CN108586998A - A kind of environment-friendly type antibiotic PVC - Google Patents
A kind of environment-friendly type antibiotic PVC Download PDFInfo
- Publication number
- CN108586998A CN108586998A CN201810487102.9A CN201810487102A CN108586998A CN 108586998 A CN108586998 A CN 108586998A CN 201810487102 A CN201810487102 A CN 201810487102A CN 108586998 A CN108586998 A CN 108586998A
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- Prior art keywords
- parts
- pvc
- nano
- antibacterial powder
- environment
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/328—Phosphates of heavy metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses a kind of environment-friendly type antibiotic PVC, which is characterized in that including following parts by weight material：95 100 parts of PVC；45 50 parts of plasticizer；13 parts of environmentally friendly calcium zinc heat stabilizer；30 35 parts of calcium carbonate；35 parts of lubricant；10 15 parts of MBS modifying agent；15 20 parts of ACR modifying agent；10 15 parts of nano-antibacterial powder；15 parts of titanate coupling agent；15 parts of stearic acid；It is added in PVC after polymethylacrylic acid and polybutene solid phase fusion；Nano-antibacterial powder is to carry silver-colored titanium dioxide antibiotic powder, silver-loaded zirconium phosphate nano-antibacterial powder 1:1 mixture.The present invention has the advantages that good anti-bacterial effect, good mechanical property.
Description
Technical field
The present invention relates to a kind of environment-friendly type antibiotic PVC.
Background technology
With social city, technicalization, hommization development, the high speed development of PVC industries, PVC materials are increasingly
Close to people’s lives, the thing followed is the increase of PVC usage amounts, and requirement of the people to PVC is higher and higher.Design is a kind of
While not influencing PVC mechanical performances, the antibiotic property for improving PVC is very necessary.
Invention content
Goal of the invention：The purpose of the present invention is to solve deficiencies in the prior art, and machinery can be ensured by providing one kind
Performance, and a kind of environment-friendly type antibiotic PVC that antibacterial environment protection effect is good.
Technical solution：A kind of environment-friendly type antibiotic PVC of the present invention, which is characterized in that including following parts by weight material：PVC
95-100 parts；45-50 parts of plasticizer；Environmentally friendly calcium zinc heat stabilizer 1-3 parts；30-35 parts of calcium carbonate；3-5 parts of lubricant；MBS changes
10-15 parts of agent of property；15-20 parts of ACR modifying agent；10-15 parts of nano-antibacterial powder；1-5 parts of titanate coupling agent；1-5 parts of stearic acid.
Further improvement of the present invention is, is added in PVC after polymethylacrylic acid and polybutene solid phase fusion.
Further improvement of the present invention is that nano-antibacterial powder is to carry silver-colored titanium dioxide antibiotic powder, silver-loaded zirconium phosphate nanometer
Antibacterial powder 1:1 mixture.
Advantageous effect：
The compounding of MBS modifying agent and ACR modifying agent shortens the time of plasticizing, improves whole mechanical performance.Carry silver-colored dioxy
The addition for changing titanium antibacterial powder, silver-loaded zirconium phosphate nano-antibacterial powder, improves antibiotic property, while also improving whole mechanicalness
Energy.Titanate coupling agent and stearic collective effect play promotion and carry silver-colored titanium dioxide antibiotic powder, silver-loaded zirconium phosphate nanometer
Antibacterial powder merges the effect in PVC.
Specific implementation mode
Illustrate that embodiments of the present invention, those skilled in the art can be by this explanations by particular specific embodiment below
Content disclosed by book understands other advantages and effect of the present invention easily.
Embodiment 1,
A kind of environment-friendly type antibiotic PVC, including following parts by weight material：95 parts of PVC；45 parts of plasticizer；Environmentally friendly calcium zinc heat stabilizer
1 part；30 parts of calcium carbonate；3 parts of lubricant；10 parts of MBS modifying agent；15 parts of ACR modifying agent；10 parts of nano-antibacterial powder；Titanate esters are even
Join 1 part of agent；1 part of stearic acid.
Further, it is added in PVC after polymethylacrylic acid and polybutene solid phase fusion.
Further, nano-antibacterial powder is to carry silver-colored titanium dioxide antibiotic powder, silver-loaded zirconium phosphate nano-antibacterial powder 1:1 mixing
Object.
Embodiment 2,
A kind of environment-friendly type antibiotic PVC, which is characterized in that including following parts by weight material：PVC100 parts；45 parts of plasticizer；Environmental protection
1 part of calcium zinc heat stabilizer；30 parts of calcium carbonate；3 parts of lubricant；10 parts of MBS modifying agent；15 parts of ACR modifying agent；Nano-antibacterial powder 10
Part；1 part of titanate coupling agent；1 part of stearic acid.
Further, it is added in PVC after polymethylacrylic acid and polybutene solid phase fusion.
Further, nano-antibacterial powder is to carry silver-colored titanium dioxide antibiotic powder, silver-loaded zirconium phosphate nano-antibacterial powder 1:1 mixing
Object.
Embodiment 3,
A kind of environment-friendly type antibiotic PVC, which is characterized in that including following parts by weight material：98 parts of PVC；45 parts of plasticizer；Environmental protection
1 part of calcium zinc heat stabilizer；30 parts of calcium carbonate；3 parts of lubricant；10 parts of MBS modifying agent；15 parts of ACR modifying agent；Nano-antibacterial powder 10
Part；1 part of titanate coupling agent；1 part of stearic acid.
Further, it is added in PVC after polymethylacrylic acid and polybutene solid phase fusion.
Further, nano-antibacterial powder is to carry silver-colored titanium dioxide antibiotic powder, silver-loaded zirconium phosphate nano-antibacterial powder 1:1 mixing
Object.
Embodiment 4,
A kind of environment-friendly type antibiotic PVC, which is characterized in that including following parts by weight material：95 parts of PVC；50 parts of plasticizer；Environmental protection
3 parts of calcium zinc heat stabilizer；35 parts of calcium carbonate；5 parts of lubricant；15 parts of MBS modifying agent；20 parts of ACR modifying agent；Nano-antibacterial powder 15
Part；5 parts of titanate coupling agent；5 parts of stearic acid.
Further, it is added in PVC after polymethylacrylic acid and polybutene solid phase fusion.
Further, nano-antibacterial powder is to carry silver-colored titanium dioxide antibiotic powder, silver-loaded zirconium phosphate nano-antibacterial powder 1:1 mixing
Object.
Embodiment 5,
A kind of environment-friendly type antibiotic PVC, which is characterized in that including following parts by weight material：100 parts of PVC；50 parts of plasticizer；Environmental protection
3 parts of calcium zinc heat stabilizer；35 parts of calcium carbonate；5 parts of lubricant；15 parts of MBS modifying agent；20 parts of ACR modifying agent；Nano-antibacterial powder 15
Part；5 parts of titanate coupling agent；5 parts of stearic acid.
Further, it is added in PVC after polymethylacrylic acid and polybutene solid phase fusion.
Further, nano-antibacterial powder is to carry silver-colored titanium dioxide antibiotic powder, silver-loaded zirconium phosphate nano-antibacterial powder 1:1 mixing
Object.
Embodiment 6,
A kind of environment-friendly type antibiotic PVC, which is characterized in that including following parts by weight material：98 parts of PVC；45 parts of plasticizer；Environmental protection
1 part of calcium zinc heat stabilizer；35 parts of calcium carbonate；3 parts of lubricant；15 parts of MBS modifying agent；15 parts of ACR modifying agent；Nano-antibacterial powder 15
Part；1 part of titanate coupling agent；3 parts of stearic acid.
Further, it is added in PVC after polymethylacrylic acid and polybutene solid phase fusion.
Further, nano-antibacterial powder is to carry silver-colored titanium dioxide antibiotic powder, silver-loaded zirconium phosphate nano-antibacterial powder 1:1 mixing
Object.
Above-mentioned specific implementation mode, technical concept and structure feature only to illustrate the invention, it is therefore intended that allow and be familiar with this
The stakeholder of item technology can implement according to this, but the above content is not intended to limit protection scope of the present invention, every according to this hair
Any equivalent change or modification made by bright Spirit Essence, should all fall under the scope of the present invention.
Claims (3)
1. a kind of environment-friendly type antibiotic PVC, which is characterized in that including following parts by weight material：95-100 parts of PVC；Plasticizer 45-
50 parts；Environmentally friendly calcium zinc heat stabilizer 1-3 parts；30-35 parts of calcium carbonate；3-5 parts of lubricant；10-15 parts of MBS modifying agent；ACR is modified
15-20 parts of agent；10-15 parts of nano-antibacterial powder；1-5 parts of titanate coupling agent；1-5 parts of stearic acid.
2. a kind of environment-friendly type antibiotic PVC according to claim 1, which is characterized in that the polymethylacrylic acid and poly- fourth
It is added in PVC after alkene solid phase fusion.
3. a kind of environment-friendly type antibiotic PVC according to claim 1, which is characterized in that the nano-antibacterial powder is to carry silver two
Titanium oxide antibacterial powder, silver-loaded zirconium phosphate nano-antibacterial powder 1:1 mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810487102.9A CN108586998A (en) | 2018-05-21 | 2018-05-21 | A kind of environment-friendly type antibiotic PVC |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810487102.9A CN108586998A (en) | 2018-05-21 | 2018-05-21 | A kind of environment-friendly type antibiotic PVC |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108586998A true CN108586998A (en) | 2018-09-28 |
Family
ID=63632333
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810487102.9A Pending CN108586998A (en) | 2018-05-21 | 2018-05-21 | A kind of environment-friendly type antibiotic PVC |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108586998A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112358697A (en) * | 2020-11-12 | 2021-02-12 | 无锡市秦金烨塑胶材料科技有限公司 | PVC toughening agent |
| CN112920445A (en) * | 2020-10-12 | 2021-06-08 | 苏州巴涛信息科技有限公司 | High-strength antibacterial plastic and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101353467A (en) * | 2008-09-17 | 2009-01-28 | 青岛高科塑胶研究开发中心 | Polychloroethylene acrylonitrile butadiene composite pipes and preparation thereof |
| CN102336957A (en) * | 2010-07-29 | 2012-02-01 | 上海亿金纳米科技有限公司 | Method for preparing functional chips for manufacturing antibacterial fibers and plastics |
| CN102964710A (en) * | 2012-12-03 | 2013-03-13 | 晋大纳米科技（厦门）有限公司 | Antibacterial poly styrene (PS) plastic without chromatic aberration and preparation method of plastic |
| CN103122111A (en) * | 2013-02-27 | 2013-05-29 | 东莞欧德雅装饰材料有限公司 | Environment-friendly PVC (polyvinyl chloride) household edge banding and preparation method thereof |
| CN107266914A (en) * | 2017-07-27 | 2017-10-20 | 合肥远科服装设计有限公司 | A kind of anti-tinea pedis Chinese medicine air permeable health-care shoe pad and preparation method thereof |
-
2018
- 2018-05-21 CN CN201810487102.9A patent/CN108586998A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101353467A (en) * | 2008-09-17 | 2009-01-28 | 青岛高科塑胶研究开发中心 | Polychloroethylene acrylonitrile butadiene composite pipes and preparation thereof |
| CN102336957A (en) * | 2010-07-29 | 2012-02-01 | 上海亿金纳米科技有限公司 | Method for preparing functional chips for manufacturing antibacterial fibers and plastics |
| CN102964710A (en) * | 2012-12-03 | 2013-03-13 | 晋大纳米科技（厦门）有限公司 | Antibacterial poly styrene (PS) plastic without chromatic aberration and preparation method of plastic |
| CN103122111A (en) * | 2013-02-27 | 2013-05-29 | 东莞欧德雅装饰材料有限公司 | Environment-friendly PVC (polyvinyl chloride) household edge banding and preparation method thereof |
| CN107266914A (en) * | 2017-07-27 | 2017-10-20 | 合肥远科服装设计有限公司 | A kind of anti-tinea pedis Chinese medicine air permeable health-care shoe pad and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112920445A (en) * | 2020-10-12 | 2021-06-08 | 苏州巴涛信息科技有限公司 | High-strength antibacterial plastic and preparation method thereof |
| CN112358697A (en) * | 2020-11-12 | 2021-02-12 | 无锡市秦金烨塑胶材料科技有限公司 | PVC toughening agent |
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| PB01 | Publication | ||
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| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180928 |