CN108476804A - A kind of degradable sludge base pot for growing seedlings and preparation method thereof - Google Patents
A kind of degradable sludge base pot for growing seedlings and preparation method thereof Download PDFInfo
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- CN108476804A CN108476804A CN201810648839.4A CN201810648839A CN108476804A CN 108476804 A CN108476804 A CN 108476804A CN 201810648839 A CN201810648839 A CN 201810648839A CN 108476804 A CN108476804 A CN 108476804A
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- Prior art keywords
- pot
- growing seedlings
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- polyvinyl alcohol
- sludge
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G9/00—Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
- A01G9/02—Receptacles, e.g. flower-pots or boxes; Glasses for cultivating flowers
- A01G9/029—Receptacles for seedlings
- A01G9/0291—Planting receptacles specially adapted for remaining in the soil after planting
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G24/00—Growth substrates; Culture media; Apparatus or methods therefor
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- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Cultivation Receptacles Or Flower-Pots, Or Pots For Seedlings (AREA)
Abstract
A kind of degradable sludge base pot for growing seedlings of the present invention and preparation method thereof, which includes that following parts by weight raw material are prepared:25 parts of polyvinyl alcohol, 80 100 parts of water, 5 10 parts of gelatin, 5 10 parts of dextrin, 5 20 parts of sludge, 0.5 1 parts of crosslinking agent, and pot for growing seedlings in preparation process forming processes prior to crosslinking Treatment;The pot for growing seedlings not only has higher mechanical property, can meet the requirement in nursery to pot for growing seedlings performance;There can also be positive effect to improving the survival rate of seedling and the growth rate of plant to which fast-growth and the extension of plant root will not be limited after transplanting or field planting by fast degradation in the soil.
Description
Technical field
The present invention relates to agriculture apparatus fields, and in particular to a kind of degradable sludge base pot for growing seedlings and preparation method thereof.
Background technology
Pot for growing seedlings is chiefly used in the fields such as nursery, breeding and greenhouse gardening and the afforestation of agricultural, is widely used, demand
Amount is big.In practical seedling raising process, transplanting is an extremely important step, need by pot for growing seedlings seedling and nutritive cube take
Continued growth in plantation to crop field or large-scale flowerpot after going out.Seedling culture bowl is needed to be carried out with pot for growing seedlings during transplanting
Technical problems, the surviving after strong influence seedling replanting such as there is damage seedlings root and seedling culture bowl be fugitive in separation
Rate.The making raw material of degradable pot for growing seedlings has shale, wooden and degradation plastic etc. at present, but these degradation materials are still
There are problems that:Shale pot for growing seedlings, degradation speed is slow, preparation process high energy consumption, and environment friendly is poor;The system of wooden pot for growing seedlings
Standby cost is few compared with high application;Degradation plastic pot for growing seedlings, technique is cumbersome, of high cost;Therefore, it is used to prepare nursery capable of being fast degraded
The material of alms bowl becomes new research hotspot.
With the development in cities and towns, the yield of municipal sludge is increasing, but resource utilization rate is low, is brought to environment huge
The recycling of big harm, sludge is the most ideal outlet of Treatment of Sludge.Containing by innoxious sludge largely has
Machine matter and mineral nutrient, the sludge after harmless treatment can be used for land use, agricultural compost, soil remediation etc., change soil
Earth physicochemical property promotes to play an important roll in terms of farm-forestry crop volume increase.Therefore, it is prepared using innoxious sludge as raw material
Degradable pot for growing seedlings, seedling can be transplanted together with pot for growing seedlings during transplanting, to avoid the damage of seedlings root
Wound and seedling cultivate the fugitive problem of bowl, can improve the survival rate of seedling;Meanwhile the sludge base pot for growing seedlings after degradation can be with
The physicochemical property for changing soil, is conducive to the growth of seedling, increases economic efficiency.
Since the growing-seedling period of plant is generally shorter, just it will be transplanted or be colonized after the completion of nursery, transplanted or be colonized
Plant root is needed to grow and extend to meet the needs of plant fast-growth as soon as possible afterwards, it is therefore desirable to which pot for growing seedlings is being transplanted
Or can degrade in a short period of time after field planting, to release the limitation that pot for growing seedlings extends to plant root.However, existing correlation
The degradable pot for growing seedlings prepared with sludge in data and patent, although equally there is degradable characteristic, due to matching for use
Side or preparation method etc. it is unreasonable, cause the degradation time of pot for growing seedlings longer, seriously limit the quick of plant shoots root system
Growth and extension, impact the fast-growth of plant after transplanting.
Invention content
It is an object of the invention to overcome the shortcomings of that the degradation time present in existing pot for growing seedlings is long, providing one kind can drop
Sludge base pot for growing seedlings and preparation method thereof is solved, which is to adjust by the specific aim to formula and match with preparation method
What conjunction was prepared;The pot for growing seedlings not only has higher mechanical property, can meet in nursery to pot for growing seedlings performance
It is required that;Can also fast degradation in the soil, to which fast-growth and the extension of plant root will not be limited after transplanting or field planting,
There is positive effect to improving the survival rate of seedling and the growth rate of plant.
In order to achieve the above-mentioned object of the invention, the present invention provides a kind of degradable sludge base pot for growing seedlings, including following weight
Part raw material are prepared:2-5 parts of polyvinyl alcohol, 80-100 parts of water, 5-10 parts of gelatin, 5-10 parts of dextrin, 5-20
The sludge of part, 0.5-1 parts of crosslinking agent;The pot for growing seedlings in preparation process forming processes prior to crosslinking Treatment.
A kind of degradable sludge base pot for growing seedlings of the present invention, by targetedly selecting degradable raw material, and limits it
Dosage makes raw material have excellent processing forming in preparation process, crosslinked can form pot for growing seedlings in the case that no
Germule;Again by crosslinking Treatment after molding, cross-linking reaction is set only to be carried out on the surface of pot for growing seedlings, to which pot for growing seedlings can be improved
Mechanical property, and can prevent from being excessively crosslinked inside pot for growing seedlings, the degradation time of pot for growing seedlings in the soil is made significantly to shorten,
Pot for growing seedlings will not limit the fast-growth of plant root and extension, can improve the survival rate of seedling and the growth speed of plant
Rate.
Wherein, the polyvinyl alcohol has degradability, can carry out cross-linking reaction with crosslinking agent, be degradable pot for growing seedlings
Framework material, and the degree of polymerization of polyvinyl alcohol influences the viscosity and mechanical property of polyvinyl alcohol, has to the overall performance of pot for growing seedlings
There is large effect;Preferably, the polyvinyl alcohol degree of polymerization is 500-2000;The polyvinyl alcohol of the degree of polymerization both have compared with
Good mechanical property and viscosity, is conducive to the molding of pot for growing seedlings, so as to get pot for growing seedlings mechanical property it is preferable, and will not be because poly-
It is right excessively high, cause the degradation speed of pot for growing seedlings to reduce;Most preferably, the polyvinyl alcohol degree of polymerization is 1000-1500.
Wherein, the gelatin and dextrin are conducive to the molding of pot for growing seedlings, can improve pot for growing seedlings as material binder
Mechanical property, and derive from a wealth of sources, degradation speed is slower in air, and degradation speed is fast in the soil.
Wherein, the sludge is the sludge by harmless treatment, containing a large amount of organic matter and mineral nutrient, to planting
The growth of strain has facilitation.
Wherein, the crosslinking agent refers to the material that cross-linking reaction can be carried out with raw material, and cross-linking reaction can significantly improve
The mechanical property and chemical stability of pot for growing seedlings, while can also extend the degradation time of pot for growing seedlings;Preferably, the crosslinking agent
It is one or more in formaldehyde, acetaldehyde, epoxychloropropane;Preferred crosslinking agent and raw material cross-linking reaction are easy to control, crosslinking
Effect is moderate, and obtained pot for growing seedlings performance is best.
Wherein, it is preferred that the preparation method of the pot for growing seedlings includes the following steps:
(1)Dissolving, decentralized processing:It is dissolved in water polyvinyl alcohol, gelatin and dextrin to form mixed solution;In mixed solution
Sludge is added, shaping dope is formed after mixing dispersion;
(2)Forming processes:It is molded with shaping dope, obtains pot for growing seedlings germule;
(3)Crosslinking Treatment:Pot for growing seedlings germule and crosslinking agent are subjected to cross-linking reaction, pot for growing seedlings of the present invention is obtained after the completion of reaction.
Wherein, it is preferred that step(1)The solution temperature of middle polyvinyl alcohol is 90-100 DEG C, under the temperature condition, poly- second
The solution rate of enol is most fast.
Wherein, it is preferred that step(1)Middle gelatin and dextrin are dissolved as 70-80 DEG C, under the temperature condition, gelatin and paste
The solution rate of essence is fast, and gelatin and dextrin will not be denaturalized.
Wherein, it is preferred that step(1)The temperature of middle shaping dope is 60-70 DEG C, under the temperature condition, the viscosity of shaping dope
It is moderate, it is convenient for moisture evaporation, is conducive to molding.
Wherein, it is preferred that step(3)The temperature of middle crosslinking Treatment is 50-60 DEG C, crosslinking time 5-8h, under this condition
Carry out that crosslinked degree is best, obtained pot for growing seedlings mechanical property and degradation time reaches optimum balance.
Wherein, it is preferred that step(3)Further include the carrying out washing treatment to pot for growing seedlings after the completion of middle germule cross-linking reaction;Pass through
Carrying out washing treatment can remove the crosslinking agent not reacted completely on pot for growing seedlings.
Compared with prior art, beneficial effects of the present invention:
1, pot for growing seedlings of the present invention is prepared using degradation material, can be degradable, to soil and environmental nonpollution.
2, pot for growing seedlings specific aim selection raw material of the present invention and dosage, make raw material just have very in the case of uncrosslinked
Good mouldability, convenient for molding.
3, pot for growing seedlings of the present invention is using the preparation method for being first molded post-crosslinking, cross-linking reaction only the surface of pot for growing seedlings into
Row, pot for growing seedlings not only have a preferable mechanical property, but can fast degradation in the soil, to will not be to the plant transplanting or be colonized
The fast-growth of root system and extension cause to limit.
4, pot for growing seedlings preparation method of the present invention is simple, reliable, and energy consumption is few, at low cost, is convenient for degradable sludge base pot for growing seedlings
Large-scale production and application.
Description of the drawings:
Fig. 1 is the preparation technology flow chart of the degradable sludge base pot for growing seedlings of the present invention.
Fig. 2 is the product pictorial diagram of the degradable sludge base pot for growing seedlings of the present invention.
Specific implementation mode
With reference to test example and specific implementation mode, the present invention is described in further detail.But this should not be understood
It is only limitted to embodiment below for the range of the above-mentioned theme of the present invention, it is all that this is belonged to based on the technology that the content of present invention is realized
The range of invention.
Embodiment 1
1, dissolving, decentralized processing:The polyvinyl alcohol of 3 parts by weight is added in the water of 90 parts by weight, is dissolved under conditions of 95 DEG C
Completely, it is prepared into polyvinyl alcohol water solution;Under conditions of 75 DEG C, the gelatin of 8 parts by weight is added, after being completely dissolved, adds 8
The dextrin of parts by weight, is stirred to uniformly mixed, obtains mixed solution;The innoxious place of 15 parts by weight is added under conditions of 65 DEG C
The sludge managed is dispersed with stirring and uniformly obtains shaping dope;
2, forming processes:Shaping dope is poured into mold, germule is made in the near room temperature of water cooling;
3, crosslinking Treatment:By germule and epoxychloropropane cross-linking reaction 6h at 55 DEG C;With anhydrous ether and going after the completion of crosslinking
Ion water washing obtains degradable sludge base pot for growing seedlings.
Embodiment 2
1, dissolving, decentralized processing:The polyvinyl alcohol of 2 parts by weight is added in the water of 80 parts by weight, is dissolved under conditions of 90 DEG C
Completely, it is prepared into polyvinyl alcohol water solution;Under conditions of 80 DEG C, the gelatin of 5 parts by weight is added, after being completely dissolved, adds
The dextrin of 10 parts by weight, is stirred to uniformly mixed, obtains mixed solution;The innoxious of 5 parts by weight is added under conditions of 70 DEG C
Processed sludge is dispersed with stirring and uniformly obtains shaping dope;
2, forming processes:Shaping dope is poured into mold, germule is made in the near room temperature of water cooling;
3, crosslinking Treatment:By germule and formaldehyde cross-linking reaction 5h at 60 DEG C;Absolute ethyl alcohol and deionized water are used after the completion of crosslinking
Washing, obtains degradable sludge base pot for growing seedlings.
Embodiment 3
1, dissolving, decentralized processing:The polyvinyl alcohol of 5 parts by weight is added in the water of 100 parts by weight, it is molten under conditions of 100 DEG C
Solution is complete, is prepared into polyvinyl alcohol water solution;Under conditions of 70 DEG C, the gelatin of 10 parts by weight is added, after being completely dissolved, then adds
The dextrin for entering 5 parts by weight, is stirred to uniformly mixed, obtains mixed solution;The harmless of 20 parts by weight is added under conditions of 60 DEG C
Change processed sludge, is dispersed with stirring and uniformly obtains shaping dope;
2, forming processes:Shaping dope is poured into mold, germule is made in the near room temperature of water cooling;
3, crosslinking Treatment:By germule and acetaldehyde cross-linking reaction 5-8h at 50 DEG C;Absolute ethyl alcohol and deionization are used after the completion of crosslinking
Water washing obtains degradable sludge base pot for growing seedlings.
Comparative example 1
1, dissolving, decentralized processing:The polyvinyl alcohol of 3 parts by weight is added in the water of 90 parts by weight, is dissolved under conditions of 95 DEG C
Completely, it is prepared into polyvinyl alcohol water solution;Under conditions of 75 DEG C, the gelatin of 8 parts by weight is added, after being completely dissolved, adds 8
The dextrin of parts by weight, is stirred to uniformly mixed, obtains mixed solution;The innoxious place of 15 parts by weight is added under conditions of 65 DEG C
The sludge managed is dispersed with stirring and uniformly obtains shaping dope;
2, crosslinking Treatment:Epoxychloropropane, and the cross-linking reaction 6h at 55 DEG C are added in shaping dope, generates cross moulding liquid;
3, forming processes:Cross moulding liquid is poured into mold, the near room temperature of water cooling, degradable sludge base pot for growing seedlings is made.
Comparative example 2
1, dissolving, decentralized processing:The polyvinyl alcohol of 10 parts by weight is added in the water of 90 parts by weight, is dissolved under conditions of 95 DEG C
Completely, it is prepared into polyvinyl alcohol water solution;Under conditions of 75 DEG C, the gelatin of 8 parts by weight is added, after being completely dissolved, adds 8
The dextrin of parts by weight, is stirred to uniformly mixed, obtains mixed solution;The innoxious place of 15 parts by weight is added under conditions of 65 DEG C
The sludge managed is dispersed with stirring and uniformly obtains shaping dope;
2, forming processes:Shaping dope is poured into mold, germule is made in the near room temperature of water cooling;
3, crosslinking Treatment:By germule and epoxychloropropane cross-linking reaction 6h at 55 DEG C;With anhydrous ether and going after the completion of crosslinking
Ion water washing obtains degradable sludge base pot for growing seedlings.
Comparative example 3
1, dissolving, decentralized processing:The polyvinyl alcohol of 1 parts by weight is added in the water of 90 parts by weight, is dissolved under conditions of 95 DEG C
Completely, it is prepared into polyvinyl alcohol water solution;Under conditions of 75 DEG C, the gelatin of 8 parts by weight is added, after being completely dissolved, adds 8
The dextrin of parts by weight, is stirred to uniformly mixed, obtains mixed solution;The innoxious place of 15 parts by weight is added under conditions of 65 DEG C
The sludge managed is dispersed with stirring and uniformly obtains shaping dope;
2, forming processes:Shaping dope is poured into mold, germule is made in the near room temperature of water cooling;
3, crosslinking Treatment:By germule and epoxychloropropane cross-linking reaction 6h at 55 DEG C;With anhydrous ether and going after the completion of crosslinking
Ion water washing obtains degradable sludge base pot for growing seedlings.
Comparative example 4
1, dissolving, decentralized processing:The polyvinyl alcohol of 3 parts by weight is added in the water of 90 parts by weight, is dissolved under conditions of 95 DEG C
Completely, it is prepared into polyvinyl alcohol water solution;Under conditions of 75 DEG C, the gelatin of 8 parts by weight is added, after being completely dissolved, adds 8
The dextrin of parts by weight, is stirred to uniformly mixed, obtains mixed solution;The innoxious place of 15 parts by weight is added under conditions of 65 DEG C
The sludge managed is dispersed with stirring and uniformly obtains shaping dope;
2, forming processes:Shaping dope is poured into mold, the near room temperature of water cooling, obtains degradable sludge base pot for growing seedlings.
The sludge base pot for growing seedlings being prepared in above-described embodiment 1-3 and comparative example 1-4 is subjected to performance detection(In experiment
The standard of degradation refers to 40% or more pot for growing seedlings Mass lost), testing result is as follows:
Serial number | Tensile strength(MPa) | In air(25 DEG C of humidity 60%, temperature)Middle degradation time (d) | In soil(25 DEG C of water content 60%, temperature)Middle degradation time (d) | After transplanting 30d together with cucumber seedlings and pot for growing seedlings, rice shoot growing way, root system stretch feelings Condition |
Embodiment 1 | 6.3 | ≥120 | ≤20 | Rice shoot growing way is good, and root growth goes out pot for growing seedlings |
Embodiment 2 | 6.5 | ≥120 | ≤20 | Rice shoot growing way is good, and root growth goes out pot for growing seedlings |
Embodiment 3 | 6.2 | ≥120 | ≤20 | Rice shoot growing way is good, and root growth goes out pot for growing seedlings |
Comparative example 1 | 7.6 | ≥150 | ≥30 | Rice shoot growing way is general, and root system does not grow pot for growing seedlings |
Comparative example 2 | 7.1 | ≥140 | ≥25 | Rice shoot growing way is general, and root system does not grow pot for growing seedlings |
Comparative example 3 | 5.3 | ≤100 | ≤15 | In seedling raising process, pot for growing seedlings splits, and influences nursery |
Comparative example 4 | 4.5 | ≤90 | ≤12 | In seedling raising process, pot for growing seedlings splits, and influences nursery |
By above-mentioned testing result it is found that the pot for growing seedlings prepared in embodiment 1-3 has preferable tensile strength, meet nursery rank
For section to the performance requirement of pot for growing seedlings, degradation speed in the soil is fast;And the pot for growing seedlings in comparative example 1 is after being crosslinked raw material
It is molded again, although mechanical property is more preferable, degradation speed in the soil significantly reduces, and is unfavorable for transplanting or determine
The fast-growth of plant root and stretching, extension after plant;The polyvinyl alcohol amount added in comparative example 2 is excessive, though the pot for growing seedlings being prepared
Right mechanical property is more preferable, but degradation speed in the soil significantly reduces, and plant root is quick after being unfavorable for transplanting or being colonized
Growth and stretching, extension;The polyvinyl alcohol amount added in comparative example 3 is too small, the pot for growing seedlings poor mechanical property being prepared, degradation speed
It is too fast, it is ruptured in seedling raising process, affects nursery, meanwhile, in preparation process, difficult forming;Pot for growing seedlings in comparative example 4
Crosslinking Treatment is not carried out, and the pot for growing seedlings poor mechanical property being prepared, degradation speed is too fast, is ruptured in seedling raising process, influences
Nursery.
Claims (10)
1. a kind of degradable sludge base pot for growing seedlings, which is characterized in that be prepared including following parts by weight raw material:2-5 parts
Polyvinyl alcohol, 80-100 parts of water, 5-10 parts of gelatin, 5-10 parts of dextrin, 5-20 parts of sludge, 0.5-1 parts of crosslinking agent;
The pot for growing seedlings in preparation process forming processes prior to crosslinking Treatment.
2. pot for growing seedlings according to claim 1, which is characterized in that the polyvinyl alcohol degree of polymerization is 500-2000.
3. pot for growing seedlings according to claim 2, which is characterized in that the polyvinyl alcohol degree of polymerization is 1000-1500.
4. pot for growing seedlings according to claim 1, which is characterized in that crosslinking agent is one in formaldehyde, acetaldehyde, epoxychloropropane
Kind is a variety of.
5. pot for growing seedlings according to claim 1, which is characterized in that the preparation method of pot for growing seedlings includes the following steps:
(1)Dissolving, decentralized processing:It is dissolved in water polyvinyl alcohol, gelatin and dextrin to form mixed solution;In mixed solution
Sludge is added, shaping dope is formed after mixing dispersion;
(2)Forming processes:It is molded with shaping dope, obtains pot for growing seedlings germule;
(3)Crosslinking Treatment:Pot for growing seedlings germule and crosslinking agent are subjected to cross-linking reaction, obtaining degradable sludge base after the completion of reaction educates
Seedling alms bowl.
6. pot for growing seedlings according to claim 5, which is characterized in that step(1)The solution temperature of middle polyvinyl alcohol is 90-
100℃。
7. pot for growing seedlings according to claim 5, which is characterized in that step(1)Middle gelatin and dextrin are dissolved as 70-80
℃。
8. pot for growing seedlings according to claim 5, which is characterized in that step(1)The temperature of middle shaping dope is 60-70 DEG C.
9. pot for growing seedlings according to claim 5, which is characterized in that step(3)The temperature of middle crosslinking Treatment is 50-60 DEG C,
Crosslinking time is 5-8h.
10. pot for growing seedlings according to claim 5, which is characterized in that step(3)After the completion of middle germule cross-linking reaction, also wrap
Include the carrying out washing treatment to pot for growing seedlings.
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CN201810648839.4A CN108476804A (en) | 2018-06-22 | 2018-06-22 | A kind of degradable sludge base pot for growing seedlings and preparation method thereof |
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CN201810648839.4A CN108476804A (en) | 2018-06-22 | 2018-06-22 | A kind of degradable sludge base pot for growing seedlings and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110679345A (en) * | 2019-11-11 | 2020-01-14 | 广西中医药大学 | A degradable seedling-raising alms bowl for mangrove breeds |
CN114341433A (en) * | 2019-09-06 | 2022-04-12 | 日本甜菜制糖株式会社 | Corrosion-resistant paper |
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Application publication date: 20180904 |