CN102061045A - Renewable resource modified multifunctional nano composite glue-free environmentally-friendly decorative slab - Google Patents

Renewable resource modified multifunctional nano composite glue-free environmentally-friendly decorative slab Download PDF

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Publication number
CN102061045A
CN102061045A CN2010105941287A CN201010594128A CN102061045A CN 102061045 A CN102061045 A CN 102061045A CN 2010105941287 A CN2010105941287 A CN 2010105941287A CN 201010594128 A CN201010594128 A CN 201010594128A CN 102061045 A CN102061045 A CN 102061045A
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China
Prior art keywords
percent
renewable resource
multifunctional nano
exempting
polyvinyl chloride
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Pending
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CN2010105941287A
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Chinese (zh)
Inventor
陈声文
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YAAN JINGQIANG PLATE CO Ltd
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YAAN JINGQIANG PLATE CO Ltd
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Priority to CN2010105941287A priority Critical patent/CN102061045A/en
Publication of CN102061045A publication Critical patent/CN102061045A/en
Pending legal-status Critical Current

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  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a renewable resource modified multifunctional nano composite glue-free environmentally-friendly decorative slab, which relates to the technical field of chemical building materials and aims to solve the technical problems of low product strength, short service life, low geometric dimension stability, chemical toxicity and the like of the conventional plastic-simulated decorative slab. The renewable resource modified multifunctional nano composite glue-free environmentally-friendly decorative slab consists of the following components in percentage by weight: 6.30 percent of polyvinyl chloride resin, 35.80 to 45 percent of heavy calcium carbonate, 60 to 65 percent of polyvinyl chloride (PVC) material, 0.20 to 0.70 percent of stearic acid B1841, 0.90 to 1.20 percent of chlorinated polyethylene, 0.30 percent of foaming regulator, 0.10 to 0.13 percent of paraffin, 0.70 to 0.90 percent of dioctyl ester, 0.90 to 1.30 percent of stabilizer, 0.10 to 0.13 percent of calcium stearate, 0.10 percent of lead stearate and 0.90 to 1.30 percent of polyvinyl chloride.

Description

The compound glue environmental-protection decorative sheet material of exempting from of renewable resource modification multifunctional nano
Technical field
The present invention relates to the chemical building material technical field, particularly use the dalle of renewable resource such as PVC and white marble waste material as raw material.
Background technology
In present building material field, imitative plastic plate and PVC foaming plate are widely applied as dalle, and there are the following problems usually for plate but existing imitative plastic plate and PVC foam:
1. product strength is not high, and the life-span is short, meets external force and easily fractures or crackle;
2. geometrical dimension stability is bad, and is yielding under the high temperature, and embrittlement easily takes place again under the low temperature;
3. has certain chemical toxicity;
4. wear resisting property is poor.
 
Summary of the invention
The present invention is intended to solve existing imitative plastic decorative board material and has technical problems such as product strength is not high, life-span weak point, geometrical dimension poor stability, tool chemical toxicity, so that a kind of use regeneration PVC material and white marble rim charge to be provided, and have chemical stabilization, shock-resistance is good, product strength is high, the geometrical dimension good stability, the compound glue environmental-protection decorative sheet material of exempting from of the renewable resource modification multifunctional nano of heatproof weathering resistance height, long service life.
The objective of the invention is to be achieved through the following technical solutions.
The compound glue environmental-protection decorative sheet material of exempting from of renewable resource modification multifunctional nano of the present invention is made of the component of following weight part: polyvinyl chloride (PVC) RESINS 6.30%, water-ground limestone 35.80-45%, PVC material 60-65%, stearic acid B18410.20-0.70%, chlorinatedpolyethylene 0.90-1.20%, foaming control agent 0.30%, paraffin 0.10-0.13%, dibutyl ester 0.70-0.90%, stablizer 0.90-1.30%, calcium stearate 0.10-0.13%, lead stearate 0.10%, polyvinyl chloride 0.90-1.30%.
The compound glue environmental-protection decorative sheet material of exempting from of renewable resource modification multifunctional nano of the present invention, wherein said PVC material is managed material in vain for regeneration PVC.
The compound glue environmental-protection decorative sheet material of exempting from of renewable resource modification multifunctional nano of the present invention, wherein said stearic acid is stearic acid B1841.
The compound glue environmental-protection decorative sheet material of exempting from of renewable resource modification multifunctional nano of the present invention, wherein said chlorinatedpolyethylene is chlorinatedpolyethylene 135A.
The compound glue environmental-protection decorative sheet material of exempting from of renewable resource modification multifunctional nano of the present invention, wherein said foaming control agent is acrylate foaming control agent ZB-530.
The compound glue environmental-protection decorative sheet material of exempting from of renewable resource modification multifunctional nano of the present invention, wherein said stablizer is for containing lead salts high-efficiency compound stabilizer SW-206.
The compound glue environmental-protection decorative sheet material of exempting from of renewable resource modification multifunctional nano of the present invention, wherein said polyvinyl chloride is polyvinyl chloride ACR-401.
 
The compound beneficial effect of exempting from glue environmental-protection decorative sheet material of renewable resource modification multifunctional nano of the present invention:
1. use white pvc pipe waste material and white marble scrap stock to be main raw material, turn waste into wealth, save production cost, preserve the ecological environment;
2. chemical stabilization can not corrode;
3. shock-resistance is good, can follow closely, and can dig, and is hard, antiwear characteristic;
4. good insulating, it is indeformable, fire-retardant to meet heat, does not fade;
5. geometrical dimension good stability, high temperature is indeformable, and low temperature does not become fragile, and is aging.
 
Embodiment
Application principle of the present invention, effect and effect are illustrated by following embodiment.
The compound glue environmental-protection decorative sheet material of exempting from of renewable resource modification multifunctional nano of the present invention is made of the component of following weight part: polyvinyl chloride (PVC) RESINS 6.30%, water-ground limestone 35.80-45%, PVC material 60-65%, stearic acid B18410.20-0.70%, chlorinatedpolyethylene 0.90-1.20%, foaming control agent 0.30%, paraffin 0.10-0.13%, dibutyl ester 0.70-0.90%, stablizer 0.90-1.30%, calcium stearate 0.10-0.13%, lead stearate 0.10%, polyvinyl chloride 0.90-1.30%.
Wherein polyvinyl chloride (PVC) RESINS adopts PVC.RESIN, and content is 6.30%, have that fire-retardant, electrical insulating property, snappiness are good, easy-formation, be difficult for characteristics such as crisp, that gas defence is pollution-free, in the present invention mainly to act as finished product crease-resistant, wrinkle resistant.
Wherein heavy carbonic acid is about to the white marble scrap stock and carries out levigate back as raw material, and content is 35.80%-45%, and it act as intensity, thermotolerance, the ageing resistance effect that improves material.
Wherein the PVC material is about to useless white pvc pipe and carries out levigate back as raw material, and content is 60%-65%, and it act as stopping composition, and can play the effect that makes the goods foaming.
Wherein stearic acid adopts stearic acid B1841, and content is 0.20%-0.70%, in the present invention mainly act as softening agent, stablizer and lubricant.
Wherein chlorinatedpolyethylene adopts CPE135A, and content is 0.90%-1.20%, the toughness that mainly act as the increase goods in the present invention, improve shock resistance and intensity.
Wherein foaming control agent adopts acrylate foaming control agent ZB530, and content is 0.30%, and mainly acting as in the present invention promotes plasticizing, improves surface quality, improves melt strength and extensibility, reduces effects such as density.
Wherein paraffinicity is 0.10%-0.13%, and plastification is played in mainly acting as in the present invention, the brightness of reinforcement plate.
Wherein dioctyl ester content is 0.70%-0.90%, in the present invention mainly act as lubricant, increase mobile, extrusion capacity and turnout.
Wherein stablizer adopts and contains lead salts high-efficiency compound stabilizer SW-206, and content is that 0.90%-1.30% can make PVC stable in the present invention, and it is respond well to suppress initial coloration simultaneously.
Wherein calcium stearate content is 0.10%-0.13%, in the present invention as lubricant, improves raw material and extrudes and compression moulding.
Wherein lead stearate content is 0.10%, can improve the PVC goods transparency in the present invention.
Wherein polyvinyl chloride adopts polyvinyl chloride ACR-401, and its content is 0.90%-1.30%, can improve the impact resistance of finished product in the present invention and improve elongation, improve PVC and dissolve speed, shorten dissolving the time, improve stability, especially can strengthen the tenacity of product, outstanding hot strength and cohesive force are arranged, make material group smooth surface, on various processors, all can promote processing smoothly, make product surface smooth, do not have pin hole, the air striped breaks with dissolving, and reduces flake and brilliant point.
The compound glue environmental-protection decorative sheet material of exempting from of renewable resource modification multifunctional nano of the present invention when producing, carries out milled processed with each component earlier, and the component after will grinding again is mixed in proportion, and at high temperature stirs, by the mould extrusion moulding.Product thickness is 1.5mm-2.5mm, its surface is rich in gloss, can be used for the upholstery decoration, comprise large conference room, office, star hotel, luxurious place decoration, also can be used for furniture, cabinet, sanitary equipment, billboard making, art designing's material, building mould, Central European indoor suit doors etc.
Nanometer material macromolecular structure has two types basically, and first kind is structure-type, and the macromolecular compound with this structure is called the section bar macromolecular compound; Second kind of three dimensional structure is called the side chain nano-high molecule, and belonging to is linear structure, has crosslinkedly, but crosslinked less between some build molecule and the molecule, is reticulated structure, the general designation three dimensional structure.
The compound glue environmental-protection decorative sheet material of exempting from of renewable resource modification multifunctional nano of the present invention is made of structure-type and two kinds of nanometer material of build polymer, so have following technical characteristic: pollution-free; Anticorrosion, moistureproof; Fire prevention, fire-retardant, sound insulation; Water-fast flushing; Can dig, can follow closely; Environmental protection and energy saving can be produced low price in batches; Of many uses, save time, save trouble; Smooth surface such as mirror.

Claims (7)

1. the compound glue environmental-protection decorative sheet material of exempting from of renewable resource modification multifunctional nano is characterized in that being made of the component of following weight part: polyvinyl chloride (PVC) RESINS 6.30%, water-ground limestone 35.80-45%, PVC material 60-65%, stearic acid 0.20-0.70%, chlorinatedpolyethylene 0.90-1.20%, foaming control agent 0.30%, paraffin 0.10-0.13%, dibutyl ester 0.70-0.90%, stablizer 0.90-1.30%, calcium stearate 0.10-0.13%, lead stearate 0.10%, polyvinyl chloride 0.90-1.30%.
2. the compound glue environmental-protection decorative sheet material of exempting from of renewable resource modification multifunctional nano as claimed in claim 1 is characterized in that: described PVC material is managed material in vain for regeneration PVC.
3. the compound glue environmental-protection decorative sheet material of exempting from of renewable resource modification multifunctional nano as claimed in claim 1, it is characterized in that: described stearic acid is stearic acid B1841.
4. the compound glue environmental-protection decorative sheet material of exempting from of renewable resource modification multifunctional nano as claimed in claim 1, it is characterized in that: described chlorinatedpolyethylene is chlorinatedpolyethylene 135A.
5. the compound glue environmental-protection decorative sheet material of exempting from of renewable resource modification multifunctional nano as claimed in claim 1, it is characterized in that: described foaming control agent is acrylate foaming control agent ZB-530.
6. the compound glue environmental-protection decorative sheet material of exempting from of renewable resource modification multifunctional nano as claimed in claim 1, it is characterized in that: described stablizer is for containing lead salts high-efficiency compound stabilizer SW-206.
7. the compound glue environmental-protection decorative sheet material of exempting from of renewable resource modification multifunctional nano as claimed in claim 1, it is characterized in that: described polyvinyl chloride is polyvinyl chloride ACR-401.
CN2010105941287A 2010-12-17 2010-12-17 Renewable resource modified multifunctional nano composite glue-free environmentally-friendly decorative slab Pending CN102061045A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010105941287A CN102061045A (en) 2010-12-17 2010-12-17 Renewable resource modified multifunctional nano composite glue-free environmentally-friendly decorative slab

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Application Number Priority Date Filing Date Title
CN2010105941287A CN102061045A (en) 2010-12-17 2010-12-17 Renewable resource modified multifunctional nano composite glue-free environmentally-friendly decorative slab

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CN102061045A true CN102061045A (en) 2011-05-18

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102585397A (en) * 2011-12-29 2012-07-18 雅安市晶强板业有限公司 Renewable resource modified nanocomposite glue-free paint-free environment-friendly decorative plate
CN102875056A (en) * 2012-10-11 2013-01-16 云南德发绿源板业有限公司 Novel stone floor and production process thereof
CN105643754A (en) * 2015-12-04 2016-06-08 雅安市晶强板业有限公司 Method for manufacturing wooden door veneer by using regenerative PVC (Polyvinyl Chloride) white pipe glue-free composite film

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102585397A (en) * 2011-12-29 2012-07-18 雅安市晶强板业有限公司 Renewable resource modified nanocomposite glue-free paint-free environment-friendly decorative plate
CN102875056A (en) * 2012-10-11 2013-01-16 云南德发绿源板业有限公司 Novel stone floor and production process thereof
CN105643754A (en) * 2015-12-04 2016-06-08 雅安市晶强板业有限公司 Method for manufacturing wooden door veneer by using regenerative PVC (Polyvinyl Chloride) white pipe glue-free composite film

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Application publication date: 20110518