CN108559647A - 一种镀af膜玻璃清洗剂及其制备方法与应用 - Google Patents
一种镀af膜玻璃清洗剂及其制备方法与应用 Download PDFInfo
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- CN108559647A CN108559647A CN201810576648.1A CN201810576648A CN108559647A CN 108559647 A CN108559647 A CN 108559647A CN 201810576648 A CN201810576648 A CN 201810576648A CN 108559647 A CN108559647 A CN 108559647A
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- Prior art keywords
- cleaning
- parts
- sodium
- cleaning agent
- agent
- Prior art date
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Links
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 40
- 239000011521 glass Substances 0.000 title claims abstract description 27
- 238000007747 plating Methods 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 238000004140 cleaning Methods 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- -1 builder Substances 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 15
- 239000007921 spray Substances 0.000 claims abstract description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract description 10
- 239000012224 working solution Substances 0.000 claims abstract description 10
- 239000000872 buffer Substances 0.000 claims abstract description 9
- 239000008139 complexing agent Substances 0.000 claims abstract description 9
- 239000006184 cosolvent Substances 0.000 claims abstract description 9
- 239000000126 substance Substances 0.000 claims description 15
- 239000011734 sodium Substances 0.000 claims description 12
- 229910052708 sodium Inorganic materials 0.000 claims description 12
- 229920000570 polyether Polymers 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 229920000141 poly(maleic anhydride) Polymers 0.000 claims description 7
- 229920002401 polyacrylamide Polymers 0.000 claims description 7
- 230000007062 hydrolysis Effects 0.000 claims description 6
- 238000006460 hydrolysis reaction Methods 0.000 claims description 6
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 claims description 5
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- ABBQHOQBGMUPJH-UHFFFAOYSA-M Sodium salicylate Chemical compound [Na+].OC1=CC=CC=C1C([O-])=O ABBQHOQBGMUPJH-UHFFFAOYSA-M 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 229930182470 glycoside Natural products 0.000 claims description 5
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 5
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical group [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 5
- 235000010234 sodium benzoate Nutrition 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical group NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 4
- 150000001412 amines Chemical group 0.000 claims description 4
- ALSTYHKOOCGGFT-UHFFFAOYSA-N cis-oleyl alcohol Natural products CCCCCCCCC=CCCCCCCCCO ALSTYHKOOCGGFT-UHFFFAOYSA-N 0.000 claims description 4
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 4
- 239000001488 sodium phosphate Substances 0.000 claims description 4
- 229960004025 sodium salicylate Drugs 0.000 claims description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 229940043237 diethanolamine Drugs 0.000 claims description 3
- 150000004683 dihydrates Chemical class 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000004299 sodium benzoate Substances 0.000 claims description 3
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 3
- 229940059939 kayexalate Drugs 0.000 claims description 2
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 claims description 2
- 229920001467 poly(styrenesulfonates) Polymers 0.000 claims description 2
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 claims 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims 1
- 239000004280 Sodium formate Substances 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- UKJLNMAFNRKWGR-UHFFFAOYSA-N cyclohexatrienamine Chemical group NC1=CC=C=C[CH]1 UKJLNMAFNRKWGR-UHFFFAOYSA-N 0.000 claims 1
- 239000001632 sodium acetate Substances 0.000 claims 1
- 235000017281 sodium acetate Nutrition 0.000 claims 1
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 claims 1
- 235000019254 sodium formate Nutrition 0.000 claims 1
- 229910000162 sodium phosphate Inorganic materials 0.000 claims 1
- POECFFCNUXZPJT-UHFFFAOYSA-M sodium;carbonic acid;hydrogen carbonate Chemical group [Na+].OC(O)=O.OC([O-])=O POECFFCNUXZPJT-UHFFFAOYSA-M 0.000 claims 1
- AURFVNDXGLQSNN-UHFFFAOYSA-K trisodium 2-hydroxypropane-1,2,3-tricarboxylic acid phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O.OC(=O)CC(O)(C(O)=O)CC(O)=O AURFVNDXGLQSNN-UHFFFAOYSA-K 0.000 claims 1
- 239000003643 water by type Substances 0.000 claims 1
- 239000006260 foam Substances 0.000 abstract description 8
- 238000009776 industrial production Methods 0.000 abstract description 4
- 230000002000 scavenging effect Effects 0.000 abstract description 4
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 10
- 230000003115 biocidal effect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- ONLJZPFXSHXZTC-UHFFFAOYSA-M azanium sodium acetic acid diacetate Chemical compound C(C)(=O)[O-].C(C)(=O)O.C(C)(=O)[O-].[NH4+].[Na+] ONLJZPFXSHXZTC-UHFFFAOYSA-M 0.000 description 3
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 235000011008 sodium phosphates Nutrition 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 240000003273 Passiflora laurifolia Species 0.000 description 1
- 235000013762 Passiflora laurifolia Nutrition 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical class [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 229960004050 aminobenzoic acid Drugs 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- HDFXRQJQZBPDLF-UHFFFAOYSA-L disodium hydrogen carbonate Chemical group [Na+].[Na+].OC([O-])=O.OC([O-])=O HDFXRQJQZBPDLF-UHFFFAOYSA-L 0.000 description 1
- CEYULKASIQJZGP-UHFFFAOYSA-L disodium;2-(carboxymethyl)-2-hydroxybutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)CC(O)(C(=O)O)CC([O-])=O CEYULKASIQJZGP-UHFFFAOYSA-L 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000010702 perfluoropolyether Substances 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229960003885 sodium benzoate Drugs 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- MNCGMVDMOKPCSQ-UHFFFAOYSA-M sodium;2-phenylethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=CC1=CC=CC=C1 MNCGMVDMOKPCSQ-UHFFFAOYSA-M 0.000 description 1
- BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- LEAHFJQFYSDGGP-UHFFFAOYSA-K trisodium;dihydrogen phosphate;hydrogen phosphate Chemical compound [Na+].[Na+].[Na+].OP(O)([O-])=O.OP([O-])([O-])=O LEAHFJQFYSDGGP-UHFFFAOYSA-K 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- B08B1/20—
-
- B08B1/32—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/02—Cleaning by the force of jets or sprays
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/364—Organic compounds containing phosphorus containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/378—(Co)polymerised monomers containing sulfur, e.g. sulfonate
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
Abstract
本发明属于工业清洗领域，具体公开了一种镀膜玻璃清洗剂及其制备方法与应用；尤其是在镀AF膜玻璃上的清洗应用。该清洗剂包括络合剂、助洗剂、助溶剂、缓冲剂、表面活性剂以及水配制，应用时采用喷淋滚刷的方式进行清洗，工作液的浓度为5～10％，温度为40～50℃，清洗时间为30～60s。本发明对镀AF膜玻璃具有优良的清洗效果而不伤AF膜，喷淋时泡沫很少且消泡迅速，清洗过程中无异味产生，避免了对操作人员的危害，大大提高了工业生产效率。
Description
技术领域
本发明属于工业清洗领域，具体涉及一种镀AF膜玻璃清洗剂及其制备方法与应用。
背景技术
AF(anti finger)膜也称作防指纹膜，是一种含氟材料，一般称作全氟聚醚，其表面张力极低，具有疏水、疏油特性。AF膜可让触摸屏不易沾染指纹油污等，保持手机屏幕的顺滑与干净。因此，玻璃表面镀AF膜技术在触摸屏制造领域被广泛使用。
工业生产中，玻璃镀AF膜后，在进行下一个加工工序前，需要先洗净表面的脏污和富余的AF油，清洗方法一般是将清洗剂用水稀释后进行喷淋滚刷清洗。而现在的清洗工艺存在以下问题：1)为了防止喷淋过程中泡沫太多，清洗剂中均加有消泡剂，但消泡剂会在使用过程中消泡效果越来越差，直至基本没有消泡效果；2)为了达到较好的清洗效果，清洗剂的PH值一般较高，返洗时会损伤AF膜；3)清洗剂中一般含有溶剂，喷淋过程中的气味很大，危害操作人员健康。
发明内容
为了解决上述问题，本发明的目的之一在于提供一种快速高效清洗镀AF膜玻璃的清洗剂。
本发明的目的之二是提供了所述清洗剂的制备方法，该方法简单易控，易于产业化。
本发明的目的之三是提供了所述清洗剂的应用和具体应用方法，尤其是应用在清洗镀AF膜玻璃技术领域中，快速洗净玻璃工件上富余的AF油及其它脏污。
本发明是通过以下技术方案来实现的：
一种镀AF膜玻璃清洗剂，其特征在于：包括如下重量份的组分；5～11份络合剂、7～12份助洗剂、6～10份助溶剂、2～4份缓冲剂、6～10份表面活性剂以及60～67份去离子水。
进一步地，所述络合剂为二乙烯三胺五羧酸钠、氨三乙酸钠、乙二胺四甲叉磷酸钠、六偏磷酸纳、二乙醇胺中至少两种的组合物。
进一步地，所述助洗剂为聚丙烯酰胺、聚丙烯酸钠、水解聚马来酸酐、聚苯乙烯磺酸钠中至少两种的组合物。聚丙烯酰胺能有效地降低流体的摩擦阻力，能使悬浮物质通过电中和，架桥吸附作用而絮凝；聚丙烯酸钠具有良好的增稠，分散效果；水解聚马来酸酐能有效的剥离污垢并阻垢；聚苯乙烯磺酸钠具有优良的絮凝、分散及反应性乳化效果。
进一步地，所述助溶剂为苯甲酸钠，水杨酸钠，对氨基苯甲酸钠中一种或几种的组合物。苯甲酸钠，水杨酸钠，对氨基苯甲酸均可提高本发明中表面活性剂在水中的溶解度，可有效的提高所述清洗剂的浊点。
进一步地，所述缓冲剂为碳酸钠—碳酸氢钠、磷酸二氢钠—磷酸氢二钠、磷酸氢二钠-二水柠檬酸钠中的一种。
进一步地，所述表面活性剂为氧化胺、聚醚L-61、聚醚L-64、烷基糖苷FC-06、油醇聚氧乙烯(5)醚中至少两种的组合物。所述表面活性剂均为具有良好清洗效果的低泡型表面活性剂，尤其是在40℃以上时，其水溶液泡沫很少。
所述清洗剂的配制方法，先将按清洗剂计量五分之四的水加入到容器中，接着依次加入所述络合剂、助洗剂、助溶剂、缓冲剂、表面活性剂，前一种物质溶解后再加入后一种物质，待完全溶解后用水补充至计量值，完成制备，制得所述清洗剂。先加络合剂可以软化水，防止水中的金属离子对所加的药剂产生影响，之后加入的助洗剂也可起到辅助络合的作用，加入助溶剂以确保后面加入的药剂也能溶解完全，然后加入缓冲剂后再加入表面活性剂，因为液体药剂放在固体药剂之后加入可节省药剂的溶解时间。
本发明中的清洗剂可以用于清洗其它任何需要进行清洗的镀膜玻璃，当然，用于清洗镀AF膜玻璃效果最好。
所述清洗剂用于清洗镀AF膜玻璃的方法为，先用水将清洗剂配制成工作液并倒入喷淋槽中，将工件放在产线上，开启喷淋并同时进行滚刷清洗，清洗后依次进行两槽市水漂洗和一槽去离子水漂洗，完成清洗。
本发明用的市水即自来水，工业生产时，需要工件放在水槽里漂洗。
进一步地，所述工作液的浓度范围为5～10％。
进一步地，所述工作液的温度为40～50℃。
进一步地，清洗时间为30～60s。
进一步地，每一槽漂洗时间为30～60s。
本发明采用络合剂、助洗剂、助溶剂、缓冲剂、表面活性剂以及水配制，优选工作液浓度范围为5～10％，温度范围为40～50℃，清洗时间30～60s，清洗干净而不会损伤AF膜，喷淋时泡沫很少且消泡迅速，清洗过程中无异味产生，避免了对操作人员的危害，大大提高了工业生产效率。本发明所提供的一种稳定的、性能优良的镀AF膜玻璃清洗技术，包括镀AF膜玻璃清洗剂的配制及在清洗剂中清洗镀AF膜玻璃的方法，有着广泛的应用前景。
具体的实施方式
下面结合具体实施方式对本发明作进一步的详细说明，以助于本领域技术人员理解本发明。
实施例1
一种用于清洗抗菌玻璃的清洗剂，由以下方法制得：首先将52份水加入到容器中，然后依次加入3份二乙烯三胺五羧酸钠，4份氨三乙酸钠，5份聚丙烯酰胺，4份水解聚马来酸酐，8份苯甲酸钠，1.2份碳酸钠，1份碳酸氢钠，3份氧化胺，3份聚醚L-61，2份烷基糖苷FC-06；前一种物质溶解后再加入后一种物质，待完全溶解后再加入13.8份水，完成制备。
实施例2
一种用于清洗抗菌玻璃的清洗剂，由以下方法制得：首先将48份水加入到容器中，然后依次加入3份乙二胺四甲叉磷酸钠，2份六偏磷酸纳，3份聚丙烯酰胺，4份聚苯乙烯磺酸钠，5份水解聚马来酸酐，5份水杨酸钠，5份对氨基苯甲酸钠，1份磷酸氢二钠，2份二水柠檬酸钠，6份聚醚L-61，4份油醇聚氧乙烯(5)醚；前一种物质溶解后再加入后一种物质，待完全溶解后再加入12份水，完成制备。
实施例3
一种用于清洗抗菌玻璃的清洗剂，由以下方法制得：首先将52份水加入到容器中，然后依次加入4份乙二胺四甲叉磷酸钠，4份二乙醇胺，3份聚丙烯酸钠，4份聚丙烯酰胺，5份水杨酸钠，4份苯甲酸钠，0.7份磷酸氢二钠，1.3份二水柠檬酸钠，3份氧化胺，3份聚醚L-64，3份油醇聚氧乙烯(5)醚；前一种物质溶解后再加入后一种物质，待完全溶解后再加入13份水，完成制备。
实施例4
一种用于清洗抗菌玻璃的清洗剂，由以下方法制得：首先将54份水加入到容器中，然后依次加入6份氨三乙酸钠，5份六偏磷酸纳，2份水解聚马来酸酐，3份聚丙烯酸钠，3份聚苯乙烯磺酸钠，6份对氨基苯甲酸钠，0.7份磷酸二氢钠，1.3份磷酸氢二钠，2份聚醚L-64，2份烷基糖苷FC-06，2份油醇聚氧乙烯(5)醚；前一种物质溶解后再加入后一种物质，待完全溶解后再加入13份水，完成制备。
实施例5
一种用于清洗抗菌玻璃的清洗剂，由以下方法制得：首先将52份水加入到容器中，然后依次加入3份二乙烯三胺五羧酸钠，3份乙二胺四甲叉磷酸钠，3份聚丙烯酰胺，4份聚苯乙烯磺酸钠，4份水解聚马来酸酐，7份对氨基苯甲酸钠，2.3份碳酸钠，1.7份碳酸氢钠，3份聚醚L-61，4份烷基糖苷FC-06；前一种物质溶解后再加入后一种物质，待完全溶解后再加入13份水，完成制备。
以下为本发明的各实施例的实验效果。
1.不同实施例的泡沫高度
试验方法：分别用去离子水将实施例配制成5％和10％的工作液，加热到40℃，在具塞量筒中倒入30ml，盖好筒塞后上下振动1min，振幅约30cm，然后放置在桌面观察泡沫高度。
不同实施例的泡沫高度如表1所示：
表1
由表1可知，本发明实施例的泡沫很少，且消泡迅速。
2.不同实施例对镀AF膜玻璃的清洗效果
试验方法：用去离子水将清洗剂配制成5％工作液并倒入喷淋槽中，将工件放在产线上，开启喷淋并同时进行滚刷清洗，清洗后依次进行两槽市水漂洗和一槽去离子水漂洗。
表2
由表2可知，本发明实施例对镀AF膜玻璃具有优良的清洗效果。
3.不同实施例对AF膜的腐蚀情况
试验方法：延长清洗时间并多次返洗，以测试实施例是否腐蚀AF膜。
表3
由表3可知，本发明实施例对AF膜没有腐蚀的风险。
Claims (10)
1.一种镀AF膜玻璃清洗剂，其特征在于：包括如下重量份的组分；5～11份络合剂、7～12份助洗剂、6～10份助溶剂、2～4份缓冲剂、6～10份表面活性剂以及60～67份去离子水。
2.如权利要求1所述的清洗剂，其特征在于：所述络合剂为二乙烯三胺五羧酸钠、氨三乙酸钠、乙二胺四甲叉磷酸钠、六偏磷酸纳、二乙醇胺中至少两种的组合物。
3.如权利要求1所述清洗剂，其特征在于：所述助洗剂为聚丙烯酰胺、聚丙烯酸钠、水解聚马来酸酐、聚苯乙烯磺酸钠中至少两种的组合物。
4.如权利要求1所述清洗剂，其特征在于：所述助溶剂为苯甲酸钠、水杨酸钠、对氨基苯甲酸钠中一种或几种的组合物。
5.如权利要求1所述清洗剂，其特征在于：所述缓冲剂为碳酸钠-碳酸氢钠、磷酸二氢钠-磷酸氢二钠、磷酸氢二钠-二水柠檬酸钠中的一种。
6.如权利要求1所述清洗剂，其特征在于：所述表面活性剂为氧化胺、聚醚L-61、聚醚L-64、烷基糖苷FC-06、油醇聚氧乙烯(5)醚中至少两种的组合物。
7.如权利要求1-6中任一项所述的清洗剂的制备方法，其特征在于：先将按清洗剂计量五分之四的水加入到容器中，接着依次加入所述络合剂、助洗剂、助溶剂、缓冲剂、表面活性剂，前一种物质溶解后再加入后一种物质，待完全溶解后用水补充至计量值，完成制备，制得所述清洗剂。
8.权利要求1-6中任意一项所述的清洗剂在清洗镀AF膜玻璃上的应用，所述应用方法为：先用水将清洗剂配制成工作液并倒入喷淋槽中，将工件放在产线上，开启喷淋并同时进行滚刷清洗，清洗后依次进行两槽市水漂洗和一槽去离子水漂洗，完成清洗。
9.如权利要求8所述的应用，其特征在于：所述工作液的浓度范围为5～10％。
10.如权利要求9所述清洗剂的应用，其特征在于：所述工作液的温度为40～50℃，清洗时间为30～60min，每一槽漂洗时间为30～60s。
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| CN114075120B (zh) * | 2021-10-27 | 2024-01-23 | 深圳飞世尔新材料股份有限公司 | 一种pH稳定剂、其制备方法和钼铝钼镀膜玻璃用清洗剂及其制备方法 |
| CN114085717A (zh) * | 2021-11-24 | 2022-02-25 | 福州硕榕光电有限公司 | 一种镀膜玻璃清洗剂及其制备方法与应用 |
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