CN108565222A - A kind of variety lateral doping junction termination structures production method of SiC device - Google Patents

A kind of variety lateral doping junction termination structures production method of SiC device Download PDF

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Publication number
CN108565222A
CN108565222A CN201810618045.3A CN201810618045A CN108565222A CN 108565222 A CN108565222 A CN 108565222A CN 201810618045 A CN201810618045 A CN 201810618045A CN 108565222 A CN108565222 A CN 108565222A
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dielectric layer
production method
sic
termination structures
lateral doping
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蔺增金
孙茂友
周丽哲
朱继红
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Jiangsu Silicon Guide Integrated Technology Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/28Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection
    • H01L23/29Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection characterised by the material, e.g. carbon
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/26Bombardment with radiation
    • H01L21/263Bombardment with radiation with high-energy radiation
    • H01L21/265Bombardment with radiation with high-energy radiation producing ion implantation
    • H01L21/266Bombardment with radiation with high-energy radiation producing ion implantation using masks
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/34Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies not provided for in groups H01L21/0405, H01L21/0445, H01L21/06, H01L21/16 and H01L21/18 with or without impurities, e.g. doping materials
    • H01L21/42Bombardment with radiation
    • H01L21/423Bombardment with radiation with high-energy radiation
    • H01L21/425Bombardment with radiation with high-energy radiation producing ion implantation
    • H01L21/426Bombardment with radiation with high-energy radiation producing ion implantation using masks
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/28Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection
    • H01L23/29Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection characterised by the material, e.g. carbon
    • H01L23/298Semiconductor material, e.g. amorphous silicon

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  • Physics & Mathematics (AREA)
  • Power Engineering (AREA)
  • General Physics & Mathematics (AREA)
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  • Condensed Matter Physics & Semiconductors (AREA)
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Abstract

The invention discloses a kind of variety lateral doping junction termination structures production methods of SiC device in field of semiconductor devices, include the following steps:1)Clean SiC semiconductor device;2)In the SiC device surface deposition dielectric layer SiO2;3)Lithographic definition dielectric layer SiO2, opening is formed among photoresist, the mask as subsequent etching dielectric layer;4)Wet etching dielectric layer SiO2, using the isotropic etching characteristic of wet etching, formed from the ramp structure for being open and being gradually increased to thickness of two sides, the barrier layer as subsequent ion injection;5)Remove photoresist;6)P-type doping is formed by masking layer high temperature Al ion implantings, form the knot terminal expansion structure for the variety lateral doping that junction depth continuously decreases outward from device inside, this invention simplifies device preparation technologies, technology difficulty and process costs are reduced while effectively improving device electric breakdown strength, can be used in power electronic system.

Description

A kind of variety lateral doping junction termination structures production method of SiC device
Technical field
The present invention relates to a kind of semiconductor devices, more particularly to a kind of manufacturing method of semiconductor device.
Background technology
Power electronic technique is that electric energy is converted and controlled using the power electronic devices such as such as thyristor, GTO, IGBT An electronic technology, current energy development and utilize in play very important effect.Currently, traditional silicon substrate electric power The performance indicator level of electronic device is maintained essentially at 109-1010W Hz have approached silicon materials because parasitic diode restricts And the attainable limit.In order to break through the current device limit, it is typically chosen the semiconductor made of wide band gap material Device, such as silicon carbide(SiC)Or gallium nitride(GaN)Device.
Carbofrax material has excellent physically and electrically characteristic, with its wide energy gap, high thermal conductivity, big full With the particular advantages such as drift velocity and high critical breakdown electric field, becomes and make high-power, high frequency, high temperature resistant, radioresistance device Ideal semiconductor material.The breakdown voltage of silicon carbide power electronic device can reach ten times of silicon device, and conducting resistance is only For tens of points of silicon device one, switching speed is fast, and thermal conductivity is high, and electric energy transition loss is small, and cooling system is simple, finally makes whole The volume and weight of a system significantly reduces.Current semiconductor applications are had become with power electronic devices prepared by SiC material One of hot spot device and research frontier are the mostly important developing direction of power electronic technique, in military and civilian field It is with important application prospects.
In power electronic system, the characteristic of power electronic devices plays the realization and improvement of system performance most important Effect.Edge highfield caused by depending greatly on knot curvature due to the breakdown voltage of device, in order to slow The electric field for solving the knot edge of surface termination is concentrated, and the actual breakdown voltage of device is improved, and needs to carry out knot terminal knot to device The design of structure.Junction termination structures include mainly field plate(FP), field limiting ring(FLR), knot terminal extend(JTE)Deng.At planar junction end In the technology of end, field plate techniques are limited to the promotion of pressure resistance, cannot reach resistance to pressure request;Field limiting ring technology can reach resistance to pressure request, But its to interannular away from too sensitive, device design and processes difficulty is big;The breakdown efficiency highest of JTE, in SiC power electronics devices There is very extensive application in part structure.
In the preparation of SiC device junction termination structures, there are a figure of merit concentration, the figure of merit concentration and N in the areas p-type JTE-Drift The concentration for moving layer is related, and generally 1017cm-3The order of magnitude is labeled as P-Area.There are one very typical contradictions for tool in single area JTE Relationship:When JTE dosage is very high, a new electric field spike can be formed in the edges JTE so that device is hit herein It wears;When JTE dosage is too low, and the protection to main knot edge can be weakened so that device punctures here.This is solved to close contradiction The method of system is exactly the JTE structures using multi-region.The JTE of multi-region no longer has unified dosage, but close to agent at main knot Amount is high, to enhance its protection to main knot;Far from main knot end, dosage is low, to reduce spike electric field herein.Even if by more Area's junction terminal extension technology can reduce sensibility of the device electric breakdown strength to JTE concentration, but in device fabrication process, equally The Al ion implantings of various dose twice or more are needed to form multiple knot terminal elongated areas, which increases techniques Complexity, to increase cost of manufacture.
Accordingly, it is desirable to provide a kind of SiC device junction termination structures production method, while improving the breakdown voltage of device Simplification of flowsheet reduces technology difficulty and process costs.
Invention content
The object of the present invention is to provide a kind of variety lateral doping junction termination structures production methods of SiC device, utilize wet method The isotropic etching characteristic of etching forms and has acclive ion implanting masking layer, because the different barrier layer of thickness is to note The barrier effect for entering ion is different, the knot terminal expansion structure with variety lateral doping can be formed after ion implanting, using one Secondary Al ion implantings can form the P of variety lateral doping-Knot terminal expansion structure had both played property identical with multi-region JTE Energy effect in turn avoids the multiple Al ion implantings during multi-region JTE makes, simplifies device preparation technology, effectively improving device Technology difficulty and process costs are reduced while part breakdown voltage.
The object of the present invention is achieved like this:A kind of variety lateral doping junction termination structures production method of SiC device, packet Include following steps:
1)Clean SiC semiconductor device;
2)In the SiC device surface deposition dielectric layer SiO2
3)Lithographic definition dielectric layer SiO2, opening is formed among photoresist, the mask as subsequent etching dielectric layer;
4)Wet etching dielectric layer SiO2, using the isotropic etching characteristic of wet etching, formation is open from described to both sides The ramp structure that thickness gradually increases, the barrier layer as subsequent ion injection;
5)Remove photoresist;
6)P-type doping is formed by masking layer high temperature Al ion implantings, forms the cross that junction depth continuously decreases outward from device inside To the knot terminal expansion structure of varying doping.
As further limiting for the present invention, the P-The doping concentration of knot terminal expansion structure be less than or equal to 1.0 × 1018cm-3
As further limiting for the present invention, the P-The junction depth of knot terminal expansion structure uniformly drops outward from device inside It is low.
As further limiting for the present invention, the P-The junction depth of knot terminal expansion structure is from device inside outward by 0.5 μ M is gradually reduced to 0.
As further limiting for the present invention, the SiO2Ranging from 2 °~45 ° of medium inclination layer can be situated between by controlling Thickness, consistency and the wet etching time of matter layer control inclination angle.
As further limiting for the present invention, the wet etching is with the mixed of hydrofluoric acid solution or hydrofluoric acid and ammonium fluoride Conjunction liquid is main etching solution.
As further limiting for the present invention, the wet etching time is -30 minutes 1 minute.
As further limiting for the present invention, the Al ion implantings include:
The Al ion implantings of different-energy and dosage combination are carried out at a temperature of 300~500 DEG C, Implantation Energy is ranging from:10~ 700KeV, implantation dosage ranging from 1 × 1013~1 × 1015cm-2
In 1500 DEG C ~ 1700 DEG C temperature ranges, the ion-activated annealing of Al of 10~30min is carried out in ar gas environment, obtains P- Knot terminal expansion structure.
Compared with prior art, the beneficial effects of the present invention are:
The present invention utilizes the isotropic etching characteristic of wet etching, forms the ion implanting masking layer with certain slope, leads to It crosses masking layer and carries out ion implanting, because the different barrier layer of thickness is different to the barrier effect for injecting ion, to form cross To the knot terminal expansion structure of varying doping, in the present invention, it can be formed using an Al ion implanting and be mixed with laterally change Miscellaneous P-Knot terminal expansion structure had both played effect identical with multi-region JTE, in turn avoided multiple during multi-region JTE makes Al ion implantings, simplify device preparation technology, and technology difficulty and work are reduced while effectively improving device electric breakdown strength Skill cost.The present invention can be used in power electronic system.
Description of the drawings
Fig. 1 shows the SiC device diagrammatic cross-section with variety lateral doping knot terminal expansion structure.
Fig. 2 shows the structural schematic diagrams of SiC device.
Fig. 3 shows that device surface deposits SiO2Structural schematic diagram.
Fig. 4 shows SiO2Surface coats the schematic diagram after photoresist and photoetching.
Fig. 5 is shown using photoresist as etch mask, to dielectric layer SiO2Schematic diagram after progress wet etching.
Fig. 6 is the dielectric layer SiO that device surface residue has ramped shaped2Schematic diagram
Fig. 7 is shown with dielectric layer SiO2Ion implanting rear surface, which is carried out, for mask is formed by the extension of variety lateral doping P- knot terminals The diagrammatic cross-section of structure.
Fig. 8 is the production flow diagram of variety lateral doping knot terminal expansion structure in SiC devices in embodiment.
Specific implementation mode
In order to illustrate more clearly of the present invention, the present invention is done further with reference to preferred embodiments and drawings It is bright.Similar component is indicated with identical reference numeral in attached drawing.It will be appreciated by those skilled in the art that institute is specific below The content of description is illustrative and be not restrictive, and should not be limited the scope of the invention with this.
It is formed to doping parameters excessively sensitivity and using the Al ion implantings of multiple various dose for single area JTE structures The P of multi-region-Technology difficulty and process costs relatively high problem when the areas-JTE, the present invention are tied using the JTE of variety lateral doping Structure, and an available Al ion implanting can form the variety lateral doping P of junction depth gradual change-- JTE structures.
The purpose of the present invention is to provide a kind of variety lateral doping junction termination structures production methods of SiC semiconductor device.
In order to achieve the above objectives, the present invention uses following technical proposals:
As shown in figure 8, a kind of variety lateral doping junction termination structures production method of SiC device, includes the following steps:
Clean SiC semiconductor device;
In the SiC device surface deposition dielectric layer SiO2
Lithographic definition dielectric layer SiO2, opening is formed among photoresist, the mask as subsequent etching dielectric layer;
Wet etching dielectric layer SiO2, using the isotropic etching characteristic of wet etching, formed and be open from described to both sides thickness The ramp structure gradually increased is spent, the barrier layer as subsequent ion injection;
Remove photoresist;
P-type doping is formed by masking layer high temperature Al ion implantings, it is whole to form the knot that junction depth continuously decreases outward from device inside Hold expansion structure;
In the present invention, using the isotropic etching characteristic of wet etching, after wet etching, as ion implanting barrier layer SiO2Certain gradient can be obtained, to form the sloping ion implanting barrier layer of tool.When carrying out Al ion implantings, due to oblique Different-thickness position is different to the blocking capability of Al ions in the dielectric layer of slope, so that SiC device surface is made to be mixed The different p type island region domain of miscellaneous dosage, that is, form the knot terminal extended area of variety lateral doping structure.
Preferably, the P-The doping concentration of knot terminal expansion structure is less than or equal to 1.0 × 1018cm-3
Preferably, the P-The junction depth of knot terminal expansion structure uniformly reduces outward from device inside.
Preferably, the P-The junction depth of knot terminal expansion structure is gradually reduced to 0 by 0.5 μm outward from device inside.
Preferably, the SiO2Ranging from 2 °~45 ° of medium inclination layer, can be by controlling the thickness of dielectric layer, densification Degree and wet etching time control inclination angle.
Preferably, the wet etching is molten mainly to etch with the mixed liquor of hydrofluoric acid solution or hydrofluoric acid and ammonium fluoride Liquid.
Preferably, the wet etching time is -30 minutes 1 minute.
Preferably, described inject includes:
The Al ion implantings of different-energy and dosage combination are carried out at a temperature of 300~500 DEG C, Implantation Energy is ranging from:10~ 700KeV, implantation dosage ranging from 1 × 1013~1 × 1015cm-2
In 1500 DEG C ~ 1700 DEG C temperature ranges, the ion-activated annealing of Al of 10~30min is carried out in ar gas environment, obtains P- Knot terminal expansion structure.
Embodiment 1
As illustrated in figs. 2-7, the variety lateral doping knot terminal expansion structure production method of a kind of SiC device, is as follows:
Step 1:In 1 surface PECVD dielectric layer depositeds 2 of SiC device, dielectric layer 2 is by SiO2Material is constituted;The thickness of dielectric layer 2 For 100nm~2 μm;
Step 2:In SiO22 surface of dielectric layer coats a layer photoresist 3, and is carried out at photoetching, development and carbonization using mask Reason;Photoresist after exposure carries out barrier layer of the high temperature cabonization as wet etching dielectric layer;
Step 3:Using the photoresist having been cured, i.e. barrier layer, wet etching is carried out to dielectric layer 2;The wet etching With the mixed liquor of hydrofluoric acid solution or hydrofluoric acid and ammonium fluoride for main etching solution, the time of the wet etching is 1 point Clock -30 minutes, due to the isotropic etching characteristic of wet etching, after wet etching, dielectric layer can obtain certain gradient, from And slope dielectric layer is formed, the barrier layer as follow-up Al ion implantings;
Step 4:High temperature Al ion implantings form p-type doping, carried out at a temperature of 400 DEG C the Al of different-energy and dosage combination from Son injection, Implantation Energy are respectively:500KeV、280KeV、30KeV;Implantation dosage is respectively 7.8 × 1014cm-2、5.2× 1014cm-2、8.6×1013cm-2, due to the difference of barrier layer thickness, the blocking degree to injecting Al ions will be different, therefore The second conductivity type regions of the variety lateral doping structure of junction depth gradual change can be formed in this region;
It should be noted that Al ion implantings are not limited to the injection form in the present invention, different zones in the present invention can be met and adulterated Concentration, such as:At a temperature of 400 DEG C, the energy of Al ion implantings is 30kev to 550kev;The energy packet of the injection Include 30keV, 70keV, 100keV, 136keV, 150keV, 215keV, 307keV, 412keV and 550keV;The energy corresponds to Implantation dosage be respectively 2 × 1014cm-2、2.6×1014cm-2、3.5×1014cm-2、6.5×1014cm-2、5.2×1013cm-2、 7.7×1013cm-2、9×1013cm-2、1.02×1014cm-2With 1.67 × 1014cm-2
Step 5:Remove photomask surface glue, in 1500 DEG C to 1700 DEG C temperature ranges, in inert gas such as argon atmospher In enclosing, the activation annealing after Al ion implantings is carried out, the P of doping concentration gradual change is obtained-Knot terminal expansion area.
Step 6:Front back metal is made, the preparation of device is completed, obtains product as shown in Figure 1.
The invention is not limited in above-described embodiments, on the basis of technical solution disclosed by the invention, the skill of this field For art personnel according to disclosed technology contents, one can be made to some of which technical characteristic by not needing performing creative labour A little to replace and deform, these are replaced and deformation is within the scope of the invention.

Claims (8)

1. a kind of variety lateral doping junction termination structures production method of SiC device, which is characterized in that include the following steps:
1)Clean SiC semiconductor device;
2)In the SiC device surface deposition dielectric layer SiO2
3)Lithographic definition dielectric layer SiO2, opening is formed among photoresist, the mask as subsequent etching dielectric layer;
4)Wet etching dielectric layer SiO2, using the isotropic etching characteristic of wet etching, formed and be open from described to both sides thickness The ramp structure gradually increased is spent, the barrier layer as subsequent ion injection;
5)Remove photoresist;
6)P-type doping is formed by masking layer high temperature Al ion implantings, forms the cross that junction depth continuously decreases outward from device inside To the knot terminal expansion structure of varying doping.
2. a kind of variety lateral doping junction termination structures production method of SiC device according to claim 1, feature exist In the P-The doping concentration of knot terminal expansion structure is less than or equal to 1.0 × 1018cm-3
3. a kind of variety lateral doping junction termination structures production method of SiC device according to claim 1, feature exist In the P-The junction depth of knot terminal expansion structure uniformly reduces outward from device inside.
4. a kind of variety lateral doping junction termination structures production method of SiC device according to claim 1, feature exist In the P-The junction depth of knot terminal expansion structure is gradually reduced to 0 by 0.5 μm outward from device inside.
5. a kind of variety lateral doping junction termination structures production method of SiC device according to claim 1, feature exist In the SiO2Ranging from 2 °~45 ° of medium inclination layer can be carved by controlling thickness, consistency and the wet method of dielectric layer The erosion time controls inclination angle.
6. a kind of variety lateral doping junction termination structures production method of SiC device according to claim 1, feature exist In the wet etching is with the mixed liquor of hydrofluoric acid solution or hydrofluoric acid and ammonium fluoride for main etching solution.
7. a kind of variety lateral doping junction termination structures production method of SiC device according to claim 1, feature exist In the wet etching time is -30 minutes 1 minute.
8. a kind of variety lateral doping junction termination structures production method of SiC device according to claim 1, feature exist In the Al ion implantings include:
The Al ion implantings of different-energy and dosage combination are carried out at a temperature of 300~500 DEG C, Implantation Energy is ranging from:10~ 700KeV, implantation dosage ranging from 1 × 1013~1 × 1015cm-2
In 1500 DEG C ~ 1700 DEG C temperature ranges, the ion-activated annealing of Al of 10~30min is carried out in ar gas environment, obtains P-Knot Termination extension structure.
CN201810618045.3A 2018-06-15 2018-06-15 A kind of variety lateral doping junction termination structures production method of SiC device Pending CN108565222A (en)

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Cited By (5)

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Publication number Priority date Publication date Assignee Title
CN112310188A (en) * 2019-07-23 2021-02-02 珠海格力电器股份有限公司 Lateral variable doping terminal structure and manufacturing method thereof
CN112447820A (en) * 2019-08-28 2021-03-05 飞锃半导体(上海)有限公司 Chip terminal structure with gradually-changed junction depth and manufacturing method thereof
CN113223941A (en) * 2021-04-28 2021-08-06 杰华特微电子股份有限公司 Manufacturing method of transverse variable doping structure and transverse power semiconductor device
CN114300530A (en) * 2022-03-09 2022-04-08 芯众享(成都)微电子有限公司 Junction terminal structure of silicon carbide power device and preparation method thereof
CN114823857A (en) * 2022-04-27 2022-07-29 中国工程物理研究院电子工程研究所 Silicon carbide device junction-like lateral variable doped junction terminal structure and preparation method thereof

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CN106992117A (en) * 2017-03-30 2017-07-28 北京燕东微电子有限公司 A kind of preparation method of SiC junction barrel Schottky diode
CN107591324A (en) * 2017-08-24 2018-01-16 西安电子科技大学 The preparation method and structure of knot terminal terminal extension structure

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US20060076612A1 (en) * 2004-09-30 2006-04-13 Seiji Otake Semiconductor device and manufacturing method of the same
CN102931218A (en) * 2012-09-29 2013-02-13 西安龙腾新能源科技发展有限公司 Junction terminal structure for super junction device
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CN106992117A (en) * 2017-03-30 2017-07-28 北京燕东微电子有限公司 A kind of preparation method of SiC junction barrel Schottky diode
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112310188A (en) * 2019-07-23 2021-02-02 珠海格力电器股份有限公司 Lateral variable doping terminal structure and manufacturing method thereof
CN112447820A (en) * 2019-08-28 2021-03-05 飞锃半导体(上海)有限公司 Chip terminal structure with gradually-changed junction depth and manufacturing method thereof
CN113223941A (en) * 2021-04-28 2021-08-06 杰华特微电子股份有限公司 Manufacturing method of transverse variable doping structure and transverse power semiconductor device
CN113223941B (en) * 2021-04-28 2024-05-24 杰华特微电子股份有限公司 Manufacturing method of transverse variable doping structure and transverse power semiconductor device
CN114300530A (en) * 2022-03-09 2022-04-08 芯众享(成都)微电子有限公司 Junction terminal structure of silicon carbide power device and preparation method thereof
CN114823857A (en) * 2022-04-27 2022-07-29 中国工程物理研究院电子工程研究所 Silicon carbide device junction-like lateral variable doped junction terminal structure and preparation method thereof

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Application publication date: 20180921