CN108592016A - A kind of low NOx drainage circulating fluidized bed boiler using high nitrogen biomass - Google Patents

A kind of low NOx drainage circulating fluidized bed boiler using high nitrogen biomass Download PDF

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Publication number
CN108592016A
CN108592016A CN201810455062.XA CN201810455062A CN108592016A CN 108592016 A CN108592016 A CN 108592016A CN 201810455062 A CN201810455062 A CN 201810455062A CN 108592016 A CN108592016 A CN 108592016A
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China
Prior art keywords
fuel
loop back
pretreater apparatus
back device
fuel pretreater
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CN201810455062.XA
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CN108592016B (en
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邓博宇
张缦
单露
杨海瑞
吕俊复
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Tsinghua University
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Tsinghua University
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00Fluidised bed combustion apparatus
    • F23C10/18Details; Accessories
    • F23C10/20Inlets for fluidisation air, e.g. grids; Bottoms
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00Fluidised bed combustion apparatus
    • F23C10/18Details; Accessories
    • F23C10/24Devices for removal of material from the bed
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2206/00Fluidised bed combustion
    • F23C2206/10Circulating fluidised bed

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Fluidized-Bed Combustion And Resonant Combustion (AREA)

Abstract

A kind of low NO using high nitrogen biomassxCirculating fluidized bed boiler, including burner hearth, feed separation and loop back device, back-end ductwork and feed and fuel Pretreater apparatus.Feed and fuel Pretreater apparatus include at least one charging gear and at least one fuel Pretreater apparatus, charging gear is arranged in fuel Pretreater apparatus side, and fuel Pretreater apparatus is then arranged between burner hearth and feed separation and loop back device, and be connected to by refeed line with burner hearth, and its top setting pyrolysis gaseous state product pathways is connected with feed separation with loop back device entrance.The dipleg cross-sectional area of feed separation and loop back device is the 1/60~1/40 of burner hearth cross-sectional area.The present invention does carrier using hot ash and is pyrolyzed in advance to high nitrogen biomass fuel by the way that fuel Pretreater apparatus is arranged between feed back pipe, realizes the cleaning burning of high nitrogen biomass fuel.

Description

A kind of low NOx drainage circulating fluidized bed boiler using high nitrogen biomass
Technical field
Invention describes a kind of low NOx drainage circulating fluidized bed boiler using high nitrogen biomass, belong to combustion apparatus Field more particularly to circulating fluidized bed boiler field.
Background technology
In China, economy rapid development, primary energy consumption amount continue to increase the background increasingly increased with environmental protection pressure Under, in recent years, regenerative resource has become the main pushing hands of China's Energy restructuring.As important in regenerative resource One ring, according to statistics, the developable Biomass Energy Resources total amount in China are about 700,000,000 tons of standard coals.And in various biomass utilizations In technology, biomass generation is again at present technical maturity highest, the maximum one kind of development scale.
Currently, biomass direct combustion power generation technology includes mainly layer combustion and fluidized combustion two ways, middle level combustion power generation Mode has the advantages that easy to operate, operating cost is low etc. based on water-cooling vibration furnace grate stove, but that there is also efficiencies of combustion is low, by The problems such as hot area ash and seriously corroded;And the circulating fluidized bed boiler scheme in fluidized combustion generation mode, due to its skill Art reaches its maturity, just gradually convex in the advantage of fuel tolerance, load adjustment ability, pollutant emission level etc. It is aobvious, become the first choice of current China's biomass direct combustion power generation boiler.
For the higher biomass fuel of N element content, such as vinasse, the mass fraction of organic nitrogen is up to 3% or more, Although circulating fluidized bed boiler has the characteristics that nitrogen oxides, raw emissions are low, but still it is ultralow to cannot be satisfied current pollutant Requirement (NOx≤50mg/m of discharge3), it still needs to be equipped with complicated denitrating flue gas for the circulating fluidized bed boiler of the type thus Processing system (SNCR denitration equipment even SCR denitration equipment) so that the initial outlay of unit and operating cost greatly increase, Seriously weaken the economic advantages and competitiveness of Properties of CFB.Exactly in this context, it would be desirable to have in mind In the combustion characteristics of the especially high nitrogen fuel of biomass fuel, and combine the structure of circulating fluidized bed boiler itself and operation special Point, is improved existing equipment, not being added to this under the premise of substantially, is effectively reduced NOx in boiler raw emissions Concentration really realizes the unification of the economic benefit, social benefit and environmental benefit of renewable energy utilization.
Invention content
The purpose of the present invention is to provide a kind of cost and discharge the lower recirculating fluidized bed for using high nitrogen biomass Boiler, to realize the cleaning burning of high nitrogen-containing biomass fuel, to meet economic benefit, the society of renewable energy utilization The unification of benefit and environmental benefit.
The present invention is achieved through the following technical solutions:
A kind of low NOx drainage circulating fluidized bed boiler using high nitrogen biomass, the boiler include burner hearth, feed separation With loop back device, back-end ductwork and feed and fuel Pretreater apparatus, the upper furnace is filled with the feed separation and loopback The entrance set is connected, and the feed separation is connected with the exhanst gas outlet of loop back device with the back-end ductwork, inside back-end ductwork It is disposed with heat-transfer surface, it is characterised in that:The feed and fuel Pretreater apparatus include at least one charging gear and at least one A fuel Pretreater apparatus, the charging gear are arranged in the fuel Pretreater apparatus side;The fuel Pretreater apparatus It is arranged between the burner hearth and the feed separation and loop back device;The fuel Pretreater apparatus and the lower furnace portion It is connected to by refeed line;Be provided at the top of the fuel Pretreater apparatus pyrolysis gaseous state product pathways and the feed separation with Loop back device entrance is connected;The feed separation is connected by dipleg with the fuel Pretreater apparatus with loop back device.
In above-mentioned technical proposal, the dipleg cross-sectional area of the feed separation and loop back device is the burner hearth cross-sectional area 1/60~1/40.
In above-mentioned technical proposal, using extension distance of the device between burner hearth and dipleg as width, and in burner hearth longitudinal direction The distance that extends is depth, and the depth B of the fuel Pretreater apparatus is the dipleg diameter D of the feed separation and loop back device 1~1.5 times, i.e. B=(1~1.5) D;The width L of the fuel Pretreater apparatus is the feed separation and loop back device 4~6 times of dipleg diameter D, i.e. L=(4~6) D;The height H of the fuel Pretreater apparatus is the feed separation and returns Send the dipleg diameter D of device 3.8~4.2 times, i.e. H=(3.8~4.2) D.
In above-mentioned technical proposal, according to boiler capacity, the feed separation and loop back device setting are more than two.
In above-mentioned technical proposal, according to boiler capacity, the fuel Pretreater apparatus is set up in parallel two or more, and each Fuel Pretreater apparatus is at least correspondingly arranged a feed separation with loop back device and by the material of feed separation and loop back device Leg connects.
As further improved technical solution, the refeed line setting is more than two, described two above refeed lines It evenly and symmetrically is arranged on the fuel Pretreater apparatus, and high with the center of the fuel Pretreater apparatus junction Spend the dipleg diameter D that h is the feed separation and loop back device 2.3~2.7 times, i.e. h=(2.3~2.7) D.
Several are arranged in the charging gear, several described charging gears are symmetrically arranged at the fuel pretreatment dress Set both sides.
The fuel Pretreater apparatus top is provided with gasification agent inlet, and the gasification agent inlet is arranged in the pyrolysis Below gaseous products channel, and vapor is passed through as gasifying agent.
The first air-distribution device is arranged in the burner hearth bottom, for being passed through oxidant;The fuel Pretreater apparatus bottom is set The second air-distribution device is set, for being passed through oxidant and/or gasifying agent;Third air-distribution device is arranged in the dipleg bottom, for leading to Enter to loosen wind.
The burner hearth selects water wall structure, preferably film water cold wall structure.
The present invention has the following advantages and beneficial effects:1) chemical reaction process of high nitrogen biomass fuel combustion has been divided into Two stages of afterburning in material pretreatment and burner hearth, the reaction zone different by building two oxygen contents so that high nitrogen biomass fuel Material successively experience pyrolysis and two chemical reaction processes of burning realize minimum discharge to efficiently reduce the generation of its NOx; 2) it is reasonably arranged by components such as dipleg, fuel Pretreater apparatus and refeed lines, realizes fuel and circulating ash macroscopically Opposite-flushing type flowing, promote mixing and heat transfer between the two, and extend the residence time of fuel, further enhance height Pyrolysis of the nitrogen biomass fuel in fuel Pretreater apparatus, has objectively built stronger reducing atmosphere, greatly Ground inhibits fuel to be generated in the NOx of pyrolysis phase;3) gaseous products that will be generated after high nitrogen biomass fuel thermal decomposition, it is main It is CO, H2And CH4Equal reducibility gas, are passed through feed separation and loop back device, to restore generated NOx, further decrease The raw emissions of NOx.
Description of the drawings
Fig. 1 is a kind of low NOx drainage circulating fluidized bed boiler schematic diagram using high nitrogen biomass according to the present invention.
Fig. 2 is that the feed of one of which embodiment according to the present invention and the arrangement of fuel Pretreater apparatus are illustrated Figure.
In figure:1-burner hearth;2-feed separations and loop back device;3-back-end ductworks;4-feeds are filled with fuel pretreatment It sets;5-charging gears;6-fuel Pretreater apparatus;7-refeed lines;8-pyrolysis gaseous state product pathways;9-third cloth wind fill It sets;10-the second air-distribution devices;11-the first air-distribution devices;12-diplegs.
Specific implementation mode
The specific implementation mode and its workflow of the present invention are further described below in conjunction with attached drawing.
The orientation such as upper, lower, left, right, front and rear in present specification term be position relationship based on ... shown in the drawings and It establishes.Attached drawing is different, then corresponding position relationship is also possible to change therewith, therefore cannot be interpreted as with this to protection The restriction of range.
As shown in Figure 1, a kind of low NOx drainage circulating fluidized bed boiler using high nitrogen biomass, including burner hearth 1, material Separation and loop back device 2, back-end ductwork 3 and the parts such as feed and fuel Pretreater apparatus 4.1 top of burner hearth and feed separation with The entrance of loop back device 2 is connected, and feed separation is connected with the exhanst gas outlet of loop back device 2 with back-end ductwork 3, in back-end ductwork 3 Portion is disposed with heat-transfer surface, such as superheater, economizer, air preheater.Feed includes at least one with fuel Pretreater apparatus 4 A charging gear 5 and at least one fuel Pretreater apparatus 6, charging gear 5 are arranged symmetrically in fuel pretreatment processing unit 6 Both sides, fuel Pretreater apparatus 6 are arranged between burner hearth 1 and feed separation and loop back device 2.6 middle part of fuel Pretreater apparatus It is connected to by refeed line 7 with 1 lower part of burner hearth, top is by being pyrolyzed gaseous state product pathways 8 and feed separation and loop back device 2 Entrance is connected, and its underpart is connected with feed separation with the dipleg 12 of 2 lower part of loop back device.
When boiler operatiopn, high nitrogen biomass fuel is sent into fuel pretreatment dress such as screw(-type) feeder through charging gear 4 6 are set, 6 bottom of fuel Pretreater apparatus is installed with the second air-distribution device 10, the oxidants such as air or gasifying agent and is filled through the second cloth wind It sets 10 and enters fuel Pretreater apparatus 6, the flow by controlling oxidant or gasifying agent can make stream in fuel Pretreater apparatus 6 Change wind speed and is maintained at 1~2m/s or so.At this point, high nitrogen biomass fuel will occur in fuel Pretreater apparatus 6 because of anoxic Pyrolysis is generated CO, H by pyrolytic reaction, the volatile matter that part is precipitated2And CH4Equal reducibility gas are built relatively strong in a device Reducing atmosphere, so as to effectively inhibit NOx generate.Product after pyrolysis will leave fuel from two paths respectively Pretreatment unit 6, the solid fuel not reacted completely will enter burner hearth 1 together with circulating ash from 7 overflow of refeed line, and be pyrolyzed Gaseous products by being pyrolyzed gaseous state product pathways 8 will enter feed separation and loop back device 2 after then being mixed with appropriate vapor, The NOx that also crude fuel generates in burner hearth 1 after burning.Overflow, which will enter the fuel of burner hearth 1 and circulating ash, to be filled by the first cloth wind The oxidant for setting 11 feedings is moved upwards with the fluidising air velocity of 3~5m/s or so.The not reaction completely during moving upwards High nitrogen biomass fuel combustion reaction will further occur, since the volatile matter of fuel at this time has removed substantially, therefore fuel fires The stage, NOx generation amount was also less to the greatest extent, so as to realize the cleaning burning of high nitrogen-containing biomass fuel.The middle and upper part of burner hearth 1 Overfiren air port and tertiary air orifice can be arranged as needed, to improve fuel burn-off rate.Ash-laden gas after burning will be from burner hearth 1 Top enters feed separation and loop back device 2 after being mixed with the gaseous products of pyrolysis, such as cyclone separator, carries out gas solid separation. The oxidant that the solid particle obtained after separation will be sent by third air-distribution device 9, it is left with 0.2~0.5m/s of fluidising air velocity The right side is transmitted back to 6 lower part of fuel Pretreater apparatus by dipleg 12, to continue to participate in Matter Transfer process next time.And it detaches The high-temperature flue gas obtained afterwards will then enter back-end ductwork 3, and air is discharged into being arranged therein after heating surface heat exchange cools down.
Technical solution as an optimization, feed separation and 12 sectional area of dipleg of loop back device 2 are 1 sectional areas of burner hearth 1/60~1/40.
Using extension distance of the device between burner hearth and dipleg as width, and it is depth in burner hearth longitudinal direction extension distance, The depth B of fuel Pretreater apparatus 6 is 1~1.5 times of the 12 diameter D of dipleg of feed separation and loop back device 2, i.e. B=(1~ 1.5)D;The width L of fuel Pretreater apparatus 6 is 4~6 times of feed separation and the 12 diameter D of dipleg of loop back device 2, i.e. L= (4~6) D;The height H of fuel Pretreater apparatus 6 is the 3.8~4.2 of feed separation and the 12 diameter D of dipleg of loop back device 2 Times, i.e. H=(3.8~4.2) D.
According to boiler capacity, feed separation is set up in parallel two or more with loop back device 2.
According to boiler capacity, fuel Pretreater apparatus 6 is set up in parallel two or more, and each fuel Pretreater apparatus 6 to It is correspondingly arranged a feed separation less with loop back device 2 and is connect by feed separation with the dipleg 12 of loop back device 2.
As further improved technical solution, two or more is arranged in refeed line 7, and more than two refeed lines are uniform and right Claim ground be arranged on fuel Pretreater apparatus 6, and with the centre-height h of 6 junction of fuel Pretreater apparatus be feed separation and 2.3~2.7 times of the 12 diameter D of dipleg of loop back device 2, i.e. h=(2.3~2.7) D.
Several are arranged in charging gear 5, several charging gears are symmetrically arranged at 6 both sides of fuel Pretreater apparatus.It is excellent Choosing, the centre-height h of charging gear 5 and 6 junction of fuel Pretreater apparatus2For the feed separation and loop back device 2 1.8~2.2 times of 12 diameter D of dipleg.
6 top of fuel Pretreater apparatus is provided with gasification agent inlet, and gasification agent inlet setting is logical in pyrolysis gaseous products 8 lower section of road, and vapor is passed through as gasifying agent.
The first air-distribution device 11 is arranged in 1 bottom of burner hearth, for being passed through oxidant;6 bottom of fuel Pretreater apparatus setting the Two air-distribution devices 10, for being passed through oxidant and/or gasifying agent;Third air-distribution device 9 is arranged in 12 bottom of dipleg, for being passed through Loosen wind.Preferred technical solution is that the fluidising air velocity in burner hearth 1 is 3~5m/s, the fluidized wind in fuel Pretreater apparatus 6 Speed control is in 1~2m/s.
One of which embodiment as shown in Figure 2, feed separation selects adiabatic form with loop back device 2, and left and right is each Arrangement one, the sectional area of dipleg 12 is taken as the 1/50 of 1 sectional area of burner hearth;One fuel Pretreater apparatus 6 and above-mentioned two Feed separation is respectively connected with loop back device 2, and its depth and width and height are taken as 1.5,4 and the 4 of 12 diameter of dipleg respectively Times;Two refeed lines 7 evenly and symmetrically are arranged in the front end face of fuel Pretreater apparatus 6, and diameter d is taken as dipleg 12 Diameter D, and with the high h in center of 6 junction of fuel Pretreater apparatus1It is taken as 2.5 times of 12 diameter D of dipleg;Two charging gears 5 are symmetrically arranged at two side end faces of fuel Pretreater apparatus 6, and with the high h in center of 6 junction of fuel Pretreater apparatus2 It is taken as 2 times of 12 diameter D of dipleg.In addition, burner hearth 1 uses film water cold wall structure and is disposed with pendant superheater to carry out work The heat exchange of matter and bed side, and in the setting of its bottom, there are one bed materials to feed mouth, bed material is required supplementation with according to operation, to ensure in stove The foundation of ash cycle.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, any made by Modification, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of low NOx drainage circulating fluidized bed boiler using high nitrogen biomass, the boiler includes burner hearth (1), material point From with loop back device (2), back-end ductwork (3) and feed and fuel Pretreater apparatus (4), burner hearth (1) top and the object Material separation is connected with the entrance of loop back device (2), exhanst gas outlet and the tail portion cigarette of the feed separation with loop back device (2) Road (3) is connected, and heat-transfer surface is disposed with inside back-end ductwork (3), it is characterised in that:The feed and fuel Pretreater apparatus (4) Including at least one charging gear (5) and at least one fuel Pretreater apparatus (6), the charging gear (5) is arranged in described Fuel Pretreater apparatus (6) side;The fuel Pretreater apparatus (6) setting the burner hearth (1) and the feed separation with Between loop back device (2);The fuel Pretreater apparatus (6) is connected to the burner hearth (1) lower part by refeed line (7);It is described Pyrolysis gaseous state product pathways (8) and the feed separation and loop back device (2) entrance are provided at the top of fuel Pretreater apparatus (6) It is connected;The feed separation is connected by dipleg (12) with the fuel Pretreater apparatus (6) with loop back device (2).
2. a kind of low NOx drainage circulating fluidized bed boiler using high nitrogen biomass according to claim 1, feature exist In:The feed separation and loop back device (2) setting are more than two.
3. a kind of low NOx drainage circulating fluidized bed boiler using high nitrogen biomass according to claim 1 or 2, special Sign is:The feed separation and dipleg (12) sectional area of loop back device (2) are the 1/60~1/ of the burner hearth (1) sectional area 40。
4. a kind of low NOx drainage circulating fluidized bed boiler using high nitrogen biomass according to claim 3, feature exist In:The depth B of the fuel Pretreater apparatus (6) is the 1 of the feed separation and dipleg (12) diameter D of loop back device (2) ~1.5 times;The width L of the fuel Pretreater apparatus (6) is dipleg (12) diameter of the feed separation and loop back device (2) 4~6 times of D;The height H of the fuel Pretreater apparatus (6) is that the feed separation and the dipleg (12) of loop back device (2) are straight 3.8~4.2 times of diameter D.
5. a kind of low NOx drainage circulating fluidized bed boiler using high nitrogen biomass according to claim 1 or 4, special Sign is:The fuel Pretreater apparatus (6) is set up in parallel two or more, and each fuel Pretreater apparatus (6) and at least one A feed separation is connect with the dipleg (12) of loop back device (2).
6. a kind of low NOx drainage circulating fluidized bed boiler using high nitrogen biomass according to claim 1, feature exist In:Refeed line (7) setting is more than two, and described two above refeed lines are uniformly distributed in the fuel pretreatment dress It sets on (6), and is the feed separation and loop back device (2) with the centre-height h of the fuel Pretreater apparatus (6) junction 2.3~2.7 times of dipleg (12) diameter D.
7. a kind of low NOx drainage circulating fluidized bed boiler using high nitrogen biomass according to claim 1, feature exist In:Several are arranged in the charging gear (5), several described charging gears are symmetrically arranged at the fuel Pretreater apparatus (6) both sides.
8. a kind of low NOx drainage circulating fluidized bed boiler using high nitrogen biomass according to claim 1, feature exist In:Fuel Pretreater apparatus (6) top is provided with gasification agent inlet, and the gasification agent inlet is passed through vapor as gasification Agent.
9. a kind of low NOx drainage circulating fluidized bed boiler using high nitrogen biomass according to claim 1, feature exist In:The first air-distribution device (11) is arranged in burner hearth (1) bottom, for being passed through oxidant;Fuel Pretreater apparatus (6) bottom The second air-distribution device (10) is arranged in portion, for being passed through oxidant and/or gasifying agent;Third cloth wind is arranged in dipleg (12) bottom Device (9), for being passed through loosening wind.
10. a kind of low NOx drainage circulating fluidized bed boiler using high nitrogen biomass according to claim 1, feature It is:The burner hearth (1) selects water wall structure.
CN201810455062.XA 2018-05-11 2018-05-11 Low NOx emission circulating fluidized bed boiler for burning high-nitrogen biomass Active CN108592016B (en)

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Publication number Priority date Publication date Assignee Title
CN111617878A (en) * 2020-05-12 2020-09-04 路德环境科技股份有限公司 Impurity removing device suitable for continuous fluidized bed drying process

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111617878A (en) * 2020-05-12 2020-09-04 路德环境科技股份有限公司 Impurity removing device suitable for continuous fluidized bed drying process

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