CN104312385B - A kind of corrosion-proof epoxy powder liquid coating and preparation method thereof - Google Patents
A kind of corrosion-proof epoxy powder liquid coating and preparation method thereof Download PDFInfo
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- CN104312385B CN104312385B CN201410668813.8A CN201410668813A CN104312385B CN 104312385 B CN104312385 B CN 104312385B CN 201410668813 A CN201410668813 A CN 201410668813A CN 104312385 B CN104312385 B CN 104312385B
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Abstract
The present invention proposes a kind of corrosion-proof epoxy powder liquid coating.This corrosion-proof epoxy powder liquid coating is prepared by following raw materials according, following raw materials is by weight ratio: modified epoxy anti-corrosive powder paint 100 parts, amine cross-linking agent 0.3~1.0 parts, surface finishing agent methyl-silicone oil 1.0~4.0 parts, plasticiser 2.0~4.0 parts, ketones solvent 130~160 parts.This coating not only solves epoxy powder room temperature brushing problem of solidification, and improve adhesive force and the flexility of coating, coating is made to be provided with good antiseptic effect, there is again the highest shock resistance, case hardness and anti-wear performance, it is that a kind of anticorrosion process is easy, the preferable anticorrosive paint of favorable anti-corrosion effect.
Description
Technical field:
The present invention relates to a kind of steel tank body, special-shaped pipeline, boats and ships, technique radiator inside and outside
The anti-corrosion material of ambient spray solidification, belongs to a kind of corrosion-proof epoxy powder liquid coating and preparation thereof
Method.
Background technology:
Currently, at home in each oilfield construction, for steel tank body, special-shaped pipeline, boats and ships,
Technique radiator inside and outside antiseptical material is a lot, but coating can be as electrostatic spraying corrosion-proof epoxy
End coating antiseptic effect, again can ambient spray solidification anti-corrosion material little.Particularly to oil
Field oil storage, water storage tank body, the application aspect of boats and ships ectosome, be suitable for the high-quality of ambient spray solidification
The anticorrosive paint of amount is less.Owing to the antiseptic effect of generally acknowledged electrostatic spraying powder coating is fine,
But it is only used for steel pipeline anti-corrision, if for steel tank body, boats and ships, special-shaped pipeline, heating installation
The anticorrosions such as sheet, it is impossible to solve to add hot-melt problem.If wanting to be applied to steel tank body and different
The anticorrosion of type pipeline, boats and ships etc., is necessary for using a kind of novel process to make powdery paints energy room temperature
Solidification, had both met the requirement of aseptic technic, also can reduce production cost, solved preventing in application
Detritus amount.
Summary of the invention:
In order to solve the problem that technical background exists, the present invention proposes a kind of corrosion-proof epoxy powder liquid
Body coating and preparation method thereof.This coating not only solves epoxy powder room temperature brushing solidification and asks
Topic, and improve adhesive force and the flexility of coating, make coating be provided with good anticorrosion
Effect, has again the highest shock resistance, case hardness and anti-wear performance, is a kind of anticorrosion work
Skill is easy, the preferable anticorrosive paint of favorable anti-corrosion effect.
The technical scheme is that this corrosion-proof epoxy powder liquid coating is by following raw materials according system
, following raw materials by weight ratio: modified epoxy anti-corrosive powder paint 100 parts, amine
Cross-linking agent 0.3~1.0 parts, surface finishing agent methyl-silicone oil 1.0~4.0 parts, plasticiser 2.0~
4.0 parts, ketones solvent 130~160 parts.
In such scheme, amine cross-linking agent is ethylenediamine or hexamethylene diamine.Plasticiser is phthalic acid
Dibutyl ester or dioctyl phthalate.
The preparation method of the corrosion-proof epoxy powder liquid coating of such scheme comprises the following steps: head
First modified epoxy anti-corrosive powder paint is put in dissolving tank according to quantity, add ketones solvent, stir
Mix uniformly, soak and dissolve 10~20min, after being stirred for 5~10min, add amine crosslinking
Agent, surface finishing agent methyl-silicone oil, plasticiser mix and blend 10min, then high speed dispersion 20min,
Corrosion-proof epoxy powder liquid coating is obtained with the sieves of 100~140 mesh after filtering.
The bubble that in such scheme, surface finishing agent methyl-silicone oil is formed when can eliminate film forming;Modified
Epoxide powder coating is Patent No. 201010221871.8, entitled a kind of Wear-resistant, high-temperature resistant
The concrete application of the inside and outside anti-corrosive powder paint of steel pipe;Cross-linking agent ethylenediamine, hexamethylene diamine energy
Promote liquid coating normal temperature cure;Plasticiser dibutyl phthalate, phthalic acid two are pungent
Ester can make film plasticizing softening have flexibility.
There is advantages that this coating not only solves epoxy powder room temperature brushing
Problem of solidification, and improve adhesive force and the flexility of coating, make coating be provided with very well
Antiseptic effect, have again the highest shock resistance, case hardness and anti-wear performance, be a kind of
Anticorrosion process is easy, the preferable anticorrosive paint of favorable anti-corrosion effect.Corrosion-inhibiting coating after solidification has
With electrostatic spraying powder coating coating equivalent effect, superpower adhesive force, fine case hardness,
Resisting strong impact, bending resistance and weatherability.Solve steel tank body and special-shaped pipeline, boats and ships,
Employing electrostatic spraying corrosion-proof epoxy powder coating antiseptical cannot be heated in technique radiator etc. difficult
Topic.Using corrosion-proof epoxy powder liquid coating anticorrosion, its coating process is simple, film after solidification
With electrostatic spraying anticorrosive powder coating, antiseptic effect is the best, not only increases corrosion-inhibiting coating and makes
With the life-span, and normal temperature cure reduces production cost, has saved production capital.
Detailed description of the invention:
Below in conjunction with embodiment, the invention will be further described:
This corrosion-proof epoxy powder liquid coating is prepared by following raw materials according, and following raw materials is by weight
Proportioning: modified epoxy anti-corrosive powder paint 100 parts, amine cross-linking agent 0.3~1.0 parts, table
Face finishing agent methyl-silicone oil 1.0~4.0 parts, plasticiser 2.0~4.0 parts, ketones solvent 130~
160 parts.
The corrosion-proof epoxy powder liquid coating technological process of production is: first by modified epoxy antiseptin
End coating is put in dissolving tank according to quantity, adds ketones solvent, stirs, and soaks and dissolves
10~20min, add amine cross-linking agent, surface finishing agent methyl after being stirred for 5~10min
Silicone oil, plasticiser mix and blend 10min, then high speed dispersion 20min, by 100~140 purposes
Sieves obtains corrosion-proof epoxy powder liquid coating after filtering.Wherein amine cross-linking agent be ethylenediamine or
Hexamethylene diamine.Plasticiser is dibutyl phthalate or dioctyl phthalate.
Now preparing corrosion-proof epoxy powder liquid coating with different technical schemes, prepared epoxy is prevented
Rotten powder liquid coating is checked according to SY/T0315-2005 and Q/CNPC38-2002 standard sample
As follows:
Embodiment 1, first by modified epoxy anti-corrosive powder paint 100kg, ketones solvent 140kg
Put in dissolving tank, mix and blend 5min, soak and dissolve 20min, stir 10min, then
Add surface finishing agent methyl-silicone oil 2.0kg, dibutyl phthalate 2.0kg, ethylenediamine
0.6kg mix and blend 10min, high speed dispersion stirring 10min, is epoxy anticorrosion after filtering
Powder liquid coating finished product.Detection viscosity: 26s;Brushing print assay: hardening time:
Surface drying time (room temperature) 20min, does solid work the time (room temperature) 48h;Coating surface is smooth, color
Pool is uniformly, bubble-free is without shrinkage cavity;Adhesive force: 1 grade;Anti-10J impacts: free of pinholes;24h
Cathodic disbonding: 3.0mm;Anti-3 ° of bendings: flawless.Conform to quality requirements.
Embodiment 2, first by modified epoxy anti-corrosive powder paint 100kg, ketones solvent 150kg
Put in dissolving tank, mix and blend 5min, soak and dissolve 20min, stir 10min, then
Add surface finishing agent methyl-silicone oil 2kg, dibutyl phthalate 2kg, ethylenediamine 0.3kg
Mix and blend 10min, high speed dispersion stirring 10min, is W1-01 epoxy anticorrosion after filtering
Powder liquid coating.Detection viscosity: 31s;Painting brushing piece assay: hardening time: surface drying
Time (room temperature) 50min, does solid work the time (room temperature) 56h;Appearance of coat: surfacing,
Uniform color, bubble-free are without shrinkage cavity;Adhesive force: 1 grade;Anti-10J impacts: free of pinholes;24h
Cathodic disbonding: 5.0mm;Anti-3 ° of bendings: flawless.The soft quality that do not meets of coating surface is wanted
Ask.
Embodiment 3, first by modified epoxy anti-corrosive powder paint 100kg, ketones solvent 160
Put in dissolving tank, mix and blend 5min, soak and dissolve 20min, stir 10min, then
Add surface finishing agent methyl-silicone oil 4kg, dioctyl phthalate 4kg, hexamethylene diamine 1.0kg
Mix and blend 10min, high speed dispersion stirring 10min, be W1-01 epoxy after filtering and prevent
Rotten powder liquid coating.Detection viscosity: 21s;Brushing sample survey result: hardening time:
Surface drying time (room temperature) 14min, does solid work the time (room temperature) 46h;Appearance of coat: surface is put down
Whole, uniform color, bubble-free are without shrinkage cavity;Adhesive force: 1 grade;Anti-10J impacts: have crackle;
24h cathodic disbonding: 3.0mm;Anti-3 ° of bendings: have crackle.Do not meet prescription.
Ambient spray curing and anticorrosive, anticorrosion coats and can use spraying, roller coating, brushing, and one
As coat 2~3 times, 30min surface drying, 48h solidification after can obtain surfacing smooth 150~
The corrosion-inhibiting coating of 250 μ m-thick.
Claims (2)
1. a corrosion-proof epoxy powder liquid coating, is prepared by following raw materials according, following raw materials
By weight ratio: modified epoxy anti-corrosive powder paint 100 parts, amine cross-linking agent 0.3~1.0
Part, surface finishing agent methyl-silicone oil 1.0~4.0 parts, plasticiser 2.0~4.0 parts, ketone is molten
Agent 130~160 parts;Amine cross-linking agent is ethylenediamine or hexamethylene diamine;Plasticiser is phthalic acid
Dibutyl ester or dioctyl phthalate;Wherein modified epoxy anti-corrosive powder paint is by following component
Composition, each component by weight ratio: epoxy resin E-12 60~80 parts, WT800 is pure to be had
Machine silicones 10~20 parts, azanol base rubber resin 8~10 parts, phenols curing agent 18~24
Part, catalyst 2-methylimidazole 0.6~0.8 part, levelling agent acrylic polymer 10~
16 parts, defoamer 0.6~0.8 part, titanium dioxide 10~15 parts, carborundum 20~40 parts,
Wollastonite in powder 15~30 parts, sericite 2~4 parts, graphite 3~5 parts, pigment 3~5 parts,
Dibutyl phthalate 2~4 parts;Wherein azanol base rubber resin is purchased from Xi'an organic chemical industry
Factory, model is HDT.
2. the preparation method of the corrosion-proof epoxy powder liquid coating described in claim 1, including
The following step: first put into according to quantity in dissolving tank by modified epoxy anti-corrosive powder paint, adds
Ketones solvent, stirs, and soaks dissolving 10~20min, after being stirred for 5~10min again
Add amine cross-linking agent, surface finishing agent methyl-silicone oil, plasticiser mix and blend 10min, then
High speed dispersion 20min, obtains corrosion-proof epoxy powder liquid with the sieves of 100~140 mesh after filtering
Body coating.
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CN104312385A CN104312385A (en) | 2015-01-28 |
CN104312385B true CN104312385B (en) | 2016-09-28 |
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CN106634413A (en) * | 2016-11-15 | 2017-05-10 | 成都陵川特种工业有限责任公司 | Process for manufacturing anti-corrosion automobile silencer |
CN108006333B (en) * | 2017-11-29 | 2021-10-26 | 大连新光管道制造有限公司 | Long-distance conveying high-temperature water pipe network system, pipeline and pipe fitting |
CN109082195A (en) * | 2018-06-20 | 2018-12-25 | 孟鋆辉 | A kind of one-component bottom surface unification ships anticorrosion antifouling paint and preparation method |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101899253A (en) * | 2010-07-09 | 2010-12-01 | 孟鋆辉 | Wear-resistant and high temperature-resistant powder coating for preventing corrosion of inside and outside of steel pipeline |
CN102229778A (en) * | 2011-06-17 | 2011-11-02 | 山东大学 | Anticorrosion conductive coating for metal grounding network and application method thereof |
CN102702973A (en) * | 2012-06-01 | 2012-10-03 | 北京帅臻高新科技有限公司 | Anti-corrosive paint |
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US6576718B1 (en) * | 1999-10-05 | 2003-06-10 | General Electric Company | Powder coating of thermosetting resin(s) and poly(phenylene ethers(s)) |
US6998365B2 (en) * | 2003-09-29 | 2006-02-14 | Ppg Industries Ohio, Inc. | Catalysts for low-cure powder coatings and methods for using the same |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101899253A (en) * | 2010-07-09 | 2010-12-01 | 孟鋆辉 | Wear-resistant and high temperature-resistant powder coating for preventing corrosion of inside and outside of steel pipeline |
CN102229778A (en) * | 2011-06-17 | 2011-11-02 | 山东大学 | Anticorrosion conductive coating for metal grounding network and application method thereof |
CN102702973A (en) * | 2012-06-01 | 2012-10-03 | 北京帅臻高新科技有限公司 | Anti-corrosive paint |
Non-Patent Citations (1)
Title |
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一种新型环氧防腐粉末液体涂料;赵秋玲等;《现代经济信息》;20130715(第13期);第345页 * |
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