol, pentanediol, hexylene glycol, Ethohexadiol etc..These being added from the amount of about 0.001% to about 5% by weight with such as composition.

Alcohols

In one embodiment, composition of the invention can be free from alcohol or substantially free of alcohol.

In other embodiments, composition of the invention typically can also include alcohol (for example, fatty alcohol), such as its amount For from about 0.1% to about 5%, or more typically account for composition by weight from about 1% to about 5%.In one embodiment, Alcohol accounts for by weight about the 1% of composition.Any alcohol may be used in the composition of the present invention, but preferably the alcohol is C_6-24 Fatty alcohol, such as or mixtures thereof stearyl alcohol, cetanol.

The weight ratio of polyalcohol and alcohol typically will be from about 10:1 to about 1:5 or about 5:1 to about 1:2, about 4:1 to about 1:2, from about 3:1 to about 1:1 or from about 2:1 to about 1:1.Preferably, the weight ratio of polyalcohol and alcohol will be 4:1.

Film forming agent

These compositions can include natural or synthetic film forming polymer, to assign benefit such as humidity condition.It is suitable The polymer film-forming agent of conjunction includes polyolefin, silicone polymer (such as dimethicone, polydimethylsiloxanes alcohol (dimethiconol), ammonia end dimethyl silicone polymer (amodimethicone), silicone resin etc.), (methyl) acrylate, Alkyl (methyl) acrylate, polyurethanes, fluoropolymer, silicone polyurethanes and Silicone acrylates, such as Acrylate/dimethyl silicone copolymer.In some embodiments, it may be desirable to add hydrophily or water-soluble into composition Property film forming agent (for example, cellulose, polysaccharide, polyquaternium (such as polyquaternium -37 (INCI)) with improve sprawl, emulsion-stabilizing Property, aesthetic appearance and feeling etc..The elastomer formed by ethylene, propylene, butylene, and/or styrene monomer can also be useful 's.Typically, the amount of film forming agent be composition by weight from about 0.0001% to about 25%, including by weight from About 0.001%-20% or by weight 0.01%-10% or by weight from 0.05%-5% or by weight from The amount of 0.1%-1%.

Colorant and filler

Composition can further include one or more colorants or filler.Suitable colorant and filler includes as contaminated Those of material, pigment and color lake.As used herein, term " pigment " includes color lake and filler, such as talcum, calcium carbonate.Example Property inorganic pigment includes but not limited to inorganic oxide and hydroxide, as magnesia, magnesium hydroxide, calcium oxide, calcium hydroxide, Aluminium oxide, aluminium hydroxide, iron oxide (α-Fe₂O₃、γ-Fe₂O₃、Fe₃O₄, FeO) and iron hydroxide (including iron oxide red, oxidation Iron oxide yellow and iron oxide black), titanium dioxide, the protoxide of titanium, zirconium oxide, manganous hydroxide, chromium oxide, chromium hydroxide, oxidation Manganese, cobalt oxide, cobalt hydroxide, cerium oxide, cerium hydroxide, nickel oxide, nickel hydroxide, zinc oxide and zinc hydroxide and compound Oxide and complex hydroxide (such as iron titanate, cobalt titanate and cobalt aluminate).Inorganic oxide particles can be selected from such as two Silica, aluminium oxide, zinc oxide, iron oxide and titanium dioxide granule and its mixture.However, it is preferable that the pigment of selection It does not include mica.

In addition exemplary color additive color lake includes, such as：The red No.19 of D＆C (such as CI 45170, CI 73360 Or CI 45430)；The red No.9 of D＆C (CI 15585)；The red No.21 of D＆C (CI 45380)；D＆C oranges No.4 (CI 15510)；D&C Orange No.5 (CI 45370)；The red No.27 of D＆C (CI 45410)；The red No.13 of D＆C (CI 15630)；Red No.7 (the CI of D＆C 15850:1)；The red No.6 of D＆C (CI 15850:2)；D＆C Huangs No.5 (CI 19140)；The red No.36 of D＆C (CI 12085)；D＆C oranges No.10(CI 45475)；D＆C Huangs No.19 (CI 15985)；The red #40 of FD＆C (CI#16035)；FD＆C indigo plants #1 (CI#42090)； FD＆C Huangs #5 (CI#19140)；Or any combination thereof.

The amount of colorant and filler in the composition can be composition by weight from about 0.0001% to about 25%, including by weight from about 0.001%-20% or 0.01%-10% by weight or by weight from 0.05%- 5% or by weight from the amount of 0.1%-1%.

Carrier

Composition can further include acceptable carrier on any suitable cosmetics, in an amount of from by weight from about 1% to 99% or from about 50% to 90%, from about 60% to 90%, from about 70% to 90% or from about 80% to 90%.

Composition can be anhydrous, substantially anhydrous, or can include water." substantially anhydrous " means not to group Close in object and intentionally add water, and only include typically with the water of the relevant those amounts of material composition (for example, due to glycerine and The hygroscopic nature of alcohol).More typically, these compositions are aqueous and include the water for being enough to prepare the amount of the composition.

Can use other cosmetics on or medium acceptable in dermatology, such as ethanol vehicle, silicone (example Such as, cyclomethicone, dimethicone etc.), hydrocarbon (for example, vaseline, Permethyl 99A etc.), ester oil (myristic acid Isopropyl ester, myristyl myristate) etc..Medium can be anhydrous and can include oil, such as dimethicone, hydrocarbon (such as Permethyl 99A), vaseline, ester oil etc..The medium can further include emulsifier, gelling agent, construction agent, rheology Conditioning agent (such as thickener), film forming agent etc..The medium may be at the shape of such as slurries, emulsifiable paste, lotion, gel or stick Formula, and may include lotion (for example, Water-In-Oil, oil-in-water, silicone Bao Shui, water packet silicone, silicone polyol, polyalcohol Packet silicone emulsion etc.), or may include aqueous or medium can account for composition by weight from about 25% to about 99%.

Emollient

Composition can further include one or more emollients, such as ester oil, hydrocarbon ils, silicone oil.Suitable emollient Including ether, isopropyl myristate, vaseline, isopropyl lanolate, polydimethyl siloxane oil, polymethyl siloxane oil, Ester oil, mineral oil, thylhexoic acid spermaceti base ester, isopropyl isostearate, dimerized linoleic acid diisopropyl ester (diisopropyl Dimer dilinoeate), hydrocarbon ils or its any mixture.Any emollient may be used in the composition of the present invention, such as U.S. Patent number 8,545,821 and 8, those of described in 580,283, these patents are integrally joined to this by quoting with it. The amount of emollient be composition by weight from about 0.1% to 25%, from about 0.1% to 10% or from about 0.1% to 1%.In one embodiment, composition contains the emollient of 1%-3% amounts.

Preservative

Conventional use of one or more preservatives may be embodied in composition in cosmetics/personal care field.It is excellent Selection of land, family (for example, benzalkonium chloride, cetrimonium chloride, benzethonium chloride etc.) of the preservative from quaternary ammonium salt.This is one or more anti- Rotten agent there are total amount can be total composition by weight from about 0.01% to about 0.1%.

Antioxidant

Composition can include any antioxidant conventionally used for cosmetic field, will not make aromatic oil and composition Other compositions separation or otherwise give composition stink.The example for the antioxidant that can be used in the present composition Include the compound with phenolic hydroxyl group functional group, such as ascorbic acid and its derivative/ester；Beta carotene；Catechin；Curcumin； Ferulic acid derivative (for example, ferulic acid ethyl ester, sodium ferulate)；Gallic acid-derivate (for example, propylgallate)；Tomato Red pigment；Reductic acid；Rosmarinic acid；Tannic acid；Tetrahydro curcumin；Tocopherol and its derivative；Uric acid；Butylated Hydroxytoluene (BHT) or Its any mixture.Other suitable antioxidants be with reduction or non-reduced form one or more thiol functionalities (- Those of SH), such as glutathione, lipoic acid, thioacetic acid, thio-2 acid and other sulfhydryl compounds.Antioxidant can be with Be it is inorganic, as bisulfites, metabisulfite, sulphite or other include the inorganic salts and acid of sulphur.Preferably, resist Oxidant includes at least one cyclic annular (i.e. aryl) ring.The composition of the present invention can include the composition total weight from about 0.001% to about 0.20% or from the antioxidant of about 0.001% to about 0.1%.In one embodiment, the composition is basic On not with or without antioxidant.In another embodiment, the composition substantially free of or be free of antioxidant BHT. In another embodiment, the composition can contain metal ion chelation agent, such as EDTA.

Other optional member

Composition can also optionally include it is following in it is one or more：Anti-allergic agent, antifungal agent, preservative, anti-thorn Swash agent, anti-inflammatory agent, antimicrobial (for example, methylchloroisothiazandnone, methylisothiazolinone, methyl p-hydroxybenzoate, Propylparaben, Phenoxyethanol or ethohexadiol), antibacterial agent and analgesic, in an amount of from composition total weight from about 0.001 weight % to about 20 weight %.

May include sun-screening agent to protect the skin from the damage of ultraviolet light.In one embodiment, sun-screening agent is by making The protection of both UVA and UVB are provided with the combination of single sun-screening agent or sun-screening agent.There is Avobenzene benzene in suitable sun-screening agent Ancestor, cinnamic acid derivative (such as cinnamic acid octyl methoxyl base ester), octyl salicylate, Oxybenzone, octocrylene, two Titanium oxide, zinc oxide or its any mixture.Sun-screening agent can depositing from about 1% to about 30% by weight with total composition .

Other suitable components include providing those of prevention or treatment benefit reagent to skin.It can be with specifically mentioned α-hydroxyl Acid, β-hydroxy acid, ascorbic acid or vitamin C and its derivative (such as its C₁-C₈Ester)；Retinoid, such as retinol (vitamin ) and its ester (such as C A₁-C₈Ester, such as palmitate) and hyaluronic acid.

The composition of the present invention can optionally include any other skin used in antiperspirant composition or other are beautiful Hold beneficial agent.For example, composition can include optical modifier particle (such as soft focus particle), wax, vegetable oil, ester and fat Alcohol/aliphatic acid, skin penetration enhancer, conditioner, active material (such as plant extracts etc.) solvent；Pulvis and filler；Skin Plentiful dose of skin (such as palmityl oligopeptide), wetting agent (such as polyalcohol, including propylene glycol, glycerine etc.)；Vitamin and Wei Sheng Plain derivative (such as ascorbic acid, tocopherol, ascorbic acid monopalmitate, tocopherol acetate, tocopheryl palmitate Deng)；Alpha-hydroxy acid (such as glycolic), β-hydroxy acid (such as salicylic acid)；Retinoid (for example, retinoic acid, all-trans retinoic acid, Retinene, retinol and retinyl ester such as acetate or palmitate)；Other aging ingredients (such as collagen stimulation Agent, collagenase inhibitors, elastatinal)；Depigmenting agent (such as TDPA, hydroquinone, kojic acid etc.)；Exfoliator (such as glycolic, 3,6,9- trioxa heneicosanedioic acids etc.)；Estrogen synzyme stimulus compound (such as caffeine and derivative Object)；It can inhibit the active compound of 5α-reductase (for example, leukotrienes, linoleic acid, Finasteride and its mixture)；With Barriers function reinforcing agent is (for example, ceramide, glyceride, cholesterol and its ester, Alpha-hydroxy and ω-hydroxy fatty acid and its ester Deng) and pH adjusting agent (citric acid, ethanol amine, sodium hydroxide etc.), excipient, emulsifier, antioxidant, surfactant, at Film, chelating agent, gelling agent, thickener, emollient, wetting agent, moisturizer, minerals, viscosity and/or rheology modifier are prevented It shines agent, keratolytic, depigmenting agent, retinoid, hormonal compounds, alpha-hydroxy acid, 2-ketoacid, anti-mycobacteria agent, resist Epiphyte pharmaceutical, antimicrobial, antivirotic, analgesic, lipid compounds, anti-allergic agent, H1 or H2 antihistaminics, anti-inflammatory agent, Counter-stimulus, antitumor agent, immune-system enhancers, immune system suppressants, anti-acne agents, anesthetic, preservative, expelling parasite Agent, skin cooling compound, Derma-Guard, skin penetration enhancer, lubricant, aromatic, colorant, coloring agent, pigment Desalinate agent (hypopigmenting agent), preservative, stabilizer, medicament, light stabilizer and its mixture, names just a few. The amount of these different materials is in cosmetics/personal care field conventionally used for realizing that it is intended to those of purposes, such as it May be constructed composition total weight by weight from about 0.001% to about 20%.

In some embodiments, composition can optionally include that hair minimizes active material (hair minimizing active).The example that suitable hair minimizes active material includes but not limited to hydrolytic soya bean protein, salicylic acid, witch hazel Extract, extract of willow bark, or combinations thereof.Hair minimizes the amount of active material in the composition typically by weight Gauge is from about 0.001%-5%.

In some embodiments, these compositions can optionally include skin lightening agent, as thio-2 acid (TDPA), Dilauryl-TDPA, citric acid, alpha-hydroxy acid, kojic acid, ascorbic acid or its ester derivant；Hydroquinone and glutathione；It plants Object extract is (for example, Stenoloma chusana (Stenoloma chusana), Nuo Li (Morinda citrifolia), Radix Glycyrrhizae (licorice), glycyrrhiza glabra (Glycyrrhiza glabra), ursin, black bearberry, chlorella extract, extractive of perilla and Coconut fruit extract) or other brighteners, such as that described in U.S. Patent Application Publication sequence number 2004/0126344 (patent application is integrally joined to this with it for all purposes) and its derivative and combination a bit.Typically, skin lightening The amount of agent is composition by weight from about 0.0001%-20%.

The composition of the present invention can optionally include typically to live with relevant other of cosmetics and personal care product Property and non-active ingredient, including but not limited to excipient, filler, emulsifier, antioxidant, surfactant, film forming agent, chelating Agent, gelling agent, thickener and emollient.Either individually or collectively total amount can for these other optional active and inactive ingredients Think composition by weight from about 0.001%-20%.

Other suitable additives include metal-chelator, such as EDTA or its salt, in an amount of from composition by weight from About 0.01% to 0.5%.

In one embodiment, composition is in the form of the liquid for being suitable as rollon antiperspirant.In another reality It applies in example, the viscosity that composition has at 25 DEG C is 2,000-20,000cps or from 5,000-10,000cps or from 6,000- 7,000cps。

In some embodiments, composition of the invention is transparent or translucent gels forms.Composition can be adopted With semisolid, not flowable or flowable gel form.In other embodiments, composition of the invention can be formulated At emulsifiable paste, foaming agent, stylus or spray.

The composition of the present invention can be used for any suitable antiperspirant composition, including but not limited to emulsifiable paste, gel, deodorization Agent etc. is especially used for local application.

With containing it is one or more in total having less than 75% saturated fatty acid vegetable triglycerides oil at other The identical composition of aspect is compared, and composition of the invention can retain fragrance in storage through the longer period.The present invention Composition for being applied to mankind's integumental system, including skin, lip, first, hair and other keratin surfaces.Such as this paper institutes With term " keratin surface " refers to the part containing keratin of mankind's integumental system comprising but it is not limited to mammal, excellent The skin (such as oxter) of class of choosing, lip, hair (including eyebrow and eyelashes, hair of scalp, facial hair and chaeta such as arm, leg Hair etc.) and first (toenail, finger nail, cuticula etc.)

The composition can be often applied as needed to assign antiperspirancy performance desired by skin.Combination according to the present invention The durability period that the extended release of aromatic oil is persistently grown may be implemented in object, such as from about 1 to about 48 hour, from about 1 to about 24 hour or From about 1 to about 12 hour.

Composition according to the present invention can be suitably packaged in container, which is equipped to deliver the composition To skin.The composition can be in the liquid with the rheological characteristic and viscosity for being suitable for being used together with rollon applicator Form, wherein the composition are transmitted to skin by the reservoir out of container such as rotatable ball, porous material.The present invention's In another embodiment, a kind of personal care product of packaging is provided comprising：Container, wherein being disposed with according to the present invention Liquid composition；With the rollon applicator for a certain amount of the composition to be delivered to user's body quilt, the rollon Applicator is attached to the container and is contacted with the liquid in reservoir.In other embodiments, the individual of packaging is provided Care product comprising：Container, wherein accommodating composition according to the present invention, the composition is in the form of solid or gel； With the device (for example, rotatable screw arbor assembly) for promoting the composition from the opening aperture of the container.

Example

Example 1

Two kinds of compositions are prepared according to the formula in table 1.Each formula is identical, the difference is that reference composition includes By weight 4% sunflower oil (being the content of fatty acid of unsaturated fatty acid with wherein 85% or more) (sample A), and The coconut oil that the present composition includes by weight 4% (is the aliphatic acid of saturation with wherein 75% or more aliphatic acid Content).(sample B).

Table 1

Sample A and B are stored under 4.4 DEG C (40 °F) as a contrast, and are stored under 43 DEG C (110 °F) as acceleration Condition.The third composition of the antioxidant of additional 0.1% weight of identical component of composition A (sunflower oil) will be included Storage is under the same conditions.Behind one month, two months and trimestral accelerating storage phase, these compositions are applied to skin Skin, and the fragrance characters and intensity of each sample by the group assessment of three aromatic experts, three kinds of compositions.Assess model It encloses extremely to perceive 1 point (worst) less than fragrance from 10 points (best) perceiving original fragrance characters and intensity completely.Median 5 It is designated as " being subjected to " or " passing through ".Table 2 is shown by using coconut oil in antiperspirant composition rather than sunflower oil The unexpected benefit realized.

Table 2

As shown in table 2, match made of the fragrance characters of the control formula made of sunflower oil and intensity ratio coconut oil Side degrades faster.Sample A (sunflower oil) becomes unacceptable between storage one and two months, and in storage three Almost without fragrant trace after month.In contrast, sample B (coconut oil) remains acceptable fragrance when storing three months. In addition, after storage one month, the degradation of the sample A fragrance characters observed is not through comprising antioxidant (i.e. sample Product C) and it is retarded.On the contrary, the antioxidant becomes physically not when causing to impinging upon between accelerating storage one and two months Stablize.

Other sample formulations that can be within the scope of the present invention are as follows：

Ingredient
		Glycerine	4
Low HLB emulsifier (1-6)	2.772
		High HLB emulsifier	0.9
Emollient ether	1.65
		Coconut oil	4
Sunflower oil	0
		Aluminium zirconium active material (anhydrous)	10.25
Preservative	0.05
		Alcohol	0-1
Metal ion chelation agent (EDTA)	0-1
		Aromatic A	1.5
	Water is supplied to 100

It is described herein and is not limited by specific embodiment disclosed here in range with claimed invention, because these Embodiment is intended to illustrate several aspects of invention.Any equivalent integers expection is within the scope of the present invention.In fact, In addition to those of shown here and description, different modifications of the invention are retouched from aforementioned for those of ordinary skills It states and will be apparent.Such modification, which is also intended to, to be fallen within the scope of the appended claims.All publications incorporated herein It is hereby incorporated by with its entirety by quoting.

Claims (20)

1. a kind of antiperspirant composition, which is characterized in that the fragrance characters of reduction over time and loss of strength, the hidroschesis group It includes one or more aromatic oil being dispersed in oil phase to close object, and the oil phase includes one or more triglyceride oils, wherein The triglyceride oil is in total at least 75% saturated fatty acid content.

2. antiperspirant composition as described in claim 1, wherein the triglyceride oil is in total at least 85% saturated fat Fat acid content.

3. antiperspirant composition as described in claim 1, wherein the triglyceride oil is in total at least 90% saturated fat Fat acid content.

4. antiperspirant composition as described in claim 1, wherein the content of fatty acid of the triglyceride oil includes at least 75% The aliphatic acid with C16 or less chain lengths.

5. antiperspirant composition as described in claim 1, wherein one or more triglyceride oils include coconut oil.

6. antiperspirant composition as described in claim 1, wherein the oil phase includes the triglycerides selected from the group below less than 5% Oil, the group are made of following item：Sunflower oil, rapeseed oil, corn oil, cottonseed oil, linseed oil, olive oil, safflower oil, soybean Oil, canola oil, peanut oil, sesame oil, apricot kernel oil, castor oil, and combinations thereof.

7. antiperspirant composition as described in claim 1, which further includes one or more based on aluminium or base In the antiperspirant actives substance of aluminium/zirconium.

8. antiperspirant composition as claimed in claim 7, wherein one or more antiperspirant actives substances are selected from the group, the group It is made of following item：Aluminium salt, aluminium/zirconates, two alcohol complex of aluminium, two alcohol complex of aluminium/zirconium, or combinations thereof.

9. antiperspirant composition as described in claim 1, which further includes polyalcohol.

10. antiperspirant composition as claimed in claim 9, wherein the polyalcohol includes glycerine.

11. antiperspirant composition as described in claim 1, which further includes water and one or more emulsifications Agent, wherein the antiperspirant composition is in the form of oil-in-water emulsion.

12. antiperspirant composition as claimed in claim 11, the antiperspirant composition include：

(a) from about 0.1% to about 3% one or more aromatic oil；

(b) from the coconut oil of about 1% to about 20%；

(c) from about 5% to the about 25% antiperspirant actives substance based on aluminium or based on aluminium/zirconium；

(d) from the polyalcohol of about 2% to about 20%；

(e) from the water of about 50% to about 90%；And

(f) from the one or more emulsifying agents of about 1% to about 7%.

13. antiperspirant composition as claimed in claim 12, wherein the one or more emulsifying agents have in total 6-12 it Between HLB value.

14. antiperspirant composition as described in claim 1, wherein the composition is to have less than 7000cps's at 25 DEG C The liquid of viscosity.

15. antiperspirant composition as described in claim 1, which further includes one or more antioxidants.

16. antiperspirant composition as described in claim 1, wherein one or more antioxidants include position not soluble in water Hinder phenol antioxidant.

17. a kind of hidroschesis personal care product comprising：Packaging, the packaging include container and for will be received in the container In liquid antiperspirant composition be delivered to the rollon applicator of user's body quilt, the liquid antiperspirant composition includes that hidroschesis is lived Property substance and one or more aromatic oil being dispersed in oil phase, the oil phase includes one or more to have at least 75% in total Saturated fatty acid content triglyceride oil.

18. antiperspirant composition as described in claim 1, wherein the composition, which contain one or more hairs, minimizes active matter Matter.

19. antiperspirant composition as described in claim 1, wherein the composition contain one or more skin lightening agent.

20. antiperspirant composition as claimed in claim 15, wherein the total amount of one or more antioxidants is the combination Object by weight≤0.20%.