CN108531089A - A kind of special adhesive of environment friendly decorative material and preparation method thereof - Google Patents
A kind of special adhesive of environment friendly decorative material and preparation method thereof Download PDFInfo
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- CN108531089A CN108531089A CN201810425105.XA CN201810425105A CN108531089A CN 108531089 A CN108531089 A CN 108531089A CN 201810425105 A CN201810425105 A CN 201810425105A CN 108531089 A CN108531089 A CN 108531089A
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- environment friendly
- decorative material
- friendly decorative
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
Abstract
The invention discloses special adhesives of a kind of environment friendly decorative material and preparation method thereof.The special adhesive of environment friendly decorative material includes the raw material of following parts by weight：20 25 parts of polyvinyl alcohol, 6 15 parts of sodium hypochlorite, 8 15 parts of tributyl 2-acetylcitrate, 6 17 parts of maleic anhydride modified rosin glycerides, 6 10 parts of lignin, 58 parts of benzisothia oxazolone, 8 12 parts of butyl acrylate, 6 12 parts of toluene di-isocyanate(TDI), 4 10 parts of manganese naphthenate.The advantages of special adhesive of environment friendly decorative material of the present invention has toxicity low, and using effect is good, heat resistance, water-tolerant, excellent storage stability；Preparation method is simple, is conducive to produce, and product quality is high, is worthy to be popularized.
Description
Technical field
The present invention relates to a kind of adhesive, specifically a kind of special adhesive of environment friendly decorative material and preparation method thereof.
Background technology
As the improvement of people's living standards, while being increasingly particular about to quality of the life, more focus on environmental protection and health, body
It is now higher and higher to the decoration demand of living environment.Thus modern finishing theory to be not only satisfied with decoration beauty relax
Clothes, also require that ornament materials is nuisanceless, health environment-friendly.
At present, it is bonded the adhesive extensive use of ornament materials.Neoprene class adhesive with based on SBS
Adhesive be in main Types.Wherein neoprene adhesive characteristic is：Initial viscous force is big, adhesive strength is high, durability is good,
Glue-line is flexible, and elasticity is good, and impact resistance and vibration have preferable oil resistant, water-fast, alkaline-resisting, acidproof, solvent resistance, to a variety of
Material has preferable cementability, easy to use, cheap.But that there are heat resistances is poor for it, and water resistance is bad, and toxicity is big,
The shortcomings of bin stability is poor.Therefore, a kind of special adhesive of environment friendly decorative material of present invention offer and preparation method thereof.
Invention content
It is above-mentioned to solve the purpose of the present invention is to provide special adhesive of a kind of environment friendly decorative material and preparation method thereof
The problem of being proposed in background technology.
To achieve the above object, the present invention provides the following technical solutions：
A kind of special adhesive of environment friendly decorative material, the special adhesive of environment friendly decorative material include the original of following parts by weight
Material：20-25 parts of polyvinyl alcohol, 6-15 parts of sodium hypochlorite, 8-15 parts of tributyl 2-acetylcitrate, maleic anhydride modified rosin glycerine
6-17 parts of ester, 6-10 parts of lignin, 5-8 parts of benzisothia oxazolone, 8-12 parts of butyl acrylate, toluene di-isocyanate(TDI) 6-12
Part, 4-10 parts of manganese naphthenate.
As a further solution of the present invention：The special adhesive of environment friendly decorative material includes the original of following parts by weight
Material：22-24 parts of polyvinyl alcohol, 8-13 parts of sodium hypochlorite, 9-13 parts of tributyl 2-acetylcitrate, maleic anhydride modified rosin glycerine
8-15 parts of ester, 7-9 parts of lignin, 6-8 parts of benzisothia oxazolone, 9-11 parts of butyl acrylate, 7-10 parts of toluene di-isocyanate(TDI),
6-8 parts of manganese naphthenate.
As a further solution of the present invention：The special adhesive of environment friendly decorative material includes the original of following parts by weight
Material：23 parts of polyvinyl alcohol, 10 parts of sodium hypochlorite, 10 parts of tributyl 2-acetylcitrate, 12 parts of maleic anhydride modified rosin glycerides,
8 parts of lignin, 7 parts of benzisothia oxazolone, 10 parts of butyl acrylate, 9 parts of toluene di-isocyanate(TDI), 7 parts of manganese naphthenate.
A kind of preparation method of the special adhesive of environment friendly decorative material, includes the following steps：
（1）It is sweet that polyvinyl alcohol, sodium hypochlorite, tributyl 2-acetylcitrate, maleic anhydride modified rosin are weighed according to above-mentioned formula
Grease, lignin, benzisothia oxazolone, butyl acrylate, toluene di-isocyanate(TDI) and manganese naphthenate；
（2）Polyvinyl alcohol, sodium hypochlorite and tributyl 2-acetylcitrate are mixed, 20-40min is stirred to react at 85-95 DEG C；
（3）Maleic anhydride modified rosin glycerides, lignin and benzisothia oxazolone are mixed, are stirred to react at 55-75 DEG C
20-30min；
（4）Butyl acrylate, toluene di-isocyanate(TDI) and manganese naphthenate are mixed, 10-20min is stirred to react at 40-55 DEG C；
（5）By step（2）Gains and step（3）Gains, step（4）Gains mix, and 1- is stirred to react at 30-35 DEG C
2h to get.
As a further solution of the present invention：Step（2）Polyvinyl alcohol, sodium hypochlorite and tributyl 2-acetylcitrate are mixed
It closes, 30min is stirred to react at 90 DEG C.
As a further solution of the present invention：Step（3）By maleic anhydride modified rosin glycerides, lignin and benzisoxa
Thiazolone mixes, and 25min is stirred to react at 65 DEG C.
As a further solution of the present invention：Step（4）Butyl acrylate, toluene di-isocyanate(TDI) and manganese naphthenate are mixed
It closes, 16min is stirred to react at 45 DEG C.
As a further solution of the present invention：Step（5）By step（2）Gains, step（3）Gains and step（4）
Gains mix, be stirred to react at 32 DEG C 1.4h to get.
Compared with prior art, the beneficial effects of the invention are as follows：
The special adhesive of environment friendly decorative material of the present invention passes through polyvinyl alcohol, sodium hypochlorite, tributyl 2-acetylcitrate, Malaysia
Anhydride modified rosin glycerides, lignin, benzisothia oxazolone, butyl acrylate, toluene di-isocyanate(TDI) and manganese naphthenate system
Standby to form, the adhesive toxicity being prepared is low, using effect is good, heat resistance, water-tolerant, excellent storage stability；Preparation side
Method is simple, is conducive to produce, and product quality is high, is worthy to be popularized.
Specific implementation mode
The technical solution of this patent is described in more detail With reference to embodiment.
Embodiment 1
A kind of special adhesive of environment friendly decorative material, the special adhesive of environment friendly decorative material include the original of following parts by weight
Material：20 parts of polyvinyl alcohol, 6 parts of sodium hypochlorite, 8 parts of tributyl 2-acetylcitrate, 6 parts of maleic anhydride modified rosin glycerides, wood
6 parts of quality, 5 parts of benzisothia oxazolone, 8 parts of butyl acrylate, 6 parts of toluene di-isocyanate(TDI), 4 parts of manganese naphthenate.
A kind of preparation method of the special adhesive of environment friendly decorative material, includes the following steps：（1）It is weighed according to above-mentioned formula
Polyvinyl alcohol, sodium hypochlorite, tributyl 2-acetylcitrate, maleic anhydride modified rosin glycerides, lignin, benzisothiazole
Ketone, butyl acrylate, toluene di-isocyanate(TDI) and manganese naphthenate；（2）By three fourth of polyvinyl alcohol, sodium hypochlorite and acetyl tributyl citrate
Ester mixes, and 20min is stirred to react at 85 DEG C；（3）By maleic anhydride modified rosin glycerides, lignin and benzisothia oxazolone
Mixing, 20min is stirred to react at 55 DEG C；（4）Butyl acrylate, toluene di-isocyanate(TDI) and manganese naphthenate are mixed, 40
10min is stirred to react at DEG C；（5）By step（2）Gains and step（3）Gains, step（4）Gains mix, at 30 DEG C
Under be stirred to react 1h to get.
Embodiment 2
A kind of special adhesive of environment friendly decorative material, the special adhesive of environment friendly decorative material include the original of following parts by weight
Material：25 parts of polyvinyl alcohol, 15 parts of sodium hypochlorite, 15 parts of tributyl 2-acetylcitrate, 17 parts of maleic anhydride modified rosin glycerides,
10 parts of lignin, 8 parts of benzisothia oxazolone, 12 parts of butyl acrylate, 12 parts of toluene di-isocyanate(TDI), 10 parts of manganese naphthenate.
A kind of preparation method of the special adhesive of environment friendly decorative material, includes the following steps：（1）It is weighed according to above-mentioned formula
Polyvinyl alcohol, sodium hypochlorite, tributyl 2-acetylcitrate, maleic anhydride modified rosin glycerides, lignin, benzisothiazole
Ketone, butyl acrylate, toluene di-isocyanate(TDI) and manganese naphthenate；（2）By three fourth of polyvinyl alcohol, sodium hypochlorite and acetyl tributyl citrate
Ester mixes, and 40min is stirred to react at 95 DEG C；（3）By maleic anhydride modified rosin glycerides, lignin and benzisothia oxazolone
Mixing, 30min is stirred to react at 75 DEG C；（4）Butyl acrylate, toluene di-isocyanate(TDI) and manganese naphthenate are mixed, 55
20min is stirred to react at DEG C；（5）By step（2）Gains and step（3）Gains, step（4）Gains mix, at 35 DEG C
Under be stirred to react 2h to get.
Embodiment 3
A kind of special adhesive of environment friendly decorative material, the special adhesive of environment friendly decorative material include the original of following parts by weight
Material：23 parts of polyvinyl alcohol, 10 parts of sodium hypochlorite, 10 parts of tributyl 2-acetylcitrate, 12 parts of maleic anhydride modified rosin glycerides,
8 parts of lignin, 7 parts of benzisothia oxazolone, 10 parts of butyl acrylate, 9 parts of toluene di-isocyanate(TDI), 7 parts of manganese naphthenate.
A kind of preparation method of the special adhesive of environment friendly decorative material, includes the following steps：（1）It is weighed according to above-mentioned formula
Polyvinyl alcohol, sodium hypochlorite, tributyl 2-acetylcitrate, maleic anhydride modified rosin glycerides, lignin, benzisothiazole
Ketone, butyl acrylate, toluene di-isocyanate(TDI) and manganese naphthenate；（2）By three fourth of polyvinyl alcohol, sodium hypochlorite and acetyl tributyl citrate
Ester mixes, and 30min is stirred to react at 90 DEG C.（3）By maleic anhydride modified rosin glycerides, lignin and benzisothia oxazolone
Mixing, 25min is stirred to react at 65 DEG C.（4）Butyl acrylate, toluene di-isocyanate(TDI) and manganese naphthenate are mixed, 45
16min is stirred to react at DEG C.（5）By step（2）Gains, step（3）Gains and step（4）Gains mix, at 32 DEG C
Under be stirred to react 1.4h to get.
Embodiment 4
A kind of special adhesive of environment friendly decorative material, the special adhesive of environment friendly decorative material include the original of following parts by weight
Material：22 parts of polyvinyl alcohol, 8 parts of sodium hypochlorite, 9 parts of tributyl 2-acetylcitrate, 8 parts of maleic anhydride modified rosin glycerides, wood
7 parts of quality, 6 parts of benzisothia oxazolone, 9 parts of butyl acrylate, 7 parts of toluene di-isocyanate(TDI), 6 parts of manganese naphthenate.
A kind of preparation method of the special adhesive of environment friendly decorative material, includes the following steps：（1）It is weighed according to above-mentioned formula
Polyvinyl alcohol, sodium hypochlorite, tributyl 2-acetylcitrate, maleic anhydride modified rosin glycerides, lignin, benzisothiazole
Ketone, butyl acrylate, toluene di-isocyanate(TDI) and manganese naphthenate；（2）By three fourth of polyvinyl alcohol, sodium hypochlorite and acetyl tributyl citrate
Ester mixes, and 22min is stirred to react at 88 DEG C；（3）By maleic anhydride modified rosin glycerides, lignin and benzisothia oxazolone
Mixing, 24min is stirred to react at 58 DEG C；（4）Butyl acrylate, toluene di-isocyanate(TDI) and manganese naphthenate are mixed, 48
12min is stirred to react at DEG C；（5）By step（2）Gains and step（3）Gains, step（4）Gains mix, at 31 DEG C
Under be stirred to react 1.2h to get.
Embodiment 5
A kind of special adhesive of environment friendly decorative material, the special adhesive of environment friendly decorative material include the original of following parts by weight
Material：24 parts of polyvinyl alcohol, 13 parts of sodium hypochlorite, 13 parts of tributyl 2-acetylcitrate, 15 parts of maleic anhydride modified rosin glycerides,
9 parts of lignin, 8 parts of benzisothia oxazolone, 11 parts of butyl acrylate, 10 parts of toluene di-isocyanate(TDI), 8 parts of manganese naphthenate.
A kind of preparation method of the special adhesive of environment friendly decorative material, includes the following steps：（1）It is weighed according to above-mentioned formula
Polyvinyl alcohol, sodium hypochlorite, tributyl 2-acetylcitrate, maleic anhydride modified rosin glycerides, lignin, benzisothiazole
Ketone, butyl acrylate, toluene di-isocyanate(TDI) and manganese naphthenate；（2）By three fourth of polyvinyl alcohol, sodium hypochlorite and acetyl tributyl citrate
Ester mixes, and 35min is stirred to react at 92 DEG C；（3）By maleic anhydride modified rosin glycerides, lignin and benzisothia oxazolone
Mixing, 26min is stirred to react at 70 DEG C；（4）Butyl acrylate, toluene di-isocyanate(TDI) and manganese naphthenate are mixed, 52
17min is stirred to react at DEG C；（5）By step（2）Gains and step（3）Gains, step（4）Gains mix, at 33 DEG C
Under be stirred to react 1.7h to get.
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party
Formula, one skilled in the relevant art within the scope of knowledge, can also be under the premise of not departing from this patent objective
Various changes can be made.
Claims (8)
1. a kind of special adhesive of environment friendly decorative material, which is characterized in that the special adhesive of environment friendly decorative material include with
The raw material of lower parts by weight：20-25 parts of polyvinyl alcohol, 6-15 parts of sodium hypochlorite, 8-15 parts of tributyl 2-acetylcitrate, maleic acid
6-17 parts of anhydride modification rosin glycerides, 6-10 parts of lignin, 5-8 parts of benzisothia oxazolone, 8-12 parts of butyl acrylate, toluene two
6-12 parts of isocyanates, 4-10 parts of manganese naphthenate.
2. the special adhesive of environment friendly decorative material according to claim 1, which is characterized in that the environment friendly decorative material is special
Include the raw material of following parts by weight with adhesive：22-24 parts of polyvinyl alcohol, 8-13 parts of sodium hypochlorite, three fourth of acetyl tributyl citrate
9-13 parts of ester, rosin glycerides 8-15 parts maleic anhydride modified, 7-9 parts of lignin, 6-8 parts of benzisothia oxazolone, acrylic acid fourth
9-11 parts of ester, 7-10 parts of toluene di-isocyanate(TDI), 6-8 parts of manganese naphthenate.
3. the special adhesive of environment friendly decorative material according to claim 1, which is characterized in that the environment friendly decorative material is special
Include the raw material of following parts by weight with adhesive：23 parts of polyvinyl alcohol, 10 parts of sodium hypochlorite, tributyl 2-acetylcitrate 10
Part, 12 parts of maleic anhydride modified rosin glycerides, 8 parts of lignin, 7 parts of benzisothia oxazolone, 10 parts of butyl acrylate, toluene two
9 parts of isocyanates, 7 parts of manganese naphthenate.
4. a kind of preparation method according to any special adhesives of environment friendly decorative material of claim 1-3, feature exists
In including the following steps：
（1）It is sweet that polyvinyl alcohol, sodium hypochlorite, tributyl 2-acetylcitrate, maleic anhydride modified rosin are weighed according to above-mentioned formula
Grease, lignin, benzisothia oxazolone, butyl acrylate, toluene di-isocyanate(TDI) and manganese naphthenate；
（2）Polyvinyl alcohol, sodium hypochlorite and tributyl 2-acetylcitrate are mixed, 20-40min is stirred to react at 85-95 DEG C；
（3）Maleic anhydride modified rosin glycerides, lignin and benzisothia oxazolone are mixed, are stirred to react at 55-75 DEG C
20-30min；
（4）Butyl acrylate, toluene di-isocyanate(TDI) and manganese naphthenate are mixed, 10-20min is stirred to react at 40-55 DEG C；
（5）By step（2）Gains and step（3）Gains, step（4）Gains mix, and 1- is stirred to react at 30-35 DEG C
2h to get.
5. the preparation method of the special adhesive of environment friendly decorative material according to claim 4, which is characterized in that step（2）
Polyvinyl alcohol, sodium hypochlorite and tributyl 2-acetylcitrate are mixed, 30min is stirred to react at 90 DEG C.
6. the preparation method of the special adhesive of environment friendly decorative material according to claim 4, which is characterized in that step（3）
Maleic anhydride modified rosin glycerides, lignin and benzisothia oxazolone are mixed, 25min is stirred to react at 65 DEG C.
7. the preparation method of the special adhesive of environment friendly decorative material according to claim 4, which is characterized in that step（4）
Butyl acrylate, toluene di-isocyanate(TDI) and manganese naphthenate are mixed, 16min is stirred to react at 45 DEG C.
8. the preparation method of the special adhesive of environment friendly decorative material according to claim 4, which is characterized in that step（5）
By step（2）Gains, step（3）Gains and step（4）Gains mix, be stirred to react at 32 DEG C 1.4h to get.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201810425105.XA CN108531089A (en) | 2018-05-07 | 2018-05-07 | A kind of special adhesive of environment friendly decorative material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810425105.XA CN108531089A (en) | 2018-05-07 | 2018-05-07 | A kind of special adhesive of environment friendly decorative material and preparation method thereof |
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| CN108531089A true CN108531089A (en) | 2018-09-14 |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50158651A (en) * | 1974-06-14 | 1975-12-22 | ||
| CN103788911A (en) * | 2014-02-20 | 2014-05-14 | 铜陵祥云消防科技有限责任公司 | Environment-friendly adhesive containing modified nanometer bamboo charcoal powder |
| CN103897639A (en) * | 2014-04-03 | 2014-07-02 | 中山火炬职业技术学院 | Starch modified polyvinyl alcohol environment-friendly adhesive for buildings and preparation method of adhesive |
| CN105001822A (en) * | 2015-07-24 | 2015-10-28 | 南通康尔乐复合材料有限公司 | Adhesive |
| CN105950070A (en) * | 2016-06-17 | 2016-09-21 | 枞阳县新天地高新材料有限公司 | Heat-resisting environment-friendly glue |
| CN106367015A (en) * | 2016-08-27 | 2017-02-01 | 苏州雅晟建筑装饰工程有限公司 | Water-proof high-strength adhesive and preparation method thereof |
| CN106590510A (en) * | 2016-12-23 | 2017-04-26 | 安庆市德诚化工有限公司 | Waterborne polyurethane adhesive used for preventing paper packaging box from degumming and preparation method for waterborne polyurethane adhesive |
-
2018
- 2018-05-07 CN CN201810425105.XA patent/CN108531089A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50158651A (en) * | 1974-06-14 | 1975-12-22 | ||
| CN103788911A (en) * | 2014-02-20 | 2014-05-14 | 铜陵祥云消防科技有限责任公司 | Environment-friendly adhesive containing modified nanometer bamboo charcoal powder |
| CN103897639A (en) * | 2014-04-03 | 2014-07-02 | 中山火炬职业技术学院 | Starch modified polyvinyl alcohol environment-friendly adhesive for buildings and preparation method of adhesive |
| CN105001822A (en) * | 2015-07-24 | 2015-10-28 | 南通康尔乐复合材料有限公司 | Adhesive |
| CN105950070A (en) * | 2016-06-17 | 2016-09-21 | 枞阳县新天地高新材料有限公司 | Heat-resisting environment-friendly glue |
| CN106367015A (en) * | 2016-08-27 | 2017-02-01 | 苏州雅晟建筑装饰工程有限公司 | Water-proof high-strength adhesive and preparation method thereof |
| CN106590510A (en) * | 2016-12-23 | 2017-04-26 | 安庆市德诚化工有限公司 | Waterborne polyurethane adhesive used for preventing paper packaging box from degumming and preparation method for waterborne polyurethane adhesive |
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Application publication date: 20180914 |