CN102585397A - Renewable resource modified nanocomposite glue-free paint-free environment-friendly decorative plate - Google Patents
Renewable resource modified nanocomposite glue-free paint-free environment-friendly decorative plate Download PDFInfo
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- CN102585397A CN102585397A CN2011104489935A CN201110448993A CN102585397A CN 102585397 A CN102585397 A CN 102585397A CN 2011104489935 A CN2011104489935 A CN 2011104489935A CN 201110448993 A CN201110448993 A CN 201110448993A CN 102585397 A CN102585397 A CN 102585397A
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Abstract
The invention discloses a renewable resource modified nanocomposite glue-free paint-free environment-friendly decorative plate, relates to the technical field of chemical building materials, and aims to solve the technical problems of low strength, short service life, low geometric dimensional stability, chemical toxicity and the like of the conventional imitation plastic decorative plate. The decorative plate consists of the following components in percentage by weight: 44.6 percent of polyvinyl chloride (PVC) material, 7.9 percent of PVC resin, 39.7 percent of heavy calcium carbonate, 0.3 percent of stearic acid, 0.7 percent of chlorinated polyethylene, 2 percent of foaming regulator, 0.3 percent of paraffin, 0.7 percent of novel plasticizer, 1.8 percent of stabilizing agent, 0.1 percent of calcium stearate, 0.1 percent of lead stearate and 1.8 percent of PVC.
Description
Technical field
The present invention relates to the chemical building material technical field, particularly utilize renewable resource such as useless pvc pipe of regeneration and white marble water-ground limestone to exempt from glue and exempt to coat with lacquer environmental-protection decorative sheet material for the modified Nano of raw material is compound.
Background technology
In present building material field, imitative plastic plate and PVC foaming plate are widely applied as dalle, but there are following problem usually in existing imitative plastic plate and PVC foaming plate:
1. product strength is not high, and the life-span is short, meets external force and is prone to fracture or crackle;
2. geometrical dimension stability is bad, and is yielding under the high temperature, is prone to take place embrittlement under the low temperature again;
3. has certain chemical toxicity;
4. wear resisting property is poor.
Summary of the invention
The present invention is intended to solve that existing imitative decorative plastic sheet material exists that product strength is not high, life-span weak point, geometrical dimension poor stability, have technical problem such as chemical toxicity, uses to provide a kind of that regeneration pvc pipe material and white marble rim charge, production cost are low, hardness and amount of elasticity is good, size is wet stablizes and the compound glue of exempting from of thermally-stabilised renewable resource modified Nano good, long service life exempts to coat with lacquer environmental-protection decorative sheet material.
The objective of the invention is to realize through following technical scheme.
The compound glue of exempting from of renewable resource modified Nano of the present invention exempts to coat with lacquer environmental-protection decorative sheet material, is made up of the component of following weight part: PVC material 44.6%, PVC RESINS 7.9%, water-ground limestone 39.7%, Triple Pressed Stearic Acid 0.3%, chlorinatedpolyethylene 0.7%, foaming control agent 2%, paraffin 0.3%, new plasticizer 0.7%, stablizer 1.8%, calcium stearate 0.1%, lead stearate 0.1%, SE 1.8%.
The compound glue of exempting from of renewable resource modified Nano of the present invention exempts to coat with lacquer environmental-protection decorative sheet material, and wherein said PVC material is regenerated using pvc pipe material.
The compound glue of exempting from of renewable resource modified Nano of the present invention exempts to coat with lacquer environmental-protection decorative sheet material, and wherein said Triple Pressed Stearic Acid is Triple Pressed Stearic Acid B1841.
The compound glue of exempting from of renewable resource modified Nano of the present invention exempts to coat with lacquer environmental-protection decorative sheet material, and wherein said chlorinatedpolyethylene is chlorinatedpolyethylene 135A.
The compound glue of exempting from of renewable resource modified Nano of the present invention exempts to coat with lacquer environmental-protection decorative sheet material, and wherein said foaming control agent is propenoate foaming control agent ZB-530.
The compound glue of exempting from of renewable resource modified Nano of the present invention exempts to coat with lacquer environmental-protection decorative sheet material, and wherein said stablizer is for containing lead salts high-efficiency compound stabilizer SW-206.
The compound glue of exempting from of renewable resource modified Nano of the present invention exempts to coat with lacquer environmental-protection decorative sheet material, and wherein said SE is SE ACR-401.
The compound beneficial effect of exempting from glue environmental-protection decorative sheet material of renewable resource modification multifunctional nano of the present invention:
1. use white pvc pipe waste material and white marble scrap stock to be main raw material, turn waste into wealth, save production cost, preserve the ecological environment;
2. chemical stabilization can not corrode;
3. shock-resistance is good, and the consistency and elasticity amount is good, can follow closely, and can dig, and is hard, antiwear characteristic;
4. size is wet stable and thermally-stabilised good, good insulating, and chance heat is indeformable, fire-retardant, does not fade long service life.
Embodiment
Application principle of the present invention, effect and effect are explained through following embodiment.
The compound glue of exempting from of renewable resource modified Nano of the present invention exempts to coat with lacquer environmental-protection decorative sheet material, is made up of the component of following weight part: PVC material 44.6%, PVC RESINS 7.9%, water-ground limestone 39.7%, Triple Pressed Stearic Acid 0.3%, chlorinatedpolyethylene 0.7%, foaming control agent 2%, paraffin 0.3%, new plasticizer 0.7%, stablizer 1.8%, calcium stearate 0.1%, lead stearate 0.1%, SE 1.8%.
Regeneration PVC material is regenerated using pvc pipe material; It is the useless pvc pipe of a kind of renewable resource utilization, the nano molecular that decomposes through mechanical disintegration be produce process exempt from glue paint-free decorating plate material, most important stopping composition; Utilize polyvinyl chemical structure and physicsization in the nanometer; In goods, not only play foamed stability, also improved goods wear resisting property and tensile strength simultaneously, changed the stability of goods.
PVC RESINS is PVC RESINS PVC, and it has fire-retardant, electrical insulating property, snappiness is good, and easy-formation is difficult for crisply, refuses poison, gas defence is pollution-free, and long service life is corrosion-resistant, firm and durable, and chemical proofing height and physical strength are high.Be the main raw material of regeneration PVC board materials production, polyvinyl chloride resin is widely used in building material industry, not only in industrial production, shows the advantage that its high-quality is cheap.And, be deep in the common people's the construction, for other people life adds lustre.
Water-ground limestone is the water-ground limestone of natural white marble stone flour sorting, its for natural white marble scrap stock with the natural heavy calcium carbonate (abbreviation coarse whiting) that mechanical means is pulverized, sorting forms, its application aspect the polymkeric substance of sheet material; Lime carbonate is very important stopping composition, adds in the goods, not only plays increase-volume, increment, reduces cost; Improve product surface and solidify wear resisting property tensile strength, shock strength; Flexural strength; Elongation at break and goods thermal property add coarse whiting in addition, can change the stability of goods.
Triple Pressed Stearic Acid is Triple Pressed Stearic Acid B1841, as softening agent, stablizer, is the PVC thermo-stabilizer, has good oilness and light, heat stabilization preferably.Add Triple Pressed Stearic Acid B1841 and help to prevent " coking " in the course of processing.
Chlorinatedpolyethylene is chlorinatedpolyethylene 135A, and it has good heat oxygen aging resistance, ozone ageing, acid and alkali-resistance, pharmaceutical chemicals performance.Oil resistance is outstanding, has splendid flame retardant properties, improves the toughness and the shock resistance of PVC goods.
Foaming control agent is propenoate foaming control agent ZB-530, and it is a kind of ethene polymers with superelevation nanometer of board product structure, is used for goods regeneration PVC plasticizing and improves surface quality and improve melt strength and ductile effect.Regeneration PVC extrudes and adds the ZB-530 foaming control agent in little foaming product; Can promote the gelation of PVC, that improves melt lets hot strength and extensibility, improves the trickle cell stabilization that products surface quality makes foaming; Do not make bubble wall rupture, so not only density is little but also intensity good for the bubble of gained.
Stablizer is for containing lead salts high-efficiency compound stabilizer SW-206, and its used auxiliary agent of PVC board materials production that is used to regenerate makes the thermal stability of product more superior, and it is lasting to make product have more resistance to deterioration, static resistance and smooth finish.
SE is SE ACR-401, and it can improve the PVC melting rate, shortens the fusion time; Improve stability, especially can strengthen the tenacity of product, outstanding hot strength and cohesive force are arranged; Make material group smooth surface, on various processors, all can promote processing smoothly to make product surface smooth; Do not have pin hole, air striped and melt fracture reduce flake and brilliant point.
The compound glue environmental-protection decorative sheet material of exempting from of renewable resource modification multifunctional nano of the present invention when producing, carries out milled processed with each component earlier, the component proportional mixing after will grinding again, and at high temperature stir, through the mould extrusion moulding.Product thickness is 1.5mm-2.5mm; Its surface is rich in gloss; Can be used for the upholstery decoration; Comprise large conference room, office, star hotel, luxurious place decoration, also can be used for furniture, cabinet, sanitary equipment, billboard making, art designing's material, building mould, Central European indoor suit doors etc.
Through experimental verification, renewable resource modified Nano of the present invention is compound exempts from glue and exempts to coat with lacquer environmental-protection decorative sheet material and can reach following technological standard:
Table 1 sheet material book size and permissible variation unit: mm
Table 2 sheet metal thickness deviation metric: mm
| Basic thickness | Permissible variation |
| 0.5≦h≦1.0 | ±0.05 |
| 1.0≦h≦2.0 | ±0.10 |
| 2.0≦h≦3.0 | ±0.20 |
Table 3 sheet material physical and mechanical property detects
It is mg/L that table 4 sheet material formaldehyde discharges the unit of limiting the quantity of
| Class emblem | Limit the quantity of | Use range |
| E0 | ≦0.5 | Can directly be used for indoor |
| E1 | ≦1.5 | Can directly be used for indoor |
| E2 | ≦5.0 | Handling the rear through facing can be used for indoor |
Table 5 sheet material radionuclide is limited the quantity of
| Project | Unit | Technical requirements |
| The internal radiation index | Ira | ≦1.0 |
| The external radiation exposure index | Ir | ≦1.3 |
In sum; The compound glue of exempting from of renewable resource modified Nano of the present invention exempts to coat with lacquer environmental-protection decorative sheet material, uses that regeneration pvc pipe material and white marble rim charge, production cost are low, hardness and amount of elasticity is good, size is wet stablizes and many technological merits of thermally-stabilised good, long service life.
Claims (7)
1. the compound glue of exempting from of renewable resource modified Nano exempts to coat with lacquer environmental-protection decorative sheet material, it is characterized in that being made up of the component of following weight part: PVC material 44.6%, PVC RESINS 7.9%, water-ground limestone 39.7%, Triple Pressed Stearic Acid 0.3%, chlorinatedpolyethylene 0.7%, foaming control agent 2%, paraffin 0.3%, new plasticizer 0.7%, stablizer 1.8%, calcium stearate 0.1%, lead stearate 0.1%, SE 1.8%.
2. the compound glue of exempting from of renewable resource modified Nano according to claim 1 exempts to coat with lacquer environmental-protection decorative sheet material, it is characterized in that: described PVC material is regenerated using pvc pipe material.
3. the compound glue of exempting from of renewable resource modified Nano according to claim 1 exempts to coat with lacquer environmental-protection decorative sheet material, and it is characterized in that: described Triple Pressed Stearic Acid is Triple Pressed Stearic Acid B1841.
4. the compound glue of exempting from of renewable resource modified Nano according to claim 1 exempts to coat with lacquer environmental-protection decorative sheet material, and it is characterized in that: described chlorinatedpolyethylene is chlorinatedpolyethylene 135A.
5. the compound glue of exempting from of renewable resource modified Nano according to claim 1 exempts to coat with lacquer environmental-protection decorative sheet material, it is characterized in that: described foaming control agent is propenoate foaming control agent ZB-530.
6. the compound glue of exempting from of renewable resource modified Nano according to claim 1 exempts to coat with lacquer environmental-protection decorative sheet material, it is characterized in that: described stablizer is for containing lead salts high-efficiency compound stabilizer SW-206.
7. the compound glue of exempting from of renewable resource modified Nano according to claim 1 exempts to coat with lacquer environmental-protection decorative sheet material, and it is characterized in that: described SE is SE ACR-401.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104489935A CN102585397A (en) | 2011-12-29 | 2011-12-29 | Renewable resource modified nanocomposite glue-free paint-free environment-friendly decorative plate |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104489935A CN102585397A (en) | 2011-12-29 | 2011-12-29 | Renewable resource modified nanocomposite glue-free paint-free environment-friendly decorative plate |
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| CN102585397A true CN102585397A (en) | 2012-07-18 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102875056A (en) * | 2012-10-11 | 2013-01-16 | 云南德发绿源板业有限公司 | Novel stone floor and production process thereof |
| CN105255065A (en) * | 2015-11-17 | 2016-01-20 | 雅安市晶强板业有限公司 | Green environment-friendly composite paint-free decorative material and production technology thereof |
| CN105643754A (en) * | 2015-12-04 | 2016-06-08 | 雅安市晶强板业有限公司 | Method for manufacturing wooden door veneer by using regenerative PVC (Polyvinyl Chloride) white pipe glue-free composite film |
| CN109720059A (en) * | 2019-01-17 | 2019-05-07 | 广东未来家园环保科技有限公司 | A kind of anion ecological dalle and its production and processing technology |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102061045A (en) * | 2010-12-17 | 2011-05-18 | 雅安市晶强板业有限公司 | Renewable resource modified multifunctional nano composite glue-free environmentally-friendly decorative slab |
| CN102070856A (en) * | 2010-12-09 | 2011-05-25 | 安徽省温禾木业有限公司 | Stone-plastic wood floor and processing technology thereof |
-
2011
- 2011-12-29 CN CN2011104489935A patent/CN102585397A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102070856A (en) * | 2010-12-09 | 2011-05-25 | 安徽省温禾木业有限公司 | Stone-plastic wood floor and processing technology thereof |
| CN102061045A (en) * | 2010-12-17 | 2011-05-18 | 雅安市晶强板业有限公司 | Renewable resource modified multifunctional nano composite glue-free environmentally-friendly decorative slab |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102875056A (en) * | 2012-10-11 | 2013-01-16 | 云南德发绿源板业有限公司 | Novel stone floor and production process thereof |
| CN105255065A (en) * | 2015-11-17 | 2016-01-20 | 雅安市晶强板业有限公司 | Green environment-friendly composite paint-free decorative material and production technology thereof |
| CN105643754A (en) * | 2015-12-04 | 2016-06-08 | 雅安市晶强板业有限公司 | Method for manufacturing wooden door veneer by using regenerative PVC (Polyvinyl Chloride) white pipe glue-free composite film |
| CN109720059A (en) * | 2019-01-17 | 2019-05-07 | 广东未来家园环保科技有限公司 | A kind of anion ecological dalle and its production and processing technology |
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Application publication date: 20120718 |