CN103788911A - Environment-friendly adhesive containing modified nanometer bamboo charcoal powder - Google Patents
Environment-friendly adhesive containing modified nanometer bamboo charcoal powder Download PDFInfo
- Publication number
- CN103788911A CN103788911A CN201410057025.5A CN201410057025A CN103788911A CN 103788911 A CN103788911 A CN 103788911A CN 201410057025 A CN201410057025 A CN 201410057025A CN 103788911 A CN103788911 A CN 103788911A
- Authority
- CN
- China
- Prior art keywords
- parts
- bamboo charcoal
- charcoal powder
- environment
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000843 powder Substances 0.000 title claims abstract description 44
- 235000017166 Bambusa arundinacea Nutrition 0.000 title claims abstract description 34
- 235000017491 Bambusa tulda Nutrition 0.000 title claims abstract description 34
- 241001330002 Bambuseae Species 0.000 title claims abstract description 34
- 235000015334 Phyllostachys viridis Nutrition 0.000 title claims abstract description 34
- 239000011425 bamboo Substances 0.000 title claims abstract description 34
- 239000003610 charcoal Substances 0.000 title claims abstract description 34
- 239000000853 adhesive Substances 0.000 title claims abstract description 19
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 19
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000010881 fly ash Substances 0.000 claims abstract description 16
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 12
- -1 phosphate ester Chemical class 0.000 claims abstract description 12
- KJHYAEZMOHLVCH-UHFFFAOYSA-N 2-ethyl-1-benzofuran Chemical compound C1=CC=C2OC(CC)=CC2=C1 KJHYAEZMOHLVCH-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004793 Polystyrene Substances 0.000 claims abstract description 11
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 11
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims abstract description 11
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920002223 polystyrene Polymers 0.000 claims abstract description 11
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 11
- 229920005989 resin Polymers 0.000 claims abstract description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000005058 Isophorone diisocyanate Substances 0.000 claims abstract description 8
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 6
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 6
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 6
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000006004 Quartz sand Substances 0.000 claims abstract description 3
- 239000010445 mica Substances 0.000 claims abstract description 3
- 239000000661 sodium alginate Substances 0.000 claims abstract description 3
- 229940005550 sodium alginate Drugs 0.000 claims abstract description 3
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 238000002360 preparation method Methods 0.000 claims description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- 229920013649 Paracril Polymers 0.000 claims description 10
- 239000010883 coal ash Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 claims description 5
- 150000004645 aluminates Chemical class 0.000 claims description 5
- 239000007822 coupling agent Substances 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 5
- 238000009775 high-speed stirring Methods 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 238000004898 kneading Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 239000002105 nanoparticle Substances 0.000 claims description 5
- 238000012856 packing Methods 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 239000001069 triethyl citrate Substances 0.000 claims description 5
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 claims description 5
- 235000013769 triethyl citrate Nutrition 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000347 magnesium hydroxide Substances 0.000 claims description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 2
- 229920000459 Nitrile rubber Polymers 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 239000012975 dibutyltin dilaurate Substances 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- 239000005350 fused silica glass Substances 0.000 abstract 1
- 229920005610 lignin Polymers 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 238000004513 sizing Methods 0.000 description 8
- 235000012254 magnesium hydroxide Nutrition 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 235000010215 titanium dioxide Nutrition 0.000 description 4
- 239000003245 coal Substances 0.000 description 3
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 3
- 239000010453 quartz Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- XOGODJOZAUTXDH-UHFFFAOYSA-M (N-methylanilino)methanesulfonate Chemical compound CN(CS([O-])(=O)=O)c1ccccc1 XOGODJOZAUTXDH-UHFFFAOYSA-M 0.000 description 1
- 240000004859 Gamochaeta purpurea Species 0.000 description 1
- QKZIVVMOMKTVIK-UHFFFAOYSA-M anilinomethanesulfonate Chemical compound [O-]S(=O)(=O)CNC1=CC=CC=C1 QKZIVVMOMKTVIK-UHFFFAOYSA-M 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses an environment-friendly adhesive containing modified nanometer bamboo charcoal powder. The environment-friendly adhesive comprises the following components in parts by weight: 100-150 parts of polyvinyl alcohol resin, 50-80 parts of 2-ethylbenzofuran, 20-30 parts of dibutyl phthalate, 15-20 parts of polystyrene, 10-15 parts of ditolyl phosphate ester, 20-30 parts of isophorone diisocyanate, 5-10 parts of nitrile rubber, 10-15 parts of calcium carbonate, 5-8 parts of titanium dioxide, 5-20 parts of nanometer magnesium hydrate, 15-20 parts of modified nanometer bamboo charcoal powder, 10-15 parts of lignin, 3-5 parts of fused silica, 3-5 parts of sodium alginate, 20-30 parts of quartz sand, 1-3 parts of boron powder, 5-10 parts of windshield washer fluid, 0.7-0.9 parts of dibutyltin dilaurate, 2-4 parts of mica iron oxide, 1-3 parts of silane coupling agent and 10-15 parts of modified fly ash. The adhesive disclosed by the invention has the characteristics of high adhesive strength, no pollution, long storage life and the like, and is harmless to a human body, and environment-friendly.
Description
Technical field
The present invention relates to sizing agent technical field, relate in particular to a kind of environment-protective adhesive that contains modified Nano bamboo charcoal powder.
Background technology
Sizing agent is a kind of material that similar or inhomogeneous material can be closely linked.Along with the development of science and technology and national economy, tackiness agent has been widely used in every profession and trade and the high-tech areas such as wood working, construction work, textile printing and dyeing, shoemaking, leather, electronics, automobile, machinery, aerospace, biologic medical.
At present, in order to improve some performance of tackiness agent, in the sizing agent of being everlasting, add some properties-correcting agent, thickening material, tackifier, emulsifying agent etc., and in these materials, some is poisonous, some or even poison extremely, and most can produce environmental pollution.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide a kind of and have that water-tolerant, bonding strength are high, the sizing agent that contains modified Nano bamboo charcoal powder of environmentally safe,, environmental protection harmless to human body.
The present invention adopts following technical scheme to achieve these goals:
A kind of environment-protective adhesive that contains modified Nano bamboo charcoal powder, comprise the component of following weight part: polyvinyl alcohol resin 100-150 part, 2-ethyl benzofuran 50-80 part, neck phthalic acid dibutyl ester 20-30 part, polystyrene 15-20 part, xylyl phosphoric acid ester 10-15 part, isophorone diisocyanate 20-30 part, paracril 5-10 part, calcium carbonate 10-15 part, titanium dioxide 5-8 part, nano-sized magnesium hydroxide 5-20 part, modified Nano bamboo charcoal powder 15-20 part, xylogen 10-15 part, gas-phase silica 3-5 part, sodium alginate 3-5 part, quartz sand 20-30 part, boron powder 1-3 part, bath of glass 5-10 part, dibutyl tin laurate 0.7-0.9 part, iron mica 2-4 part, silane coupling agent 1-3 part, modified coal ash 10-15 part.
The preparation method of described modified Nano bamboo charcoal powder is: bamboo charcoal powder is soaked 5-8h with 10-15% sodium hydroxide solution, then use deionized water wash, dry, add again and be equivalent to 2,4,6 trisphenols of its weight 1-2%, the a-cyanacrylate of 1-3%, the crosslink agent DCP of 1-3%, 3000-5000 rev/min is stirred 30-50 minute, dry, grind to form nanometer powder.
Described modified coal ash is prepared by following steps: first flyash is dried in 100-110 ℃ of baking oven, then the flyash after drying is put into high-speed kneading machine, add and be equivalent to the aluminate coupling agent of flyash weight 3-5%, the wooden sodium sulfonate of 2-4%, triethyl citrate, the whiteruss of 1-2% and the talcum powder of 2-5% of 2-4%, after high-speed mixing, dry, pulverize and grind to form ultrafine powder.
The preparation method of the described environment-protective adhesive that contains modified Nano bamboo charcoal powder, comprises following preparation process:
(1) by recipe ratio, just polyvinyl alcohol resin, 2-ethyl benzofuran, neck phthalic acid dibutyl ester, polystyrene, xylyl phosphoric acid ester, isophorone diisocyanate, paracril, dibutyl tin laurate join reactor and are heated to 100-130 ℃, high-speed stirring 3-4h;
(2) again other compositions are joined in the reactor in step (1), stir 1-2h, be cooled to normal temperature, packing.
Compared with the prior art, beneficial effect of the present invention is as follows:
The present invention is by adding the compositions such as modified Nano bamboo charcoal powder, xylogen in sizing agent, can effectively eliminate toxicity and the pollution on the environment of sizing agent, simultaneously, add modified coal ash, obviously improve the dispersing uniformity of each component, can improve the adhesion intensity of sizing agent, and have the advantages that cost is low, effect is good.Sizing agent of the present invention has the features such as bonding strength is high, pollution-free, storage period is long, harmless to human body, environmental protection.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
A kind of environment-protective adhesive that contains modified Nano bamboo charcoal powder, comprise the component of following weight part: 130 parts of polyvinyl alcohol resins, 70 parts of 2-ethyl benzofurans, 20 parts of neck phthalic acid dibutyl esters, 15 parts of polystyrene, 13 parts of xylyl phosphoric acid ester, 25 parts of isophorone diisocyanates, 7 parts of paracrils, 10 parts, calcium carbonate, 5 parts of titanium dioxides, 6 parts of nano-sized magnesium hydroxides, 18 parts of modified Nano bamboo charcoal powder, 15 parts, xylogen, 4 parts of gas-phase silicas, 4 parts of sodium alginates, 25 parts of quartz sands, 2 parts, boron powder, 6 parts of baths of glass, 0.8 part of dibutyl tin laurate, 3 parts of iron micas, 2 parts of silane coupling agents, 13 parts of modified coal ashs.
Wherein, the preparation method of modified Nano bamboo charcoal powder is: bamboo charcoal powder is soaked 8h with 15% sodium hydroxide solution, then use deionized water wash, dry, then add and be equivalent to 2 of its weight 2%, 4,6 trisphenols, 3% a-cyanacrylate, 3% crosslink agent DCP, 5000 revs/min are stirred 50 minutes, dry, grind to form nanometer powder.
Modified coal ash is prepared by following steps: first flyash is dried in 110 ℃ of baking ovens, then the flyash after drying is put into high-speed kneading machine, add aluminate coupling agent, 3% wooden sodium sulfonate, 3% the triethyl citrate, 2% whiteruss and 4% the talcum powder that are equivalent to flyash weight 5%, after high-speed mixing, dry, pulverize and grind to form ultrafine powder.
The preparation method of the environment-protective adhesive that contains modified Nano bamboo charcoal powder, comprises following preparation process:
(1) by recipe ratio, just polyvinyl alcohol resin, 2-ethyl benzofuran, neck phthalic acid dibutyl ester, polystyrene, xylyl phosphoric acid ester, isophorone diisocyanate, paracril, dibutyl tin laurate join reactor and are heated to 130 ℃, high-speed stirring 3h;
(2) again other compositions are joined in the reactor in step (1), stir 1h, be cooled to normal temperature, packing.
Embodiment 2:
A kind of environment-protective adhesive that contains modified Nano bamboo charcoal powder, comprise the component of following weight part: 100 parts of polyvinyl alcohol resins, 50 parts of 2-ethyl benzofurans, 20 parts of neck phthalic acid dibutyl esters, 15 parts of polystyrene, 10 parts of xylyl phosphoric acid ester, 20 parts of isophorone diisocyanates, 5 parts of paracrils, 10 parts, calcium carbonate, 7 parts of titanium dioxides, nano-sized magnesium hydroxide 5, part, 15 parts of modified Nano bamboo charcoal powder, 10 parts, xylogen, 3 parts of gas-phase silicas, 3 parts of sodium alginates, 20 parts of quartz sands, 1 part, boron powder, 5 parts of baths of glass, 0.7 part of dibutyl tin laurate, 2 parts of iron micas, 2 parts of silane coupling agents, 10 parts of modified coal ashs.
Wherein, the preparation method of modified Nano bamboo charcoal powder is: bamboo charcoal powder is soaked 7h with 10% sodium hydroxide solution, then use deionized water wash, dry, then add and be equivalent to 2 of its weight 2%, 4,6 trisphenols, 1% a-cyanacrylate, 1% crosslink agent DCP, 3000 revs/min are stirred 30 minutes, dry, grind to form nanometer powder.
Modified coal ash is prepared by following steps: first flyash is dried in 100 ℃ of baking ovens, then the flyash after drying is put into high-speed kneading machine, add aluminate coupling agent, 2% wooden sodium sulfonate, 2% the triethyl citrate, 1% whiteruss and 2% the talcum powder that are equivalent to flyash weight 3%, after high-speed mixing, dry, pulverize and grind to form ultrafine powder.
The preparation method of the environment-protective adhesive that contains modified Nano bamboo charcoal powder, comprises following preparation process:
(1) by recipe ratio, just polyvinyl alcohol resin, 2-ethyl benzofuran, neck phthalic acid dibutyl ester, polystyrene, xylyl phosphoric acid ester, isophorone diisocyanate, paracril, dibutyl tin laurate join reactor and are heated to 100 ℃, high-speed stirring 3h;
(2) again other compositions are joined in the reactor in step (1), stir 1h, be cooled to normal temperature, packing.
Embodiment 3:
A kind of environment-protective adhesive that contains modified Nano bamboo charcoal powder, comprise the component of following weight part: 150 parts of polyvinyl alcohol resins, 80 parts of 2-ethyl benzofurans, 30 parts of neck phthalic acid dibutyl esters, 20 parts of polystyrene, 15 parts of xylyl phosphoric acid ester, 30 parts of isophorone diisocyanates, 10 parts of paracrils, 15 parts, calcium carbonate, 8 parts of titanium dioxides, 20 parts of nano-sized magnesium hydroxides, 20 parts of modified Nano bamboo charcoal powder, 15 parts, xylogen, 5 parts of gas-phase silicas, 5 parts of sodium alginates, 30 parts of quartz sands, 3 parts, boron powder, 8 parts of baths of glass, 0.9 part of dibutyl tin laurate, 4 parts of iron micas, 3 parts of silane coupling agents, 15 parts of modified coal ashs.
Wherein, the preparation method of modified Nano bamboo charcoal powder is: bamboo charcoal powder is soaked 5h with 15% sodium hydroxide solution, then use deionized water wash, dry, then add and be equivalent to 2 of its weight 2%, 4,6 trisphenols, 3% a-cyanacrylate, 3% crosslink agent DCP, 5000 revs/min are stirred 50 minutes, dry, grind to form nanometer powder.
Described modified coal ash is prepared by following steps: first flyash is dried in 110 ℃ of baking ovens, then the flyash after drying is put into high-speed kneading machine, add aluminate coupling agent, 4% wooden sodium sulfonate, 4% the triethyl citrate, 2% whiteruss and 5% the talcum powder that are equivalent to flyash weight 5%, after high-speed mixing, dry, pulverize and grind to form ultrafine powder.
The preparation method of the described environment-protective adhesive that contains modified Nano bamboo charcoal powder, comprises following preparation process:
(1) by recipe ratio, just polyvinyl alcohol resin, 2-ethyl benzofuran, neck phthalic acid dibutyl ester, polystyrene, xylyl phosphoric acid ester, isophorone diisocyanate, paracril, dibutyl tin laurate join reactor and are heated to 130 ℃, high-speed stirring 3h;
(2) again other compositions are joined in the reactor in step (1), stir 2h, be cooled to normal temperature, packing.
Claims (4)
1. an environment-protective adhesive that contains modified Nano bamboo charcoal powder, it is characterized in that: the component that comprises following weight part: polyvinyl alcohol resin 100-150 part, 2-ethyl benzofuran 50-80 part, neck phthalic acid dibutyl ester 20-30 part, polystyrene 15-20 part, xylyl phosphoric acid ester 10-15 part, isophorone diisocyanate 20-30 part, paracril 5-10 part, calcium carbonate 10-15 part, titanium dioxide 5-8 part, nano-sized magnesium hydroxide 5-20 part, modified Nano bamboo charcoal powder 15-20 part, xylogen 10-15 part, gas-phase silica 3-5 part, sodium alginate 3-5 part, quartz sand 20-30 part, boron powder 1-3 part, bath of glass 5-10 part, dibutyl tin laurate 0.7-0.9 part, iron mica 2-4 part, silane coupling agent 1-3 part, modified coal ash 10-15 part.
2. the environment-protective adhesive that contains modified Nano bamboo charcoal powder according to claim 1, is characterized in that:
The preparation method of described modified Nano bamboo charcoal powder is: bamboo charcoal powder is soaked 5-8h with 10-15% sodium hydroxide solution, then use deionized water wash, dry, add again and be equivalent to 2,4,6 trisphenols of its weight 1-2%, the a-cyanacrylate of 1-3%, the crosslink agent DCP of 1-3%, 3000-5000 rev/min is stirred 30-50 minute, dry, grind to form nanometer powder.
3. the environment-protective adhesive that contains modified Nano bamboo charcoal powder according to claim 1, it is characterized in that: described modified coal ash is prepared by following steps: first flyash is dried in 100-110 ℃ of baking oven, then the flyash after drying is put into high-speed kneading machine, add and be equivalent to the aluminate coupling agent of flyash weight 3-5%, the wooden sodium sulfonate of 2-4%, triethyl citrate, the whiteruss of 1-2% and the talcum powder of 2-5% of 2-4%, after high-speed mixing, dry, pulverize and grind to form ultrafine powder.
4. the preparation method of the environment-protective adhesive that contains modified Nano bamboo charcoal powder according to claim 1, is characterized in that: comprise following preparation process:
(1) by recipe ratio, just polyvinyl alcohol resin, 2-ethyl benzofuran, neck phthalic acid dibutyl ester, polystyrene, xylyl phosphoric acid ester, isophorone diisocyanate, paracril, dibutyl tin laurate join reactor and are heated to 100-130 ℃, high-speed stirring 3-4h;
(2) again other compositions are joined in the reactor in step (1), stir 1-2h, be cooled to normal temperature, packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410057025.5A CN103788911B (en) | 2014-02-20 | 2014-02-20 | Environment-friendly adhesive containing modified nanometer bamboo charcoal powder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410057025.5A CN103788911B (en) | 2014-02-20 | 2014-02-20 | Environment-friendly adhesive containing modified nanometer bamboo charcoal powder |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103788911A true CN103788911A (en) | 2014-05-14 |
| CN103788911B CN103788911B (en) | 2015-06-10 |
Family
ID=50664978
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410057025.5A Expired - Fee Related CN103788911B (en) | 2014-02-20 | 2014-02-20 | Environment-friendly adhesive containing modified nanometer bamboo charcoal powder |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103788911B (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559907A (en) * | 2014-12-26 | 2015-04-29 | 邢柯君 | Environment-friendly composite adhesive as well as preparation method and application thereof |
| CN105646823A (en) * | 2016-01-13 | 2016-06-08 | 宜兴市华夏化工材料有限公司 | Preparation method and application of bamboo fiber micropowder |
| CN105885490A (en) * | 2016-06-22 | 2016-08-24 | 杨玉双 | Environmentally friendly coating added with modified nano bamboo charcoal powder and preparation method of environmentally friendly coating |
| CN106010556A (en) * | 2016-05-31 | 2016-10-12 | 山东胜伟园林科技有限公司 | Bamboo charcoal nanopowder-containing penetration resisting material, and method for planting blueberries in saline and alkaline land by using penetration resisting material |
| CN106381031A (en) * | 2016-08-30 | 2017-02-08 | 乐凯特科技铜陵有限公司 | Three-proofing lacquer for high-temperature-resistant printed circuit board and preparation method thereof |
| CN106674716A (en) * | 2016-12-23 | 2017-05-17 | 安徽天元电缆有限公司 | Eco-friendly flame-retardant thermoplastic elastomer and preparation method thereof |
| CN106699046A (en) * | 2016-11-17 | 2017-05-24 | 铜陵祥云消防科技有限责任公司 | Washing resistant heat insulation and flame retardant material for exterior walls |
| CN107117823A (en) * | 2017-06-30 | 2017-09-01 | 合肥利裕泰玻璃制品有限公司 | A kind of foam glass and preparation method thereof |
| CN107142793A (en) * | 2017-07-05 | 2017-09-08 | 合肥市片叶装饰工程有限公司 | Environment-friendly antibacterial wallpaper |
| CN108531089A (en) * | 2018-05-07 | 2018-09-14 | 安吉祥力胶粘剂有限公司 | A kind of special adhesive of environment friendly decorative material and preparation method thereof |
| CN109998222A (en) * | 2019-04-25 | 2019-07-12 | 东莞市东城赤洪节能设备厂 | A kind of insole that can be breathed |
| CN111346619A (en) * | 2020-04-20 | 2020-06-30 | 黑龙江大学 | Preparation method of modified red mud filter material and removal of ammonia nitrogen in low-temperature sewage by using modified red mud filter material |
| CN113862824A (en) * | 2021-10-22 | 2021-12-31 | 广州明晖新材料有限公司 | High-temperature-resistant brush wire and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005105010A (en) * | 2003-09-26 | 2005-04-21 | Yamaguchi Prefecture | Inorganic coating material and voc-adsorbing functional material using the same |
| CN102965050A (en) * | 2012-11-02 | 2013-03-13 | 铜陵祥云消防科技有限责任公司 | Nano-kieselguhr modified adhesive for packaging |
| CN103013135A (en) * | 2012-11-25 | 2013-04-03 | 安徽六方重联机械股份有限公司 | Automobile valve oil seal rubber and preparation method thereof |
-
2014
- 2014-02-20 CN CN201410057025.5A patent/CN103788911B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005105010A (en) * | 2003-09-26 | 2005-04-21 | Yamaguchi Prefecture | Inorganic coating material and voc-adsorbing functional material using the same |
| CN102965050A (en) * | 2012-11-02 | 2013-03-13 | 铜陵祥云消防科技有限责任公司 | Nano-kieselguhr modified adhesive for packaging |
| CN103013135A (en) * | 2012-11-25 | 2013-04-03 | 安徽六方重联机械股份有限公司 | Automobile valve oil seal rubber and preparation method thereof |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559907A (en) * | 2014-12-26 | 2015-04-29 | 邢柯君 | Environment-friendly composite adhesive as well as preparation method and application thereof |
| CN105646823B (en) * | 2016-01-13 | 2018-01-09 | 宜兴市华夏化工材料有限公司 | A kind of preparation method and applications of bamboo fibre superfine powder |
| CN105646823A (en) * | 2016-01-13 | 2016-06-08 | 宜兴市华夏化工材料有限公司 | Preparation method and application of bamboo fiber micropowder |
| CN106010556A (en) * | 2016-05-31 | 2016-10-12 | 山东胜伟园林科技有限公司 | Bamboo charcoal nanopowder-containing penetration resisting material, and method for planting blueberries in saline and alkaline land by using penetration resisting material |
| CN105885490A (en) * | 2016-06-22 | 2016-08-24 | 杨玉双 | Environmentally friendly coating added with modified nano bamboo charcoal powder and preparation method of environmentally friendly coating |
| CN106381031A (en) * | 2016-08-30 | 2017-02-08 | 乐凯特科技铜陵有限公司 | Three-proofing lacquer for high-temperature-resistant printed circuit board and preparation method thereof |
| CN106699046A (en) * | 2016-11-17 | 2017-05-24 | 铜陵祥云消防科技有限责任公司 | Washing resistant heat insulation and flame retardant material for exterior walls |
| CN106674716A (en) * | 2016-12-23 | 2017-05-17 | 安徽天元电缆有限公司 | Eco-friendly flame-retardant thermoplastic elastomer and preparation method thereof |
| CN107117823A (en) * | 2017-06-30 | 2017-09-01 | 合肥利裕泰玻璃制品有限公司 | A kind of foam glass and preparation method thereof |
| CN107142793A (en) * | 2017-07-05 | 2017-09-08 | 合肥市片叶装饰工程有限公司 | Environment-friendly antibacterial wallpaper |
| CN108531089A (en) * | 2018-05-07 | 2018-09-14 | 安吉祥力胶粘剂有限公司 | A kind of special adhesive of environment friendly decorative material and preparation method thereof |
| CN109998222A (en) * | 2019-04-25 | 2019-07-12 | 东莞市东城赤洪节能设备厂 | A kind of insole that can be breathed |
| CN109998222B (en) * | 2019-04-25 | 2020-10-23 | 东莞市东城赤洪节能设备厂 | Breathable insole |
| CN111346619A (en) * | 2020-04-20 | 2020-06-30 | 黑龙江大学 | Preparation method of modified red mud filter material and removal of ammonia nitrogen in low-temperature sewage by using modified red mud filter material |
| CN111346619B (en) * | 2020-04-20 | 2022-08-26 | 黑龙江大学 | Preparation method of modified red mud filter material and removal of ammonia nitrogen in low-temperature sewage by using modified red mud filter material |
| CN113862824A (en) * | 2021-10-22 | 2021-12-31 | 广州明晖新材料有限公司 | High-temperature-resistant brush wire and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103788911B (en) | 2015-06-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103788911B (en) | Environment-friendly adhesive containing modified nanometer bamboo charcoal powder | |
| CN103437144B (en) | Preparation method for nanometer titanium dioxide finishing agent | |
| CN104017466A (en) | High-temperature-resistant corrosion-resistant coating for aluminum plate | |
| CN110172180A (en) | Inorfil/silica nano material and its preparation method and application | |
| CN110982307A (en) | Ecological shell powder interior wall coating and preparation method thereof | |
| CN102691205A (en) | Method using hydrothermal method to prepare nano-zinc-oxide assembly cotton fibers | |
| CN109971047B (en) | Natural rubber-white carbon black composite material and preparation method and application thereof | |
| CN105839452B (en) | A kind of special calcium carbonate of papermaking | |
| CN106752100A (en) | Modified morphology controllable nano-calcium carbonate powder of a kind of compound alkali lignin APEO activating agent and preparation method thereof | |
| CN104151465B (en) | PAN-g-SiO is prepared based on the Tong Bu in-situ hydrolysis of PAN with TEOS2the method of polymer | |
| CN104233788A (en) | Finishing technology for yellowing prevention of silk fabric | |
| CN108165212A (en) | One kind eliminates the unusual smell adhesive | |
| CN106590052A (en) | Polydopamine polyethenoxy ether active agent modified shape-controllable nano calcium carbonate powder and preparation method thereof | |
| CN109796913A (en) | A kind of adhesive containing modified Nano bamboo charcoal powder | |
| CN106283728B (en) | A kind of production technology of high color fastness blend polyester woollen blanket | |
| CN108165211A (en) | A kind of adhesive containing modified Nano bamboo charcoal powder | |
| CN104947409A (en) | Production technology of nano coffee bamboo charcoal fiber fabric | |
| CN108795138A (en) | A kind of blue tangerine line waterproof powdery paints applied on electric appliance | |
| CN107099120A (en) | A kind of preparation method and applications of light flame-retardant construction material | |
| CN103468016B (en) | A kind of environment-protective rubber material and preparation method thereof | |
| CN104963192A (en) | Fire-resistant heat insulation coating for interior decoration textile | |
| CN106590053A (en) | Organic rare earth complex coating modified nanometer calcium carbonate powder with controllable morphological structure and preparation method thereof | |
| CN112980112A (en) | Preparation method of modified rubber particles | |
| CN104891505A (en) | Preparation method of high-dispersity white carbon black | |
| CN108722361A (en) | A kind of absorbent-type water pollution inorganic agent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20161221 Address after: 542899 Hezhou the Guangxi Zhuang Autonomous Region Electronic Science and technology park is run on the road No. 1 Patentee after: GUANGXI HUIZHI PRODUCTIVITY PROMOTION CENTER Co.,Ltd. Address before: 244100 Tongling Jinqiao Industrial Park, Tongling, Anhui Patentee before: TONGLING XIANGYUN FIRE-FIGHTING TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20171016 Address after: Xinhua Street in Zhaoping town Hezhou city the Guangxi Zhuang Autonomous Region Zhaoping County 546800 No. 3 Patentee after: ZHAOPING SCIENCE TECHNOLOGY GUIDANCE STATION Address before: 542899 Hezhou the Guangxi Zhuang Autonomous Region Electronic Science and technology park is run on the road No. 1 Patentee before: GUANGXI HUIZHI PRODUCTIVITY PROMOTION CENTER Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150610 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |