CN108546455A - A kind of coloured oiled crayon and preparation method thereof - Google Patents
A kind of coloured oiled crayon and preparation method thereof Download PDFInfo
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- CN108546455A CN108546455A CN201810833219.8A CN201810833219A CN108546455A CN 108546455 A CN108546455 A CN 108546455A CN 201810833219 A CN201810833219 A CN 201810833219A CN 108546455 A CN108546455 A CN 108546455A
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- Prior art keywords
- parts
- aliphatic acid
- honey
- polyalcohol
- powder
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D13/00—Pencil-leads; Crayon compositions; Chalk compositions
Abstract
The invention belongs to colored appliance technology of painting, a kind of coloured oiled crayon and preparation method thereof is specifically disclosed, including polyvinyl butyral, polyalcohol, aliphatic acid, pigment powder, glass powder, carbon fiber, silica flour, the components such as honey;When making coloured oiled crayon, using honey as adhesive, the potential hazard that the use of chemical adhesive is brought is avoided;In addition, wax ester is made with vegetable fatty acid and polyol reaction so that gained wax crayon has preferable flexibility and elasticity, it is not easy to damage.
Description
Technical field
The invention belongs to colored appliance technologies of painting, and in particular to a kind of coloured oiled crayon and preparation method thereof.
Background technology
Wax crayon is that pigment is mixed the manufactured pen in wax, can have tens of kinds of colors, drawing to use.Wax crayon does not have permeability, is
It is fixed on picture by adhesive force, is not suitable for using excessively smooth paper, plate, cannot also be acquired by the superposition repeatedly of color compound
Color.It is the ideal tools that children for learning color is drawn, some artists are painted from life with it and color record.
Wax crayon usually there will be easily broken frangible disadvantage, and tinting strength, tinting power is poor, and after a long time placement, color is easy for the works of drawing
Fuzzy, color is easy thin out.
Invention content
The invention discloses a kind of coloured oiled crayons and preparation method thereof to avoid chemical adhesion using honey as adhesive
Agent uses the potential hazard brought, while the vegetable fatty acid and polyalcohol contained in component so that making gained wax crayon has
Preferable flexibility and elasticity, are not easily broken.
In order to achieve the above objectives, technical solution of the present invention is as follows:
A kind of coloured oiled crayon, it is characterised in that:Including following component:
Polyvinyl butyral, polyalcohol, aliphatic acid, pigment powder, glass powder, carbon fiber, silica flour, honey;
Wherein, the polyalcohol is any one of ethylene glycol, dipropylene glycol, trimethylolpropane or pentaerythrite;
Wherein, the aliphatic acid is C16 ~ C18 aliphatic acid.
Preferably, the ingredient is weighed by following parts by weight:
5 ~ 8 parts of polyvinyl butyral, 10 ~ 17 parts of polyalcohol, 25 ~ 40 parts of aliphatic acid, 5 ~ 10 parts of pigment powder, 3 ~ 5 parts of glass powder,
3 ~ 5 parts of carbon fiber, 3 ~ 5 parts of silica flour, 20 ~ 35 parts of honey.
One kind pastel production method comprises the steps of:
(1)Glass powder, fiber powder and silica flour are taken by weight, is ground, and are crossed 325 mesh sieve, are obtained mixed powder filler;
(2)Honey is taken by weight, is diluted with water, and control water content is between 25 ~ 35%, agitating and heating, heating temperature 50 ~ 65
DEG C, 3 ~ 5h of heating time, 270 mesh of rear mistake sieve obtains honey liquid;
(3)Aliphatic acid and polyalcohol are taken by weight, aliphatic acid is added in polyalcohol, agitating and heating, and temperature is controlled 40 ~ 55
DEG C, until all dissolvings;
(4)Polyvinyl butyral, pigment powder are taken by weight, with step(1)Gained mixed powder filler and step(2)Institute
The mixing of honey liquid, add water to stir, control water content 10 ~ 15%, uniformly after and step(3)Obtained fatty acid alcohol solution
Mixing, heat temperature raising simultaneously stir, and control temperature is at 50 ~ 60 DEG C, after heating 2 ~ 3h, carry out homogenization, mold is packed into after homogeneous,
Required shape is produced, it is cooling, obtain finished product coloured oiled crayon.
Preferably, step(3)The aliphatic acid is vegetable fatty acid.
Advantageous effect of the present invention:
When the present invention makes coloured oiled crayon, using honey as adhesive, the potential danger that the use of chemical adhesive is brought is avoided
Evil;In addition, wax ester is made with vegetable fatty acid and polyol reaction so that gained wax crayon has preferable flexibility and elasticity,
It is less likely to be damaged.The present invention makes gained coloured oiled crayon and is applied to paint, fugitive color or does not fade, be turned into it is not hygroscopic by
The occurrence of tide, the use that color will not thicken, while also avoid fixative keeps picture subduing.
Specific implementation mode
Below by specific embodiment, the technical solution that further illustrates the present invention.
Embodiment 1
A kind of coloured oiled crayon, including following component:
Polyvinyl butyral, polyalcohol, aliphatic acid, pigment powder, glass powder, carbon fiber, silica flour, honey;
Wherein, the polyalcohol is ethylene glycol;
Wherein, the aliphatic acid is linoleic acid;
Wherein, the ingredient is weighed by following parts by weight:
5 parts of polyvinyl butyral, 10 parts of polyalcohol, 25 parts of aliphatic acid, 5 parts of pigment powder, 3 parts of glass powder, 3 parts of carbon fiber, stone
3 parts of English powder, 20 parts of honey;
One kind pastel production method comprises the steps of:
(1)Glass powder, fiber powder and silica flour are taken by weight, is ground, and are crossed 325 mesh sieve, are obtained mixed powder filler;
(2)Honey is taken by weight, is diluted with water, control water content is between 25 ~ 30%, agitating and heating, 50 DEG C of heating temperature,
Heating time 5h, 270 mesh of rear mistake sieve, obtains honey liquid;
(3)Linoleic acid and ethylene glycol are taken by weight, linoleic acid is added in ethylene glycol, agitating and heating, and temperature is controlled 40 ~ 45
DEG C, until all dissolvings;
(4)Polyvinyl butyral, red or blue pigment powder are taken by weight, with step(1)Gained mixed powder filler
And step(2)Gained honey liquid mixes, and water is added to stir, control water content 10 ~ 15%, uniformly after and step(3)Obtained Asia
Oleic acid alcoholic solution mixes, and heat temperature raising simultaneously stirs, and control temperature is at 50 ~ 53 DEG C, after heating 2 ~ 3h, carries out homogenization, homogeneous
After be packed into mold, produce required shape, it is cooling, obtain finished products-red or blue wax crayon;
Make the red or blue wax crayon of gained and be applied to drawing, draw color and fugitive color or do not fade, be turned into it is not hygroscopic make moist, color
The occurrence of use that will not be thickened, while also avoid fixative keeps picture subduing.
Embodiment 2
A kind of coloured oiled crayon, including following component:
Polyvinyl butyral, polyalcohol, aliphatic acid, pigment powder, glass powder, carbon fiber, silica flour, honey;
Wherein, the polyalcohol is dipropylene glycol;
Wherein, the aliphatic acid is brown eleostearic acid;
Wherein, the ingredient is weighed by following parts by weight:
8 parts of polyvinyl butyral, 17 parts of polyalcohol, 40 parts of aliphatic acid, 10 parts of pigment powder, 5 parts of glass powder, 5 parts of carbon fiber, stone
5 parts of English powder, 35 parts of honey;
One kind pastel production method comprises the steps of:
(1)Glass powder, fiber powder and silica flour are taken by weight, is ground, and are crossed 325 mesh sieve, are obtained mixed powder filler;
(2)Honey is taken by weight, is diluted with water, control water content is between 30 ~ 35%, agitating and heating, 65 DEG C of heating temperature,
Heating time 3h, 270 mesh of rear mistake sieve, obtains honey liquid;
(3)Brown eleostearic acid and dipropylene glycol are taken by weight, brown eleostearic acid is added in dipropylene glycol, agitating and heating, and temperature control exists
50 ~ 55 DEG C, until all dissolvings;
(4)Polyvinyl butyral, green or yellow pigment powder are taken by weight, with step(1)Gained mixed powder filler
And step(2)Gained honey liquid mixes, and water is added to stir, control water content 10 ~ 15%, uniformly after and step(3)Obtained palm fibre
Eleostearic acid alcoholic solution mixes, and heat temperature raising simultaneously stirs, and control temperature is at 60 DEG C, after heating 2h, carries out homogenization, is packed into after homogeneous
Mold produces required shape, cooling, obtains finished product green or yellow wax crayon.
Embodiment 3
A kind of coloured oiled crayon, including following component:
Polyvinyl butyral, polyalcohol, aliphatic acid, pigment powder, glass powder, carbon fiber, silica flour, honey;
Wherein, the polyalcohol is any one of trimethylolpropane or pentaerythrite;
Wherein, the aliphatic acid is stearic acid;
Wherein, the ingredient is weighed by following parts by weight:
6 parts of polyvinyl butyral, 13 parts of polyalcohol, 30 parts of aliphatic acid, 7 parts of pigment powder, 4 parts of glass powder, 4 parts of carbon fiber, stone
4 parts of English powder, 29 parts of honey;
One kind pastel production method comprises the steps of:
(1)Glass powder, fiber powder and silica flour are taken by weight, is ground, and are crossed 325 mesh sieve, are obtained mixed powder filler;
(2)Honey is taken by weight, is diluted with water, control water content is between 28 ~ 32%, agitating and heating, 60 DEG C of heating temperature,
Heating time 4h, 270 mesh of rear mistake sieve, obtains honey liquid;
(3)Stearic acid and trimethylolpropane or pentaerythrite are taken by weight, and trimethylolpropane or season is added in stearic acid
In penta tetrol, agitating and heating, temperature is controlled at 50 DEG C, until all dissolvings;
(4)Polyvinyl butyral, purple or brown powder are taken by weight, with step(1)Gained mixed powder filler
And step(2)Gained honey liquid mixes, and water is added to stir, control water content 10 ~ 15%, uniformly after and step(3)What is obtained is hard
Resin acid alcoholic solution mixes, and heat temperature raising simultaneously stirs, and control temperature is at 55 DEG C, after heating 3h, carries out homogenization, is packed into after homogeneous
Mold produces required shape, cooling, obtains finished product purple or brown coloured oiled crayon.
Claims (4)
1. a kind of coloured oiled crayon, it is characterised in that:Including following component:
Polyvinyl butyral, polyalcohol, aliphatic acid, pigment powder, glass powder, carbon fiber, silica flour, honey;
Wherein, the polyalcohol is any one of ethylene glycol, dipropylene glycol, trimethylolpropane or pentaerythrite;
Wherein, the aliphatic acid is C16 ~ C18 aliphatic acid.
2. coloured oiled crayon according to claim 1, it is characterised in that:The ingredient is weighed by following parts by weight:
5 ~ 8 parts of polyvinyl butyral, 10 ~ 17 parts of polyalcohol, 25 ~ 40 parts of aliphatic acid, 5 ~ 10 parts of pigment powder, 3 ~ 5 parts of glass powder,
3 ~ 5 parts of carbon fiber, 3 ~ 5 parts of silica flour, 20 ~ 35 parts of honey.
3. a kind of coloured oiled crayon as claimed in claim 1 or 2, it is characterised in that:The pastel production method include with
Lower step:
(1)Glass powder, fiber powder and silica flour are taken by weight, is ground, and are crossed 325 mesh sieve, are obtained mixed powder filler;
(2)Honey is taken by weight, is diluted with water, and control water content is between 25 ~ 35%, agitating and heating, heating temperature 50 ~ 65
DEG C, 3 ~ 5h of heating time, 270 mesh of rear mistake sieve obtains honey liquid;
(3)Aliphatic acid and polyalcohol are taken by weight, aliphatic acid is added in polyalcohol, agitating and heating, and temperature is controlled 40 ~ 55
DEG C, until all dissolvings;
(4)Polyvinyl butyral, pigment powder are taken by weight, with step(1)Gained mixed powder filler and step(2)Institute
The mixing of honey liquid, add water to stir, control water content 10 ~ 15%, uniformly after and step(3)Obtained fatty acid alcohol solution
Mixing, heat temperature raising simultaneously stir, and control temperature is at 50 ~ 60 DEG C, after heating 2 ~ 3h, carry out homogenization, mold is packed into after homogeneous,
Required shape is produced, it is cooling, obtain finished product coloured oiled crayon.
4. pastel production method according to claim 3, it is characterised in that:Step(3)The aliphatic acid is plant
Aliphatic acid.
Priority Applications (1)
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CN201810833219.8A CN108546455A (en) | 2018-07-26 | 2018-07-26 | A kind of coloured oiled crayon and preparation method thereof |
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CN201810833219.8A CN108546455A (en) | 2018-07-26 | 2018-07-26 | A kind of coloured oiled crayon and preparation method thereof |
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CN201810833219.8A Pending CN108546455A (en) | 2018-07-26 | 2018-07-26 | A kind of coloured oiled crayon and preparation method thereof |
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101559688A (en) * | 2009-06-03 | 2009-10-21 | 北京绿岛缘蜂产品有限公司 | Erasable colorful wax pencil |
WO2018081336A1 (en) * | 2016-10-26 | 2018-05-03 | Danimer Bioplastics, Inc. | Renewable, biodegradable marking wax composition |
-
2018
- 2018-07-26 CN CN201810833219.8A patent/CN108546455A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101559688A (en) * | 2009-06-03 | 2009-10-21 | 北京绿岛缘蜂产品有限公司 | Erasable colorful wax pencil |
WO2018081336A1 (en) * | 2016-10-26 | 2018-05-03 | Danimer Bioplastics, Inc. | Renewable, biodegradable marking wax composition |
Non-Patent Citations (4)
Title |
---|
[法]米歇尔•帕斯图罗: "《色彩列传 黑色》", 31 August 2016, 生活 读书 新知三联书店 * |
曹惟诚等: "《胶接技术手册》", 31 August 1988, 上海科学技术出版社 * |
李东光等: "《精细化工产品配方与工艺(一)》", 30 June 2006, 化学工业出版社 * |
江苏省地方志编纂委员会: "《江苏省志 生物志 动物篇》", 31 December 2005, 凤凰出版社 * |
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Application publication date: 20180918 |