CN108504200A - Metal ion crosslinked type multicolor finish - Google Patents
Metal ion crosslinked type multicolor finish Download PDFInfo
- Publication number
- CN108504200A CN108504200A CN201810248898.2A CN201810248898A CN108504200A CN 108504200 A CN108504200 A CN 108504200A CN 201810248898 A CN201810248898 A CN 201810248898A CN 108504200 A CN108504200 A CN 108504200A
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- CN
- China
- Prior art keywords
- parts
- metal ion
- rotating speed
- crosslinked type
- multicolor finish
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses metal ion crosslinked type multicolor finishes, include the raw material of following parts by weight：200~250 parts of water, 8~10 parts of 10 emulsifiers of OP, 15~20 parts of lauryl sodium sulfate, 20~25 parts of polyacrylate, 150~180 parts of talcum powder, 50~60 parts of pigment, 1.0~1.5 parts of cellulose, 6.2~8.6 parts of styrene, 3.4~5.6 parts of butyl acrylate, 4.3~8.5 parts of acrylic acid, 2.4~3.5 parts of acrylic amine, 150~200 parts of zinc acetate.By based on coating, zinc ion is added by phenylpropyl alcohol breast in the present invention, and zinc ion and the hydroxyl in butyl acrylate form stable complex compound, so that molecular weight is multiplied, can significantly improve the chemoresistance and water resistance of coating.
Description
Technical field
The present invention relates to technical field of coatings more particularly to metal ion crosslinked type multicolor finishes.
Background technology
Coating refers to being coated on body surface, can with base material bonding and form the material of complete, tough and tensile protective film, coating
Using other than it can play a protective role to article, additionally it is possible to article color and gloss are assigned, to play decoration function.
The problems such as general coating is likely to occur poor water resistance, and adhesive force is weak, and the characteristics of metal height cross-linked type macromolecule material, is
Crosslink density is big, transparent good, solvent resistance and water resistance are all relatively good.Metal ion crosslinked type coating not only has chemistry
Repellence and water-tolerant, and crosslinking agent is nontoxic, there is prodigious development prospect.
Invention content
The purpose of the present invention is to solve disadvantages existing in the prior art, and the metal ion crosslinked type proposed is colorful
Coating.
To achieve the goals above, present invention employs following technical solutions：
Metal ion crosslinked type multicolor finish, includes the raw material of following parts by weight：200~250 parts of water, OP-10 emulsifiers 8~10
Part, 15~20 parts of lauryl sodium sulfate, 20~25 parts of polyacrylate, 150~180 parts of talcum powder, 50~60 parts of pigment, fibre
1.0~1.5 parts of dimension element, 6.2~8.6 parts of styrene, 3.4~5.6 parts of butyl acrylate, 4.3~8.5 parts of acrylic acid, acrylic acid
2.4~3.5 parts of amine, 150~200 parts of zinc acetate.
Preferably, the weight ratio of the emulsifiers of the OP~10 and lauryl sodium sulfate is 1:2.
Preferably, the hydroxyl value of the butyl acrylate of the hydroxyl is in the range of 30 mgKOH/g-180 mgKOH/g,
Weight average molecular weight is in the range of 1200-8000.
Preferably, the mesh number of the talcum powder is -2000 mesh of 800 mesh, wherein the weight of the talcum powder of -1800 mesh of 1000 mesh
Proportion accounts for 75 %-85 %.
Preferably, the pigment can be selected according to actual demand.
Preferably, the preparation method of the metal ion crosslinked type multicolor finish is：
S1：It adds water in container and stirs, cellulose is added in whipping process, with turning for 115 r/min-160 r/min
Speed 6 min-8 min of dispersion, are then added OP-10 emulsifiers and lauryl sodium sulfate, with 400 r/min-500 in a reservoir
The rotating speed of r/min disperses 6 min-10 min, forms complex emulsions.
S2：Then talcum powder, acrylic acid, acrylic amine, polyacrylate and second is added according to than part in complex emulsions
Sour zinc disperses 25 min-30 min with the rotating speed of 1500 r/min-2200 r/min, base paint is made；
S3：Pigment is proportionally added in base paint, is stirred with the rotating speed of 550 r/min-750 r/min, stirring point
The scattered time is 10 min-20 min, obtains mixed paint；
S4：Styrene, butyl acrylate and water are mixed with another container, with the rotating speed of 750 r/min-900 r/min into
Row stirring, the time being dispersed with stirring are 5 min-8 min, obtain cladding lotion, then that mixed paint and cladding lotion is fully mixed
It closes, is stirred fusion with the rotating speed of 1200 r/min-1800 r/min, the time of stirring is 25 min-40 min, and gold is made
Belong to ionomer type multicolor finish.
The beneficial effects of the invention are as follows：This metal ion crosslinked type multicolor finish, by based on coating, is added by phenylpropyl alcohol breast
Zinc ion, the hydroxyl in zinc ion and butyl acrylate form stable complex compound, so that molecular weight is multiplied, can significantly improve
Multigroup paint film is impregnated and finds that the coefficient of softing of paint film is 0.85- in water by the chemoresistance and water resistance of coating
0.89, illustrate its water-tolerant.
Specific implementation mode
The present invention is made further to explain with reference to specific embodiment.
Embodiment one
S1：150 kg of water is added to the container and is stirred, 1 kg of cellulose is added in whipping process, with turning for 120 r/min
Then speed 6 min of dispersion are added OP-10 and emulsify 8 kg and 16 kg of lauryl sodium sulfate, in a reservoir with 400 r/min's
Rotating speed disperses 6 min, forms complex emulsions.
S2：In complex emulsions according to than part be added talcum powder 150 kg, 4.5 kg of acrylic acid, 2.5 kg of acrylic amine,
150 kg of 20 kg of polyacrylate and zinc acetate disperses 25 min with the rotating speed of 1600 r/min, base paint is made；
S3：50 kg of pigment is proportionally added in base paint, is stirred with the rotating speed of 550 r/min, be dispersed with stirring when
Between be 10 min, obtain mixed paint；
S4：6.5 kg of styrene, 3.5 kg of butyl acrylate and 60 kg of water are mixed with another container, with 750 r/min's
Rotating speed is stirred, and the time being dispersed with stirring is 5 min, obtains cladding lotion, then that mixed paint and cladding lotion is fully mixed
It closes, is stirred fusion with the rotating speed of 1200 r/min, the time of stirring is 25 min, and the colorful painting of metal ion crosslinked type is made
Material.
The paint film of gained is impregnated in water, by measuring and calculation, the coefficient of softing for obtaining paint film is 0.88.
Embodiment two
S1：180 kg of water is added to the container and is stirred, 1.5 kg of cellulose is added in whipping process, with 130 r/min's
Rotating speed disperses 7 min, 9 kg and 18 kg of lauryl sodium sulfate of OP-10 emulsifiers is then added in a reservoir, with 450 r/
The rotating speed of min disperses 7 min, forms complex emulsions.
S2：Then in complex emulsions according to than part be added talcum powder 160 kg, 6 kg of acrylic acid, 3 kg of acrylic amine,
175 kg of 23 kg of polyacrylate and zinc acetate disperses 28 min with the rotating speed of 1800 r/min, base paint is made；
S3：Pigment yellow 155 kg is proportionally added in base paint, is stirred with the rotating speed of 650 r/min, be dispersed with stirring when
Between be 15 min, obtain mixed paint；
S4：7.5 kg of styrene, 5 kg of butyl acrylate and 50 kg of water are mixed with another container, with turning for 800 r/min
Speed is stirred, and the time being dispersed with stirring is 6 min, obtains cladding lotion, is then sufficiently mixed mixed paint and cladding lotion,
It is stirred fusion with the rotating speed of 1500 r/min, the time of stirring is 30 min, and metal ion crosslinked type multicolor finish is made.
The paint film of gained is impregnated in water, by measuring and calculation, the coefficient of softing for obtaining paint film is 0.86.
Embodiment three
S1：190 kg of water is added to the container and is stirred, 1.5 kg of cellulose is added in whipping process, with 150 r/min's
Rotating speed disperses 8 min, 10 kg and 20 kg of lauryl sodium sulfate of OP-10 emulsifiers is then added in a reservoir, with 500 r/
The rotating speed of min disperses 10 min, forms complex emulsions.
S2：Then 180 kg of talcum powder, 8 kg of acrylic acid, acrylic amine 3.2 is added according to than part in complex emulsions
200 kg of kg, 5 kg of polyacrylate and zinc acetate disperses 30 min with the rotating speed of 2200 r/min, base paint is made；
S3：60 kg of pigment is proportionally added in base paint, is stirred with the rotating speed of 750 r/min, be dispersed with stirring when
Between be 18 min, obtain mixed paint；
S4：8 kg of styrene, 5 kg of butyl acrylate and 60 kg of water are mixed with another container, with the rotating speed of 900 r/min
It is stirred, the time being dispersed with stirring is 8 min, obtains cladding lotion, is then sufficiently mixed mixed paint and cladding lotion, uses
The rotating speed of 1800 r/min is stirred fusion, and the time of stirring is 35 min, and metal ion crosslinked type multicolor finish is made.
The paint film of gained is impregnated in water, by measuring and calculation, the coefficient of softing for obtaining paint film is 0.85.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (6)
1. metal ion crosslinked type multicolor finish, which is characterized in that include the raw material of following parts by weight：200~250 parts of water, OP-
10 8~10 parts of emulsifiers, 15~20 parts of lauryl sodium sulfate, 20~25 parts of polyacrylate, 150~180 parts of talcum powder, face
50~60 parts of material, 1.0~1.5 parts of cellulose, 6.2~8.6 parts of styrene, 3.4~5.6 parts of butyl acrylate, acrylic acid 4.3~
8.5 parts, 2.4~3.5 parts of acrylic amine, 150~200 parts of zinc acetate.
2. metal ion crosslinked type multicolor finish according to claim 1, which is characterized in that the emulsifiers of the OP~10 with
The weight ratio of lauryl sodium sulfate is 1:2.
3. metal ion crosslinked type multicolor finish according to claim 1, which is characterized in that the acrylic acid of the hydroxyl
For the hydroxyl value of butyl ester in the range of 30mgKOH/g-180mgKOH/g, weight average molecular weight is in the range of 1200-8000.
4. metal ion crosslinked type multicolor finish according to claim 1, which is characterized in that the mesh number of the talcum powder is
- 2000 mesh of 800 mesh, wherein the weight proportion of the talcum powder of -1800 mesh of 1000 mesh accounts for 75%-85%.
5. metal ion crosslinked type multicolor finish according to claim 1, which is characterized in that the pigment can be according to reality
Border demand is selected.
6. thermal-insulation artificial granite paint according to claim 1, which is characterized in that the metal ion crosslinked type
The preparation method of multicolor finish is：
S1：It adds water in container and stirs, cellulose is added in whipping process, with the rotating speed of 115r/min-160r/min
Disperse 6min-8min, OP-10 emulsifiers and lauryl sodium sulfate are then added in a reservoir, uses 400r/min-500r/min
Rotating speed disperse 6min-10min, formed complex emulsions.
S2：Then talcum powder, acrylic acid, acrylic amine, polyacrylate and zinc acetate is added according to than part in complex emulsions,
Disperse 25min-30min with the rotating speed of 1500r/min-2200r/min, base paint is made；
S3：Pigment is proportionally added in base paint, is stirred, is dispersed with stirring with the rotating speed of 550r/min-750r/min
Time be 10min-20min, obtain mixed paint；
S4：Styrene, butyl acrylate and water are mixed with another container, carried out with the rotating speed of 750r/min-900r/min
Stirring, the time being dispersed with stirring are 5min-8min, obtain cladding lotion, are then sufficiently mixed mixed paint and cladding lotion, use
The rotating speed of 1200r/min-1800r/min is stirred fusion, and the time of stirring is 25min-40min, and metal ion is made and hands over
Connection type multicolor finish.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810248898.2A CN108504200A (en) | 2018-03-25 | 2018-03-25 | Metal ion crosslinked type multicolor finish |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810248898.2A CN108504200A (en) | 2018-03-25 | 2018-03-25 | Metal ion crosslinked type multicolor finish |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108504200A true CN108504200A (en) | 2018-09-07 |
Family
ID=63378274
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810248898.2A Pending CN108504200A (en) | 2018-03-25 | 2018-03-25 | Metal ion crosslinked type multicolor finish |
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| Country | Link |
|---|---|
| CN (1) | CN108504200A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114456666A (en) * | 2022-03-30 | 2022-05-10 | 北京化工大学 | High-temperature-resistant water-based gloss oil, and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104119715A (en) * | 2014-08-06 | 2014-10-29 | 吴江华诚复合材料科技有限公司 | Aqueous colorful-pattern coating material |
| CN106632808A (en) * | 2016-11-29 | 2017-05-10 | 中山摩尔化学工业有限公司 | Metallic-ion crosslinking polyacrylate emulsion and preparation method thereof |
| CN106675295A (en) * | 2016-12-27 | 2017-05-17 | 成都巴德富科技有限公司 | Finish-coat-free matte water-based colored paint and preparation method thereof |
| CN107163761A (en) * | 2017-05-19 | 2017-09-15 | 佛山市顺德区巴德富实业有限公司 | A kind of colorful base paint emulsion of excellent performance and preparation method thereof |
-
2018
- 2018-03-25 CN CN201810248898.2A patent/CN108504200A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104119715A (en) * | 2014-08-06 | 2014-10-29 | 吴江华诚复合材料科技有限公司 | Aqueous colorful-pattern coating material |
| CN106632808A (en) * | 2016-11-29 | 2017-05-10 | 中山摩尔化学工业有限公司 | Metallic-ion crosslinking polyacrylate emulsion and preparation method thereof |
| CN106675295A (en) * | 2016-12-27 | 2017-05-17 | 成都巴德富科技有限公司 | Finish-coat-free matte water-based colored paint and preparation method thereof |
| CN107163761A (en) * | 2017-05-19 | 2017-09-15 | 佛山市顺德区巴德富实业有限公司 | A kind of colorful base paint emulsion of excellent performance and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114456666A (en) * | 2022-03-30 | 2022-05-10 | 北京化工大学 | High-temperature-resistant water-based gloss oil, and preparation method and application thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180907 |
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