CN108455766B - A kind of intelligent water treatment system of the solution containing smeary sea water - Google Patents
A kind of intelligent water treatment system of the solution containing smeary sea water Download PDFInfo
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- CN108455766B CN108455766B CN201810056676.0A CN201810056676A CN108455766B CN 108455766 B CN108455766 B CN 108455766B CN 201810056676 A CN201810056676 A CN 201810056676A CN 108455766 B CN108455766 B CN 108455766B
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- agitating shaft
- unit
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Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/444—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/463—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrocoagulation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/08—Seawater, e.g. for desalination
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/002—Construction details of the apparatus
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- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
The invention discloses a kind of intelligent water treatment system of the solution containing smeary sea water, including coagulating basin, electric flocculation unit, clear water reserviors, ultra filtration unit, reverse osmosis units and fresh-water pool；Automatic detection unit is equipped between the fresh-water pool and the reverse osmosis units;Film process unit is equipped between the clear water reserviors and ultra filtration unit, the film process unit is silicon carbide film processing unit.The present invention is by coagulation and electric flocculation two operations while carrying out, good purification;Film process is carried out using silicon carbide film processing unit, the greasy dirt in seawater can be completely removed substantially, further increase the effect of seawater cleaning;Secondly, automatic detection unit is set, purified water can be detected automatically, avoid containing harmful substance in water body, avoid impacting the health of human body.
Description
Technical field
The invention belongs to technical fields, more particularly, to a kind of intelligent water treatment system of the solution containing smeary sea water.
Background technique
Currently, with the rapid development of economy, be also at the state being skyrocketed through for the demand of fresh water, but due to light
Water resource is limited, and the shortage of freshwater resources is increasingly severe now.To solve the above-mentioned problems, occur in the prior art
It is the technology of drinking water by sea water desalination, to solve the problems, such as shortage of fresh water.But existing seawater is passed through due to being contaminated
Can often there be greasy dirt, traditional desalination system is difficult to effectively remove the greasy dirt in seawater, it is difficult to meet the needs of seawater cleaning.
Summary of the invention
The present invention for overcome the deficiencies in the prior art, provides that a kind of purifying water effect is good, high intelligent of oily waste degradation rate
Solve the water treatment system containing smeary sea water.
To achieve the goals above, the invention adopts the following technical scheme: a kind of intelligent water of the solution containing smeary sea water
Processing system, including coagulating basin, electric flocculation unit, clear water reserviors, ultra filtration unit, reverse osmosis units and fresh-water pool；The fresh-water pool
Automatic detection unit is equipped between the reverse osmosis units;Film process unit is equipped between the clear water reserviors and ultra filtration unit,
The film process unit is silicon carbide film processing unit.The present invention is by coagulation and electric flocculation two operations while carrying out, effectively
Remove the greasy dirt in seawater, guarantee in purified seawater will not residual greasy dirt, good purification;It is handled and is filled using silicon carbide film
Set carry out film process, for comparing traditional organic film process, have better oil resistance and membrane flux, can to greasy dirt into
Row effectively filtering, can completely remove the greasy dirt in seawater substantially, further increase the effect of seawater cleaning;Secondly, it is arranged certainly
Dynamic detection unit, can detect automatically purified water, avoid containing harmful substance in water body, avoid the health to human body
It impacts.
Further, the automatic detection unit includes for connecting the pipeline of the clear water reserviors and ultra filtration unit, being set to
Detection device on pipeline and the warning device being electrically connected with the detection device；Detect in purified water containing harmful substance or
When being not suitable for the substance that human body is drunk, warning device will be sounded an alarm, more intuitive prompt operator, and avoiding will be containing nocuousness
The water of substance is injected into clear water reserviors.
Further, the coagulating basin includes pond body, for the administration device of dosing coagulant into pond body and set on pond
Intracorporal agitating device, the agitating device include actuator, the driving member being connected with actuator, can stir with moving up and down
Axis, the agitating paddle on agitating shaft and for driving the agitating shaft in the vibrational structure moved up and down in pond body；It is logical
The setting of vibrational structure is crossed, so that during coagulation stirs a degree of up and down action can occur for agitating device, into
Enter so that seawater is completely in disturbance state in coagulation process, seawater mixes sufficiently with coagulant, and coagulation effect is good, to greasy dirt
Removal rate it is high, so that remaining organic matter, impurity etc. seldom, further promote the water quality of fresh water in seawater after desalination.
Further, the vibrational structure include the first vibration section part matched with the agitating shaft top and with it is described
The second vibration section part that agitating shaft lower part matches；So that agitating shaft top and the bottom can be vibrated effect, Oscillation Amplitude is big,
Mixing effect is good.
Further, the first vibration section part includes the grafting for supplying the driving member to penetrate set on the agitating shaft top
Slot, multiple rolling members between the inserting groove and driving member lower surface, multiple lower semispheres in the grafting groove bottom wall
Shape slot and multiple upper half spherical grooves on driving member lower surface, the upper and lower semi-spherical grooves are interleaved setting, described
There is spacing between driving member side wall and the inserting groove inner wall；When relatively rotating between agitating shaft and driving member, rolling
Moving part will move around in inserting groove, when and be stuck in lower half spherical groove, when and be stuck in upper half spherical groove, and due to it is upper,
Lower half spherical groove is staggered, and has spacing between the driving member side wall and the inserting groove inner wall；Due to spacing
In the presence of so that the shaking on left and right directions can occur between driving member and inserting groove, so that rolling member can constantly exist
It is moved on different location, so that the spacing between driving member lower surface and grafting groove bottom is straight in the diameter and rolling member of rolling member
Diameter subtracts to be changed between semi-spherical grooves diameter, to realize agitating shaft moving up and down with respect to driving member, and then agitating shaft
Movement up and down, on left and right directions can be reduced relative to driving member, the vibration of agitating shaft during rotation is realized, to confuse mixed
Seawater in solidifying pond guarantees that seawater is sufficiently mixed with coagulant, and coagulation effect is good, further increases purifying water effect and oily waste degradation
Rate.
Further, the radius of the upper and lower semi-spherical grooves is set greater than the radius of the rolling member；Avoid the occurrence of rolling
Moving part is stuck in semi-spherical grooves the case where can not moving place, reduces failure rate.
Further, the agitating shaft is equipped with the floating retaining member matched with the driving member, the floating anticreep
Component include two limit plates for being removably connected to the agitating shaft upper end, be set to the driving member on respectively with two limit plate phases
The elastic component that two accommodating chambers of cooperation and one end and the limit plate lower surface are connected, the elastic component other end and the accommodating chamber
It offsets；Limit plate is penetrated to accommodating chamber, be can effectively avoid agitating shaft and is disengaged with respect to driving member, equipment is avoided to break down；And
Due to the setting of elastic component so that limit plate can be carried out in accommodating chamber it is up and down, thus avoid limit plate and accommodating chamber it
Between cooperation the up and down action of agitating shaft is impacted.
Further, the pool bottom is equipped with the locating part matched with the agitating shaft；The second vibration section part
Including be set to the agitating shaft lower part matched with the locating part open slot, the ball between open slot and locating part,
Set on opening groove bottom wall on multiple upper grooves and multiple lower grooves on locating part upper surface, the upper and lower groove it
Between for interleaved be arranged；When relatively rotating between agitating shaft and locating part, ball will move around in open slot,
When and be stuck in lower groove, when and be stuck in upper groove, and since upper and lower groove is staggered, the locating part side wall
There is spacing between described the inner wall of the open slot；Due to the presence of spacing, so that left and right can occur between locating part and open slot
Shaking on direction, so that ball can be moved constantly on different location, so that locating part lower surface and open slot
Spacing between bottom surface is subtracted in the diameter and ball diameter of ball to be changed between groove diameter, to realize agitating shaft phase
Driving member is moved up and down, and then agitating shaft can reduce movement up and down, on left and right directions relative to driving member, realizes agitating shaft
Vibration during rotation guarantees that seawater is sufficiently mixed with coagulant, coagulation effect to confuse the seawater in coagulating basin
It is good.
Further, the agitating shaft is equipped with the first seal that matches with the driving member, on the agitating shaft
Equipped with the second seal matched with the locating part；By the setting of sealing element, coagulation in coagulating basin is effectively avoided to generate
Sediment enter in grafting chamber or open slot, so that sediment be avoided to be filled semi-spherical grooves and groove, guarantee equipment
Normal operation.
Further, described first seal one end and the driving member outer wall are connected, one end and the agitating shaft outer wall
It is connected.
Further, described second seal one end and the locating part outer wall are connected, one end and the agitating shaft outer wall
It is connected.
Further, the first seal, second seal at least partially corrugated structure are arranged；By corrugated
Structure, the floating for enabling the first, second sealing element to cooperate agitating shaft when agitating shaft shakes generate deformation, avoid pair
The movement of agitating shaft impacts.
In conclusion the invention has the following advantages that by coagulation and electric flocculation two operations while carrying out, clean-up effect
It is good;Film process is carried out using silicon carbide film processing unit, the greasy dirt in seawater can be completely removed substantially, further increase seawater
The effect of purification;Automatic detection unit is set, purified water can be detected automatically, avoid containing nuisance in water body
Matter avoids impacting the health of human body.
Detailed description of the invention
Fig. 1 is the structural diagram of the present invention.
Fig. 2 is the structural schematic diagram of coagulating basin of the invention.
Fig. 3 is the enlarged drawing in Fig. 2 at B.
Fig. 4 is the enlarged drawing in Fig. 2 at D.
Specific embodiment
In order to make those skilled in the art better understand the present invention program, below in conjunction in the embodiment of the present invention
Attached drawing, the technical scheme in the embodiment of the invention is clearly and completely described.
As shown in Figs 1-4, a kind of intelligent water treatment system of the solution containing smeary sea water, including coagulating basin 1, electric flocculation list
Member 2, clear water reserviors 3, ultra filtration unit 4, reverse osmosis units 5 and fresh-water pool 7；The electric flocculation unit 2 is using electrolytic coagulation to sea
The pool wall of the pond body that water is handled, the pond body can be made of cement or stainless steel；The fresh-water pool 7 and the reverse osmosis units
Automatic detection unit 6 is equipped between 5;The automatic detection unit includes pipeline 61, detection device 62 and warning device 63；Institute
It states pipeline one end to be connected with clear water reserviors 3, the other end is connected with the ultra filtration unit 4；The detection device 62 is set to pipeline
On, which is the water quality testing meter directly bought on the market, and the warning device 63 is the report directly bought on the market
Alert device, the warning device are electrically connected with the detection device, contain harmful substance or people in purified water when detection device detects
Impotable substance when, warning device will sound an alarm, and the principle of specific implementation is the prior art, repeat no more；Into one
Step, film process unit 10 is equipped between the clear water reserviors 3 and ultra filtration unit 4, the film process unit is silicon carbide film processing
Device, the silicon carbide film processing unit are the prior art, " the silicon carbide film filtering as disclosed in Chinese patent CN203525403U
Device ", so it will not be repeated.
Specifically, the coagulating basin 1 includes pond body 11, for the administration device 12 of dosing coagulant into pond body and is set to
The intracorporal agitating device in pond, the administration device 12 are the chemicals dosing plant directly bought on the market, and specific structure and principle are existing
There is technology；The agitating device include actuator 14, the driving member being connected with actuator 15, can move up and down ground agitating shaft 16,
Agitating paddle 17 on agitating shaft and for driving the agitating shaft 16 in the vibrational structure moved up and down in pond body 11；
The actuator is the motor bought on the market, and the driving member is the transmission shaft with the output shaft fixed connection of the motor；The vibration
Dynamic structure includes the first vibration section part 8 matched with 16 top of agitating shaft and match with the agitating shaft lower part
Two vibration components 9；Specifically, the first vibration section part 8 include inserting groove 81, multiple rolling members 82, lower half spherical groove 83 and
Upper half spherical groove 84, the inserting groove 81 are column construction, the agitating shaft top are set to, so that the driving member penetrates；Institute
Stating rolling member 82 is stainless steel ball, is set between the inserting groove and driving member lower surface；The lower half spherical groove 83 is set as
It is multiple, and be specially the radially multi-turn setting along the grafting groove bottom wall, every circle all has evenly spaced multiple lower semispheres
Shape slot 83, the spacing between an adjacent ring recess are set as equal；The upper half spherical groove 84 is also configured as multiple, and specially edge
The radially multi-turn of the driving member lower surface is arranged, and every enclose all has evenly spaced multiple upper half spherical grooves 84, and adjacent one
Spacing between ring recess is set as equal；Wherein, the semi-spherical grooves refer to that inner surface is the slot of spherical surface setting；As excellent
Choosing, the radius of the upper and lower semi-spherical grooves are set greater than the radius of the rolling member 82, convenient for rolling member by upper and lower hemisphere
It is rolled out in shape slot；Further, there is spacing, and upper and lower half between 15 side wall of driving member and 81 inner wall of the inserting groove
Spherical groove is interleaved setting, i.e., is a circle upper half spherical groove between two adjacent circle lower half spherical grooves.
Further, the agitating shaft 16 is equipped with the floating retaining member matched with the driving member, specifically, should
Floating retaining member includes two limit plates 201, two accommodating chambers 202 and elastic component 203, and the limit plate 201 is arcuate structure
Setting, is removably attachable on the upper surface of the agitating shaft by screw, and two accommodating chamber 202 is separately positioned on described
On the left and right sides of driving member, accommodating chamber 202 is similarly arcuate structure setting, and the height of accommodating chamber 202 should be set as big
In the thickness of limit plate 201, specifically, the limit plate a part is penetrated to the accommodating chamber 202, a part extend out to receiving
Chamber 202 is connected with the agitating shaft；The elastic component 203 is spring, which is connected to limit plate 201 and protrudes into
It to the part of accommodating chamber 202, and is connected on the lower surface, the lower end other end of elastic component 203 and the accommodating chamber 202 contradict and match
It closes, so that limit plate can move up and down in accommodating chamber.
Further, 11 bottom of pond body is equipped with the locating part 111 matched with the agitating shaft, the locating part 111
For the cylinder extended to form directly up by pool bottom；The second vibration section part include cylindrical open slot 91, ball 92,
Upper groove 93 and lower groove 94, the open slot 91 are set to 16 lower part of agitating shaft, for locating part insertion；It is described
Ball 92 is made of stainless steel, and is set as multiple, and ball 92 is set between the open slot and locating part；The upper groove 93
It is set as multiple, and is specially the radially multi-turn setting along the opening groove bottom wall, every circle all has evenly spaced multiple
Upper groove 93, the spacing between an adjacent ring recess are set as equal；The lower groove 94 is set as multiple, and is specially along described
The radially multi-turn of locating part upper surface is arranged, and every enclose all has evenly spaced multiple lower grooves 94, between an adjacent ring recess
Spacing be set as equal；Further, there is spacing between the locating part outer surface and described the inner wall of the open slot, and above,
It is arranged between lower groove for interleaved, specifically there is between two adjacent upper grooves a lower groove.
Preferably, the agitating shaft 16 is equipped with the first seal 161 matched with the driving member, the stirring
Axis 16 is equipped with the second seal 162 matched with the locating part；Specifically, the first seal 161 and the second sealing
Part 162 is rubber sleeve made of rubber, and is set in outside agitating shaft；The upper end of the first seal 161 with it is described
15 outer wall of driving member is connected, and lower end and 16 outer wall of agitating shaft are connected, and is specially to be bonded；Under the second seal 162
End is connected with 111 outer wall of locating part, and upper end and 16 outer wall of agitating shaft are connected, and is specially bonded, to effectively avoid
Sediment in coagulation process enters in the inserting groove and open slot；Preferably, the first seal 161 and
Two sealing elements, 162 a portion is set as wave-like or bending shape, so that first seal 161 and second seal
162 deformability is enhanced；The wave-like or bending shape can be in first seals 161 and second seal 162
Straight forming when processing or injection molding.
The clear water reserviors 3, fresh-water pool 7 are pond body made of stainless steel, are the prior art；The ultra filtration unit 4 is existing
There is technology may be implemented, such as ultrafiltration apparatus；The reverse osmosis units 5 also may be implemented for the prior art, and such as reverse osmosis seawater is light
Makeup is set；The deep desalting unit 6 also may be implemented for the prior art, such as continuous electric desalination device；Structure that so it will not be repeated
And working principle.
Obviously, described embodiment is only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment should fall within the scope of the present invention.
Claims (6)
1. a kind of intelligent water treatment system of the solution containing smeary sea water, including coagulating basin (1), electric flocculation unit (2), clear water reserviors
(3), ultra filtration unit (4), reverse osmosis units (5) and fresh-water pool (7)；It is characterized by: the fresh-water pool (7) with it is described reverse osmosis
Automatic detection unit (6) are equipped between unit (5);Film process unit is equipped between the clear water reserviors (3) and ultra filtration unit (4)
(10), the film process unit is silicon carbide film processing unit；The coagulating basin (1) includes pond body (11), for into pond body
The administration device (12) of dosing coagulant and be set to the intracorporal agitating device in pond, the agitating device include actuator (14), with
The connected driving member (15) of actuator can be moved up and down to drive seawater to generate the agitating shaft (16) of disturbance state, be set to stirring
Agitating paddle (17) on axis and for driving the vibrational structure moved up and down in the agitating shaft (16) Yu Chiti (11)；Institute
Stating vibrational structure includes the first vibration section part (8) matched with the agitating shaft (16) top, the first vibration section part (8) packet
It includes the inserting groove (81) for being set to the agitating shaft top and penetrating for the driving member, multiple rolling members (82) and is caught in for rolling member
Multiple lower half spherical grooves (83), lower half spherical groove (83) be set to the grafting groove bottom wall on；When being sent out between agitating shaft and driving member
It is raw when relatively rotating, rolling member can interval be caught in in lower half spherical groove so that driving member lower surface and grafting groove bottom it
Between spacing change;Pond body (11) bottom is equipped with the locating part (111) matched with the agitating shaft；The vibration
Dynamic structure further includes the second vibration section part (9) matched with agitating shaft lower part, which includes being set to described stir
It mixes open slot (91) that axis (16) lower part matches with the locating part, the ball (92) between open slot and locating part, set
It is described upper and lower in multiple upper grooves (93) in opening groove bottom wall and multiple lower grooves (94) on locating part upper surface
It is arranged between groove for interleaved.
2. intelligent water treatment system of the solution containing smeary sea water according to claim 1, it is characterised in that: described automatic
Detection unit includes for connecting the clear water reserviors (3) and the pipeline (61) of ultra filtration unit (4), the detection device on pipeline
(62) and with the detection device warning device (63) being electrically connected.
3. intelligent water treatment system of the solution containing smeary sea water according to claim 1, it is characterised in that: the transmission
Part lower surface is equipped with multiple upper half spherical grooves (84), upper half spherical groove and lower half spherical groove as interleaved setting, the biography
There is spacing between moving part (15) side wall and the inserting groove (81) inner wall.
4. intelligent water treatment system of the solution containing smeary sea water according to claim 3, it is characterised in that: on described,
The radius of lower half spherical groove is set greater than the radius of the rolling member (82).
5. intelligent water treatment system of the solution containing smeary sea water according to claim 1, it is characterised in that: the stirring
Axis (16) is equipped with the floating retaining member matched with the driving member, which includes being removably connected to institute
Two limit plates (201) for stating agitating shaft upper end, two accommodating chambers matched respectively with two limit plates on the driving member
(202) and the elastic component (203) that is connected of one end and the limit plate lower surface, elastic component (203) other end and the receiving
Chamber (202) offsets.
6. intelligent water treatment system of the solution containing smeary sea water according to claim 1, it is characterised in that: the stirring
Axis (16) is equipped with the first seal (161) matched with the driving member, and the agitating shaft (16) is equipped with and the limit
The second seal (162) that position part matches.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810056676.0A CN108455766B (en) | 2018-01-21 | 2018-01-21 | A kind of intelligent water treatment system of the solution containing smeary sea water |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810056676.0A CN108455766B (en) | 2018-01-21 | 2018-01-21 | A kind of intelligent water treatment system of the solution containing smeary sea water |
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| CN108455766B true CN108455766B (en) | 2019-03-29 |
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| CN109095698A (en) * | 2018-09-13 | 2018-12-28 | 苏州特曼清环保科技有限公司 | One kind filtering industrial waste water high-efficiency processing equipment based on electrochemistry and film |
| CN113493239A (en) * | 2021-08-23 | 2021-10-12 | 中国科学院生态环境研究中心 | Electrochemical treatment device, seawater desalination system and method |
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| FR2927622B1 (en) * | 2008-02-14 | 2014-08-01 | Otv Sa | METHOD FOR WATER TREATMENT BY A NANOFILTRATION OR REVERSE OSMOSIS MEMBRANE SYSTEM ENABLING HIGH CONVERSION RATES BY ELIMINATING ORGANIC MATTER. |
| CN101306895B (en) * | 2008-07-11 | 2010-09-01 | 东北大学 | Device for treating oil extraction waste water by coagulation-electrocoagulation-ultrafiltration method and the method |
| CN102336491A (en) * | 2010-07-14 | 2012-02-01 | 北京纬纶华业环保科技股份有限公司 | Advanced treatment and recycling method for polymer-bearing oil extraction waste water |
| CN103601310B (en) * | 2013-07-15 | 2016-03-30 | 浙江斯科能科技股份有限公司 | A kind of seawater desalination system water treatment method and device thereof |
| CN104649436A (en) * | 2013-11-20 | 2015-05-27 | 联安海洋工程（天津）有限公司 | Separation treatment apparatus of marine oil stain sewage |
| CN206481897U (en) * | 2016-11-30 | 2017-09-12 | 犍为县雩龙茶业有限公司 | A kind of efficient tea deblocking machine |
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