CN108570303A - A kind of novel metal Plastics adhesives and its preparation method and application - Google Patents
A kind of novel metal Plastics adhesives and its preparation method and application Download PDFInfo
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- CN108570303A CN108570303A CN201710300657.3A CN201710300657A CN108570303A CN 108570303 A CN108570303 A CN 108570303A CN 201710300657 A CN201710300657 A CN 201710300657A CN 108570303 A CN108570303 A CN 108570303A
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- novel metal
- metal plastics
- door leaf
- plastics adhesives
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
- E06B3/70—Door leaves
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/06—Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
- E06B3/70—Door leaves
- E06B2003/7049—Specific panel characteristics
Abstract
The invention discloses a kind of novel metallo-plastic adhesive, including following group is grouped as：16~24 parts of polyurethane formic acid esters；7~18 parts of dibutyl phthalate；4~10 parts of propylene oxide phenyl ether；3~6 parts of tricresyl phosphate；5~14 parts of borax；8~13 parts of quartz sand；4~7 parts of calcium carbonate；12~20 parts of boron oxide；4~8 parts of zinc oxide；8~15 parts of sodium bicarbonate；4~8 parts of antifoaming agent；2~4 parts of initiator；5~7 parts of toughener；(NH4)3C6H5O77~18 parts.The adhesive of gained has very good adhesion simultaneously to metal and plastics.
Description
Technical field
The present invention relates to field of material technology, more specifically, it relates to a kind of novel metal Plastics adhesives and its system
Preparation Method and application.
Background technology
Building decorative plates have broad application prospects in building field and are increasingly valued by people, wherein various
Door trim panels are exactly one such.Existing door trim panels are mostly aluminum alloy material, and people are before the use often in door
Plate surface is coated with one layer of protective paint.However since protective paint is plastics, door-plate is metal, adhesive force of the protective paint on door-plate
Limited, it is easy to appear protective paints to fall off after a period of use.
The method for solving problem above at present is usually that plate surface is chemically treated on the door before coating, improves surface
Roughness to facilitate protective paint to be adhered to above.This method can solve the problems, such as that protective paint falls off to a certain extent, but
Apply chemical treatment process trouble.So the present invention proposes that one kind applying last layer adhesive before coating protective paint on door-plate
Method, to improve the binding force between protective paint and door-plate.
Adhesive is a kind of object that a variety of materials are firmly bonded together by interface interaction (physical force, chemical force)
Matter, existing adhesive intermolecular interaction is uneven, and cohesive force is inadequate, cannot play bond effect well, there is viscosity
Uneven, easy to crack disadvantage, therefore, for existing adhesive up for further improving.
Invention content
The first object of the present invention is to provide a kind of novel metal Plastics adhesives.
To achieve the above object, it is realized by following technological means：
A kind of novel metal Plastics adhesives, which is characterized in that the group including following parts by weight is grouped as：
Advanced optimize for：A kind of novel metal Plastics adhesives, which is characterized in that the group grouping including following parts by weight
At：
Advanced optimize for：A kind of novel metal Plastics adhesives, which is characterized in that the group grouping including following parts by weight
At：
Advanced optimize for：The antifoaming agent is diethylene glycol monomethyl ether or the equal polyethers of PolyTHF or two kinds
Combination.
Advanced optimize for：The initiator is one kind in triethanolamine, polyamide, potassium peroxydisulfate, ammonium persulfate
Or it is a variety of.
Advanced optimize for：The toughener is polysulfide rubber or fully cured ultrafine powdered styrene-butadiene rubber or two kinds of group
It closes.
The second object of the present invention is to provide a kind of a kind of novel metal Plastics adhesives that can at least solve the above problems
Preparation method, include the following steps：
Step 1: weighing each raw material according to components by weight percent；
Step 2: alleged dibutyl phthalate, tricresyl phosphate and the polyurethane formic acid esters obtained is sufficiently mixed,
It is charged with borax and quartz sand, 100~150 DEG C of 30~50min of high-speed stirred is heated to, keeps borax and quartz sand fully molten
Solution obtains clear solution；
Step 3: the alleged boron oxide obtained and zinc oxide are added in propylene oxide phenyl ether, it is heated to 200~300 DEG C
Quickly 20~40min of stirring, obtains turbid solution；
Step 4: the clear solution obtained by step 2 is poured into the turbid solution obtained by step 3, and sequentially add carbonic acid
Calcium, sodium bicarbonate, (NH4)3C6H5O7With antifoaming agent, initiator, 1~2h of stirring at normal temperature obtains emulsion state mixture；
Step 5: toughener is added into the emulsion state mixture obtained by step 4,20~40min of stirring at normal temperature to obtain the final product
Adhesive.
It is as follows the present invention also provides a kind of production technology of the door-plate using the novel metal Plastics adhesives：
One, phosphatization removes the oil and rust of doorframe door leaf surface by chemistry and electrochemical reaction；
Two, it coats, the metallo-plastic adhesive is coated on the doorframe door leaf after phosphatization；
Three, plastic-spraying sprays upper required plastic powders on the doorframe door leaf after coated；
Four, it transfers, the grain pattern on transfer paper is transferred to doorframe door leaf surface by hot pressing；
Five, it paints, is applied together in doorframe door leaf surface or a few road varnish increase or improve coating surface glossiness.
Six, general assembly, by accessories such as main lock, side chain, lock forks loaded in door leaf, and by defined technology requirement by doorframe and door
Fan fits together, and is packaged, and final products are formed.
Beneficial effects of the present invention are：(NH4)3C6H5O7It is a kind of good complexant, is connected on its phenyl ring multiple
Oxygen atom, oxygen atom are in electronegativity, and (NH is added in energy adsorbing metal cation in adhesive4)3C6H5O7, adhesive coated exists
Metal surface especially aluminum alloy door and window door frame surface when, (NH4)3C6H5O7In active oxygen ion can be with the table on doorframe door leaf
The aluminium ion in face combines, formed coordination community so that adhesive adhered on doorframe door leaf more securely,
(NH4)3C6H5O7Addition increase the adhesion strength of adhesive and metal.On the other hand, (NH4)3C6H5O7This is as phenyl ring chemical combination
Object has good dissolubility, the main component of adhesive or organically esters and ethers, inorganic ore in organic solvent
Ingredient and inorganic salts ingredient constitute the skeleton of adhesive, (NH4)3C6H5O7Then become organic ester ethers and inorganic constituents it
Between bridge, help inorganic ore and inorganic salts to be merged with organic ester ethers, to two under the action of initiator
Chemical action occurs between person, ultimately forms the mixture of emulsion state, there is very good adhesion.Toughener polysulfide rubber is complete
Vulcanize superfines butadiene-styrene rubber in contain polysulfide chain, be added in adhesive, toughener with organic ester ethers
Learn reaction so that toughener forms one with organic ester ethers, and the polysulfide chain on toughener can also be with (NH4)3C6H5O7On benzene
Base phase-polymerization so that all components are glued together, and the presence of the polysulfide functional group on toughener makes adhesive be easy to again
It is secondary that polymerisation occurs with organic compound, that is, the binding force between adhesive and organic plastics is increased, so that gained
Adhesive both had good binding force to metal, also have good binding force to plastics.
Specific implementation mode
Invention is described in further detail below by specific embodiment, following embodiment is descriptive, is not to limit
Protection scope of the present invention of property.
Embodiment 1
A kind of novel metal Plastics adhesives, including the group of following parts by weight are grouped as：
The antifoaming agent is diethylene glycol monomethyl ether.
The initiator is triethanolamine.
The toughener is polysulfide rubber.
A kind of preparation method of novel metal Plastics adhesives, includes the following steps：
Step 1: weighing each raw material according to components by weight percent；
Step 2: alleged dibutyl phthalate, tricresyl phosphate and the polyurethane formic acid esters obtained is sufficiently mixed,
It is charged with borax and quartz sand, is heated to 100 DEG C of high-speed stirred 30min, so that borax and quartz sand is fully dissolved and obtains clearly
Solution；
Step 3: the alleged boron oxide obtained and zinc oxide are added in propylene oxide phenyl ether, it is heated to 200 DEG C and quickly stirs
20min is mixed, turbid solution is obtained；
Step 4: the clear solution obtained by step 2 is poured into the turbid solution obtained by step 3, and sequentially add carbonic acid
Calcium, sodium bicarbonate, (NH4)3C6H5O7With antifoaming agent, initiator, stirring at normal temperature 1h obtains emulsion state mixture；
Step 5: toughener is added into the emulsion state mixture obtained by step 4, stirring at normal temperature 20min is up to gluing
Agent.
Embodiment 2
A kind of novel metal Plastics adhesives, including the group of following parts by weight are grouped as：
The antifoaming agent is the equal polyethers of PolyTHF.
The initiator is polyamide.
The toughener is fully cured ultrafine powdered styrene-butadiene rubber.
A kind of preparation method of novel metal Plastics adhesives, includes the following steps：
Step 1: weighing each raw material according to components by weight percent；
Step 2: alleged dibutyl phthalate, tricresyl phosphate and the polyurethane formic acid esters obtained is sufficiently mixed,
It is charged with borax and quartz sand, is heated to 150 DEG C of high-speed stirred 50min, so that borax and quartz sand is fully dissolved and obtains clearly
Solution；
Step 3: the alleged boron oxide obtained and zinc oxide are added in propylene oxide phenyl ether, it is heated to 300 DEG C and quickly stirs
40min is mixed, turbid solution is obtained；
Step 4: the clear solution obtained by step 2 is poured into the turbid solution obtained by step 3, and sequentially add carbonic acid
Calcium, sodium bicarbonate, (NH4)3C6H5O7With antifoaming agent, initiator, stirring at normal temperature 2h obtains emulsion state mixture；
Embodiment 3
A kind of novel metal Plastics adhesives, including the group of following parts by weight are grouped as：
The antifoaming agent is diethylene glycol monomethyl ether.
The initiator is potassium peroxydisulfate.
The toughener is polysulfide rubber.
A kind of preparation method of novel metal Plastics adhesives, includes the following steps：
Step 1: weighing each raw material according to components by weight percent；
Step 2: alleged dibutyl phthalate, tricresyl phosphate and the polyurethane formic acid esters obtained is sufficiently mixed,
It is charged with borax and quartz sand, is heated to 120 DEG C of high-speed stirred 40min, so that borax and quartz sand is fully dissolved and obtains clearly
Solution；
Step 3: the alleged boron oxide obtained and zinc oxide are added in propylene oxide phenyl ether, it is heated to 250 DEG C and quickly stirs
30min is mixed, turbid solution is obtained；
Step 4: the clear solution obtained by step 2 is poured into the turbid solution obtained by step 3, and sequentially add carbonic acid
Calcium, sodium bicarbonate, (NH4)3C6H5O7With antifoaming agent, initiator, stirring at normal temperature 1.2h obtains emulsion state mixture；
Step 5: toughener is added into the emulsion state mixture obtained by step 4, stirring at normal temperature 20min is up to gluing
Agent.
Embodiment 4
A kind of novel metal Plastics adhesives, including the group of following parts by weight are grouped as：
The antifoaming agent is the equal polyethers of PolyTHF.
The initiator is ammonium persulfate.
The toughener is fully cured ultrafine powdered styrene-butadiene rubber.
A kind of preparation method of novel metal Plastics adhesives, includes the following steps：
Step 1: weighing each raw material according to components by weight percent；
Step 2: alleged dibutyl phthalate, tricresyl phosphate and the polyurethane formic acid esters obtained is sufficiently mixed,
It is charged with borax and quartz sand, is heated to 130 DEG C of high-speed stirred 40min, so that borax and quartz sand is fully dissolved and obtains clearly
Solution；
Step 3: the alleged boron oxide obtained and zinc oxide are added in propylene oxide phenyl ether, it is heated to 280 DEG C and quickly stirs
30min is mixed, turbid solution is obtained；
Step 4: the clear solution obtained by step 2 is poured into the turbid solution obtained by step 3, and sequentially add carbonic acid
Calcium, sodium bicarbonate, (NH4)3C6H5O7With antifoaming agent, initiator, stirring at normal temperature 1.8h obtains emulsion state mixture；
Embodiment 5
A kind of novel metal Plastics adhesives, including the group of following parts by weight are grouped as：
The antifoaming agent is the equal polyethers of PolyTHF.
The initiator is ammonium persulfate.
The toughener is the mixture of triethanolamine, polyamide, potassium peroxydisulfate, ammonium persulfate.
A kind of preparation method of novel metal Plastics adhesives, includes the following steps：
Step 1: weighing each raw material according to components by weight percent；
Step 2: alleged dibutyl phthalate, tricresyl phosphate and the polyurethane formic acid esters obtained is sufficiently mixed,
It is charged with borax and quartz sand, is heated to 125 DEG C of high-speed stirred 30min, so that borax and quartz sand is fully dissolved and obtains clearly
Solution；
Step 3: the alleged boron oxide obtained and zinc oxide are added in propylene oxide phenyl ether, it is heated to 250 DEG C and quickly stirs
25min is mixed, turbid solution is obtained；
Step 4: the clear solution obtained by step 2 is poured into the turbid solution obtained by step 3, and sequentially add carbonic acid
Calcium, sodium bicarbonate, (NH4)3C6H5O7With antifoaming agent, initiator, stirring at normal temperature 1.5h obtains emulsion state mixture；
Comparative example 1
A kind of novel metal Plastics adhesives, including the group of following parts by weight are grouped as：
The antifoaming agent is the equal polyethers of PolyTHF.
The initiator is triethanolamine, polyamide, potassium peroxydisulfate.
The toughener is fully cured ultrafine powdered styrene-butadiene rubber.
A kind of preparation method of novel metal Plastics adhesives, includes the following steps：
Step 1: weighing each raw material according to components by weight percent；
Step 2: alleged dibutyl phthalate, tricresyl phosphate and the polyurethane formic acid esters obtained is sufficiently mixed,
It is charged with borax and quartz sand, is heated to 140 DEG C of high-speed stirred 25min, so that borax and quartz sand is fully dissolved and obtains clearly
Solution；
Step 3: the alleged boron oxide obtained and zinc oxide are added in propylene oxide phenyl ether, it is heated to 270 DEG C and quickly stirs
33min is mixed, turbid solution is obtained；
Step 4: the clear solution obtained by step 2 is poured into the turbid solution obtained by step 3, and sequentially add carbonic acid
Calcium, sodium bicarbonate, (NH4)3C6H5O7With antifoaming agent, initiator, stirring at normal temperature 1.7h obtains emulsion state mixture；
The adhesive of gained in embodiment 1 to 5 and comparative example 1 is respectively coated on door leaf, then all door leafs are sprayed
Plastic powders are coated, transfer, paint, general assembly obtain finished product door-plate.Door described here is antitheft door.Door is fanned by obtained six
CSR-1 types scratching instrument (day) is used to measure the binding force between plastics and door-plate respectively, obtaining binding force numerical value is respectively
650MPa, 700MPa, 680MPa, 710MPa, 660MPa, 320MPa, it is known that do not add (NH4)3C6H5O7Adhesive to gold
The adhesive attraction belonged between plastics is far from being added to (NH4)3C6H5O7It is good.
The above is only a preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-mentioned implementation
Example, all technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It should be pointed out that for the art
Those of ordinary skill for, several improvements and modifications without departing from the principles of the present invention, these improvements and modifications
It should be regarded as protection scope of the present invention.
Claims (8)
1. a kind of novel metal Plastics adhesives, which is characterized in that the group including following parts by weight is grouped as：
2. a kind of novel metal Plastics adhesives according to claim 1, which is characterized in that include the group of following parts by weight
It is grouped as：
3. a kind of novel metal Plastics adhesives according to claim 2, which is characterized in that include the group of following parts by weight
It is grouped as：
4. a kind of novel metal Plastics adhesives according to any one of claims 1 to 3, which is characterized in that the defoaming
Agent is diethylene glycol monomethyl ether or the equal polyethers of PolyTHF or two kinds of combination.
5. a kind of novel metal Plastics adhesives according to any one of claims 1 to 3, which is characterized in that the initiation
Agent is one or more in triethanolamine, polyamide, potassium peroxydisulfate, ammonium persulfate.
6. a kind of novel metal Plastics adhesives according to any one of claims 1 to 3, which is characterized in that the toughening
Agent is polysulfide rubber or fully cured ultrafine powdered styrene-butadiene rubber or two kinds of combination.
7. a kind of a kind of preparation method of novel metal Plastics adhesives as claimed any one in claims 1 to 3, feature
It is, includes the following steps：
Step 1: weighing each raw material according to components by weight percent；
Step 2: alleged dibutyl phthalate, tricresyl phosphate and the polyurethane formic acid esters obtained is sufficiently mixed, toward it
Middle addition borax and quartz sand are heated to 100~150 DEG C of 30~50min of high-speed stirred, borax and quartz sand are made fully to dissolve
To clear solution；
Step 3: the alleged boron oxide obtained and zinc oxide are added in propylene oxide phenyl ether, it is heated to 200~300 DEG C quickly
20~40min is stirred, turbid solution is obtained；
Step 4: the clear solution obtained by step 2 is poured into the turbid solution obtained by step 3, and sequentially add calcium carbonate, carbon
Sour hydrogen sodium, (NH4)3C6H5O7With antifoaming agent, initiator, 1~2h of stirring at normal temperature obtains emulsion state mixture；
Step 5: toughener is added into the emulsion state mixture obtained by step 4,20~40min of stirring at normal temperature is up to gluing
Agent.
8. a kind of with a kind of production of the door-plate of novel metal Plastics adhesives as claimed any one in claims 1 to 3
Technique, which is characterized in that include the following steps：
One, phosphatization removes the oil and rust of doorframe door leaf surface by chemistry and electrochemical reaction；
Two, it coats, the metallo-plastic adhesive is coated on the doorframe door leaf after phosphatization；
Three, plastic-spraying sprays upper required plastic powders on the doorframe door leaf after coated；
Four, it transfers, the grain pattern on transfer paper is transferred to doorframe door leaf surface by hot pressing；
Five, it paints, is applied together in doorframe door leaf surface or a few road varnish increase or improve coating surface glossiness.
Six, general assembly, by accessories such as main lock, side chain, lock forks loaded in door leaf, and by defined technology requirement by doorframe and door leaf group
It is fitted together, is packaged, form final products.
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| CN201710300657.3A CN108570303A (en) | 2017-05-02 | 2017-05-02 | A kind of novel metal Plastics adhesives and its preparation method and application |
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| CN201710300657.3A CN108570303A (en) | 2017-05-02 | 2017-05-02 | A kind of novel metal Plastics adhesives and its preparation method and application |
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Cited By (1)
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| CN112226138A (en) * | 2020-06-17 | 2021-01-15 | 谢丹 | Super-hybrid composite material roller and preparation method thereof |
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Application publication date: 20180925 |