CN100582197C - Circulating fluidized bed heat-power-gas-tar multi-joint-production apparatus and method - Google Patents

Circulating fluidized bed heat-power-gas-tar multi-joint-production apparatus and method Download PDF

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CN100582197C
CN100582197C CN200610154581A CN200610154581A CN100582197C CN 100582197 C CN100582197 C CN 100582197C CN 200610154581 A CN200610154581 A CN 200610154581A CN 200610154581 A CN200610154581 A CN 200610154581A CN 100582197 C CN100582197 C CN 100582197C
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fluidized bed
stove
gas
dry distillation
circulating fluidized
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CN1978591A (en
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骆仲泱
方梦祥
王勤辉
施正伦
余春江
王树荣
周劲松
程乐鸣
高翔
倪明江
岑可法
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Zhejiang University ZJU
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Abstract

The invention discloses a circulating fluid-bed heat-electric-gas-tar connection device and the method. The device combines the circulating fluid-bed burning furnace and the retort furnace to produce the heat-electric-gas-tar in a suit of system. The device is made up of the fluid-bed retort furnace, the circulating fluid-bed burning furnace, the high temperature separator and the material return which connected the two furnaces, the corresponding appurtenance. So the every components of coal can be used fully by the device; the tar productive rate is high and the calm value of the coal gas is high, the CO content is low by using the circulating fluid-bed solid heating carrier and the warm retort technology. Also it doesn't need the special O2 making device and the CO transforming process, so it has the simple process and the low cost comparing to the gas furnace and the retort furnace.

Description

Circulating fluidized bed heat-power-gas-tar multi-joint-production apparatus and method thereof
Technical field
The present invention relates to combustion unit, relate in particular to a kind of circulating fluidized bed heat-power-gas-tar multi-joint-production apparatus and method thereof.
Background technology
China is the main energy sources resource for a long time with coal, but the coal in China utilization is in a kind of single development of coal production always, does not pay attention to the unreasonable industrial pattern of coal comprehensive utilization, unreasonable on deficiency on technical matters, the installations and facilities and product structure of electric power, chemical industry and other industry, the energy consumption per unit of output value that causes China is 3-4 a times of developed country, the exploitation of coal and processing and utilization become the main source of China's environmental pollutant discharging, make China's environment become typical coal-smoke pollution.
The polygenerations systeme of coal is this angle of resource of industries such as electric power, chemical industry, metallurgy simultaneously from coal, characteristic at coal, the realization classification utilizes, and produces products such as heat and power and multiple Chemicals with high added value, liquid fuel in same system.Like this, polygenerations systeme can be from the height of system, superiority in conjunction with various production technology routes, production process is coupled, reach that efficiency of energy utilization is the highest, energy consumption is minimum, pollution is minimum, investment and running cost are saved most, solve the control problem of pollutent in the coal utilization process with most economical method.Therefore, by Poly-generation technology, can really realize the efficient clean utilization of coal.
Summary of the invention
The purpose of this invention is to provide a kind of circulating fluidized bed heat-power-gas-tar multi-joint-production apparatus and method thereof.
Circulating fluidized bed heat-power-gas-tar multi-joint-production apparatus has fluidized bed dry distillation stove and circulating fluidized bed combustion stove; Fluidized bed dry distillation stove bottom joins through material returning device and circulating fluidized bed combustion stove bottom, fluidized bed dry distillation stove bottom joins with circular fluid bed high-temperature separator, circulating fluidized bed combustion stove middle part respectively through two-way material controlling device, fluidized bed dry distillation stove top and gas cleaning system are joined, and circulating fluidized bed combustion stove top joins with circular fluid bed high-temperature separator, circular fluid bed back-end surfaces successively; First coal supply joins through feeding machine and fluidized bed dry distillation stove, the superheated vapo(u)r import of the vapor outlet port of circulating fluidized bed combustion stove and circular fluid bed back-end surfaces is joined, and the superheated vapo(u)r outlet of circular fluid bed back-end surfaces is joined with turbine driven set; The fluidized bed dry distillation stove is with water vapor or the air blast of recirculation coal gas, the heat absorption of fluidized bed dry distillation stove is delivered to the fluidized bed dry distillation stove by the isolating high temperature circulation material of the high-temperature separator of circulating fluidized bed combustion outlet of still through two-way material controlling device to be provided, semicoke and recycle stock are sent into the circulating fluidized bed combustion stove through material returning device and are burnt, the circulating fluidized bed combustion stove adopts air blast, using semicoke that the fluidized bed dry distillation stove comes and recycle stock produces heat and adds hot water and become steam, the recycle stock that comes from the fluidized bed dry distillation stove with heating becomes high-temperature material and delivers to the fluidized bed dry distillation stove again the destructive distillation heat absorption is provided, from gas retort come out warm coal gas through the gas cleaning system dedusting, cooling, after reclaiming tar, coal gas output after the purification, the flue gas that comes out from the circulating fluidized bed combustion stove is behind the high-temperature separator separation of material, enter the back-end surfaces cooling of circular fluid bed after enter atmosphere after the dedusting, the generating of superheated vapour steam supply turbine generator group and the heat supply that produce in the back-end surfaces.
Described two-way material controlling device is three cell structures that are interconnected, the centre is two-way material controlling device feed chamber, both sides are respectively the first two-way material controlling device returning charge chamber and the second two-way material controlling device returning charge chamber, adopt humidified blast, the isolating high-temperature material of high-temperature separator is delivered to fluidized bed dry distillation stove and circulating fluidized bed combustion stove respectively, stop gas to seal in high-temperature separator simultaneously, and regulate two the stove recycle stock amounts that enter by first variable valve, second variable valve from fluidized bed dry distillation stove and circulating fluidized bed combustion stove.
Material returning device is the double-chamber structure that is interconnected, comprise material returning device returning charge chamber, material returning device feed chamber, adopt humidified blast, the semicoke of fluidized bed dry distillation stove and high-temperature material are delivered to the circulating fluidized bed combustion stove, stop gas to seal in the fluidized bed dry distillation stove simultaneously, and open and turn-off the recycle stock amount by steam regulating valve from the circulating fluidized bed combustion stove.
The circulating fluidized bed heat-power-gas-tar multi-joint-production method comprises:
1) the fluidized bed dry distillation stove adopts steam or recirculation coal gas as fluidizing agent, and the gas retort operating temperature is 500~700 ℃, realizes the medium temperature carbonization of coal;
2) fluidized bed dry distillation stove fluidising air velocity is controlled at 2.5-3.5m/s, the operation emulsion zone adopts the dark height of bed of 2-3.5m, the feed particle diameter is>0≤8mm, and the mean residence time of control fuel in stove is 2-4 minute, thereby the assurance fluidized gas scale of construction is less and coal supply has enough residence time destructive distillation;
3) cross section, fluidized bed dry distillation stove top be lower section 1.5-3 doubly, to reduce top gas speed, reduce the flying dust drag-out, control fluidized-bed gas retort upper space height simultaneously and be emulsion zone height 2-4 doubly, with the second pyrolysis that reduces tar,
4) the two-way material controlling device of connection roasting kiln high-temperature separator and gas retort and roasting kiln bottom, adopt the superheated vapour air blast, control gas speed is 0.5-2m/s, enter the ratio of the amount of fluidized bed dry distillation stove and circulating fluidized bed combustion stove recycle stock by the mechanical adjustment valve regulation, stop gas to seal in high-temperature separator simultaneously from fluidized bed dry distillation stove and circulating fluidized bed combustion stove;
5) material returning device of connection gas retort and roasting kiln is a double-chamber structure, adopt the superheated vapour air blast, control gas speed is 0.5-2m/s, realization is delivered to the circulating fluidized bed combustion stove with the semicoke and the high-temperature material of fluidized bed dry distillation stove, stop gas to seal in the fluidized bed dry distillation stove simultaneously, and open and turn-off the recycle stock amount by steam regulating valve from the circulating fluidized bed combustion stove;
6) circulating fluidized bed combustion stove adopts air blast, and the operation fluidising air velocity is 3-5m/s, adopts staged air distribution, and primary air flow is 70/30-50/50 with the ratio of secondary air flow, and operating temperature is 800~950 ℃.
Beneficial effect of the present invention:
1) the present invention combines closely circulating fluidized bed combustion stove and gas retort, is implemented in the combination producing of heat, electricity, gas, tar in the cover system, has realized the rational and efficient use of the various compositions of coal;
2) adopt circulating fluidized bed solid thermal carriers and medium temperature carbonization technology, the tar yield height that device produces, oil extracting rate can reach more than 65%, and wherein the light oil productive rate reaches more than 30%, and caloric power of gas is higher, can reach 12~16Mj/Nm 3More than, CO content is low, satisfies the relevant domestic gas regulation of country, does not need special oxygen generating plant and CO conversion process, compares with gas retort with similar domestic gas stove, and technology is simple, reduced investment, running cost is low;
3) adopt Combustion technology of circulating fluidized, semicoke directly as boiler oil, send the combustion chamber to burn after the destructive distillation, and the generating of steaming makes that gas and solid composition are all reasonably made full use of in the fuel.Therefore, the device fuel availability is higher, can reach more than 90%;
4) the fired basis fugitive constituent all is applicable to this technology at the various coals more than 20%, this technology does not have special requirement to coal particle size yet, just adopt the required coal particle size of ordinary cycle bed, this has just been avoided existing domestic gasization and distillation process coal and coal particle size to be had the shortcoming of strict restriction.Therefore, the fuel tolerance of device is wide;
5) this technology can realize ash comprehensive utilization, and lime-ash has very high reactivity after circulating fluidized bed combustion, can be used as cement admixture;
6) utilize circulating fluidized bed high-efficiency desulfurization, denitration characteristics can realize lower pollutant emission, satisfy national coal clean utilization requirement fully.
Description of drawings
Fig. 1 is circulating fluidized bed heat-power-gas-tar multi-joint-production apparatus and process schematic representation;
Fig. 2 is the circulating fluidized bed heat-power-gas-tar multi-joint-production apparatus synoptic diagram;
Among the figure: the coal gas 1 after the purification, gas cleaning system 2, the tar 3 that reclaims, raw gas 4, first coal supply 5, recirculation coal gas 6, water vapor 7, material returning device 8, semicoke and recycle stock 9, fluidized bed dry distillation stove 10, two-way material controlling device 11, circulating fluidized bed combustion stove 12, deslagging 13, air 14, second coal supply 15, feedwater 16, high-temperature separator 17, high temperature circulation material 18, high-temperature flue gas 19, the back-end surfaces 20 of circular fluid bed, superheated vapour 21, turbine driven set 22, heat supply 23, generating 24, steam 25, material returning device returning charge chamber 26, material returning device feed chamber 27, steam 28, two-way material controlling device returning charge chamber 29, two-way material controlling device feed chamber 30, two-way material controlling device returning charge chamber 31, first variable valve 32, second variable valve 33.
Embodiment
As shown in the figure, circulating fluidized bed heat-power-gas-tar multi-joint-production apparatus, it comprises fluidized bed dry distillation stove 10 and circulating fluidized bed combustion stove 12; Fluidized bed dry distillation stove bottom joins by high-temperature pipe and material returning device 8 and circulating fluidized bed combustion stove 12, and join by high-temperature pipe and two-way material controlling device 11 and circular fluid bed high-temperature separator 17, fluidized bed dry distillation stove top joins by pipeline and gas cleaning system 2.Circulating fluidized bed combustion stove bottom is connected with two-way material controlling device 11 with material returning device 8 by high-temperature pipe, and circulating fluidized bed combustion stove top is connected with circular fluid bed high-temperature separator 17, circular fluid bed back-end surfaces 20 and turbine driven set 22 successively.Fluidized bed dry distillation stove water vapor 7 or 6 air blast of recirculation coal gas, operating temperature is 500~700 ℃, first coal supply 5 feeds fluidized bed dry distillation stove 10 through feeding machine, coal at first is subjected to thermo-cracking, separate out the high heating value fugitive constituent and comprise coal gas and tar, the heat absorption of fluidized bed dry distillation stove is delivered to the fluidized bed dry distillation stove by the high-temperature separator 17 isolating high temperature circulation materials 18 of circulating fluidized bed combustion stove 12 outlets through two-way material controlling device 11 and is provided, semicoke and recycle stock 9 are sent into circulating fluidized bed combustion stove 12 through material returning device 8 and are burnt, the circulating fluidized bed combustion stove adopts air 14 air blast, operating temperature is 800~950 ℃, use semicoke and recycle stock 9 that the fluidized bed dry distillation stove comes, producing heat adds hot water 16 and becomes recycle stock that steam and heating come from the fluidized bed dry distillation stove and become high-temperature material and deliver to the fluidized bed dry distillation stove again the destructive distillation heat absorption is provided, from gas retort come out warm coal gas through gas cleaning system 2 dedustings, cooling, after reclaiming tar 3, coal gas 1 output after the purification is for industry and civilian, also recyclable benzene in scavenging process, sweet smell waits other byproduct.The flue gas that comes out from the circulating fluidized bed combustion stove is behind high-temperature separator 17 separation of material, and back-end surfaces 20 coolings that enter circular fluid bed are after enter atmosphere after the dedusting.But superheated vapour 21 steam supply turbine generator groups 22 generating 24 and the heat supplies 23 that produce in the back-end surfaces.
Fluidized bed dry distillation stove of the present invention adopts steam and/or recirculation coal gas as fluidizing agent, and operating temperature is 500~700 ℃, thereby realizes the medium temperature carbonization of coal, reaches higher tar yield.The fluidized bed dry distillation furnace structure guarantees that for little big down the fluidized gas scale of construction is tried one's best little and coal supply has enough residence time destructive distillation, and fluidized bed dry distillation stove upper space height can not be too high as long as assurance has certain ash content from height, reduces the second pyrolysis of tar.
Two-way material controlling device 11 of the present invention is three cell structures, adopt humidified blast, can realize high-temperature separator 17 isolating high-temperature materials are delivered to fluidized bed dry distillation stove 10 and circulating fluidized bed combustion stove 12 respectively, stop gas to seal in high-temperature separator simultaneously, and regulate the amount that enters 2 stove recycle stocks by variable valve from fluidized bed dry distillation stove and circulating fluidized bed combustion stove.
Material returning device 8 of the present invention is a double-chamber structure, adopt humidified blast, can realize the semicoke and the high-temperature material of fluidized bed dry distillation stove 10 are delivered to circulating fluidized bed combustion stove 12, stop gas to seal in the fluidized bed dry distillation stove simultaneously, and can open and turn-off the recycle stock amount by steam regulating valve from the circulating fluidized bed combustion stove.
Circulating fluidized bed combustion stove 12 of the present invention adopts air blast, and operating temperature is 800~950 ℃, the raw coal that both can burn, and the semicoke that also can burn, and when burning raw coal and semicoke, can keep the boiler nominal parameter.
The circulating fluidized bed heat-power-gas-tar multi-joint-production method comprises:
1) fuel feeds the fluidized bed dry distillation stove through feeding machine, at first be subjected to thermo-cracking, separate out the high heating value fugitive constituent and comprise coal gas and tar, gas retort heat absorption is provided by the high temperature circulation material of circulating fluidized bed combustion stove, and semicoke is sent into the circulating fluidized bed combustion stove with recycle stock and burnt after the destructive distillation.The circulating fluidized bed combustion stove adopts air blast, use the semicoke of vaporizer, producing heat produces cold cycle material that water vapor and heating come from gas retort and becomes high-temperature material and deliver to gas retort again the destructive distillation heat absorption is provided, from gas retort come out warm coal gas behind gas cleaning device dedusting, cooling, recovery tar, coal gas output after the purification is for industry and civilian, other byproducts such as also recyclable benzene, sweet smell in scavenging process.The flue gas that comes out from circular fluid bed enters atmosphere after the fly-ash separator dedusting.But generate electricity and heat supply by the steam steam supply turbine that circular fluid bed produces.Realize the combination producing of heat, electricity, gas, tar in the covering device thus, thereby realize the high-efficiency comprehensive utilization of coal.
2) the fluidized bed dry distillation stove adopts steam or recirculation coal gas as fluidizing agent, and the gas retort operating temperature is 500~700 ℃, realizes the medium temperature carbonization of coal; Fluidized bed dry distillation stove fluidising air velocity is controlled at 2.5-3.5m/s, the operation emulsion zone adopts the dark height of bed of 2-3.5m, the feed particle diameter is>0≤8mm, and the mean residence time of control fuel in stove is 2-4 minute, thereby the assurance fluidized gas scale of construction is less and coal supply has enough residence time destructive distillation; The fluidized bed dry distillation furnace structure is for little big down, and the cross section, top is 1.5-3 a times of lower section, to reduce top gas speed, reduces the flying dust drag-out, and controlling fluidized-bed gas retort upper space height simultaneously is emulsion zone height 2-4 times, to reduce the second pyrolysis of tar.
3) the two-way material controlling device of connection roasting kiln high-temperature separator and gas retort and roasting kiln bottom, adopt the superheated vapour air blast, control gas speed is 0.5-2m/s, enter the ratio of the amount of fluidized bed dry distillation stove and circulating fluidized bed combustion stove recycle stock by the mechanical adjustment valve regulation, stop gas to seal in high-temperature separator simultaneously from fluidized bed dry distillation stove and circulating fluidized bed combustion stove;
4) material returning device of connection gas retort and roasting kiln is a double-chamber structure, adopt the superheated vapour air blast, control gas speed is 0.5-2m/s, realization is delivered to the circulating fluidized bed combustion stove with the semicoke and the high-temperature material of fluidized bed dry distillation stove, stop gas to seal in the fluidized bed dry distillation stove simultaneously, and open and turn-off the recycle stock amount by steam regulating valve from the circulating fluidized bed combustion stove;
5) circulating fluidized bed combustion stove adopts air blast, and the operation fluidising air velocity is 3-5m/s, adopt staged air distribution, primary air flow is 70/30-50/50 with the ratio of secondary air flow, and operating temperature is 800~950 ℃, adopts high temperature to separate, the design cycle multiplying power is 10-20, boiler efficiency is more than 88%, both can 100% burning raw coal, and also can 100% burning semicoke, and when burning raw coal and semicoke, all keep boiler and reach nominal parameter.The flue gas that comes out from circular fluid bed enters atmosphere after the fly-ash separator dedusting.But generate electricity and heat supply by the steam steam supply turbine that circular fluid bed produces.
6) enter gas cleaning system from the raw gas that pyrolyzer produced, at first enter secondary cyclone and separate flying dust, then after quench tower cooling, electrical tar precipitator capture tar, part coal gas can be by sending the vapourizing furnace bottom after the pressurization of coal gas recirculation blower again back to, as the fluidizing medium of vapourizing furnace.All the other coal gas then enter equipment continuation purifications such as desulfurization, other byproducts such as also recyclable benzene, sweet smell in scavenging process.The outlet purified gas satisfies country's industry and domestic gas requirement, and output is for industry and civilian.

Claims (4)

1. circulating fluidized bed heat-power-gas-tar multi-joint-production apparatus, it is characterized in that: it has fluidized bed dry distillation stove (10) and circulating fluidized bed combustion stove (12); Fluidized bed dry distillation stove bottom joins through material returning device (8) and circulating fluidized bed combustion stove (12) bottom, fluidized bed dry distillation stove bottom joins with circular fluid bed high-temperature separator (17), circulating fluidized bed combustion stove (12) middle part respectively through two-way material controlling device (11), fluidized bed dry distillation stove top and gas cleaning system (2) are joined, and circulating fluidized bed combustion stove top joins with circular fluid bed high-temperature separator (17), circular fluid bed back-end surfaces (20) successively; First coal supply (5) joins through feeding machine and fluidized bed dry distillation stove (10), the superheated vapo(u)r import of the vapor outlet port of circulating fluidized bed combustion stove and circular fluid bed back-end surfaces (20) is joined, and the superheated vapo(u)r outlet of circular fluid bed back-end surfaces (20) is joined with turbine driven set (22); Fluidized bed dry distillation stove water vapor (7) or recirculation coal gas (6) air blast, the heat absorption of fluidized bed dry distillation stove is delivered to the fluidized bed dry distillation stove by the isolating high temperature circulation material of high-temperature separator (17) (18) of circulating fluidized bed combustion stove (12) outlet through two-way material controlling device (11) and is provided, semicoke and recycle stock (9) are sent into circulating fluidized bed combustion stove (12) through material returning device (8) and are burnt, the circulating fluidized bed combustion stove adopts air (14) air blast, use semicoke and recycle stock (9) that the fluidized bed dry distillation stove comes, producing heat adds hot water (16) and becomes recycle stock that steam and heating come from the fluidized bed dry distillation stove and become high-temperature material and deliver to the fluidized bed dry distillation stove again the destructive distillation heat absorption is provided, from gas retort come out warm coal gas through gas cleaning system (2) dedusting, cooling, after reclaiming tar (3), coal gas after the purification (1) output, the flue gas that comes out from the circulating fluidized bed combustion stove is behind high-temperature separator (17) separation of material, enter back-end surfaces (20) cooling of circular fluid bed after enter atmosphere after the dedusting, the superheated vapour that produces in the back-end surfaces (21) (24) and heat supply (23) but steam supply turbine generator group (22) is generated electricity.
2. a kind of circulating fluidized bed heat-power-gas-tar multi-joint-production apparatus according to claim 1, it is characterized in that: three cell structures of described two-way material controlling device (11) for being interconnected, the centre is a two-way material controlling device feed chamber (30), both sides are respectively the first two-way material controlling device returning charge chamber (29) and the second two-way material controlling device returning charge chamber (31), adopt humidified blast, the isolating high-temperature material of high-temperature separator (17) is delivered to fluidized bed dry distillation stove (10) and circulating fluidized bed combustion stove (12) respectively, stop gas to seal in high-temperature separator simultaneously from fluidized bed dry distillation stove and circulating fluidized bed combustion stove, and by first variable valve (32), second variable valve (33) is regulated two the stove recycle stock amounts that enter.
3. a kind of circulating fluidized bed heat-power-gas-tar multi-joint-production apparatus according to claim 1, it is characterized in that: the double-chamber structure of described material returning device (8) for being interconnected, comprise material returning device returning charge chamber (26), material returning device feed chamber (27), adopt humidified blast, the semicoke of fluidized bed dry distillation stove (10) and high-temperature material are delivered to circulating fluidized bed combustion stove (12), stop gas to seal in the fluidized bed dry distillation stove simultaneously, and open and turn-off the recycle stock amount by steam regulating valve from the circulating fluidized bed combustion stove.
4. circulating fluidized bed heat-power-gas-tar multi-joint-production method that use is installed according to claim 1 is characterized in that:
1) the fluidized bed dry distillation stove adopts steam or recirculation coal gas as fluidizing agent, and the gas retort operating temperature is 500~700 ℃, realizes the medium temperature carbonization of coal;
2) fluidized bed dry distillation stove fluidising air velocity is controlled at 2.5-3.5m/s, the operation emulsion zone adopts the dark height of bed of 2-3.5m, the feed particle diameter is greater than 0 smaller or equal to 8mm, and the mean residence time of control fuel in stove is 2-4 minute, thereby guarantees that the less and coal supply of the fluidized gas scale of construction has enough residence time destructive distillation;
3) cross section, fluidized bed dry distillation stove top be lower section 1.5-3 doubly, to reduce top gas speed, reduce the flying dust drag-out, control fluidized-bed gas retort upper space height simultaneously and be emulsion zone height 2-4 doubly, to reduce the second pyrolysis of tar;
4) the two-way material controlling device of connection roasting kiln high-temperature separator and gas retort and roasting kiln bottom, adopt the superheated vapour air blast, control gas speed is 0.5-2m/s, enter the ratio of the amount of fluidized bed dry distillation stove and circulating fluidized bed combustion stove recycle stock by the mechanical adjustment valve regulation, stop gas to seal in high-temperature separator simultaneously from fluidized bed dry distillation stove and circulating fluidized bed combustion stove;
5) material returning device of connection gas retort and roasting kiln is a double-chamber structure, adopt the superheated vapour air blast, control gas speed is 0.5-2m/s, realization is delivered to the circulating fluidized bed combustion stove with the semicoke and the high-temperature material of fluidized bed dry distillation stove, stop gas to seal in the fluidized bed dry distillation stove simultaneously, and open and turn-off the recycle stock amount by steam regulating valve from the circulating fluidized bed combustion stove;
6) circulating fluidized bed combustion stove adopts air blast, and the operation fluidising air velocity is 3-5m/s, adopts staged air distribution, and primary air flow is 70/30-50/50 with the ratio of secondary air flow, and operating temperature is 800~950 ℃.
CN200610154581A 2006-11-08 2006-11-08 Circulating fluidized bed heat-power-gas-tar multi-joint-production apparatus and method Active CN100582197C (en)

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循环流化床多联产洁净煤技术的研究及应用. 王志锋,梁鹏,董众兵,毕继诚.煤化工,第5期. 2005
循环流化床多联产洁净煤技术的研究及应用. 王志锋,梁鹏,董众兵,毕继诚.煤化工,第5期. 2005 *

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