CN108587816A - A kind of Hydrogen-rich liquid biocleaner and the preparation method and application thereof - Google Patents
A kind of Hydrogen-rich liquid biocleaner and the preparation method and application thereof Download PDFInfo
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- CN108587816A CN108587816A CN201810479576.9A CN201810479576A CN108587816A CN 108587816 A CN108587816 A CN 108587816A CN 201810479576 A CN201810479576 A CN 201810479576A CN 108587816 A CN108587816 A CN 108587816A
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- Prior art keywords
- hydrogen
- biocleaner
- solvent
- rich liquid
- water
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
- C01B3/042—Decomposition of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- General Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of Hydrogen-rich liquid biocleaners and the preparation method and application thereof, include the raw material of following parts by weight：Include the protium of solvent and dissolving in a solvent, the saturation degree of hydrogen is 0.1~100% in solvent, the solvent is purified water or drinking public water supply, include the following steps, S1, hydrogen is prepared first, hydrogen is then passed through 5min or more in the solvent, and then obtains the Hydrogen-rich liquid biocleaner of different saturation；Hydrogen-rich liquid biocleaner is carried out soaking and washing by S2, the application of the hydrogen-rich biocleaner to washing clean article；The article includes clothing, fabric, greasy dirt, ceramics, metal, glass；S3, the water electrolysis method are：Distilled water is electrolysed using 2~24V DC voltages, dry pure hydrogen is obtained after aqueous vapor separation and drying.The present invention is at low cost, and stability is high, pollution-free, noresidue, environmental protection.
Description
Technical field
The present invention relates to biocleaner technical field more particularly to a kind of Hydrogen-rich liquid biocleaner and its preparation sides
Method and application.
Background technology
Detergent is artificial synthesized organic compound, such as washing powder, liquid detergent mostly.It is wherein phosphorous（Sodium phosphate）Amount
Higher, phosphorous waste water flows into rivers and lakes after washing, causes body eutrophication, causes Measures of Algae in Water Body breeding vigorous, makes
At fish and other aquatile hypoxia deaths, until water quality degenerates or even goes bad smelly.In addition high phosphorus detergent has skin
Direct stimulation can cause multiple dermatosis.Therefore, the regulation that many countries have made to prohibit phosphorus, limit phosphorus to detergent now,
People are advocated energetically uses non-phosphate detergent.
Start within 1954 to produce and use synthetic detergent.The world produces synthetic detergent per year ten thousand tons about more than 1300 at present.Contain
The waste water of synthetic detergent mainly has detergent wastewaer, industrial detergent ejected wash water, laundry workshop waste water and life dirty
Water.The surfactant of early application such as sodium alkyl benzene sulfonate (ABS) not easily biological-degradable, retention time is longer in the environment.
Used sodium n-alkylbenzenesulfonate (LAS) instead later, biological degradability is obviously improved, but the two has benzene nucleus, cannot be complete
It decomposes.ABS and LAS is required for phosphate as increasing net agent.Phosphate is discharged into water body, is an important original for causing eutrophication
Cause.Detergent addition can make the hydrophobic organic pollution emulsification such as the oil product into water body, Polychlorinated biphenyls and disperse, and give waste water
Processing brings difficulty.
Hydrogen is the gas most light in the world being currently known.
Its density is very small, only the 1/14 of air, i.e., under standard atmospheric pressure, 0 °C, the density of hydrogen is
0.0899g/L, boiling point are -252.77 °C, and fusing point is -259.2 °C, relative molecular mass 2.016, and thermal coefficient is
0.1289w/(m•K).Under room temperature, the property of hydrogen is very stable, it is not easy to be chemically reacted with other materials.But when condition changes
When change（It such as lights, heat, using catalyst）, the chemical property of hydrogen is then very active, is commonly used for reducing agent.Hydrogen making
Method have very much, such as electrolysis water, metal/water hydrogen manufacturing, photoelectrolysis hydrogen manufacturing.But in view of production hydrogen purity, economy and practicality etc.
Factor, researcher, also can be directly from producer's purchase gas steel usually using SPE electrolysis water method hydrogen makings in the lab
Bottle.In terms of the storage and transportation of hydrogen, since hydrogen density is low, molecular diameter is small, easily spread, it might even be possible to directly through rubber and
The molecular gap of the materials such as glass is escaped；On the other hand, since hydrogen is colourless, odorless, nontoxic and inflammable and explosive, liquified hydrogen leakage
When can also cause frostbite and asphyxia etc., therefore hydrogen is typically chosen the sealing aluminium pot or steel alloy of quality densification in storage and transport process
Bottle, and appropriate ethyl mercaptan is added in hydrogen, so that sense organ is discovered.Due to the special physicochemical property of hydrogen, at present laboratory inspection
The method for surveying hydrogen is also very limited, and hydrogen generally uses gas chromatographic detection, detector to use thermal conductivity detector (TCD).
Detergent has stimulation to human body mucous membrane and skin, can cause contact dermatitis；After being discharged into water body, consumption dissolving
Oxygen, and have mild toxicity to aquatile, fish can be caused lopsided.As nonionic surface active agent has anesthesia to make fish
With making the sensory feeling ability such as taste bud reduce and lose avoiding reaction ability.Detergent sewage has a large amount of foams, water supply
Treatment plant's operating brings difficulty.Detergent content reaches a certain concentration, will produce not to the fermentation process in biological wastewater treatment
Good influence.
In daily life, the use of people's too busy to get away detergent, is not difficult to find out, detergent leads to environmental hazard
Reason is all to maintain the cost of washing effect.So to reduce harm of the detergent for environment it is necessary in holding washing effect
Above-mentioned harmful components are avoided under the premise of rate.The appearance of non-phosphide detergent is a kind of progress, they are usually using not phosphorous nothing
Machine ingredient replaces phosphate to be combined with calcium ions and magnesium ions.It is successful naturally for reducing the environmental hazard of phosphorus.But these are replaced
Enter nature for ingredient and bring other pollutions again, thus, the simple phosphate that substitutes only alleviates " popular indignation " greatly
Pollution, and not necessarily just completely eliminate the pollution of detergent.Only " without phosphorus " just declares " environmentally protective " and not responsible
Appoint.Therefore, the washing cleaning that researching and developing and promote the use of efficient Green detergent both can solve in mankind's daily life needs
It asking, while can also effectively make up the deficiency of the above method, the mankind are because using chemical detergent healthhazard for protection,
Reduce pollution simultaneously, improves environment.
Invention content
The purpose of the present invention is to solve disadvantages existing in the prior art, and a kind of Hydrogen-rich liquid biology proposed is washed
Wash agent and the preparation method and application thereof.
To achieve the goals above, present invention employs following technical solutions：
A kind of Hydrogen-rich liquid biocleaner, includes the raw material of following parts by weight：Include the hydrogen member of solvent and dissolving in a solvent
Element, the saturation degree of hydrogen is 0.1~100% in solvent, and the solvent is purified water or drinking public water supply.
Preferably, it is not added with any other substance in the solvent.
A kind of preparation method of Hydrogen-rich liquid biocleaner and application, include the following steps,
S1 prepares hydrogen first, and hydrogen is then passed through 5min or more in the solvent, and then obtains the richness of different saturation
Hydrogen liquid biological detergent；
Using water electrolysis method, either metal/water hydrogen manufacturing or photoelectrolysis method are prepared or are discharged by hydrogen gas cylinder the hydrogen；
S2, the application of the hydrogen-rich biocleaner impregnate washing clean article Hydrogen-rich liquid biocleaner
Cleaning；
The article includes clothing, fabric, greasy dirt, ceramics, metal, glass；
S3, the water electrolysis method are：Distilled water is electrolysed using 2~24V DC voltages, is done after aqueous vapor separation and drying
Dry pure hydrogen.
Preferably, photoelectrolysis hydrogen manufacturing is：Light-catalyzed reaction can be divided into two classes, including reduce energy barrier and to increase energy barrier anti-
It answers, photocatalytic oxidation degradation organic matter, which belongs to, reduces energy barrier reaction, the △ G of such reaction<0, reaction process is irreversible, this kind of anti-
It answers to cause under the action of photochemical catalyst and generates O2, HO2, OH and H+ active groups；It is then high that water decomposition, which generates H2 and O2,
Energy barrier reacts, the △ G of such reaction>0 (kJ/mo1 of △ G=237), such reaction convert light energy into chemical energy.
Advantageous effect of the present invention proposed by the present invention：We were absorbed in always hydrogen to degreasing, reduction Er Evil in recent years
The research of English etc., result of study show that hydrogen has stronger oxidation resistance, dissolve in water, become with interface activation effect
The water of fruit, and bioxin can be decomposed with air aeration；Our research also found that hydrogen can not only enhance cleaning greasy dirt
Cleaned clothing can also be made soft, it is shrink-proof etc.；Our research is it has also been found that hydrogen not only can be such as above-mentioned effect, together
When, the water pollution caused by with chemical detergent is not had with the Hydrogen-rich liquid detergent, and environmental ecology is destroyed；Used in the present invention
Be the Hydrogen-rich liquid biocleaner that can be directly sustained low-concentration hydrogen, under room temperature, hydrogen can be discharged from liquid naturally
Into air；
The present invention further confirms that hydrogen can be protected article surface by anti-oxidant.
Using Hydrogen-rich liquid biocleaner because natural interfacial activity can wash off dirt, glass, automobile do not have to chemistry
Detergent also can be shinny.
A kind of Hydrogen-rich liquid biocleaner provided by the present invention and its application, have further the advantage that：It need not rinse,
Bubble 10min is invaded, 5min is washed, because not having to chemical detergent, not only saves the time, but also save 3/4 water.Normal automatic washing machine
40 minutes are spent, need to rinse and is dehydrated.
A kind of Hydrogen-rich liquid biocleaner provided by the present invention and its application, because that can be washed without chemical detergent
All clothes, article.It cannot can be washed with feather, fur, cotton, the pure wool etc. that chemical detergent cleans in the past.
A kind of Hydrogen-rich liquid biocleaner provided by the present invention and its application be not because having to chemical detergent, so will not draw
Skin allergy etc. caused by cause chemical residual.
1）It is at low cost：Hydrogen-rich liquid biocleaner in the present invention derives from a wealth of sources, and can be obtained by electrolysis water, also be led to
It crosses metal/water hydrogen manufacturing to obtain, according to measuring and calculating, 1kgKBH4 can at least prepare 10,000 liters of saturation hydrogen-rich waters, cheap；
2）Stability is high：The density of hydrogen chemical property under normal operation of Hydrogen-rich liquid biocleaner release in the present invention
Stablize, diffusion is fast, the not danger of detonation very low using concentration；
3）Pollution-free, noresidue, environmental protection：Since hydrogen under normal operation stablize by chemical property, will not occur with environment secondary
Reaction, noresidue will not generate harmful effect to human body or environment；
Have a wide range of application：The freshness that this method can be additionally used in the bathing of daily life, cook and can improve food.
Specific implementation mode
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.
Embodiment one
A kind of preparation method of Hydrogen-rich liquid biocleaner proposed by the present invention and application, include the following steps,
S1 prepares hydrogen first, and hydrogen is then passed through 5min or more in the solvent, and then obtains the richness of different saturation
Hydrogen liquid biological detergent；
Using water electrolysis method, either metal/water hydrogen manufacturing or photoelectrolysis method are prepared or are discharged by hydrogen gas cylinder the hydrogen；
S2, the application of the hydrogen-rich biocleaner impregnate washing clean article Hydrogen-rich liquid biocleaner
Cleaning；
The article includes clothing, fabric, greasy dirt, ceramics, metal, glass；
S3, the water electrolysis method are：Distilled water is electrolysed using 2~24V DC voltages, is obtained after aqueous vapor separation and drying
Dry pure hydrogen.
Specifically, photoelectrolysis hydrogen manufacturing is：Light-catalyzed reaction can be divided into two classes, including reduce energy barrier and to increase energy barrier anti-
It answers, photocatalytic oxidation degradation organic matter, which belongs to, reduces energy barrier reaction, the △ G of such reaction<0, reaction process is irreversible, this kind of anti-
It answers to cause under the action of photochemical catalyst and generates O2, HO2, OH and H+ active groups；It is then high that water decomposition, which generates H2 and O2,
Energy barrier reacts, the △ G of such reaction>0 (kJ/mo1 of △ G=237), such reaction convert light energy into chemical energy.
Advantageous effect of the present invention proposed by the present invention：We were absorbed in always hydrogen to degreasing, reduction Er Evil in recent years
The research of English etc., result of study show that hydrogen has stronger oxidation resistance, dissolve in water, become with interface activation effect
The water of fruit, and bioxin can be decomposed with air aeration；Our research also found that hydrogen can not only enhance cleaning greasy dirt
Cleaned clothing can also be made soft, it is shrink-proof etc.；Our research is it has also been found that hydrogen not only can be such as above-mentioned effect, together
When, the water pollution caused by with chemical detergent is not had with the Hydrogen-rich liquid detergent, and environmental ecology is destroyed；Used in the present invention
Be the Hydrogen-rich liquid biocleaner that can be directly sustained low-concentration hydrogen, under room temperature, hydrogen can be discharged from liquid naturally
Into air；
The present invention further confirms that hydrogen can be protected article surface by anti-oxidant.
Using Hydrogen-rich liquid biocleaner because natural interfacial activity can wash off dirt, glass, automobile do not have to chemistry
Detergent also can be shinny.
A kind of Hydrogen-rich liquid biocleaner provided by the present invention and its application, have further the advantage that：It need not rinse,
Bubble 10min is invaded, 5min is washed, because not having to chemical detergent, not only saves the time, but also save 3/4 water.Normal automatic washing machine
40 minutes are spent, need to rinse and is dehydrated.
A kind of Hydrogen-rich liquid biocleaner provided by the present invention and its application, because that can be washed without chemical detergent
All clothes, article.It cannot can be washed with feather, fur, cotton, the pure wool etc. that chemical detergent cleans in the past.
A kind of Hydrogen-rich liquid biocleaner provided by the present invention and its application be not because having to chemical detergent, so will not draw
Skin allergy etc. caused by cause chemical residual.
1）It is at low cost：Hydrogen-rich liquid biocleaner in the present invention derives from a wealth of sources, and can be obtained by electrolysis water, also be led to
It crosses metal/water hydrogen manufacturing to obtain, according to measuring and calculating, 1kgKBH4 can at least prepare 10,000 liters of saturation hydrogen-rich waters, cheap；
2）Stability is high：The density of hydrogen chemical property under normal operation of Hydrogen-rich liquid biocleaner release in the present invention
Stablize, diffusion is fast, the not danger of detonation very low using concentration；
3）Pollution-free, noresidue, environmental protection：Since hydrogen under normal operation stablize by chemical property, will not occur with environment secondary
Reaction, noresidue will not generate harmful effect to human body or environment；
Have a wide range of application：The freshness that this method can be additionally used in the bathing of daily life, cook and can improve food.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (4)
1. a kind of Hydrogen-rich liquid biocleaner, which is characterized in that include the raw material of following parts by weight：Including solvent and it is dissolved in
Protium in solvent, the saturation degree of hydrogen is 0.1~100% in solvent, and the solvent is purified water or drinking public water supply.
2. a kind of Hydrogen-rich liquid biocleaner according to claim 1, which is characterized in that be not added with and appoint in the solvent
What his substance.
3. preparation method and the application of a kind of Hydrogen-rich liquid biocleaner, which is characterized in that include the following steps,
S1 prepares hydrogen first, and hydrogen is then passed through 5min or more in the solvent, and then obtains the richness of different saturation
Hydrogen liquid biological detergent；
Using water electrolysis method, either metal/water hydrogen manufacturing or photoelectrolysis method are prepared or are discharged by hydrogen gas cylinder the hydrogen；
S2, the application of the hydrogen-rich biocleaner impregnate washing clean article Hydrogen-rich liquid biocleaner
Cleaning；
The article includes clothing, fabric, greasy dirt, ceramics, metal, glass；
S3, the water electrolysis method are：Distilled water is electrolysed using 2~24V DC voltages, is obtained after aqueous vapor separation and drying
Dry pure hydrogen.
4. preparation method and the application of a kind of Hydrogen-rich liquid biocleaner, which is characterized in that photoelectrolysis hydrogen manufacturing is：Photocatalysis is anti-
It should can be divided into two classes, including reduce energy barrier and increase energy barrier reaction, it is anti-that photocatalytic oxidation degradation organic matter belongs to reduction energy barrier
It answers, the △ G of such reaction<0, reaction process is irreversible, causes generating O2, HO in this kind of reaction under the action of photochemical catalyst2
, OH and H+ active groups；It is then high energy barrier reaction, the △ G of such reaction that water decomposition, which generates H2 and O2,>0(△G=237 kJ/
Mo1), such reaction converts light energy into chemical energy.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810479576.9A CN108587816A (en) | 2018-05-18 | 2018-05-18 | A kind of Hydrogen-rich liquid biocleaner and the preparation method and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810479576.9A CN108587816A (en) | 2018-05-18 | 2018-05-18 | A kind of Hydrogen-rich liquid biocleaner and the preparation method and application thereof |
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| CN201810479576.9A Pending CN108587816A (en) | 2018-05-18 | 2018-05-18 | A kind of Hydrogen-rich liquid biocleaner and the preparation method and application thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111019773A (en) * | 2019-12-21 | 2020-04-17 | 张先良 | Synthetic detergent capable of automatically generating mechanical action |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1163802A (en) * | 1996-03-27 | 1997-11-05 | 佛朗帝克股份公司 | Cleaning method and apparatus for the same |
| CN106345327A (en) * | 2015-07-17 | 2017-01-25 | 野村微科学股份有限公司 | Washing hydrogen water producing method and producing apparatus |
-
2018
- 2018-05-18 CN CN201810479576.9A patent/CN108587816A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1163802A (en) * | 1996-03-27 | 1997-11-05 | 佛朗帝克股份公司 | Cleaning method and apparatus for the same |
| CN106345327A (en) * | 2015-07-17 | 2017-01-25 | 野村微科学股份有限公司 | Washing hydrogen water producing method and producing apparatus |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111019773A (en) * | 2019-12-21 | 2020-04-17 | 张先良 | Synthetic detergent capable of automatically generating mechanical action |
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