CN108584911A - Reduce the environment-friendlycharcoal charcoal and preparation method thereof of ignition point - Google Patents
Reduce the environment-friendlycharcoal charcoal and preparation method thereof of ignition point Download PDFInfo
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- CN108584911A CN108584911A CN201810654439.4A CN201810654439A CN108584911A CN 108584911 A CN108584911 A CN 108584911A CN 201810654439 A CN201810654439 A CN 201810654439A CN 108584911 A CN108584911 A CN 108584911A
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- C01—INORGANIC CHEMISTRY
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Abstract
The invention discloses the environment-friendlycharcoal charcoals and preparation method thereof for reducing ignition point, include the following steps：1) feedstock processing：By mushroom residue, it is ground into the filter mud given off in particle and cane sugar factory production process and is mixed with bagasse；2) batch mixing；3) it ferments：1 part of fermenting agent mixing, accumulation are added in the material obtained to the step 2) of 100 parts by weight, top burrows ventilation, it is 68 to control pH, water content is 60 65%, start-up temperature is 15 DEG C, and fermentation temperature is at 70 DEG C hereinafter, fermenting 37 days, the leavening is made of sulfur oxidizing bacterium and denitrification bacillus, is mixed to get for arbitrary proportion；4) drying, stick processed molding：Bar is made by bar-producing machine in the drying materials that step 3) is obtained at high temperature under high pressure；5) charing process：The bar that step 4) is obtained carries out charing process in retort, then takes out cooling, packs to obtain finished product.
Description
Technical field
The invention belongs to fuel processing technique fields, and in particular to reduce environment-friendlycharcoal charcoal of ignition point and preparation method thereof.
Background technology
In recent years, popularizing with fungus growing technique, planting edible mushroom area expands rapidly, and kind constantly increases
It is more, it has also become one of the major economic crops in China's agricultural production.Cultivate the solid waste that leaves after various edible mushrooms
Mushroom residue, abbreviation mushroom slag are called mushroom chaff, bacteria residue, leftover bits and pieces etc. in the place of cultivated mushroom, can all there is largely discarded mushroom every year
Mushroom material residue generates.After harvesting 100kg fresh mushrooms, 60kg mushroom slag wastes can also be obtained.Edible Fungi person mushroom harvest after,
It is that the waste material stayed had not only accounted in place, but also pollution environment to feel troublesome.
Resource plaque is weary, environmental degradation is vital issue facing mankind in the world today, finds the renewable sources of energy and exactly works as moderns
The great difficult problem that class faces.China is as agricultural production big country, and according to the statistics made by the departments concerned, the residues such as annual agricultural crop straw are
Hundred million tons of 60-70, but its utilization rate only has 20%, and remaining also has more than one hundred million as garbage disposal, branch, sawdust, straw, cornstalk etc.
Ton is thrown away.
Environment-friendlycharcoal charcoal has two layers of meaning, when energy conservation and environmental protection when it is produced, second is that environmental protection when it is used.The exploitation profit of environment-friendlycharcoal charcoal
With all of above waste material can be made to become new energy just, save forest (forestry) resource, alleviate charcoal supply it is small sufficient tight
Situation is opened, reduces environmental pollution, improves the ecological environment, be conducive to national economy sustainable and healthy development.The product of environment-friendlycharcoal charcoal is main
For the civil fields such as the industrial circles such as metallurgy, chemical industry and food barbecue, heating, have the advantage that：Environmental protection, when burning colourless nothing
It is taste, smokeless；Resistance to burning, every 0.5 kilogram of firewood charcoal incendivity 1 hour, and environment-friendlymachine-made machine-made charcoal incendivity per jin 3-4 hours,
It is also the inexorable trend of development in science and technology simultaneously.
It using mushroom residue and lignocellulose degradation strain by ferment making environment-friendlycharcoal charcoal, not only reduced environmental pollution, but also can increase
Multi-level utilization to living resources improves ecological benefits, realizes the cyclic utilization of waste and agricultural sustainable development.Existing making
In the raw material of environment-friendlycharcoal charcoal, a large amount of organic protein, nitrogen and sulfide, direct pressing system are rich in especially in fermentation raw material
It is made environment-friendlycharcoal charcoal, or only passes through simple ferment making environment-friendlycharcoal charcoal, when use still will produce flue gas, actually use
Cheng Zhong, consumer, which generally reflects fuel combustion still, has flue gas to smoke eye phenomenon, and in kitchen, use must force air draft with wind turbine
It can work normally, cause use environment bad.
Invention content
The purpose of the present invention is overcoming the deficiencies of the prior art and provide the environment-friendlycharcoal charcoal and preparation method thereof for reducing ignition point,
Obtained environment-friendlycharcoal charcoal, calorific value is high, can effectively reduce ignition point, and not will produce flue gas fumigation problem.
The preparation method of the environment-friendlycharcoal charcoal of the present invention for reducing ignition point, includes the following steps：
1) feedstock processing：Mushroom residue is ground into the filter mud given off in particle and cane sugar factory production process and sugarcane
Slag mixes；
2) batch mixing：0.1-2.0 parts of quick lime, sodium bicarbonate are added in the mixture obtained to the step 1) of 100 parts by weight
0.1-1.0 parts, 0.1-1.0 parts of calcium superphosphate, 0.1-1.0 parts of potassium sulfate, 0.1-1.0 parts of magnesium sulfate, 0.1-0.5 parts of sodium nitrate,
0.1-0.5 parts of copper sulphate, 0.1-1.0 parts of iron chloride, mixing is spare；
3) it ferments：1 part of fermenting agent mixing, accumulation are added in the material obtained to the step 2) of 100 parts by weight, top is beaten
Hole is ventilated, and control pH is 6-8, and water content 60-65%, start-up temperature is 15 DEG C, and fermentation temperature is at 70 DEG C hereinafter, fermentation 3-7
It, the leavening is made of sulfur oxidizing bacterium and denitrification bacillus, is mixed to get for arbitrary proportion；
4) drying, stick processed molding：Stick is made by bar-producing machine in the drying materials that step 3) is obtained at high temperature under high pressure
Material；
5) charing process：The bar that step 4) is obtained carries out charing process in retort, then takes out cooling, packaging
Obtain finished product.
Crushing described in step 1) of the present invention, particle are less than 3mm.
The filter mud given off in described in step 1) and cane sugar factory production process is with bagasse according to 60-70:30-40
Mass ratio mixing.
In leavening described in step 3), sulfur oxidizing bacterium is photoautotrophy, chemosynthetic autotroph photosynthetic bacteria, Latin literary fame
Sulphur-oxidising Bacteria, ammonia nitrogen, nitrosonium salts, hydrogen sulfide in trans-utilization material, accelerate nutrient recycling.
Denitrification bacillus, the entitled Fanbacillus of Latin, one kind of denitrifying bacteria, the nitrite in reducing material,
It is allowed to generate harmless nitrogen, releases the harm of nitrite.
Leavening described in step 3) is to expand to cultivate by strain, and liquid bacterial agent or solid fungicide is made, adopts respectively
It prepares with the following methods：
The preparation of liquid bacterial agent：The above strain is inoculated in scale-up medium, under aerobic condition, 25 DEG C expand training
3-5d is supported, pH value is 3-6 after fermentation, and the living bacteria count of gained microbial inoculum is more than 100,000,000/g, and miscellaneous bacteria rate is less than 20%；
The preparation of solid fungicide：It will be inoculated in and expand in culture medium in the above strain, under aerobic condition, 25 DEG C of expansions
3-5d is cultivated, pH value is 3-6 after fermentation, and vacuum freeze-drying after fermentation grinds or crushes, is uniformly mixed, effective work of gained microbial inoculum
Bacterium number is more than 2.5 hundred million/g, and miscellaneous bacteria rate is less than 30%.
Drying described in step 4), control moisture is within 12%；The high temperature and pressure, temperature are 150-200 DEG C, pressure
Power is 60-80MPa；Bar is made, is formed into the hollow bar of hexagonal configuration.
Charing process described in step 5) is handled 20 hours with reference to the prior art.
The invention further relates to the environment-friendlycharcoal charcoals obtained using above-mentioned preparation method.
Compared with prior art, the advantage of the invention is that：
1, batch mixing of the invention is the formula added for orientation fermentation culture, by can be effective after microorganism conversion
The generation for reducing smog, keeps the comfortable of use environment.
2, the sulfur oxidizing bacterium that the present invention adds, can be under anaerobism illumination or aerobic dark condition using organic in nature
Object, sulfide, ammonia etc. carry out photosynthetic microorganism as hydrogen donor and carbon source, can largely consume nitrogen, element sulphur.This
The denitrifying bacterium of addition is invented, bacterial strain denitrifying capacity is strong, can make nitrogen source with nitrite nitrogen and nitrate nitrogen.The present invention passes through sulphur
The raw material of oxidation bacteria and denitrification bacillus fermentation processing environment-friendlycharcoal charcoal, has decomposed the ingredient in feed particles, can effectively prevent firing
Snuff phenomenon during burning.
3, the obtained environment-friendlycharcoal charcoal of the present invention, has that burning time is long, firepower is prosperous, calorific value is big, and ash content is low, smokeless, tasteless
The characteristics of, existing environment-friendlycharcoal charcoal incendivity 3-4 hours, the environment-friendlycharcoal charcoal that the present invention obtains can burn 4.7-5.6 hours, meanwhile, it can
Effectively to reduce ignition point.
4, the environment-friendlycharcoal charcoal that the present invention obtains, every physical and chemical index are superior to common charcoal, and coal, calorie can be replaced to reach 5100
More than kilocalorie, operating mode enterprise burning boiler is suitble to use；It can also be used for warming oneself, in the daily lifes such as barbecue.
Specific implementation mode
With embodiment, the invention will be further described below, but the invention is not limited in these embodiments.
Embodiment 1：
The preparation method for reducing the environment-friendlycharcoal charcoal of ignition point, includes the following steps：
1) feedstock processing：Mushroom residue is ground into the filter given off in the particle less than 3mm and cane sugar factory production process
Mud is with bagasse according to 60:40 mass ratio mixing；
2) batch mixing：In the mixture obtained to the step 1) of 100 parts by weight be added 0.1 part of quick lime, 1.0 parts of sodium bicarbonate,
0.1 part of calcium superphosphate, 1.0 parts of potassium sulfate, 0.1 part of magnesium sulfate, 0.5 part of sodium nitrate, 0.1 part of copper sulphate, 1.0 parts of iron chloride mix
It is even spare；
3) it ferments：1 part of fermenting agent mixing, accumulation are added in the material obtained to the step 2) of 100 parts by weight, top is beaten
Hole is ventilated, and control pH is 6-8, and water content 60-65%, start-up temperature is 15 DEG C, and fermentation temperature is at 70 DEG C hereinafter, fermentation 3-7
It, the leavening is made of sulfur oxidizing bacterium and denitrification bacillus, is mixed to get for arbitrary proportion；
4) drying, stick processed molding：The drying materials that step 3) is obtained, control moisture pass through bar-producing machine within 12%
At high temperature under high pressure, temperature is 150-200 DEG C, pressure 60-80MPa, and the hollow bar of hexagonal configuration is made；
5) charing process：The bar that step 4) is obtained carries out charing process 20 hours in retort, then takes out cold
But, finished product is packed to obtain.
Embodiment 2：
The preparation method for reducing the environment-friendlycharcoal charcoal of ignition point, includes the following steps：
1) feedstock processing：Mushroom residue is ground into the filter given off in the particle less than 3mm and cane sugar factory production process
Mud is with bagasse according to 65:35 mass ratio mixing；
2) batch mixing：In the mixture obtained to the step 1) of 100 parts by weight be added 2.0 parts of quick lime, 0.1 part of sodium bicarbonate,
1.0 parts of calcium superphosphate, 0.1 part of potassium sulfate, 1.0 parts of magnesium sulfate, 0.1 part of sodium nitrate, 0.5 part of copper sulphate, 0.1 part of iron chloride mix
It is even spare；
3) it ferments：1 part of fermenting agent mixing, accumulation are added in the material obtained to the step 2) of 100 parts by weight, top is beaten
Hole is ventilated, and control pH is 6-8, and water content 60-65%, start-up temperature is 15 DEG C, and fermentation temperature is at 70 DEG C hereinafter, fermentation 3-7
It, the leavening is made of sulfur oxidizing bacterium and denitrification bacillus, is mixed to get for arbitrary proportion；
4) drying, stick processed molding：The drying materials that step 3) is obtained, control moisture pass through bar-producing machine within 12%
At high temperature under high pressure, temperature is 150-200 DEG C, pressure 60-80MPa, and the hollow bar of hexagonal configuration is made；
5) charing process：The bar that step 4) is obtained carries out charing process 20 hours in retort, then takes out cold
But, finished product is packed to obtain.
Embodiment 3：
The preparation method for reducing the environment-friendlycharcoal charcoal of ignition point, includes the following steps：
1) feedstock processing：Mushroom residue is ground into the filter given off in the particle less than 3mm and cane sugar factory production process
Mud is with bagasse according to 70:30 mass ratio mixing；
2) batch mixing：In the mixture obtained to the step 1) of 100 parts by weight be added 1.0 parts of quick lime, 0.5 part of sodium bicarbonate,
0.5 part of calcium superphosphate, 0.5 part of potassium sulfate, 0.5 part of magnesium sulfate, 0.2 part of sodium nitrate, 0.3 part of copper sulphate, 0.5 part of iron chloride mix
It is even spare；
3) it ferments：1 part of fermenting agent mixing, accumulation are added in the material obtained to the step 2) of 100 parts by weight, top is beaten
Hole is ventilated, and control pH is 6-8, and water content 60-65%, start-up temperature is 15 DEG C, and fermentation temperature is at 70 DEG C hereinafter, fermentation 3-7
It, the leavening is made of sulfur oxidizing bacterium and denitrification bacillus, is mixed to get for arbitrary proportion；
4) drying, stick processed molding：The drying materials that step 3) is obtained, control moisture pass through bar-producing machine within 12%
At high temperature under high pressure, temperature is 150-200 DEG C, pressure 60-80MPa, and the hollow bar of hexagonal configuration is made；
5) charing process：The bar that step 4) is obtained carries out charing process 20 hours in retort, then takes out cold
But, finished product is packed to obtain.
Comparative example 1：
1) feedstock processing：Mushroom residue is ground into the filter given off in the particle less than 3mm and cane sugar factory production process
Mud is with bagasse according to 70:30 mass ratio mixing；
2) drying, stick processed molding：The drying materials that step 1) is obtained to moisture within 12%, by bar-producing machine in height
The hollow bar of hexagonal configuration is made under warm high pressure；
3) charing process：The bar that step 2) is obtained carries out charing process 20 hours in retort, then takes out cold
But, finished product is packed to obtain.
Comparative example 2：
1) feedstock processing：Mushroom residue is ground into the filter given off in the particle less than 3mm and cane sugar factory production process
Mud is with bagasse according to 70:30 mass ratio mixing；
2) fermentation process：Step 1) is obtained Bifidobacterium, actinomyces are added in raw material, according to 1000:1 weight ratio
Mixing adjusts humidity 70%, aseptically ferments 3 days；
3) drying, stick processed molding：The drying materials that step 2) is obtained, control moisture pass through bar-producing machine within 12%
At high temperature under high pressure, temperature is 150-200 DEG C, pressure 60-80MPa, and the hollow bar of hexagonal configuration is made；
4) charing process：The bar that step 3) is obtained carries out charing process 20 hours in retort, then takes out cold
But, finished product is packed to obtain.
As a result 1：
As a result 2：
Claims (7)
1. reducing the preparation method of the environment-friendlycharcoal charcoal of ignition point, which is characterized in that include the following steps：
1) feedstock processing：By mushroom residue, it is ground into the filter mud given off in particle and cane sugar factory production process and bagasse is mixed
It closes；
2) batch mixing：0.1-2.0 parts of quick lime, sodium bicarbonate 0.1-1.0 are added in the mixture obtained to the step 1) of 100 parts by weight
Part, 0.1-1.0 parts of calcium superphosphate, 0.1-1.0 parts of potassium sulfate, 0.1-1.0 parts of magnesium sulfate, 0.1-0.5 parts of sodium nitrate, copper sulphate
0.1-0.5 parts, 0.1-1.0 parts of iron chloride, mixing is spare；
3) it ferments：1 part of fermenting agent mixing, accumulation are added in the material obtained to the step 2) of 100 parts by weight, top burrows logical
Gas, control pH be 6-8, water content 60-65%, start-up temperature be 15 DEG C, fermentation temperature at 70 DEG C hereinafter, fermentation 3-7 days, institute
The leavening stated is made of sulfur oxidizing bacterium and denitrification bacillus, is mixed to get for arbitrary proportion；
4) drying, stick processed molding：Bar is made by bar-producing machine in the drying materials that step 3) is obtained at high temperature under high pressure；
5) charing process：The bar that step 4) is obtained carries out charing process in retort, then takes out cooling, pack at
Product.
2. the preparation method of the environment-friendlycharcoal charcoal according to claim 1 for reducing ignition point, it is characterised in that：Step 1) of the present invention
The crushing, particle are less than 3mm.
3. the preparation method of the environment-friendlycharcoal charcoal according to claim 1 for reducing ignition point, it is characterised in that：Described in step 1)
Sugaring waste, it is described and being given off in cane sugar factory production process for the filter mud and molasses obtained after sugar refinery's production
Filter mud is with bagasse according to 60-70:The mass ratio of 30-40 mixes.
4. the preparation method of the environment-friendlycharcoal charcoal according to claim 1 for reducing ignition point, it is characterised in that：Described in step 3)
Leavening is to expand to cultivate by strain, and liquid bacterial agent or solid fungicide is made, and following manner preparation is respectively adopted：
The preparation of liquid bacterial agent：The above strain is inoculated in scale-up medium, under aerobic condition, 25 DEG C expand culture 3-
5d, pH value is 3-6 after fermentation, and the living bacteria count of gained microbial inoculum is more than 100,000,000/g, and miscellaneous bacteria rate is less than 20%；
The preparation of solid fungicide：It will be inoculated in and expand in culture medium in the above strain, under aerobic condition, 25 DEG C expand culture 3-
5d, pH value is 3-6 after fermentation, and vacuum freeze-drying after fermentation grinds or crushes, is uniformly mixed, the living bacteria count of gained microbial inoculum is big
In 2.5 hundred million/g, miscellaneous bacteria rate is less than 30%.
5. the preparation method of the environment-friendlycharcoal charcoal according to claim 1 for reducing ignition point, it is characterised in that：Described in step 4)
Drying is control moisture within 12%；The high temperature and pressure, temperature are 150-200 DEG C, pressure 60-80MPa；It is made
Bar is formed into the hollow bar of hexagonal configuration.
6. the preparation method of the environment-friendlycharcoal charcoal according to claim 1 for reducing ignition point, it is characterised in that：Described in step 5)
Charing process is handled 20 hours with reference to the prior art.
7. the environment-friendlycharcoal charcoal for the reduction ignition point that any one of claim 1-6 the methods obtain.
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| CN201810654439.4A CN108584911A (en) | 2018-06-22 | 2018-06-22 | Reduce the environment-friendlycharcoal charcoal and preparation method thereof of ignition point |
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| CN201810654439.4A CN108584911A (en) | 2018-06-22 | 2018-06-22 | Reduce the environment-friendlycharcoal charcoal and preparation method thereof of ignition point |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105272468A (en) * | 2015-10-29 | 2016-01-27 | 广西海盛源生物科技有限公司 | Biological organic fertilizer for aquaculture and preparation method thereof |
| CN105778947A (en) * | 2016-04-18 | 2016-07-20 | 广西海虹能源科技有限公司 | Environment-friendly charcoal and preparation technology |
| CN106281562A (en) * | 2016-09-23 | 2017-01-04 | 福建省农业科学院农业工程技术研究所 | The method preparing biomass fuel for primary raw material with fresh pig manure |
-
2018
- 2018-06-22 CN CN201810654439.4A patent/CN108584911A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105272468A (en) * | 2015-10-29 | 2016-01-27 | 广西海盛源生物科技有限公司 | Biological organic fertilizer for aquaculture and preparation method thereof |
| CN105778947A (en) * | 2016-04-18 | 2016-07-20 | 广西海虹能源科技有限公司 | Environment-friendly charcoal and preparation technology |
| CN106281562A (en) * | 2016-09-23 | 2017-01-04 | 福建省农业科学院农业工程技术研究所 | The method preparing biomass fuel for primary raw material with fresh pig manure |
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