CN108539581A - A kind of Metal Substrate graphene film cathode gas spark switch - Google Patents

A kind of Metal Substrate graphene film cathode gas spark switch Download PDF

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Publication number
CN108539581A
CN108539581A CN201810503670.3A CN201810503670A CN108539581A CN 108539581 A CN108539581 A CN 108539581A CN 201810503670 A CN201810503670 A CN 201810503670A CN 108539581 A CN108539581 A CN 108539581A
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switch
cathode
graphene film
metal substrate
support plate
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CN201810503670.3A
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CN108539581B (en
Inventor
王刚
苏建仓
张喜波
刘胜
王俊杰
潘亚峰
王利民
孙旭
樊旭亮
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Northwest Institute of Nuclear Technology
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Northwest Institute of Nuclear Technology
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01TSPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
    • H01T2/00Spark gaps comprising auxiliary triggering means
    • H01T2/02Spark gaps comprising auxiliary triggering means comprising a trigger electrode or an auxiliary spark gap
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01TSPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
    • H01T1/00Details of spark gaps
    • H01T1/20Means for starting arc or facilitating ignition of spark gap
    • H01T1/22Means for starting arc or facilitating ignition of spark gap by the shape or the composition of the electrodes

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  • Plasma Technology (AREA)

Abstract

A kind of Metal Substrate graphene film cathode gas spark switch of the present invention, belongs to technical field of pulse power.Switch includes four Metal Substrate graphene film cathode, insulating gas, metal anode, switch cavity parts.Switch generally axial symmery shape, Metal Substrate graphene film cathode are to grow graphene film by chemical vapour deposition technique in metal cathode surface to constitute.Metallic cathode and metal anode are Bruce shape, the clearance distance of Metal Substrate graphene film cathode and anode can be adjusted, insulating gas type and pressure can change, it connect with pulse power device on the left of switch-mode metal base graphene lamel cathode, is connect with pulse power device on the right side of switch-mode metal anode.The present invention is applied in pulse power device, gas spark switch operating voltage be hundred KV levels, solve the problems, such as gas spark switch breakdown voltage large dispersion, take into account construction of switch it is simple while, the reliability for improving switch ensure that the stable operation of pulse power device.

Description

A kind of Metal Substrate graphene film cathode gas spark switch
Technical field
The invention belongs to technical field of pulse power, are related to a kind of Metal Substrate graphene film cathode gas spark switch.
Background technology
In technical field of pulse power, switching technique has special consequence.It not only determines that pulse power fills The output characteristics set, the even key of pulse power system success or failure.Wherein, gas switch has high pressure, through-flow big, structure Simple feature, is widely used;But the stability of this switch work is poor, and repetition rate is relatively low, it is difficult to meet Gao Zhongying, height The requirement of steady operation occasion.The achievement in research of forefathers summarizes gas switch electrode material, field distribution, surface topography, gas The factors such as body state, voltage type achieve breakthrough to the affecting laws of breakdown characteristics to the understanding of gas switch working mechanism Property progress.
In terms of electrode material, Luo Weixi et al. researchs think graphite as high-current switch electrode, from static self breakdown Voltage stability and insulator service life are significantly better than metal (stainless steel, tungsten-copper alloy, copper alloy) electrode;Graphite electrode is slightly Under non-uniform field, switch room is away from 5mm, and when dry air pressure 0.25MPa, average self-breakdown voltage is 43.6kV, relative standard Deviation is 1.28%.Literature survey finds that the gas switch research about nano material electrode is very few.And carbon nanomaterial is true In empty electron emission application, there is apparent launch stability advantage.The carbon nanotube that the nineties finds is in Flied emission field table Reveal great application value, autoelectronic current is thousand times or more of conventional field emission material (such as diamond), single CNT emissioies have reached 107A/cm2.2004 find star's material graphene, because its super excellent optics, Electricity, mechanical and thermal characteristics, while there is high draw ratio and more emission edges, should theoretically there be better field Emitting performance.And grapheme material is applied to the research in high current electron emitting cathode and gas switch and is had not been reported.
Invention content
The purpose of the present invention is:To solve the problems, such as high pressure gas spark switch breakdown voltage large dispersion, it is proposed that one Kind Metal Substrate graphene film cathode gas spark switch.
The technical solution of the present invention is to provide a kind of Metal Substrate graphene film cathode gas spark switch, including switch cavity Body, the insulating gas for being filled in switch inside cavity and the switch cathode positioned at switch inside cavity and switch anode;
It is characterized in that:
Above-mentioned switch cathode is the sections Bruce electrode (Bruce electrode) with switch anode, is separately fixed at switch cavity On opposite two walls of body;
Above-mentioned switch cathode is Metal Substrate cathode, and surface deposits n-layer graphene film, wherein n >=1, especially by change It learns vapour deposition process and grows graphene film.
Graphene film is a kind of hexagonal cell shape two-dimensional structure being made of carbon atom, it is preferable that per layer graphene The thickness of film is less than 1nm, 1≤n≤5, and per layer graphene film covering Metal Substrate cathode surface coverage rate up to 50% with On.
Preferably, above-mentioned switch cavity includes outer barrel and is arranged the insulated left side support plate in two open end of outer barrel and right side Insulation support plate;Cathode and insulated left side support plate coaxial cooperation are switched, outside is fixed by left electrodes fixed ring;Switch sun Pole and side insulation right support plate coaxial cooperation, outside are fixed by right electrodes fixed ring, and the thickness of outer barrel is selected by switch The pressure size of insulating gas determines.
Preferably, insulated left side support plate and side insulation right center position of support plate are provided with and switch cathode and switch anode The matched through-hole of pedestal;Switch cathode and the pedestal for switching anode are each passed through through-hole and are fixed on insulated left side support plate and right side On insulation support plate.
Preferably, between outer barrel and insulated left side support plate and side insulation right support plate, insulated left side support plate and right side It is equipped with insulated enclosure circle between insulation support plate and switch cathode, switch anode, it is exhausted that insulated enclosure circle will switch inside cavities Edge gas is isolated from the outside.
Preferably, it is circular o shape sealing rings that insulated enclosure circle, which is cross section, and annulus and circular cross sectional dimensions are by close Seal structure and form determine.
Preferably, switch anode can be adjusted with the clearance distance for switching cathode by two lateral electrode fixed rings, switch sun Maximum clearance distance between pole and switch cathode is no more than the 1/3 of switch cathode or switch anode outer diameter;It switchs on the left of cathode It connect with pulse power device, is connect with pulse power device on the right side of switch anode.
The present invention operation principle be:After pulse power device charges to certain voltage to switch, Metal Substrate graphene is thin Quasi- uniform electric field is built between film cathode and metal anode, graphene film is under certain forceful electric power field action, due to multidimensional Tip field emission structure and edge flashing mechanism collective effect, cathode surface formed plasmasphere, carried by metallic cathode Stable electron source is formed for high density electronics, with insulating gas ionization by collision, electron avalanche is formed and extremely fast develops on the sunny side, Insulating gas punctures completely between eventually leading to entire switch anode and cathode, and the switch course of work terminates.
The beneficial effects of the invention are as follows:
The present invention is based on the electric properties that graphene is excellent, it is proposed that a kind of Metal Substrate graphene film cathode gas spark Switch is applied in pulse power device, and gas spark switch operating voltage is hundred KV levels, solves gas spark switch and hits Wear the big problem of distribution of voltage, take into account construction of switch it is simple while, improve the reliability of switch, ensure that pulse power The stable operation of device.
Description of the drawings
Fig. 1 is a kind of Metal Substrate graphene film cathode gas spark switch diagrammatic cross-section proposed by the present invention;
Fig. 2 is Metal Substrate graphene film cathode surface schematic diagram.
Reference numeral is in figure:1- graphene films, 2- stainless steel anodes, 3- high pure nitrogens, 4- copper-base graphite alkene films Cathode, 6- organic glass support plates, 7- outer barrels, 8- nuts, 9- sealing rings, 10- switch cavity.
Specific implementation mode
A kind of Metal Substrate graphene film cathode gas spark of the present invention is done in detail with reference to the accompanying drawings and examples Description.
A kind of Metal Substrate graphene film cathode gas spark in the present embodiment, including copper-base graphite alkene lamel cathode 4, High pure nitrogen 3, stainless steel anode 2,10 4 parts of switch cavity, generally axial symmery shape.
Refering to fig. 1, Fig. 2, copper-base graphite alkene lamel cathode 4 are grown by chemical vapour deposition technique in red copper cathode surface Number layer graphene film 1 is constituted, and the thickness of graphene film 1 is less than 1nm, and the number of plies is between 1-5 layers, and covering per layer film Lid rate is up to 50% or more.Copper-base graphite alkene lamel cathode 4 and stainless steel anode 2 are Bruce shape, and overall diameter is 25mm, Thickness of electrode is 8mm, and the straight mouth diameter of electrode tip holder is 10mm, and electrode tip holder screw thread is M8;Copper-base graphite alkene lamel cathode 4 and a left side 6 coaxial cooperation of side organic glass support plate, outside are connected by left side stainless steel nut 8;Stainless steel anode 2 and the organic glass in right side 6 coaxial cooperation of glass support plate, outside are connected by right side stainless steel nut 8;Stainless steel outer barrel 7 and left and right organic glass support plate 6 coaxial cooperations, silicone rubber O-ring 9 are isolated from the outside 10 inside high pressure nitrogen 3 of cavity is switched.
Left and right sides insulation support plate 6 is disc-shape, and thickness 3mm, center is reserved thin with copper-base graphite alkene The through-hole identical with 2 pedestal of stainless steel anode of film cathode 4, diameter 10mm;Outside 6 outside diameter of organic glass support plate and stainless steel 7 inner surface diameters of cylinder are identical, are 140mm.2 maximum pressure of nitrogen is 0.8MPa, and the thickness of stainless steel outer barrel 7 is 5mm.
The clearance distance of copper-base graphite alkene lamel cathode 4 and stainless steel anode 2 can be adjusted by both sides stainless steel nut 8 Section, maximum clearance distance should be no more than 8mm.
Silicone rubber O-ring 9 be circular ring structure, cross section be circle, annulus overall diameter be 140mm, interior diameter 130mm, Cross-sectional diameter is 10mm.
Under the conditions of identical switch form, on-load voltage, 0.8MPa high pure nitrogens, when cathode is red copper cathode, open Pass breakdown voltage average value is 100kV, and the relative standard deviation of voltage magnitude is 5%;And when cathode is copper-base graphite alkene film When cathode, switch breakdown voltage average value is 80kV, and the relative standard deviation of voltage magnitude is only 1%, and dispersibility is obviously reduced, The breakdown stability and functional reliability for improving high pressure gas spark switch, ensure that the stable operation of pulse power device.

Claims (7)

1. a kind of Metal Substrate graphene film cathode gas spark switch, including switch cavity, be filled in switch inside cavity Insulating gas and the switch cathode positioned at switch inside cavity and switch anode;
It is characterized in that:
The switch cathode is the sections Bruce electrode with switch anode, is separately fixed on opposite two walls of switch cavity;
The switch cathode is Metal Substrate cathode, and surface deposits n-layer graphene film, wherein n >=1.
2. Metal Substrate graphene film cathode gas spark switch according to claim 1, it is characterised in that:Every layer of graphite The thickness of alkene film is less than 1nm, 1≤n≤5, and the coverage rate of every layer graphene film covering Metal Substrate cathode surface up to 50% More than.
3. Metal Substrate graphene film cathode gas spark switch according to claim 1, it is characterised in that:The switch Cavity includes outer barrel and is arranged insulated left side support plate and side insulation right support plate in two open end of outer barrel;Switch cathode and a left side Side insulation support plate coaxial cooperation, outside are fixed by left electrodes fixed ring;It switchs anode and side insulation right support plate is coaxial Cooperation, outside is fixed by right electrodes fixed ring.
4. Metal Substrate graphene film cathode gas spark switch according to claim 3, it is characterised in that:Insulated left side Support plate and side insulation right center position of support plate are provided with and switch cathode and the switch matched through-hole of anode pedestal;Switch cathode Through-hole is each passed through with the pedestal of switch anode to be fixed in insulated left side support plate and side insulation right support plate.
5. Metal Substrate graphene film cathode gas spark switch according to claim 4, it is characterised in that:Outer barrel and a left side Between side insulation support plate and side insulation right support plate, insulated left side support plate and side insulation right support plate and switch cathode, open It is equipped with insulated enclosure circle between the anode of pass.
6. Metal Substrate graphene film cathode gas spark switch according to claim 5, it is characterised in that:Insulated enclosure Circle is that cross section is circular o shape sealing rings.
7. Metal Substrate graphene film cathode gas spark switch according to claim 6, it is characterised in that:Switch anode Maximum clearance distance between switch cathode is no more than the 1/3 of switch cathode or switch anode outer diameter.
CN201810503670.3A 2018-05-23 2018-05-23 Metal-based graphene film cathode gas spark switch Active CN108539581B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110600999A (en) * 2019-09-24 2019-12-20 中国工程物理研究院流体物理研究所 Novel high-voltage large-current rotary arc switch

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CN101777730A (en) * 2010-04-09 2010-07-14 华中科技大学 Designing method of graphite electrode of high energy pulse gas switch
CN102163805A (en) * 2010-12-23 2011-08-24 中国人民解放军理工大学 Remote high-voltage pulse nanosecond switch applying insulating oil
CN103095268A (en) * 2013-01-18 2013-05-08 大连理工大学 Large current high voltage trigger switch with controllable air intake
CN103553029A (en) * 2013-10-31 2014-02-05 中国科学院上海微系统与信息技术研究所 Method for preparing vertical graphene-based thermal material
CN103779292A (en) * 2013-12-31 2014-05-07 中国科学院上海微系统与信息技术研究所 Method for preparing graphene-based chip heat-radiating material
CN104616945A (en) * 2015-02-09 2015-05-13 东南大学 Field-emission code cathode
CN105220214A (en) * 2015-11-13 2016-01-06 中国科学院上海高等研究院 A kind of preparation method of graphene film
CN105470078A (en) * 2015-12-29 2016-04-06 无锡吉仓纳米材料科技有限公司 Focused tripolar structured fully-packaged X-ray bulb tube based on carbon nanotube cold cathode
CN106128906A (en) * 2016-08-29 2016-11-16 重庆启越涌阳微电子科技发展有限公司 Vertical type graphene film field-transmitting cathode and preparation method thereof, electrode
CN106405359A (en) * 2016-11-17 2017-02-15 西北核技术研究所 Insulating oil test oil cup for 100 kV pulse voltage
CN107311467A (en) * 2017-05-27 2017-11-03 北京大学 A kind of preparation method, Graphene glass and the photo-thermal conversion device of the photo-thermal conversion device based on Graphene glass

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101777730A (en) * 2010-04-09 2010-07-14 华中科技大学 Designing method of graphite electrode of high energy pulse gas switch
CN102163805A (en) * 2010-12-23 2011-08-24 中国人民解放军理工大学 Remote high-voltage pulse nanosecond switch applying insulating oil
CN103095268A (en) * 2013-01-18 2013-05-08 大连理工大学 Large current high voltage trigger switch with controllable air intake
CN103553029A (en) * 2013-10-31 2014-02-05 中国科学院上海微系统与信息技术研究所 Method for preparing vertical graphene-based thermal material
CN103779292A (en) * 2013-12-31 2014-05-07 中国科学院上海微系统与信息技术研究所 Method for preparing graphene-based chip heat-radiating material
CN104616945A (en) * 2015-02-09 2015-05-13 东南大学 Field-emission code cathode
CN105220214A (en) * 2015-11-13 2016-01-06 中国科学院上海高等研究院 A kind of preparation method of graphene film
CN105470078A (en) * 2015-12-29 2016-04-06 无锡吉仓纳米材料科技有限公司 Focused tripolar structured fully-packaged X-ray bulb tube based on carbon nanotube cold cathode
CN106128906A (en) * 2016-08-29 2016-11-16 重庆启越涌阳微电子科技发展有限公司 Vertical type graphene film field-transmitting cathode and preparation method thereof, electrode
CN106405359A (en) * 2016-11-17 2017-02-15 西北核技术研究所 Insulating oil test oil cup for 100 kV pulse voltage
CN107311467A (en) * 2017-05-27 2017-11-03 北京大学 A kind of preparation method, Graphene glass and the photo-thermal conversion device of the photo-thermal conversion device based on Graphene glass

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110600999A (en) * 2019-09-24 2019-12-20 中国工程物理研究院流体物理研究所 Novel high-voltage large-current rotary arc switch

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