CN108587304A - A kind of wood surface silk-screen printing aqueous UV ink and preparation method - Google Patents
A kind of wood surface silk-screen printing aqueous UV ink and preparation method Download PDFInfo
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- CN108587304A CN108587304A CN201810309761.3A CN201810309761A CN108587304A CN 108587304 A CN108587304 A CN 108587304A CN 201810309761 A CN201810309761 A CN 201810309761A CN 108587304 A CN108587304 A CN 108587304A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to a kind of novel timber surface screen-printeds to be become with aqueous UV ink and preparation method, group:Aqueous UV resins link stuff 40% 80%, deionized water 10% 40%, pigment 3% 30%, absolute ethyl alcohol 1% 10%, photoinitiator 0.5% 4%, wetting dispersing agent 0.1% 3%, levelling agent 1% 6%, coalescents 1% 10%, surfactant 0.1% 2%, conditioning agent 0.1% 5%, aqueous defoamer 0.01% 3%, resistance to anti-agent 0.01% 3%, the above component the sum of be 100%.This invention ink in addition to rate of drying is fast, low energy consumption, high resistance, the advantages that large-scale production may be implemented other than, also simplify technological process instead of technological means such as traditional timber surface faced deorative, transfers in technique.
Description
Technical field
The invention belongs to ink areas, are related to a kind of wood surface ink, and especially a kind of wood surface silk-screen printing is used
Aqueous UV ink and preparation method.
Background technology
Wood surface decoration refers to use and the decorative visual requirement according to wood materials and product, is carried out to wood surface
Decorate the process of processing.The wood surface decoration technique of mainstream includes currently on the market:Covering with paint processing, decorating base paper post processing
And machining processes.However, original technology haves the shortcomings that complex manufacturing technology and energy consumption are big.With printing and ink
The development of technology makes it possible that wood surface directly prints decoration technique, changes existing decorating base paper decoration treatment process,
Process means are simplified, there is preferable application value.
Aqueous UV ink is matched by prepolymer (water base light-cured resin), pigment, deionized water, photoinitiator, auxiliary agent etc.
A kind of novel ink made of system.Compared with conventional organic solvents type ink and oiliness UV ink, aqueous UV ink has safety
It is environmentally friendly, nontoxic, be practically free of the advantages that volatile organic matter.
Decoration is directly printed on wood surface using aqueous UV ink, there is simple for process, environmental-friendly, safety and environmental protection
The features such as, meet the requirement of the environmentally protective decoration of wood surface, is wood surface decoration technique new trend.
According to retrieval, it is found that specific disclosure is as follows as follows with the application relevant patent document:
1, a kind of wear-resisting type UV cured printing ink compositions (106318020A), include the component of following parts by weight:Epoxy third
50-70 parts of olefin(e) acid ester, bis- [2- (methacryloxy) ethyoxyl] 10-20 parts of dimethylsilanes, 2-8 parts of photoinitiator are fine
Plain 2-8 parts of the aeroge of dimension, 5-15 parts of pigment, 3-7 parts of levelling agent.
2, a kind of water-borne UV-curing ink and preparation method thereof (102977684B), component and mass percentage are:
Silica sol modified aqueous polyurethane acrylate prepolymer 60%-85%, photoinitiator 1%-10%, pigment 5%-15%,
Solvent 5%-20%, auxiliary agent 0-1%.The ink is environment-protecting and non-poisonous, and solidification rate is fast, and stability is good, and ageing-resistant and solvent resistance is excellent
Good, adhesive force and abrasion resistance properties are excellent, are suitble to a variety of mode of printings and production requirement, can be widely applied to paper material, wood
The surface of the stocks such as material, plastics, metal, glass.
3, a kind of hydroxyl silicon oil modified aqueous UV ink and preparation method thereof (103613993A), component and quality percentage
Content is:Hydroxyl silicon oil modified hyperbranched aqueous polyurethane acrylic ester prepolymer (binder) 60~85%, photoinitiator
1~10%, pigment 5~15%, solvent 5~20%, auxiliary agent 0~1%.Prepolymer, pigment and solvent is taken to carry out respectively according to the ratio
It is fully ground, 1~2h is disperseed under 40~50 DEG C, 400~600rpm rotating speeds, photoinitiator and auxiliary agent is added, stirs evenly,
It stands and obtains the aqueous UV ink of the present invention.
Above-mentioned patent does not use the aqueous UV resins link stuff in the present invention, and the technique effect obtained with the present invention is not
Together, the novelty and creativeness of the present invention are not influenced.
Invention content
The present invention is in view of the deficiencies of the prior art.A kind of wood surface silk-screen printing aqueous UV oil is provided
Ink and preparation method, solve current wood surface decoration technology complexity and the big disadvantage of energy consumption, and made ink has dry
The features such as dry speed is fast, stability is good, printing quality is high.
The present invention provides following technical scheme:
A kind of aqueous UV ink of wood surface silk-screen printing, ingredient and percentage composition are as follows:
Moreover, the aqueous UV resin binders include epoxy/organosilicon modified aqueous polyurethane acrylic resin, nanometer
Modified aqueous acrylic acid resin, fluorine-containing hyperbranched aqueous polyurethane acrylate.
Moreover, the aqueous UV resin binders include epoxy/organosilicon modified aqueous polyurethane acrylic resin, nanometer
Modified aqueous acrylic acid resin, fluorine-containing hyperbranched aqueous polyurethane acrylate are ring according to resin gross mass proportioning
Oxygen/organic silicon modified aqueous polyurethane acrylic resin is 21%-50%, nanometer modified aqueous acrylic resin is 16%-
45%, fluorine-containing hyperbranched aqueous polyurethane acrylate 25%-45%.
Moreover, the pigment be phthalocyanine blue, lithol red, lemon yellow, titanium dioxide and carbon black.
Moreover, the wetting dispersing agent includes the mixture of BYK190, BYK193, BYK198 one or more.
Moreover, the photoinitiator is 2,4,6- trimethylbenzoy-dipheny phosphine oxides, benzophenone, 2- hydroxyls
- 1 phenylacetone of -2 methyl-1 of base.
Moreover, the levelling agent is 2- [2- (2- Butoxyethoxies) ethyoxyl] ethyl alcohol.
Moreover, the coalescents are butyl glycol ether, the surfactant is siloxanes and polysilane mixture, institute
It is polyether modified siloxane mixture to state conditioning agent.
Moreover, the aqueous defoamer group is divided into 2-amino-2-methyl-1-propanol and 2- methyl -2- methylaminos -1- third
Alcohol.
A kind of wood surface silk-screen printing preparation method of aqueous UV ink, includes the following steps:
(1) dispensing:Arrange percentage composition feeding;
(2) wetting and dispersing;Wetting and dispersing condition is:Jitter time 10-30min, rotating speed 600-3000r/min;
(3) grinding distribution:Grinding distribution is that the semi-finished product of wetting and dispersing are put into vertical grinding machine, and zirconium pearl is added and carries out
The mass percent of grinding, ink and zirconium pearl is 1:The mass percent of 1-3, diameter 0.5mm zirconiums pearl and diameter 1mm zirconium pearls is 1:
0.5-2;Rotating speed 3500-5500r/min, milling time are respectively
(4) filter:Filtering is filtered using the polyester webs of -400 mesh of 200 mesh, and ink is obtained.
The epoxy/organosilicon modified aqueous polyurethane acrylic resin, emulsion solid content (%):30 ± 1 viscosity
(mPa.s/25℃):200-400pH values (1/10):7-8, glued membrane technical performance index:100% stretched film amount (MPa):10~12
Tensile strength (MPa):>=40 elongation at breaks (%):>=500 water absorption rates (%):≤ 10 crisp pack temperatures (DEG C):≤ -35 thermal deformations
Temperature (DEG C):≥140.It recommends and originates from Anqing De Cheng Chemical Co., Ltd.s, model PUD-A303F.
The nanometer modified aqueous acrylic resin contains admittedly, %:40 ± 1, viscosity (mPas, 25 DEG C):10-200, pH
Value:7.0-9.0 MFFT (DEG C):44, it is recommended to use:Chemical limited liability company of ten thousand China, Yantai, model6318;
The fluorine-containing hyperbranched aqueous polyurethane acrylate is by aliphatic isocyanates and special polyether polyalcohol
Aqueous dispersion made of copolymerization forms a film transparent bright, smooth, with homogeneous tree lipid phase than showing quite excellent elongation, resisting
The performances such as water-disintegrable, weatherability, water resistance, low temperature resistant, viscosity (mPa.s):50-150;Acid-base value:7-8;Amount of solid:35±
1%;It is ionic:Anion;Elongation:600%, it is recommended to use the auxiliary reagent factories Zhong Fang of Taixing City, the resistance to highly basic of model PU186-2 are high-elastic
Waterborne polyurethane resin.
The present invention achieves following technique effect compared with the existing technology:
Ink of the present invention in addition to rate of drying is fast, low energy consumption, high resistance, may be implemented the advantages that large-scale production with
Outside, in technique technological process is simplified also instead of technological means such as traditional timber surface faced deorative, transfers.
It is detected according to experiment, the hardening time of ink of the present invention is 8s, and ink can be in 0.6 μm of lower storage-stable with reference to state
GB/T9286-1998 is marked, grid is marked using blade, using 3M adhesive force adhesive tapes, measures ink adhesion-tight, surveyed ink is attached
It firmness and reaches 3B or more.Ink reproduces excellent in middle tone (50% tint hierarchy):Blue, red, yellow, black four color inks
Color density can respectively reach 1.9,1.88,1.56,1.88.It is respectively 6pt, 6pt, 8pt, 8pt that word, which reproduces minimum value, and lines are most
Small reproduction width is respectively 0.10pt, 0.15pt, 0.15pt, 0.15p.
Description of the drawings
Fig. 1 blue ink particle diameter distributions;
Fig. 2 red ink grain size distributions.
Specific implementation mode
Below by specific embodiment, the invention will be further described, and following embodiment is descriptive, is not limit
Qualitatively, protection scope of the present invention cannot be limited with this.
The ingredient and percentage composition of the aqueous UV ink of wood surface silk-screen printing provided by the invention are as follows:
Moreover, the aqueous UV resin binders include epoxy/organosilicon modified aqueous polyurethane acrylic resin, nanometer
Modified aqueous acrylic acid resin, fluorine-containing hyperbranched aqueous polyurethane acrylate.
Moreover, the aqueous UV resin binders include epoxy/organosilicon modified aqueous polyurethane acrylic resin, nanometer
Modified aqueous acrylic acid resin, fluorine-containing hyperbranched aqueous polyurethane acrylate are ring according to resin gross mass proportioning
Oxygen/organic silicon modified aqueous polyurethane acrylic resin is 21%-50%, nanometer modified aqueous acrylic resin is 16%-
45%, fluorine-containing hyperbranched aqueous polyurethane acrylate 25%-45%.
The pigment is phthalocyanine blue, lithol red, lemon yellow, titanium dioxide and carbon black.
The wetting dispersing agent includes that the collaboration of BYK190, BYK193, BYK198 one or more uses, and makes pigment
Average grain diameter can be steadily in the long term at 0.6 μm or less.
The photoinitiator is 2,4,6- trimethylbenzoy-diphenies phosphine oxide, benzophenone, -2 first of 2- hydroxyls
Base -1-1 phenylacetones.
The levelling agent is 2- [2- (2- Butoxyethoxies) ethyoxyl] ethyl alcohol.
The coalescents are butyl glycol ether.
The surfactant is siloxanes and polysilane mixture.
The conditioning agent is polyether modified siloxane mixture.
The aqueous defoamer group is divided into 2-amino-2-methyl-1-propanol and 2- methyl -2- methylamino -1- propyl alcohol.
It is described by aqueous UV resins link stuff, water, pigment, absolute ethyl alcohol, wetting dispersing agent, levelling agent, coalescents, table
Face activating agent, conditioning agent, aqueous defoamer and resistance to anti-agent etc. weigh dispensing according to formula.
The wood surface silk-screen printing preparation method of aqueous UV ink, includes the following steps:
(1) dispensing:Arrange percentage composition feeding
(2) wetting and dispersing;Wetting and dispersing condition is:Jitter time 10-30min, rotating speed 600-3000r/min.
(3) grinding distribution:Grinding distribution is that the semi-finished product of wetting and dispersing are put into vertical grinding machine, and zirconium pearl is added and carries out
The mass percent of grinding, ink and zirconium pearl is 1:The mass percent of 1-3, diameter 0.5mm zirconiums pearl and diameter 1mm zirconium pearls is 1:
0.5-2;Rotating speed 3500-5500r/min, milling time are respectively:Blue ink grinds 3-7h, red ink grinding 2-8h, Huang
Color ink 2-6h, white ink 3-9h, black ink 3-9h.
(4) filter:Filtering is filtered using the polyester webs of the mesh of 200 mesh~400.
(5) ink performance detects:Performance detection includes that ink grain size, ink setting speed, ink viscosity etc. are detected.
(6) printing is drawn a design and quality evaluation:Printing draws a design to refer to prints out required color using screen process press in wood surface
Sample, quality testing refer to being detected to ink color density, ink adhesion-tight etc..
(7) adjust:According to ink performance parameter and printing performance Testing index, ink formulations and process conditions are carried out excellent
Changing improves.
For the effect that the present invention will be described in detail, embodiment in detail below is provided.
The epoxy/organosilicon modified aqueous polyurethane acrylic resin, emulsion solid content (%):30 ± 1 viscosity
(mPa.s/25℃):200-400pH values (1/10):7-8, glued membrane technical performance index:100% stretched film amount (MPa):10~12
Tensile strength (MPa):>=40 elongation at breaks (%):>=500 water absorption rates (%):≤ 10 crisp pack temperatures (DEG C):≤ -35 thermal deformations
Temperature (DEG C):≥140.It recommends and originates from Anqing De Cheng Chemical Co., Ltd.s, model PUD-A303F.
The nanometer modified aqueous acrylic resin contains admittedly, %:40 ± 1, viscosity (mPas, 25 DEG C):10-200, pH
Value:7.0-9.0 MFFT (DEG C):44, it is recommended to use:Chemical limited liability company of ten thousand China, Yantai, model6318;
The fluorine-containing hyperbranched aqueous polyurethane acrylate is by aliphatic isocyanates and special polyether polyalcohol
Aqueous dispersion made of copolymerization forms a film transparent bright, smooth, with homogeneous tree lipid phase than showing quite excellent elongation, resisting
The performances such as water-disintegrable, weatherability, water resistance, low temperature resistant, viscosity (mPa.s):50-150;Acid-base value:7-8;Amount of solid:35±
1%;It is ionic:Anion;Elongation:600%, it is recommended to use the auxiliary reagent factories Zhong Fang of Taixing City, the resistance to highly basic of model PU186-2 are high-elastic
Waterborne polyurethane resin.
Embodiment 1
(1) dispensing
According to ink formulations by aqueous UV resins link stuff, water, absolute ethyl alcohol, phthalocyanine blue, photoinitiator, wetting and dispersing
Agent, levelling agent, coalescents, surfactant, conditioning agent and aqueous defoamer etc. are weighed according to formula, and specific dosage is shown in
Table 1.
The blue timber silk screen aqueous surface UV ink formulations of table 1
Wherein aqueous UV resins link stuff is:Epoxy/organosilicon modified aqueous polyurethane acrylic resin 45%, nanometer change
Property water-based acrylic resin 25%, fluorine-containing hyperbranched aqueous polyurethane acrylate 30% mixing be added.
(2) wetting and dispersing
Drug will be weighed using dgital electric mixer and carry out wetting and dispersing, dispersion condition is time 15min, rotating speed
2500r/min。
(3) grinding distribution
The good ink semi-finished product of wetting and dispersing are added in vertical grinding machine, then according to ink and zirconium pearl quality percentage
Than being 1:2, zirconium pearl is added during being stirred for, and the mass percent of diameter 0.5mm zirconiums pearl and diameter 1mm zirconium pearls is 1:1.5
(4) it filters
Ink is obtained by filtration using self-control 250 mesh of polyester webs, and canned.
(5) ink performance detects
1. the droplet measurement of ink pigment
By ink finished product by Malvern Mastersizer its particle size of 3000E series lasers particle size instrument and
Distribution, for characterizing ink dispersion performance, ink as shown in Figure 1 can be in 0.6 μm of lower storage-stable.
2. ink viscosity measures
The viscosity characteristics of ink also determine the key of ink quality quality to a certain extent, and the viscosity of ink is also one
Determine to affect the mobility of ink in degree, and then influences the osmosis of ink.The measurement of aqueous UV ink viscosities uses
Vertebral plate viscosity apparatus CAP2000+ arrange parameters are time 120s, rotating speed 20rpm, sample initial time 30s, are spaced 10s, sampling 10
A, data are as shown in table 2.
2 ink viscosity of table is tested
3. hardening time is detected
The sample of silk-screen printing is put under UV curing UN50013-0001 cured, and records hardening time.Sentence
The quasi- touch of calibration is inviscid, moves ink film crack-free in five kilograms or so pressure backspin turnings, and nothing draws cross.The surveyed ink solidification time
For 8s.
(6) printing is drawn a design and quality evaluation
1. color density detects
It is divided densimeter X-rite528 using Ai Lise and color density is measured to each different dot area percentage color lumps,
The color density of different dot area percentage color lumps is as shown in table 3.
The color density of the different dot area percentage color lumps of table 3
2. adhesion-tight detects
With reference to national standard GB/T9286-1998, grid is marked using blade, using 3M adhesive force adhesive tapes, measures ink attachment
Securely, surveyed ink adhesion-tight degree reaches 3B or more.
(7) it adjusts
The adjustment refer to according to ink performance parameter and printing performance Testing index, to ink formulations and process conditions into
Row optimization improves.
Embodiment 2
(1) dispensing
According to the aqueous UV resins link stuff of ink formulations, deionized water, absolute ethyl alcohol, lithol red, photoinitiator, wetting
Dispersant, levelling agent, coalescents, conditioning agent, surfactant and antifoaming agent etc. are weighed according to formula, and specific dosage is shown in
Table 4.
4 redwood silk screen aqueous surface ink formulations of table
Wherein aqueous UV resins link stuff is:Epoxy/organosilicon modified aqueous polyurethane acrylic resin 45%, nanometer change
Property water-based acrylic resin 25%, fluorine-containing hyperbranched aqueous polyurethane acrylate 30% mixing be added.
(2) wetting and dispersing
Pre-dispersed time 14min, rotating speed 2600r/min are carried out using dgital electric mixer.
(3) grinding distribution
The good ink semi-finished product of wetting and dispersing are poured into vertical grinding machine, according to ink and zirconium pearl mass percent
200%, add zirconium pearl during being stirred for.And the mass percent of diameter 0.5mm zirconiums pearl and diameter 1mm zirconium pearls is 150%, is ground
Consume time 6h.
(4) it filters
Ink and canned is obtained by filtration using 250 mesh polyester webs of self-control.
(5) ink performance detects
1. the droplet measurement of ink pigment
By ink finished product by Malvern Mastersizer its particle size of 3000E series lasers particle size instrument and
Distribution, for characterizing ink dispersion performance.Ink can be in 0.6 μm of lower storage-stable.
2. ink viscosity measures
The viscosity characteristics of ink also determine the key of ink quality quality to a certain extent, and the viscosity of ink is also one
Determine to affect the mobility of ink in degree, and then influences the osmosis of ink.The measurement of aqueous UV ink viscosities uses
Vertebral plate viscosity apparatus CAP2000+ arrange parameters are time 120s, rotating speed 20rpm, sample initial time 30s, are spaced 10s, sampling 10
A, data are as shown in table 5.
5 ink viscosity of table is tested
3. hardening time is detected
The sample of silk-screen printing is put under UV curing UN50013-0001 is cured and records hardening time.Judgement
Standard touch is inviscid, moves ink film crack-free in five kilograms or so pressure backspin turnings, horizontal without drawing.Time 8s
(6) printing is drawn a design and quality evaluation
1. color density detects
It is divided densimeter X-rite528 using Ai Lise and color density is measured to each different dot area percentage color lumps,
The color density of different dot area percentage color lumps such as table 6.
The different site color densities of table 6
2. adhesion-tight detects
The measurement (with reference to national standard GB/T9286-1998) of attachment fastness marks grid glutinous using 3M adhesive tapes using blade
Stickily tear is split, and adhesion-tight degree reaches 3B or more.
(7) it adjusts
The adjustment refer to according to ink performance parameter and printing performance Testing index, to ink formulations and process conditions into
Row optimization improves.
Claims (10)
1. a kind of aqueous UV ink of wood surface silk-screen printing, it is characterised in that:Ingredient and percentage composition are as follows:
2. the aqueous UV ink of wood surface silk-screen printing according to claim 1, it is characterised in that:The aqueous UV trees
Fat binder includes epoxy/organosilicon modified aqueous polyurethane acrylic resin, nanometer modified aqueous acrylic resin, fluorine-containing super
Waterborne branched polyurethane acrylate.
3. the aqueous UV ink of wood surface silk-screen printing according to claim 1, it is characterised in that:The aqueous UV trees
Fat binder includes epoxy/organosilicon modified aqueous polyurethane acrylic resin, nanometer modified aqueous acrylic resin, fluorine-containing super
Waterborne branched polyurethane acrylate is epoxy/organosilicon modified aqueous polyurethane propylene according to resin gross mass proportioning
Acid resin is 21%-50%, nanometer modified aqueous acrylic resin is 16%-45%, fluorine-containing hyperbranched aqueous polyurethane propylene
Acid ester resin 25%-45%.
4. the aqueous UV ink of wood surface silk-screen printing according to claim 1, it is characterised in that:The pigment is phthalein
Cyanines indigo plant, lithol red, lemon yellow, titanium dioxide and carbon black.
5. the aqueous UV ink of wood surface silk-screen printing according to claim 1, it is characterised in that:The wetting and dispersing
Agent includes the mixture of BYK190, BYK193, BYK198 one or more.
6. the aqueous UV ink of wood surface silk-screen printing according to claim 1, it is characterised in that:The photoinitiator
For 2,4,6- trimethylbenzoy-diphenies phosphine oxide, benzophenone, -1 phenylacetone of -2 methyl-1 of 2- hydroxyls.
7. the aqueous UV ink of wood surface silk-screen printing according to claim 1, it is characterised in that:The levelling agent is
2- [2- (2- Butoxyethoxies) ethyoxyl] ethyl alcohol.
8. the aqueous UV ink of wood surface silk-screen printing according to claim 1, it is characterised in that:The coalescents
For butyl glycol ether, the surfactant is siloxanes and polysilane mixture, and the conditioning agent is polyether modified siloxane
Mixture.
9. the aqueous UV ink of wood surface silk-screen printing according to claim 1, it is characterised in that:The aqueous defoaming
Agent group is divided into 2-amino-2-methyl-1-propanol and 2- methyl -2- methylamino -1- propyl alcohol.
10. a kind of preparation method of the aqueous UV ink of wood surface silk-screen printing as described in claim 1, feature exist
In:Include the following steps:
(1) dispensing:Arrange percentage composition feeding;
(2) wetting and dispersing;Wetting and dispersing condition is:Jitter time 10-30min, rotating speed 600-3000r/min;
(3) grinding distribution:Grinding distribution is that the semi-finished product of wetting and dispersing are put into vertical grinding machine, and zirconium pearl is added and is ground,
The mass percent of ink and zirconium pearl is 1:The mass percent of 1-3, diameter 0.5mm zirconiums pearl and diameter 1mm zirconium pearls is 1:0.5-
2;Rotating speed 3500-5500r/min, milling time are respectively
(4) filter:Filtering is filtered using the polyester webs of -400 mesh of 200 mesh, and ink is obtained.
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Cited By (1)
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CN111548673A (en) * | 2020-06-05 | 2020-08-18 | 苏州市博来特油墨有限公司 | Green environment-friendly curing printing ink for high-speed printing |
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