CN108587333A - A kind of low peculiar smell PE coating and preparation method thereof - Google Patents

A kind of low peculiar smell PE coating and preparation method thereof Download PDF

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Publication number
CN108587333A
CN108587333A CN201810403795.9A CN201810403795A CN108587333A CN 108587333 A CN108587333 A CN 108587333A CN 201810403795 A CN201810403795 A CN 201810403795A CN 108587333 A CN108587333 A CN 108587333A
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Prior art keywords
coating
parts
weight
agent
trade mark
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CN201810403795.9A
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Chinese (zh)
Inventor
刘炳国
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China Zhanchen Paints Group Ltd
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China Zhanchen Paints Group Ltd
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Priority to CN201810403795.9A priority Critical patent/CN108587333A/en
Publication of CN108587333A publication Critical patent/CN108587333A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/04Homopolymers or copolymers of ethene
    • C09D123/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0893Zinc

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention belongs to paint fields more particularly to a kind of low peculiar smell PE coating and preparation method thereof.Coating provided by the invention in terms of parts by weight, including:60~80 parts of PE resins;10~30 parts of filler;0.1~0.3 part of polymerization inhibitor;0.5~5 part of anti-settling agent;1~8 part of solvent;0.1~0.5 part of Ricinate;0.1~0.3 part of antifoaming agent;0.1~0.5 part of levelling agent;0.05~0.5 part of PE eliminating smell agents;0.05~0.2 part of PE mask agents;The trade mark of the PE eliminating smell agents is CPEJ 11;The trade mark of the PE mask agents is OA 10.The content of each component, can be obviously reduced the peculiar smell of PE coating in eliminating smell agent and mask agent and optimization design coating that the present invention passes through the specific trade mark of addition of arranging in pairs or groups in PE coating, efficiently solve PE coating big problem of peculiar smell in construction, polishing.

Description

A kind of low peculiar smell PE coating and preparation method thereof
Technical field
The invention belongs to paint fields more particularly to a kind of low peculiar smell PE coating and preparation method thereof.
Background technology
Paint be it is a kind of can securely be covered in body surface, the chemistry for playing protection, decoration, mark and other specific uses is mixed Close object coating.Paint is generally made of four part such as film forming matter, filler, solvent, auxiliary agent.
Paint currently used for woodenware product is there are many planting, as country is increasingly stringenter coating environmental requirement, PE paints There has also been significant progress, application is also more and more extensive.PE coating occupies certain market share on the market, but due to PE Paint product contains unsaturated-resin and styrene monomer, and peculiar smell is larger, and painter is difficult often by having in construction, polishing A little people even can nausea and vomiting.
Invention content
In view of this, the purpose of the present invention is to provide a kind of low peculiar smell PE coating and preparation method thereof, the present invention provides PE coating peculiar smell it is smaller, without pungent sense when construction operation.
The present invention provides a kind of low peculiar smell PE coating, in terms of parts by weight, including following components:
The trade mark of the PE eliminating smell agents is CPEJ-11;
The trade mark of the PE mask agents is OA-10.
Preferably, the trade mark of the PE resins is FX-8304.
Preferably, the filler includes one or more in talcum powder, zinc powder and transparent powder.
Preferably, the polymerization inhibitor includes hydroquinone.
Preferably, the trade mark of the anti-settling agent includes one or more in A200, SD-1 and HX-8800.
Preferably, the trade mark of the Ricinate includes EFKA4010 and/or BYK-103.
Preferably, the trade mark of the antifoaming agent includes EFKA2720 and/or HX-2300.
Preferably, the trade mark of the levelling agent includes HX3200 and/or BYK-358N.
Preferably, the solvent includes ethyl acetate and/or ethylene.
The present invention provides a kind of preparation methods of coating described in above-mentioned technical proposal, include the following steps:
By PE resins, filler, polymerization inhibitor, anti-settling agent, solvent, Ricinate, antifoaming agent, levelling agent, PE eliminating smell agents and PE mask agents mix, and obtain low peculiar smell PE coating.
Compared with prior art, the present invention provides a kind of low peculiar smell PE coating and preparation method thereof.It is provided by the invention Coating in terms of parts by weight, including:60~80 parts of PE resins;10~30 parts of filler;0.1~0.3 part of polymerization inhibitor;Anti-settling agent 0.5 ~5 parts;1~8 part of solvent;0.1~0.5 part of Ricinate;0.1~0.3 part of antifoaming agent;0.1~0.5 part of levelling agent;PE is removed 0.05~0.5 part of taste agent;0.05~0.2 part of PE mask agents;The trade mark of the PE eliminating smell agents is CPEJ-11;The PE mask agents The trade mark be OA-10.The present invention adds the eliminating smell agent and mask agent of the specific trade mark by arranging in pairs or groups in PE coating, and optimization is set The content for counting each component in coating, can be obviously reduced the peculiar smell of PE coating, and it is different in construction, polishing to efficiently solve PE coating The big problem of taste.The coating can large-area construction, a variety of forms of construction work such as spraying, showering can be used, be well it is environmental-friendly Type coating.Assuming that coating smell is divided into five etc., first etc. by we:Smelling good;Second etc.:Without pungent;Third etc.:It is slight pungent; 4th etc.:It is larger pungent;5th equal stenches.General PE coating products are essentially all that the 4th is equal or the 5th waits gas in the market Taste, and the smell of low peculiar smell PE coating provided by the invention can reach second etc., product is not pungent.
Specific implementation mode
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field Art personnel acquired every other embodiment without making creative work belongs to the model that the present invention protects It encloses.
The present invention provides a kind of low peculiar smell PE coating, in terms of parts by weight, including following components:
The trade mark of the PE eliminating smell agents is CPEJ-11;
The trade mark of the PE mask agents is OA-10.
PE coating provided by the invention includes PE resins, filler, polymerization inhibitor, anti-settling agent, solvent, Ricinate, defoaming Agent, levelling agent, PE eliminating smell agents and PE mask agents.Wherein, the trade mark of the PE resins is preferably FX-8304.In the present invention, board It number is preferably provided by the prosperous chemical industry in side for the PE resins of FX-8304, is a kind of PE resin materials of low smell.In the present invention, Content of the PE resins in coating is 60~80 parts by weight, concretely 60 parts by weight, 61 parts by weight, 62 parts by weight, 63 Parts by weight, 64 parts by weight, 65 parts by weight, 66 parts by weight, 67 parts by weight, 68 parts by weight, 69 parts by weight, 70 parts by weight, 71 weight Part, 72 parts by weight, 73 parts by weight, 74 parts by weight, 75 parts by weight, 76 parts by weight, 77 parts by weight, 78 parts by weight, 79 parts by weight or 80 parts by weight.
In the present invention, the filler includes but not limited to one or more in talcum powder, zinc powder and transparent powder.At this In invention, the talcum powder is preferably provided by the wide chemical industry in Jiangmen osmanthus, and the zinc powder is preferably provided by hundred Li He companies, described transparent Powder is preferably provided by Ao Te companies.In the present invention, content of the filler in coating is 10~30 parts by weight, concretely 10 parts by weight, 11 parts by weight, 12 parts by weight, 13 parts by weight, 14 parts by weight, 15 parts by weight, 16 parts by weight, 17 parts by weight, 18 weights Measure part, 19 parts by weight, 20 parts by weight, 21 parts by weight, 22 parts by weight, 23 parts by weight, 24 parts by weight, 25 parts by weight, 26 parts by weight, 27 parts by weight, 28 parts by weight, 29 parts by weight or 30 parts by weight.
In the present invention, the polymerization inhibitor includes but not limited to hydroquinone.In the present invention, the polymerization inhibitor is in coating In content be 0.1~0.3 parts by weight, concretely 0.1 parts by weight, 0.15 parts by weight, 0.2 parts by weight, 0.25 parts by weight or 0.3 parts by weight.
In the present invention, the trade mark of the anti-settling agent includes but not limited to one kind or more in A200, SD-1 and HX-8800 Kind.In the present invention, the trade mark is preferably provided by goldschmidt chemical corporation for the anti-settling agent of A200, the trade mark be SD-1 anti-settling agent preferably by This company of hamming provides, and the trade mark is preferably provided by China's auxiliary agent for the anti-settling agent of HX-8800.In the present invention, the anti-settling agent Content in coating is 0.5~5 parts by weight, concretely 0.5 parts by weight, 1 parts by weight, 1.5 parts by weight, 2 parts by weight, 2.5 Parts by weight, 3 parts by weight, 3.5 parts by weight, 4 parts by weight, 4.5 parts by weight or 5 parts by weight.
In the present invention, the solvent includes but not limited to ethyl acetate and/or ethylene.In the present invention, the solvent Content in coating is 1~8 parts by weight, concretely 1 parts by weight, 2 parts by weight, 3 parts by weight, 4 parts by weight, 5 parts by weight, 6 Parts by weight, 7 parts by weight or 8 parts by weight.
In the present invention, the trade mark of the Ricinate includes but not limited to EFKA4010 and/or BYK-103.At this In invention, the trade mark is preferably provided by Efka company for the Ricinate of EFKA4010, and the moistening that the trade mark is BYK-103 is disperseed Agent is preferably provided by German BYK companies.In the present invention, content of the Ricinate in coating is 0.1~0.5 weight Part, concretely 0.1 parts by weight, 0.2 parts by weight, 0.3 parts by weight, 0.4 parts by weight or 0.5 parts by weight.
In the present invention, the trade mark of the antifoaming agent includes but not limited to EFKA2720 and/or HX-2300.In the present invention In, the trade mark is preferably provided by Efka company for the antifoaming agent of EFKA2720, and the trade mark is the antifoaming agent of HX-2300 preferably by China Auxiliary agent provides.In the present invention, content of the antifoaming agent in coating is 0.1~0.3 parts by weight, concretely 0.1 weight Part, 0.15 parts by weight, 0.2 parts by weight, 0.25 weight or 0.3 parts by weight.
In the present invention, the trade mark of the levelling agent includes but not limited to HX3200 and/or BYK-358N.In the present invention In, the trade mark is preferably provided by China's auxiliary agent for the levelling agent of HX3200, and the trade mark is the levelling agent of BYK-358N preferably by German BYK Company provides.In the present invention, content of the levelling agent in coating is 0.1~0.5 parts by weight, concretely 0.1 weight Part, 0.2 parts by weight, 0.3 parts by weight, 0.4 parts by weight or 0.5 parts by weight.
In the present invention, the trade mark of the PE eliminating smell agents is CPEJ-11.The trade mark is that the PE of CPEJ-11 is removed in the present invention Taste agent is preferably provided by Hangzhou get Li Ke Co., Ltds.In the present invention, content of the PE eliminating smell agents in coating is preferably 0.05~0.5 parts by weight, concretely 0.05 parts by weight, 0.1 parts by weight, 0.15 parts by weight, 0.2 parts by weight, 0.25 parts by weight, 0.3 parts by weight, 0.35 parts by weight, 0.4 parts by weight, 0.45 parts by weight or 0.5 parts by weight.
In the present invention, the trade mark of the PE mask agents is OA-10.The trade mark is the PE mask agents of OA-10 in the present invention It is preferred that being provided by Shanghai Tuo Bang companies.In the present invention, content of the PE mask agents in coating is preferably 0.05~0.2 weight Part is measured, concretely 0.05 parts by weight, 0.1 parts by weight, 0.15 parts by weight or 0.2 parts by weight.
The present invention provides a kind of preparation methods of coating described in above-mentioned technical proposal, include the following steps:
By PE resins, filler, polymerization inhibitor, anti-settling agent, solvent, Ricinate, antifoaming agent, levelling agent, PE eliminating smell agents and PE mask agents mix, and obtain low peculiar smell PE coating.
In preparation method provided by the invention, directly above-mentioned each component is mixed in proportion and can be obtained low peculiar smell PE coating, specific mixed process are preferably:PE resins, polymerization inhibitor, Ricinate and antifoaming agent are first added in dispersion machine, Filler is added, is dispersed to after requiring fineness and remaining component is added, is uniformly mixed.Wherein, the fineness preferably≤55 μm.
The eliminating smell agent and mask agent and optimization design coating that the present invention passes through the specific trade mark of addition of arranging in pairs or groups in PE coating The peculiar smell of PE coating can be obviously reduced in the content of middle each component, and it is big to efficiently solve PE coating peculiar smell in construction, polishing Problem.The coating can large-area construction, a variety of forms of construction work such as spraying, showering can be used, be good Environmentally friendly coatings. Assuming that coating smell is divided into five etc., first etc. by we:Smelling good;Second etc.:Without pungent;Third etc.:It is slight pungent;4th etc.: It is larger pungent;5th equal stenches.General PE coating products are essentially all the 4th etc. or the 5th equal smells in the market, and this hair The smell of the low peculiar smell PE coating of bright offer can reach second etc., and product is not pungent.
For the sake of becoming apparent from, it is described in detail below by following embodiment and comparative example.
In following embodiment provided by the invention and comparative example, used PE resins are the FX-8304 of the prosperous chemical industry in side, Filler is the talcum powder that the wide chemical industry in Jiangmen osmanthus provides, and polymerization inhibitor is hydroquinone, and anti-settling agent is the A200 of goldschmidt chemical corporation, solvent For ethylene, Ricinate is the EFKA4010 of Efka company, and antifoaming agent is the EFKA2720 of Efka company, and levelling agent is The HX3200 of China's auxiliary agent, PE eliminating smell agent are the CPEJ-11 of Hangzhou get Li Ke Co., Ltds, and PE mask agents are Shanghai Tuo Bang companies OA-10.
Embodiment 1
1) component and parts by weight:
65 parts of PE resins, 28 parts of filler, polymerization inhibitor 0.2,1 part of anti-settling agent, 5 parts of solvent, 0.2 part of Ricinate, defoaming 0.2 part of agent, levelling agent 0.2,0.1 part of PE eliminating smell agents, 0.1 part of PE mask agents.
2) preparation process:
PE resins, polymerization inhibitor, Ricinate, antifoaming agent is first added, adds filler, high speed dispersion to fineness qualification Remaining component is added in (≤55 μm) afterwards, stirs evenly, and obtains low peculiar smell PE coating.
Above-mentioned low peculiar smell PE coating is sprayed on furniture, need to add accounting for PE coating qualities 1% before spraying in coating PE accelerating agents (cobalt naphthenate) and the PE initiators (Methyl Ethyl Ketone Oxidation) for accounting for PE coating qualities 1% wait for 8 hours after spraying one time Or after drying overnight, polish flat, then spray next time, it sprays two to three times in total.Painter is in spraying, polishing, paint Work will not feel that peculiar smell is big, nausea and vomiting.Assuming that coating smell is divided into five etc., first etc. by we:Smelling good;Second etc.:It is stingless Nose;Third etc.:It is slight pungent;4th etc.:It is larger pungent;5th equal stenches.Then low peculiar smell PE coating provided in this embodiment Smell can reach second etc..
Embodiment 2
1) component and parts by weight:
78 parts of PE resins, 15 parts of filler, polymerization inhibitor 0.2,2 parts of anti-settling agent, 3 parts of solvent, 0.3 part of Ricinate, defoaming 0.2 part of agent, levelling agent 0.3,0.2 part of PE eliminating smell agents, 0.1 part of PE mask agents.
2) preparation process:
PE resins, polymerization inhibitor, Ricinate, antifoaming agent is first added, adds filler, high speed dispersion to fineness qualification Remaining component is added in (≤55 μm) afterwards, stirs evenly, and obtains low peculiar smell PE coating.
Above-mentioned low peculiar smell PE coating is sprayed on furniture, need to add accounting for PE coating qualities 1% before spraying in coating PE accelerating agents (cobalt naphthenate) and the PE initiators (Methyl Ethyl Ketone Oxidation) for accounting for PE coating qualities 1% wait for 8 hours after spraying one time Or after drying overnight, polish flat, then spray next time, it sprays two to three times in total.Painter is in spraying, polishing, paint Work will not feel that peculiar smell is big, nausea and vomiting.Assuming that coating smell is divided into five etc., first etc. by we:Smelling good;Second etc.:It is stingless Nose;Third etc.:It is slight pungent;4th etc.:It is larger pungent;5th equal stenches.Then low peculiar smell PE coating provided in this embodiment Smell can reach second etc..
Comparative example 1
1) component and parts by weight:
65 parts of PE resins, 28 parts of filler, polymerization inhibitor 0.2,1 part of anti-settling agent, 5 parts of solvent, 0.2 part of Ricinate, defoaming 0.2 part of agent, levelling agent 0.2.
2) preparation process:
PE resins, polymerization inhibitor, Ricinate, antifoaming agent is first added, adds filler, high speed dispersion to fineness qualification Remaining component is added in (≤55 μm) afterwards, stirs evenly, and obtains PE coating.
Above-mentioned PE coating is sprayed on furniture, the PE promotions for accounting for PE coating qualities 1% need to be added before spraying in coating Agent (cobalt naphthenate) and the PE initiators (Methyl Ethyl Ketone Oxidation) for accounting for PE coating qualities 1%, spraying one time after, wait for 8 hours or every It after night drying, polishes flat, then sprays next time, spray two to three times in total.In spraying, polishing, painter can feel painter It is big to peculiar smell, nausea and vomiting.Assuming that coating smell is divided into five etc., first etc. by we:Smelling good;Second etc.:Without pungent;Third Deng:It is slight pungent;4th etc.:It is larger pungent;5th equal stenches.The smell for the PE coating that then this comparative example provides can reach the Four etc..
Comparative example 2
1) component and parts by weight:
65 parts of PE resins, 28 parts of filler, polymerization inhibitor 0.2,1 part of anti-settling agent, 5 parts of solvent, 0.2 part of Ricinate, defoaming 0.2 part of agent, levelling agent 0.2,0.3 part of PE eliminating smell agents.
2) preparation process:
PE resins, polymerization inhibitor, Ricinate, antifoaming agent is first added, adds filler, high speed dispersion to fineness qualification Remaining component is added in (≤55 μm) afterwards, stirs evenly, and obtains PE coating.
Above-mentioned PE coating is sprayed on furniture, the PE promotions for accounting for PE coating qualities 1% need to be added before spraying in coating Agent (cobalt naphthenate) and the PE initiators (Methyl Ethyl Ketone Oxidation) for accounting for PE coating qualities 1%, spraying one time after, wait for 8 hours or every It after night drying, polishes flat, then sprays next time, spray two to three times in total.In spraying, polishing, painter can feel painter To there is peculiar smell, nausea.Assuming that coating smell is divided into five etc., first etc. by we:Smelling good;Second etc.:Without pungent;Third etc.:Gently Aculea nose;4th etc.:It is larger pungent;5th equal stenches.The smell for the PE coating that then this comparative example provides can reach third etc..
Comparative example 3
1) component and parts by weight:
65 parts of PE resins, 28 parts of filler, polymerization inhibitor 0.2,1 part of anti-settling agent, 5 parts of solvent, 0.2 part of Ricinate, defoaming 0.2 part of agent, levelling agent 0.2,0.3 part of PE mask agents.
2) preparation process:
PE resins, polymerization inhibitor, Ricinate, antifoaming agent is first added, adds filler, high speed dispersion to fineness qualification Remaining component is added in (≤55 μm) afterwards, stirs evenly, and obtains PE coating.
Above-mentioned PE coating is sprayed on furniture, the PE promotions for accounting for PE coating qualities 1% need to be added before spraying in coating Agent (cobalt naphthenate) and the PE initiators (Methyl Ethyl Ketone Oxidation) for accounting for PE coating qualities 1%, spraying one time after, wait for 8 hours or every It after night drying, polishes flat, then sprays next time, spray two to three times in total.In spraying, polishing, painter can feel painter To there is peculiar smell, nausea.Assuming that coating smell is divided into five etc., first etc. by we:Smelling good;Second etc.:Without pungent;Third etc.:Gently Aculea nose;4th etc.:It is larger pungent;5th equal stenches.The smell for the PE coating that then this comparative example provides can reach third etc..
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered It is considered as protection scope of the present invention.

Claims (10)

1. a kind of low peculiar smell PE coating, in terms of parts by weight, including following components:
The trade mark of the PE eliminating smell agents is CPEJ-11;
The trade mark of the PE mask agents is OA-10.
2. coating according to claim 1, which is characterized in that the trade mark of the PE resins is FX-8304.
3. coating according to claim 1, which is characterized in that the filler includes in talcum powder, zinc powder and transparent powder It is one or more.
4. coating according to claim 1, which is characterized in that the polymerization inhibitor includes hydroquinone.
5. coating according to claim 1, which is characterized in that the trade mark of the anti-settling agent includes A200, SD-1 and HX- It is one or more in 8800.
6. coating according to claim 1, which is characterized in that the trade mark of the Ricinate include EFKA4010 and/ Or BYK-103.
7. coating according to claim 1, which is characterized in that the trade mark of the antifoaming agent includes EFKA2720 and/or HX- 2300。
8. coating according to claim 1, which is characterized in that the trade mark of the levelling agent includes HX3200 and/or BYK- 358N。
9. coating according to claim 1, which is characterized in that the solvent includes ethyl acetate and/or ethylene.
10. a kind of preparation method of any one of claim 1~9 coating, includes the following steps:
PE resins, filler, polymerization inhibitor, anti-settling agent, solvent, Ricinate, antifoaming agent, levelling agent, PE eliminating smell agents and PE are hidden Taste agent mixes, and obtains low peculiar smell PE coating.
CN201810403795.9A 2018-04-28 2018-04-28 A kind of low peculiar smell PE coating and preparation method thereof Pending CN108587333A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1432608A (en) * 2002-01-16 2003-07-30 大塚化学株式会社 Aldelyde deodorant composition and deodorizing aldehyde paint
CN103589246A (en) * 2012-08-16 2014-02-19 展辰涂料集团股份有限公司 Polyethylene paint
CN105524553A (en) * 2014-10-21 2016-04-27 庄小侃 High-concentrated water-soluble water-proof coating
CN107936447A (en) * 2017-10-27 2018-04-20 中广核俊尔新材料有限公司 It is a kind of dust-proof low to distribute low-odor thermoplastic elastomer and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1432608A (en) * 2002-01-16 2003-07-30 大塚化学株式会社 Aldelyde deodorant composition and deodorizing aldehyde paint
CN103589246A (en) * 2012-08-16 2014-02-19 展辰涂料集团股份有限公司 Polyethylene paint
CN105524553A (en) * 2014-10-21 2016-04-27 庄小侃 High-concentrated water-soluble water-proof coating
CN107936447A (en) * 2017-10-27 2018-04-20 中广核俊尔新材料有限公司 It is a kind of dust-proof low to distribute low-odor thermoplastic elastomer and preparation method thereof

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Application publication date: 20180928