CN108468044A - 一种在铝合金表面制备掺杂石墨烯自组装复合膜的方法 - Google Patents
一种在铝合金表面制备掺杂石墨烯自组装复合膜的方法 Download PDFInfo
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- CN108468044A CN108468044A CN201810152785.2A CN201810152785A CN108468044A CN 108468044 A CN108468044 A CN 108468044A CN 201810152785 A CN201810152785 A CN 201810152785A CN 108468044 A CN108468044 A CN 108468044A
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- Prior art keywords
- aluminum alloy
- solution
- alloy surface
- doped graphene
- composite film
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Links
- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 37
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 239000002131 composite material Substances 0.000 title claims abstract description 13
- 238000000034 method Methods 0.000 title claims abstract description 11
- 239000000243 solution Substances 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000008367 deionised water Substances 0.000 claims abstract description 11
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 11
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims abstract description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011259 mixed solution Substances 0.000 claims abstract description 7
- 238000004506 ultrasonic cleaning Methods 0.000 claims abstract description 6
- 150000003384 small molecules Chemical class 0.000 claims abstract description 4
- 239000002904 solvent Substances 0.000 claims abstract description 4
- 238000001291 vacuum drying Methods 0.000 claims abstract description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 235000019441 ethanol Nutrition 0.000 claims description 6
- 229910000989 Alclad Inorganic materials 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 244000137852 Petrea volubilis Species 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- 238000004458 analytical method Methods 0.000 claims description 3
- 125000005909 ethyl alcohol group Chemical group 0.000 claims description 3
- 238000003760 magnetic stirring Methods 0.000 claims description 3
- 238000005498 polishing Methods 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- DPLVEEXVKBWGHE-UHFFFAOYSA-N potassium sulfide Chemical compound [S-2].[K+].[K+] DPLVEEXVKBWGHE-UHFFFAOYSA-N 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 238000005260 corrosion Methods 0.000 abstract description 11
- 230000007797 corrosion Effects 0.000 abstract description 10
- 239000011159 matrix material Substances 0.000 abstract description 3
- 238000002203 pretreatment Methods 0.000 abstract description 3
- 238000001338 self-assembly Methods 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract 1
- 230000003075 superhydrophobic effect Effects 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 239000000956 alloy Substances 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910001094 6061 aluminium alloy Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000002120 nanofilm Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
- C23C22/56—Treatment of aluminium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/02—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using non-aqueous solutions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/78—Pretreatment of the material to be coated
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
Description
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201810152785.2A CN108468044B (zh) | 2018-02-19 | 2018-02-19 | 一种在铝合金表面制备掺杂石墨烯自组装复合膜的方法 |
Applications Claiming Priority (1)
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CN201810152785.2A CN108468044B (zh) | 2018-02-19 | 2018-02-19 | 一种在铝合金表面制备掺杂石墨烯自组装复合膜的方法 |
Publications (2)
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CN108468044A true CN108468044A (zh) | 2018-08-31 |
CN108468044B CN108468044B (zh) | 2020-02-18 |
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CN201810152785.2A Active CN108468044B (zh) | 2018-02-19 | 2018-02-19 | 一种在铝合金表面制备掺杂石墨烯自组装复合膜的方法 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110644036A (zh) * | 2019-08-14 | 2020-01-03 | 桂林理工大学 | 一步电沉积法制备超疏水和自清洁复合功能膜层的方法 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101577151A (zh) * | 2009-06-12 | 2009-11-11 | 华北电力大学 | 一种抑制输电裸导线表面覆冰的方法 |
CN103469274A (zh) * | 2013-09-17 | 2013-12-25 | 中南大学 | 一种金属硫属化合物薄膜的制备方法 |
CN103966646A (zh) * | 2014-04-16 | 2014-08-06 | 湖北大学 | 一种还原氧化石墨烯/硅烷复合膜的电沉积制备方法及其用途 |
CN103985552A (zh) * | 2014-05-21 | 2014-08-13 | 南开大学 | 过渡金属硫化物与石墨烯复合材料对电极及其制备和应用 |
CN104630749A (zh) * | 2015-02-22 | 2015-05-20 | 桂林理工大学 | 一种铝合金表面耐腐蚀自组装掺杂膜层及其制备方法 |
CN105543824A (zh) * | 2016-01-21 | 2016-05-04 | 燕山大学 | 一种在铝合金表面制备锆/硒复合转化膜的方法 |
CN105543823A (zh) * | 2016-03-16 | 2016-05-04 | 燕山大学 | 一种在铝合金表面制备钛/硒多彩复合转化膜的方法 |
CN105925975A (zh) * | 2016-05-12 | 2016-09-07 | 上海渊泉集币收藏品有限公司 | 一种在银制品表面制备黄色系化学转化膜的方法 |
-
2018
- 2018-02-19 CN CN201810152785.2A patent/CN108468044B/zh active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101577151A (zh) * | 2009-06-12 | 2009-11-11 | 华北电力大学 | 一种抑制输电裸导线表面覆冰的方法 |
CN103469274A (zh) * | 2013-09-17 | 2013-12-25 | 中南大学 | 一种金属硫属化合物薄膜的制备方法 |
CN103966646A (zh) * | 2014-04-16 | 2014-08-06 | 湖北大学 | 一种还原氧化石墨烯/硅烷复合膜的电沉积制备方法及其用途 |
CN103985552A (zh) * | 2014-05-21 | 2014-08-13 | 南开大学 | 过渡金属硫化物与石墨烯复合材料对电极及其制备和应用 |
CN104630749A (zh) * | 2015-02-22 | 2015-05-20 | 桂林理工大学 | 一种铝合金表面耐腐蚀自组装掺杂膜层及其制备方法 |
CN105543824A (zh) * | 2016-01-21 | 2016-05-04 | 燕山大学 | 一种在铝合金表面制备锆/硒复合转化膜的方法 |
CN105543823A (zh) * | 2016-03-16 | 2016-05-04 | 燕山大学 | 一种在铝合金表面制备钛/硒多彩复合转化膜的方法 |
CN105925975A (zh) * | 2016-05-12 | 2016-09-07 | 上海渊泉集币收藏品有限公司 | 一种在银制品表面制备黄色系化学转化膜的方法 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110644036A (zh) * | 2019-08-14 | 2020-01-03 | 桂林理工大学 | 一步电沉积法制备超疏水和自清洁复合功能膜层的方法 |
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Application publication date: 20180831 Assignee: Guilin Changlong Machinery Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980044482 Denomination of invention: A Method for Preparing Doped Graphene Self assembled Composite Films on Aluminum Alloy Surface Granted publication date: 20200218 License type: Common License Record date: 20231027 Application publication date: 20180831 Assignee: Guilin Xinglong Metal Products Processing Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980044405 Denomination of invention: A Method for Preparing Doped Graphene Self assembled Composite Films on Aluminum Alloy Surface Granted publication date: 20200218 License type: Common License Record date: 20231026 |
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