CN108586085A - A kind of production method of amino-acid trace element Water soluble fertilizer - Google Patents
A kind of production method of amino-acid trace element Water soluble fertilizer Download PDFInfo
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- CN108586085A CN108586085A CN201810769327.3A CN201810769327A CN108586085A CN 108586085 A CN108586085 A CN 108586085A CN 201810769327 A CN201810769327 A CN 201810769327A CN 108586085 A CN108586085 A CN 108586085A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
- C05G5/23—Solutions
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- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
Abstract
A kind of production method of amino-acid trace element Water soluble fertilizer, includes the following steps：（1）Mixed liquor in being pre-configured with three respectively, it is added according to material rate, it is stirred in addition, wherein mixed liquor one is made of copper sulphate, water, ammonium paramolybdate, amino-acid plant tonic liquor, mixed liquor two is made of ferrous sulfate, water, ammonium polyphosphate, amino-acid plant tonic liquor, urea, and mixed liquor three is made of water, manganese sulfate, zinc sulfate, boric acid, amino-acid plant tonic liquor；（2）Mixed liquor one, mixed liquor two, mixed liquor three are added to circulating emulsion in liquid shear machine, potassium pyrophosphate, stabilizer, bleeding agent are sequentially added while emulsification, continue emulsification 10 30 minutes, forms mixed liquor four, the mixed solution is through cooling, filtering, filling formation product.Trace element after amino acid and the double chelatings of ammonium polyphosphate, easily absorbs, it is not easy to be provided by soil, plant recovery of nutrient improves, and various nutritional deficiency phenomenons can be alleviated rapidly by being applied by foliage-spray and water-soluble punching.
Description
Technical field
The invention belongs to field of fertilizer production, are specifically related to a kind of production method of amino-acid trace element Water soluble fertilizer.
Background technology
Current China Water soluble fertilizer market product quality is irregular, and product effect gap is larger, especially microelement type
Water soluble fertilizer using effect is unstable, and npk nutrient utilization rate is not high, does not play the advantage of Water soluble fertilizer.In this regard, water chestnut collects
Engineering department of group utilizes the platform advantage of the national-level enterprise technique center of itself, integrated multi-party resource to increase Innovation Input, at
Vertical tackling key problem group, identifies by test of many times, filters out an optimum formula and process route repeatedly.
Invention content
The low present situation of unicity and utilization rate for current trace element chelated fertilizer material, the object of the present invention is to provide one
Kind amino-acid plant tonic liquor chelated copper, molybdenum trace element, the combined producing tech of ammonium polyphosphate chelating divalent iron microelement.
Technical scheme is as follows：A kind of production method of amino-acid trace element Water soluble fertilizer, steps are as follows：
(1) it is pre-configured with three kinds of mixed liquors respectively, is added according to material rate, is stirred in addition, wherein mixed liquor one
It is made of copper sulphate, water, ammonium paramolybdate, amino-acid plant tonic liquor, mixed liquor two is by ferrous sulfate, water, ammonium polyphosphate, amino
Sour plant nutrition liquid, urea composition, mixed liquor three are made of water, manganese sulfate, zinc sulfate, boric acid, amino-acid plant tonic liquor；
(2) by mixed liquor one, mixed liquor two, mixed liquor three according to 1:1:1 volume ratio is added in liquid shear machine and follows
Ring emulsifies, and potassium pyrophosphate, stabilizer, bleeding agent are sequentially added while emulsification, continues to emulsify 10min~30min, is formed mixed
Liquid four is closed, the mixed solution is through cooling, filtering, filling formation product.
Preferred embodiment, the key component and content of step (1) amino-acid plant tonic liquor are：Amino acid 1 8.5%~
21.5%, nitrogen 5.5%~6.0%, phosphorus 0.8%~1.1%, potassium 0.65%~0.85%, organic matter 20.5%~22%, reduction
Sugar 0.8%~0.9%.
The consumption proportion of preferred embodiment, one each raw material of step (1) mixed liquor is ammonium paramolybdate：Water：Copper sulphate：Amino acid
Plant nutrition liquid=5~10：5000:70~180:6000~8000, reaction temperature is 30 DEG C~50 DEG C, and the reaction time is
10min~30min, mixing speed are 60r/min~300r/min.
The consumption proportion of preferred embodiment, two raw material of step (1) mixed liquor is ferrous sulfate：Water：Ammonium polyphosphate：Amino acid
Plant nutrition liquid：Urea=2500~4500:10000:8000：37500, reaction temperature is 30 DEG C~50 DEG C, and the reaction time is
10min~50min, mixing speed are 60r/min~300r/min.
The consumption proportion of preferred embodiment, three raw material of step (1) mixed liquor is water：Manganese sulfate：Zinc sulfate：Boric acid：Amino acid
Plant nutrition liquid=5000:600~1600:100~200:100~200:43750, reaction temperature is 30 DEG C~50 DEG C, reaction
Time is 10min~20min, and mixing speed is 60r/min~300r/min.
Preferred embodiment, step (2) described stabilizer are in xanthans, sodium carboxymethylcellulose, 1 in sodium alginate or 2
Kind, additive amount is 0.05%~1%.
Preferred embodiment, the bleeding agent described in step (2) are a kind or 2 kinds in azone, organosilicon, additive amount 0.02%
~0.5%.
Preferred embodiment, the reaction temperature during step (2) circulating emulsion are 30 DEG C~50 DEG C, reaction time 10min
~20min, shear velocity are 1000r/min~3000r/min.
The additive amount of preferred embodiment, step (2) potassium pyrophosphate is 2.5%~24%.
The excellent effect of the present invention is embodied in：
1. the trace element after amino acid and the double chelatings of ammonium polyphosphate, easily absorbs, it is not easy to be provided by soil, nutrient
Utilization rate improves, and various nutritional deficiency phenomenons can be alleviated rapidly by being applied by foliage-spray and water-soluble punching.It can be used as the main of gourd, fruit and vegetable
Top dressing uses.
2. the trace element after chelating amino acids, can be by root system and Foliage Absorption.Mainly pass through wood from root system
Matter portion or Apoplastic spaces, as transpiration is transported up；It is mainly absorbed from blade face by stomata, into bast, downwards
Transport.The tissues such as root system, stem, blade, fruit are assigned to, transamination is then passed through, amino acid backbone is closed again
At other amino acid, structural proteins and functional protein are formed, it is micro- then be integrated into functional site, realize efficiently utilization.
3. being added step by step so that raw material fully dissolves, gained water in preparation method of the present invention by presetting three kinds of mixed liquors
Molten fertilizer mixing is more uniform, stablizes, it is not easy to generate layering and precipitation.
Description of the drawings
Fig. 1 is the production method flow chart of amino-acid trace element Water soluble fertilizer.
Specific implementation mode
Below in conjunction with the drawings and specific embodiments, the invention will be further described.It should be noted that following the description
Merely to explaining the present invention, its content is not defined.Unless otherwise instructed, the content of following each ingredients used is attached most importance to
Measure degree.Wherein the raw materials used in the present invention can be bought from raw materials market or voluntarily prepare.Amino-acid plant tonic
Liquid is produced by the Liangshan bio tech ltd Ling Hua of subordinate enterprise of Ling Hua groups；Zinc sulfate, manganese sulfate, copper sulphate, sulfuric acid are sub-
The trace element such as iron, ammonium paramolybdate, boric acid is the analysis pure raw material of market purchasing；Ammonium polyphosphate, potassium pyrophosphate, urea etc. are a large amount of
Element raw material is the industrial raw material of market purchasing；Azone, organosilicon, xanthans, sodium carboxymethylcellulose, sodium alginate are city
The industrial raw material of field buying；Water is the homemade deionized water of factory.
Embodiment 1
A kind of production method of amino-acid trace element Water soluble fertilizer, includes the following steps：
(1) it is pre-configured with three kinds of mixed liquors respectively, is added according to material rate, is stirred in addition, wherein mixed liquor one
It is made of 0.05g ammonium paramolybdate+50g water+0.78g copper sulphate+50ml amino-acid plant tonic liquors, reaction temperature is 30 DEG C, instead
It is 10min, mixing speed 60r/min between seasonable；
Mixed liquor two by 29.79g ferrous sulfate+100g water+80g ammonium polyphosphate+300ml amino-acid plant tonic liquors+
180g urea forms, and reaction temperature is 30 DEG C, reaction time 10min, mixing speed 60r/min
Mixed liquor three is by 50g water+6.11g manganese sulfate+1.77g zinc sulfate+1.14g boric acid+250ml amino-acid plant tonics
Liquid；Reaction temperature is 30 DEG C, reaction time 10min, mixing speed 60r/min；
The component and content of amino-acid plant tonic liquor be：Amino acid 1 8.5%~21.5%, nitrogen 5.5%~6.0%, phosphorus
0.8%~1.1%, potassium 0.65%~0.85%, organic matter 20.5%~22%, reduced sugar 0.8%~0.9%.
(2) by mixed liquor one, mixed liquor two, mixed liquor three according to 1:1:1 volume ratio is added in liquid shear machine and follows
Ring emulsifies, and reaction temperature is 30 DEG C, reaction time 10min, shear velocity 1000r/min, adds successively while emulsification
Enter 160g potassium pyrophosphates, stabilizer xanthans 0.8g, penetrant azone 0.4g, continues to emulsify 10min, form mixed liquor four, it should
Mixed solution is through cooling, filtering, filling formation product.
Embodiment 2
A kind of production method of amino-acid trace element Water soluble fertilizer, includes the following steps：
(1) it is pre-configured with three kinds of mixed liquors respectively, is added according to material rate, is stirred in addition, wherein mixed liquor one
It is made of 0.1g ammonium paramolybdate+50g water+0.78g copper sulphate+50ml amino-acid plant tonic liquors, reaction temperature is 30 DEG C, reaction
Time is 30min, mixing speed 100r/min；
Mixed liquor two by 29.79g ferrous sulfate+100g water+160g ammonium polyphosphate+300ml amino-acid plant tonic liquors+
90g urea forms, and reaction temperature is 30 DEG C, reaction time 30min, mixing speed 300r/min；
Mixed liquor three is by 50g water+6.11g manganese sulfate+1.77g zinc sulfate+1.14g boric acid+250ml amino-acid plant tonics
Liquid；Reaction temperature is 30 DEG C, reaction time 30min, mixing speed 200r/min；
The component and content of amino-acid plant tonic liquor be：Amino acid 1 8.5%~21.5%, nitrogen 5.5%~6.0%, phosphorus
0.8%~1.1%, potassium 0.65%~0.85%, organic matter 20.5%~22%, reduced sugar 0.8%~0.9%.
(2) by mixed liquor one, mixed liquor two, mixed liquor three according to 1:1:1 volume ratio is added in liquid shear machine and follows
Ring emulsifies, and reaction temperature is 45 DEG C, reaction time 10min, shear velocity 2000r/min, adds successively while emulsification
Enter 300g potassium pyrophosphates, stabilizer sodium carboxymethylcellulose 0.7g, bleeding agent organosilicon 0.9g, continue to emulsify 10min, is formed mixed
Liquid four is closed, the mixed solution is through cooling, filtering, filling formation product.
Embodiment 3
A kind of production method of amino-acid trace element Water soluble fertilizer, includes the following steps：
(1) it is pre-configured with three kinds of mixed liquors respectively, is added according to material rate, is stirred in addition, wherein mixed liquor one
It is made of 0.05g ammonium paramolybdate+50g water+0.78g copper sulphate+50ml amino-acid plant tonic liquors, reaction temperature is 30 DEG C, instead
It is 15min, mixing speed 60r/min between seasonable；
Mixed liquor two by 45.31g ferrous sulfate+100g water+20g ammonium polyphosphate+300ml amino-acid plant tonic liquors+
540g urea forms, and reaction temperature is 30 DEG C, reaction time 10min, mixing speed 60r/min
Mixed liquor three is sought by 50g water+15.28g manganese sulfate+1.77g zinc sulfate+1.14g boric acid+250ml amino acid plants
Nutrient solution；Reaction temperature is 30 DEG C, reaction time 30min, mixing speed 60r/min；
The component and content of amino-acid plant tonic liquor be：Amino acid 1 8.5%~21.5%, nitrogen 5.5%~6.0%, phosphorus
0.8%~1.1%, potassium 0.65%~0.85%, organic matter 20.5%~22%, reduced sugar 0.8%~0.9%.
(2) by mixed liquor one, mixed liquor two, mixed liquor three according to 1:1:1 volume ratio is added in liquid shear machine and follows
Ring emulsifies, and reaction temperature is 30 DEG C, reaction time 10min, shear velocity 3000r/min, adds successively while emulsification
Enter 40g potassium pyrophosphates, stabilizer sodium alginate 1.2g, penetrant azone and organosilicon 2.4g, continue to emulsify 10min, is formed mixed
Liquid four is closed, the mixed solution is through cooling, filtering, filling formation product.
Contrast experiment's example 1
A kind of production method of amino-acid trace element Water soluble fertilizer, compared with Example 1, difference lies in sulphur in step (1)
Sour zinc is added in mixed liquor two.
As a result as follows：
Table 1
Comparative example 2
A kind of production method of amino-acid trace element Water soluble fertilizer, compared with Example 1, difference lies in step (2) not
Add potassium pyrophosphate.As a result as follows：
Table 2
Comparative example 3
A kind of production method of amino-acid trace element Water soluble fertilizer, compared with Example 1, difference lies in step (2) shearings
Machine rotating speed is less than 1000r/min, and emulsification times are less than 10min.As a result as follows：
Table 3
Influence of the different factors for product quality, as follows：
Table 4
Using effect
The amino-acid trace element fertilizer of preparation is used as top dressing, be colonized in tomato, bear fruit respectively, swollen fruit, first fruit and Sheng
Five period equivalent of fruit apply, and compare the chemical Water soluble fertilizer for equal N-P-K content.To measure effect of fertilizer, respectively in maturation
Phase measures plant height, stem thickness, root dry weight, overground part dry weight and fruit yield.It is sprinkled profoundly water after transplanting, laying plastic, before bearing fruit not
Watering, timely lifting rope.Tomato is pinched after retaining 4 layers of fruit.First layer fruit retains 4, and second layer fruit retains 3, third
Layer fruit retains 3, and the 4th layer of fruit retains 2.Plant protection management is carried out according to green standard.
Maturity period Major Yield Characters are as follows
Table 5
From the foregoing, it will be observed that using amino acid Water soluble fertilizer, either stem thickness, root dry weight, overground part dry weight obtained by the application, still
Fruit yield is significantly better than that using chemical synthesis Water soluble fertilizer.It can be explained accordingly, by amino acid and the double chelatings of ammonium polyphosphate
Trace element afterwards easily absorbs, it is not easy to be provided by soil, plant recovery of nutrient improves, and can dramatically increase the yield of fruit.
Claims (10)
1. a kind of production method of amino-acid trace element Water soluble fertilizer, which is characterized in that include the following steps：
（1）It is pre-configured with three kinds of mixed liquors respectively, is added according to material rate, is stirred in addition, wherein mixed liquor one is by sulphur
Sour copper, water, ammonium paramolybdate, amino-acid plant tonic liquor composition, mixed liquor two are planted by ferrous sulfate, water, ammonium polyphosphate, amino acid
Object nutrient solution, urea composition, mixed liquor three are made of water, manganese sulfate, zinc sulfate, boric acid, amino-acid plant tonic liquor；
（2）By mixed liquor one, mixed liquor two, mixed liquor three according to 1:1:1 volume ratio is added in liquid shear machine and recycles breast
Change, potassium pyrophosphate, stabilizer, bleeding agent are sequentially added while emulsification, continues to emulsify 10min ~ 30min, form mixed liquor
Four, the mixed solution is through cooling, filtering, filling formation product.
2. production method as described in claim 1, which is characterized in that step（1）The key component of amino-acid plant tonic liquor
And content is：Amino acid 1 8.5% ~ 21.5%, nitrogen 5.5% ~ 6.0%, phosphorus 0.8% ~ 1.1%, potassium 0.65% ~ 0.85%, organic matter 20.5% ~
22%, reduced sugar 0.8% ~ 0.9%.
3. production method as claimed in claim 2, which is characterized in that step（1）The density of amino-acid plant tonic liquor adjusts
For 1250kg/m3。
4. production method as described in claim 1, which is characterized in that step（1）The consumption proportion of one each raw material of mixed liquor is,
Ammonium paramolybdate：Water：Copper sulphate：Amino-acid plant tonic liquor=5 ~ 10：5000:70~180:6000 ~ 8000, reaction temperature is 30 DEG C
~ 50 DEG C, the reaction time is 10min ~ 30min, and mixing speed is the r/min of 60 r/min ~ 300.
5. production method as described in claim 1, which is characterized in that step（1）The consumption proportion of two raw material of mixed liquor is sulphur
It is sour ferrous：Water：Ammonium polyphosphate：Amino-acid plant tonic liquor：Urea=2500 ~ 4500:10000:8000：37500, reaction temperature
It it is 30 DEG C ~ 50 DEG C, the reaction time is 10min ~ 50min, and mixing speed is the r/min of 60 r/min ~ 300.
6. production method as described in claim 1, which is characterized in that step（1）The consumption proportion of three raw material of mixed liquor is,
Water：Manganese sulfate：Zinc sulfate：Boric acid：Amino-acid plant tonic liquor=5000:600~1600:100~200:100~200:43750, instead
It is 30 DEG C ~ 50 DEG C to answer temperature, and the reaction time is 10min ~ 20min, and mixing speed is the r/min of 60 r/min ~ 300.
7. production method as described in claim 1, which is characterized in that step（2）The stabilizer is xanthans, carboxymethyl fibre
1 kind or 2 kinds in the plain sodium of dimension, sodium alginate, additive amount is 0.05% ~ 1%.
8. production method as described in claim 1, which is characterized in that step（2）The bleeding agent is in azone, organosilicon
1 kind or 2 kinds, additive amount be 0.02% ~ 0.5%.
9. production method as described in claim 1, which is characterized in that step（2）Reaction temperature during circulating emulsion is
30 DEG C ~ 50 DEG C, the reaction time is 10min ~ 20min, and shear velocity is the r/min of 1000 r/min ~ 3000.
10. production method as described in claim 1, which is characterized in that step（2）The additive amount of potassium pyrophosphate be 2.5% ~
24%。
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110790611A (en) * | 2019-12-03 | 2020-02-14 | 杭州三得农业科技有限公司 | Manufacturing process of special organic soluble fertilizer for leguminous plants |
| CN114940636A (en) * | 2022-06-27 | 2022-08-26 | 北京君德同创生物技术股份有限公司 | Liquid water-soluble fertilizer and preparation method and application thereof |
| CN115304422A (en) * | 2022-08-19 | 2022-11-08 | 北京建佳农科技发展有限责任公司 | Liquid fertilizer and preparation method thereof |
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