JP2006198595A - Application of electrolytic water generator to medical field - Google Patents
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本発明は、医療分野に於ける電解水生成装置の使用とその電解水の有する殺菌及び洗浄に関するものであり、特に塩害を生じない殺菌効果と洗浄能力並びに洗浄後の廃液処理が容易な各種物品及び機器の洗浄剤に関する。The present invention relates to the use of an electrolyzed water generating apparatus in the medical field and the sterilization and cleaning of the electrolyzed water. In particular, the present invention relates to sterilizing effect and cleaning ability that do not cause salt damage, and various articles that can be easily treated after washing. And a cleaning agent for equipment.
医療分野での電解水生成装置は、強酸性電解水の殺菌効果を利用した方法が殆どである。また、従来の電解水生成装置は電解水にナトリウムが混入し、使用後に塩害が生じるため充分な効果が得られない。さらに、電解水生成装置から生成された強酸性電解水と強アルカリ性電解水の両極端な電解水を充分生かすことが出来ず、いずれか一方、特に強酸性の電解水を利用するのみでは、電解水生成装置の能力を充分発揮しているとは思えない。
本発明は、電解水生成装置から生成される塩害のない強酸性電解水と強アルカリ性電解水のそれぞれの能力を生かして、医療分野で利用することを目的とする。Most electrolyzed water generators in the medical field use a method utilizing the sterilizing effect of strongly acidic electrolyzed water. Moreover, the conventional electrolyzed water generating apparatus cannot obtain a sufficient effect because sodium is mixed in the electrolyzed water and salt damage occurs after use. Furthermore, it is not possible to make full use of both extreme acidic electrolyzed water and strong alkaline electrolyzed water generated from the electrolyzed water generator, and in particular, only using strongly acidic electrolyzed water I don't think the generator is fully utilized.
An object of this invention is to utilize in the medical field | area using the capability of each of the strong acidic electrolyzed water and strong alkaline electrolyzed water without salt damage produced | generated from an electrolyzed water generating apparatus.
医療分野での電解水生成装置の利用は強酸性電解水の使用が目的で、強アルカリ性電解水の利用は充分とは言えなかった。主に、強酸性電解水の利用はアトピー性皮膚炎の殺菌と院内や寝たきり患者の滅菌及び厨房及び食材の滅菌である。しかし、電解水の中に混入するナトリウムが皮膚に刺激的であり、院内の滅菌においても建物内の金属類を酸化させ、食材の滅菌もナトリウムの混入が気になるため、効果は期待できるものの問題点を抱えていた。強酸性電解水の問題点は、ナトリウムが混入しない電解水を利用することで解決できる。ナトリウムの混入がない電解水を得るには、エレテック・エンジニアリング株式会社の開発したイオン選択透過性能を有する隔膜を用いた円筒状電極を組み込んだ電解水生成装置を使用することで目的を達成できる。
上記の通り強酸性電解水の利用が多く、医療分野では強アルカリ性電解水の利用は少なく、強アルカリ性電解水を医療に利用する方法を考えることが医療関係の発展につながる。
そこで、強アルカリ性電解水を病院内で利用可能な全ての場所、例えば院内の病室、厨房、トイレ、浴室、待合室、玄関や使用器具の洗浄剤として利用することを考案した。強アルカリ性電解水の利用においても、洗浄するに際してナトリウムが混入しない電解水を得ることが条件であるが、この条件を満たすには強酸性電解水を生成する際に同時生成される強アルカリ性電解水を使用することで解決できる。The use of electrolyzed water generators in the medical field is intended to use strongly acidic electrolyzed water, and the use of strong alkaline electrolyzed water has not been sufficient. Mainly, the use of strong acidic electrolyzed water is for the sterilization of atopic dermatitis, the sterilization of hospital and bedridden patients, and the sterilization of kitchens and foodstuffs. However, the sodium mixed in the electrolyzed water is irritating to the skin, and in the hospital sterilization, the metal in the building is oxidized, and the sterilization of the food is also worried about the mixing of sodium. I had a problem. The problem of strongly acidic electrolyzed water can be solved by using electrolyzed water that does not contain sodium. In order to obtain electrolyzed water free from sodium contamination, the object can be achieved by using an electrolyzed water generating apparatus incorporating a cylindrical electrode using a diaphragm having ion selective permeation performance developed by Eletech Engineering Co., Ltd.
As described above, strong acidic electrolyzed water is often used, and in the medical field, strong alkaline electrolyzed water is rarely used. Considering a method of using strongly alkaline electrolyzed water for medical treatment leads to the development of medical relations.
Therefore, it was devised to use strong alkaline electrolyzed water as a cleaning agent for all the places where it can be used in hospitals, such as hospital rooms, kitchens, toilets, bathrooms, waiting rooms, entrances, and appliances. Even in the use of strong alkaline electrolyzed water, it is a condition to obtain electrolyzed water that does not contain sodium during washing. To satisfy this condition, strong alkaline electrolyzed water that is simultaneously produced when producing strongly acidic electrolyzed water is used. Can be solved by using.
従来の一般洗浄剤には、フッ素化有機化合物からなる洗浄剤で、溶解性、低温での乾燥性及び基材が不溶性等の優れた特性を有するものとして広く利用されていた。フッ素化有機化合物からなる洗浄剤は、油脂等の有機質を溶解除去する洗浄剤として極めて優れているが、環境汚染、特にオゾン層破壊等の問題によってその使用が禁止されるようになった。
こうしたフッ素化有機化合物に代わる溶剤として、生態系保護ならびに環境破壊させない溶剤が開発された。開発したのは日本政府が国内電力安定のために、電力会社と協力して「電源開発株式会社」を設立、その子会社である「株式会社電発環境緑化センター」が、発電所の洗浄とその排水処理を目的に、周囲の河川や海水汚染及び生態系の変化や環境破壊を招かないように開発されたのが、緩衝材としてメタ珪酸ナトリウム或は炭酸ナトリウムを適量添加した強アルカリ性電解水による地球にやさしい洗浄剤である。この環境に優しい洗浄剤を医療分野に利用すべく、この洗浄剤の製造方法を改良し、さらに、電解水にナトリウムが混入しないように工夫を凝らした電解水生成装置を使用して、強アルカリ性電解水の洗浄剤を生成した。
総合病院や工業関係の洗浄剤は機械部品、電子部品、衣類にフッ素化有機化合物が主に使用され、一般的洗浄剤はその殆どが石油を原料とした合成洗剤、主成分に化学物質である水酸化ナトリウム(苛性ソーダ)と水酸化カリウムを原料とした食器洗浄用洗剤、動植物油に苛性ソーダを加え加熱して反応させた石鹸(脂肪酸ナトリウム)、そして塩素系を主成分とした漂白剤である。
それらの洗剤は、その排水が河川や海水を富栄養化させ、各地で汚泥やアオコそして赤潮の発生、さらに主成分であるフッ素や界面活性剤の有害性や分解の遅さなどから環境汚染の原因になっている。医療分野においても、環境破壊を招かない前記の強アルカリ性電解水の洗浄能力と強酸性電解水の殺菌能力を利用することが課題である。Conventional general detergents are widely used as detergents composed of fluorinated organic compounds having excellent properties such as solubility, drying property at low temperature, and insolubility of substrates. A cleaning agent composed of a fluorinated organic compound is extremely excellent as a cleaning agent for dissolving and removing organic substances such as fats and oils, but its use has been prohibited due to problems such as environmental pollution, particularly ozone layer destruction.
As a substitute for these fluorinated organic compounds, a solvent that protects the ecosystem and does not destroy the environment has been developed. The Japanese government has established “Power Development Co., Ltd.” in cooperation with a power company to stabilize domestic power, and its subsidiary “Dentsu Environmental Greening Center Co., Ltd.” For the purpose of wastewater treatment, it was developed so as not to cause pollution of surrounding rivers and seawater, ecosystem changes and environmental destruction, using strong alkaline electrolyzed water with an appropriate amount of sodium metasilicate or sodium carbonate added as a buffer material. It is an earth-friendly cleaning agent. In order to use this environmentally friendly cleaning agent in the medical field, the manufacturing method of this cleaning agent has been improved, and an electrolyzed water generator that has been devised to prevent sodium from being mixed into the electrolyzed water has been used to provide strong alkalinity. A detergent for electrolyzed water was produced.
General hospitals and industrial cleaning agents are mainly fluorinated organic compounds used in machine parts, electronic parts, and clothing, and most of the general cleaning agents are synthetic detergents that use petroleum as the raw material, and the main ingredients are chemical substances. It is a dishwashing detergent using sodium hydroxide (caustic soda) and potassium hydroxide as raw materials, soap (fatty acid sodium) reacted by adding caustic soda to animal and vegetable oils and heating, and a bleaching agent based on chlorine.
These detergents cause eutrophication of rivers and seawater, the generation of sludge, blue sea urchins, and red tides in each region, and the harmful effects of fluorine and surfactants, which are the main components, and the slowness of decomposition. It is the cause. Also in the medical field, it is a problem to use the strong alkaline electrolyzed water cleaning ability and the strong acidic electrolyzed water sterilizing ability that do not cause environmental destruction.
課題を解決するためには、洗浄剤に関しては界面活性剤やフッ素化有機化合物を使用しない洗浄剤を生成することである。洗浄剤の生成には電解水生成装置を使用して強アルカリ性電解水を生成し、その電解水に緩衝材として適量のメタ珪酸ナトリウムもしくは炭酸ナトリウムを添加し生成する。殺菌液の生成には生成されたペーハー3以下の強酸性電解水を使用して、殺菌作用を発揮させる。しかし、従来の電解水生成装置は電解槽の隔膜と電極との間隔を均一に保つためにスペーサを用いなければならないが、スペーサは流路障害による供給水の圧力損失や局部的な隔膜の電極への押し付けを起させるという問題点もある。さらに、スペーサを種々工夫して均一な隔膜への接触を試みても、両槽間圧力に対して中間槽圧力が最適な陽極になるように細心の注意を払う必要があり、電解槽からの生成水の取り扱いに制限が生じてしまう、もしくは煩雑な圧力バランス調整機構を設けなければならないという問題点もある。
また、中間槽圧力を上記した方法で両側槽に対して陽圧に設定すると、消耗品である隔膜の劣化により通水率が上昇し、未分解の高濃度電解質溶液が流入してしまい、電解質の余分な損失や所定の生成水物性を得られなくなる。
このような問題点を解決し、水或は電解質を含む溶液を電気透析分解して高純度の電解水を連続的に生成する装置に使用可能な電極装置及び電解槽を提供することで解決できる。In order to solve the problem, it is necessary to produce a cleaning agent that does not use a surfactant or a fluorinated organic compound. For the production of the cleaning agent, an electrolyzed water generator is used to produce strongly alkaline electrolyzed water, and an appropriate amount of sodium metasilicate or sodium carbonate is added to the electrolyzed water as a buffer material. For the production of the sterilizing solution, the generated strongly acidic electrolyzed water of pH 3 or lower is used to exert the sterilizing action. However, the conventional electrolyzed water generating apparatus must use a spacer to keep the distance between the diaphragm and the electrode of the electrolytic cell uniform. However, the spacer is a pressure loss of supply water due to a flow path failure or a local diaphragm electrode. There is also the problem of causing pressure on the Furthermore, even if various attempts are made to contact the spacer with various spacers, it is necessary to pay close attention so that the intermediate tank pressure becomes the optimum anode for the pressure between both tanks. There is also a problem in that the generated water is restricted in handling or a complicated pressure balance adjusting mechanism must be provided.
In addition, when the intermediate tank pressure is set to a positive pressure with respect to both tanks by the above-described method, the water flow rate increases due to deterioration of the diaphragm which is a consumable product, and the undecomposed high-concentration electrolyte solution flows into the electrolyte. It is impossible to obtain an extra loss of water and predetermined physical properties of the generated water.
This problem can be solved by providing an electrode device and an electrolytic cell that can be used in a device that continuously generates high-purity electrolyzed water by electrodialysis of a solution containing water or an electrolyte. .
従来の電解水生成装置は、希釈したNaCl溶液(約1000〜2000ppm)を不織布などで仕切った陽極液/陰極液に導入して電解を行う。この際、有効塩素濃度50ppmの水を生成するのに約900〜1800ppmの未分解の余剰なNaClの混入を避けることが出来ない。
本発明に使用する電解水生成装置では従来の電解水生成装置とは違い、陽極室でファラデーの法則に従い隔膜を透析されてきたCl−を電極表面にて有効塩素に励起する。この際、隔膜にイオン交換膜を使用する事により、Na+の混入を厳に制限することが出来る。
従来の電解生成装置が均一濃度のNaCl溶液中のCl−から有効塩素を生成するのに対し、本発明に使用する電解水生成装置では前述したイオン交換膜の近傍に電極を設置する事で透析されたCl−バルク溶液中に拡散する前に電極表面上にて有効塩素化されるので非常に効率の良い電解が可能である。
例えば、強酸性電解水や強アルカリ性電解水中に含まれるCl−濃度が従来の電解水生成装置の約10分の1〜8分の1の180ppm程度で有効塩素50ppmの強酸性電解水や強アルカリ性電解水を生成することが可能である。Na+に関しては、原水中に含まれるものを除けば殆ど含まれない。
このように本発明に使用する電解水生成装置で生成された強酸性電解水や強アルカリ性電解水は、NaClを殆ど含まれないため、長期間の洗浄効果を維持できる。このNaClを含まない強アルカリ性電解水に緩衝材として適量のメタ珪酸ナトリウム或は炭酸ナトリウムを添加して作られた洗浄剤は、生態系や環境を破壊することなく目的を達成できる。殺菌作用を有する強酸性電解水においても、本発明に使用する電解水生成装置はエレックス・エンジニアリング株式会社の製品を使用することで、長期間洗浄能力を維持出来る強アルカリ性電解水と殺菌効果を有する強酸性電解水を得ることができる.A conventional electrolyzed water generator performs electrolysis by introducing a diluted NaCl solution (about 1000 to 2000 ppm) into an anolyte / catholyte partitioned with a nonwoven fabric or the like. At this time, in order to produce water having an effective chlorine concentration of 50 ppm, it is unavoidable to mix undecomposed excess NaCl of about 900 to 1800 ppm.
Unlike the conventional electrolyzed water generating device, the electrolyzed water generating device used in the present invention excites Cl −, which has been dialyzed in the anode chamber according to Faraday's law, to effective chlorine on the electrode surface. At this time, by using an ion exchange membrane for the diaphragm, it is possible to strictly limit Na + contamination.
Whereas a conventional electrolysis generator produces effective chlorine from Cl- in a uniformly concentrated NaCl solution, the electrolyzed water generator used in the present invention dialyzes by installing an electrode in the vicinity of the ion exchange membrane described above. Since it is effectively chlorinated on the electrode surface before diffusing into the formed Cl-bulk solution, very efficient electrolysis is possible.
For example, the strongly acidic electrolyzed water or strong alkaline electrolyzed water has a Cl-concentration of about 180 ppm, which is about 1/10 to 1/8 of that of a conventional electrolyzed water generator, and has an effective chlorine of 50 ppm. It is possible to generate electrolyzed water. About Na +, except for what is contained in raw | natural water, it is hardly contained.
Thus, since the strongly acidic electrolyzed water and strong alkaline electrolyzed water produced | generated with the electrolyzed water generating apparatus used for this invention hardly contain NaCl, the long-term washing | cleaning effect can be maintained. A detergent made by adding an appropriate amount of sodium metasilicate or sodium carbonate as a buffer material to strong alkaline electrolyzed water not containing NaCl can achieve its purpose without destroying the ecosystem and the environment. Even in strongly acidic electrolyzed water having a bactericidal action, the electrolyzed water generating apparatus used in the present invention has a bactericidal effect with strong alkaline electrolyzed water that can maintain a long-term cleaning ability by using a product of Elex Engineering Co., Ltd. Strongly acidic electrolyzed water can be obtained.
本発明に使用する電解水生成装置から生成される強アルカリ性電解水に緩衝材としてメタ珪酸ナトリウム或は炭酸ナトリウムを適量添加した洗浄剤や強酸性電解水による殺菌効果を有する殺菌液は、その素材をできる限り天然、自然な状態に維持しかつその新鮮さを保持しつつ素材から商品化への加工工程において、添加物や熱、水、圧力、空気、酸化等の品質劣化要因の少ない商品形態に考慮しなければならない。また、一日の使用量、取扱い易さ、コスト、関係法規の要因も考慮しなければならない。
適量添加されたメタ珪酸ナトリウム或は炭酸ナトリウムを添加した強アルカリ性電解水或は殺菌作用を有する強酸性電解水の製品化は、自体公知の添加物或は賦形剤、医薬担体と自体公知の方法で配合し、効能効果を有する洗浄剤や殺菌効果を有する殺菌液とすることができる。用いる添加物は特に限定するものではなく、目的とする効能効果の具体的用途に応じて当業者が適宜選択できる。また、形態も特に限定するものではなく、具体的用途に応じていろいろな形状にすることができる。A sterilizing solution having a sterilizing effect by using a strong alkaline electrolyzed water or a detergent obtained by adding an appropriate amount of sodium metasilicate or sodium carbonate as a buffer material to the strongly alkaline electrolyzed water generated from the electrolyzed water generating device used in the present invention In the process of processing from raw materials to commercialization while maintaining the natural and natural state of the product as much as possible, the product form has few quality deterioration factors such as additives, heat, water, pressure, air, oxidation, etc. Must be taken into account. In addition, factors such as daily usage, ease of handling, cost, and related laws and regulations must be considered.
Commercialization of strongly alkaline electrolyzed water added with an appropriate amount of sodium metasilicate or sodium carbonate or strongly acidic electrolyzed water having a bactericidal effect is known per se. It mix | blends by the method and it can be set as the cleaning agent which has an effect effect, and the sterilization liquid which has a bactericidal effect. The additive to be used is not particularly limited, and can be appropriately selected by those skilled in the art depending on the specific use of the intended effect. Further, the form is not particularly limited, and various shapes can be used according to specific applications.
群馬県猿ヶ京温泉の「万葉亭」は、40名程度収容の旅館で、厨房に全自動食器洗浄機を使用している。その全自動食器洗浄機に3倍希釈のメタ珪酸ナトリウム入り強アルカリ性電解水を使用した。結果、非常に食器類の油やタンパク質の汚れ落ちが良く、洗浄機のガラス窓も中の状態が見えるようになった。泡がたたないため使いやすく、風呂の掃除にも使用している。“Manyotei” in Sarugakyo Onsen, Gunma Prefecture is a ryokan that can accommodate about 40 people and uses a fully automatic dishwasher in the kitchen. Strong alkaline electrolyzed water containing sodium metasilicate diluted 3 times was used for the fully automatic dishwasher. As a result, the oil and protein in the tableware were very well removed, and the inside of the glass window of the washing machine became visible. It is easy to use because it doesn't batter, and it is also used for bath cleaning.
4人家族で、夕食に中華料理を食べた。食後に食器を洗う際に、メタ珪酸ナトリウムを添加した強アルカリ性電解水の原液を水道水で100倍に希釈して液を作り、油が多く付着した食器を100倍希釈のメタ珪酸ナトリウム入り強アルカリ性電解水を入れたポリバケツにどぶ漬けした。30秒程度時間を置いて、お湯で食器を洗った。油分や汚れが取れ食器に光沢が出た。A family of four ate Chinese food for dinner. When washing dishes after a meal, a strong alkaline electrolyzed water solution with sodium metasilicate added is diluted 100-fold with tap water to make a solution. It was soaked in a plastic bucket containing alkaline electrolyzed water. After about 30 seconds, the dishes were washed with hot water. The oil and dirt were removed and the tableware became shiny.
強酸性電解水は岡山県玉野市にある山田病院で効果を試した。この副院長山田真人氏は、全身アトピー性皮膚炎に悩まされている。全身に常にかゆみを伴い、休む間も無く、身体をかきむしる。今までも、従来型の電解水生成装置の強酸性電解水を使用したことがあるが、ナトリウムが混入している強酸性電解水は、傷ついた皮膚には刺激的で使用を続けることが出来なかった。本発明に使用する電解装置から生成された強酸性電解水を風呂上りに吹きかけたところ、皮膚に刺激を感じることがなく、皮膚のかゆみも感じなくなった。The effect of strongly acidic electrolyzed water was tested at Yamada Hospital in Tamano City, Okayama Prefecture. This assistant director Masato Yamada suffers from systemic atopic dermatitis. The body is always itchy and there is no time to rest, and the body is scratched. Until now, we used strong acid electrolyzed water from conventional electrolyzed water generators, but strong acid electrolyzed water mixed with sodium is irritating to damaged skin and can continue to be used. There wasn't. When strong acidic electrolyzed water generated from the electrolyzer used in the present invention was sprayed over the bath, no irritation was felt on the skin and no itching of the skin was felt.
メタ珪酸ナトリウムを添加した強アルカリ性電解水は、界面活性剤より環境に優しく、洗浄効果も優れている。特に、油脂、タンパク質の分解に能力を発揮するため、食器を洗浄することで、処理水が排水溝をきれいにし、さらにグリストラップの清掃にも役立つ。Strong alkaline electrolyzed water to which sodium metasilicate has been added is more environmentally friendly than a surfactant and has an excellent cleaning effect. In particular, because it demonstrates its ability to decompose fats and oils and proteins, by washing the dishes, the treated water cleans the drain and further helps clean the grease strap.
従来の電解水生成装置で生成されたメタ珪酸ナトリウムを添加した強アルカリ性電解水は、発電所はもとより、新幹線の車体洗浄、ジェット機の機体洗浄、外車車体の油落し、洗濯会社の洗浄剤、油脂使用の製造会社にとすでに使用されている。Strong alkaline electrolyzed water added with sodium metasilicate produced by conventional electrolyzed water generators is used for power stations, Shinkansen car body washing, jet machine air washing, foreign car body oil spills, washing company detergents, oils and fats Used by the manufacturing company and already used.
従来の電解水生成装置は強酸性電解水を皮膚炎の消炎作用に利用されている。長野県の飯田病院は強酸性電解水を使用して、アトピー性皮膚炎の治療に使用していることで有名である。強酸性水の効果は充分期待できるため、全国の病院で強酸性電解水が利用されている。Conventional electrolyzed water generators use strongly acidic electrolyzed water for the anti-inflammatory action of dermatitis. Iida Hospital in Nagano Prefecture is famous for using strongly acidic electrolyzed water to treat atopic dermatitis. Since the effect of strong acidic water can be expected sufficiently, strong acidic electrolyzed water is used in hospitals nationwide.
本発明に使用される電解水生成装置で生成された強アルカリ性電解水は、NaClを出来る限り除去した画期的な洗浄剤として利用ことが出来る。さらに、本発明に使用される電解水生成装置の特徴である生成電解水にNaClを混入させない利点を生かして、強アルカリ性電解水の洗浄剤のみだけでなく同時生成される殺菌効果を有する強酸性電解水も、従来の使用方法で効果を発揮することが出来る。The strongly alkaline electrolyzed water produced by the electrolyzed water producing apparatus used in the present invention can be used as an innovative cleaning agent from which NaCl is removed as much as possible. Furthermore, taking advantage of the fact that NaCl is not mixed into the generated electrolyzed water, which is a feature of the electrolyzed water generating apparatus used in the present invention, not only a strong alkaline electrolyzed water cleaning agent but also a strong acidity having a sterilizing effect that is generated simultaneously. Electrolyzed water can also be effective with conventional methods of use.
さらに、農業では従来の電解水生成装置の問題点である未分解の高濃度電解質溶液の流入、電解質の隔膜の劣化による損失、有害ガスの発生等を解決した本発明に使用する電解水生成装置により、塩害を起さないため無農薬栽培に十分効果を発揮できるようになった。
本発明に使用する電解水生成装置を利用して、カゴメ株式会社が無農薬栽培に着手した。Furthermore, in agriculture, the electrolyzed water generator used in the present invention solves the problems of conventional electrolyzed water generators such as inflow of undecomposed high-concentration electrolyte solution, loss due to deterioration of electrolyte diaphragm, generation of harmful gases, etc. As a result, salt damage is not caused, so that it is possible to exert a sufficient effect on pesticide-free cultivation.
Kagome Co., Ltd. has begun pesticide-free cultivation using the electrolyzed water generator used in the present invention.
医療分野では皮膚にナトリウムが付着しないためアトピー性皮膚炎の治療に、また、病院内の設備がナトリウムの弊害を受けず、院内感染の予防や寝たきり患者の滅菌そして医療施設や機器の洗浄にも利用できる。In the medical field, sodium does not adhere to the skin, so it can be used to treat atopic dermatitis. Also, hospital facilities are not affected by sodium, preventing hospital infections, sterilizing bedridden patients, and cleaning medical facilities and equipment. Available.
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Cited By (3)
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EP2450313A1 (en) * | 2010-11-09 | 2012-05-09 | Caliopa AG | Method for producing an electrochemically activated solution by means of electrolysis |
JP5238899B1 (en) * | 2012-07-13 | 2013-07-17 | 稔 菅野 | Disinfecting water generating apparatus and disinfecting cleaning method |
CN112998541A (en) * | 2021-02-27 | 2021-06-22 | 陈玉霞 | Intelligent soybean milk machine capable of achieving rapid filtration |
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Publication number | Priority date | Publication date | Assignee | Title |
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EP2450313A1 (en) * | 2010-11-09 | 2012-05-09 | Caliopa AG | Method for producing an electrochemically activated solution by means of electrolysis |
WO2012062461A1 (en) * | 2010-11-09 | 2012-05-18 | Caliopa Ag | Method for generating an electrochemically activated solution by electrolysis |
JP5238899B1 (en) * | 2012-07-13 | 2013-07-17 | 稔 菅野 | Disinfecting water generating apparatus and disinfecting cleaning method |
CN112998541A (en) * | 2021-02-27 | 2021-06-22 | 陈玉霞 | Intelligent soybean milk machine capable of achieving rapid filtration |
CN112998541B (en) * | 2021-02-27 | 2023-02-03 | 广东德玛仕家电有限公司 | Intelligent soybean milk machine capable of achieving rapid filtration |
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