CN108535671B - A method for measuring magnetization dynamics at the nanoscale - Google Patents

A method for measuring magnetization dynamics at the nanoscale Download PDF

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CN108535671B
CN108535671B CN201810429134.3A CN201810429134A CN108535671B CN 108535671 B CN108535671 B CN 108535671B CN 201810429134 A CN201810429134 A CN 201810429134A CN 108535671 B CN108535671 B CN 108535671B
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张向平
方晓华
范晓雯
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Jiaxing Noone Medical Technology Co ltd
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Jinhua Polytechnic
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Abstract

The invention relates to the field of material surface magnetism measurement, in particular to a method for measuring nanoscale magnetization dynamics, wherein a measuring device comprises a pulse laser, a time delay device, an 1/4 wave plate, a concave lens, a convex lens I, a plane mirror, a polaroid, a beam splitter, a convex lens II, a lens platform, an atomic force microscope I, a probe I, a lens seat, an objective lens, a sample, a waveguide, a sample platform, a signal generator, an oscilloscope, a detector, a bias tee joint, an amplifier I, a mixer, an amplifier II, an analog-to-digital converter, a computer, an atomic force microscope II, a probe II and a phase sensitive detector, can measure a single nanostructure, can achieve submicron-order spatial resolution for measuring the magnetization dynamics of the surface of the sample, and adopts two different atomic force microscope tips to respectively carry out contact-mode atomic force microscope scanning and near-field time resolution magneto-optic effect experiments, and a frequency domain method is adopted to detect the magnetization dynamics of a GHz frequency band on the surface of the sample, so that the method has high sensitivity.

Description

一种纳米尺度磁化动态的测量方法A method for measuring magnetization dynamics at the nanoscale

技术领域technical field

本发明涉及材料表面磁性测量领域,尤其是一种能够对材料表面单个纳米结构的高频动态磁化进行测量的一种纳米尺度磁化动态的测量方法。The invention relates to the field of material surface magnetic measurement, in particular to a nanoscale magnetization dynamic measurement method capable of measuring the high-frequency dynamic magnetization of a single nanostructure on the material surface.

背景技术Background technique

磁光克尔效应测量装置是材料表面磁性研究中的一种重要手段,其工作原理是基于由光与磁化介质间相互作用而引起的磁光克尔效应,其不仅能够进行单原子层厚度材料的磁性检测,而且可实现非接触式测量,在磁性超薄膜的磁有序、磁各向异性、层间耦合和磁性超薄膜的相变行为等方面的研究中都有重要应用。磁光克尔效应测量装置主要是通过检测一束线偏振光在材料表面反射后的偏振态变化引起的光强变化进行样品表面的磁化观测,因此其成像的效果极易受到光学元件限制,现有技术缺陷一:传统的使用显微镜物镜的聚焦克尔显微镜的空间分辨率由光学衍射极限所决定,因此无法得到纳米尺度的磁化动态特征;现有技术缺陷二:无法获得样品中较高频率的磁化动态信息,所述一种纳米尺度磁化动态的测量方法能解决问题。The magneto-optical Kerr effect measurement device is an important method in the study of material surface magnetism. Its working principle is based on the magneto-optical Kerr effect caused by the interaction between light and magnetized media. It has important applications in the study of magnetic order, magnetic anisotropy, interlayer coupling and phase transition behavior of magnetic ultra-thin films. The magneto-optical Kerr effect measurement device mainly observes the magnetization of the sample surface by detecting the light intensity change caused by the polarization state change of a beam of linearly polarized light reflected on the material surface. There are technical defects 1: the spatial resolution of the traditional focusing Kerr microscope using microscope objective is determined by the optical diffraction limit, so the dynamic characteristics of magnetization at the nanoscale cannot be obtained; The magnetization dynamic information, the method for measuring the nano-scale magnetization dynamic can solve the problem.

发明内容SUMMARY OF THE INVENTION

为了解决上述问题,本发明提供一种纳米尺度磁化动态的测量方法,测量装置采用高精度的定位装置来获得纳米尺度样品表面的磁化信息,并采用频域方法来探测样品表面GHz频段的磁化动态。In order to solve the above problems, the present invention provides a method for measuring the nanoscale magnetization dynamics. The measuring device adopts a high-precision positioning device to obtain the magnetization information of the nanoscale sample surface, and adopts the frequency domain method to detect the magnetization dynamics of the sample surface in the GHz frequency band. .

本发明所采用的技术方案是:The technical scheme adopted in the present invention is:

测量装置主要包括脉冲激光器、延时器、1/4波片、凹透镜、凸透镜I、平面镜、偏振片、分束器、凸透镜II、透镜台、原子力显微镜I、探针I、透镜座、物镜、样品、波导、样品台、信号发生器、示波器、光桥探测器、偏置三通、放大器I、混频器、放大器II、模数转换器、计算机、原子力显微镜II、探针II、相敏检测器、正弦信号发生器、入射光路及反射光路,所述光桥探测器的输入端具有一个45度角的偏振器,所述原子力显微镜II与原子力显微镜I结构相同,所述探针I位于原子力显微镜I下端,所述探针II位于原子力显微镜II下端,所述物镜位于透镜座下端,所述脉冲激光器、信号发生器、波导、示波器依次电缆连接,所述光桥探测器、偏置三通、放大器I、混频器、放大器II、模数转换器、计算机依次电缆连接,所述脉冲激光器发射的激光束依次经延时器、1/4波片、凹透镜、凸透镜I、平面镜、偏振片、分束器、凸透镜II、透镜台、原子力显微镜I、探针I,从而形成入射光路,所述激光束照射到样品表面产生的反射光依次经探针I、原子力显微镜I、透镜台、凸透镜II、分束器,从而形成反射光路,所述反射光被分束器偏转至所述光桥探测器,所述透镜台为透光圆盘且具有中心轴,所述原子力显微镜I、透镜座、原子力显微镜II分别位于透镜台下面、且均能够相对于透镜台的位置微调,当透镜台绕其中心轴转动时,能够分别将原子力显微镜I或透镜座或原子力显微镜II置于样品(15)正上方,所述探针II为接触型原子力显微镜探针,波导位于样品台上,通过磁控溅射方法将样品直接接触地制备于波导上表面,所述探针I和探针II为相同外形尺寸的原子力显微镜探针、且外形均为圆台,所述圆台轴线垂直于水平面,所述探针I中具有圆台形通孔;所述探针I和探针II的所述外形圆台的上底面直径为3微米、下底面直径为2微米,所述探针I中的所述圆台形通孔的上部开口直径为500纳米、下部开口直径为900纳米,所述透镜台直径为十厘米;所述波导长为80微米、宽为50微米、厚度为150纳米,特征阻抗为50欧姆;所述样品长为10微米、宽为9微米、厚度为50纳米。The measuring device mainly includes pulsed laser, delay device, 1/4 wave plate, concave lens, convex lens I, plane mirror, polarizer, beam splitter, convex lens II, lens stage, atomic force microscope I, probe I, lens holder, objective lens, Sample, Waveguide, Sample Stage, Signal Generator, Oscilloscope, Optical Bridge Detector, Bias Tee, Amplifier I, Mixer, Amplifier II, A/D Converter, Computer, AFM II, Probe II, Phase Sensitive Detector, sinusoidal signal generator, incident light path and reflected light path, the input end of the optical bridge detector has a polarizer with an angle of 45 degrees, the atomic force microscope II has the same structure as the atomic force microscope I, and the probe I is located at The lower end of the atomic force microscope I, the probe II is located at the lower end of the atomic force microscope II, the objective lens is located at the lower end of the lens holder, the pulsed laser, the signal generator, the waveguide, and the oscilloscope are connected by cables in sequence, and the optical bridge detector, offset three Amplifier I, mixer, amplifier II, analog-to-digital converter, and computer are connected with cables in sequence, and the laser beam emitted by the pulsed laser passes through the delay device, 1/4 wave plate, concave lens, convex lens I, plane mirror, polarization Sheet, beam splitter, convex lens II, lens stage, atomic force microscope I, probe I, thereby forming an incident light path, and the reflected light generated by the laser beam irradiating the surface of the sample passes through probe I, atomic force microscope I, lens stage, Convex lens II, beam splitter, thus forming a reflected light path, the reflected light is deflected by the beam splitter to the optical bridge detector, the lens stage is a light-transmitting disk and has a central axis, the atomic force microscope I, lens The seat and AFM II are located under the lens stage respectively, and can be fine-tuned relative to the position of the lens stage. When the lens stage is rotated around its central axis, the AFM I or the lens seat or AFM II can be placed on the sample (15) ) directly above, the probe II is a contact-type atomic force microscope probe, the waveguide is located on the sample stage, and the sample is directly contacted on the upper surface of the waveguide by the magnetron sputtering method, and the probe I and probe II are The atomic force microscope probes of the same external dimensions have a circular truncated shape, the axis of the truncated truncated cone is perpendicular to the horizontal plane, and the probe I has a truncated truncated through hole; The diameter of the upper bottom surface is 3 micrometers, the diameter of the lower bottom surface is 2 micrometers, the diameter of the upper opening of the frustum-shaped through hole in the probe 1 is 500 nanometers, the diameter of the lower opening is 900 nanometers, and the diameter of the lens stage is ten centimeters ; The waveguide length is 80 microns, the width is 50 microns, the thickness is 150 nanometers, and the characteristic impedance is 50 ohms; the sample length is 10 microns, the width is 9 microns, and the thickness is 50 nanometers.

所述光桥探测器输出端与一个相敏检测器输入端相连,所述相敏检测器的参考频率设置为与所述信号发生器的输出频率一致,相敏检测器输出端连接偏置三通,正弦信号发生器输出端连接混频器输入端II。所述光桥探测器的输入端具有一个45度角的偏振器,反射光经过所述偏振器后光强为

Figure GSB0000188053060000021
其中I0是反射光到达所述偏振器时的光强,θk是克尔角。所述混频器具有输入端I和输入端II的两个信号输入端。当反射光强对样品磁化的依赖关系是线性的,能够估计光桥探测器中的由样品磁化导致的电流的交流分量δI≈IDCθK0δmz,其中θK0是样品在磁化饱和条件下的克尔角,δmz是面外磁化的变化,IDC是光桥探测器中的电流的直流分量。The output end of the optical bridge detector is connected to the input end of a phase sensitive detector, the reference frequency of the phase sensitive detector is set to be consistent with the output frequency of the signal generator, and the output end of the phase sensitive detector is connected to the offset three. The output terminal of the sine signal generator is connected to the input terminal II of the mixer. The input end of the optical bridge detector has a polarizer with an angle of 45 degrees. After the reflected light passes through the polarizer, the light intensity is
Figure GSB0000188053060000021
where I 0 is the light intensity of the reflected light when it reaches the polarizer, and θ k is the Kerr angle. The mixer has two signal inputs, input I and input II. When the dependence of the reflected light intensity on the sample magnetization is linear, it is possible to estimate the AC component of the current in the optical bridge detector caused by the sample magnetization δI≈I DC θ K0 δm z , where θ K0 is the sample at the magnetization saturation condition The Kerr angle, δm z is the change in out-of-plane magnetization, and I DC is the DC component of the current in the optical bridge detector.

测量装置采用高精度的定位装置来获得纳米尺度样品表面的磁化信息,即采用两个不同的原子力显微镜针尖分别进行接触模式原子力显微镜扫描以及近场时间分辨磁光克尔效应实验,并采用频域方法来探测样品表面GHz频段的磁化动态,具有较高空间灵敏度,较快的测试速度,装置结构简单,探针使用寿命长。The measurement device uses a high-precision positioning device to obtain the magnetization information of the nanoscale sample surface, that is, two different atomic force microscope tips are used to conduct contact mode atomic force microscope scanning and near-field time-resolved magneto-optical Kerr effect experiments, and use frequency domain. The method to detect the magnetization dynamics of the sample surface in the GHz frequency band has the advantages of higher spatial sensitivity, faster testing speed, simple device structure and long service life of the probe.

所述一种纳米尺度磁化动态的测量方法的步骤如下:The steps of the method for measuring the nanoscale magnetization dynamics are as follows:

一.旋转透镜台使得原子力显微镜II位于样品正上方,采用探针II对波导上包含样品的区域进行扫描,以获得表面形貌图像,初步确定样品位置,当探针II位于样品边缘时,令探针II缩回,并记录原子力显微镜II中各位置参数;1. Rotate the lens stage so that the atomic force microscope II is directly above the sample, and use the probe II to scan the area containing the sample on the waveguide to obtain the surface topography image, and preliminarily determine the position of the sample. When the probe II is located at the edge of the sample, let The probe II is retracted, and the position parameters of the atomic force microscope II are recorded;

二.旋转透镜台使得原子力显微镜I位于样品正上方,将步骤一中记录的各位置参数输入原子力显微镜I;2. Rotating the lens stage makes atomic force microscope 1 be positioned directly above the sample, and input each position parameter recorded in step 1 into atomic force microscope 1;

三.将探针I向样品表面逼近,然后采用探针I对样品所在区域进行扫描,扫描速度2nm/s,一旦探测到样品表面后即停止逼近,并向上回缩距离100nm,同时关闭原子力显微镜I的扫描反馈;3. Approach probe I to the surface of the sample, and then use probe I to scan the area where the sample is located at a scanning speed of 2 nm/s. Once the surface of the sample is detected, the approach is stopped, and the distance is retracted upwards by 100 nm, and the atomic force microscope is turned off at the same time. I scan feedback;

四.调整平面镜位置,使得激光束通过透镜台和原子力显微镜I射到探针I上;4. Adjust the plane mirror position so that the laser beam is projected onto the probe 1 through the lens stage and the atomic force microscope 1;

五.脉冲激光器产生脉冲激光,周期小于100fs,重复率50MHz,波长700nm,信号发生器的触发波形与激光重复率同步;5. The pulse laser generates pulsed laser, the period is less than 100fs, the repetition rate is 50MHz, the wavelength is 700nm, and the trigger waveform of the signal generator is synchronized with the laser repetition rate;

六.信号发生器产生频率f为1GHz的RF电流输出至波导用于激发样品;6. The signal generator generates an RF current with a frequency f of 1GHz and outputs it to the waveguide for exciting the sample;

七.在关闭原子力显微镜I的扫描反馈的状态下,设置探针I进行扫描;7. In the state of turning off the scanning feedback of the atomic force microscope 1, set the probe 1 to scan;

八.从样品表面反射的光束依次经过探针I、原子力显微镜I、透镜台、凸透镜II、分束器后进入光桥探测器,所述相敏检测器将进入光桥探测器的信号中的1GHz频率的极向克尔信号分离出来,并以电流形式输出;8. The light beam reflected from the sample surface passes through the probe I, atomic force microscope I, lens stage, convex lens II, and beam splitter in sequence and then enters the optical bridge detector, and the phase-sensitive detector will enter the signal of the optical bridge detector. The polar Kerr signal of 1GHz frequency is separated and output in the form of current;

九.所述相敏检测器输出的电流的交流分量经过放大器I放大30dB后,输入混频器的输入端I;9. After the AC component of the current output by the phase sensitive detector is amplified by 30dB through the amplifier I, it is input to the input end I of the mixer;

十.所述正弦信号发生器锁频至信号发生器,产生频率为f-Δf的参考信号,Δf=3KHz,所述参考信号输入混频器的输入端II;10. The sinusoidal signal generator is frequency-locked to the signal generator to generate a reference signal with a frequency of f-Δf, Δf = 3KHz, and the reference signal is input to the input terminal II of the mixer;

十一.混频器输出的混频信号频率为Δf,所述混频信号被放大器II继续放大,最终由模数转换器进行采样;11. The frequency of the mixing signal output by the mixer is Δf, the mixing signal is continuously amplified by the amplifier II, and finally sampled by the analog-to-digital converter;

十二.计算机记录由模数转换器输出的信号,并在Δf频率对该信号实施快速傅里叶变换,并与原子力显微镜I采集的样品位置数据相关联,从而得到样品表面的磁共振图像。12. The computer records the signal output by the analog-to-digital converter, performs fast Fourier transform on the signal at the Δf frequency, and correlates it with the sample position data collected by the atomic force microscope 1, thereby obtaining a magnetic resonance image of the sample surface.

本发明的有益效果是:The beneficial effects of the present invention are:

本发明能够对单个纳米结构进行测量,对样品表面的磁化动态的测量能达到亚微米量级的空间分辨率,具有较高空间灵敏度,装置简单,测试速度快。所述探针I和探针II为相同外缘尺寸的原子力显微镜探针,分别进行接触模式原子力显微镜扫描以及近场时间分辨磁光克尔效应实验,优点是无需使用探针I扫描大范围的样品表面,不会造成探针I中纳米尺度孔径的损坏而影响实验精度。The invention can measure a single nanostructure, and can measure the magnetization dynamics of the sample surface to reach the spatial resolution of sub-micron level, has high spatial sensitivity, simple device and fast test speed. The probe I and probe II are atomic force microscope probes with the same outer edge size, which are respectively used for contact mode AFM scanning and near-field time-resolved magneto-optical Kerr effect experiments. The advantage is that there is no need to use probe I to scan a large area. The surface of the sample will not cause damage to the nano-scale pore size in the probe I and affect the experimental accuracy.

附图说明Description of drawings

下面结合本发明的图形进一步说明:Further illustrate below in conjunction with the graphics of the present invention:

图1是本发明示意图。Figure 1 is a schematic diagram of the present invention.

图2是透镜台仰视图。FIG. 2 is a bottom view of the lens stage.

图中,1.脉冲激光器,2.延时器,3.1/4波片,4.凹透镜,5.凸透镜I,6.平面镜,7.偏振片,8.分束器,9.凸透镜II,10.透镜台,11.原子力显微镜I,12.探针I,13.透镜座,14.物镜,15.样品,16.波导,17.样品台,18.信号发生器,19.示波器,20.光桥探测器,21.偏置三通,22.放大器I,23.混频器,24.放大器II,25.模数转换器,26.计算机,27.原子力显微镜II,28.探针II。In the figure, 1. Pulse laser, 2. Delayer, 3.1/4 wave plate, 4. Concave lens, 5. Convex lens I, 6. Flat mirror, 7. Polarizer, 8. Beam splitter, 9. Convex lens II, 10 .Lens stage, 11. AFM I, 12. Probe I, 13. Lens holder, 14. Objective lens, 15. Sample, 16. Waveguide, 17. Sample stage, 18. Signal generator, 19. Oscilloscope, 20. Optical Bridge Detector, 21. Bias Tee, 22. Amplifier I, 23. Mixer, 24. Amplifier II, 25. Analog-to-Digital Converter, 26. Computer, 27. Atomic Force Microscope II, 28. Probe II .

具体实施方式Detailed ways

如图1是本发明示意图,所述脉冲激光器1、信号发生器18、波导16、示波器19依次电缆连接,所述光桥探测器20、偏置三通21、放大器I22、混频器23、放大器II24、模数转换器25、计算机26依次电缆连接,所述脉冲激光器1发射的激光束依次经延时器2、1/4波片3、凹透镜4、凸透镜I5、平面镜6、偏振片7、分束器8、凸透镜II9、透镜台10、原子力显微镜I11、探针I12,从而形成入射光路,所述激光束照射到样品15表面产生的反射光依次经探针I12、原子力显微镜I11、透镜台10、凸透镜II9、分束器8,从而形成反射光路,所述反射光被分束器8偏转至所述光桥探测器20,所述探针II28为接触型原子力显微镜探针,波导16位于样品台17上,通过磁控溅射方法将样品15直接接触地制备于波导16上表面,所述探针I12和探针II28为相同外形尺寸的原子力显微镜探针、且外形均为圆台,所述圆台轴线垂直于水平面,所述探针I12中具有圆台形通孔;所述探针I12和探针II28的所述外形圆台的上底面直径为3微米、下底面直径为2微米,所述探针I12中的所述圆台形通孔的上部开口直径为500纳米、下部开口直径为900纳米,所述透镜台10直径为十厘米;所述波导16长为80微米、宽为50微米、厚度为150纳米,特征阻抗为50欧姆;所述样品15长为10微米、宽为9微米、厚度为50纳米。1 is a schematic diagram of the present invention, the pulsed laser 1, the signal generator 18, the waveguide 16, and the oscilloscope 19 are connected by cables in sequence, the optical bridge detector 20, the bias tee 21, the amplifier I22, the mixer 23, The amplifier II24, the analog-to-digital converter 25, and the computer 26 are connected with cables in sequence, and the laser beam emitted by the pulsed laser 1 passes through the delay device 2, the 1/4 wave plate 3, the concave lens 4, the convex lens I5, the plane mirror 6, and the polarizer 7 in turn. , beam splitter 8, convex lens II9, lens stage 10, atomic force microscope I11, probe I12, thereby forming an incident light path, and the reflected light generated by the laser beam irradiating the surface of the sample 15 passes through the probe I12, atomic force microscope I11, lens in turn Stage 10, convex lens II9, beam splitter 8, thereby forming a reflected light path, the reflected light is deflected by beam splitter 8 to the optical bridge detector 20, the probe II28 is a contact-type atomic force microscope probe, and the waveguide 16 On the sample stage 17, the sample 15 is prepared in direct contact with the upper surface of the waveguide 16 by the magnetron sputtering method, the probe I12 and the probe II28 are atomic force microscope probes with the same external dimensions, and the external shapes are both circular truncated, The axis of the frustum is perpendicular to the horizontal plane, and the probe I12 has a frustum-shaped through hole; the diameter of the upper bottom surface of the outer frustum of the probe I12 and the probe II28 is 3 microns, and the diameter of the lower bottom surface is 2 microns, so The diameter of the upper opening of the frustum-shaped through hole in the probe I12 is 500 nanometers, the diameter of the lower opening is 900 nanometers, the diameter of the lens stage 10 is ten centimeters; the length of the waveguide 16 is 80 micrometers, and the width is 50 micrometers , the thickness is 150 nanometers, and the characteristic impedance is 50 ohms; the sample 15 is 10 micrometers long, 9 micrometers wide, and 50 nanometers thick.

如图2是透镜台仰视图,所述原子力显微镜II27与原子力显微镜I11结构相同,所述探针I12位于原子力显微镜I11下端,所述探针II28位于原子力显微镜II27下端,所述物镜14位于透镜座13下端,所述探针I12和探针II28为相同外形尺寸的原子力显微镜探针,所述透镜台10为透光圆盘且具有中心轴,所述原子力显微镜I11、透镜座13、原子力显微镜II27分别位于透镜台10下面、且均能够相对于透镜台10的位置微调,当透镜台10绕其中心轴转动时,能够分别将原子力显微镜I11或透镜座13或原子力显微镜II27置于样品15正上方。2 is a bottom view of the lens stage, the atomic force microscope II27 has the same structure as the atomic force microscope I11, the probe I12 is located at the lower end of the atomic force microscope I11, the probe II28 is located at the lower end of the atomic force microscope II27, and the objective lens 14 is located at the lens seat 13 at the lower end, the probe I12 and the probe II28 are atomic force microscope probes with the same external dimensions, the lens stage 10 is a light-transmitting disc and has a central axis, the atomic force microscope I11, the lens holder 13, the atomic force microscope II27 They are respectively located under the lens stage 10 and can be fine-tuned relative to the position of the lens stage 10. When the lens stage 10 is rotated around its central axis, the atomic force microscope I11 or the lens holder 13 or the atomic force microscope II27 can be placed directly above the sample 15. .

测量装置主要包括脉冲激光器1、延时器2、1/4波片3、凹透镜4、凸透镜I5、平面镜6、偏振片7、分束器8、凸透镜II9、透镜台10、原子力显微镜I11、探针I12、透镜座13、物镜14、样品15、波导16、样品台17、信号发生器18、示波器19、光桥探测器20、偏置三通21、放大器I22、混频器23、放大器II24、模数转换器25、计算机26、原子力显微镜II27、探针II28、相敏检测器、正弦信号发生器、入射光路及反射光路,所述光桥探测器20的输入端具有一个45度角的偏振器,所述原子力显微镜II27与原子力显微镜I11结构相同,所述探针I12位于原子力显微镜I11下端,所述探针II28位于原子力显微镜II27下端,所述物镜14位于透镜座13下端,所述脉冲激光器1、信号发生器18、波导16、示波器19依次电缆连接,所述光桥探测器20、偏置三通21、放大器I22、混频器23、放大器II24、模数转换器25、计算机26依次电缆连接,所述脉冲激光器1发射的激光束依次经延时器2、1/4波片3、凹透镜4、凸透镜I5、平面镜6、偏振片7、分束器8、凸透镜II9、透镜台10、原子力显微镜I11、探针I12,从而形成入射光路,所述激光束照射到样品15表面产生的反射光依次经探针I12、原子力显微镜I11、透镜台10、凸透镜II9、分束器8,从而形成反射光路,所述反射光被分束器8偏转至所述光桥探测器20,所述透镜台10为透光圆盘且具有中心轴,所述原子力显微镜I11、透镜座13、原子力显微镜II27分别位于透镜台10下面、且均能够相对于透镜台10的位置微调,当透镜台10绕其中心轴转动时,能够分别将原子力显微镜I11或透镜座13或原子力显微镜II27置于样品15正上方,所述探针II28为接触型原子力显微镜探针,波导16位于样品台17上,通过磁控溅射方法将样品15直接接触地制备于波导16上表面,所述探针I12和探针II28为相同外形尺寸的原子力显微镜探针、且外形均为圆台,所述圆台轴线垂直于水平面,所述探针I12中具有圆台形通孔;所述探针I12和探针II28的所述外形圆台的上底面直径为3微米、下底面直径为2微米,所述探针I12中的所述圆台形通孔的上部开口直径为500纳米、下部开口直径为900纳米,所述透镜台10直径为十厘米;所述波导16长为80微米、宽为50微米、厚度为150纳米,特征阻抗为50欧姆;所述样品15长为10微米、宽为9微米、厚度为50纳米。The measuring device mainly includes a pulsed laser 1, a delay device 2, a quarter wave plate 3, a concave lens 4, a convex lens I5, a plane mirror 6, a polarizer 7, a beam splitter 8, a convex lens II9, a lens stage 10, an atomic force microscope I11, a probe Needle I12, Lens Holder 13, Objective Lens 14, Sample 15, Waveguide 16, Sample Stage 17, Signal Generator 18, Oscilloscope 19, Optical Bridge Detector 20, Bias Tee 21, Amplifier I22, Mixer 23, Amplifier II24 , analog-to-digital converter 25, computer 26, atomic force microscope II27, probe II28, phase sensitive detector, sinusoidal signal generator, incident light path and reflected light path, the input end of the optical bridge detector 20 has a 45-degree angle Polarizer, the atomic force microscope II27 has the same structure as the atomic force microscope I11, the probe I12 is located at the lower end of the atomic force microscope I11, the probe II28 is located at the lower end of the atomic force microscope II27, the objective lens 14 is located at the lower end of the lens holder 13, the pulse The laser 1, the signal generator 18, the waveguide 16, and the oscilloscope 19 are connected by cables in sequence. The optical bridge detector 20, the bias tee 21, the amplifier I22, the mixer 23, the amplifier II24, the analog-to-digital converter 25, and the computer 26 The cables are connected in sequence, and the laser beam emitted by the pulsed laser 1 passes through the delay device 2, the 1/4 wave plate 3, the concave lens 4, the convex lens I5, the plane mirror 6, the polarizer 7, the beam splitter 8, the convex lens II9, and the lens stage. 10. Atomic force microscope I11 and probe I12, thereby forming an incident light path, and the reflected light generated by the laser beam irradiating the surface of the sample 15 passes through the probe I12, the atomic force microscope I11, the lens stage 10, the convex lens II9, and the beam splitter 8 in sequence, Thus, a reflected light path is formed, the reflected light is deflected by the beam splitter 8 to the optical bridge detector 20, the lens stage 10 is a light-transmitting disc and has a central axis, the atomic force microscope I11, the lens holder 13, the atomic force The microscope II27 is located under the lens stage 10, and can be fine-tuned relative to the position of the lens stage 10. When the lens stage 10 is rotated around its central axis, the atomic force microscope I11 or the lens holder 13 or the atomic force microscope II27 can be placed on the sample 15 respectively. Right above, the probe II28 is a contact-type atomic force microscope probe, the waveguide 16 is located on the sample stage 17, and the sample 15 is prepared directly on the upper surface of the waveguide 16 by magnetron sputtering. The needle II28 is an atomic force microscope probe with the same external dimensions, and the external shape is a circular truncated cone, the axis of the circular truncated cone is perpendicular to the horizontal plane, and the probe I12 has a circular truncated through hole; the probe I12 and the probe II28 have the The diameter of the upper bottom surface of the outer frustum is 3 micrometers, the diameter of the lower bottom surface is 2 micrometers, the diameter of the upper opening of the frustum-shaped through hole in the probe I12 is 500 nanometers, and the diameter of the lower opening is 900 nanometers, and the lens stage 10 The diameter is ten centimeters; the length of the waveguide 16 is 80 microns, the width is 50 microns, the thickness is 150 nanometers, and the characteristic impedance is 5 0 ohm; the sample 15 is 10 microns long, 9 microns wide, and 50 nanometers thick.

所述光桥探测器20输出端与一个相敏检测器输入端相连,所述相敏检测器的参考频率设置为与所述信号发生器18的输出频率一致,相敏检测器输出端连接偏置三通,正弦信号发生器输出端连接混频器输入端II。所述光桥探测器20的输入端具有一个45度角的偏振器,反射光经过所述偏振器后光强为

Figure GSB0000188053060000061
其中I0是反射光到达所述偏振器时的光强,θk是克尔角。所述混频器23具有输入端I和输入端II的两个信号输入端。当反射光强对样品磁化的依赖关系是线性的,能够估计光桥探测器20中的由样品磁化导致的电流的交流分量δI≈IDCθK0δmz,其中θK0是样品在磁化饱和条件下的克尔角,δmz是面外磁化的变化,IDC是光桥探测器中的电流的直流分量。The output end of the optical bridge detector 20 is connected to the input end of a phase sensitive detector, the reference frequency of the phase sensitive detector is set to be consistent with the output frequency of the signal generator 18, and the output end of the phase sensitive detector is connected to the offset. Set the tee, and the output terminal of the sine signal generator is connected to the input terminal II of the mixer. The input end of the optical bridge detector 20 has a polarizer with an angle of 45 degrees. After the reflected light passes through the polarizer, the light intensity is
Figure GSB0000188053060000061
where I 0 is the light intensity of the reflected light when it reaches the polarizer, and θ k is the Kerr angle. The mixer 23 has two signal input terminals, input terminal I and input terminal II. When the dependence of the reflected light intensity on the sample magnetization is linear, it is possible to estimate the AC component of the current in the optical bridge detector 20 caused by the sample magnetization δI≈I DC θ K0 δm z , where θ K0 is the sample at the magnetization saturation condition The Kerr angle below, δm z is the change in out-of-plane magnetization, and I DC is the DC component of the current in the optical bridge detector.

所述一种纳米尺度磁化动态的测量方法的步骤如下:The steps of the method for measuring the nanoscale magnetization dynamics are as follows:

一.旋转透镜台10使得原子力显微镜II27位于样品15正上方,采用探针II28对波导16上包含样品15的区域进行扫描,以获得表面形貌图像,初步确定样品位置,当探针II28位于样品15边缘时,令探针II28缩回,并记录原子力显微镜II27中各位置参数;1. Rotate the lens stage 10 so that the atomic force microscope II27 is located directly above the sample 15, use the probe II28 to scan the area containing the sample 15 on the waveguide 16 to obtain a surface topography image, and preliminarily determine the position of the sample. When the probe II28 is located at the sample When the edge is 15, retract the probe II28, and record the position parameters of the atomic force microscope II27;

二.旋转透镜台10使得原子力显微镜I11位于样品15正上方,将步骤一中记录的各位置参数输入原子力显微镜I11;2. Rotate the lens stage 10 so that the atomic force microscope I11 is directly above the sample 15, and input the position parameters recorded in the step 1 into the atomic force microscope I11;

三.将探针I12向样品15表面逼近,然后采用探针I12对样品15所在区域进行扫描,扫描速度2nm/s,一旦探测到样品表面后即停止逼近,并向上回缩距离100nm,同时关闭原子力显微镜I11的扫描反馈;3. Approach the surface of the sample 15 with the probe I12, and then use the probe I12 to scan the area where the sample 15 is located at a scanning speed of 2 nm/s. Once the surface of the sample is detected, the approach is stopped, and the distance is retracted upward by 100 nm, and the Scanning feedback of AFM I11;

四.调整平面镜6位置,使得激光束通过透镜台10和原子力显微镜I11射到探针I12上:4. Adjust the position of the plane mirror 6 so that the laser beam passes through the lens stage 10 and the atomic force microscope I11 and hits the probe I12:

五.脉冲激光器1产生脉冲激光,周期小于100fs,重复率50MHz,波长700nm,信号发生器18的触发波形与激光重复率同步;5. The pulse laser 1 generates pulsed laser light, the period is less than 100fs, the repetition rate is 50MHz, the wavelength is 700nm, and the trigger waveform of the signal generator 18 is synchronized with the laser repetition rate;

六.信号发生器18产生频率f为1GHz的RF电流输出至波导16用于激发样品;6. The signal generator 18 generates an RF current with a frequency f of 1 GHz and outputs it to the waveguide 16 for exciting the sample;

七.在关闭原子力显微镜I11的扫描反馈的状态下,设置探针I12进行扫描;7. In the state of turning off the scanning feedback of the atomic force microscope I11, set the probe I12 to scan;

八.从样品15表面反射的光束依次经过探针I12、原子力显微镜I11、透镜台10、凸透镜II9、分束器8后进入光桥探测器20,所述相敏检测器将进入光桥探测器20的信号中的1GHz频率的极向克尔信号分离出来,并以电流形式输出;8. The light beam reflected from the surface of the sample 15 passes through the probe I12, the atomic force microscope I11, the lens stage 10, the convex lens II9, and the beam splitter 8 in sequence, and then enters the optical bridge detector 20, and the phase-sensitive detector will enter the optical bridge detector. The polar Kerr signal of 1GHz frequency in the signal of 20 is separated and output in the form of current;

九.所述相敏检测器输出的电流的交流分量经过放大器I22放大30dB后,输入混频器23的输入端I;9. After the AC component of the current output by the phase sensitive detector is amplified by 30dB through the amplifier I22, it is input to the input end I of the mixer 23;

十.所述正弦信号发生器锁频至信号发生器18,产生频率为f-Δf的参考信号,Δf=3KHz,所述参考信号输入混频器23的输入端II;10. The sinusoidal signal generator is frequency-locked to the signal generator 18 to generate a reference signal with a frequency of f-Δf, Δf = 3KHz, and the reference signal is input to the input terminal II of the mixer 23;

十一.混频器23输出的混频信号频率为Δf,所述混频信号被放大器II24继续放大,最终由模数转换器25进行采样;11. The frequency of the mixed signal output by the mixer 23 is Δf, and the mixed signal is continuously amplified by the amplifier II24, and finally sampled by the analog-to-digital converter 25;

十二.计算机26记录由模数转换器25输出的信号,并在Δf频率对该信号实施快速傅里叶变换,并与原子力显微镜I11采集的样品位置数据相关联,从而得到样品表面的磁共振图像。12. The computer 26 records the signal output by the analog-to-digital converter 25, performs fast Fourier transform on the signal at the Δf frequency, and correlates it with the sample position data collected by the atomic force microscope I11, thereby obtaining the magnetic resonance of the sample surface image.

测量装置采用高精度的定位装置来获得纳米尺度样品表面的磁化信息,即采用两个不同的原子力显微镜针尖分别进行接触模式原子力显微镜扫描以及近场时间分辨磁光克尔效应实验,并采用频域方法来探测样品表面GHz频段的磁化动态,具有较高空间灵敏度,较快的测试速度,装置结构简单,探针使用寿命长。本发明能够对单个纳米结构进行测量,对样品表面的磁化动态的测量能达到亚微米量级的空间分辨率,具有较高空间灵敏度,装置简单,测试速度快。The measurement device uses a high-precision positioning device to obtain the magnetization information of the nanoscale sample surface, that is, two different atomic force microscope tips are used to conduct contact mode atomic force microscope scanning and near-field time-resolved magneto-optical Kerr effect experiments, and use frequency domain. The method to detect the magnetization dynamics of the sample surface in the GHz frequency band has the advantages of higher spatial sensitivity, faster testing speed, simple device structure and long service life of the probe. The invention can measure a single nanostructure, and can measure the magnetization dynamics of the sample surface to reach the spatial resolution of sub-micron level, has high spatial sensitivity, simple device and fast test speed.

Claims (1)

1.一种纳米尺度磁化动态的测量方法,测量装置主要包括脉冲激光器、延时器、1/4波片、凹透镜、凸透镜I、平面镜、偏振片、分束器、凸透镜II、透镜台、原子力显微镜I、探针I、透镜座、物镜、样品、波导、样品台、信号发生器、示波器、光桥探测器、偏置三通、放大器I、混频器、放大器II、模数转换器、计算机、原子力显微镜II、探针II、相敏检测器、正弦信号发生器、入射光路及反射光路,所述光桥探测器的输入端具有一个45度角的偏振器,所述混频器具有输入端I和输入端II,所述原子力显微镜II与原子力显微镜I结构相同,所述探针I位于原子力显微镜I下端,所述探针II位于原子力显微镜II下端,所述物镜位于透镜座下端,所述脉冲激光器、信号发生器、波导、示波器依次电缆连接,所述光桥探测器、偏置三通、放大器I、混频器、放大器II、模数转换器、计算机依次电缆连接,所述脉冲激光器发射的激光束依次经延时器、1/4波片、凹透镜、凸透镜I、平面镜、偏振片、分束器、凸透镜II、透镜台、原子力显微镜I、探针I,从而形成入射光路,所述激光束照射到样品表面产生的反射光依次经探针I、原子力显微镜I、透镜台、凸透镜II、分束器,从而形成反射光路,所述反射光被分束器偏转至所述光桥探测器,所述透镜台为透光圆盘且具有中心轴,所述原子力显微镜I、透镜座、原子力显微镜II分别位于透镜台下面、且均能够相对于透镜台的位置微调,当透镜台绕其中心轴转动时,能够分别将原子力显微镜I或透镜座或原子力显微镜II置于样品正上方,所述探针II为接触型原子力显微镜探针,波导位于样品台上,通过磁控溅射方法将样品直接接触地制备于波导上表面,所述探针I和探针II为相同外形尺寸的原子力显微镜探针、且外形均为圆台,所述圆台轴线垂直于水平面,所述探针I中具有圆台形通孔,所述探针I和探针II的所述外形圆台的上底面直径为3微米、下底面直径为2微米,所述探针I中的所述圆台形通孔的上部开口直径为500纳米、下部开口直径为900纳米,所述透镜台直径为十厘米,所述波导长为80微米、宽为50微米、厚度为150纳米,特征阻抗为50欧姆,所述样品长为10微米、宽为9微米、厚度为50纳米,所述光桥探测器输出端与相敏检测器输入端相连,所述相敏检测器的参考频率设置为与所述信号发生器的输出频率一致,相敏检测器输出端连接偏置三通,正弦信号发生器输出端连接混频器输入端II,反射光经过所述偏振器后光强为
Figure FSB0000188053050000011
其中I0是反射光到达所述偏振器时的光强,θk是克尔角,当反射光强对样品磁化的依赖关系是线性的,能够估计光桥探测器中的由样品磁化导致的电流的交流分量δI≈IDCθK0δmz,其中θK0是样品在磁化饱和条件下的克尔角,δmz是面外磁化的变化,IDC是光桥探测器中的电流的直流分量,
1. A method for measuring nanoscale magnetization dynamics, the measuring device mainly includes a pulsed laser, a delay device, a 1/4 wave plate, a concave lens, a convex lens I, a plane mirror, a polarizer, a beam splitter, a convex lens II, a lens stage, an atomic force Microscope I, Probe I, Lens Holder, Objective Lens, Sample, Waveguide, Sample Stage, Signal Generator, Oscilloscope, Optical Bridge Detector, Bias Tee, Amplifier I, Mixer, Amplifier II, A/D Converter, Computer, atomic force microscope II, probe II, phase sensitive detector, sinusoidal signal generator, incident light path and reflected light path, the input end of the optical bridge detector has a polarizer with an angle of 45 degrees, and the mixer has Input end I and input end II, the atomic force microscope II has the same structure as the atomic force microscope I, the probe I is located at the lower end of the atomic force microscope I, the probe II is located at the lower end of the atomic force microscope II, the objective lens is located at the lower end of the lens seat, The pulsed laser, the signal generator, the waveguide, and the oscilloscope are connected by cables in sequence, and the optical bridge detector, bias tee, amplifier I, mixer, amplifier II, analog-to-digital converter, and computer are connected by cables in sequence. The laser beam emitted by the pulsed laser passes through the delayer, 1/4 wave plate, concave lens, convex lens I, plane mirror, polarizer, beam splitter, convex lens II, lens stage, atomic force microscope I, and probe I in turn to form an incident optical path. , the reflected light generated by the laser beam irradiating the sample surface passes through the probe I, the atomic force microscope I, the lens stage, the convex lens II, and the beam splitter in sequence to form a reflected light path, and the reflected light is deflected by the beam splitter to the Optical bridge detector, the lens stage is a light-transmitting disc and has a central axis, the AFM I, the lens holder, and the AFM II are respectively located under the lens stage, and can be fine-tuned relative to the position of the lens stage, when the lens When the stage rotates around its central axis, the AFM I or the lens holder or the AFM II can be placed directly above the sample, respectively. The probe II is a contact-type AFM probe, and the waveguide is located on the sample stage. The sample is prepared in direct contact with the upper surface of the waveguide, the probe I and the probe II are atomic force microscope probes with the same external dimensions, and the shapes are both circular truncated cones, the axis of the circular truncated cone is perpendicular to the horizontal plane, and the probes There is a frustum-shaped through hole in the probe I and the outer frustum of the probe I and the probe II. The diameter of the upper bottom surface is 3 microns, and the diameter of the lower bottom surface is 2 microns. The frustum shaped through hole in the probe I The diameter of the upper opening is 500 nanometers, the diameter of the lower opening is 900 nanometers, the diameter of the lens stage is ten centimeters, the length of the waveguide is 80 micrometers, the width is 50 micrometers, the thickness is 150 nanometers, and the characteristic impedance is 50 ohms. The length of the sample is 10 microns, the width is 9 microns, and the thickness is 50 nanometers. The output end of the optical bridge detector is connected to the input end of the phase-sensitive detector, and the reference frequency of the phase-sensitive detector is set to be the same as that of the signal generator. The output frequency of the phase sensitive detector is the same, the output end of the phase sensitive detector is connected to the bias tee, the output end of the sine signal generator is connected to the input end II of the mixer, and the reflected light passes through the bias tee. The light intensity after the vibrator is
Figure FSB0000188053050000011
where I 0 is the light intensity of the reflected light when it reaches the polarizer, and θ k is the Kerr angle. When the dependence of the reflected light intensity on the sample magnetization is linear, it is possible to estimate the optical bridge detector caused by the sample magnetization. The AC component of the current δI≈I DC θ K0 δm z , where θ K0 is the Kerr angle of the sample at magnetization saturation, δm z is the change in out-of-plane magnetization, and I DC is the DC component of the current in the optical bridge detector ,
其特征是,所述一种纳米尺度磁化动态的测量方法的步骤如下:It is characterized in that, the steps of the method for measuring the nanoscale magnetization dynamics are as follows: 一.旋转透镜台使得原子力显微镜II位于样品正上方,采用探针II对波导上包含样品的区域进行扫描,以获得表面形貌图像,初步确定样品位置,当探针II位于样品边缘时,令探针II缩回,并记录原子力显微镜II中各位置参数;1. Rotate the lens stage so that the atomic force microscope II is directly above the sample, and use the probe II to scan the area containing the sample on the waveguide to obtain the surface topography image, and preliminarily determine the position of the sample. When the probe II is located at the edge of the sample, let The probe II is retracted, and the position parameters of the atomic force microscope II are recorded; 二.旋转透镜台使得原子力显微镜I位于样品正上方,将步骤一中记录的各位置参数输入原子力显微镜I;2. Rotating the lens stage makes atomic force microscope 1 be positioned directly above the sample, and input each position parameter recorded in step 1 into atomic force microscope 1; 三.将探针I向样品表面逼近,然后采用探针I对样品所在区域进行扫描,扫描速度2nm/s,一旦探测到样品表面后即停止逼近,并向上回缩距离100nm,同时关闭原子力显微镜I的扫描反馈;3. Approach probe I to the surface of the sample, and then use probe I to scan the area where the sample is located at a scanning speed of 2 nm/s. Once the surface of the sample is detected, the approach is stopped, and the distance is retracted upwards by 100 nm, and the atomic force microscope is turned off at the same time. I scan feedback; 四.调整平面镜位置,使得激光束通过透镜台和原子力显微镜I射到探针I上;4. Adjust the plane mirror position so that the laser beam is projected onto the probe 1 through the lens stage and the atomic force microscope 1; 五.脉冲激光器产生脉冲激光,周期小于100fs,重复率50MHz,波长700nm,信号发生器的触发波形与激光重复率同步;5. The pulse laser generates pulsed laser, the period is less than 100fs, the repetition rate is 50MHz, the wavelength is 700nm, and the trigger waveform of the signal generator is synchronized with the laser repetition rate; 六.信号发生器产生频率f为1GHz的RF电流输出至波导用于激发样品;6. The signal generator generates an RF current with a frequency f of 1GHz and outputs it to the waveguide for exciting the sample; 七.在关闭原子力显微镜I的扫描反馈的状态下,设置探针I进行扫描;7. In the state of turning off the scanning feedback of the atomic force microscope 1, set the probe 1 to scan; 八.从样品表面反射的光束依次经过探针I、原子力显微镜I、透镜台、凸透镜II、分束器后进入光桥探测器,所述相敏检测器将进入光桥探测器的信号中的1GHz频率的极向克尔信号分离出来,并以电流形式输出;8. The light beam reflected from the sample surface passes through the probe I, atomic force microscope I, lens stage, convex lens II, and beam splitter in sequence and then enters the optical bridge detector, and the phase-sensitive detector will enter the signal of the optical bridge detector. The polar Kerr signal of 1GHz frequency is separated and output in the form of current; 九.所述相敏检测器输出的电流的交流分量经过放大器I放大30dB后,输入混频器的输入端I;9. After the AC component of the current output by the phase sensitive detector is amplified by 30dB through the amplifier I, it is input to the input end I of the mixer; 十.所述正弦信号发生器锁频至信号发生器,产生频率为f-Δf的参考信号,Δf=3KHz,所述参考信号输入混频器的输入端II;10. The sinusoidal signal generator is frequency-locked to the signal generator to generate a reference signal with a frequency of f-Δf, Δf = 3KHz, and the reference signal is input to the input terminal II of the mixer; 十一.混频器输出的混频信号频率为Δf,所述混频信号被放大器II继续放大,最终由模数转换器进行采样;11. The frequency of the mixing signal output by the mixer is Δf, the mixing signal is continuously amplified by the amplifier II, and finally sampled by the analog-to-digital converter; 十二.计算机记录由模数转换器输出的信号,并在Δf频率对该信号实施快速傅里叶变换,并与原子力显微镜I采集的样品位置数据相关联,从而得到样品表面的磁共振图像。12. The computer records the signal output by the analog-to-digital converter, performs fast Fourier transform on the signal at the Δf frequency, and correlates it with the sample position data collected by the atomic force microscope 1, thereby obtaining a magnetic resonance image of the sample surface.
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